CN106215509A - A kind of carbon fiber composite and application thereof - Google Patents

A kind of carbon fiber composite and application thereof Download PDF

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Publication number
CN106215509A
CN106215509A CN201610783089.2A CN201610783089A CN106215509A CN 106215509 A CN106215509 A CN 106215509A CN 201610783089 A CN201610783089 A CN 201610783089A CN 106215509 A CN106215509 A CN 106215509A
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CN
China
Prior art keywords
carbon fiber
fiber composite
filter element
parts
application
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Pending
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CN201610783089.2A
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Chinese (zh)
Inventor
曹佐国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGZHOU RAJA ELECTRICAL APPLIANCE Co Ltd
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GUANGZHOU RAJA ELECTRICAL APPLIANCE Co Ltd
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Application filed by GUANGZHOU RAJA ELECTRICAL APPLIANCE Co Ltd filed Critical GUANGZHOU RAJA ELECTRICAL APPLIANCE Co Ltd
Priority to CN201610783089.2A priority Critical patent/CN106215509A/en
Publication of CN106215509A publication Critical patent/CN106215509A/en
Priority to PCT/CN2017/072188 priority patent/WO2018040500A1/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/02Loose filtering material, e.g. loose fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/02Loose filtering material, e.g. loose fibres
    • B01D39/06Inorganic material, e.g. asbestos fibres, glass beads or fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2101/00Types of filters having loose filtering material
    • B01D2101/02Carbon filters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/02Types of fibres, filaments or particles, self-supporting or supported materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0407Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0442Antimicrobial, antibacterial, antifungal additives

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Filtering Materials (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a kind of carbon fiber composite and application thereof, this carbon fiber composite, it is to be prepared from by the component of following weight portion meter: activated carbon 30 40 parts, NACF 30 40 parts, synthetic fibers 10 15 parts, sulfurous acid calcium powder 8 15 parts, Zinc alloy powder 5 10 parts, binding agent 0.5 2 parts, 90 100 parts of water.It addition, the present invention also provides for the application of a kind of carbon fiber composite.Calcium sulfite powder and ormolu powder are distributed in the thin hole of Carbon fibe material by carbon fiber composite, add Carbon fibe and the contact area crossing drainage, extended the drainage process time by Carbon fiber filter element, guarantee to filter more fully a more thorough, efficiently solve Carbon fibe material chlorine residue removal ability when big flow and, than relatively low shortcoming, significantly improve chlorine residue removal ability.

Description

A kind of carbon fiber composite and application thereof
Technical field
The invention belongs to field of compound material, be specifically related to a kind of carbon fiber composite and application thereof.
Background technology
Carbon fibe is manufactured chemical's fiber higher by phosphorus content, not melted in heat treatment process, through thermally-stabilised oxidation The material that the techniques such as process, carbonization treatment and graphitization are made, the proportion less due to it and bigger serface, the most extensively should For every field.Carbon fiber composite is the material that Domestic water purifying field is favored very much, often applies in field of purification, its work It is by separating solid particle in liquid or gas as principle, or makes different material compositions be fully contacted, add fast response Time, normal work or the cleaning of air of equipment can be protected, be equipped with the Carbon fibe of certain specification filter screen again when fluid enters After condensation material, its impurity is blocked, and the stream thing cleaned is flowed out by carbon fiber composite.
The common carbon fiber composite of domestic the most on sale is because of the restriction of installation specification dimensional requirement, in filtered water stream When speed is less than 4L/min, its filter effect can reach optimum efficiency, if the chlorine residue clearance of tap water is up to more than 98%;But Due in family life, water tap water outlet or have a bath shower time, the flow velocity of water outlet can be more than 8L/min, the biggest Flow velocity under, domestic Carbon fibe filtration of material tap water chlorine residue ability the most on sale can drop to less than 75%, does not reaches pre- The using effect of phase.
Summary of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of carbon fiber composite, this charcoal is fine Dimension composite calcium sulfite powder and ormolu powder are distributed in the thin hole of Carbon fibe material, add Carbon fibe with Cross the contact area of drainage, extend the drainage process time by Carbon fiber filter element, it is ensured that filter more fully a more thorough, have Effect ground solves Carbon fibe material chlorine residue removal ability when big flow and, than relatively low shortcoming, significantly improves chlorine residue removal ability.
It addition, the present invention also provides for the application of a kind of carbon fiber composite.
Realize the purpose of the present invention to reach by adopting the following technical scheme that:
A kind of carbon fiber composite, it is to be prepared from by the component of following weight portion meter:
Preferably, the one during described binding agent is polyvinyl acetate, vinyl acetate resin, polyvinyl pyrrolidone.
The application of a kind of carbon fiber composite, described carbon fiber composite is applied in the processing technology of filter element.
Preferably, the processing technology of described filter element comprises the following steps that
1) by the activated carbon after proportioning preliminary screening, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder, Add binding agent and water mix homogeneously, obtain mixed slurry;
2) by step 1) mixed slurry that obtains is placed in former, is processed into filter element semi-finished product;
3) by step 2) the filter element semi-finished product that obtain put in centrifuge, and dehydration dries;
4) last, filter element semi-finished product are put in baking box and dry, obtain filter element finished product.
Preferably, described step 1) before the most in steps 5), described step 5) be respectively by activated carbon, NACF, Synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder are ground processing, and divide through 100-200 mesh sieve.
Preferably, step 3) in the rotary speed of centrifuge be 1500r/min.
Preferably, step 4) in the temperature of baking box be 105-120 DEG C.
The beneficial effects of the present invention is:
1, common activated carbon fiber material is loose porous construction features, big more than 8L/min of tap water flow velocity Under traffic conditions, tap water is through the thin hole of Carbon fibe material, and water is the shortest due to the time of staying through Carbon fibe material, charcoal Fibrous material has little time to process, so chlorine residue removal ability ratio is relatively low, the carbon fiber composite of the present invention is by sulfurous acid calcium powder End and ormolu powder are distributed in the thin hole of Carbon fibe material, the contact area adding Carbon fibe with crossing drainage, extend Spend the drainage process time by Carbon fiber filter element, it is ensured that filter more fully a more thorough, efficiently solve Carbon fibe material and exist During big flow, chlorine residue removal ability is than relatively low shortcoming, significantly improves chlorine residue removal ability;
2, after common Carbon fiber filter element uses a period of time, Carbon fibe material meeting breed bacteria, use ormolu mixing Carbon fiber filter element have good fungistatic effect, it is ensured that Carbon fiber filter element energy life-time service, simultaneously also can remove the huge sum of money in water Belong to;Activated carbon composite fabric filter element can be used in have a shower shower and full house water purifying use completely, meets the requirement that big flux filtration is effective;
3, the activated carbon of the present invention is filled in the pore of NACF, has the performance energy simultaneously of kind NACF Reduce the cost of NACF;Activated carbon fiber powder plays main adsorption in Water treatment and is key material, determines The performance of fixed output quota product;Synthetic fibers are conducive to activated carbon composite fiber each material sulfurous acid calcium powder, ormolu powder and Carbon fibe Synthesis;The filter effect that several component synergism make carbon fiber composite is more preferable;
4, the calcium sulfite in carbon fiber composite component of the present invention removes chlorine residue ability very soon, only needs 0.8 second Time of contact just can process the chlorine residue in water completely, through great many of experiments 1 gram of calcium sulfite energy continuous processing of test more than 2 tons from the beginning The chlorine residue of water, tap water uses disinfection by chlorine, has the strongest penetrating odor, itself and the reaction principle of calcium sulfite:
Cl2+H2O=HClO+HCl
HClO+HCl+2CaSO3=CaSO4↓+CaCl2+H2O+O2
Ormolu therein has antibacterial, except the ability heavily belonged to: when water processes medium by ormolu, and its oxidation is also Former current potential changes to-500mV from+200mV, and in the ordinary course of things, various types of microorganisms can only be in specific oxidoreduction Grow under current potential, being widely varied of current potential, the cell of antibacterial can be destroyed, thus control the growth of microorganism, play antibacterial Effect.Ormolu process medium can remove the heavy metal ion in water, as lead, hydrargyrum, copper, nickel, cadmium, arsenic, antimony and other Many soluble heavy metal ions, are completed by redox reaction effect;The mechanism of ormolu heavy-metal ion removal As follows: metal ion plating processes the surface of medium in ormolu or enters in ormolu lattice, so that a poisonous huge sum of money Belonging to pollutant to be combined on ormolu, such as, the lead ion dissolved in water is reduced into insoluble lead atom, and plating is in copper The surface of kirsite medium;X-ray diffraction studies finds that the removal of hydrargyrum is to define copper-amalgam.
Detailed description of the invention
Below, in conjunction with detailed description of the invention, the present invention is described further:
A kind of filter element, it is made up of carbon fiber composite, and this carbon fiber composite is by the group of following weight portion meter Divide and be prepared from:
Wherein, the one during binding agent is polyvinyl acetate, vinyl acetate resin, polyvinyl pyrrolidone.
The processing technology of filter element comprises the following steps that
1) it is ground processing by activated carbon, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder respectively, And divide through 100-200 mesh sieve;
2) by the activated carbon after proportioning preliminary screening, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder, Add binding agent and water mix homogeneously, obtain mixed slurry;
3) by step 2) mixed slurry that obtains is placed in former, is processed into filter element semi-finished product;
4) by step 3) the filter element semi-finished product that obtain put in centrifuge, and centrifuge rotary speed is 1500r/min, dehydration Dry;
5) last, filter element semi-finished product to be put in baking box and dry, the temperature of baking box is 105-120 DEG C, obtains filter element finished product.
Embodiment 1
A kind of filter element, it is made up of carbon fiber composite, and this carbon fiber composite is by the group of following weight portion meter Divide and be prepared from:
The processing technology of filter element comprises the following steps that
1) it is ground processing by activated carbon, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder respectively, And divide through 100 mesh sieves;
2) activated carbon after preparing screening by proportioning, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder End, adds polyvinyl acetate and water mix homogeneously, obtains mixed slurry;
3) by step 2) mixed slurry that obtains is placed in former, is processed into filter element semi-finished product;
4) by step 3) the filter element semi-finished product that obtain put in centrifuge, and centrifuge rotary speed is 1500r/min, dehydration Dry;
5) last, filter element semi-finished product to be put in baking box and dry, the temperature of baking box is 105 DEG C, obtains filter element finished product.
Embodiment 2
A kind of filter element, it is made up of carbon fiber composite, and this carbon fiber composite is by the group of following weight portion meter Divide and be prepared from:
The processing technology of filter element comprises the following steps that
1) it is ground processing by activated carbon, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder respectively, And divide through 200 mesh sieves;
2) by the activated carbon after proportioning preliminary screening, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder, Add vinyl acetate resin and water mix homogeneously, obtain mixed slurry;
3) by step 2) mixed slurry that obtains is placed in former, is processed into filter element semi-finished product;
4) by step 3) the filter element semi-finished product that obtain put in centrifuge, and centrifuge rotary speed is 1500r/min, dehydration Dry;
5) last, filter element semi-finished product to be put in baking box and dry, the temperature of baking box is 110 DEG C, obtains filter element finished product.
Embodiment 3
A kind of filter element, it is made up of carbon fiber composite, and this carbon fiber composite is by the group of following weight portion meter Divide and be prepared from:
The processing technology of filter element comprises the following steps that
1) it is ground processing by activated carbon, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder respectively, And divide through 160 mesh sieves;
2) by the activated carbon after proportioning preliminary screening, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder, Add polyvinyl pyrrolidone and water mix homogeneously, obtain mixed slurry;
3) by step 2) mixed slurry that obtains is placed in former, is processed into filter element semi-finished product;
4) by step 3) the filter element semi-finished product that obtain put in centrifuge, and centrifuge rotary speed is 1500r/min, dehydration Dry;
5) last, filter element semi-finished product to be put in baking box and dry, the temperature of baking box is 105 DEG C, obtains filter element finished product.
Embodiment 4
A kind of filter element, it is made up of carbon fiber composite, and this carbon fiber composite is by the group of following weight portion meter Divide and be prepared from:
The processing technology of filter element comprises the following steps that
1) it is ground processing by activated carbon, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder respectively, And divide through 100 mesh sieves;
2) by the activated carbon after proportioning preliminary screening, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder, Add polyvinyl acetate and water mix homogeneously, obtain mixed slurry;
3) by step 2) mixed slurry that obtains is placed in former, is processed into filter element semi-finished product;
4) by step 3) the filter element semi-finished product that obtain put in centrifuge, and centrifuge rotary speed is 1500r/min, dehydration Dry;
5) last, filter element semi-finished product to be put in baking box and dry, the temperature of baking box is 120 DEG C, obtains filter element finished product.
The impact of performance test of the filter element that the present invention prepares:
With the Carbon fiber filter element of commercially available specification same with embodiment 1-4 as a comparison case, the filter obtained with embodiment 1-4 Core finished product, as experimental example, is passed through same water source, the tap water of same flow (8L/min) filters, and detects drainage simultaneously The amount of middle chlorine residue, testing result is as shown in the table:
The clearance of chlorine residue in table 1 filter element filtering water
Total flow Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Comparative example
10L 99.99% 99.98% 99.98% 99.99% 73.37%
500L 99.95% 99.91% 99.91% 99.93% 73.34%
2000L 99.85% 99.83% 99.82% 99.81% 73.04%
4000L 99.46% 99.42% 99.45% 99.43% 67.17%
6000L 98.45% 98.39% 98.46% 98.36% 60.72%
8000L 97.81% 97.72% 97.75% 97.72% 59.46%
10000L 94.99% 94.91% 95.01% 94.08% 53.18%
12000L 94.23% 94.15% 94.31% 94.18% 51.56%
14000L 91.05% 90.99% 91.01% 90.98% 41.18%
As can be seen from the above table, the filter element of the present embodiment 1-4 is compared with commercially available filter element, and the filter element of the present invention can be inhaled in a large number Receive the chlorine in water, it is ensured that filter more fully a more thorough, meet the requirement that big flux filtration is effective.
For a person skilled in the art, can technical scheme as described above and design, make other each Plant corresponding change and deformation, and all these changes and deforms the protection model that all should belong to the claims in the present invention Within enclosing.

Claims (7)

1. a carbon fiber composite, it is characterised in that it is to be prepared from by the component of following weight portion meter:
Carbon fiber composite the most according to claim 1, it is characterised in that described binding agent be polyvinyl acetate, One in vinyl acetate resin, polyvinyl pyrrolidone.
The application of carbon fiber composite the most according to claim 2, it is characterised in that described carbon fiber composite should In the processing technology of filter element.
The application of carbon fiber composite the most according to claim 3, it is characterised in that the processing technology bag of described filter element Include the steps:
1) by the activated carbon after proportioning preliminary screening, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder, add Binding agent and water, mix homogeneously, obtain mixed slurry;
2) by step 1) mixed slurry that obtains is placed in former, is processed into filter element semi-finished product;
3) by step 2) the filter element semi-finished product that obtain put in centrifuge, and dehydration dries;
4) last, filter element semi-finished product are put in baking box and dry, obtain filter element finished product.
The application of carbon fiber composite the most according to claim 4, it is characterised in that described step 1) also have step before Rapid 5), described step 5) for respectively activated carbon, NACF, synthetic fibers, sulfurous acid calcium powder, Zinc alloy powder are ground Mill processes, and divides through 100-200 mesh sieve.
The application of carbon fiber composite the most according to claim 4, it is characterised in that step 3) in the rotation of centrifuge Speed is 1500r/min.
The application of carbon fiber composite the most according to claim 4, it is characterised in that step 4) in the temperature of baking box be 105-120℃。
CN201610783089.2A 2016-08-30 2016-08-30 A kind of carbon fiber composite and application thereof Pending CN106215509A (en)

Priority Applications (2)

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CN201610783089.2A CN106215509A (en) 2016-08-30 2016-08-30 A kind of carbon fiber composite and application thereof
PCT/CN2017/072188 WO2018040500A1 (en) 2016-08-30 2017-01-23 Carbon fibre composite material, filter element, filter element forming method and forming device

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CN107175075A (en) * 2017-07-17 2017-09-19 金科伟业(中国)有限公司 A kind of composite activated carbon filter core and preparation method thereof
CN107570114A (en) * 2017-09-18 2018-01-12 惠州市银嘉环保科技有限公司 A kind of super passage ultrafiltration effect active carbon stick and preparation method thereof
WO2018040500A1 (en) * 2016-08-30 2018-03-08 广州澜泉家用电器有限公司 Carbon fibre composite material, filter element, filter element forming method and forming device
CN108159783A (en) * 2018-01-12 2018-06-15 广州康瑞环保科技有限公司 Utilize the sintering method of self-heating sintered filter medium and the sintering equipment of implementation this method
CN109292836A (en) * 2018-09-19 2019-02-01 广州澜泉家用电器有限公司 A kind of compound water-purifying material of nano carbon fiber and its preparation method and application
CN113120988A (en) * 2021-04-20 2021-07-16 北京碧水源膜科技有限公司 Composite filter element and preparation method and application thereof
CN113304726A (en) * 2021-05-28 2021-08-27 北京碧水源净水科技有限公司 Preparation method of disinfection by-product adsorption type carbon membrane filter element, product obtained by preparation method and application of product

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TWI746362B (en) * 2021-01-29 2021-11-11 富利康科技股份有限公司 A method of forming an impregnated filtering member

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Publication number Priority date Publication date Assignee Title
WO2018040500A1 (en) * 2016-08-30 2018-03-08 广州澜泉家用电器有限公司 Carbon fibre composite material, filter element, filter element forming method and forming device
CN107175075A (en) * 2017-07-17 2017-09-19 金科伟业(中国)有限公司 A kind of composite activated carbon filter core and preparation method thereof
CN107570114A (en) * 2017-09-18 2018-01-12 惠州市银嘉环保科技有限公司 A kind of super passage ultrafiltration effect active carbon stick and preparation method thereof
WO2019052023A1 (en) * 2017-09-18 2019-03-21 惠州市银嘉环保科技有限公司 Super-channel ultrafiltration-effect activated carbon rod and preparation method therefor
CN108159783A (en) * 2018-01-12 2018-06-15 广州康瑞环保科技有限公司 Utilize the sintering method of self-heating sintered filter medium and the sintering equipment of implementation this method
CN109292836A (en) * 2018-09-19 2019-02-01 广州澜泉家用电器有限公司 A kind of compound water-purifying material of nano carbon fiber and its preparation method and application
CN113120988A (en) * 2021-04-20 2021-07-16 北京碧水源膜科技有限公司 Composite filter element and preparation method and application thereof
CN113304726A (en) * 2021-05-28 2021-08-27 北京碧水源净水科技有限公司 Preparation method of disinfection by-product adsorption type carbon membrane filter element, product obtained by preparation method and application of product

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Application publication date: 20161214