Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
  • A61K8/89—Polysiloxanes
  • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
  • A61K8/89—Polysiloxanes
  • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
  • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
  • A61Q1/02—Preparations containing skin colorants, e.g. pigments
  • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
  • A61Q1/06—Lipsticks
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q19/00—Preparations for care of the skin
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/59—Mixtures
  • A61K2800/594—Mixtures of polymers
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof

Definitions

• Cosmetic composition comprising at least one silicone-polyurethane polymer and a silicone resin.
• the subject of the present invention is a cosmetic makeup or care composition for keratin materials comprising at least one silicone-polyurethane polymer and a silicone resin.
• the subject of the invention is also a process for making up or caring for keratin materials of human beings, comprising the application to the skin of said composition.
• Makeup or care compositions are commonly used to provide an aesthetic appearance when applied to the skin and lips, this effect to persist over time. In particular, they must withstand the various external factors that may modify their aesthetic effect, such as sweat or saliva. In particular, cosmetic products, and especially lipsticks, must not migrate or spin in wrinkles or fine lines, or transfer to a fabric. They must also be pleasant to apply and their deposit must provide a feeling of comfort to the user, while maintaining satisfactory aesthetic properties.
• film-forming polymers in order to limit the color transfer of the cosmetic compositions and to improve the holding of their hue, to incorporate into the formulas so-called film-forming polymers.
• film-forming polymers conventionally used, mention may be made of polyorganosiloxanes, in particular polydimethylsiloxanes (PDMS or Dimethicone) such as those described in documents US 6780402 (L'Oreal), US5318775 (Mary Kay Cosmetics), US4699780. (Estee Lauder) ; and US4578266 (Revlon). More recently, the use of silicone-polyurethane polymers has developed. However, these film-forming polymers do not always make it possible to obtain good results in terms of holding the color of the makeup, and resistance to friction.
• PDMS or Dimethicone polydimethylsiloxanes
• silicone-polyurethane polymers More recently, the use of silicone-polyurethane polymers has developed.
• these film-forming polymers do not always make
• the object of the present invention is therefore to provide a make-up or skincare composition for keratinous substances, in particular for lips, which has excellent properties for holding makeup, and in particular for its color, and for resistance to friction.
• the invention thus has, according to a first aspect, a cosmetic composition for makeup or care of keratin materials comprising, in a physiologically acceptable medium, at least one silicone-polyurethane polymer and a silicone resin.
• the subject of the invention is also, according to a second aspect, a process for making up or caring for keratin materials, in particular for the lips, comprising the application to said keratin materials of such a composition.
• the subject of the invention is, according to a third aspect, the use of a particular silicone resin, for improving the resistance to friction and the holding of a cosmetic composition
• a cosmetic composition comprising, in a physiologically acceptable medium, at least one polymer. silicone-polyurethane.
• compositions having improved properties of resistance and resistance to friction by associating a particular silicone-polyurethane polymer with a silicone resin, said silicone-polyurethane polymer that can be used in a sufficiently low content to not alter the frictional resistance of the composition.
• the composition according to the invention comprises at least one silicone-polyurethane polymer.
• the choice of the polyurethane silicone polymer should not be particularly limited and may relate to any polymer comprising organosiloxane units and urethane linkages.
• the silicone-polyurethane polymer is the reaction product of a polyorganosiloxane functionalized with hydroxyl groups, preferably comprising two or more hydroxyl groups, with a diisocyanate compound.
• the polyorganosiloxane functionalized with hydroxyl groups typically corresponds to the structure of formula I:
• R is independently selected at each occurrence from a hydrogen atom, a hydroxyl group, and optionally substituted hydrocarbon groups containing from 1 to 10 carbon atoms, and in particular from an alkyl, alkenyl, alkynyl, aryl, aryl group; -alkyl or alkyl-aryl substituted or unsubstituted; preferably R is selected from linear, cyclic or branched and optionally substituted C 1-6 alkyl or alkenyl groups, including, but not limited to, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, t-butyl, amyl hexyl, cyclohexyl, vinyl, allyl or Cl-8 aryl, aryl-alkyl or alkyl-aryl, including but not limited to phenyl, benzyl, tolyl, xylyl; wherein each of the above R groups may be optionally substituted with one
• R can comprise an additional group -
• L represents either a bond or a linking group; preferably L is a linking group selected from divalent hydrocarbons having 1 to 10 carbon atoms, including a divalent alkyl, alkenyl, alkynyl, aryl, alkyl-aryl or aryl-alkyl group, such as, for example, an alkyl group having Cl-10, including, but not limited to, bivalent groups of the formula - (CH 2 ) i -i 0 -, preferably - (CH 2 ) i-6 ⁇ , and more preferably, L is -CH 2 CH 2 _CH 2 -;
• n is an integer between 0 and 5000, preferably between 1 and 200, more preferably between 10 and 100, and even more preferably between 10 and 50.
• R represents at least one or more occurrences of a group. methyl, more preferably, R represents a methyl group at all or almost all occurrences, which means that R represents a group methylation at more than 90% of occurrences, including more than 95% of occurrences, or even more than 98% of occurrences.
• the polyorganosiloxane functionalized with hydroxyl groups comprises a polymethylsiloxane corresponding for example to the structure of formula la:
• the polyorganosiloxane functionalized with hydroxyl groups comprises a polymethylsiloxane corresponding for example to the structure of formula Ib:
• Suitable diisocyanates within the scope of the invention include, but are not limited to, toluene diisocyanate; methylene diphenyl diisocyanate, including 2,2'-MDI, 2,4'-MDI and 4,4'-MDI; 1,6-hexamethylene diisocyanate; isophorone diisocyanate; methylene diisocyanate dicyclohexyl; xylene diisocyanate; cyclohexane diisocyanate; diisocyanate
• the diisocyanate is selected from the group consisting of 1,6-hexamethylene diisocyanate, dicyclohexyl methylene diisocyanate, isophorone diisocyanate, and combinations thereof.
• the diisocyanate comprises or consists essentially of 1,6-hexamethylene diisocyanate.
• the diisocyanate comprises or consists essentially of isophorone diisocyanate.
• the diisocyanate comprises or consists essentially of dicyclohexyl methylene diisocyanate, this embodiment being particularly preferred.
• the silicone-polyurethane polymer according to the invention comprises recurring units derived from the polyorganosiloxane functionalized with hydroxyl groups and diisocyanate in the form of an alternating copolymer AB, where the unit A has the structure of formula 11:
• R, L and n are defined as above in relation to formula I, la, Ib and le, and wherein unit B has the structure of formula III:
• R 1 -est as defined above, and wherein the units A and B are arranged in a linear, branched or cyclic configuration, and preferably linear.
• the polymer may also comprise branching or grafting points in the polyorganosiloxane in which one or more R groups in formula I or II is a group such that:
• R is as defined for formula I, and R * may represent a group -LO- further coupling the side chain of a unit B of formula III, which in turn may be coupled further to the unit A of formula II, and so on, or R * may represent -L-OH, a group R as defined above, or a terminal group.
• the polyorganosiloxane may be present in the form of T or Q type grafts, where T indicates that only one R group on the Si atom is a polyorganosiloxane chain, as indicated in FIG. above and Q indicates that the two R groups are polyorganosiloxanes.
• T indicates that only one R group on the Si atom is a polyorganosiloxane chain, as indicated in FIG. above and Q indicates that the two R groups are polyorganosiloxanes.
• These types of polyorganosiloxane compounds are referred to as silicone-polyurethane polymer copolymer and T-resin or Q-resin, branche
• the silicone-polyurethane polymers can also be prepared from functionalized isocyanate prepolymers.
• an isocyanate prepolymer may be a difunctional or multi-functional polyorganosiloxane isocyanate, such as polyisocyanate.
• R, R 1 and L are as defined above, and where x is an integer between 0 and 5000, preferably between 1 and 200, more preferably between 10 and 100, and still more preferably 10 and 50.
• the prepolymer may also be multifunctional by introducing additional isocyanate groups carrying one or more R groups.
• the functionalized isocyanate prepolymer is reacted with a group functionalized polyorganosiloxane. hydroxyl to obtain a compound of formula I or a multifunctional analogue thereof.
• the prepolymer according to Formula V generally has a molecular weight ranging from 4000 to about 15,000 Daltons.
• the silicone-polyurethane polymer is free or substantially free of polyalkylene glycol subunits, including polyethylene glycol (PEG) or polypropylene glycol (PPG).
• PEG polyethylene glycol
• PPG polypropylene glycol
• the polymer comprises less than about 1% by weight, preferably less than about 0.5% by weight, and more preferably less than about 0.1% by weight of sub polyalkylene glycol units.
• the silicone-polyurethane polymer used in the cosmetic compositions of the invention is a linear polymer comprising the reaction product of formula Ib with a diisocyanate selected from the group consisting of diisocyanate of 1, 6-hexamethylene, dicyclohexyl methylene diisocyanate, isophorone diisocyanate, and combinations thereof.
• a silicone-polyurethane polymer is, for example, available from Siltech Corporation in the form of a premix in isododecane, under the tradename SILMER UR 5050 or UR 100100.
• composition according to the invention comprises in particular the silicone-polyurethane polymer in a content ranging from 8 to
• compositions comprising more than 16% of active silicone-polyurethane material had a lower resistance to friction and resistance.
• composition according to the invention comprises at least one silicone resin.
• a polydimethylsiloxane is not a silicone resin.
• silicone resins also called siloxane resins or silicone resins
• MDTQ silicone resins
• the letter "M” represents the monofunctional unit of formula RlR2R3SiOi / 2, the silicon atom being connected to a single oxygen atom in the polymer comprising this unit.
• the letter “D” signifies a Difunctional unit R 1 R 2 SO 2/2 in which the silicon atom is connected to two oxygen atoms.
• T represents a trifunctional unit of formula R1SiO3 / 2.
• R namely R1 and R2
• R1 and R2 represents a hydrocarbon radical (in particular alkyl) having 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or a hydroxyl group.
• the letter "Q" means a tetrafunctional unit S1O 4/2 wherein the silicon atom is bonded to four oxygen atoms themselves bonded to the rest of the polymer.
• silicone resins of different properties can be obtained from these different units, the properties of these polymers varying according to the type of monomers (or units), the nature and the number of the radical R, the length of the polymer chain , the degree of branching and the size of the hanging chains.
• the silicone resins used in the compositions according to the invention may for example be silicone resins of MQ type, T type or MQ type.
• the resins MQ, T or MQT are in solid form, in particular in powder form.
• the silicone resins used in the compositions according to the invention are film-forming, that is to say that they make it possible to form a film on the keratin materials to which they are applied.
• the silicone resins used in the compositions according to the invention are hot-soluble in silicone solvents, as opposed to polymethylsilsesquioxane (or T-resins) type resins, which are in the form of insoluble powder.
• an MQ resin is used.
• silicone resins of the MQ type mention may be made of the alkylsiloxysilicates of formula [(RI) 3S11 / 2] x (SiO4 / 2) y (MQ units) in which x and y are integers ranging from 50 to 80, and such that the group RI represents a radical as defined above, and preferably is an alkyl group having 1 to 8 carbon atoms or a hydroxyl group, preferably a methyl group.
• MQ resins trimethylsiloxysilicate type are thus preferred.
• solid silicone resins of MQ type trimethylsiloxysilicate type include those sold under the reference SR1000 by the company General Electric, under the reference TMS 803 by the company Wacker, under the name “KF-7312J” by the company Shin- Etsu, "DC 749", “DC 593” by Dow Corning.
• silicone resins comprising MQ siloxysilicate units
• phenylalkylsiloxysilicate resins such as phenylpropyldimethylsiloxysilicate (Silshine 151 sold by General Electric). The preparation of such resins is described in particular in US5817302.
• T-type silicone resins By way of example of T-type silicone resins, mention may be made of polysilsesquioxanes of formula (RSiO 3/2) x (T units) in which x is greater than 100 and such that the R group is an alkyl group having from 1 to 10 carbon atoms, said polysilsesquioxanes may further comprise Si-OH end groups.
• the polymethylsilsesquioxane resins in which R represents a methyl group can be used, for example those marketed:
• Resin MK polymer comprising repeating units of CH 3 Si0 3/2 (T units), which may also comprise up to 1% by weight of units (CH 3) 2 SiO 2/2 (D units) and having an average molecular weight of about 10,000 g / mol, or
• MQT-propyl resins As a resin comprising MQT units, those known from US 5,110,890 are particularly known.
• a preferred form of MQT type resins are MQT-propyl resins (also called MQTPr). Such resins that can be used in the compositions according to the invention are in particular those described and prepared in application WO 2005/075542, the content of which is incorporated herein by reference.
• the MQ-T-propyl resin preferably comprises the units:
• R1, R2 and R3 independently representing a hydrocarbon radical (in particular alkyl) having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or else a hydroxyl group and preferably an alkyl radical having from 1 to 8 carbon atoms; carbon or a phenyl group,
• a hydrocarbon radical in particular alkyl having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or else a hydroxyl group and preferably an alkyl radical having from 1 to 8 carbon atoms; carbon or a phenyl group
• a being between 0.05 and 0.5
• the siloxane resins which can be used according to the invention can be obtained by a process comprising the reaction of A) an MQ resin comprising at least 80 mol% of units (R13SiOi 2) a and (SiC> / 2) di R1 representing an alkyl group having 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group, a and d being greater than zero, the ratio a / d being between 0.5 and 1.5; and of
• a propyl resin T comprising at least 80 mol% of units (R3SiOi / 2) C i R3 representing an alkyl group having 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group, c being greater than zero, with the proviso that at least 40 mol% of the R 3 groups are propyl groups, in which the mass ratio A / B is between 95: 5 and 15:85, preferably the mass ratio A / B is 30:70.
• composition according to the invention comprises in particular a silicone resin, preferably MQ, in a content ranging from 1 to 20% by weight of resin, relative to the total weight of the composition, preferably from 5 to 10% by weight.
• a silicone resin preferably MQ
• Physiologically acceptable medium preferably MQ
• composition according to the invention comprises a physiologically acceptable and preferably cosmetically acceptable medium, that is to say which has no deleterious side effects and in particular which does not produce redness, heating, tugging or unacceptable tingling for a user of cosmetics.
• the physiologically acceptable medium may in particular comprise at least one oil.
• oil means a compound which is liquid at ambient temperature (25 ° C.) and which, when it is introduced at a rate of at least 1% by weight in water at 25 ° C. C, is not at all soluble in water, or soluble less than 10% by weight, relative to the weight of oil introduced into the water.
• the oil can be volatile or nonvolatile, polar or apolar. Those skilled in the art will take care to choose the oils constituting the physiologically acceptable medium of the composition according to the invention so that they are compatible with the silicone acrylate polymer and the silicone resin it contains.
• oils that can be used in the compositions according to the invention there may be mentioned hydrocarbon oils, silicone oils, fluorosilicone oils, fluorinated oils, and mixtures thereof.
• composition according to the invention comprises at least one hydrocarbon-based oil.
• hydrocarbon oil is meant an oil containing only hydrogen and carbon atoms.
• the hydrocarbon oil may be volatile, and in particular have a flash point ranging from 40 ° C. to 102 ° C., preferably ranging from 40 ° C. to 55 ° C., and preferably ranging from 40 ° C. to 50 ° C.
• the volatile hydrocarbon oil may especially be chosen from volatile hydrocarbon oils having from 8 to 16 carbon atoms and mixtures thereof, and in particular:
• C 6 -C 16 branched alkanes such as C 6 -C 16 iso-alkanes (also known as isoparaffins), 1 isododecane, isodecane, 1 isohexadecane, and for example the oils sold under the trade names of Isopars or Permetyls,
• linear alkanes for example such as n-dodecane (C12) and ntetradecane (C14) sold by Sasol respectively under the references PARAFOL 12-97 and PARAFOL 14-97, and mixtures thereof, the undecane-tridecane mixture ( Cetitol UT), the mixtures of n-undecane (Cil) and n-tridecane (C13) obtained in Examples 1 and 2 of Application WO2008 / 155059 from Cognis and mixtures thereof.
• the volatile hydrocarbon oil is preferably isododecane.
• the hydrocarbon oil may be nonvolatile hydrocarbon, preferably polar.
• said non-volatile oil may be an ester oil, in particular having between 18 and 70 carbon atoms.
• the ester oils may in particular be hydroxylated.
• the non-volatile ester oil may preferably be chosen from:
• R 1 represents the residue of a linear or branched fatty acid comprising from 4 to 40 carbon atoms and R 2 represents a hydrocarbon chain, in particular branched containing from 4 to 40 carbon atoms with the proviso that R1 + R2 is 18, such as, for example, purcellin oil (cetostearyl octanoate), isononyl isononanoate, C12-C15 alcohol benzoate, palmitate 2-hexyl ethyl, octyledodecyl neopentanoate, 2-octyl dodecyl stearate, 2-octyl dodecyl erucate, 1 isostearyl isostearate, 2-octyl dodecyl benzoate, octanoates , decanoates or ricinoleates of alcohol
• esters of formula R 1 COOR 2 in which R 1 represents the residue of a linear or branched fatty acid containing from 4 to 40 carbon atoms and R 2 represents a hydrocarbon chain, in particular a branched hydrocarbon chain containing from 4 to 40 carbon atoms. carbon, R1 and R2 being such that R1 + R2 is 18.
• the ester comprises between 18 and 40 carbon atoms in total.
• isononyl isononanoate mention may be made of isononyl isononanoate.
• diesters in particular comprising between 18 and 60 carbon atoms in total, in particular between 18 and 50 carbon atoms in total. It is especially possible to use diesters of dicarboxylic acid and monoalcohols, such as diisostearyl malate.
• the diesters may be glycol diesters and monocarboxylic acids, such as neopentyl glycol diheptanoate or polyglyceryl-2 diisostearate (especially such as the compound sold under the commercial reference DERMOL DGDIS by Alzo)
• the triesters in particular comprising between 35 and 70 carbon atoms in total, in particular such as tri tries of triacid carboxylic acid, such as triisostearyl citrate, or tridecyl trimellitate, or triesters of glycol and mono carboxylic acids such as triisostearate of polyglycerol-2;
• tetraesters in particular having a total number of carbon ranging from 35 to 70, such as the tetraesters of penthaerythritol or of polyglycerol and of a monocarboxylic acid, for example such as pentaerythrityl tetrapelargonate, pentaerythrityl of tetraisostearate, tetraisononate of pentaerythrityl, glyceryl tri-2-tetradecanoate, polyglyceryl-2 tetraisostearate or pentaerythrityl tetra decyl-2 tetradecanoate
• polyesters obtained by condensation of dimer and / or trimer of unsaturated fatty acid and of diol, such as those described in patent application FR 0 853 634, such as in particular dilinoleic acid and 1,4-diol; butanediol.
• esters and polyesters of dimer diol and mono- or dicarboxylic acid such as diol dimer esters and of fatty acid and the esters of dimer diols and dimer of dicarboxylic acid, in particular can be obtained from a dimer of dicarboxylic acid derived in particular from the dimerization of an unsaturated fatty acid in particular C8 to C34, especially C12 at C22, in particular at C16 to C20, and more particularly at C18, such as esters of dilinoleic diacids and of dilinoleic diol dimers, for example such as those marketed by the company NIPPON FINE CHEMICAL under the trade name LUSPLAN DD-DA5® and DD-DA7®
• silicone oil means an oil comprising at least one silicon atom, and in particular at least one Si-O group.
• the silicone oil can be volatile or non-volatile.
• Non-volatile silicone oils that may especially be mentioned include polydimethylsiloxanes containing at least 8 silicon atoms, polyalkylmethylsiloxanes including the alkyl chain. contains from 8 to 20 carbon atoms and the oils identified by the INCI name phenyl trimethicone.
• Volatile silicone oils that may be mentioned include certain dimethicones of viscosity 5 and 6 cSt, octamethyl cyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyl disiloxane and octamethyl. trisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, the compounds identified by the INCI names methyl trimethicone and caprylyl methicone and mixtures thereof.
• Examples of vegetable oils include wheat germ, sunflower oil, grape seed oil, sesame, maize, apricot, castor oil, shea butter, avocado, olive, soya, sweet almond oil, palm oil, rapeseed oil, cotton oil, hazelnut oil, macadamia oil, jojoba oil, alfalfa oil, poppy oil, pumpkin oil, sesame oil, pumpkin oil, rapeseed oil, blackcurrant oil, evening primrose oil , millet, barley, quinoa, rye, safflower,nadooulier, passionflower, muscat rose or camellia.
• fluorinated oils means an oil containing at least one fluorine atom, such as nonafluoromethoxybutane or perfluoromethylcyclopentane, perfluorodimethylcyclohexane, perfluoroperhydrophenanthrene, perfluorodecalin, and mixtures thereof, without this list being limiting.
• composition according to the invention preferably comprises from 40 to 80% by weight of oil, especially hydrocarbon, in particular from 45 to 75% by weight, and more preferably from 50 to 70% by weight of oil.
• the composition according to the invention may further comprise at least one wax and / or at least one lipophilic gelling agent.
• wax is meant a fatty substance having a melting temperature above 30 ° C. and generally below 100 ° C., which is liquid under the conditions of preparation of the composition and has an anisotropic crystalline organization in the solid state.
• waxes include plant, mineral or synthetic waxes, the latter may advantageously be hydrocarbon or silicone waxes. It is thus possible to mention carnauba, candelilla, rice, bee (Cera alba), optionally functionalized polyethylene waxes, and paraffin waxes, as well as ozokerite, microcrystalline waxes and C1-C22 linear fatty alcohols.
• C8-C20 acids and glycerine such as glycerin tribehenate, and mixtures thereof, without this list being limiting.
• the composition according to the invention comprises at least one apolar wax.
• Apolar wax is defined as a hydrocarbon or silicone apolar wax.
• the apolar hydrocarbon wax contains at least 95% by weight of chemical compounds consisting of carbon and hydrogen. These chemical compounds are advantageously chosen from saturated, linear or branched alkanes.
• the apolar wax may be chosen from linear hydrocarbon waxes.
• Linear hydrocarbon waxes include polymers and copolymers of ethylene, linear paraffin waxes and Fischer Tropsch waxes.
• the apolar wax may alternatively be a polyoxyalkylenated silicone type wax, that is to say a silicone comprising at least one oxyalkylene group of type (- ⁇ 3 ⁇ 4 ⁇ ) in which x can vary from 2 to 6 and a is greater than or equal to 2.
• the composition according to the invention comprises at least one polyethylene wax.
• composition according to the invention may in particular comprise a wax in a content ranging from 1 to 20% by weight, preferably from 5 to 15% by weight, relative to the total weight of the composition.
• lipophilic gelling agents are in particular fillers making it possible to modify the rheology or the texture of the composition.
• Charge is understood to mean colorless or white, mineral or synthetic, solid particles of any form, which are in an insoluble form and dispersed in the medium of the composition, irrespective of the temperature at which the composition is manufactured.
• the fillers can be mineral or organic of any shape, platelet, spherical or oblong, irrespective of the crystallographic form (for example sheet, cubic, hexagonal, orthorhombic, etc.).
• the filler may be chosen from talc, mica, silica, kaolin, hectorite type clay (bentone), fumed silica particles, optionally hydrophilic or hydrophobic treated, polyamide (Nylon®) powders (Orgasol® from Atochem), poly- (3-alanine and polyethylene, tetrafluoroethylene polymer powders (Teflon®), lauroyl-lysine, starch, boron nitride, polymeric hollow microspheres such as those of polyvinylidene chloride / acrylonitrile such as Expancel® (Nobel Industrie), copolymers of acrylic acid (Polytrap® from Dow Corning), silicone resin microbeads (Tospearls® from TOSHIBA, for example), precipitated calcium carbonate, magnesium carbonate and 1-carbonate, hydroxyapatite, silica microspheres hollow (Silica Beads® from Maprecos), elastomeric polyorgan
• the filler is selected from silica, kaolin, bentone, starch, lauroyl-lysine, fumed silica particles, optionally hydrophilic or hydrophobic treated, and mixtures thereof.
• the lipophilic gelling agent is preferably bentone.
• composition used according to the invention may comprise one or more lipophilic gelling agents in a content ranging from 0.1 to 13% by weight relative to the total weight of the composition, in particular from 0.2 to 10% by weight relative to relative to the total weight of the composition.
• composition according to the invention may further comprise at least one dyestuff which may be chosen from pigments, pearlescent agents, liposoluble dyes, lacquers (organic pigment) and mixtures thereof.
• pigments it is necessary to include white or colored particles, mineral or organic, insoluble in an aqueous solution, intended to color and / or opacify the composition.
• inorganic pigments that can be used in the invention, mention may be made of titanium oxide, zirconium oxide or cerium oxide, as well as zinc, iron or chromium oxides, blue ferric, manganese violet, ultramarine blue and chromium hydrate.
• EP-A-787730, EP-A-787731 and WO-A-96/08537 are examples of EP-A-787730, EP-A-787731 and WO-A-96/08537.
• the pigments used in the cosmetic composition according to the invention may be surface-treated with a hydrophobic treatment agent.
• the hydrophobic treatment agent may be chosen from silicones such as meticones, dimethicones, perfluoroalkylsilanes and alkyl alkoxy silanes; fatty acids such as stearic acid; metallic soaps such as aluminum dimyristate, hydrogenated tallow glutamate aluminum salt, perfluoroalkyl phosphates, perfluoroalkyl silanes, perfluoroalkyl silazanes, hexafluoropropylene polyoxides, polyorganosiloxanes comprising perfluoroalkyl perfluoropolyether groups, amino acids ; N-acyl amino acids or their salts; lecithin, isopropyl trisostearyl titanate, and mixtures thereof.
• silicones such as meticones, dimethicones, perfluoroalkylsilanes and alkyl alkoxy silanes
• fatty acids such as stearic acid
• metallic soaps such as aluminum
• the hydrophobic treatment agent is chosen from alkyl alkoxy silanes, in particular octyl triethoxy silane (OTS).
• OTS octyl triethoxy silane
• nacres it is necessary to include colored particles of any shape, iridescent or not, in particular produced by certain shellfish in their shell or else synthesized and which exhibit a color effect by optical interference.
• dyes are meant generally organic compounds soluble in fatty substances such as oils. Liposoluble dyes are, for example, Sudan red, DC Red 17, DC Green 6, ⁇ -carotene, Sudan brown, DC Yellow 11, DC Violet 2, DC orange 5, quinoline yellow.
• the dyestuffs may be present in a content ranging from 0.1 to 15% by weight, especially from 1 to 10% by weight, and in particular from 1 to 10% by weight, relative to the total weight of the cosmetic composition. assets
• composition according to the invention may also contain one or more active agents, in particular chosen from moisturizing agents (especially vitamin E), healing agents and / or anti-aging agents, skin and / or lips, and in particular lips.
• active agents in particular chosen from moisturizing agents (especially vitamin E), healing agents and / or anti-aging agents, skin and / or lips, and in particular lips.
• the invention also relates to a method of care and / or makeup (non-therapeutic) of the skin and / or lips, and in particular of the lips comprising the application of a composition according to the invention on the skin and or lips.
• the deposit made with a composition according to the invention having a good level of resistance makes it possible to ensure the persistence of the active ingredient on the skin and / or the lips and thus to improve the effectiveness of the care (moisturizing, healing effect and / or age) of the skin and / or the lips.
• composition used according to the invention may further contain humectants such as hyaluronic acid and its salts and / or polyols such as glycerine.
• humectants such as hyaluronic acid and its salts and / or polyols such as glycerine.
• composition according to the invention may also comprise any usual cosmetic ingredient that may be chosen in particular from antioxidants, perfumes, preservatives, neutralizers, surfactants, sunscreens, vitamins, moisturizers, self-tanning compounds, anti-wrinkle active agents, emollients, hydrophilic or lipophilic active agents, anti-free radical agents, deodorant agents, sequestering agents, and their mixtures.
• any usual cosmetic ingredient may be chosen in particular from antioxidants, perfumes, preservatives, neutralizers, surfactants, sunscreens, vitamins, moisturizers, self-tanning compounds, anti-wrinkle active agents, emollients, hydrophilic or lipophilic active agents, anti-free radical agents, deodorant agents, sequestering agents, and their mixtures.
• composition according to the invention may comprise at least one sunscreen.
• composition according to the invention can be advantageously used for the care or makeup of the skin or lips, and in particular the makeup of the lips.
• the product of the invention can be in the form of a base layer in the context of a double-layer makeup product of the skin or lips.
• the subject of the invention is also a process for making up or caring for keratinous substances, in particular for the lips, comprising the application to said keratin materials of at least one composition as defined above.
• the method according to the invention comprises:
• base composition also called “base coat”
• top coat a coating composition
• the top coat coating composition is chosen in particular by those skilled in the art so as to be incompatible with the base composition in order to prevent the migration of the constituents of each composition towards the other, which would alter the behavior and the intensity of color conferred by the base composition according to the invention, and would reduce the brightness conferred by the top coat coating composition.
• the top coat composition preferably comprises at least one nonvolatile, preferably glossy, oil which is incompatible with the base composition.
• the non-volatile oil may especially be a non-volatile silicone oil.
• top coat makes it possible to impart shine to the base composition, and to reduce or even eliminate the sticky feeling provided by the base composition when it is applied alone.
• Another subject of the invention is, according to another aspect, the use of a particular silicone resin, for improving the resistance to friction and the holding of a cosmetic composition
• a cosmetic composition comprising, in a physiologically acceptable medium, at least one silicone polymer - polyurethane.
• compositions were evaluated visually by an experienced makeup artist on the following criteria:
• composition 1 according to the invention left more residual deposit on the lips after wiping with a tissue than the comparative composition 2.
• compositions 1 and 2 were again applied (3 successive layers) to the lips of a panel of 9 people, then, this time, covered with a bright colorless "top coat” having the following formula:
• the makeup result was visually assessed by an experienced makeup artist on the following criteria:
• composition 1 according to the invention made it possible to obtain a more intense shade (especially during the day), homogeneous during application and spinning less (sharper outlines) than the comparative composition 2.
• a test of the compositions after a meal (pasta in sauce) also allowed to show a better hold of the hue obtained with the composition 1 according to the invention compared to the comparative composition 2.

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• 2016
  • 2016-06-14 FR FR1655494A patent/FR3052357B1/fr active Active
• 2017
  • 2017-06-13 EP EP17745375.0A patent/EP3468671B1/fr active Active
  • 2017-06-13 US US16/309,711 patent/US20190133918A1/en not_active Abandoned
  • 2017-06-13 KR KR1020187036464A patent/KR102317469B1/ko active Active
  • 2017-06-13 CN CN201780036301.1A patent/CN109310886A/zh active Pending
  • 2017-06-13 WO PCT/FR2017/051522 patent/WO2017216475A1/fr not_active Ceased
  • 2017-06-13 ES ES17745375T patent/ES2996985T3/es active Active
  • 2017-06-13 JP JP2018565356A patent/JP2019518042A/ja active Pending

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