WO2018086639A1 - Ecological alabaster glass - Google Patents
Ecological alabaster glass Download PDFInfo
- Publication number
- WO2018086639A1 WO2018086639A1 PCT/CZ2017/050051 CZ2017050051W WO2018086639A1 WO 2018086639 A1 WO2018086639 A1 WO 2018086639A1 CZ 2017050051 W CZ2017050051 W CZ 2017050051W WO 2018086639 A1 WO2018086639 A1 WO 2018086639A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- oxide
- parts
- alabaster
- glass
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims abstract description 29
- 239000010441 alabaster Substances 0.000 title claims abstract description 18
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 title claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims abstract description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 9
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 9
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 8
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims abstract description 8
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910000464 lead oxide Inorganic materials 0.000 claims abstract description 6
- 230000008018 melting Effects 0.000 claims abstract description 6
- 238000002844 melting Methods 0.000 claims abstract description 6
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims abstract description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 5
- 229910000413 arsenic oxide Inorganic materials 0.000 claims abstract description 5
- 229960002594 arsenic trioxide Drugs 0.000 claims abstract description 5
- 230000000035 biogenic effect Effects 0.000 claims abstract description 5
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000002222 fluorine compounds Chemical class 0.000 claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010425 asbestos Substances 0.000 claims abstract description 4
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 4
- 231100000701 toxic element Toxicity 0.000 claims abstract description 3
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 4
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 4
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- FZFYOUJTOSBFPQ-UHFFFAOYSA-M dipotassium;hydroxide Chemical compound [OH-].[K+].[K+] FZFYOUJTOSBFPQ-UHFFFAOYSA-M 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 4
- 231100000331 toxic Toxicity 0.000 description 4
- 230000002588 toxic effect Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 2
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 2
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 description 1
- 239000005391 art glass Substances 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 239000000075 oxide glass Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/005—Compositions for glass with special properties for opaline glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/04—Opaque glass, glaze or enamel
Definitions
- the present invention relates to ecological alabaster glass based on biogenic components, free of toxic components such as lead oxide, fluorides, antimony oxide, barium oxide, asbestos, arsenic oxide, which have technological stability for the manual production of high-quality utility glass produced in gas and electric melting devices.
- Alabaster glasses are opacifiered glasses with higher turbidity than opaline with a characteristic paraffin-like appearance.
- alabaster glasses include toxic components - for example, translucent alabaster glass according to U.S. Pat. No. 2417898 contains 30% to 60% toxic lead oxide as the basic component, and at least 18% alumina, at least 5% boron oxide and at least 10% silicate. This alabaster glass contains light diffusing crystals of aluminium borate.
- alabaster glasses are opacifiered by a combination of toxic substances - fluorides, phosphates and sulphates.
- the above mentioned deficiencies of the known alabaster glasses are removed by the ecological alabaster glass based on the biogenic components according to the invention which contains 68 to 78 parts by weight of silica (Si0 2 ), 0.2 to 5 parts by weight of boron trioxide, 0.2 to 5 parts by weight of alumina (Ai 2 (3 ⁇ 4), 0.02 to 0.025 parts by weight of ferric oxide (FeiOs), 6 to 16 parts by weight of sodium oxide (Na 2 0), 5 to 15 parts by weight of potassium oxide (K 2 0), 0.5 to 5 parts by weight of magnesium oxide (MgO), 5 to 15 parts by weight of calcium oxide (CaO) and 2 to 8 parts by weight of phosphorus pentoxide (P 2 i3 ⁇ 4).
- silica Si0 2
- boron trioxide 0.2 to 5 parts by weight of alumina
- FeiOs ferric oxide
- Na 2 0 sodium oxide
- K 2 0 potassium oxide
- MgO magnesium oxide
- CaO calcium
- the alabaster glass according to the invention does not contain any toxic elements such as lead oxide, fluorides, antimony oxide, barium oxide, asbestos, arsenic oxide. There are only biogenic elements that are part of living organisms.
- the melting conditions are comparable to the standard, i.e. in the range of 1410 - 1450 ° C, in accordance with the required coefficient of thermal expansion, which can be adjusted in the range of 9.0 - 10. 2xlO ⁇ 6 K ⁇ 1 . Coloring of this glass is also standard.
- Iron oxide Fe 2 0 3 0.02
- the melting temperature of this glass is 1420°C
- the coefficient of the thermal expansion a(2o- 300 °c) ⁇ ⁇ ⁇ .9.6.10 ⁇ 6 K _1
- composition of other alabaster glasses (in parts by weight) in the exemplary embodiment is shown in the following table:
- the ecological alabaster glass according to the invention is suitable for all types of melting devices. It enables manual and semi-automatic production of utility, lighting and art glass in the form of both pot-opal and flashed glass (duplex, triplex). This glass is environmentally friendly and is also suitable for making replicas of historically significant glass
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CZPV2016-698 | 2016-11-09 | ||
| CZ2016-698A CZ2016698A3 (cs) | 2016-11-09 | 2016-11-09 | Ekologické alabastrové sklo |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2018086639A1 true WO2018086639A1 (en) | 2018-05-17 |
Family
ID=60477021
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CZ2017/050051 WO2018086639A1 (en) | 2016-11-09 | 2017-10-25 | Ecological alabaster glass |
Country Status (2)
| Country | Link |
|---|---|
| CZ (1) | CZ2016698A3 (cs) |
| WO (1) | WO2018086639A1 (cs) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ308079B6 (cs) * | 2019-02-18 | 2019-12-18 | Preciosa, A.S. | Sklokeramický materiál spinelového typu pro výrobu bižuterních a šperkových kamenů |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2417898A (en) | 1945-04-30 | 1947-03-25 | Corning Glass Works | Alabaster glass |
| GB1254260A (en) * | 1969-02-24 | 1971-11-17 | Owens Illinois Inc | Glass compositions |
| WO1996006052A1 (en) * | 1994-08-24 | 1996-02-29 | Glasforskningsinstitutet | Opal glass |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA448123A (en) * | 1948-04-27 | Houston Armistead William | Alabaster glass | |
| CS216325B1 (cs) * | 1980-02-27 | 1982-10-29 | Zdenek Honcu | Univerzální alabastrové sklo |
| FR2682101B1 (fr) * | 1991-10-03 | 1994-10-21 | Saint Gobain Vitrage Int | Composition de verre colore destine a la realisation de vitrages. |
| CZ279603B6 (cs) * | 1993-11-03 | 1995-05-17 | Vysoká Škola Chemicko-Technologická | Křišťálové bezolovnaté sklo s indexem lomu vyšším než 1,52 |
| FR2731696B1 (fr) * | 1995-03-16 | 1997-04-25 | Saint Gobain Vitrage | Feuilles de verre destinees a la fabrication de vitrages |
| CN103030296A (zh) * | 2012-12-05 | 2013-04-10 | 毛庆云 | 一种耐水的微晶玻璃及其制备方法 |
-
2016
- 2016-11-09 CZ CZ2016-698A patent/CZ2016698A3/cs unknown
-
2017
- 2017-10-25 WO PCT/CZ2017/050051 patent/WO2018086639A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2417898A (en) | 1945-04-30 | 1947-03-25 | Corning Glass Works | Alabaster glass |
| GB1254260A (en) * | 1969-02-24 | 1971-11-17 | Owens Illinois Inc | Glass compositions |
| WO1996006052A1 (en) * | 1994-08-24 | 1996-02-29 | Glasforskningsinstitutet | Opal glass |
Also Published As
| Publication number | Publication date |
|---|---|
| CZ307041B6 (cs) | 2017-12-06 |
| CZ2016698A3 (cs) | 2017-12-06 |
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