WO2018040500A1 - Carbon fibre composite material, filter element, filter element forming method and forming device - Google Patents

Carbon fibre composite material, filter element, filter element forming method and forming device Download PDF

Info

Publication number
WO2018040500A1
WO2018040500A1 PCT/CN2017/072188 CN2017072188W WO2018040500A1 WO 2018040500 A1 WO2018040500 A1 WO 2018040500A1 CN 2017072188 W CN2017072188 W CN 2017072188W WO 2018040500 A1 WO2018040500 A1 WO 2018040500A1
Authority
WO
WIPO (PCT)
Prior art keywords
skeleton
filter element
carbon fiber
filter
composite material
Prior art date
Application number
PCT/CN2017/072188
Other languages
French (fr)
Chinese (zh)
Inventor
曹佐国
Original Assignee
广州澜泉家用电器有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 广州澜泉家用电器有限公司 filed Critical 广州澜泉家用电器有限公司
Publication of WO2018040500A1 publication Critical patent/WO2018040500A1/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/02Loose filtering material, e.g. loose fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/02Loose filtering material, e.g. loose fibres
    • B01D39/06Inorganic material, e.g. asbestos fibres, glass beads or fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2101/00Types of filters having loose filtering material
    • B01D2101/02Carbon filters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/02Types of fibres, filaments or particles, self-supporting or supported materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0407Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0442Antimicrobial, antibacterial, antifungal additives

Definitions

  • the invention relates to the field of water purification materials, in particular to a carbon fiber composite material, a filter element, a filter core forming method and a molding device.
  • Carbon fiber is made of man-made chemical fiber with high carbon content and not melting during heat treatment. It is made by heat-stable oxidation treatment, carbonization treatment and graphitization. Due to its small specific gravity and large specific surface area, Therefore, it is widely used in various fields. Carbon fiber composite material is a very popular material in the field of household water purification. It is often used in the field of purification. Its working principle is to protect the equipment by separating solid particles in liquid or gas, or making full contact with different substances. Normal work or clean air, when the fluid enters the carbon fiber composite with a certain size of the filter, its impurities are blocked, and the clean flow can flow through the carbon fiber composite.
  • the traditional household carbon fiber filter element has the limitation of installation size and size.
  • the filtration effect can achieve the best effect.
  • the residual chlorine removal rate of tap water can reach 98% or more; Because in the family life, when the tap water comes out of the water or bathes and bathes, the flow rate of the effluent will exceed 8L/min.
  • the conventional household carbon fiber filter can reduce the residual chlorine capacity of the tap water to below 75%. Less than expected results.
  • a carbon fiber composite material prepared from the following parts by weight:
  • the carbon fiber composite comprises the following components by weight:
  • the synthetic fiber is selected from at least one of a hydrophilic polyacrylonitrile-based synthetic fiber and a hydrophilic polypropylene synthetic fiber.
  • the binder is selected from at least one of polyvinyl acetate, vinyl acetate, and polyvinyl pyrrolidone.
  • the activated carbon, the activated carbon fiber, the calcium sulfite powder, and the copper-zinc alloy powder have a particle size of no more than 100 mesh.
  • a filter cartridge comprising the carbon fiber composite material of any of the above embodiments.
  • the filter element further includes a skeleton and a flat membrane disposed on the skeleton, the skeleton is provided with a plurality of water passing holes and has a water channel therein; and the carbon fiber composite material covers the skeleton on.
  • the water passage hole has a length of 20 to 40 mm * a width of 5 to 8 mm.
  • the flat membrane is a hydrophilic membrane having a filtration accuracy of 0.1 to 0.3 ⁇ m.
  • a filter core forming method includes the following steps:
  • the mixed slurry is placed in a filter core forming device and processed into a filter core semi-finished product;
  • the filter core semi-finished product is dehydrated and obtained after removing water.
  • the filter element forming method further comprises symmetrically taking the activated carbon, the activated carbon fiber Dimensions, the synthetic fibers, the calcium sulfite powder, and the copper-zinc alloy powder are subjected to a grinding treatment and sieved through 100 to 200 mesh.
  • the dehydration treatment specifically includes:
  • the filter core semi-finished product is placed in a centrifuge, dehydrated and dried;
  • the filter core semi-finished product after dewatering and drying is placed in an oven for drying.
  • the spin speed of the centrifuge is between 1400 and 1600 r/min during the dewatering and drying process.
  • the oven has a temperature of 105 to 120 ° C during the drying process.
  • the mixing slurry is placed in a filter element forming device, and processed into a filter core semi-finished product.
  • the mixed slurry is placed in a filter element forming device, and a skeleton provided with a flat film is disposed.
  • rotating the skeleton to automatically flow the mixed slurry to the surface of the skeleton to form a semi-finished filter covering the skeleton, and the semi-finished filter is matched with the flat film.
  • the skeleton constitutes the filter core semi-finished product.
  • the width of the leakage opening for the mixed slurry blanking in the filter element forming device is 10-15 mm, and the length is not less than the length of the skeleton;
  • the rotation speed of rotating the skeleton is 60 to 100 r/min, and the time is 2 to 3 minutes.
  • a filter core forming device comprises a frame and a lower hopper, a skeleton mounting shaft and a skeleton rotation driving device disposed on the frame; an elongated leakage opening is arranged below the lower hopper; the skeleton is installed A shaft is located below the lower hopper for mounting a skeleton of the filter membrane to be coated, and the skeleton rotation driving device is coupled to the skeleton mounting shaft for driving the skeleton mounting shaft to rotate.
  • the filter element forming apparatus further includes a recovery hopper, a reflux pump and a return pipe; the recovery hopper is below the shaft mounting shaft for recovering the mixed slurry; one end of the return pipe Connected to the bottom of the recovery hopper, the other end is in communication with the lower hopper; the return pump is disposed on the return line for pumping the mixed slurry recovered by the recovery hopper into the lower hopper use.
  • the carbon fiber composite material of the invention has a specific surface area of up to 1500 m 2 /g, and has good adsorption effect, for example, the adsorption value of the macromolecular organic substance methylene blue is 200 mg/g, and the service life is long, and the total amount of tap water can be more than 20 tons, which can be widely used.
  • the carbon fiber composite material of the present invention has the following beneficial effects:
  • the activated carbon fiber material has the characteristics of loose and porous structure.
  • the tap water flow rate exceeds 8L/min, the tap water passes through the carbon fiber material, and the carbon fiber material is too short when the water passes through the carbon fiber material. It is too late to process, so the residual chlorine removal ability is relatively low, and the carbon fiber composite material of the present invention will be a calcium sulfite powder.
  • the copper-zinc alloy powder is dispersed into the pores of the activated carbon fiber material, increasing the contact area between the activated carbon fiber and the filtered water, prolonging the processing time of the filtered water through the carbon fiber composite material filter element, ensuring that the filtration is more fully and thoroughly, and effectively solving
  • the disadvantage of the residual chlorine removal ability of the activated carbon fiber material at a large flow rate is remarkably improved, and the residual chlorine removal ability can be improved, for example, the residual chlorine removal capacity can reach 99% or more.
  • the activated carbon of the invention is filled in the pores of the activated carbon fiber, and the performance of the activated carbon fiber can reduce the cost of the activated carbon fiber; the main adsorption of the activated carbon fiber powder in the water purification process is a key material and determines the performance of the product.
  • Synthetic fiber is beneficial to the synthesis of calcium sulphite powder, copper-zinc alloy powder and carbon fiber of composite carbon fiber materials; the synergistic action of several components makes the carbon fiber composite material have better filtering effect.
  • the calcium sulfite in the carbon fiber composite component of the present invention has a very fast ability to remove residual chlorine, and the residual chlorine in the water can be completely treated in a contact time of 0.8 seconds. After a large number of experiments, 1 gram of calcium sulfite can be continuously processed. More than 2 tons of residual chlorine from tap water. The tap water is disinfected with chlorine gas and has a strong pungent odor. Its reaction principle with calcium sulfite:
  • HClO+HCl+2CaSO 3 CaSO 4 ⁇ +CaCl 2 +H 2 O+O 2 ⁇ .
  • the carbon fiber filter mixed with copper-zinc alloy has good antibacterial effect, ensuring the long-term use of the carbon fiber filter, and also removing heavy metals in the water.
  • the composite carbon fiber filter can be used in shower bath and whole house water purification to meet the requirements of large flux filtration. Specifically: when water passes through a copper-zinc alloy treatment medium, its oxidation-reduction potential changes from +200 mV to -500 mV. Under normal circumstances, various types of microorganisms can only grow under a specific oxidation-reduction potential, and the potential changes greatly.
  • the copper-zinc alloy treatment medium can remove heavy metal ions in water, such as lead, mercury, copper, nickel, cadmium, arsenic, antimony and many other soluble heavy metal ions, through redox reaction; the mechanism of copper-zinc alloy removal of heavy metal ions is as follows: : metal ions are plated on the surface of the copper-zinc alloy treatment medium or into the copper-zinc alloy crystal lattice, so that toxic heavy metal contaminants are combined on the copper-zinc alloy, for example, the dissolved lead ions in water are reduced to insoluble lead atoms, and Plated on the surface of copper-zinc alloy media, X-ray diffraction studies found that the removal of mercury is the formation of copper-mercury alloy.
  • heavy metal ions in water such as lead, mercury, copper, nickel, cadmium, arsenic, antimony and many other soluble heavy metal ions
  • FIG. 1 is a schematic structural view of a skeleton of an embodiment
  • Fig. 2 is a schematic view showing the structure of a filter element molding apparatus according to an embodiment.
  • the present embodiment provides a carbon fiber composite material prepared by the following components by weight: 30-40 parts by weight of activated carbon, 30-40 parts of activated carbon fiber, 10-15 parts of synthetic fiber, 8 to 15 parts by weight of calcium sulfite powder, 5 to 10 parts by weight of copper-zinc alloy powder, 0.5 to 2 parts of binder, and 90 to 100 parts of water; preferably 35 parts by weight of activated carbon, 35 parts by weight
  • the activated carbon fiber, 12 parts by weight of synthetic fiber, 10 parts by weight of calcium sulfite powder, 8 parts by weight of copper-zinc alloy powder, 0.8 parts by weight of a binder, and 95 parts by weight of water were prepared.
  • the synthetic fiber is selected from at least one of a hydrophilic polyacrylonitrile-based synthetic fiber and a hydrophilic polypropylene synthetic fiber.
  • Synthetic fiber is beneficial to the synthesis of activated carbon, calcium sulfite powder and copper-zinc alloy powder and activated carbon fiber.
  • the binder is at least one selected from the group consisting of polyvinyl acetate, vinyl acetate, and polyvinyl pyrrolidone.
  • the activated carbon, the activated carbon fiber, the calcium sulfite powder and the copper-zinc alloy powder have a particle size of not more than 100 mesh, such as activated carbon, activated carbon fiber, calcium sulfite powder and copper zinc. After the alloy powder is ground, the meshing number is not less than 100 mesh.
  • the embodiment also provides a filter element comprising the above carbon fiber composite material.
  • the filter element further includes a skeleton 100 and a flat membrane (not shown) provided on the skeleton 100.
  • the skeleton 100 is provided with a plurality of water passing holes 102 and has a water channel carbon fiber composite material covering the skeleton.
  • the skeleton 100 of the present embodiment has a cylindrical shape. It can be understood that in other embodiments, the skeleton 100 may also have a flat shape or the like.
  • the size of the water passing hole 102 is preferably, but not limited to, 20 to 40 mm in length * 5 to 8 mm in width, preferably 30 mm * 8 mm.
  • the flat membrane is preferably, but not limited to, a hydrophilic membrane having a filtration accuracy of 0.1 to 0.3 ⁇ m.
  • the embodiment further provides a filter core forming method, which comprises the following steps:
  • the mixed slurry is placed in a filter core forming device and processed into a filter core semi-finished product;
  • the semi-finished product of the filter element is dehydrated and obtained after removing water.
  • the filter element forming method further comprises the steps of arbitrarily taking activated carbon, activated carbon fiber, synthetic fiber, calcium sulfite powder and copper-zinc alloy powder for grinding, and sieving through 100 to 200 mesh.
  • the dehydration treatment specifically comprises:
  • the filter core semi-finished product is placed in a centrifuge, dehydrated and dried;
  • the semi-finished filter element after dewatering and drying is placed in an oven for drying.
  • the centrifuge has a rotational speed of 1400 to 1600 r/min, preferably 1500 r/min.
  • the temperature of the oven is 105 to 120 °C.
  • the dehydration efficiency can be improved by the centrifuge first, and the subsequent baking time can be shortened, and the productivity can be increased and the energy consumption can be reduced.
  • the mixed slurry is placed in the filter element forming device, and the processing into the filter element semi-finished product is: the mixed slurry is placed in the filter element forming device, and the skeleton provided with the flat plate film is placed in the filter element forming device.
  • the skeleton is rotated to automatically flow the mixed slurry to the surface of the skeleton to form a semi-finished filter film covering the skeleton, and the semi-finished product of the filter membrane is matched with a skeleton having a flat membrane to constitute a semi-finished product of the filter core.
  • the rotational speed of the rotating skeleton is 60 to 100 r/min, and the time is 2 to 3 minutes.
  • the present embodiment further provides a filter element forming apparatus 200 including a frame 210 , a lower hopper 220 disposed on the frame 210 , a skeleton mounting shaft 230 , and a skeleton rotation driving device (not shown). .
  • An elongated leakage port 222 is provided below the lower hopper 220.
  • the leakage port 222 has a width of 10 to 15 mm, preferably 15 mm, and a length of not less than the length of the skeleton 100.
  • a skeleton mounting shaft 230 is located below the lower hopper 220 for mounting the skeleton 100 to be coated with a filter.
  • the skeleton rotation driving device is coupled to the skeleton mounting shaft 230 for driving the rotation of the skeleton mounting shaft 230, thereby driving the skeleton 100 to rotate.
  • the filter element molding apparatus 200 of the present embodiment further includes a recovery hopper 240, a return pump (not shown), and a return line 250.
  • the recovery hopper 240 is below the skeleton mounting shaft 230 for recovery of the mixed slurry.
  • One end of the return pipe 250 communicates with the bottom of the recovery hopper 240, and the other end communicates with the lower hopper 220.
  • a reflux pump is provided on the return line 250 for pumping the mixed slurry recovered by the recovery hopper 240 into the lower hopper 220 for reuse.
  • the carbon fiber composite material of the invention has a specific surface area of up to 1500 m 2 /g, and has good adsorption effect, for example, the adsorption value of the macromolecular organic substance methylene blue is 200 mg/g, and the service life is long, and the total amount of tap water can be more than 20 tons, which can be widely used. In large water purifiers and other water purification equipment.
  • the filter core is made of a carbon fiber composite material with a skeleton, a flat membrane and the like, and the carbon fiber composite material is prepared from the following components by weight:
  • the manufacturing process of the filter element includes the following steps:
  • the mixed slurry obtained in the step 2) is placed in a filter core forming device, and processed into a filter core semi-finished product;
  • step 4) The filter element semi-finished product obtained in step 3) is placed in a centrifuge, the rotation speed of the centrifuge is 1500r/min, and the dewatering is dried;
  • the semi-finished product of the filter element is dried in an oven, and the temperature of the oven is 105 ° C to obtain a finished filter product.
  • a filter element is made of a carbon fiber composite material with a skeleton, a flat membrane, and the like, and the carbon fiber composite material is prepared from the following components by weight:
  • the manufacturing process of the filter element includes the following steps:
  • the mixed slurry obtained in the step 2) is placed in a filter core forming device, and processed into a filter core semi-finished product;
  • step 4) The filter element semi-finished product obtained in step 3) is placed in a centrifuge, the rotation speed of the centrifuge is 1500r/min, and the dewatering is dried;
  • the semi-finished product of the filter element is dried in an oven, and the temperature of the oven is 110 ° C to obtain a finished filter product.
  • a filter element is made of a carbon fiber composite material with a skeleton, a flat membrane, and the like, and the carbon fiber composite material is prepared from the following components by weight:
  • the manufacturing process of the filter element includes the following steps:
  • the mixed slurry obtained in the step 2) is placed in a filter core forming device, and processed into a filter core semi-finished product;
  • step 4) The filter element semi-finished product obtained in step 3) is placed in a centrifuge, the rotation speed of the centrifuge is 1500r/min, and the dewatering is dried;
  • the semi-finished product of the filter element is dried in an oven, and the temperature of the oven is 105 ° C to obtain a finished filter product.
  • a filter element is made of a carbon fiber composite material with a skeleton, a flat membrane, and the like, and the carbon fiber composite material is prepared from the following components by weight:
  • the manufacturing process of the filter element includes the following steps:
  • the mixed slurry obtained in the step 2) is placed in a filter core forming device, and processed into a filter core semi-finished product;
  • step 4) The filter element semi-finished product obtained in step 3) is placed in a centrifuge, the rotation speed of the centrifuge is 1500r/min, and the dewatering is dried;
  • the semi-finished product of the filter element is dried in an oven, and the temperature of the oven is 120 ° C to obtain a finished filter product.
  • Example 2 Example 3
  • Example 4 Comparative example 10L 99.99% 99.98% 99.98% 99.99% 73.37% 500L 99.95% 99.91% 99.91% 99.93% 73.34% 2000L 99.85% 99.83% 99.82% 99.81% 73.04% 4000L 99.46% 99.42% 99.45% 99.43% 67.17% 6000L 98.45% 98.39% 98.46% 98.36% 60.72% 8000L 97.81% 97.72% 97.75% 97.72% 59.46% 10000L 94.99% 94.91% 95.01% 94.08% 53.18% 12000L 94.23% 94.15% 94.31% 94.18% 51.56% 14000L 91.05% 90.99% 91.01% 90.98% 41.18%
  • the filter elements of the first to fourth embodiments of the present invention can absorb chlorine in water in a large amount compared with a commercially available filter element, thereby ensuring more complete and thorough filtration, and satisfying the large-flux filtration effect. Requirements.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Filtering Materials (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Provided are a carbon fibre composite material, a filter element, a filter element forming method and a forming device. The carbon fibre composite material is prepared from the following components in parts by weight: 30-40 parts of activated carbon, 30-40 parts of an activated carbon fibre, 10-15 parts of a synthetic fibre, 8-15 parts of calcium sulphite powder, 5-10 parts of copper-zinc alloy powder, 0.5-2 parts of a binder and 90-100 parts of water. The filter element formed from the carbon fibre composite material solves the disadvantage that a carbon fibre material has a lower residual chlorine removal capacity at a large flow rate, and significantly improves the residual chlorine removal capability.

Description

炭纤维复合材料、滤芯、滤芯成型方法和成型装置Carbon fiber composite material, filter element, filter core forming method and molding device 技术领域Technical field
本发明涉及净水材料领域,尤其是涉及一种炭纤维复合材料、滤芯、滤芯成型方法和成型装置。The invention relates to the field of water purification materials, in particular to a carbon fiber composite material, a filter element, a filter core forming method and a molding device.
背景技术Background technique
炭纤维是由含碳量较高、在热处理过程中不熔融的人造化学纤维,经热稳定氧化处理、碳化处理及石墨化等工艺制成的材料,由于其较小的比重和大比表面积,因此广泛应用于各个领域。炭纤维复合材料是家用净水领域非常青睐的材料,常应用在净化领域,其工作原理是通过分离液体或者气体中固体颗粒,或者使不同的物质成分充分接触,加快反应时间,可保护设备的正常工作或者空气的洁净,当流体进入置有一定规格滤网的炭纤维复合材料后,其杂质被阻挡,而清洁的流物能够通过炭纤维复合材料流出。Carbon fiber is made of man-made chemical fiber with high carbon content and not melting during heat treatment. It is made by heat-stable oxidation treatment, carbonization treatment and graphitization. Due to its small specific gravity and large specific surface area, Therefore, it is widely used in various fields. Carbon fiber composite material is a very popular material in the field of household water purification. It is often used in the field of purification. Its working principle is to protect the equipment by separating solid particles in liquid or gas, or making full contact with different substances. Normal work or clean air, when the fluid enters the carbon fiber composite with a certain size of the filter, its impurities are blocked, and the clean flow can flow through the carbon fiber composite.
传统的家用普通的炭纤维滤芯因安装规格尺寸要求的限制,在过滤水流速不超过4L/min时,其过滤效果能达到最佳效果,如自来水的余氯去除率可达98%以上;但是由于在家庭生活中,自来水龙头出水或洗澡沐浴时,出水的流速会超过8L/min,在如此大的流速下,传统的家用普通炭纤维滤芯过滤自来水余氯能力会下降到75%以下,达不到预期的使用效果。The traditional household carbon fiber filter element has the limitation of installation size and size. When the filtered water flow rate does not exceed 4L/min, the filtration effect can achieve the best effect. For example, the residual chlorine removal rate of tap water can reach 98% or more; Because in the family life, when the tap water comes out of the water or bathes and bathes, the flow rate of the effluent will exceed 8L/min. At such a large flow rate, the conventional household carbon fiber filter can reduce the residual chlorine capacity of the tap water to below 75%. Less than expected results.
发明内容Summary of the invention
基于此,有必要提供一种净水效果好的炭纤维复合材料、滤芯、滤芯成型方法和成型装置。Based on this, it is necessary to provide a carbon fiber composite material, a filter element, a filter element molding method, and a molding device with good water purification effect.
一种炭纤维复合材料,由如下重量份数的各组分制备而成:A carbon fiber composite material prepared from the following parts by weight:
Figure PCTCN2017072188-appb-000001
Figure PCTCN2017072188-appb-000001
Figure PCTCN2017072188-appb-000002
Figure PCTCN2017072188-appb-000002
在其中一个实施例中,优选的,所述炭纤维复合材料包括如下重量份数的各组分:In one embodiment, preferably, the carbon fiber composite comprises the following components by weight:
Figure PCTCN2017072188-appb-000003
Figure PCTCN2017072188-appb-000003
在其中一个实施例中,所述合成纤维选自亲水性聚丙烯腈基合成纤维及亲水性聚丙烯合成纤维中的至少一种。In one embodiment, the synthetic fiber is selected from at least one of a hydrophilic polyacrylonitrile-based synthetic fiber and a hydrophilic polypropylene synthetic fiber.
在其中一个实施例中,所述粘结剂选自聚醋酸乙烯酯、乙酸乙烯酯及聚乙烯醇吡咯烷酮中的至少一种。In one embodiment, the binder is selected from at least one of polyvinyl acetate, vinyl acetate, and polyvinyl pyrrolidone.
在其中一个实施例中,所述活性炭、所述活性炭纤维、所述亚硫酸钙粉末及所述铜锌合金粉末的颗粒大小均不超过100目。In one embodiment, the activated carbon, the activated carbon fiber, the calcium sulfite powder, and the copper-zinc alloy powder have a particle size of no more than 100 mesh.
一种滤芯,其含有上述任一实施例所述的炭纤维复合材料。A filter cartridge comprising the carbon fiber composite material of any of the above embodiments.
在其中一个实施例中,所述滤芯还包括骨架及设在所述骨架上的平板膜,所述骨架上设有多个通水孔且内部具有水道;所述碳纤维复合材料覆盖在所述骨架上。In one embodiment, the filter element further includes a skeleton and a flat membrane disposed on the skeleton, the skeleton is provided with a plurality of water passing holes and has a water channel therein; and the carbon fiber composite material covers the skeleton on.
在其中一个实施例中,所述通水孔的尺寸为长度20~40mm*宽度5~8mm。In one embodiment, the water passage hole has a length of 20 to 40 mm * a width of 5 to 8 mm.
在其中一个实施例中,所述平板膜是过滤精度为0.1~0.3μm的亲水性膜。In one embodiment, the flat membrane is a hydrophilic membrane having a filtration accuracy of 0.1 to 0.3 μm.
一种滤芯成型方法,包括如下步骤:A filter core forming method includes the following steps:
按照上述任一实施例所述的炭纤维复合材料中各组分的重量份数称取各组分;Each component is weighed according to the parts by weight of each component in the carbon fiber composite material according to any of the above embodiments;
将称取的所述活性炭、所述活性炭纤维、所述合成纤维、所述亚硫酸钙粉末及所述铜锌合金粉末混合,再加入粘结剂和水,混合均匀,得到混合浆料;Mixing the weighed activated carbon, the activated carbon fiber, the synthetic fiber, the calcium sulfite powder and the copper-zinc alloy powder, adding a binder and water, and uniformly mixing to obtain a mixed slurry;
将所述混合浆料置于滤芯成型装置中,加工成为滤芯半成品;The mixed slurry is placed in a filter core forming device and processed into a filter core semi-finished product;
对所述滤芯半成品进行脱水处理,除水后即得。The filter core semi-finished product is dehydrated and obtained after removing water.
在其中一个实施例中,所述滤芯成型方法还包括对称取的所述活性炭、所述活性炭纤 维、所述合成纤维、所述亚硫酸钙粉末及所述铜锌合金粉末进行研磨处理,并经100~200目筛分的步骤。In one embodiment, the filter element forming method further comprises symmetrically taking the activated carbon, the activated carbon fiber Dimensions, the synthetic fibers, the calcium sulfite powder, and the copper-zinc alloy powder are subjected to a grinding treatment and sieved through 100 to 200 mesh.
在其中一个实施例中,所述脱水处理具体包括:In one embodiment, the dehydration treatment specifically includes:
将所述滤芯半成品置于离心机中,脱水甩干;The filter core semi-finished product is placed in a centrifuge, dehydrated and dried;
将脱水甩干后的所述滤芯半成品置于烘箱中烘干。The filter core semi-finished product after dewatering and drying is placed in an oven for drying.
在其中一个实施例中,在所述脱水甩干过程中,离心机的旋转速度为1400~1600r/min。In one embodiment, the spin speed of the centrifuge is between 1400 and 1600 r/min during the dewatering and drying process.
在其中一个实施例中,在所述烘干过程中,所述烘箱的温度为105~120℃。In one embodiment, the oven has a temperature of 105 to 120 ° C during the drying process.
在其中一个实施例中,所述将所述混合浆料置于滤芯成型装置中,加工成为滤芯半成品具体是:将所述混合浆料置于滤芯成型装置中,并将设有平板膜的骨架置于滤芯成型装置中,转动所述骨架,使所述混合浆料自动流至所述骨架表面,以形成覆盖所述骨架的滤膜半成品,所述滤膜半成品配合所述设有平板膜的骨架构成所述滤芯半成品。In one embodiment, the mixing slurry is placed in a filter element forming device, and processed into a filter core semi-finished product. Specifically, the mixed slurry is placed in a filter element forming device, and a skeleton provided with a flat film is disposed. Putting in the filter forming device, rotating the skeleton to automatically flow the mixed slurry to the surface of the skeleton to form a semi-finished filter covering the skeleton, and the semi-finished filter is matched with the flat film. The skeleton constitutes the filter core semi-finished product.
在其中一个实施例中,所述滤芯成型装置中用于所述混合浆料下料的漏料口的宽度为10~15mm,长度不小于所述骨架的长度;In one embodiment, the width of the leakage opening for the mixed slurry blanking in the filter element forming device is 10-15 mm, and the length is not less than the length of the skeleton;
所述转动所述骨架的转速为60~100r/min,时间为2~3min。The rotation speed of rotating the skeleton is 60 to 100 r/min, and the time is 2 to 3 minutes.
一种滤芯成型装置,包括机架及设于所述机架上的下料斗、骨架安装轴及骨架转动驱动装置;所述下料斗的下方设有长条形的漏料口;所述骨架安装轴位于所述下料斗的下方以用于安装待覆滤膜的骨架,所述骨架转动驱动装置与所述骨架安装轴连接以用于驱动所述骨架安装轴转动。A filter core forming device comprises a frame and a lower hopper, a skeleton mounting shaft and a skeleton rotation driving device disposed on the frame; an elongated leakage opening is arranged below the lower hopper; the skeleton is installed A shaft is located below the lower hopper for mounting a skeleton of the filter membrane to be coated, and the skeleton rotation driving device is coupled to the skeleton mounting shaft for driving the skeleton mounting shaft to rotate.
在其中一个实施例中,所述滤芯成型装置还包括回收料斗、回流泵及回流管道;所述回收料斗为与所述骨架安装轴的下方以用于回收混合浆料;所述回流管道的一端与所述回收料斗的底部连通,另一端与所述下料斗连通;所述回流泵设在所述回流管道上以用于将所述回收料斗回收的混合浆料泵入所述下料斗中重新利用。In one embodiment, the filter element forming apparatus further includes a recovery hopper, a reflux pump and a return pipe; the recovery hopper is below the shaft mounting shaft for recovering the mixed slurry; one end of the return pipe Connected to the bottom of the recovery hopper, the other end is in communication with the lower hopper; the return pump is disposed on the return line for pumping the mixed slurry recovered by the recovery hopper into the lower hopper use.
本发明的炭纤维复合材料的比表面积可达1500m2/g,吸附效果好,如大分子有机物亚甲基蓝的吸附值为200mg/g,使用寿命长,如处理自来水总量可以超过20吨,可广泛于大通量净水器等净水设备中。此外,本发明的炭纤维复合材料还具有如下有益效果:The carbon fiber composite material of the invention has a specific surface area of up to 1500 m 2 /g, and has good adsorption effect, for example, the adsorption value of the macromolecular organic substance methylene blue is 200 mg/g, and the service life is long, and the total amount of tap water can be more than 20 tons, which can be widely used. In the water purification equipment such as the large flux water purifier. In addition, the carbon fiber composite material of the present invention has the following beneficial effects:
1、活性炭纤维材料具有疏松多孔的结构特点,在自来水流速超过8L/min的大流量情况下,自来水经过炭纤维材料的疏孔时,水经过炭纤维材料时由于停留时间太短,炭纤维材料来不及处理,所以余氯去除能力比较低,而本发明的炭纤维复合材料将亚硫酸钙粉末 及铜锌合金粉末分散到活性炭纤维材料的疏孔中,增加了活性炭纤维与过滤水的接触面积,延长过滤水通过炭纤维复合材料滤芯的处理时间,确保过滤得更充分更彻底,有效地解决活性炭纤维材料在大流量时余氯去除能力比较低的缺点,显著提高余氯去除能力,如余氯的去除能力可达99%以上。1. The activated carbon fiber material has the characteristics of loose and porous structure. When the tap water flow rate exceeds 8L/min, the tap water passes through the carbon fiber material, and the carbon fiber material is too short when the water passes through the carbon fiber material. It is too late to process, so the residual chlorine removal ability is relatively low, and the carbon fiber composite material of the present invention will be a calcium sulfite powder. And the copper-zinc alloy powder is dispersed into the pores of the activated carbon fiber material, increasing the contact area between the activated carbon fiber and the filtered water, prolonging the processing time of the filtered water through the carbon fiber composite material filter element, ensuring that the filtration is more fully and thoroughly, and effectively solving The disadvantage of the residual chlorine removal ability of the activated carbon fiber material at a large flow rate is remarkably improved, and the residual chlorine removal ability can be improved, for example, the residual chlorine removal capacity can reach 99% or more.
2、本发明的活性炭填充在活性炭纤维的细孔里,具有活性炭纤维的性能同时能降低活性炭纤维的成本;活性炭纤维粉在净水过程中起主要的吸附作用是关键性材料、决定产品的性能;合成纤维有利于复合炭纤维各材料亚硫酸钙粉末、铜锌合金粉末与炭纤维的合成;几种组分协同作用使炭纤维复合材料的过滤效果更好。2. The activated carbon of the invention is filled in the pores of the activated carbon fiber, and the performance of the activated carbon fiber can reduce the cost of the activated carbon fiber; the main adsorption of the activated carbon fiber powder in the water purification process is a key material and determines the performance of the product. Synthetic fiber is beneficial to the synthesis of calcium sulphite powder, copper-zinc alloy powder and carbon fiber of composite carbon fiber materials; the synergistic action of several components makes the carbon fiber composite material have better filtering effect.
3、本发明炭纤维复合材料组分中的亚硫酸钙去除余氯能力非常快,只需0.8秒的接触时间就能完全处理水中的余氯,经大量实验测试1克亚硫酸钙能连续处理超过2吨自来水的余氯。自来水采用氯气消毒,具有很强的刺激性气味,其与亚硫酸钙的反应原理:3. The calcium sulfite in the carbon fiber composite component of the present invention has a very fast ability to remove residual chlorine, and the residual chlorine in the water can be completely treated in a contact time of 0.8 seconds. After a large number of experiments, 1 gram of calcium sulfite can be continuously processed. More than 2 tons of residual chlorine from tap water. The tap water is disinfected with chlorine gas and has a strong pungent odor. Its reaction principle with calcium sulfite:
Cl2+H2O=HClO+HClCl 2 +H 2 O=HClO+HCl
HClO+HCl+2CaSO3=CaSO4↓+CaCl2+H2O+O2↑。HClO+HCl+2CaSO 3 =CaSO 4 ↓+CaCl 2 +H 2 O+O 2 ↑.
4、普通炭纤维滤芯使用一段时间后,炭纤维材料会滋生细菌,采用铜锌合金混合的炭纤维滤芯有很好的抑菌效果,保证炭纤维滤芯能长期使用,同时也能去除水中的重金属;复合炭纤维滤芯完全可以用在冲凉沐浴及全屋净水用,满足大通量过滤效果好的要求。具体的:水通过铜锌合金处理介质时,其氧化还原电位从+200mV变化到-500mV,在一般情况下,各种类型的微生物只能在特定的氧化还原电位下生长,电位的大幅度变化,能破坏细菌的细胞,从而控制了微生物的生长,起到抑菌的作用。铜锌合金处理介质可以去除水中的重金属离子,如铅、汞、铜、镍、镉、砷、锑和其他许多可溶性重金属离子,通过氧化还原反应作用完成的;铜锌合金去除重金属离子的机理如下:金属离子镀覆于铜锌合金处理介质的表面或进入铜锌合金晶格中,从而使有毒重金属污染物结合在铜锌合金上,例如,水中溶解的铅离子还原成不溶性的铅原子,并镀覆于铜锌合金介质的表面,X射线衍射研究发现汞的去除是形成了铜-汞合金。4. After using the ordinary carbon fiber filter for a period of time, the carbon fiber material will breed bacteria. The carbon fiber filter mixed with copper-zinc alloy has good antibacterial effect, ensuring the long-term use of the carbon fiber filter, and also removing heavy metals in the water. The composite carbon fiber filter can be used in shower bath and whole house water purification to meet the requirements of large flux filtration. Specifically: when water passes through a copper-zinc alloy treatment medium, its oxidation-reduction potential changes from +200 mV to -500 mV. Under normal circumstances, various types of microorganisms can only grow under a specific oxidation-reduction potential, and the potential changes greatly. It can destroy the cells of bacteria, thus controlling the growth of microorganisms and acting as a bacteriostatic agent. The copper-zinc alloy treatment medium can remove heavy metal ions in water, such as lead, mercury, copper, nickel, cadmium, arsenic, antimony and many other soluble heavy metal ions, through redox reaction; the mechanism of copper-zinc alloy removal of heavy metal ions is as follows: : metal ions are plated on the surface of the copper-zinc alloy treatment medium or into the copper-zinc alloy crystal lattice, so that toxic heavy metal contaminants are combined on the copper-zinc alloy, for example, the dissolved lead ions in water are reduced to insoluble lead atoms, and Plated on the surface of copper-zinc alloy media, X-ray diffraction studies found that the removal of mercury is the formation of copper-mercury alloy.
附图说明DRAWINGS
图1为一实施方式的骨架的结构示意图;1 is a schematic structural view of a skeleton of an embodiment;
图2为一实施方式的滤芯成型装置的结构示意图。 Fig. 2 is a schematic view showing the structure of a filter element molding apparatus according to an embodiment.
具体实施方式detailed description
为了便于理解本发明,下面将参照相关附图对本发明进行更全面的描述。附图中给出了本发明的较佳实施例。但是,本发明可以以许多不同的形式来实现,并不限于本文所描述的实施例。相反地,提供这些实施例的目的是使对本发明的公开内容的理解更加透彻全面。In order to facilitate the understanding of the present invention, the present invention will be described more fully hereinafter with reference to the accompanying drawings. Preferred embodiments of the invention are shown in the drawings. However, the invention may be embodied in many different forms and is not limited to the embodiments described herein. Rather, these embodiments are provided so that the understanding of the present disclosure will be more fully understood.
除非另有定义,本文所使用的所有的技术和科学术语与属于本发明的技术领域的技术人员通常理解的含义相同。本文中在本发明的说明书中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本发明。本文所使用的术语“和/或”包括一个或多个相关的所列项目的任意的和所有的组合。All technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs, unless otherwise defined. The terminology used in the description of the present invention is for the purpose of describing particular embodiments and is not intended to limit the invention. The term "and/or" as used herein includes any and all combinations of one or more of the associated listed items.
本实施方式提供了一种炭纤维复合材料,其由如下重量份数的各组分制备而成:30~40重量份的活性炭、30~40份的活性炭纤维、10~15份的合成纤维、8~15重量份的亚硫酸钙粉末、5~10重量份的铜锌合金粉末、0.5~2份的粘结剂以及90~100份的水;优选的是由35重量份的活性炭、35重量份的活性炭纤维、12重量份的合成纤维、10重量份的亚硫酸钙粉末、8重量份的铜锌合金粉末、0.8重量份的粘结剂以及95重量份的水制备而成。The present embodiment provides a carbon fiber composite material prepared by the following components by weight: 30-40 parts by weight of activated carbon, 30-40 parts of activated carbon fiber, 10-15 parts of synthetic fiber, 8 to 15 parts by weight of calcium sulfite powder, 5 to 10 parts by weight of copper-zinc alloy powder, 0.5 to 2 parts of binder, and 90 to 100 parts of water; preferably 35 parts by weight of activated carbon, 35 parts by weight The activated carbon fiber, 12 parts by weight of synthetic fiber, 10 parts by weight of calcium sulfite powder, 8 parts by weight of copper-zinc alloy powder, 0.8 parts by weight of a binder, and 95 parts by weight of water were prepared.
其中,合成纤维选自亲水性聚丙烯腈基合成纤维及亲水性聚丙烯合成纤维中的至少一种。合成纤维有利于活性炭、亚硫酸钙粉末及铜锌合金粉末与活性炭纤维的合成。粘结剂选自聚醋酸乙烯酯、乙酸乙烯酯及聚乙烯醇吡咯烷酮中的至少一种。The synthetic fiber is selected from at least one of a hydrophilic polyacrylonitrile-based synthetic fiber and a hydrophilic polypropylene synthetic fiber. Synthetic fiber is beneficial to the synthesis of activated carbon, calcium sulfite powder and copper-zinc alloy powder and activated carbon fiber. The binder is at least one selected from the group consisting of polyvinyl acetate, vinyl acetate, and polyvinyl pyrrolidone.
优选的,本实施方式的炭纤维复合材料中活性炭、活性炭纤维、亚硫酸钙粉末及铜锌合金粉末的颗粒大小均不超过100目,如可以将活性炭、活性炭纤维、亚硫酸钙粉末及铜锌合金粉末研磨后过目数不小于100目的筛分。Preferably, in the carbon fiber composite material of the present embodiment, the activated carbon, the activated carbon fiber, the calcium sulfite powder and the copper-zinc alloy powder have a particle size of not more than 100 mesh, such as activated carbon, activated carbon fiber, calcium sulfite powder and copper zinc. After the alloy powder is ground, the meshing number is not less than 100 mesh.
本实施方式还提供了一种滤芯,其含有上述炭纤维复合材料。具体的,在本实施方式中,如图1所示,该滤芯还包括骨架100及设在骨架100上的平板膜(图未示)。骨架100上设有多个通水孔102且内部具有水道碳纤维复合材料覆盖在骨架上。优选的,本实施方式的骨架100呈圆柱形,可理解,在其他实施例中,骨架100也可以为平板状等结构。通水孔102的尺寸优选但不限于为长度20~40mm*宽度5~8mm,优选是30mm*8mm。平板膜优选但不限于过滤精度是0.1~0.3μm的亲水性膜。The embodiment also provides a filter element comprising the above carbon fiber composite material. Specifically, in the present embodiment, as shown in FIG. 1 , the filter element further includes a skeleton 100 and a flat membrane (not shown) provided on the skeleton 100. The skeleton 100 is provided with a plurality of water passing holes 102 and has a water channel carbon fiber composite material covering the skeleton. Preferably, the skeleton 100 of the present embodiment has a cylindrical shape. It can be understood that in other embodiments, the skeleton 100 may also have a flat shape or the like. The size of the water passing hole 102 is preferably, but not limited to, 20 to 40 mm in length * 5 to 8 mm in width, preferably 30 mm * 8 mm. The flat membrane is preferably, but not limited to, a hydrophilic membrane having a filtration accuracy of 0.1 to 0.3 μm.
本实施方式还提供了一种滤芯成型方法,其包括如下步骤:The embodiment further provides a filter core forming method, which comprises the following steps:
按照上述炭纤维复合材料中各组分的重量份数称取各组分; Each component is weighed according to the parts by weight of each component in the above carbon fiber composite;
将称取的活性炭、活性炭纤维、合成纤维、亚硫酸钙粉末及铜锌合金粉末混合,再加入粘结剂和水,混合均匀,得到混合浆料;Mixing the weighed activated carbon, activated carbon fiber, synthetic fiber, calcium sulfite powder and copper-zinc alloy powder, adding binder and water, and mixing uniformly to obtain a mixed slurry;
将混合浆料置于滤芯成型装置中,加工成为滤芯半成品;The mixed slurry is placed in a filter core forming device and processed into a filter core semi-finished product;
对滤芯半成品进行脱水处理,除水后即得。The semi-finished product of the filter element is dehydrated and obtained after removing water.
优选的,在本实施方式中,该滤芯成型方法还包括对称取的活性炭、活性炭纤维、合成纤维、亚硫酸钙粉末及铜锌合金粉末进行研磨处理,并经100~200目筛分的步骤。Preferably, in the embodiment, the filter element forming method further comprises the steps of arbitrarily taking activated carbon, activated carbon fiber, synthetic fiber, calcium sulfite powder and copper-zinc alloy powder for grinding, and sieving through 100 to 200 mesh.
其中,所述脱水处理具体包括:Wherein, the dehydration treatment specifically comprises:
将滤芯半成品置于离心机中,脱水甩干;The filter core semi-finished product is placed in a centrifuge, dehydrated and dried;
将脱水甩干后的滤芯半成品置于烘箱中烘干。The semi-finished filter element after dewatering and drying is placed in an oven for drying.
优选的,在脱水甩干过程中,离心机的旋转速度为1400~1600r/min,优选为1500r/min。在烘干过程中,烘箱的温度为105~120℃。Preferably, during the dehydration and drying process, the centrifuge has a rotational speed of 1400 to 1600 r/min, preferably 1500 r/min. During the drying process, the temperature of the oven is 105 to 120 °C.
在脱水处理时,先通过离心机甩干脱水可以提高脱水效率,缩短后续的烘烤时间,可以级大地提高产能,降低能耗。In the dehydration treatment, the dehydration efficiency can be improved by the centrifuge first, and the subsequent baking time can be shortened, and the productivity can be increased and the energy consumption can be reduced.
进一步,在本实施方式中,将混合浆料置于滤芯成型装置中,加工成为滤芯半成品具体是:将混合浆料至于滤芯成型装置中,并将设有平板膜的骨架至于滤芯成型装置中,转动骨架,使混合浆料自动流至骨架表面,以形成覆盖骨架的滤膜半成品,滤膜半成品配合设有平板膜的骨架构成滤芯半成品。优选的,转动骨架的转速为60~100r/min,时间为2~3min。Further, in the present embodiment, the mixed slurry is placed in the filter element forming device, and the processing into the filter element semi-finished product is: the mixed slurry is placed in the filter element forming device, and the skeleton provided with the flat plate film is placed in the filter element forming device. The skeleton is rotated to automatically flow the mixed slurry to the surface of the skeleton to form a semi-finished filter film covering the skeleton, and the semi-finished product of the filter membrane is matched with a skeleton having a flat membrane to constitute a semi-finished product of the filter core. Preferably, the rotational speed of the rotating skeleton is 60 to 100 r/min, and the time is 2 to 3 minutes.
如图2所示,本实施方式还提供了一种滤芯成型装置200,其包括机架210及设于机架210上的下料斗220、骨架安装轴230及骨架转动驱动装置(图未示)。下料斗220的下方设有长条形的漏料口222。漏料口222的宽度为10~15mm,优选为15mm,长度不小于骨架100的长度。骨架安装轴230位于下料斗220的下方以用于安装待覆滤膜的骨架100。骨架转动驱动装置与骨架安装轴230连接以用于驱动骨架安装轴230转动,进而带动骨架100转动。As shown in FIG. 2 , the present embodiment further provides a filter element forming apparatus 200 including a frame 210 , a lower hopper 220 disposed on the frame 210 , a skeleton mounting shaft 230 , and a skeleton rotation driving device (not shown). . An elongated leakage port 222 is provided below the lower hopper 220. The leakage port 222 has a width of 10 to 15 mm, preferably 15 mm, and a length of not less than the length of the skeleton 100. A skeleton mounting shaft 230 is located below the lower hopper 220 for mounting the skeleton 100 to be coated with a filter. The skeleton rotation driving device is coupled to the skeleton mounting shaft 230 for driving the rotation of the skeleton mounting shaft 230, thereby driving the skeleton 100 to rotate.
进一步,本实施方式的滤芯成型装置200还包括回收料斗240、回流泵(图未示)及回流管道250。回收料斗240为与骨架安装轴230的下方以用于回收混合浆料。回流管道250的一端与回收料斗240的底部连通,另一端与下料斗220连通。回流泵设在回流管道250上以用于将回收料斗240回收的混合浆料泵入下料斗220中重新利用。通过设置回收 料斗240、回流泵及回流管道250等回收机构,可以确保产品的批量质量的一致性。Further, the filter element molding apparatus 200 of the present embodiment further includes a recovery hopper 240, a return pump (not shown), and a return line 250. The recovery hopper 240 is below the skeleton mounting shaft 230 for recovery of the mixed slurry. One end of the return pipe 250 communicates with the bottom of the recovery hopper 240, and the other end communicates with the lower hopper 220. A reflux pump is provided on the return line 250 for pumping the mixed slurry recovered by the recovery hopper 240 into the lower hopper 220 for reuse. By setting up recycling The recycling mechanism of the hopper 240, the return pump and the return pipe 250 can ensure the consistency of the batch quality of the product.
本发明的炭纤维复合材料的比表面积可达1500m2/g,吸附效果好,如大分子有机物亚甲基蓝的吸附值为200mg/g,使用寿命长,如处理自来水总量可以超过20吨,可广泛于大通量的净水器等净水设备中。The carbon fiber composite material of the invention has a specific surface area of up to 1500 m 2 /g, and has good adsorption effect, for example, the adsorption value of the macromolecular organic substance methylene blue is 200 mg/g, and the service life is long, and the total amount of tap water can be more than 20 tons, which can be widely used. In large water purifiers and other water purification equipment.
以下为具体实施例部分The following is a part of the specific embodiment
实施例1Example 1
一种滤芯,其是由炭纤维复合材料配合骨架、平板膜等结构制成,该炭纤维复合材料由如下重量份计的各组分制备而成:The filter core is made of a carbon fiber composite material with a skeleton, a flat membrane and the like, and the carbon fiber composite material is prepared from the following components by weight:
Figure PCTCN2017072188-appb-000004
Figure PCTCN2017072188-appb-000004
滤芯的制作工艺包括如下的步骤:The manufacturing process of the filter element includes the following steps:
1)分别将活性炭、活性炭纤维、亲水性聚丙烯腈基合成纤维、亚硫酸钙粉末、铜锌合金粉末进行研磨处理,并经100目筛分;亲水性聚丙烯腈基合成纤维;1) respectively, activated carbon, activated carbon fiber, hydrophilic polyacrylonitrile-based synthetic fiber, calcium sulfite powder, copper-zinc alloy powder are ground and sieved through 100 mesh; hydrophilic polyacrylonitrile-based synthetic fiber;
2)按配比准备将筛分后的活性炭、活性炭纤维、亲水性聚丙烯腈基合成纤维、亚硫酸钙粉末、铜锌合金粉末,加入聚醋酸乙烯酯和水混合均匀,得到混合料浆;2) preparing the activated carbon, activated carbon fiber, hydrophilic polyacrylonitrile-based synthetic fiber, calcium sulfite powder, copper-zinc alloy powder after being sieved according to the ratio, adding polyvinyl acetate and water to be uniformly mixed to obtain a mixed slurry;
3)将步骤2)得到的混合料浆置于滤芯成型装置中,加工成为滤芯半成品;3) The mixed slurry obtained in the step 2) is placed in a filter core forming device, and processed into a filter core semi-finished product;
4)将步骤3)得到的滤芯半成品放入离心机中,离心机旋转速度为1500r/min,脱水甩干;4) The filter element semi-finished product obtained in step 3) is placed in a centrifuge, the rotation speed of the centrifuge is 1500r/min, and the dewatering is dried;
5)最后,将滤芯半成品放入烤箱中烘干,烤箱的温度为105℃,得到滤芯成品。5) Finally, the semi-finished product of the filter element is dried in an oven, and the temperature of the oven is 105 ° C to obtain a finished filter product.
实施例2Example 2
一种滤芯,其是由炭纤维复合材料配合骨架、平板膜等结构制成,该炭纤维复合材料由如下重量份计的组分制备而成: A filter element is made of a carbon fiber composite material with a skeleton, a flat membrane, and the like, and the carbon fiber composite material is prepared from the following components by weight:
Figure PCTCN2017072188-appb-000005
Figure PCTCN2017072188-appb-000005
滤芯的制作工艺包括如下的步骤:The manufacturing process of the filter element includes the following steps:
1)分别将活性炭、活性炭纤维、亲水性聚丙烯腈基合成纤维、亚硫酸钙粉末、铜锌合金粉末进行研磨处理,并经200目筛分;1) grinding activated carbon, activated carbon fiber, hydrophilic polyacrylonitrile-based synthetic fiber, calcium sulfite powder, copper-zinc alloy powder, and sieved through 200 mesh;
2)按配比准备筛分后的活性炭、活性炭纤维、亲水性聚丙烯合成纤维、亚硫酸钙粉末、铜锌合金粉末,加入乙酸乙烯脂和水混合均匀,得到混合料浆;2) preparing activated carbon, activated carbon fiber, hydrophilic polypropylene synthetic fiber, calcium sulfite powder, copper-zinc alloy powder after being sieved according to the ratio, adding vinyl acetate and water to be evenly mixed to obtain a mixed slurry;
3)将步骤2)得到的混合料浆置于滤芯成型装置中,加工成为滤芯半成品;3) The mixed slurry obtained in the step 2) is placed in a filter core forming device, and processed into a filter core semi-finished product;
4)将步骤3)得到的滤芯半成品放入离心机中,离心机旋转速度为1500r/min,脱水甩干;4) The filter element semi-finished product obtained in step 3) is placed in a centrifuge, the rotation speed of the centrifuge is 1500r/min, and the dewatering is dried;
5)最后,将滤芯半成品放入烤箱中烘干,烤箱的温度为110℃,得到滤芯成品。5) Finally, the semi-finished product of the filter element is dried in an oven, and the temperature of the oven is 110 ° C to obtain a finished filter product.
实施例3Example 3
一种滤芯,其是由炭纤维复合材料配合骨架、平板膜等结构制成,该炭纤维复合材料由如下重量份计的组分制备而成:A filter element is made of a carbon fiber composite material with a skeleton, a flat membrane, and the like, and the carbon fiber composite material is prepared from the following components by weight:
Figure PCTCN2017072188-appb-000006
Figure PCTCN2017072188-appb-000006
滤芯的制作工艺包括如下的步骤:The manufacturing process of the filter element includes the following steps:
1)分别将活性炭、活性炭纤维、亲水性聚丙烯腈基合成纤维、亚硫酸钙粉末、铜锌 合金粉末进行研磨处理,并经160目筛分;1) Activated carbon, activated carbon fiber, hydrophilic polyacrylonitrile-based synthetic fiber, calcium sulfite powder, copper zinc The alloy powder is ground and sieved through 160 mesh;
2)按配比准备筛分后的活性炭、活性炭纤维、亲水性聚丙烯腈基合成纤维、亚硫酸钙粉末、铜锌合金粉末,加入聚乙烯醇吡咯烷酮和水混合均匀,得到混合料浆;2) preparing activated carbon, activated carbon fiber, hydrophilic polyacrylonitrile-based synthetic fiber, calcium sulfite powder, copper-zinc alloy powder after being sieved according to the ratio, adding polyvinyl alcohol pyrrolidone and water to uniformly mix to obtain a mixed slurry;
3)将步骤2)得到的混合料浆置于滤芯成型装置中,加工成为滤芯半成品;3) The mixed slurry obtained in the step 2) is placed in a filter core forming device, and processed into a filter core semi-finished product;
4)将步骤3)得到的滤芯半成品放入离心机中,离心机旋转速度为1500r/min,脱水甩干;4) The filter element semi-finished product obtained in step 3) is placed in a centrifuge, the rotation speed of the centrifuge is 1500r/min, and the dewatering is dried;
5)最后,将滤芯半成品放入烤箱中烘干,烤箱的温度为105℃,得到滤芯成品。5) Finally, the semi-finished product of the filter element is dried in an oven, and the temperature of the oven is 105 ° C to obtain a finished filter product.
实施例4Example 4
一种滤芯,其是由炭纤维复合材料配合骨架、平板膜等结构制成,该炭纤维复合材料由如下重量份计的组分制备而成:A filter element is made of a carbon fiber composite material with a skeleton, a flat membrane, and the like, and the carbon fiber composite material is prepared from the following components by weight:
Figure PCTCN2017072188-appb-000007
Figure PCTCN2017072188-appb-000007
滤芯的制作工艺包括如下的步骤:The manufacturing process of the filter element includes the following steps:
1)分别将活性炭、活性炭纤维、亲水性聚丙烯腈基合成纤维、亚硫酸钙粉末、铜锌合金粉末进行研磨处理,并经100目筛分;1) grinding activated carbon, activated carbon fiber, hydrophilic polyacrylonitrile-based synthetic fiber, calcium sulfite powder, copper-zinc alloy powder, and sieved through 100 mesh;
2)按配比准备筛分后的活性炭、活性炭纤维、亲水性聚丙烯腈基合成纤维、亚硫酸钙粉末、铜锌合金粉末,加入聚醋酸乙烯酯和水混合均匀,得到混合料浆;2) preparing activated carbon, activated carbon fiber, hydrophilic polyacrylonitrile-based synthetic fiber, calcium sulfite powder, copper-zinc alloy powder after being sieved according to the ratio, adding polyvinyl acetate and water to be uniformly mixed to obtain a mixed slurry;
3)将步骤2)得到的混合料浆置于滤芯成型装置中,加工成为滤芯半成品;3) The mixed slurry obtained in the step 2) is placed in a filter core forming device, and processed into a filter core semi-finished product;
4)将步骤3)得到的滤芯半成品放入离心机中,离心机旋转速度为1500r/min,脱水甩干;4) The filter element semi-finished product obtained in step 3) is placed in a centrifuge, the rotation speed of the centrifuge is 1500r/min, and the dewatering is dried;
5)最后,将滤芯半成品放入烤箱中烘干,烤箱的温度为120℃,得到滤芯成品。5) Finally, the semi-finished product of the filter element is dried in an oven, and the temperature of the oven is 120 ° C to obtain a finished filter product.
性能效果测试:Performance test:
以市售的规格尺寸为外径45*内径20*长度140毫米的普通纯活性炭纤维滤芯与实施 例1~4相同规格尺寸的复合炭纤维滤芯作为对比例,以实施例1-4得到的滤芯成品作为实验例,同时通入同一水源、同一流速(8L/min)的自来水进行过滤,自来水中的余氯浓度含量为1.0~1.2mg/L,检测过滤水中余氯的量,检测结果过滤去除率如下表1所示。Ordinary pure activated carbon fiber filter with external diameter 45* inner diameter 20* length 140 mm and its implementation The composite carbon fiber filter cartridges of the same specifications and sizes as the comparative examples 1 to 4 were used as the comparative examples, and the filter product obtained in Example 1-4 was used as an experimental example, and the tap water of the same water source and the same flow rate (8 L/min) was passed through for filtration. The residual chlorine concentration is 1.0 to 1.2 mg/L, and the amount of residual chlorine in the filtered water is detected. The filtration removal rate of the test results is shown in Table 1 below.
表1滤芯过滤水中余氯的去除率Table 1 Removal rate of residual chlorine in filter-filtered water
总流量Total flow 实施例1Example 1 实施例2Example 2 实施例3Example 3 实施例4Example 4 对比例Comparative example
10L10L 99.99%99.99% 99.98%99.98% 99.98%99.98% 99.99%99.99% 73.37%73.37%
500L500L 99.95%99.95% 99.91%99.91% 99.91%99.91% 99.93%99.93% 73.34%73.34%
2000L2000L 99.85%99.85% 99.83%99.83% 99.82%99.82% 99.81%99.81% 73.04%73.04%
4000L4000L 99.46%99.46% 99.42%99.42% 99.45%99.45% 99.43%99.43% 67.17%67.17%
6000L6000L 98.45%98.45% 98.39%98.39% 98.46%98.46% 98.36%98.36% 60.72%60.72%
8000L8000L 97.81%97.81% 97.72%97.72% 97.75%97.75% 97.72%97.72% 59.46%59.46%
10000L10000L 94.99%94.99% 94.91%94.91% 95.01%95.01% 94.08%94.08% 53.18%53.18%
12000L12000L 94.23%94.23% 94.15%94.15% 94.31%94.31% 94.18%94.18% 51.56%51.56%
14000L14000L 91.05%91.05% 90.99%90.99% 91.01%91.01% 90.98%90.98% 41.18%41.18%
由上表1可以看出,本实施例1~4的滤芯与市售的滤芯相比,本发明的滤芯能大量吸收水中的氯,确保过滤得更充分更彻底,满足大通量过滤效果好的要求。It can be seen from the above Table 1 that the filter elements of the first to fourth embodiments of the present invention can absorb chlorine in water in a large amount compared with a commercially available filter element, thereby ensuring more complete and thorough filtration, and satisfying the large-flux filtration effect. Requirements.
以上所述实施例的各技术特征可以进行任意的组合,为使描述简洁,未对上述实施例中的各个技术特征所有可能的组合都进行描述,然而,只要这些技术特征的组合不存在矛盾,都应当认为是本说明书记载的范围。The technical features of the above-described embodiments may be arbitrarily combined. For the sake of brevity of description, all possible combinations of the technical features in the above embodiments are not described. However, as long as there is no contradiction between the combinations of these technical features, All should be considered as the scope of this manual.
以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。 The above-described embodiments are merely illustrative of several embodiments of the present invention, and the description thereof is more specific and detailed, but is not to be construed as limiting the scope of the invention. It should be noted that a number of variations and modifications may be made by those skilled in the art without departing from the spirit and scope of the invention. Therefore, the scope of the invention should be determined by the appended claims.

Claims (18)

  1. 一种炭纤维复合材料,其特征在于,由如下重量份数的各组分制备而成:A carbon fiber composite material prepared by the following components by weight:
    Figure PCTCN2017072188-appb-100001
    Figure PCTCN2017072188-appb-100001
  2. 如权利要求1所述的炭纤维复合材料,其特征在于,由如下重量份数的各组分制备而成:The carbon fiber composite material according to claim 1, which is prepared from the following components by weight:
    Figure PCTCN2017072188-appb-100002
    Figure PCTCN2017072188-appb-100002
  3. 如权利要求1或2所述的炭纤维复合材料,其特征在于,所述合成纤维选自亲水性聚丙烯腈基合成纤维及亲水性聚丙烯合成纤维中的至少一种。The carbon fiber composite material according to claim 1 or 2, wherein the synthetic fiber is at least one selected from the group consisting of hydrophilic polyacrylonitrile-based synthetic fibers and hydrophilic polypropylene synthetic fibers.
  4. 如权利要求1或2所述的炭纤维复合材料,其特征在于,所述粘结剂选自聚醋酸乙烯酯、乙酸乙烯酯及聚乙烯醇吡咯烷酮中的至少一种。The carbon fiber composite material according to claim 1 or 2, wherein the binder is at least one selected from the group consisting of polyvinyl acetate, vinyl acetate, and polyvinyl pyrrolidone.
  5. 如权利要求1或2所述的炭纤维复合材料,其特征在于,所述活性炭、所述活性炭纤维、所述亚硫酸钙粉末及所述铜锌合金粉末的颗粒大小均不超过100目。The carbon fiber composite material according to claim 1 or 2, wherein the activated carbon, the activated carbon fiber, the calcium sulfite powder, and the copper-zinc alloy powder have a particle size of not more than 100 mesh.
  6. 一种滤芯,其特征在于,含有权利要求1~5中任一项所述的炭纤维复合材料。A filter element comprising the carbon fiber composite material according to any one of claims 1 to 5.
  7. 如权利要求6所述的滤芯,其特征在于,还包括骨架及设在所述骨架上的平板膜,所述平板膜通过超声波机焊接在所述骨架上,所述骨架上设有多个通水孔且内部具有水 道;所述碳纤维复合材料覆盖在所述骨架上。A filter cartridge according to claim 6, further comprising a skeleton and a flat membrane provided on said skeleton, said flat membrane being welded to said skeleton by an ultrasonic machine, said skeleton being provided with a plurality of passages Water hole and water inside The carbon fiber composite material covers the skeleton.
  8. 如权利要求7所述的滤芯,其特征在于,所述通水孔的尺寸为长度20~40mm*宽度5~8mm。The filter element according to claim 7, wherein said water passage hole has a length of 20 to 40 mm * a width of 5 to 8 mm.
  9. 如权利要求7所述的滤芯,其特征在于,所述平板膜是过滤精度为0.1~0.3μm的亲水性膜。The filter element according to claim 7, wherein the flat membrane is a hydrophilic membrane having a filtration accuracy of 0.1 to 0.3 μm.
  10. 一种滤芯成型方法,其特征在于,包括如下步骤:A filter core forming method, comprising the following steps:
    按照如权利要求1~5中任一项所述的炭纤维复合材料中各组分的重量份数称取各组分;Each component is weighed according to the parts by weight of each component in the carbon fiber composite material according to any one of claims 1 to 5;
    将称取的所述活性炭、所述活性炭纤维、所述合成纤维、所述亚硫酸钙粉末及所述铜锌合金粉末混合,再加入粘结剂和水,混合均匀,得到混合浆料;Mixing the weighed activated carbon, the activated carbon fiber, the synthetic fiber, the calcium sulfite powder and the copper-zinc alloy powder, adding a binder and water, and uniformly mixing to obtain a mixed slurry;
    将所述混合浆料置于滤芯成型装置中,加工成为滤芯半成品;The mixed slurry is placed in a filter core forming device and processed into a filter core semi-finished product;
    对所述滤芯半成品进行脱水处理,除水后即得。The filter core semi-finished product is dehydrated and obtained after removing water.
  11. 如权利要求10所述的滤芯成型方法,其特征在于,还包括对称取的所述活性炭、所述活性炭纤维、所述合成纤维、所述亚硫酸钙粉末及所述铜锌合金粉末进行研磨处理,并经100~200目筛分的步骤。The filter element molding method according to claim 10, further comprising arranging said activated carbon, said activated carbon fiber, said synthetic fiber, said calcium sulfite powder and said copper-zinc alloy powder symmetrically. And the step of screening through 100 to 200 mesh.
  12. 如权利要求10所述的滤芯成型方法,其特征在于,所述脱水处理具体包括:The filter element molding method according to claim 10, wherein the dehydration treatment specifically comprises:
    将所述滤芯半成品置于离心机中,脱水甩干;The filter core semi-finished product is placed in a centrifuge, dehydrated and dried;
    将脱水甩干后的所述滤芯半成品置于烘箱中烘干。The filter core semi-finished product after dewatering and drying is placed in an oven for drying.
  13. 如权利要求12所述的滤芯成型方法,其特征在于,在所述脱水甩干过程中,离心机的旋转速度为1400~1600r/min。The filter element molding method according to claim 12, wherein in the dehydrating and drying process, the rotation speed of the centrifuge is 1400 to 1600 r/min.
  14. 根据权利要求12所述的滤芯成型方法,其特征在于,在所述烘干过程中,所述烘箱的温度为105~120℃。The filter element molding method according to claim 12, wherein in the drying process, the temperature of the oven is 105 to 120 °C.
  15. 如权利要求10~14中任一项所述的滤芯成型方法,其特征在于,所述将所述混合浆料置于滤芯成型装置中,加工成为滤芯半成品具体是:将所述混合浆料置于滤芯成型装置中,并将设有平板膜的骨架置于滤芯成型装置中,转动所述骨架,使所述混合浆料自动流至所述骨架表面,以形成覆盖所述骨架的滤膜半成品,所述滤膜半成品配合所述设有平板膜的骨架构成所述滤芯半成品。The filter element molding method according to any one of claims 10 to 14, wherein the mixing slurry is placed in a filter element forming device, and the processing into a filter element semi-finished product is specifically: placing the mixed slurry In the filter element forming device, the skeleton provided with the flat membrane is placed in the filter element forming device, and the skeleton is rotated to automatically flow the mixed slurry to the surface of the skeleton to form a semi-finished filter film covering the skeleton. The filter semi-finished product is combined with the skeleton provided with the flat membrane to constitute the filter core semi-finished product.
  16. 如权利要求15所述的滤芯成型方法,其特征在于,所述滤芯成型装置中用于所 述混合浆料下料的漏料口的宽度为10~15mm,长度不小于所述骨架的长度;A filter element molding method according to claim 15, wherein said filter element molding device is used for The width of the leakage opening of the mixed slurry blank is 10-15 mm, and the length is not less than the length of the skeleton;
    所述转动所述骨架的转速为60~100r/min,时间为2~3min。The rotation speed of rotating the skeleton is 60 to 100 r/min, and the time is 2 to 3 minutes.
  17. 一种滤芯成型装置,其特征在于,包括机架及设于所述机架上的下料斗、骨架安装轴及骨架转动驱动装置;所述下料斗的下方设有长条形的漏料口;所述骨架安装轴位于所述下料斗的下方以用于安装待覆滤膜的骨架,所述骨架转动驱动装置与所述骨架安装轴连接以用于驱动所述骨架安装轴转动。A filter core forming device, comprising: a frame and a lower hopper, a skeleton mounting shaft and a skeleton rotation driving device disposed on the frame; and an elongated leakage opening under the lower hopper; The skeleton mounting shaft is located below the lower hopper for mounting a skeleton of the filter membrane to be coated, and the skeleton rotation driving device is coupled to the skeleton mounting shaft for driving the skeleton mounting shaft to rotate.
  18. 如权利要求17所述的滤芯成型装置,其特征在于,还包括回收料斗、回流泵及回流管道;所述回收料斗为与所述骨架安装轴的下方以用于回收混合浆料;所述回流管道的一端与所述回收料斗的底部连通,另一端与所述下料斗连通;所述回流泵设在所述回流管道上以用于将所述回收料斗回收的混合浆料泵入所述下料斗中重新利用。 A filter element molding apparatus according to claim 17, further comprising a recovery hopper, a reflux pump, and a return pipe; said recovery hopper being disposed below said skeleton mounting shaft for recovering the mixed slurry; said reflux One end of the pipe is in communication with the bottom of the recovery hopper, and the other end is in communication with the lower hopper; the return pump is disposed on the return pipe for pumping the mixed slurry recovered by the recovery hopper into the lower portion Reuse in the hopper.
PCT/CN2017/072188 2016-08-30 2017-01-23 Carbon fibre composite material, filter element, filter element forming method and forming device WO2018040500A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610783089.2 2016-08-30
CN201610783089.2A CN106215509A (en) 2016-08-30 2016-08-30 A kind of carbon fiber composite and application thereof

Publications (1)

Publication Number Publication Date
WO2018040500A1 true WO2018040500A1 (en) 2018-03-08

Family

ID=58073063

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/072188 WO2018040500A1 (en) 2016-08-30 2017-01-23 Carbon fibre composite material, filter element, filter element forming method and forming device

Country Status (2)

Country Link
CN (1) CN106215509A (en)
WO (1) WO2018040500A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI746362B (en) * 2021-01-29 2021-11-11 富利康科技股份有限公司 A method of forming an impregnated filtering member

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106215509A (en) * 2016-08-30 2016-12-14 广州澜泉家用电器有限公司 A kind of carbon fiber composite and application thereof
CN107175075A (en) * 2017-07-17 2017-09-19 金科伟业(中国)有限公司 A kind of composite activated carbon filter core and preparation method thereof
CN107570114A (en) * 2017-09-18 2018-01-12 惠州市银嘉环保科技有限公司 A kind of super passage ultrafiltration effect active carbon stick and preparation method thereof
CN108159783A (en) * 2018-01-12 2018-06-15 广州康瑞环保科技有限公司 Utilize the sintering method of self-heating sintered filter medium and the sintering equipment of implementation this method
CN109292836A (en) * 2018-09-19 2019-02-01 广州澜泉家用电器有限公司 A kind of compound water-purifying material of nano carbon fiber and its preparation method and application
CN113120988A (en) * 2021-04-20 2021-07-16 北京碧水源膜科技有限公司 Composite filter element and preparation method and application thereof
CN113304726A (en) * 2021-05-28 2021-08-27 北京碧水源净水科技有限公司 Preparation method of disinfection by-product adsorption type carbon membrane filter element, product obtained by preparation method and application of product

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010040136A1 (en) * 1999-12-22 2001-11-15 Kimberly-Clark Worldwide, Inc. Cationically charged coating on glass and nonwoven fibers
US20060000763A1 (en) * 2004-06-30 2006-01-05 Rinker Edward B Gravity flow carbon block filter
CN101254379A (en) * 2007-12-03 2008-09-03 鞍山塞诺达碳纤维有限公司 Preparation of activated carbon fibre filtering core
CN101732926A (en) * 2010-01-08 2010-06-16 潘峰 Molecular sieve filter element and preparation method thereof
CN204127467U (en) * 2014-07-18 2015-01-28 何健宏 A kind of Novel filtration water purifying direct drinking water faucet
CN105129896A (en) * 2015-08-11 2015-12-09 厦门建霖工业有限公司 Antibacterial activated carbon-activated carbon fiber composite filter core and preparation method
CN106215509A (en) * 2016-08-30 2016-12-14 广州澜泉家用电器有限公司 A kind of carbon fiber composite and application thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3415446B2 (en) * 1997-07-03 2003-06-09 高砂熱学工業株式会社 Air purification filter, method of manufacturing the same, and advanced cleaning device
JP2005046791A (en) * 2003-07-31 2005-02-24 Nichias Corp Chemical filter and its manufacturing method
CN100404101C (en) * 2006-08-09 2008-07-23 南通三友环保科技有限公司 Active carbon fabric composite filter element and production method thereof
WO2011090261A2 (en) * 2010-01-19 2011-07-28 엘지전자 주식회사 Complex filter and water purifier including complex filter
CN104826397A (en) * 2015-05-05 2015-08-12 苏州凯虹高分子科技有限公司 Activated carbon fiber sintered filter element and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010040136A1 (en) * 1999-12-22 2001-11-15 Kimberly-Clark Worldwide, Inc. Cationically charged coating on glass and nonwoven fibers
US20060000763A1 (en) * 2004-06-30 2006-01-05 Rinker Edward B Gravity flow carbon block filter
CN101254379A (en) * 2007-12-03 2008-09-03 鞍山塞诺达碳纤维有限公司 Preparation of activated carbon fibre filtering core
CN101732926A (en) * 2010-01-08 2010-06-16 潘峰 Molecular sieve filter element and preparation method thereof
CN204127467U (en) * 2014-07-18 2015-01-28 何健宏 A kind of Novel filtration water purifying direct drinking water faucet
CN105129896A (en) * 2015-08-11 2015-12-09 厦门建霖工业有限公司 Antibacterial activated carbon-activated carbon fiber composite filter core and preparation method
CN106215509A (en) * 2016-08-30 2016-12-14 广州澜泉家用电器有限公司 A kind of carbon fiber composite and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI746362B (en) * 2021-01-29 2021-11-11 富利康科技股份有限公司 A method of forming an impregnated filtering member

Also Published As

Publication number Publication date
CN106215509A (en) 2016-12-14

Similar Documents

Publication Publication Date Title
WO2018040500A1 (en) Carbon fibre composite material, filter element, filter element forming method and forming device
Mahar et al. Rapid adsorption of lead ions using porous carbon nanofibers
US11352271B2 (en) Method and device for sewage treatment
WO2015096549A1 (en) Process and apparatus for extracting battery grade lithium from brine
US20080073288A1 (en) Multifunctional filtration and water purification systems
CN103908827B (en) High efficiency water purification catridge
CN108179022A (en) A kind of admiralty fuel oil compounding desulfurization filtering agent and its preparation method and application
CN1835802A (en) Device for treating water using iron-doped iron exchangers
CN201002003Y (en) Membrane filter
CN108623031A (en) A kind of graphene water purification catridge and water purifier
CN102120146B (en) Preparation method of filter core of composite ultrafiltration tube membrane
CN104907057B (en) Spinning immobilized carbonyl iron material and application thereof in water treatment
CN103539255A (en) Suspended ceramsite-active carbon double-layer filtering tank and method for applying filtering tank in treating raw water
CN207405047U (en) A kind of multilayer MODIFIED PP filter core
US4434060A (en) Removal of heavy metals content
CN211896135U (en) Non-woven composite active carbon mixing filter element
CN101077814B (en) Filtration device based on purified diatomite and fibre filtering element and process flow thereof
RU174088U1 (en) Filter element for drinking water purification
CN111018160A (en) Heavy metal wastewater treatment device based on magnetic sepiolite adsorbent
CN105198128B (en) A kind of saving type RO pure water production method
US20130118997A1 (en) Fluid purification media and cartridge
CN204981390U (en) A compound filter core that filters for water purification
CN110496593A (en) Lamellar graphite phase carbon nitride/montmorillonite composite material and its preparation method and application
CN220907196U (en) Waste liquid adsorption device
US11780748B2 (en) Filter for water-purification device and water-purification device including the same

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17844811

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17844811

Country of ref document: EP

Kind code of ref document: A1