WO2018088831A9 - Method for preparing stick-type cosmetic composition - Google Patents

Method for preparing stick-type cosmetic composition Download PDF

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Publication number
WO2018088831A9
WO2018088831A9 PCT/KR2017/012712 KR2017012712W WO2018088831A9 WO 2018088831 A9 WO2018088831 A9 WO 2018088831A9 KR 2017012712 W KR2017012712 W KR 2017012712W WO 2018088831 A9 WO2018088831 A9 WO 2018088831A9
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WO
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Prior art keywords
stick
cosmetic composition
weight
composition
clay mineral
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PCT/KR2017/012712
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French (fr)
Korean (ko)
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WO2018088831A1 (en
Inventor
이진성
김진모
이성천
Original Assignee
한국콜마주식회사
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Priority claimed from KR1020170144655A external-priority patent/KR102099209B1/en
Application filed by 한국콜마주식회사 filed Critical 한국콜마주식회사
Priority to US16/342,751 priority Critical patent/US10857074B2/en
Publication of WO2018088831A1 publication Critical patent/WO2018088831A1/en
Publication of WO2018088831A9 publication Critical patent/WO2018088831A9/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216Solid or semisolid forms
    • A61K8/0229Sticks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • A61K8/375Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06Lipsticks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/001Preparations for care of the lips

Definitions

  • Stick-type cosmetics are easy to use and have excellent portability.
  • lipsticks which are traditional stick-type cosmetics, sunscreens, stick-based foundations, and the like, are being widely used.
  • the stick cosmetics have a problem of being easily broken by external impact or skin application due to the inherent limitations of the components of the cosmetic composition.
  • there have been attempts to increase the content of wax in the cosmetic composition but if the content of the wax is increased, the strength of the formulation is excessively increased, the skin spreadability is lowered, and the user may due to the unique aroma of the wax. There is a limit to discomfort.
  • a stick-type formulation prepared by disposing a material having excellent mechanical properties in the center of the formulation and disposing a cosmetic composition on its outer shell is known, this method does not solve the limitations inherent in the cosmetic composition.
  • the cosmetic composition is peeled off, there is a problem such as some cracking and dropping phenomenon thereby.
  • Patent Document 1 KR 2011-0110763 A
  • the present invention as a method for producing a stick cosmetic composition, the method, based on the total weight of the composition, by mixing 0.01 to 7% by weight of clay mineral and 0.05 to 35% by weight of the first emollient, A first stabilization step of forming a clay mineral dispersion; And a second stabilizing step of mixing a moisturizing component of 0.01 to 45% by weight and a first surfactant of 0.01 to 10% by weight to form a moisturizing component dispersion; And adding the clay mineral dispersion and the moisturizing component dispersion to the oil phase.
  • the present invention provides a stick cosmetic composition prepared by the above method.
  • Method for producing a stick-like cosmetic composition of one aspect of the present invention including the step of separately stabilizing the clay mineral dispersion and the moisturizing component, it is possible to uniformly disperse the components in the composition.
  • the stick-like composition is easily broken because the components are not evenly dispersed and separation occurs between the components in the formulation.
  • the stick-shaped cosmetic composition prepared by the above method has the advantage of not easily being broken while maintaining the application and feeling of use. There is this.
  • FIG. 1 is a side view (FIG. 1A) and a schematic diagram (FIG. 1B) of a stick-shaped formulation according to an aspect of the present invention.
  • FIG. 2 is a side view (FIG. 2A) of a stick-type formulation when the stabilization of the clay mineral and stabilization of the moisturizing component are not performed (Comparative Example 1-1), and a schematic view thereof (FIG. 2B).
  • FIG. 3 is a side view (FIG. 3A) and a schematic view (FIG. 3B) of a stick-type formulation in the case of stabilizing clay minerals only (Comparative Example 1-2).
  • FIG. 4 is a stick in the case where glycerine is added after adding stearylconium hectorite, caprylic / capric triglyceride, cetearyl olivate / sorbitan oleate simultaneously to the oil phase (Comparative Example 2-1) It is a side photograph (FIG. 4A) of a type
  • the present invention in one aspect, as a method for producing a stick-like cosmetic composition, the method, based on the total weight of the composition, by mixing 0.01 to 7% by weight of clay mineral and 0.05 to 35% by weight of the first emollient, clay Forming a mineral dispersion, the first stabilizing step; And a second stabilizing step of mixing the moisturizing component with 0.01 to 45 wt% and the first surfactant with 0.01 to 10 wt% to form a moisturizing component dispersion; And adding the clay mineral dispersion and the moisturizing component dispersion to the oil phase.
  • a method for preparing a stick cosmetic composition is performed by separately stabilizing clay minerals and moisturizing components, and mixing them with an oil phase portion including wax, so that the clay component and the moisturizing component are uniform in the composition. It is dispersed and does not break well.
  • the stick-like cosmetic composition due to the morphological characteristics extending in one direction, the components contained in the composition is settled downwardly in the height direction of the formulation by stoke's law, and is uniformly distributed in the composition. If the composition comprises clay minerals, the viscosity of the composition may increase, which may slow down the settling rate of the components in the composition.
  • the clay mineral and the moisturizing component is uniformly dispersed in the composition, each particle size is reduced, the effect of reducing the sedimentation rate is have.
  • the composition which is an aspect of the present invention, reduces the sedimentation rate of the components in the composition, thereby minimizing the uniform distribution in the composition of the components contained in the composition and minimizing the separation of the components in the formulation. This breakage can be improved.
  • the step of adding the clay mineral dispersion and the moisturizing component dispersion to the oil phase may include adding a clay mineral dispersion to the oil phase, and then adding a moisturizing component dispersion.
  • the moisturizing component when the moisturizing component is a water-soluble substance, the stability of the formulation due to separation from the oil component may be a problem.
  • the moisturizing component since the moisturizing component is first stabilized and uniformly dispersed in the composition, Separation can be minimized and formulation breakage can be improved.
  • the clay mineral may be included in 0.01 to 7% by weight, preferably, 0.03 to 6% by weight, more preferably 0.05 to 5% by weight. If the content of the clay mineral is less than 0.05% by weight, based on the total weight of the composition, the moisturizing component may not be able to interact stably with the moisturizing component, thereby breaking down the stick formulation. In addition, when the content of the clay mineral is more than 5% by weight, there is a limit that the feeling of using the stick-type cosmetic composition becomes stiff, and the moisturizing power is lowered.
  • the first emollient based on the total weight of the composition, may be included in 0.05 to 35% by weight, preferably, may be included in 0.3 to 30% by weight, more preferably, 0.25 ⁇ It may be included in 25% by weight.
  • the first emollient when the total weight of the clay mineral 100 parts by weight, may be included in the weight portion of 300 ⁇ 1000.
  • the first emollient when the total weight of the clay mineral 100 parts by weight, may be included in an amount of less than 300 parts by weight when the total weight of the clay mineral is 100 parts by weight, the stability of the formulation is inferior since uniform dispersion of the clay mineral is not achieved in the composition.
  • the first emollient may be included in an amount of preferably 500 to 1000 parts by weight.
  • the first emollient may include, but is not limited to, caprylic capric triglyceride.
  • the moisturizing component based on the total weight of the composition, may be included in 0.01 to 45% by weight, preferably, 0.05 to 40% by weight, more preferably, 0.1 to 35% by weight Can be.
  • the moisturizing power of the cosmetic composition may be remarkably decreased, and when the content of the moisturizing component is more than 35% by weight, separation in the formulation may occur, thereby lowering the formulation stability of the cosmetic composition.
  • the moisturizing component may be a water-soluble moisturizing component.
  • the moisturizing component may include glycerin.
  • the first surfactant may be included in 0.01 to 10% by weight, based on the total weight of the composition, preferably, 0.05 to 7% by weight, more preferably, 0.1 to 5 It may be included in weight percent. If the content of the first surfactant is less than 0.1% by weight, separation occurs because the moisturizing component cannot be dispersed and emulsified stably. If it exceeds 5% by weight, the moisturizing ingredients are not finely dispersed but agglomerated with each other, and the moisturizing ingredients cannot be uniformly dispersed in the cosmetic composition. For example, when the content of the first surfactant exceeds 5% by weight, the average particle diameter of the moisturizing ingredient-containing material exceeds 10 ⁇ m, and the moisturizing ingredient cannot be uniformly dispersed in the cosmetic composition.
  • the moisturizing component-containing material may include a substance containing only a moisturizing component and a substance including other components in addition to the moisturizing component.
  • the average particle diameter may mean an average value of the lengths of two axes measured at any point except the longest axis and the shortest axis of the diameter of the particle.
  • the first surfactant may include cetearyl olivate, sorbitan olivate or a mixture thereof.
  • the clay mineral may include a plate-like mineral.
  • the plate-like mineral may include smectite.
  • the smectite may comprise hectorite or bentorite and may preferably be hectorite.
  • the clay mineral when the clay mineral is hectorite, the components in the stick cosmetic composition are most uniformly dispersed, and the physical strength of the stick cosmetic composition is excellent.
  • the clay mineral may be stearalconium hectorite.
  • the first stabilizing step may include stirring the clay mineral and the first emollient at 1000 ⁇ 2500rpm, preferably, can be stirred at 1500 ⁇ 2000rpm.
  • the stirring speed of the first stabilization step is less than 1000 rpm, the clay mineral is not sufficiently swelled in the first emollient to obtain the viscosity necessary to obtain a stable formulation.
  • the stirring speed of the first stabilization step exceeds 2500rpm, bubbles in the composition are excessively generated, thereby lowering the stability of the formulation.
  • the second stabilizing step may include mixing the moisturizing component and the first surfactant.
  • the temperature of the second stabilization step may be preferably 75 ⁇ 85 °C.
  • the temperature of the second stabilization step is less than 60 ° C., the solid surfactant cannot be dissolved, and if it exceeds 90 ° C., the components in the composition may be thermally deformed or volatilized off.
  • the oil phase portion may be formed by mixing 5 to 40% by weight of wax, 0.01 to 10% by weight of the second surfactant, and the balance of the second emollient based on the total weight of the composition.
  • the oil phase may further comprise butter or preservatives.
  • the butter may be included in 1 to 5% by weight, preferably, 2.5 to 3.5% by weight based on the total weight of the composition.
  • the butter may be a mango butter, shea butter, cocoa butter, or jojoba butter, but is not limited thereto.
  • the preservative based on the total weight of the composition, may be included in 0.03 to 1.5% by weight, preferably, 0.05 to 1.3% by weight may be included.
  • the preservative may be ethylhexylglycerin or 1,2-hexanediol, but is not limited thereto.
  • the wax may be included in 5 to 40% by weight, preferably, 6 to 35% by weight, more preferably 10 to 30% by weight based on the total weight of the composition. If the content of the wax is less than 10% by weight based on the total weight of the composition, it is difficult to form a stick-shaped formulation, and if it exceeds 30% by weight, the strength is too high, so that the applicability, in particular to the lips, may be reduced.
  • the wax may include one or more selected from the group consisting of carnauba wax, candelilla wax, propolis wax, ozokerite, microcrystalline wax and bees wax, but is not limited thereto. .
  • the second surfactant may be included in 0.01 to 10% by weight, preferably, 0.05 to 8% by weight, more preferably, may be included in 0.1 to 7% by weight.
  • the content of the second surfactant is less than 0.1% by weight, the components in the composition may not be stably and uniformly dispersed and emulsified, and when 7% by weight or more is included, formulation separation may occur.
  • the second surfactant may include, but is not limited to, Cetyl PEG / PIGJI-10 / 1 dimethicone (Cetyl PEG / PPG-10 Dimethicone) or sorbitan sulfate. .
  • the second emollient may include, but is not limited to, at least one selected from the group consisting of macadamia seed oil, pentaerythritol tetraisostearate, and caprylic capric triglyceride.
  • the present invention is a stick cosmetic composition prepared by the above method.
  • the cosmetic composition may be a composition for lips. Lips are difficult to produce a lip stick formulation with adequate applicability due to the structural specificity of the lips itself (e.g., bulky relative to area and no bone-like structure inside the lips). Stick-like cosmetic composition according to an aspect of the present invention, there is an advantage that does not break well, while maintaining the optimum applicability when applied to the lips.
  • the stick cosmetic composition may be for lip makeup, lip moisturizing or skin makeup.
  • the stick cosmetic composition may be lipstick or lip gloss, but is not limited thereto.
  • the composition for skin makeup may include, but is not limited to, a stick-type sunscreen, a stick-based foundation, a stick-type cleanser, and the like.
  • Stearylconium hectorite and 10% by weight of caprylic / capric triglycerides of 2% by weight relative to the total weight of the composition were stirred for 30 minutes at 1500-2000 rpm in a high speed stirrer to stabilize the clay minerals by first dispersing them in the emollient.
  • Glycerin of 10% by weight relative to the total weight of the composition and 3% by weight of cetearylolivate / sorbitanolate were dissolved at 75 ° C. to 85 ° C., and then emulsified in a high speed homomixer to stabilize the dispersion by glycerin.
  • Example 1-1 To prepare the oil phase by mixing the components shown in Table 1 at 80 ⁇ 85 °C. The stabilized clay mineral of Example 1-1 was then added to the oil phase and stirred and dispersed using a homomixer.
  • Example 1-2 the stabilized glycerin-cetearylolivate / sorbitan sulfate of Example 1-2 was added and again stirred and dispersed using a homomixer to prepare a composition. Thereafter, bubbles in the composition were removed, and impurities were filtered to finally prepare the composition, which was then prepared into a stick formulation.
  • a panel test was conducted for 50 women and 50 male panels for feeling of use (soft, moisturizing, long lasting and formulation stability).
  • the stick formulation prepared in Example 1 was rinsed with water, dried, and then applied with 0.1 g, and after 1 minute, the feeling of use was evaluated. Mold stability was assessed for crushing, crushing, or formulation stability upon lip application. The evaluation score was given as 5 points when the feeling of use was very excellent and 1 point when the feeling was very insufficient, and 1 point was given from 5 points, and the average value of the sum total of the scores of each panel was calculated
  • the results are shown in Table 2 below.
  • Example 2 Except that the clay mineral used in the stabilization step of Example 1 and the surfactant was not used, the components of the same composition as in Example 1 were mixed at the same time to prepare a general stick type formulation. In the same manner as in Experimental Example 1 for the general stick-type formulation, the feeling panel test was conducted, and the results are shown in Table 2 below.
  • the stick formulation of the present invention which has undergone the stabilization step, is generally much more comfortable than the general stick formulation that has not undergone the stabilization step, and in particular, the molding stability is about 2.5 times or more. 2).
  • a stick-type formulation was prepared in the same manner as in Example 1 except that the separate moisturizing component described in Example 1-2 was not subjected to stabilization. Thereafter, the physical properties of the stick-type formulation were measured in the same manner as in Experimental Example 1, and are shown in Table 3. In this case, due to the precipitation of glycerin, it can be seen that the physical stability of the stick is greatly reduced (Fig. 3).
  • a stick-type formulation was prepared in the same manner as in Example 1 except that the separate viscosity minerals described in Example 1-1 were not subjected to stabilization. Thereafter, the physical properties of the stick-type formulation were measured in the same manner as in Experimental Example 1, and are shown in Table 4. Even in this case, it was found that due to the precipitation of glycerin, the physical stability of the stick was greatly reduced. In this case, the side view of the stick-type formulation was similar to FIG. 3.
  • Example 2 Unlike Example 1, 2% by weight of stearylconium hectorite, 10% by weight of caprylic / capric triglycerides, and 3% by weight of cetearylolate / sorbitanate were added simultaneously to the oil phase. Thereafter, 10% by weight of glycerin was added to prepare a stick formulation. Then, the physical properties of the stick-type formulations were measured by the method described in Experimental Example 1. Even in this case, the glycerin was not stabilized, and it was found that the physical stability of the stick was greatly decreased (FIG. 4).
  • Comparative Example 3-1 Comparative Example 3-2 Comparative Example 3-3 Comparative Example 3-4 Comparative Example 3-5 Comparative Example 3-6 Comparative Example 3-7 Comparative Example 3-8 Stearalconium hectorite 2 wt% 2 wt% 2 wt% 2 wt% 2 wt% 2 wt% 0.008% by weight 7.5 wt% Caprylic / Capric Triglycerides 10 wt% 10 wt% 0.008% by weight 36% by weight 10 wt% 10% by weight 10% by weight 10% by weight glycerin 0.008% by weight 46 wt% 10% by weight 10% by weight 10% by weight 10% by weight 10% by weight 10% by weight 10% by weight 10% by weight Cetearyl Olate / Sorbitan Olate 3 wt% 3 wt% 3 wt% 0.008% by weight 11 wt% 3 wt% 3 wt%
  • the temperature of the oil phase part was set to 50 degreeC, 68 degreeC, 86 degreeC, and 90 degreeC, and it named each as the comparative example 4-2a, 4-2b, 4-2c, 4-2d. Thereafter, the physical properties were evaluated in the same manner as in Experiment 1.

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Abstract

The present specification discloses a method for preparing a stable stick-type cosmetic composition, and a stick-type cosmetic composition prepared by using same. The method for preparing the stick-type cosmetic composition according to an aspect of the present invention includes a step of separately stabilizing a moisturizing component and a clay mineral dispersion, and thus can uniformly disperse components in the composition. Since components are not uniformly dispersed in a typical stick-type composition, a stick formulation prepared by using the typical stick-type composition can be easily broken by an external impact or the like. However, a stick formulation prepared by the above method has the advantage of not being easily broken, while also retaining applicability and feel of use.

Description

스틱형 화장료 조성물의 제조방법Manufacturing method of stick type cosmetic composition
본 명세서에는, 안정적인 스틱형 화장료 조성물을 제조하는 방법 및 이를 이용하여 제조된 스틱형 화장료 조성물이 개시된다.In the present specification, a method of preparing a stable stick cosmetic composition and a stick cosmetic composition prepared using the same are disclosed.
스틱형 화장품은 사용이 간편하고, 휴대성이 우수하여, 전통적인 스틱형 화장품인 립스틱 외에도, 자외선 차단제, 스틱형 파운데이션 등 그 활용 분야가 확대되고 있다. Stick-type cosmetics are easy to use and have excellent portability. In addition to lipsticks, which are traditional stick-type cosmetics, sunscreens, stick-based foundations, and the like, are being widely used.
그러나, 스틱형 화장료는, 화장료 조성물의 성분이 갖는 내재적인 한계에 의해 외부의 충격에 의하거나, 피부 적용시 쉽게 부러지는 문제점이 있다. 이러한 문제점을 보완하기 위하여, 화장료 조성물 내의 왁스 등의 함량을 증가시키는 시도가 있었으나, 왁스의 함량이 증가하면, 제형의 강도가 지나치게 증가하여, 피부 발림성이 떨어지고, 왁스 등의 특유의 향으로 인해 사용자에게 불쾌감을 초래한다는 한계가 있다. 또한, 제형 중심부에 기계적 물성이 우수한 물질을 배치하고, 그 외각에 화장료 조성물을 배치하여 제조한 스틱형 제형도 알려져 있지만, 이러한 방법은 화장료 조성물이 내재적으로 갖는 한계를 해결한 것이 아니어서, 중심부로부터 화장료 조성물이 탈피되거나, 일부 균열 및 그로 인한 탈락현상 등의 문제점이 있다.However, the stick cosmetics have a problem of being easily broken by external impact or skin application due to the inherent limitations of the components of the cosmetic composition. In order to compensate for this problem, there have been attempts to increase the content of wax in the cosmetic composition, but if the content of the wax is increased, the strength of the formulation is excessively increased, the skin spreadability is lowered, and the user may due to the unique aroma of the wax. There is a limit to discomfort. In addition, although a stick-type formulation prepared by disposing a material having excellent mechanical properties in the center of the formulation and disposing a cosmetic composition on its outer shell is known, this method does not solve the limitations inherent in the cosmetic composition. The cosmetic composition is peeled off, there is a problem such as some cracking and dropping phenomenon thereby.
[선행기술 문헌]Prior Art Literature
(특허문헌 1) KR 2011-0110763 A(Patent Document 1) KR 2011-0110763 A
일 측면에서, 본 발명의 목적은, 스틱형 화장료 조성물 내 함유된 성분들을 균일하게 분산시키는 방법을 제공하는 것이다.In one aspect, it is an object of the present invention to provide a method for uniformly dispersing the components contained in the stick cosmetic composition.
일 측면에서, 본 발명의 목적은, 피부에의 발림성을 유지하면서, 쉽게 부러지지 않는 스틱형 화장료 조성물을 제공하는 것이다.In one aspect, it is an object of the present invention to provide a stick cosmetic composition that does not easily break while maintaining applicability to the skin.
일 측면에서, 본 발명은, 스틱형 화장료 조성물의 제조방법으로서, 상기 방법은, 조성물 총 중량을 기준으로, 0.01~7 중량%의 점토 광물 및 0.05~35 중량%의 제1 에몰리언트를 혼합하여, 점토 광물 분산물을 형성하는, 제1 안정화 단계; 및 0.01~45 중량%의 보습 성분 및 0.01~10 중량%의 제1 계면활성제를 혼합하여, 보습성분 분산물을 형성하는, 제2 안정화 단계; 및 유상부에 상기 점토 광물 분산물 및 보습 성분 분산물을 첨가하는 단계를 포함하는, 스틱형 화장료 조성물의 제조방법을 제공한다.In one aspect, the present invention, as a method for producing a stick cosmetic composition, the method, based on the total weight of the composition, by mixing 0.01 to 7% by weight of clay mineral and 0.05 to 35% by weight of the first emollient, A first stabilization step of forming a clay mineral dispersion; And a second stabilizing step of mixing a moisturizing component of 0.01 to 45% by weight and a first surfactant of 0.01 to 10% by weight to form a moisturizing component dispersion; And adding the clay mineral dispersion and the moisturizing component dispersion to the oil phase.
일 측면에서, 본 발명은, 상기 방법으로 제조된 스틱형 화장료 조성물을 제공한다.In one aspect, the present invention provides a stick cosmetic composition prepared by the above method.
본 발명의 일 측면인 스틱형 화장료 조성물의 제조방법은, 점토 광물 분산물과, 보습 성분을 별도로 안정화시키는 단계를 포함하여, 조성물 내 성분들을 균일하게 분산시킬 수 있다. 일반적인 스틱형 조성물은, 성분들이 고르게 분산되지 않고, 제형 내 성분간의 분리 현상이 나타나기 때문에, 부러지기 쉬운데, 상기 방법에 의하여 제조된 스틱형 화장료 조성물은, 발림성과 사용감을 유지하면서도, 쉽게 부러지지 않는 장점이 있다.Method for producing a stick-like cosmetic composition of one aspect of the present invention, including the step of separately stabilizing the clay mineral dispersion and the moisturizing component, it is possible to uniformly disperse the components in the composition. In general, the stick-like composition is easily broken because the components are not evenly dispersed and separation occurs between the components in the formulation. The stick-shaped cosmetic composition prepared by the above method has the advantage of not easily being broken while maintaining the application and feeling of use. There is this.
도 1은 본 발명의 일 측면에 따른 스틱형 제형의 측면 사진(도 1a)과, 그 모식도(도 1b)이다.1 is a side view (FIG. 1A) and a schematic diagram (FIG. 1B) of a stick-shaped formulation according to an aspect of the present invention.
도 2는 점토광물의 안정화 및 보습성분의 안정화를 모두 하지 않은 경우(비교예 1-1) 스틱형 제형의 측면 사진(도 2a)과, 그 모식도(도 2b)이다.2 is a side view (FIG. 2A) of a stick-type formulation when the stabilization of the clay mineral and stabilization of the moisturizing component are not performed (Comparative Example 1-1), and a schematic view thereof (FIG. 2B).
도 3은 점토광물의 안정화만 실시한 경우(비교예 1-2) 스틱형 제형의 측면 사진(도 3a)과, 그 모식도(도 3b)이다.3 is a side view (FIG. 3A) and a schematic view (FIG. 3B) of a stick-type formulation in the case of stabilizing clay minerals only (Comparative Example 1-2).
도 4는 스테아릴코늄헥토라이트, 카프릴릭/카프릭트리글리세라이드, 세테아릴올리베이트/소르비탄올리베이트를 동시에 유상부에 첨가한 이후에 글리세린을 첨가한 경우(비교예 2-1)의 스틱형 제형의 측면 사진(도 4a)과, 그 모식도(도 4b)이다. 4 is a stick in the case where glycerine is added after adding stearylconium hectorite, caprylic / capric triglyceride, cetearyl olivate / sorbitan oleate simultaneously to the oil phase (Comparative Example 2-1) It is a side photograph (FIG. 4A) of a type | mold formulation, and the schematic diagram (FIG. 4B).
이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
본 명세서에서 '제1', '제2'와 같은 표현은, 각 성분 및 제조 단계들을 구분하기 위한 것으로서, 성분의 첨가 또는 혼합 순서, 제조 단계간의 순서를 한정하기 위한 것이 아니다.In this specification, expressions such as 'first' and 'second' are used to distinguish each component and manufacturing steps, and are not intended to limit the order of adding or mixing the ingredients or the order between the manufacturing steps.
본 발명은 일 측면에서, 스틱형 화장료 조성물의 제조방법으로서, 상기 방법은, 조성물 총 중량을 기준으로, 0.01~7 중량%의 점토 광물 및 0.05~35 중량%의 제1 에몰리언트를 혼합하여, 점토 광물 분산물을 형성하는, 제1 안정화 단계; 및 0.01~45 중량%의 보습 성분 및 0.01~10 중량%의 제1 계면활성제를 혼합하여, 보습 성분 분산물을 형성하는, 제2 안정화 단계; 및 유상부에 상기 점토 광물 분산물 및 보습 성분 분산물을 첨가하는 단계를 포함하는, 스틱형 화장료 조성물의 제조방법이다.The present invention in one aspect, as a method for producing a stick-like cosmetic composition, the method, based on the total weight of the composition, by mixing 0.01 to 7% by weight of clay mineral and 0.05 to 35% by weight of the first emollient, clay Forming a mineral dispersion, the first stabilizing step; And a second stabilizing step of mixing the moisturizing component with 0.01 to 45 wt% and the first surfactant with 0.01 to 10 wt% to form a moisturizing component dispersion; And adding the clay mineral dispersion and the moisturizing component dispersion to the oil phase.
본 발명의 일 측면인, 스틱형 화장료 조성물의 제조방법은, 점토 광물과 보습 성분을 각각 별도로 안정화 공정을 거친 후에, 왁스 등을 포함하는 유상부와 혼합함으로써, 점토 성분과 보습성분이 조성물 내 균일하게 분산되어, 잘 부러지지 않는다. 특히, 스틱형 화장료 조성물은, 일방향으로 길게 연장된 형태적 특성에 의해, 조성물 내에 포함된 성분들이 stoke의 법칙에 의해, 제형의 높이 방향상의 하부로 침강하여, 조성물 내에서 분균일하게 분포하게 되는데, 조성물이 점토 광물을 포함하면, 조성물의 점성이 증가하여, 조성물 내 성분들의 침강 속도를 저하시킬 수 있다. 또한, 본 발명의 제1 안정화 단계 및/또는 제2 안정화 단계를 거치면, 점토 광물과, 보습 성분이 조성물 내에 균일하게 분산되어, 각각의 입자 크기가 감소하여, 침강 속도를 저하시킬 수 있는 효과가 있다. 본 발명의 일 측면인 조성물은, 조성물 내 성분들의 침강 속도가 감소하므로, 조성물 내 함유된 성분들의 조성물 내에서의 분균일한 분포를 최소화하고, 제형내 성분들의 분리를 최소화 할 수 있기 때문에, 제형이 부러지는 것을 개선할 수 있다. According to one aspect of the present invention, a method for preparing a stick cosmetic composition is performed by separately stabilizing clay minerals and moisturizing components, and mixing them with an oil phase portion including wax, so that the clay component and the moisturizing component are uniform in the composition. It is dispersed and does not break well. In particular, the stick-like cosmetic composition, due to the morphological characteristics extending in one direction, the components contained in the composition is settled downwardly in the height direction of the formulation by stoke's law, and is uniformly distributed in the composition. If the composition comprises clay minerals, the viscosity of the composition may increase, which may slow down the settling rate of the components in the composition. In addition, through the first stabilization step and / or the second stabilization step of the present invention, the clay mineral and the moisturizing component is uniformly dispersed in the composition, each particle size is reduced, the effect of reducing the sedimentation rate is have. The composition, which is an aspect of the present invention, reduces the sedimentation rate of the components in the composition, thereby minimizing the uniform distribution in the composition of the components contained in the composition and minimizing the separation of the components in the formulation. This breakage can be improved.
상기와 같은 측면에서, 상기 유상부에 점토 광물 분산물 및 보습 성분 분산물을 첨가하는 단계는, 유상부에 점토 광물 분산물을 첨가한 후, 보습 성분 분산물을 첨가하는 것을 포함할 수 있다. In the above aspect, the step of adding the clay mineral dispersion and the moisturizing component dispersion to the oil phase may include adding a clay mineral dispersion to the oil phase, and then adding a moisturizing component dispersion.
특히, 보습 성분이 수용성 물질일 때, 오일 성분과의 분리로 인한 제형의 안정성이 문제될 수 있는데, 본 발명의 일 구현예에서, 보습 성분을 먼저 안정화시켜 조성물 내 균일하게 분산시키기 때문에, 제형의 분리 현상을 최소화 할 수 있고, 제형이 부러지는 현상도 개선할 수 있다.In particular, when the moisturizing component is a water-soluble substance, the stability of the formulation due to separation from the oil component may be a problem. In one embodiment of the present invention, since the moisturizing component is first stabilized and uniformly dispersed in the composition, Separation can be minimized and formulation breakage can be improved.
상기와 같은 측면에서, 상기 점토 광물은, 0.01~7 중량%, 바람직하게는, 0.03~6중량%, 더욱 바람직하게는 0.05~5 중량%로 포함될 수 있다. 상기 점토 광물의 함량이, 조성물 총 중량을 기준으로 하여, 0.05 중량% 미만이면, 보습 성분과 안정적인 상호 작용을 할 수 없으므로, 보습성분이 뭉쳐 스틱제형을 무너뜨릴 수 있다. 또한, 점토 광물의 함량이 5 중량%를 초과하면, 스틱형 화장료 조성물 사용감이 뻑뻑해지고, 보습력이 저하되는 한계가 있다.In the above aspect, the clay mineral may be included in 0.01 to 7% by weight, preferably, 0.03 to 6% by weight, more preferably 0.05 to 5% by weight. If the content of the clay mineral is less than 0.05% by weight, based on the total weight of the composition, the moisturizing component may not be able to interact stably with the moisturizing component, thereby breaking down the stick formulation. In addition, when the content of the clay mineral is more than 5% by weight, there is a limit that the feeling of using the stick-type cosmetic composition becomes stiff, and the moisturizing power is lowered.
상기와 같은 측면에서, 상기 제1 에몰리언트는, 조성물 총 중량을 기준으로, 0.05~35 중량%로 포함될 수 있고, 바람직하게는, 0.3~30 중량%로 포함될 수 있으며, 더욱 바람직하게는, 0.25~25 중량%로 포함될 수 있다. In the above aspect, the first emollient, based on the total weight of the composition, may be included in 0.05 to 35% by weight, preferably, may be included in 0.3 to 30% by weight, more preferably, 0.25 ~ It may be included in 25% by weight.
또한, 상기와 같은 측면에서, 상기 제 1에몰리언트는, 점토 광물의 총 중량을 100 중량부로 했을 때, 300~1000의 중량부로 포함될 수 있다. 상기 제1 에몰리언트가, 점토 광물의 총 중량을 100 중량부로 했을 때, 300중량부 미만으로 포함되면, 조성물 내에서 점토 광물의 균일한 분산이 이루어지지 않기 때문에 제형의 안정성이 떨어지게 된다. 상기 제1에몰리언트는, 점토 광물의 총 중량을 100 중량부로 했을 때, 바람직하게는 500~1000 중량부로 포함될 수 있다. In addition, in the above aspect, the first emollient, when the total weight of the clay mineral 100 parts by weight, may be included in the weight portion of 300 ~ 1000. When the first emollient is included in an amount of less than 300 parts by weight when the total weight of the clay mineral is 100 parts by weight, the stability of the formulation is inferior since uniform dispersion of the clay mineral is not achieved in the composition. When the total weight of the clay mineral is 100 parts by weight, the first emollient may be included in an amount of preferably 500 to 1000 parts by weight.
상기와 같은 측면에서, 상기 제1 에몰리언트는, 카프릴릭 카프릭트리글리세라이드를 포함할 수 있으나, 이에 제한되는 것은 아니다.In the above aspect, the first emollient may include, but is not limited to, caprylic capric triglyceride.
상기와 같은 측면에서, 상기 보습 성분은, 조성물 총 중량을 기준으로, 0.01~45 중량%로 포함될 수 있고, 바람직하게는, 0.05~40 중량%, 더욱 바람직하게는, 0.1~35 중량%로 포함될 수 있다. 상기 보습 성분의 함량이, 0.1 중량% 미만일 경우에는, 화장료 조성물의 보습력이 현저히 떨어질 수 있고, 35 중량%를 초과하면, 제형 내 분리 현상이 발생하여, 화장료 조성물의 제형 안정성이 저하될 수 있다.In the above aspect, the moisturizing component, based on the total weight of the composition, may be included in 0.01 to 45% by weight, preferably, 0.05 to 40% by weight, more preferably, 0.1 to 35% by weight Can be. When the content of the moisturizing component is less than 0.1% by weight, the moisturizing power of the cosmetic composition may be remarkably decreased, and when the content of the moisturizing component is more than 35% by weight, separation in the formulation may occur, thereby lowering the formulation stability of the cosmetic composition.
상기와 같은 측면에서, 상기 보습 성분은 수용성 보습성분일 수 있다. 일 구현예에서, 상기 보습성분은, 글리세린을 포함할 수 있다.In the above aspect, the moisturizing component may be a water-soluble moisturizing component. In one embodiment, the moisturizing component may include glycerin.
또한, 상기와 같은 측면에서, 상기 제1 계면활성제는, 조성물 총 중량을 기준으로, 0.01~10 중량%로 포함될 수 있고, 바람직하게는, 0.05~7중량%, 더욱 바람직하게는, 0.1~5 중량%로 포함될 수 있다. 상기 제1 계면활성제의 함량이 0.1 중량% 미만이면, 보습성분을 안정적으로 분산 및 유화할 수 없기 때문에 분리현상이 일어난다. 5중량%를 초과하면, 보습 성분이 미세하게 분산되지 않고 서로 뭉쳐서, 보습성분을 화장료 조성물 내에서 균일하게 분산시킬 수 없다. 예컨대, 상기 제1 계면활성제의 함량이 5중량%를 초과하면, 보습성분 함유 물질의 평균 입경이 10㎛를 초과하게 되어, 보습성분이 화장료 조성물 내에 균일하게 분산될 수 없다. In addition, in the above aspects, the first surfactant, may be included in 0.01 to 10% by weight, based on the total weight of the composition, preferably, 0.05 to 7% by weight, more preferably, 0.1 to 5 It may be included in weight percent. If the content of the first surfactant is less than 0.1% by weight, separation occurs because the moisturizing component cannot be dispersed and emulsified stably. If it exceeds 5% by weight, the moisturizing ingredients are not finely dispersed but agglomerated with each other, and the moisturizing ingredients cannot be uniformly dispersed in the cosmetic composition. For example, when the content of the first surfactant exceeds 5% by weight, the average particle diameter of the moisturizing ingredient-containing material exceeds 10 μm, and the moisturizing ingredient cannot be uniformly dispersed in the cosmetic composition.
본 명세서에서 보습성분 함유 물질은, 보습 성분만을 함유한 물질 및 보습성분 외에 다른 성분도 포함된 물질을 포함할 수 있다. In the present specification, the moisturizing component-containing material may include a substance containing only a moisturizing component and a substance including other components in addition to the moisturizing component.
본 명세서에서 상기 평균 입경은, 입자의 직경 중 가장 길이가 긴 축과 가장 길이가 짧은 축을 제외한 임의의 지점에서 측정한 2개 축의 길이의 평균값을 의미할 수 있다. In the present specification, the average particle diameter may mean an average value of the lengths of two axes measured at any point except the longest axis and the shortest axis of the diameter of the particle.
상기와 같은 측면에서, 상기 제1 계면활성제는, 세테아릴올리베이트, 소르비탄올리베이트 또는 이들의 혼합물을 포함할 수 있다. In the above aspect, the first surfactant may include cetearyl olivate, sorbitan olivate or a mixture thereof.
일 구현예에서, 상기 점토 광물은, 판상형 광물을 포함할 수 있다. 구체적으로, 상기 판상형 광물은, 스멕타이트를 포함할 수 있다. 스멕타이트는, 헥토라이트 또는 벤토라이트를 포함할 수 있고 바람직하게는, 헥토라이트일 수 있다. 일 구현예에서, 상기 점토 광물이 헥토라이트일 때, 스틱형 화장료 조성물 내 성분들이 가장 균일하게 분산되고, 스틱형 화장료 조성물의 물리적 강도가 우수하다. In one embodiment, the clay mineral may include a plate-like mineral. Specifically, the plate-like mineral may include smectite. The smectite may comprise hectorite or bentorite and may preferably be hectorite. In one embodiment, when the clay mineral is hectorite, the components in the stick cosmetic composition are most uniformly dispersed, and the physical strength of the stick cosmetic composition is excellent.
일 구현예에서, 상기 점토 광물은 스테아랄코늄헥토라이트일 수 있다.In one embodiment, the clay mineral may be stearalconium hectorite.
또한, 상기와 같은 측면에서, 제1 안정화 단계는, 상기 점토 광물과 상기 제1 에몰리언트를, 1000~2500rpm으로 교반하는 것을 포함할 수 있으며, 바람직하게는, 1500~2000rpm으로 교반할 수 있다. 상기 제1 안정화 단계의 교반 속도가 1000rpm 미만일 경우에는, 점토 광물이 제1 에몰리언트에 충분히 스웰링되지 않아 안정한 제형을 얻는데 필요한 점도를 얻을 수 없게 된다. 또한, 상기 제1 안정화 단계의 교반 속도가 2500rpm을 초과할 경우에는, 조성물 내 기포가 과도하게 발생하여, 제형의 안정성을 떨어뜨리게 된다.In addition, in the above aspect, the first stabilizing step may include stirring the clay mineral and the first emollient at 1000 ~ 2500rpm, preferably, can be stirred at 1500 ~ 2000rpm. When the stirring speed of the first stabilization step is less than 1000 rpm, the clay mineral is not sufficiently swelled in the first emollient to obtain the viscosity necessary to obtain a stable formulation. In addition, when the stirring speed of the first stabilization step exceeds 2500rpm, bubbles in the composition are excessively generated, thereby lowering the stability of the formulation.
또한, 상기와 같은 측면에서, 상기 제2 안정화 단계는, 60~90℃에서, 보습 성분과 제1 계면활성제를 혼합하는 것을 포함할 수 있다. 상기 제2 안정화 단계의 온도는 바람직하게, 75~85℃일 수 있다. 제2 안정화 단계의 온도가 60℃ 미만일 때는, 고형상의 계면활성제를 용해시킬 수 없고, 90℃를 초과하면, 조성물 내 성분들이 열변형되거나, 휘발되어 이탈될 수 있다. In addition, in the above aspect, the second stabilizing step, at 60 ~ 90 ℃, may include mixing the moisturizing component and the first surfactant. The temperature of the second stabilization step may be preferably 75 ~ 85 ℃. When the temperature of the second stabilization step is less than 60 ° C., the solid surfactant cannot be dissolved, and if it exceeds 90 ° C., the components in the composition may be thermally deformed or volatilized off.
본 명세서에서, 별달리 표시되지 않는다면, 온도는 섭씨온도로 표현된다.In this specification, unless otherwise indicated, temperatures are expressed in degrees Celsius.
일 구현예에서, 상기 유상부는 조성물 총 중량을 기준으로, 5~40 중량%의 왁스, 0.01~10 중량%의 제2 계면활성제, 및 잔량의 제2 에몰리언트를 혼합하여 형성된 것을 포함할 수 있다. In one embodiment, the oil phase portion may be formed by mixing 5 to 40% by weight of wax, 0.01 to 10% by weight of the second surfactant, and the balance of the second emollient based on the total weight of the composition.
일 구현예에서, 상기 유상부는 버터 또는 방부제를 더 포함할 수 있다. 상기 버버터는 조성물 총 중량을 기준으로, 1~5 중량%로 포함될 수 있고, 바람직하게는, 2.5~3.5 중량%로 포함될 수 있다. 상기 버터는 망고버터, 쉐어버터, 코코아버터, 또는 호호바버터(jojoba butter) 일 수 있으나, 이에 제한되는 것은 아니다.In one embodiment, the oil phase may further comprise butter or preservatives. The butter may be included in 1 to 5% by weight, preferably, 2.5 to 3.5% by weight based on the total weight of the composition. The butter may be a mango butter, shea butter, cocoa butter, or jojoba butter, but is not limited thereto.
또한, 상기 방부제는, 조성물 총 중량을 기준으로, 0.03~1.5 중량%로 포함될 수 있고, 바람직하게는, 0.05~1.3 중량%로 포함될 수 있다. 상기 방부제는 에틸헥실글리세린 또는 1,2-헥산디올일 수 있으나, 이에 제한되는 것은 아니다.In addition, the preservative, based on the total weight of the composition, may be included in 0.03 to 1.5% by weight, preferably, 0.05 to 1.3% by weight may be included. The preservative may be ethylhexylglycerin or 1,2-hexanediol, but is not limited thereto.
상기와 같은 측면에서, 상기 왁스는, 조성물 총 중량을 기준으로 5~40 중량%로 포함될 수 있고, 바람직하게는, 6~35 중량%, 더욱 바람직하게는 10~30 중량%로 포함될 수 있다. 왁스의 함량이 조성물 총 중량을 기준으로 10 중량% 미만이면, 스틱형 제형을 형성하기 어렵고, 30중량%를 초과하면, 강도가 너무 높아서, 발림성, 특히 입술에의 발림성이 저하될수 있다.In the above aspect, the wax may be included in 5 to 40% by weight, preferably, 6 to 35% by weight, more preferably 10 to 30% by weight based on the total weight of the composition. If the content of the wax is less than 10% by weight based on the total weight of the composition, it is difficult to form a stick-shaped formulation, and if it exceeds 30% by weight, the strength is too high, so that the applicability, in particular to the lips, may be reduced.
상기와 같은 측면에서, 상기 왁스는 카나우바 왁스, 칸데릴라 왁스, 프로폴리스 왁스, 오조케라이트, 마이크로크리스탈린 왁스 및 비즈 왁스로 이루어진 군으로부터 선택된 하나 이상을 포함할 수 있으나, 이에 제한되는 것은 아니다.In the above aspect, the wax may include one or more selected from the group consisting of carnauba wax, candelilla wax, propolis wax, ozokerite, microcrystalline wax and bees wax, but is not limited thereto. .
또한, 상기와 같은 측면에서, 상기 제2 계면활성제는, 0.01~10 중량%로 포함될 수 있고, 바람직하게는, 0.05~8중량%, 더욱 바람직하게는, 0.1~7 중량%로 포함될 수 있다. 제2 계면활성제의 함량이 0.1 중량% 미만이면, 조성물 내 성분들을 안정하고, 균일하게 분산 및 유화시킬 수 없으며, 7 중량% 이상 포함되면, 제형 분리 현상이 일어날 수 있다.In addition, in the above aspect, the second surfactant may be included in 0.01 to 10% by weight, preferably, 0.05 to 8% by weight, more preferably, may be included in 0.1 to 7% by weight. When the content of the second surfactant is less than 0.1% by weight, the components in the composition may not be stably and uniformly dispersed and emulsified, and when 7% by weight or more is included, formulation separation may occur.
상기와 같은 측면에서, 상기 제2 계면활성제는, 세틸피이지/피피지-10/1 디메치콘(Cetyl PEG/PPG-10 Dimethicone) 또는 소르비탄올리베이트를 포함할 수 있으나, 이에 제한되는 것은 아니다.In the above aspect, the second surfactant may include, but is not limited to, Cetyl PEG / PIGJI-10 / 1 dimethicone (Cetyl PEG / PPG-10 Dimethicone) or sorbitan sulfate. .
상기와 같은 측면에서, 상기 제2 에몰리언트는, 마카다미아씨 오일, 펜타에리스리틸테트라이소스테아레이트 및 카프릴릭 카프릭 트리글리세라이드로 이루어진 군으로부터 선택된 하나 이상을 포함할 수 있으나, 이에 제한되는 것은 아니다. In the above aspect, the second emollient may include, but is not limited to, at least one selected from the group consisting of macadamia seed oil, pentaerythritol tetraisostearate, and caprylic capric triglyceride.
본 발명은 다른 측면에서, 상기 방법으로 제조된, 스틱형 화장료 조성물이다.In another aspect, the present invention is a stick cosmetic composition prepared by the above method.
상기 화장료 조성물은, 입술용 조성물일 수 있다. 입술은 입술 자체의 구조적 특이성(예컨대 면적 대비 부피가 크고, 입술 내부에 뼈와 같은 구조물이 없음)에 의해 적절한 발림성을 갖는 입술용 스틱 제형을 제조하는 것이 어렵다. 본 발명의 일 측면에 따른 스틱형 화장료 조성물은, 입술에 적용시 최적의 발림성을 유지하면서, 잘 부러지지 않는 장점이 있다.The cosmetic composition may be a composition for lips. Lips are difficult to produce a lip stick formulation with adequate applicability due to the structural specificity of the lips itself (e.g., bulky relative to area and no bone-like structure inside the lips). Stick-like cosmetic composition according to an aspect of the present invention, there is an advantage that does not break well, while maintaining the optimum applicability when applied to the lips.
상기 스틱형 화장료 조성물은, 립메이크업용, 립보습용 또는 피부메이크업용일 수 있다. 예컨대, 상기 스틱형 화장료 조성물은, 립스틱 또는 립글로스일 수 있으나, 이에 제한되는 것은 아니다. 또한, 상기 피부메이크업용 조성물은, 스틱형 자외선 차단제, 스틱형 파운데이션, 또는 스틱형 세안제 등을 포함할 수 있으나, 이에 제한되는 것은 아니다. The stick cosmetic composition may be for lip makeup, lip moisturizing or skin makeup. For example, the stick cosmetic composition may be lipstick or lip gloss, but is not limited thereto. In addition, the composition for skin makeup may include, but is not limited to, a stick-type sunscreen, a stick-based foundation, a stick-type cleanser, and the like.
이하, 실시예 및 시험예를 들어 본 발명의 구성 및 효과를 보다 구체적으로 설명한다. 그러나 이들 실시예 및 시험예는 본 발명에 대한 이해를 돕기 위해 예시의 목적으로만 제공된 것일 뿐 본 발명의 범주 및 범위가 하기 예에 의해 제한되는 것은 아니다.Hereinafter, the configuration and effects of the present invention will be described in more detail with reference to Examples and Test Examples. However, these examples and test examples are provided only for the purpose of illustration in order to help the understanding of the present invention is not limited to the scope and scope of the present invention by the following examples.
[실시예 1] 스틱형 화장료 조성물의 제조Example 1 Preparation of Stick Type Cosmetic Composition
[실시예 1-1] 점토 광물의 안정화Example 1-1 Stabilization of Clay Minerals
조성물 총중량 대비 2 중량%의 스테아릴코늄헥토라이트와 10 중량%의 카프릴릭/카프릭트리글리세라이드를 고속교반기에서 1500~2000rpm으로 30분간 교반하여, 점토 광물을 에몰리언트에 먼저 분산시켜 안정화하였다.Stearylconium hectorite and 10% by weight of caprylic / capric triglycerides of 2% by weight relative to the total weight of the composition were stirred for 30 minutes at 1500-2000 rpm in a high speed stirrer to stabilize the clay minerals by first dispersing them in the emollient.
[실시예 1-2] 보습 성분의 안정화Example 1-2 Stabilization of Moisturizing Components
조성물 총 중량 대비 10 중량%의 글리세린과, 3 중량%의 세테아릴올리베이트/소르비탄올리베이트를 75~85℃에서 용해시킨 후, 고속 호모믹서에서 유화하여, 글리세린을 분산시켜 안정화하였다.Glycerin of 10% by weight relative to the total weight of the composition and 3% by weight of cetearylolivate / sorbitanolate were dissolved at 75 ° C. to 85 ° C., and then emulsified in a high speed homomixer to stabilize the dispersion by glycerin.
[실시예 1-3] 유상부의 제조 및 스틱형 제형의 제조Example 1-3 Preparation of Oil Phase and Preparation of Stick-Type Formulation
하기 표 1에 기재된 성분들을 80~85℃에서 혼합하여 유상부를 제조하였다. 그 후 상기 실시예 1-1의 안정화된 점토 광물을 유상부에 첨가하고 호모믹서를 이용하여 교반 및 분산시켰다. To prepare the oil phase by mixing the components shown in Table 1 at 80 ~ 85 ℃. The stabilized clay mineral of Example 1-1 was then added to the oil phase and stirred and dispersed using a homomixer.
그 후, 실시예 1-2의 안정화된 글리세린-세테아릴올리베이트/소르비탄올리베이트를 첨가하여 다시 호모믹서를 이용하여 교반 및 분산시켜서 조성물을 제조하였다. 그 후, 조성물 내 기포를 제거하고, 불순물을 여과하여, 최종적으로 조성물을 제조하고, 이를 스틱형 제형으로 제조하였다. Thereafter, the stabilized glycerin-cetearylolivate / sorbitan sulfate of Example 1-2 was added and again stirred and dispersed using a homomixer to prepare a composition. Thereafter, bubbles in the composition were removed, and impurities were filtered to finally prepare the composition, which was then prepared into a stick formulation.
유상Paid 왁스Wax 칸데릴라왁스Candelilla wax 7 중량%7 wt%
왁스Wax 오조케라이트Ozokerite 3 중량%3 wt%
왁스Wax 마이크로크리스탈린왁스Microcrystalline Wax 3 중량%3 wt%
왁스Wax 비즈왁스Beads wax 2 중량%2 wt%
에몰리언트Emollient 마카다미아씨오일Macadamia Seed Oil 23.95 중량%23.95 wt%
에몰리언트Emollient 펜타에리스리틸테트라이소스테아레이트Pentaerythritol tetraisostearate 15 중량%15 wt%
에몰리언트Emollient 카프릴릭/카프릭트리글리세라이드Caprylic / Capric Triglycerides 15 중량%15 wt%
계면활성제Surfactants 세틸피이지/피피지-10/1디메치콘Cetyl Fiji / Fiji -10/1 dimethicone 2 중량%2 wt%
계면활성제Surfactants 소르비탄올리베이트Sorbitan olivate
버터butter 쉐어버터Shea Butter 3 중량%3 wt%
방부Embalming 에칠헥실글리세린Ethylhexylglycerin 0.05 중량%0.05 wt%
방부Embalming 1,2-헥산디올1,2-hexanediol 1 중량%1 wt%
[실험예 1] 스틱형 제형의 물성 측정Experimental Example 1 Measurement of Physical Properties of Stick-Type Formulations
50명의 여성과 50명의 남성 패널에 대하여, 사용감(소프트감, 보습감, 보습 지속성 및 제형 안정성)에 대한 패널 테스트를 실시하였다. 실시예 1에서 제조한 스틱 제형을, 입술을 수세하고, 건조 시킨 후 0.1g 도포하고, 1분이 경과한 후, 사용감에 대하여 평가하였다. 성형안정성은 입술 도포시 부러짐, 뭉게짐, 또는 제형 안정성에 대하여 평가하였다. 평가 점수는, 사용감이 매우 우수할 경우 5점으로 하고, 매우 부족할 경우 1점으로 하여, 5점부터 1점가지 부여하고, 각 패널들의 점수의 총합의 평균값을 구했다. 그 결과는 아래 표 2와 같다.A panel test was conducted for 50 women and 50 male panels for feeling of use (soft, moisturizing, long lasting and formulation stability). The stick formulation prepared in Example 1 was rinsed with water, dried, and then applied with 0.1 g, and after 1 minute, the feeling of use was evaluated. Mold stability was assessed for crushing, crushing, or formulation stability upon lip application. The evaluation score was given as 5 points when the feeling of use was very excellent and 1 point when the feeling was very insufficient, and 1 point was given from 5 points, and the average value of the sum total of the scores of each panel was calculated | required. The results are shown in Table 2 below.
[비교예 1] 안정화 단계를 거치지 않은 스틱형 제형과의 비교[Comparative Example 1] Comparison with the stick type formulation without undergoing stabilization
[비교예 1-1] 점토광물의 안정화 및 보습성분의 안정화를 모두 실시하지 않은 경우Comparative Example 1-1 Stabilization of Clay Minerals and Stabilization of Moisturizing Components
실시예 1의 안정화 단계에 사용된 점토광물과 계면활성제를 사용하지 않은 점만 제외하고, 실시예 1과 동일한 조성의 성분을 동시에 혼합하여, 일반적인 스틱형 제형을 제조하였다. 일반적인 스틱형 제형에 대해서도 실험예 1과 동일한 방법으로 사용감 패널 테스트를 진행하였고, 그 결과는 아래 표 2에 기재된 바와 같다.Except that the clay mineral used in the stabilization step of Example 1 and the surfactant was not used, the components of the same composition as in Example 1 were mixed at the same time to prepare a general stick type formulation. In the same manner as in Experimental Example 1 for the general stick-type formulation, the feeling panel test was conducted, and the results are shown in Table 2 below.
구분division 비교예1-1Comparative Example 1-1 실험예1Experimental Example 1
소프트감Soft 3.63.6 4.24.2
보습감(수분)Moisturizing (moisture) 2.82.8 4.04.0
보습감(유분)Moisturizing (oil) 3.323.32 3.483.48
보습지속성Moisturizing persistence 3.823.82 3.913.91
성형안정성Molding stability 1.531.53 3.823.82
평가기준: 매우 우수 5, 우수 4, 보통 3, 부족 2, 아주 부족 1Criteria: Very good 5, Excellent 4, Moderate 3, Low 2, Very low 1
상기 표 2를 보면, 안정화 단계를 거친 본원발명의 스틱제형이, 안정화 단계를 거치지 않은 일반적인 스틱 제형에 비하여 대체적으로 사용감이 훨씬 우수하고, 특히 성형 안정성은 약 2.5배 이상 우수함을 알 수 있었다(도 2).Looking at Table 2, it can be seen that the stick formulation of the present invention, which has undergone the stabilization step, is generally much more comfortable than the general stick formulation that has not undergone the stabilization step, and in particular, the molding stability is about 2.5 times or more. 2).
[비교예 1-2] 점토광물의 안정화는 실시하되, 보습성분의 안정화는 실시하지 않은 경우[Comparative Example 1-2] When the clay mineral is stabilized but the moisturizing component is not stabilized
상기 실시예 1-2에 기재된 별도의 보습성분의 안정화 과정을 거치지 않은 점만 제외하고 실시예 1과 동일하게 스틱형 제형을 제조하였다. 그 후 실험예 1과 동일한 방법으로 스틱형 제형의 물성을 측정하고, 표 3에 표시하였다. 이 경우, 글리세린의 침전으로 인해, 스틱의 물리적 안정성이 크게 떨어짐을 알 수 있었다(도 3).A stick-type formulation was prepared in the same manner as in Example 1 except that the separate moisturizing component described in Example 1-2 was not subjected to stabilization. Thereafter, the physical properties of the stick-type formulation were measured in the same manner as in Experimental Example 1, and are shown in Table 3. In this case, due to the precipitation of glycerin, it can be seen that the physical stability of the stick is greatly reduced (Fig. 3).
구분division 비교예 1-2Comparative Example 1-2 실험예1Experimental Example 1
소프트감Soft 3.93.9 4.24.2
보습감(수분)Moisturizing (moisture) 3.43.4 4.04.0
보습감(유분)Moisturizing (oil) 3.33.3 3.483.48
보습지속성Moisturizing persistence 3.53.5 3.913.91
성형안정성Molding stability 2.32.3 3.823.82
평가기준: 매우 우수 5, 우수 4, 보통 3, 부족 2, 아주 부족 1Criteria: Very good 5, Excellent 4, Moderate 3, Low 2, Very low 1
[비교예 1-3] 점토광물의 안정화는 실시하지 않고 보습성분의 안정화는 실시한 경우Comparative Example 1-3 Stabilization of Moisturizing Components without Stabilization of Clay Minerals
상기 실시예 1-1에 기재된 별도의 점도광물의 안정화 과정을 거치지 않은점만 제외하고 실시예 1과 동일하게 스틱형 제형을 제조하였다. 그 후 실험예 1과 동일한 방법으로 스틱형 제형의 물성을 측정하고, 표 4에 표시하였다. 이 경우에도, 글리세린의 침전으로 인해, 스틱의 물리적 안정성이 크게 떨어짐을 알 수 있었다. 이 경우 스틱형 제형의 측면 모습은 도 3과 유사하였다.A stick-type formulation was prepared in the same manner as in Example 1 except that the separate viscosity minerals described in Example 1-1 were not subjected to stabilization. Thereafter, the physical properties of the stick-type formulation were measured in the same manner as in Experimental Example 1, and are shown in Table 4. Even in this case, it was found that due to the precipitation of glycerin, the physical stability of the stick was greatly reduced. In this case, the side view of the stick-type formulation was similar to FIG. 3.
구분division 비교예 1-3Comparative Example 1-3 실험예1Experimental Example 1
소프트감Soft 3.73.7 4.24.2
보습감(수분)Moisturizing (moisture) 3.23.2 4.04.0
보습감(유분)Moisturizing (oil) 3.353.35 3.483.48
보습지속성Moisturizing persistence 3.63.6 3.913.91
성형안정성Molding stability 2.52.5 3.823.82
평가기준: 매우 우수 5, 우수 4, 보통 3, 부족 2, 아주 부족 1Criteria: Very good 5, Excellent 4, Moderate 3, Low 2, Very low 1
[비교예 2] 제조 순서에 따른 스틱형 제형의 물성 [Comparative Example 2] Physical properties of the stick-type formulation according to the manufacturing procedure
[비교예 2-1] Comparative Example 2-1
실시예 1과는 달리, 2 중량%의 스테아릴코늄헥토라이트와 10 중량%의 카프릴릭/카프릭트리글리세라이드, 3 중량%의 세테아릴올리베이트/소르비탄올리베이트를 동시에 유상부에 첨가한 이후에, 10 중량%의 글리세린을 첨가하여 스틱형 제형을 제조하였다. 그 후 상기 실험예 1에 기재되어 있는 방법에 의하여 스틱형 제형의 물성을 측정하였다. 이 경우에도, 글리세린이 안정화 되지 못하여, 스틱의 물리적 안정성이 크게 떨어짐을 알 수 있었다(도 4).Unlike Example 1, 2% by weight of stearylconium hectorite, 10% by weight of caprylic / capric triglycerides, and 3% by weight of cetearylolate / sorbitanate were added simultaneously to the oil phase. Thereafter, 10% by weight of glycerin was added to prepare a stick formulation. Then, the physical properties of the stick-type formulations were measured by the method described in Experimental Example 1. Even in this case, the glycerin was not stabilized, and it was found that the physical stability of the stick was greatly decreased (FIG. 4).
구분division 비교예 2-1Comparative Example 2-1 실험예1Experimental Example 1
소프트감Soft 3.63.6 4.24.2
보습감(수분)Moisturizing (moisture) 2.82.8 4.04.0
보습감(유분)Moisturizing (oil) 3.323.32 3.483.48
보습지속성Moisturizing persistence 3.823.82 3.913.91
성형안정성Molding stability 1.531.53 3.823.82
평가기준: 매우 우수 5, 우수 4, 보통 3, 부족 2, 아주 부족 1Criteria: Very good 5, Excellent 4, Moderate 3, Low 2, Very low 1
[비교예 2-2] Comparative Example 2-2
비교예 2-1과 반대 순서로, 스틱형 제형을 제조하고, 실험예 1과 동일한 방법으로 실험하고 그 결과를 표 6에 기재하였다. 이 경우에도, 제형이 지나치게 무르고, 제형에 포함된 성분들이 스틱형 제형의 높이 방향으로 불균일하게 분포하게 되어, 스틱의 물리적 안정성이 크게 떨어짐을 알 수 있었다. 측면에서 관찰한 외형은 도 4와 거의 유사하였다.In the reverse order to Comparative Example 2-1, a stick-type formulation was prepared, and was tested in the same manner as in Experimental Example 1, and the results are shown in Table 6. In this case, too, the formulation was too soft, the components contained in the formulation was distributed non-uniformly in the height direction of the stick-type formulation, it was found that the physical stability of the stick is greatly reduced. The appearance observed from the side is almost similar to FIG.
구분division 비교예 2-1Comparative Example 2-1 실험예1Experimental Example 1
소프트감Soft 3.653.65 4.24.2
보습감(수분)Moisturizing (moisture) 3.63.6 4.04.0
보습감(유분)Moisturizing (oil) 3.353.35 3.483.48
보습지속성Moisturizing persistence 3.83.8 3.913.91
성형안정성Molding stability 2.42.4 3.823.82
평가기준: 매우 우수 5, 우수 4, 보통 3, 부족 2, 아주 부족 1Criteria: Very good 5, Excellent 4, Moderate 3, Low 2, Very low 1
[비교예 3] 성분의 함량에 따른 스틱형 제형의 물성Comparative Example 3 Physical Properties of Stick-Type Formulations According to Contents of Ingredients
하기 표 7에 기재된 바와 같이 각 성분들의 함량을 조절하여 스틱형 제형을 제조하고 그 물성을 측정하고 그 결과를 표 8에 기재하였다.To adjust the content of each component as shown in Table 7 below to prepare a stick-shaped formulation and to measure the physical properties and the results are shown in Table 8.
비교예 3-1Comparative Example 3-1 비교예 3-2Comparative Example 3-2 비교예 3-3Comparative Example 3-3 비교예 3-4Comparative Example 3-4 비교예 3-5Comparative Example 3-5 비교예 3-6Comparative Example 3-6 비교예 3-7Comparative Example 3-7 비교예 3-8Comparative Example 3-8
스테아랄코늄헥토라이트Stearalconium hectorite 2 중량%2 wt% 2 중량%2 wt% 2중량%2 wt% 2 중량%2 wt% 2 중량%2 wt% 2중량%2 wt% 0.008중량%0.008% by weight 7.5중량%7.5 wt%
카프릴릭/카프릭트리글리세라이드Caprylic / Capric Triglycerides 10 중량%10 wt% 10 중량%10 wt% 0.008 중량%0.008% by weight 36중량%36% by weight 10 중량%10 wt% 10중량%10% by weight 10중량%10% by weight 10중량%10% by weight
글리세린glycerin 0.008중량%0.008% by weight 46 중량%46 wt% 10중량%10% by weight 10중량%10% by weight 10중량%10% by weight 10중량%10% by weight 10중량%10% by weight 10중량%10% by weight
세테아릴올리베이트/소르비탄올리베이트Cetearyl Olate / Sorbitan Olate 3중량%3 wt% 3중량%3 wt% 3중량%3 wt% 3중량%3 wt% 0.008중량%0.008% by weight 11중량%11 wt% 3중량%3 wt% 3중량%3 wt%
구분division 비교예 3-1Comparative Example 3-1 비교예 3-2Comparative Example 3-2 비교예 3-3Comparative Example 3-3 비교예 3-4Comparative Example 3-4 비교예 3-5Comparative Example 3-5 비교예 3-6Comparative Example 3-6 비교예 3-7Comparative Example 3-7 비교예 3-8Comparative Example 3-8
소프트감Soft 3.653.65 3.63.6 3.33.3 3.23.2 3.53.5 3.23.2 3.33.3 4.24.2
보습감(수분)Moisturizing (moisture) 3.63.6 3.73.7 3.13.1 3.43.4 3.553.55 3.23.2 3.43.4 4.04.0
보습감(유분)Moisturizing (oil) 1.71.7 3.73.7 3.53.5 3.53.5 3.43.4 3.23.2 3.33.3 3.483.48
보습지속성Moisturizing persistence 1.51.5 3.83.8 3.73.7 3.43.4 3.53.5 3.63.6 3.13.1 3.913.91
성형안정성Molding stability 2.42.4 2.22.2 1.81.8 1.751.75 1.851.85 2.02.0 2.32.3 3.823.82
평가기준: 매우 우수 5, 우수 4, 보통 3, 부족 2, 아주 부족 1Criteria: Very good 5, Excellent 4, Moderate 3, Low 2, Very low 1
[비교예 4] 제조 조건에 따른 스틱형 제형의 물성 평가Comparative Example 4 Evaluation of Physical Properties of Stick-Type Formulations According to Manufacturing Conditions
[비교예 4-1] 글리세린과 세테아릴올리베이트/소르비탄올리베이트 혼합시 온도에 따른 결과[Comparative Example 4-1] Results according to temperature when glycerin and cetearyl oleate / sorbitan oleate are mixed
상기 혼합 온도를 58℃로 한 경우를 비교예 4-1a로, 91℃로 한 경우를 비교예 4-1b로 하여, 스틱형 제형을 제조하고 물성을 측정하였다. Using the case where the mixing temperature was 58 ° C. was used as Comparative Example 4-1a and the case where the temperature was 91 ° C. was used as Comparative Example 4-1b, a stick-type formulation was prepared and physical properties were measured.
그 결과, 비교예 4-1a의 경우에는 글리세린과 세테아릴올리베이트 등이 용해되지 않아서, 스틱형 제형이 잘 만들어지지 않았고, 비교예 4-1b의 경우에는 물성이 실시예 1과 거의 동일함을 확인할 수 있었다.As a result, in the case of Comparative Example 4-1a, glycerin, cetearyl olivate, etc. did not dissolve, so that the stick-type formulation was not made well, and in the case of Comparative Example 4-1b, the physical properties were almost the same as in Example 1. Could confirm.
[비교예 4-2] 유상부 제조시 온도에 따른 스틱형 제형의 물성 평가[Comparative Example 4-2] Evaluation of the physical properties of the stick-type formulation according to the temperature during the oil phase manufacturing
유상부 제조시 온도를 50℃, 68℃, 86℃, 90℃로 설정하고 각각을 비교예 4-2a, 4-2b, 4-2c, 4-2d로 명명하였다. 그 후 실험예 1과 동일하게 물성 평가를 진행하였다.The temperature of the oil phase part was set to 50 degreeC, 68 degreeC, 86 degreeC, and 90 degreeC, and it named each as the comparative example 4-2a, 4-2b, 4-2c, 4-2d. Thereafter, the physical properties were evaluated in the same manner as in Experiment 1.
그 결과, 혼합 온도가 70℃ 미만인, 4-2a와 4-2b는 왁스 성분등의 충분한 용해가 이루어지지 않아서, 스틱제형이 형성되지 않았고, 90℃를 초과하는 경우에는, 안정적인 스틱제형이 형성되지 않았다.As a result, 4-2a and 4-2b having a mixing temperature of less than 70 ° C did not sufficiently dissolve wax components and the like, and thus, no stick formulation was formed, and if it exceeds 90 ° C, stable stick formulation was not formed. Did.

Claims (21)

  1. 스틱형 화장료 조성물의 제조방법으로서,As a manufacturing method of a stick cosmetic composition,
    상기 방법은, The method,
    조성물 총 중량을 기준으로,Based on the total weight of the composition,
    0.01~7 중량%의 점토 광물 및 0.05~35 중량%의 제1 에몰리언트를 혼합하여, 점토 광물 분산물을 형성하는, 제1 안정화 단계;A first stabilizing step of mixing a clay mineral of 0.01 to 7 wt% and a first emollient of 0.05 to 35 wt% to form a clay mineral dispersion;
    0.01~45 중량%의 보습 성분 및 0.01~10 중량%의 제1 계면활성제를 혼합하여, 보습 성분 분산물을 형성하는, 제2 안정화 단계; 및A second stabilizing step of mixing a moisturizing component of 0.01 to 45% by weight and a first surfactant of 0.01 to 10% by weight to form a moisturizing component dispersion; And
    유상부에 상기 점토 광물 분산물 및 보습 성분 분산물을 첨가하는 단계를 포함하는, 스틱형 화장료 조성물의 제조방법. Adding the clay mineral dispersion and the moisturizing component dispersion to the oil phase, the manufacturing method of the stick cosmetic composition.
  2. 제1항에 있어서,The method of claim 1,
    상기 유상부에 점토 광물 분산물 및 보습 성분 분산물을 첨가하는 단계는,Adding a clay mineral dispersion and a moisturizing component dispersion to the oil phase,
    유상부에 점토 광물 분산물을 첨가한 후, 보습 성분 분산물을 첨가하는 것을 포함하는, 스틱형 화장료 조성물의 제조방법. After adding a clay mineral dispersion to an oil phase part, The manufacturing method of the stick type cosmetic composition containing adding a moisturizing component dispersion.
  3. 제1항에 있어서,The method of claim 1,
    상기 점토 광물은, 판상형 광물을 포함하는, 스틱형 화장료 조성물의 제조방법. The clay mineral, a stick-like cosmetic composition manufacturing method comprising a plate-like mineral.
  4. 제1항에 있어서,The method of claim 1,
    상기 제1 에몰리언트는,The first emollient is
    카프릴릭 카프릭트리글리세라이드를 포함하는, 스틱형 화장료 조성물의 제조방법.A method for producing a stick-type cosmetic composition comprising caprylic capric triglyceride.
  5. 제1항에 있어서, The method of claim 1,
    상기 보습 성분은, 수용성 보습 성분인, 스틱형 화장료 조성물의 제조방법.The said moisturizing component is a water-soluble moisturizing component, The manufacturing method of the stick cosmetic composition.
  6. 제1항에 있어서,The method of claim 1,
    상기 제1 계면활성제는, The first surfactant,
    세테아릴올리베이트 또는 소르비탄올리베이트를 포함하는, 스틱형 화장료 조성물의 제조방법.A method for producing a stick-like cosmetic composition, comprising cetearyl olivate or sorbitan oleate.
  7. 제1항에 있어서,The method of claim 1,
    상기 제1 에몰리언트는, The first emollient is
    점토 광물의 총 중량을 100 중량부로 했을 때, 300~1000의 중량부로 포함되는, 스틱형 화장료 조성물의 제조방법.When the total weight of the clay mineral is 100 parts by weight, it is included in 300 to 1000 parts by weight, the manufacturing method of the stick cosmetic composition.
  8. 제1항에 있어서,The method of claim 1,
    상기 제1 안정화 단계는,The first stabilization step,
    상기 점토 광물과 상기 제1 에몰리언트를, 1000~2500rpm으로 교반하는 것을 포함하는, 스틱형 화장료 조성물의 제조방법.A method of producing a stick cosmetic composition comprising stirring the clay mineral and the first emollient at 1000 to 2500 rpm.
  9. 제1항에 있어서,The method of claim 1,
    상기 제2 안정화 단계는,The second stabilization step,
    60~90℃에서, 보습 성분과 제1 계면활성제를 혼합하는 것을 포함하는, 스틱형 화장료 조성물의 제조방법.The manufacturing method of the stick type cosmetic composition which mixes a moisturizing component and a 1st surfactant at 60-90 degreeC.
  10. 제1항에 있어서,The method of claim 1,
    상기 유상부는, The oil phase portion,
    조성물 총 중량을 기준으로,Based on the total weight of the composition,
    5~40 중량%의 왁스, 0.01~10 중량%의 제2 계면활성제, 및 잔량의 제2 에몰리언트를 혼합하여 형성된 것인, 스틱형 화장료 조성물의 제조방법. 5 to 40% by weight of wax, 0.01 to 10% by weight of the second surfactant, and the remaining amount of the second emollient, a method for producing a stick cosmetic composition.
  11. 제3항에 있어서,The method of claim 3,
    상기 판상형 광물은, 스멕타이트를 포함하는, 스틱형 화장료 조성물의 제조방법.The said plate-shaped mineral contains smectite, The manufacturing method of the stick cosmetic composition.
  12. 제5항에 있어서,The method of claim 5,
    상기 수용성 보습성분은, The water-soluble moisturizing component,
    글리세린을 포함하는, 스틱형 화장료 조성물의 제조방법.A method for producing a stick cosmetic composition containing glycerin.
  13. 제10항에 있어서,The method of claim 10,
    상기 유상부는,The oil phase portion,
    버터 또는 방부제를 더 포함하는, 스틱형 화장료 조성물의 제조방법.A method of producing a stick-like cosmetic composition further comprising butter or preservatives.
  14. 제10항에 있어서,The method of claim 10,
    상기 왁스는, 칸데릴라 왁스, 오조케라이트, 마이크로크리스탈린 왁슥 및 비즈왁스로 이루어진 군으로부터 선택된 하나 이상을 포함하는, 스틱형 화장료 조성물의 제조방법.The wax comprises at least one selected from the group consisting of candelilla wax, ozokerite, microcrystalline wax and beeswax, stick type cosmetic composition manufacturing method.
  15. 제10항에 있어서,The method of claim 10,
    상기 제2 계면활성제는, The second surfactant,
    세틸피이지/피피지-10/1 디메치콘(Cetyl PEG/PPG-10 Dimethicone) 또는 소르비탄올리베이트를 포함하는, 스틱형 화장료 조성물의 제조방법.Cetyl PEG / Fiji-10 / 1 dimethicone (Cetyl PEG / PPG-10 Dimethicone) or sorbitan oleate containing, the manufacturing method of the stick-type cosmetic composition.
  16. 제10항에 있어서,The method of claim 10,
    상기 제2 에몰리언트는,The second emollient is
    마카다미아씨 오일, 펜타에리스리틸테트라이소스테아레이트 및 카프릴릭 카프릭 트리글리세라이드로 이루어진 군으로부터 선택된 하나 이상을 포함하는, 스틱형 화장료 조성물의 제조방법.Macadamia seed oil, pentaerythritol tetraisostearate and caprylic capric triglyceride comprising at least one selected from the group consisting of, stick-like cosmetic composition.
  17. 제11항에 있어서,The method of claim 11,
    상기 스멕타이트는, 헥토라이트 또는 벤토나이트를 포함하는, 스틱형 화장료 조성물의 제조방법.The smectite comprises a hectorite or bentonite, method for producing a stick cosmetic composition.
  18. 제17항에 있어서,The method of claim 17,
    상기 헥토라이트는 스테아랄코늄헥토라이트인, 스틱형 화장료 조성물의 제조방법.The hectorite is stearalconium hectorite, method of producing a stick-type cosmetic composition.
  19. 제1항 내지 제18항 중 어느 한 항의 방법으로 제조된, 스틱형 화장료 조성물.A stick cosmetic composition prepared by the method of any one of claims 1 to 18.
  20. 제19항에 있어서,The method of claim 19,
    상기 화장료 조성물은, 입술용인, 스틱형 화장료 조성물. The cosmetic composition is a stick cosmetic composition for lips.
  21. 제20항에 있어서,The method of claim 20,
    상기 조성물은, 립메이크업용, 립보습용 또는 피부메이크업용인, 스틱형 화장료 조성물.The composition is a stick cosmetic composition for lip makeup, lip moisturizing or skin makeup.
PCT/KR2017/012712 2016-11-11 2017-11-10 Method for preparing stick-type cosmetic composition WO2018088831A1 (en)

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CN110897991B (en) * 2019-12-26 2022-05-27 上海新如生物科技有限公司 Lip gloss with skin care function and preparation method thereof
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US6183760B1 (en) * 1998-04-29 2001-02-06 Avon Products, Inc. Cosmetic stick
TWI285113B (en) * 1999-11-25 2007-08-11 Shiseido Co Ltd Manufacturing method of cosmetics
US20050123574A1 (en) * 2003-12-05 2005-06-09 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Massaging toilet bar with disintegrable agglomerates
KR100789345B1 (en) * 2006-08-21 2007-12-28 주식회사 엘지생활건강 Solid stick cosmetics of water-in-oil emulsion
KR101054884B1 (en) * 2007-04-02 2011-08-05 주식회사 엘지생활건강 Solid formed cosmetic composition for sunscreen
KR101081144B1 (en) * 2009-11-27 2011-11-07 한국콜마 주식회사 Washable Cleansing cosmetic composition of stick type
JP5038538B1 (en) * 2011-03-08 2012-10-03 株式会社 資生堂 Oily solid cosmetic
KR20130046272A (en) * 2011-10-27 2013-05-07 주식회사 한국화장품제조 Stick-type base make-up cosmetic composition
KR101549590B1 (en) * 2013-12-27 2015-09-03 한국콜마주식회사 Solid stick cosmetic compositions containing water-soluble moisturizer
CN105982832B (en) * 2015-03-05 2021-06-01 株式会社爱茉莉太平洋 Solid makeup cosmetic composition

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