WO2017212989A1 - Layered film, method for manufacturing layered film provided with mark, and method for manufacturing image display device - Google Patents

Layered film, method for manufacturing layered film provided with mark, and method for manufacturing image display device Download PDF

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Publication number
WO2017212989A1
WO2017212989A1 PCT/JP2017/020187 JP2017020187W WO2017212989A1 WO 2017212989 A1 WO2017212989 A1 WO 2017212989A1 JP 2017020187 W JP2017020187 W JP 2017020187W WO 2017212989 A1 WO2017212989 A1 WO 2017212989A1
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Prior art keywords
laminated film
mark
film
protective film
image display
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Application number
PCT/JP2017/020187
Other languages
French (fr)
Japanese (ja)
Inventor
幹士 藤井
Original Assignee
住友化学株式会社
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Publication date
Priority claimed from JP2017082235A external-priority patent/JP6475773B2/en
Application filed by 住友化学株式会社 filed Critical 住友化学株式会社
Priority to CN201780034623.2A priority Critical patent/CN109196393B/en
Priority to KR1020187036728A priority patent/KR102195234B1/en
Publication of WO2017212989A1 publication Critical patent/WO2017212989A1/en

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • G02B5/3041Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
    • G02B5/305Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F9/00Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements

Definitions

  • the present invention relates to a laminated film, a method for producing a marked laminated film, and a method for producing an image display device.
  • a polarizing film and a laminated film in which a temporary protective film is provided on one surface of the polarizing plate are known.
  • the laminated film is bonded to an image display panel such as a liquid crystal panel, it is necessary to accurately align the optical axis (transmission axis or absorption axis) of the polarizing plate of the laminated film with respect to the image display panel. .
  • the alignment accuracy between the image display panel and the polarizing plate is not sufficient.
  • the present invention has been made in view of the above problems, and can further improve the alignment accuracy between the image display panel and the polarizing plate, a laminated film, a method for producing a marked laminated film, and an image display device. It aims at providing the manufacturing method of.
  • the laminated film according to the present invention includes a polarizing plate and a temporary protective film provided on one surface of the polarizing plate.
  • the laminated film includes a peripheral region having a constant width from an end surface of the laminated film, and a central region inside the peripheral region.
  • the constant width is determined so as to satisfy SC / (SP + SC) ⁇ 0.7.
  • the central region has a mark.
  • the mark is provided in the central region, even if the peripheral region of the polarizing plate is curled when the polarizing plate is attached to the image display panel, the mark is not affected by the curl.
  • the polarizing plate and the image display panel can be aligned with high accuracy.
  • the mark may be a through-hole penetrating the laminated film.
  • the mark is provided on the surface of the temporary protective film, a dent provided on the surface of the temporary protective film, a through hole provided in the temporary protective film, a dyed portion provided on the temporary protective film, and a surface of the temporary protective film. And at least one selected from the group consisting of colored layers.
  • the shape of the mark may be at least one selected from the group consisting of a line, a cross, an arrow, an ellipse, and a polygon.
  • the outer shape of the laminated film can be a circle or a regular polygon.
  • the manufacturing method of the laminated film with a mark concerning this invention has the process of providing a mark in a laminated film provided with the polarizing plate and the temporary protective film provided in the one surface of the said polarizing plate.
  • the laminated film includes a peripheral region having a constant width from an end surface of the laminated film, and a central region inside the peripheral region.
  • the constant width is determined so as to satisfy SC / (SP + SC) ⁇ 0.7.
  • the mark is Provided in the central area.
  • the method of manufacturing an image display device includes the step of aligning the optical axis of the laminated film with respect to the image display panel with reference to the mark, Bonding the aligned laminated film to the image display panel.
  • a laminated film and a method for manufacturing an image display device which can further improve the accuracy of alignment between the image display panel and the polarizing plate.
  • FIG. 1A is a cross-sectional view of a laminated film according to an embodiment
  • FIG. 1B is a top view of FIG. 2A and 2B are cross-sectional views of a laminated film according to another embodiment
  • 3A to 3E are top views showing other examples of the mark shape of the laminated film.
  • FIGS. 4A to 4E are top views of laminated films according to other embodiments, respectively.
  • FIG. 5A is a top view of the image display device
  • FIG. 5B is a schematic cross-sectional view of the image display device.
  • FIG. 6 is a schematic top view of a laminated film according to a comparative example and an example.
  • a laminated film 100 includes a polarizing plate 10, a temporary protective film 8 bonded to one surface of the polarizing plate 10 with an adhesive layer 7, and a polarizing plate. It has a separate film 9 bonded to the other surface of the plate 10 with an adhesive layer 7.
  • the polarizing plate 10 includes a polarizer 2 and a protective film 3 bonded to both surfaces of the polarizer 2 with an adhesive layer 5.
  • Polyvinyl alcohol resin As the material of the polarizer 2, a known material that has been conventionally used in the production of polarizing plates can be used.
  • polyvinyl alcohol resin polyvinyl acetate resin, ethylene / vinyl acetate (EVA) resin, polyamide Examples thereof include resins and polyester resins. Of these, polyvinyl alcohol resins are preferred.
  • the polarizer 2 is obtained by subjecting this unstretched film to a dyeing process, a boric acid process, a stretching process, and the like.
  • the thickness of the polarizer 2 is preferably 3 to 20 ⁇ m, more preferably 5 to 18 ⁇ m, still more preferably 7 to 16 ⁇ m.
  • the protective film 3 is a film that prevents the main surface and end of the polarizer 2 from cracking and scratching.
  • the protective film 3 is preferably composed of various transparent resin films known in the field of polarizing plates.
  • cellulose resin whose typical example is triacetyl cellulose
  • polyolefin resin whose typical example is polypropylene resin
  • cyclic olefin resin whose typical example is norbornene resin
  • acrylic whose typical example is polymethyl methacrylate resin
  • polyester resins and polyester resins having polyethylene terephthalate resins as representative examples.
  • cellulose resin is representative.
  • the protective film is “transparent” means that the total light transmittance measured in accordance with JIS K 7361 is 70% or more.
  • the protective films 3 and 3 may be made of the same kind of material as each other, or may be made of another kind of material.
  • the protective film 3 may be a film having no optical function, or may be a film having an optical function such as a retardation film or a brightness enhancement film.
  • the thickness of the protective film 3 is preferably 5 to 30 ⁇ m, more preferably 7 to 27 ⁇ m, and still more preferably 9 to 25 ⁇ m.
  • Adhesive layer As the adhesive of the adhesive layer 5, various adhesives conventionally used for manufacturing a polarizing plate can be used.
  • an epoxy resin that does not contain an aromatic ring in the molecule is preferable from the viewpoint of weather resistance, refractive index, cationic polymerizability, and the like.
  • cures by irradiation of an active energy ray is preferable.
  • epoxy resin for example, a hydrogenated epoxy resin, an alicyclic epoxy resin, an aliphatic epoxy resin and the like are preferable.
  • polymerization initiators for example, photocationic polymerization initiators for polymerization by ultraviolet irradiation, thermal cationic polymerization initiators for polymerization by heat ray irradiation), and other additives (sensitizers, etc.) Can be added to prepare an epoxy resin composition for coating.
  • acrylic resins such as acrylamide, acrylate, urethane acrylate, and epoxy acrylate, and polyvinyl alcohol-based aqueous adhesives can be used.
  • the thickness of the polarizing plate 10 is preferably 20 to 100 ⁇ m, more preferably 25 to 90 ⁇ m, and still more preferably 30 to 80 ⁇ m.
  • the polarizing plate 10 can further include another optical layer laminated on the protective film 3.
  • a reflective polarizing film that transmits a certain kind of polarized light and reflects polarized light having the opposite properties; a film with an antiglare function having an uneven surface; a film with a surface antireflection function; surface A reflective film having a reflective function; a transflective film having both a reflective function and a transmissive function; and a viewing angle compensation film.
  • the temporary protective film 8 is a film that can be peeled off from the polarizing plate 10 together with the pressure-sensitive adhesive layer 7.
  • the temporary protective film 8 It is a film for protecting the surface from damage, abrasion and the like.
  • the temporary protective film 8 After the temporary protective film 8 is laminated on the protective film 3, it can remain bonded to the protective film 3 until the polarizing plate 10 is used.
  • the temporary protective film 8 is peeled from the protective film 3 before the polarizing plate 10 is used, the pressure-sensitive adhesive layer 7 is peeled from the polarizing plate 10 side together with the temporary protective film 8 in a state of being attached to the temporary protective film 8 side.
  • the material of the temporary protective film 8 is preferably a polyester resin such as polyethylene terephthalate, polyethylene naphthalate, polyethylene isophthalate, or polybutylene terephthalate, and the same material as the protective film 3 may be used.
  • Any other plastic film having the required strength and optical suitability for example, polyolefin film, polyacetate film, polycarbonate film, polyphenylene sulfide film, polyamide film, polyvinyl chloride film, ethylene-acetic acid A vinyl copolymer film, various liquid crystal polymer films, etc. can be used.
  • the thickness of the temporary protective film 8 is preferably 5 to 70 ⁇ m, more preferably 10 to 60 ⁇ m, and still more preferably 15 to 50 ⁇ m.
  • the pressure-sensitive adhesive layer 7 can be composed of acrylic resin, silicone resin, polyester, polyurethane, polyether, or the like.
  • the thickness of the pressure-sensitive adhesive layer 7 is preferably 2 to 40 ⁇ m, and more preferably 4 to 25 ⁇ m.
  • Examples of the method of providing the pressure-sensitive adhesive layer 7 include various pressure-sensitive adhesives such as an acrylic one-component or two-component adhesive, a rubber-based adhesive, and a silicone-based adhesive on the temporary protective film 8.
  • a temporary protective film is provided with a pressure-sensitive adhesive layer, and a temporary protective film laminate in which a pressure-sensitive adhesive layer is further provided with a release film is once wound up into a roll, and immediately before bonding with the protective film 3.
  • the release film is peeled off from the temporary protective film laminate and bonded to the protective film 3.
  • the adhesive film 7 may be provided by applying a solution containing the above-described resin or any additive component to the protective film 3 of the polarizing plate 10, and then the temporary protective film 8 may be bonded.
  • the separate film 9 is a peelable film that is stuck for the purpose of protecting the pressure-sensitive adhesive layer 7 or preventing adhesion of foreign matters, and is peeled off when the laminated film 100 is used to expose the pressure-sensitive adhesive layer 7.
  • the separate film 9 can be made of, for example, a polyethylene resin such as polyethylene, a polypropylene resin such as polypropylene, a polyester resin such as polyethylene terephthalate, or the like. Among these, a stretched film of polyethylene terephthalate is preferable.
  • the pressure-sensitive adhesive layer 7 on which the separate film 9 is laminated is a layer that functions when the polarizing plate 10 is attached to another article (for example, a liquid crystal cell or a touch panel).
  • another article for example, a liquid crystal cell or a touch panel.
  • the same material as that used when the temporary protective film 8 is laminated can be used.
  • the separation film 9 may be subjected to a release treatment with a silicone resin or the like on the surface in contact with the pressure-sensitive adhesive layer 7 so that it can be easily peeled off when the laminated film 100 is used.
  • the pressure-sensitive adhesive layer 7 remains on the polarizing plate 10 side.
  • the thickness of the separate film 9 is preferably 5 to 70 ⁇ m, more preferably 10 to 60 ⁇ m, and still more preferably 15 to 50 ⁇ m.
  • the outer shape of the laminated film 100 is circular when viewed from the lamination direction. Such a shape can be easily obtained by cutting out a wide film with a laser or a blade.
  • the laminated film 100 When viewed from the thickness direction of the laminated film 100, the laminated film 100 includes a peripheral region 100P having a constant width from the end surface of the laminated film 100, and a central region 100C inside the peripheral region 100P.
  • the constant width is determined so as to satisfy SC / (SP + SC) ⁇ 0.7.
  • SC / (SP + SC) ⁇ 0.6 is preferable
  • SC / (SP + SC) ⁇ 0.5 is more preferable
  • SC / (SP + SC) ⁇ 0.4 is further preferable
  • SC / (SP + SC) ⁇ 0.3 Is particularly preferred.
  • the center region 100C has a mark M.
  • the mark M is a colored layer 20 provided on the surface of the temporary protective film 8.
  • the colored layer 20 can be formed by a printing apparatus such as an ink jet printer.
  • the colored layer can contain colored components such as resins and pigments and dyes.
  • the mark M is not limited to the colored layer 20. Other aspects of the mark M are shown in FIGS.
  • the mark M is a recess 21 provided in the temporary protective film 8. Such a recess 21 can be easily formed by a laser, a blade or the like.
  • the depth of the recess 21 is a depth at which the pressure-sensitive adhesive layer 7 is not exposed.
  • the pressure-sensitive adhesive layer 7 may be exposed, that is, a through-hole, as indicated by a dotted line in FIG.
  • a through-hole penetrating the temporary protective film 8 and the pressure-sensitive adhesive layer 7 may be used so that the protective film 3 is exposed through the temporary protective film 8 and the pressure-sensitive adhesive layer 7.
  • the mark M is a through hole 22 that penetrates the entire laminated film 100.
  • the mark M may be, for example, a dyed portion provided on the temporary protective film 8.
  • the shape of the mark M is a cross in which the length of one line is longer than the length of the other line in FIG.
  • the shape of the mark M is not limited to a cross.
  • the line shape shown in FIG. 3A may be used
  • the arrow shape may be used as shown in FIG. 3B
  • the ellipse may be used as shown in FIG.
  • it may be a triangle (excluding a regular triangle) or a rhombus (excluding a square) as shown in (e) of FIG.
  • Other polygons (excluding regular polygons) may be used.
  • Each polygon is preferably not a regular polygon, but if it is a regular polygon, a plurality of polygons may be provided.
  • the length of the long axis (longest axis) of the mark M can be set to 0.1 to 10 mm, for example.
  • the length of the short axis (the axis in the shortest direction) of the mark M can be set to 0.1 to 7 mm, for example.
  • the mark M represents the direction of the light absorption axis or light transmission axis (optical axis) of the polarizer 2 of the polarizing plate 10.
  • the direction of the major axis of the mark M is parallel to the light absorption axis or light transmission axis (for example, the vertical direction in FIGS. 1B and 4A to 4E), etc.
  • the position of the optical axis of the polarizer is based on the direction of the mark M (the direction of the long axis, etc.) by providing the mark M so that the direction of the major axis is at a constant angle with the optical axis of the polarizer. Can be easily determined.
  • the position of the mark M is detected by providing the mark M at a fixed position with respect to the laminated film, for example, by providing the mark M so that the center of gravity of the mark M overlaps the center of gravity of the laminated film 100. By doing so, the position in the in-plane direction of the laminated film (polarizing plate 10) can be detected.
  • the laminated film 100 shown in FIG. 4A is provided with a through hole h having a circular cross section at the center, and the mark M is provided at two edges on both sides of the through hole h. In this form, only both ends of the line (a) are arranged.
  • the outer shape of the laminated film 100 is a regular polygon such as a square (see (b) in FIG. 4), a regular hexagon (see (c) in FIG. 4), and a regular octagon (see (d) in FIG. 4).
  • a regular polygon such as a square (see (b) in FIG. 4), a regular hexagon (see (c) in FIG. 4), and a regular octagon (see (d) in FIG. 4).
  • it may be a barrel shape (see FIG. 4E).
  • the direction of the optical axis cannot be determined from the outer shape, so the effect of the present invention is particularly high.
  • the mark M is provided in the central region 100C. It is sufficient that at least a part of the mark M is provided in the central region 100C, but it is preferable that all of the marks M exist in the central region 100C.
  • laminated film 90 the laminated film after peeling the separate film 9 from the laminated film 100 is referred to as a laminated film 90.
  • the image display panel 50 is prepared.
  • An example of an image display panel that requires the attachment of a polarizing plate is a liquid crystal panel, but may be an organic EL panel or the like.
  • the remaining laminated film 90 obtained by peeling the separate film 9 from the laminated film 100 is pasted on the surface of the image display panel 50.
  • a pair of marks LCM1 indicating a preferable direction of the optical axis is provided on the surface of the image display panel 50, and a pair of marks LCM2 indicating a preferable direction of the optical axis is provided on the back surface of the image display panel 50. Is provided.
  • the separate film 9 is peeled from the laminated film 100 to form a laminated film 90.
  • the rotation direction of the laminated film 90 is adjusted to a predetermined direction.
  • the laminated film 90 may be rotated so that the major axis direction of the mark M and the direction connecting the pair of marks LCM1 of the image display panel are parallel to each other.
  • the position in the in-plane direction of the laminated film 90 is adjusted to a predetermined position with respect to the image display panel 50.
  • the laminated film 90 may be moved so that the position of the mark M is between the pair of marks LCM1.
  • the laminated film 90 is placed on the surface of the image display panel 50 via the adhesive layer 7. Paste.
  • the pasting process including the positioning process includes a camera for photographing the mark, an image processing device for recognizing the shape and position of the mark based on the photographed image, and a necessary rotation amount and necessary movement amount based on the processing result. It can be realized by a positioning device including a movement control device that calculates the value and a robot hand that moves the laminated film 90. Image processing and movement control can be computer processing.
  • the separate film 9 is peeled from another laminated film 100 to form another laminated film 90, and based on the mark M of the laminated film 90 and the pair of marks LCM2 on the back side of the image display panel 50. Similarly, the laminated film 90 is attached to the back surface of the image display panel 50.
  • the optical axes and positions of the pair of laminated films 90 and 90 attached to the image display panel 50 are adjusted to a desired position.
  • it can arrange
  • the peripheral region is easily curled. Therefore, if the mark M is provided in the peripheral area of the laminated film 100 (90), the position of the mark M is displaced due to the curl, and the alignment accuracy with the image display panel may be lowered.
  • the mark M is provided in the central region 100C of the laminated film 100 (90). Therefore, when referring to the mark M with a camera, visual observation, or the like, it is possible to reduce a deviation in recognition of the position of the mark M. Therefore, the rotational position of the laminated film 90 and the position in the in-plane direction can be adjusted with respect to the image display panel 50 with high accuracy.
  • the protective films 3 and 3 are made of different materials (for example, one is triacetyl).
  • the cellulose-based resin such as cellulose and the other is a cyclic olefin-based resin
  • the moisture permeability of any layer constituting the laminated film 100 is high (for example, 250 g / m 2 ⁇ 24 h or more).
  • the peripheral region is easily curled when the outer shape of the laminated film 100 has acute corners. Since the laminated film 100 having such a layer configuration and / or outer shape is easily curled in the peripheral region, the effect of the present invention is particularly high.
  • the present invention is not limited to the above embodiment.
  • the adhesive layer 7 and the separate film 9 are provided in the opposite side to the temporary protective film 8 of the polarizing plate 10, it can implement even without these.
  • an adhesive may be provided on the image display panel side when being attached to the image display panel, and the protective film of the laminated film 100 may be directly attached to the adhesive.
  • Temporary protective film 8 (polyethylene terephthalate) / adhesive layer 7 (acrylic resin) / protective film 3 (triacetyl cellulose) / adhesive layer 5 (epoxy resin) / polarizer 2 (iodine dyed stretched PVA) / adhesive layer 5 (epoxy resin) / protective film 3 (triacetyl cellulose) / adhesive layer 7 (acrylic resin) / separate film 9 (polyethylene terephthalate)
  • the laminated film 100 is provided with a cross mark M (vertical bar length 0.5 mm, horizontal bar length 0.5 mm, vertical bar and horizontal bar width 0.05 mm) on the surface of the temporary protective film 8.
  • the mark M is a resin layer formed with black ink.
  • the mark M was arranged so that the vertical bar of the cross mark M was parallel to the short side of the laminated film 100 and the horizontal bar was parallel to the long side of the laminated film 100.
  • the boundary line B between the central region 100C and the peripheral region 100P is arranged so as to pass through the center of the vertical bar and horizontal bar of the cross mark M, respectively.
  • the width a of the peripheral region 100P was 1 mm.
  • Comparative Examples 2 and 3 and Examples 1 and 2 were the same as Comparative Example 1 except that SC / (SP + SC) was 0.86, 0.78, 0.70, and 0.63, respectively.
  • the width a of the peripheral region 100P was 3 mm, 5 mm, 7 mm, and 9 mm, respectively.
  • SYMBOLS 10 Polarizing plate, 20 ... Colored layer, 21 ... Depression, 22 ... Through-hole, 90, 100 ... Laminated film, 8 ... Temporary protective film, 100P ... Peripheral area

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Nonlinear Science (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Polarising Elements (AREA)
  • Liquid Crystal (AREA)

Abstract

Provided are a layered film whereby the precision of positional alignment between an image display panel and a polarizing plate can be further enhanced, and a method for manufacturing an image display device. A layered film 100 is provided with a polarizing plate 10 and a temporary protective film 8 provided on one side of the polarizing plate 10. The layered film 100 is provided with a peripheral region 100P extending a fixed width from the end surface of the layered film, and a central region 100C toward the inside from the peripheral region 100P. The fixed width is determined so as to satisfy the expression SC/(SP + SC) ≤ 0.7, where SP is the surface area of the peripheral region 100P and SC is the surface area of the central region 100C. The central region 100C has a mark M.

Description

積層フィルム、マーク付き積層フィルムの製造方法、及び、画像表示装置の製造方法LAMINATED FILM, MARKING LAMINATED FILM MANUFACTURING METHOD, AND IMAGE DISPLAY DEVICE
 本発明は、積層フィルム、マーク付き積層フィルムの製造方法、及び、画像表示装置の製造方法に関する。 The present invention relates to a laminated film, a method for producing a marked laminated film, and a method for producing an image display device.
 従来より、偏光板、及び、偏光板の一方の面に仮保護フィルムが設けられた積層フィルムが知られている。液晶パネル等の画像表示パネルに、この積層フィルムを貼り合わせる際には、積層フィルムの偏光板の光軸(透過軸又は吸収軸)を、画像表示パネルに対して正確に位置合わせする必要がある。 Conventionally, a polarizing film and a laminated film in which a temporary protective film is provided on one surface of the polarizing plate are known. When the laminated film is bonded to an image display panel such as a liquid crystal panel, it is necessary to accurately align the optical axis (transmission axis or absorption axis) of the polarizing plate of the laminated film with respect to the image display panel. .
 そして、この位置合わせに資するために、偏光板の端部にマークを付したり、保護フィルムの端部にマークを付したりすることが知られている。 In order to contribute to this alignment, it is known to mark the end of the polarizing plate or mark the end of the protective film.
WO2007/108244号公報WO2007 / 108244 publication 特開2005-266284号公報JP 2005-266284 A
 しかしながら、従来の方法では、画像表示パネルと偏光板との位置合わせの精度が十分でなかった。 However, in the conventional method, the alignment accuracy between the image display panel and the polarizing plate is not sufficient.
 本発明は上記課題に鑑みてなされたものであり、画像表示パネルと偏光板との位置合わせの精度をより向上させることができる、積層フィルム、マーク付き積層フィルムの製造方法、及び、画像表示装置の製造方法を提供することを目的とする。 The present invention has been made in view of the above problems, and can further improve the alignment accuracy between the image display panel and the polarizing plate, a laminated film, a method for producing a marked laminated film, and an image display device. It aims at providing the manufacturing method of.
 本発明に係る積層フィルムは、偏光板、及び、前記偏光板の一方の面に設けられた仮保護フィルムを備える。前記積層フィルムは、前記積層フィルムの端面から一定幅の周辺領域と、前記周辺領域より内側の中央領域と、を備える。前記周辺領域の面積をSP、前記中央領域の面積をSCとしたときに、SC/(SP+SC)≦0.7を満たすように前記一定幅が定められる。前記中央領域はマークを有する。 The laminated film according to the present invention includes a polarizing plate and a temporary protective film provided on one surface of the polarizing plate. The laminated film includes a peripheral region having a constant width from an end surface of the laminated film, and a central region inside the peripheral region. When the area of the peripheral region is SP and the area of the central region is SC, the constant width is determined so as to satisfy SC / (SP + SC) ≦ 0.7. The central region has a mark.
 本発明によれば、マークが中央領域に設けられているため、偏光板を画像表示パネルに貼りつける際に偏光板の周辺領域がカールしても、カールの影響を受けることなくマークを基準に高精度に偏光板と画像表示パネルとの位置合わせが可能となる。 According to the present invention, since the mark is provided in the central region, even if the peripheral region of the polarizing plate is curled when the polarizing plate is attached to the image display panel, the mark is not affected by the curl. The polarizing plate and the image display panel can be aligned with high accuracy.
 ここで、前記マークは、前記積層フィルムを貫通する貫通孔であることができる。 Here, the mark may be a through-hole penetrating the laminated film.
 また、前記マークは、前記仮保護フィルムの表面に設けられた凹み、前記仮保護フィルムに設けられた貫通孔、前記仮保護フィルムに設けられた染色部、及び、前記仮保護フィルムの表面に設けられた着色層からなる群から選択される少なくとも1つであることができる。 The mark is provided on the surface of the temporary protective film, a dent provided on the surface of the temporary protective film, a through hole provided in the temporary protective film, a dyed portion provided on the temporary protective film, and a surface of the temporary protective film. And at least one selected from the group consisting of colored layers.
 また、前記マークの形状は、線状、十字、矢印、楕円、多角形からなる群から選択される少なくとも1つであることができる。 Also, the shape of the mark may be at least one selected from the group consisting of a line, a cross, an arrow, an ellipse, and a polygon.
 また、前記積層フィルムの外形形状は、円形、又は、正多角形であることができる。 Also, the outer shape of the laminated film can be a circle or a regular polygon.
 本発明に係るマーク付き積層フィルムの製造方法は、偏光板、及び、前記偏光板の一方の面に設けられた仮保護フィルムを備える積層フィルムにマークを設ける工程を有する。
 前記積層フィルムは、前記積層フィルムの端面から一定幅の周辺領域と、前記周辺領域より内側の中央領域と、を備える。前記周辺領域の面積をSP、前記中央領域の面積をSCとしたときに、SC/(SP+SC)≦0.7を満たすように前記一定幅が定められ、 前記マークを設ける工程では前記マークを前記中央領域内に設ける。
The manufacturing method of the laminated film with a mark concerning this invention has the process of providing a mark in a laminated film provided with the polarizing plate and the temporary protective film provided in the one surface of the said polarizing plate.
The laminated film includes a peripheral region having a constant width from an end surface of the laminated film, and a central region inside the peripheral region. When the area of the peripheral region is SP and the area of the central region is SC, the constant width is determined so as to satisfy SC / (SP + SC) ≦ 0.7. In the step of providing the mark, the mark is Provided in the central area.
 本発明に係る画像表示装置の製造方法は、前記マークを参照して画像表示パネルに対して上記の積層フィルムの光軸を位置合わせする工程と、
 位置合わせされた前記積層フィルムを前記画像表示パネルに貼り合わせる工程と、を備える。
The method of manufacturing an image display device according to the present invention includes the step of aligning the optical axis of the laminated film with respect to the image display panel with reference to the mark,
Bonding the aligned laminated film to the image display panel.
 本発明によれば、画像表示パネルと偏光板との位置合わせの精度をより向上させることができる、積層フィルム、及び、画像表示装置の製造方法が提供される。 According to the present invention, there are provided a laminated film and a method for manufacturing an image display device, which can further improve the accuracy of alignment between the image display panel and the polarizing plate.
図1の(a)は一実施形態に係る積層フィルムの断面図であり、図1の(b)は(a)の上面図である。1A is a cross-sectional view of a laminated film according to an embodiment, and FIG. 1B is a top view of FIG. 図2の(a)及び(b)は、別の実施形態に係る積層フィルムの断面図である。2A and 2B are cross-sectional views of a laminated film according to another embodiment. 図3の(a)~(e)は、それぞれ積層フィルムのマークの形状の他の一例を表す上面図である。3A to 3E are top views showing other examples of the mark shape of the laminated film. 図4の(a)~(e)は、それぞれ他の実施形態に係る積層フィルムの上面図である。FIGS. 4A to 4E are top views of laminated films according to other embodiments, respectively. 図5の(a)は画像表示装置の上面図、図5の(b)は画像表示装置の概略断面図である。FIG. 5A is a top view of the image display device, and FIG. 5B is a schematic cross-sectional view of the image display device. 図6は比較例及び実施例に係る積層フィルムの概略上面図である。FIG. 6 is a schematic top view of a laminated film according to a comparative example and an example.
 以下、本発明の好適な実施形態について、図面を参照しながら詳細に説明する。なお、各図において同一部分又は相当部分には同一符号を付し、重複する説明は省略する。また、各図面の寸法比率は必ずしも実際のものとは一致せず、特に、厚さに関しては誇張して描いてある。 Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the drawings. In addition, in each figure, the same code | symbol is attached | subjected to the same part or an equivalent part, and the overlapping description is abbreviate | omitted. The dimensional ratios in the drawings do not necessarily match the actual ones, and in particular, the thickness is exaggerated.
<積層フィルム> <Laminated film>
 図1(a)に示されているとおり、本実施形態にかかる積層フィルム100は、偏光板10、偏光板10の一方の面に粘着剤層7により貼り合わされた仮保護フィルム8、及び、偏光板10の他方の面に粘着剤層7により貼り合わされたセパレートフィルム9を有する。 As shown in FIG. 1A, a laminated film 100 according to this embodiment includes a polarizing plate 10, a temporary protective film 8 bonded to one surface of the polarizing plate 10 with an adhesive layer 7, and a polarizing plate. It has a separate film 9 bonded to the other surface of the plate 10 with an adhesive layer 7.
 (偏光板)
 偏光板10は、偏光子2、及び、偏光子2の両面に接着剤層5により貼り合わされた保護フィルム3を有する。
(Polarizer)
The polarizing plate 10 includes a polarizer 2 and a protective film 3 bonded to both surfaces of the polarizer 2 with an adhesive layer 5.
 (偏光子)
 偏光子2の材料としては、従来から偏光板の製造に使用されている公知の材料を用いることができ、例えば、ポリビニルアルコール系樹脂、ポリ酢酸ビニル樹脂、エチレン/酢酸ビニル(EVA)樹脂、ポリアミド樹脂、ポリエステル系樹脂等が挙げられる。なかでもポリビニルアルコール系樹脂が好ましい。通常、偏光子2の製造の開始材料としては、例えば厚さが5~100μm、好ましくは10~80μmのポリビニルアルコール系樹脂フィルムの未延伸フィルムを用いる。偏光子2は、この未延伸フィルムを、染色処理、ホウ酸処理、延伸処理等して得られる。
(Polarizer)
As the material of the polarizer 2, a known material that has been conventionally used in the production of polarizing plates can be used. For example, polyvinyl alcohol resin, polyvinyl acetate resin, ethylene / vinyl acetate (EVA) resin, polyamide Examples thereof include resins and polyester resins. Of these, polyvinyl alcohol resins are preferred. Usually, as a starting material for manufacturing the polarizer 2, for example, an unstretched film of a polyvinyl alcohol-based resin film having a thickness of 5 to 100 μm, preferably 10 to 80 μm, is used. The polarizer 2 is obtained by subjecting this unstretched film to a dyeing process, a boric acid process, a stretching process, and the like.
 偏光子2の厚さは、3~20μmであることが好ましく、5~18μmであることがより好ましく、7~16μmであることが更に好ましい。 The thickness of the polarizer 2 is preferably 3 to 20 μm, more preferably 5 to 18 μm, still more preferably 7 to 16 μm.
 (保護フィルム)
 保護フィルム3は、偏光子2の主面や端部の割れや傷つきを防止するフィルムである。
(Protective film)
The protective film 3 is a film that prevents the main surface and end of the polarizer 2 from cracking and scratching.
 保護フィルム3は、偏光板の分野で知られている各種の透明樹脂フィルムで構成することが好ましい。例えば、トリアセチルセルロースを代表例とするセルロース系樹脂、ポリプロピレン系樹脂を代表例とするポリオレフィン系樹脂、ノルボルネン系樹脂を代表例とする環状オレフィン系樹脂、ポリメチルメタクリレート系樹脂を代表例とするアクリル系樹脂、ポリエチレンテレフタレート系樹脂を代表例とするポリエステル系樹脂等が挙げられる。なかでも、セルロース系樹脂が代表的である。 The protective film 3 is preferably composed of various transparent resin films known in the field of polarizing plates. For example, cellulose resin whose typical example is triacetyl cellulose, polyolefin resin whose typical example is polypropylene resin, cyclic olefin resin whose typical example is norbornene resin, acrylic whose typical example is polymethyl methacrylate resin Examples thereof include polyester resins and polyester resins having polyethylene terephthalate resins as representative examples. Among these, cellulose resin is representative.
 ここで、保護フィルムが「透明」であるとは、JIS K 7361に準拠して測定される全光線透過率が70%以上であることをいう。 Here, that the protective film is “transparent” means that the total light transmittance measured in accordance with JIS K 7361 is 70% or more.
 保護フィルム3,3は、互いに同種の材料からなっていてもよいし、別種の材料からなっていてもよい。 The protective films 3 and 3 may be made of the same kind of material as each other, or may be made of another kind of material.
 保護フィルム3としては、光学機能を有しないフィルムであってもよいし、位相差フィルムや輝度向上フィルムといった光学機能を併せもつフィルムであってもよい。 The protective film 3 may be a film having no optical function, or may be a film having an optical function such as a retardation film or a brightness enhancement film.
 保護フィルム3の厚さは、5~30μmであることが好ましく、7~27μmであることがより好ましく、9~25μmであることが更に好ましい。 The thickness of the protective film 3 is preferably 5 to 30 μm, more preferably 7 to 27 μm, and still more preferably 9 to 25 μm.
 (接着剤層)
 接着剤層5の接着剤としては、従来から偏光板の製造に使用されている各種の接着剤を使用することができる。例えば、耐候性や屈折率、カチオン重合性等の観点から、分子内に芳香環を含まないエポキシ樹脂が好ましい。また、活性エネルギー線(紫外線又は熱線)の照射によって硬化するものが好ましい。
(Adhesive layer)
As the adhesive of the adhesive layer 5, various adhesives conventionally used for manufacturing a polarizing plate can be used. For example, an epoxy resin that does not contain an aromatic ring in the molecule is preferable from the viewpoint of weather resistance, refractive index, cationic polymerizability, and the like. Moreover, what hardens | cures by irradiation of an active energy ray (an ultraviolet ray or a heat ray) is preferable.
 エポキシ樹脂としては、例えば水素化エポキシ樹脂、脂環式エポキシ樹脂、脂肪族エポキシ樹脂等が好ましい。エポキシ樹脂に対して、重合開始剤(例えば紫外線照射で重合させるための光カチオン重合開始剤、熱線照射によって重合させるための熱カチオン重合開始剤)や、更に他の添加剤(増感剤等)を添加して、塗布用のエポキシ樹脂組成物を調製して使用することができる。 As the epoxy resin, for example, a hydrogenated epoxy resin, an alicyclic epoxy resin, an aliphatic epoxy resin and the like are preferable. For epoxy resins, polymerization initiators (for example, photocationic polymerization initiators for polymerization by ultraviolet irradiation, thermal cationic polymerization initiators for polymerization by heat ray irradiation), and other additives (sensitizers, etc.) Can be added to prepare an epoxy resin composition for coating.
 また、接着剤としては、アクリルアミド、アクリレート、ウレタンアクリレート、エポキシアクリレート等のアクリル系樹脂や、ポリビニルアルコール系の水系接着剤を使用することもできる。 Also, as the adhesive, acrylic resins such as acrylamide, acrylate, urethane acrylate, and epoxy acrylate, and polyvinyl alcohol-based aqueous adhesives can be used.
 偏光板10の厚さは、20~100μmであることが好ましく、25~90μmであることがより好ましく、30~80μmであることが更に好ましい。 The thickness of the polarizing plate 10 is preferably 20 to 100 μm, more preferably 25 to 90 μm, and still more preferably 30 to 80 μm.
 偏光板10は、保護フィルム3上に積層される他の光学層を更に含むことができる。他の光学層としては、ある種の偏光を透過し、それと逆の性質を示す偏光を反射する反射型偏光フィルム;表面に凹凸形状を有する防眩機能付フィルム;表面反射防止機能付フィルム;表面に反射機能を有する反射フィルム;反射機能と透過機能とを併せ持つ半透過反射フィルム;視野角補償フィルム等が挙げられる。 The polarizing plate 10 can further include another optical layer laminated on the protective film 3. As another optical layer, a reflective polarizing film that transmits a certain kind of polarized light and reflects polarized light having the opposite properties; a film with an antiglare function having an uneven surface; a film with a surface antireflection function; surface A reflective film having a reflective function; a transflective film having both a reflective function and a transmissive function; and a viewing angle compensation film.
 (仮保護フィルム)
 仮保護フィルム8は、粘着剤層7と共に後工程で偏光板10から剥離することが可能なフィルムであり、画像表示素子への貼付時などにおいて積層フィルム100をハンドリングする際に、保護フィルム3の表面を損傷、摩損等から保護するためのフィルムである。
仮保護フィルム8は、保護フィルム3に積層された後、偏光板10の使用前まで保護フィルム3に貼合されたままとされることができる。偏光板10の使用前に、仮保護フィルム8を保護フィルム3から剥離する際には、粘着剤層7は仮保護フィルム8側に付着した状態で偏光板10側から仮保護フィルム8と共に剥離される。
(Temporary protective film)
The temporary protective film 8 is a film that can be peeled off from the polarizing plate 10 together with the pressure-sensitive adhesive layer 7. When the laminated film 100 is handled at the time of application to an image display element, the temporary protective film 8 It is a film for protecting the surface from damage, abrasion and the like.
After the temporary protective film 8 is laminated on the protective film 3, it can remain bonded to the protective film 3 until the polarizing plate 10 is used. When the temporary protective film 8 is peeled from the protective film 3 before the polarizing plate 10 is used, the pressure-sensitive adhesive layer 7 is peeled from the polarizing plate 10 side together with the temporary protective film 8 in a state of being attached to the temporary protective film 8 side. The
 仮保護フィルム8の材料としては、ポリエチレンテレフタレート、ポリエチレンナフタレート、ポリエチレンイソフタレート、ポリブチレンテレフタレート等のポリエステル系樹脂が好ましく、保護フィルム3と同様のものを用いてもよい。必要な強度を有しかつ光学適性を有するものであれば、他のプラスチックスフィルム、たとえば、ポリオレフィン系フィルム、ポリアセテートフィルム、ポリカーボネートフィルム、ポリフェニレンサルファイドフィルム、ポリアミドフィルム、ポリ塩化ビニルフィルム、エチレン-酢酸ビニル共重合体フィルム、各種液晶ポリマーフィルム等が使用可能である。 The material of the temporary protective film 8 is preferably a polyester resin such as polyethylene terephthalate, polyethylene naphthalate, polyethylene isophthalate, or polybutylene terephthalate, and the same material as the protective film 3 may be used. Any other plastic film having the required strength and optical suitability, for example, polyolefin film, polyacetate film, polycarbonate film, polyphenylene sulfide film, polyamide film, polyvinyl chloride film, ethylene-acetic acid A vinyl copolymer film, various liquid crystal polymer films, etc. can be used.
 仮保護フィルム8の厚さは、5~70μmであることが好ましく、10~60μmであることがより好ましく、15~50μmであることが更に好ましい。 The thickness of the temporary protective film 8 is preferably 5 to 70 μm, more preferably 10 to 60 μm, and still more preferably 15 to 50 μm.
 (粘着剤層)
 粘着剤層7は、アクリル系樹脂や、シリコーン系樹脂、ポリエステル、ポリウレタン、ポリエーテル等で構成することができる。
(Adhesive layer)
The pressure-sensitive adhesive layer 7 can be composed of acrylic resin, silicone resin, polyester, polyurethane, polyether, or the like.
 粘着剤層7の厚さは、2~40μmであることが好ましく、4~25μmであることがより好ましい。 The thickness of the pressure-sensitive adhesive layer 7 is preferably 2 to 40 μm, and more preferably 4 to 25 μm.
 粘着剤層7を設ける方法としては、例えば、仮保護フィルム8上にアクリル系の一液型または二液型の粘着剤、ゴム系粘着剤、シリコーン系粘着剤をはじめとする種々の粘着剤等で粘着剤層7を形成した後に保護フィルム3に積層する方法がある。通常は、仮保護フィルムに粘着剤層を設け、粘着剤層にさらに剥離フィルムを設けた仮保護フィルム積層体を一旦ロール状に巻き取ったものを準備し、保護フィルム3と貼合する直前に仮保護フィルム積層体から当該剥離フィルムを剥がして、保護フィルム3に貼り合わせる。
 また、偏光板10の保護フィルム3に上記樹脂や任意の添加成分を含む溶液を塗布して粘着剤層7を設け、その後に、仮保護フィルム8を貼合せてもよい。
Examples of the method of providing the pressure-sensitive adhesive layer 7 include various pressure-sensitive adhesives such as an acrylic one-component or two-component adhesive, a rubber-based adhesive, and a silicone-based adhesive on the temporary protective film 8. There is a method in which the pressure-sensitive adhesive layer 7 is formed and then laminated on the protective film 3. Usually, a temporary protective film is provided with a pressure-sensitive adhesive layer, and a temporary protective film laminate in which a pressure-sensitive adhesive layer is further provided with a release film is once wound up into a roll, and immediately before bonding with the protective film 3. The release film is peeled off from the temporary protective film laminate and bonded to the protective film 3.
Alternatively, the adhesive film 7 may be provided by applying a solution containing the above-described resin or any additive component to the protective film 3 of the polarizing plate 10, and then the temporary protective film 8 may be bonded.
 (セパレートフィルム)
 セパレートフィルム9は、粘着剤層7の保護や異物の付着防止等を目的として貼着される剥離可能なフィルムであって、積層フィルム100の使用時に剥がされて粘着剤層7が露出される。セパレートフィルム9は、例えばポリエチレンのようなポリエチレン系樹脂、ポリプロピレンのようなポリプロピレン系樹脂、ポリエチレンテレフタレートのようなポリエステル系樹脂等で構成することができる。中でも、ポリエチレンテレフタレートの延伸フィルムが好ましい。
(Separate film)
The separate film 9 is a peelable film that is stuck for the purpose of protecting the pressure-sensitive adhesive layer 7 or preventing adhesion of foreign matters, and is peeled off when the laminated film 100 is used to expose the pressure-sensitive adhesive layer 7. The separate film 9 can be made of, for example, a polyethylene resin such as polyethylene, a polypropylene resin such as polypropylene, a polyester resin such as polyethylene terephthalate, or the like. Among these, a stretched film of polyethylene terephthalate is preferable.
 セパレートフィルム9が積層されている粘着剤層7は、偏光板10を他の物品(例えば液晶セルやタッチパネル)に貼着させるときに機能する層である。粘着剤層7の材料としては、仮保護フィルム8を積層する場合のものと同様の材料を用いることができる。 The pressure-sensitive adhesive layer 7 on which the separate film 9 is laminated is a layer that functions when the polarizing plate 10 is attached to another article (for example, a liquid crystal cell or a touch panel). As the material for the pressure-sensitive adhesive layer 7, the same material as that used when the temporary protective film 8 is laminated can be used.
 セパレートフィルム9は、積層フィルム100の使用時に容易に剥がすことができるように、粘着剤層7に接する面にシリコーン樹脂等による離型処理を施してもよい。セパレートフィルム9を剥がすと、粘着剤層7は偏光板10側に残る。 The separation film 9 may be subjected to a release treatment with a silicone resin or the like on the surface in contact with the pressure-sensitive adhesive layer 7 so that it can be easily peeled off when the laminated film 100 is used. When the separate film 9 is peeled off, the pressure-sensitive adhesive layer 7 remains on the polarizing plate 10 side.
 セパレートフィルム9の厚さは、5~70μmであることが好ましく、10~60μmであることがより好ましく、15~50μmであることが更に好ましい。 The thickness of the separate film 9 is preferably 5 to 70 μm, more preferably 10 to 60 μm, and still more preferably 15 to 50 μm.
 図1の(a)に示すように、積層フィルム100の外形形状は、積層方向から見て、円形である。このような形状は、幅広のフィルムから、レーザーや刃により切り出すことにより容易に得られる。 As shown in FIG. 1A, the outer shape of the laminated film 100 is circular when viewed from the lamination direction. Such a shape can be easily obtained by cutting out a wide film with a laser or a blade.
 (マーク)
 積層フィルム100は、積層フィルム100の厚み方向から見て、積層フィルム100の端面から一定幅の周辺領域100Pと、周辺領域100Pより内側の中央領域100Cと、を備える。ここで、周辺領域100Pの面積をSP、中央領域100Cの面積をSCとしたときに、SC/(SP+SC)≦0.7を満たすように一定幅が定められる。ここで、SC/(SP+SC)≦0.6が好ましく、SC/(SP+SC)≦0.5がより好ましく、SC/(SP+SC)≦0.4がさらに好ましく、SC/(SP+SC)≦0.3が特に好ましい。
(mark)
When viewed from the thickness direction of the laminated film 100, the laminated film 100 includes a peripheral region 100P having a constant width from the end surface of the laminated film 100, and a central region 100C inside the peripheral region 100P. Here, when the area of the peripheral region 100P is SP and the area of the central region 100C is SC, the constant width is determined so as to satisfy SC / (SP + SC) ≦ 0.7. Here, SC / (SP + SC) ≦ 0.6 is preferable, SC / (SP + SC) ≦ 0.5 is more preferable, SC / (SP + SC) ≦ 0.4 is further preferable, and SC / (SP + SC) ≦ 0.3. Is particularly preferred.
 本実施形態では、この中央領域100C内に、マークMを有する。具体的には、マークMは、仮保護フィルム8の表面に設けられた着色層20である。着色層20は、たとえば、インクジェットプリンタ等の印刷装置により形成できる。着色層は、樹脂及び顔料や染料等の着色成分を含有することができる。 In this embodiment, the center region 100C has a mark M. Specifically, the mark M is a colored layer 20 provided on the surface of the temporary protective film 8. The colored layer 20 can be formed by a printing apparatus such as an ink jet printer. The colored layer can contain colored components such as resins and pigments and dyes.
 マークMは、着色層20に限定されない。マークMの他の態様を、図2の(a)及び(b)に示す。図2の(a)では、マークMは、仮保護フィルム8に設けられた凹み21である。このような凹み21は、レーザーや刃等により容易に形成できる。図2の(a)では凹み21の深さは粘着剤層7が露出しない深さであるが、粘着剤層7が露出するすなわち貫通孔でもよく、図2の(a)に点線で示すように、仮保護フィルム8及び粘着剤層7を貫通して保護フィルム3が露出するように、仮保護フィルム8及び粘着剤層7を貫通する貫通孔でもよい。また、図2の(b)では、マークMは、積層フィルム100全体を貫通する貫通孔22である。マークMは、これ以外にも、たとえば、仮保護フィルム8に設けられた染色部でもよい。 The mark M is not limited to the colored layer 20. Other aspects of the mark M are shown in FIGS. In FIG. 2A, the mark M is a recess 21 provided in the temporary protective film 8. Such a recess 21 can be easily formed by a laser, a blade or the like. In FIG. 2A, the depth of the recess 21 is a depth at which the pressure-sensitive adhesive layer 7 is not exposed. However, the pressure-sensitive adhesive layer 7 may be exposed, that is, a through-hole, as indicated by a dotted line in FIG. Furthermore, a through-hole penetrating the temporary protective film 8 and the pressure-sensitive adhesive layer 7 may be used so that the protective film 3 is exposed through the temporary protective film 8 and the pressure-sensitive adhesive layer 7. In FIG. 2B, the mark M is a through hole 22 that penetrates the entire laminated film 100. In addition to this, the mark M may be, for example, a dyed portion provided on the temporary protective film 8.
 マークMの形状は、図1の(a)では、一方の線の長さが他方の線の長さよりも長い十字である。マークMの形状は、十字に限定されない。たとえば、図3の(a)に示す線状であってもよいし、図3の(b)に示すように矢印形状でもよいし、図3の(c)に示すように楕円でもよいし、図3の(d)に示すように三角形(正三角形を除くことが好ましい)でもよいし、図3の(e)に示すように菱形(正方形を除くことが好ましい)でもよい。これ以外の多角形(正多角形を除くことが好ましい)でもよい。なお、各多角形は正多角形でないことが好適であるが、正多角形である場合にはそれを複数設ければよい。 The shape of the mark M is a cross in which the length of one line is longer than the length of the other line in FIG. The shape of the mark M is not limited to a cross. For example, the line shape shown in FIG. 3A may be used, the arrow shape may be used as shown in FIG. 3B, the ellipse may be used as shown in FIG. As shown in (d) of FIG. 3, it may be a triangle (excluding a regular triangle) or a rhombus (excluding a square) as shown in (e) of FIG. Other polygons (excluding regular polygons) may be used. Each polygon is preferably not a regular polygon, but if it is a regular polygon, a plurality of polygons may be provided.
 マークMの長軸(もっとも長い方向の軸)の長さは、たとえば0.1~10mmとすることができる。マークMの短軸(もっとも短い方向の軸)の長さは、たとえば0.1~7mmとすることができる。 The length of the long axis (longest axis) of the mark M can be set to 0.1 to 10 mm, for example. The length of the short axis (the axis in the shortest direction) of the mark M can be set to 0.1 to 7 mm, for example.
 マークMは、偏光板10の偏光子2の光吸収軸又は光透過軸(光軸)の方向を表す。たとえば、マークMの長軸の方向を、光吸収軸又は光透過軸(たとえば、図1の(b)及び図4の(a)~(e)の上下方向)に平行とするなど、マークMの長軸の方向が、偏光子の光軸と一定の角度の関係となるようにマークMを設けることにより、マークMの向き(長軸の向き等)に基づいて偏光子の光軸の位置を容易に判断できる。さらに、マークMを、たとえばマークMの重心が積層フィルム100の重心位置と重なるように設けることなど、マークMの位置を積層フィルムに対して一定の位置に設けることにより、マークMの位置を検出することにより、積層フィルム(偏光板10)の面内方向における位置を検出することができる。 The mark M represents the direction of the light absorption axis or light transmission axis (optical axis) of the polarizer 2 of the polarizing plate 10. For example, the direction of the major axis of the mark M is parallel to the light absorption axis or light transmission axis (for example, the vertical direction in FIGS. 1B and 4A to 4E), etc. The position of the optical axis of the polarizer is based on the direction of the mark M (the direction of the long axis, etc.) by providing the mark M so that the direction of the major axis is at a constant angle with the optical axis of the polarizer. Can be easily determined. Further, the position of the mark M is detected by providing the mark M at a fixed position with respect to the laminated film, for example, by providing the mark M so that the center of gravity of the mark M overlaps the center of gravity of the laminated film 100. By doing so, the position in the in-plane direction of the laminated film (polarizing plate 10) can be detected.
 積層フィルム100のマークMのさらに他の一例を説明する。図4の(a)に示す積層フィルム100は、中央部分に断面円形の貫通孔hが設けられており、マークMは、貫通孔hの両側の縁に2箇所設けられており、図3の(a)の線の両端のみが配置された形態である。 Still another example of the mark M of the laminated film 100 will be described. The laminated film 100 shown in FIG. 4A is provided with a through hole h having a circular cross section at the center, and the mark M is provided at two edges on both sides of the through hole h. In this form, only both ends of the line (a) are arranged.
 次に、積層フィルム100の外形形状の他の例を説明する。積層フィルム100の外形形状は、正方形(図4の(b)参照)、正六角形(図4の(c)参照)、及び、正八角形(図4の(d)参照)のような正多角形でもよいし、樽型(図4の(e)参照)のような形状でもよい。たとえば、正多角形や円形であると、外形形状から光軸の向きを判明できないので特に本発明の効果が高い。 Next, another example of the outer shape of the laminated film 100 will be described. The outer shape of the laminated film 100 is a regular polygon such as a square (see (b) in FIG. 4), a regular hexagon (see (c) in FIG. 4), and a regular octagon (see (d) in FIG. 4). However, it may be a barrel shape (see FIG. 4E). For example, if it is a regular polygon or a circle, the direction of the optical axis cannot be determined from the outer shape, so the effect of the present invention is particularly high.
 いずれの態様にしても、マークMは、中央領域100C内に設けられている。マークMの少なくとも一部が中央領域100C内に設けられていれば良いが、マークMのすべてが中央領域100C内に存在することが好適である。 In any aspect, the mark M is provided in the central region 100C. It is sufficient that at least a part of the mark M is provided in the central region 100C, but it is preferable that all of the marks M exist in the central region 100C.
 ここで、積層フィルム100から、セパレートフィルム9を剥離した後の積層フィルムを積層フィルム90と呼ぶ。 Here, the laminated film after peeling the separate film 9 from the laminated film 100 is referred to as a laminated film 90.
<画像表示装置の製造方法>
 続いて、図5の(a)及び(b)を参照して、上述の積層フィルム100を用いた画像表示装置の製造方法について説明する。
<Method for Manufacturing Image Display Device>
Then, with reference to (a) and (b) of FIG. 5, the manufacturing method of the image display apparatus using the above-mentioned laminated film 100 is demonstrated.
 まず、画像表示パネル50を用意する。偏光板の貼付を必要とする画像表示パネルの例は、液晶パネルであるが、有機ELパネルなどでもよい。 First, the image display panel 50 is prepared. An example of an image display panel that requires the attachment of a polarizing plate is a liquid crystal panel, but may be an organic EL panel or the like.
 次に、画像表示パネル50の表面に、上述の積層フィルム100からセパレートフィルム9を剥離した残りの積層フィルム90を貼りつける。この時、偏光板10の光軸を、所定の方向にし、かつ、画像表示パネル50の表面の所定の位置に、積層フィルム90を貼りつける必要がある。 Next, the remaining laminated film 90 obtained by peeling the separate film 9 from the laminated film 100 is pasted on the surface of the image display panel 50. At this time, it is necessary to attach the laminated film 90 at a predetermined position on the surface of the image display panel 50 with the optical axis of the polarizing plate 10 in a predetermined direction.
 本実施形態では、画像表示パネル50の表面に、好適な光軸の向きを示す一対のマークLCM1が設けられ、画像表示パネル50の裏面に、好適な光軸の向きを示す一対のマークLCM2が設けられている。 In the present embodiment, a pair of marks LCM1 indicating a preferable direction of the optical axis is provided on the surface of the image display panel 50, and a pair of marks LCM2 indicating a preferable direction of the optical axis is provided on the back surface of the image display panel 50. Is provided.
 本実施形態では、まず、積層フィルム100からセパレートフィルム9を剥離して積層フィルム90を形成する。次に、マークMの形状に基づいて、その積層フィルム90の回転方向の向きを、所定の方向に合わせる。具体的には、たとえば、マークMの長軸方向と、画像表示パネルの一対のマークLCM1同士を結ぶ方向とが平行となるように、積層フィルム90を回転させればよい。さらに、マークMの位置に基づいて、積層フィルム90の面内方向の位置を、画像表示パネル50に対して所定の位置に合わせる。具体的には、たとえば、マークMの位置が、一対のマークLCM1の中間に来るように、積層フィルム90を移動すればよい。このようにして、積層フィルム90の回転位置、及び、面内位置を、画像表示パネル50に対して合わせた後に、この積層フィルム90を、粘着剤層7を介して画像表示パネル50の表面に貼りつける。 In this embodiment, first, the separate film 9 is peeled from the laminated film 100 to form a laminated film 90. Next, based on the shape of the mark M, the rotation direction of the laminated film 90 is adjusted to a predetermined direction. Specifically, for example, the laminated film 90 may be rotated so that the major axis direction of the mark M and the direction connecting the pair of marks LCM1 of the image display panel are parallel to each other. Further, based on the position of the mark M, the position in the in-plane direction of the laminated film 90 is adjusted to a predetermined position with respect to the image display panel 50. Specifically, for example, the laminated film 90 may be moved so that the position of the mark M is between the pair of marks LCM1. Thus, after aligning the rotation position and in-plane position of the laminated film 90 with respect to the image display panel 50, the laminated film 90 is placed on the surface of the image display panel 50 via the adhesive layer 7. Paste.
 このような位置合わせ工程を含む貼りつけ工程は、マークを撮影するカメラと、撮影画像に基づいてマークの形状や位置を認識する画像処理装置と、処理結果に基づいて必要回転量や必要移動量を算出する移動制御装置と、積層フィルム90を移動させるロボットハンドと、を含む位置合わせ装置により実現できる。画像処理及び移動制御は、コンピュータによる処理であることができる。 The pasting process including the positioning process includes a camera for photographing the mark, an image processing device for recognizing the shape and position of the mark based on the photographed image, and a necessary rotation amount and necessary movement amount based on the processing result. It can be realized by a positioning device including a movement control device that calculates the value and a robot hand that moves the laminated film 90. Image processing and movement control can be computer processing.
 続いて、別の積層フィルム100からセパレートフィルム9を剥離して別の積層フィルム90を形成し、その積層フィルム90のマークMと、画像表示パネル50の裏面側の一対のマークLCM2とに基づいて、同様にして、積層フィルム90を画像表示パネル50の裏面に貼りつける。 Subsequently, the separate film 9 is peeled from another laminated film 100 to form another laminated film 90, and based on the mark M of the laminated film 90 and the pair of marks LCM2 on the back side of the image display panel 50. Similarly, the laminated film 90 is attached to the back surface of the image display panel 50.
 これにより、画像表示パネル50に貼りつけられた一対の積層フィルム90、90の光軸及び位置は、所望の位置に合わせられる。たとえば、一対の積層フィルムの偏光子の光軸を互いに直交するように配置できる。 Thereby, the optical axes and positions of the pair of laminated films 90 and 90 attached to the image display panel 50 are adjusted to a desired position. For example, it can arrange | position so that the optical axis of the polarizer of a pair of laminated film may mutually orthogonally cross.
<作用>
 偏光子を含む積層フィルム100(90)は、周辺領域がカールしやすい。したがって、積層フィルム100(90)の周辺領域にマークMが設けられていると、カールの影響により、マークMの位置にずれが生じて画像表示パネルとの位置合わせ精度が低下する場合がある。
<Action>
In the laminated film 100 (90) including the polarizer, the peripheral region is easily curled. Therefore, if the mark M is provided in the peripheral area of the laminated film 100 (90), the position of the mark M is displaced due to the curl, and the alignment accuracy with the image display panel may be lowered.
 しかしながら、本実施形態によれば、積層フィルム100(90)の中央領域100CにマークMが設けられている。したがって、カメラや目視等でマークMを参照する際に、マークMの位置の認識のずれを少なくすることができる。したがって、積層フィルム90の回転位置や、面内方向における位置を、画像表示パネル50に対して高精度に合わせすることができる。 However, according to the present embodiment, the mark M is provided in the central region 100C of the laminated film 100 (90). Therefore, when referring to the mark M with a camera, visual observation, or the like, it is possible to reduce a deviation in recognition of the position of the mark M. Therefore, the rotational position of the laminated film 90 and the position in the in-plane direction can be adjusted with respect to the image display panel 50 with high accuracy.
 周辺領域がカールしやすい積層フィルム100の層構成の例は、積層フィルムの厚さが薄く(特に200μm以下)剛性が低い場合、保護フィルム3,3がそれぞれ別種の材料(例えば、一方がトリアセチルセルロースなどのセルロース系樹脂、他方が環状オレフィン系樹脂)である場合、いずれか一方の保護フィルム3を有さない場合、及び、積層フィルム100を構成するいずれかの層の透湿度が高い(例えば、250g/m・24h以上)場合である。また、積層フィルム100の外形形状が鋭角の角部を有する場合などにも、周辺領域がカールしやすい。この様な層構成及び/又は外形形状を有する積層フィルム100は、周辺領域にカールが生じやすいため、特に本発明の効果が高い。 As an example of the layer structure of the laminated film 100 in which the peripheral region is easily curled, when the thickness of the laminated film is thin (particularly 200 μm or less) and the rigidity is low, the protective films 3 and 3 are made of different materials (for example, one is triacetyl). When the cellulose-based resin such as cellulose and the other is a cyclic olefin-based resin), when any one of the protective films 3 is not provided, and the moisture permeability of any layer constituting the laminated film 100 is high (for example, 250 g / m 2 · 24 h or more). Also, the peripheral region is easily curled when the outer shape of the laminated film 100 has acute corners. Since the laminated film 100 having such a layer configuration and / or outer shape is easily curled in the peripheral region, the effect of the present invention is particularly high.
 以上、本発明の好適な実施形態について説明したが、本発明は上記実施形態に何ら限定されるものではない。例えば、上記実施形態では、偏光板10の仮保護フィルム8とは反対側に、粘着剤層7及びセパレートフィルム9が設けられているが、これらが無くても実施可能である。たとえば、画像表示パネルへの貼付時に、画像表示パネル側に粘着剤を設け、積層フィルム100の保護フィルムを直接当該粘着剤に貼りつける場合などもある。 The preferred embodiment of the present invention has been described above, but the present invention is not limited to the above embodiment. For example, in the said embodiment, although the adhesive layer 7 and the separate film 9 are provided in the opposite side to the temporary protective film 8 of the polarizing plate 10, it can implement even without these. For example, an adhesive may be provided on the image display panel side when being attached to the image display panel, and the protective film of the laminated film 100 may be directly attached to the adhesive.
 また、仮保護フィルム8と保護フィルム3との間に粘着剤層7を有さないことも可能である。 It is also possible not to have the adhesive layer 7 between the temporary protective film 8 and the protective film 3.
 (比較例1~3、実施例1、2)
 図6に示すように、120mm×70mmの矩形の積層フィルム100を用意した。積層フィルム100は総厚みが270μmであり以下のような構成を有していた。
(Comparative Examples 1 to 3, Examples 1 and 2)
As shown in FIG. 6, a rectangular laminated film 100 of 120 mm × 70 mm was prepared. The laminated film 100 had a total thickness of 270 μm and the following configuration.
 仮保護フィルム8(ポリエチレンテレフタレート)/粘着剤層7(アクリル系樹脂)/保護フィルム3(トリアセチルセルロース)/接着剤層5(エポキシ樹脂)/偏光子2(ヨウ素染色延伸PVA)/接着剤層5(エポキシ樹脂)/保護フィルム3(トリアセチルセルロース)/粘着剤層7(アクリル系樹脂)/セパレートフィルム9(ポリエチレンテレフタレート) Temporary protective film 8 (polyethylene terephthalate) / adhesive layer 7 (acrylic resin) / protective film 3 (triacetyl cellulose) / adhesive layer 5 (epoxy resin) / polarizer 2 (iodine dyed stretched PVA) / adhesive layer 5 (epoxy resin) / protective film 3 (triacetyl cellulose) / adhesive layer 7 (acrylic resin) / separate film 9 (polyethylene terephthalate)
 この積層フィルム100は、平面上に載置した時に、カールにより端部が平面から浮き上がり、最も浮き上がったところでは、平面から6mm程度(長辺に対して5%程度)浮き上がっていた。 When this laminated film 100 was placed on a flat surface, the end portion was lifted from the flat surface by curling, and the most lifted portion was about 6 mm from the flat surface (about 5% with respect to the long side).
 積層フィルム100は、仮保護フィルム8の表面に十字のマークM(縦棒の長さ0.5mm及び横棒の長さ0.5mm、縦棒及び横棒の幅0.05mm)を備える。マークMは、黒インキにより形成された樹脂層である。 The laminated film 100 is provided with a cross mark M (vertical bar length 0.5 mm, horizontal bar length 0.5 mm, vertical bar and horizontal bar width 0.05 mm) on the surface of the temporary protective film 8. The mark M is a resin layer formed with black ink.
 十字のマークMの縦棒が積層フィルム100の短辺と平行に、横棒が積層フィルム100の長辺と平行になるようにマークMを配置した。 The mark M was arranged so that the vertical bar of the cross mark M was parallel to the short side of the laminated film 100 and the horizontal bar was parallel to the long side of the laminated film 100.
 比較例1では、SC/(SP+SC)=0.95となるように中央領域100C及び周辺領域100Pを設定し、十字のマークMの一部が中央領域100C内に存在するようにマークMの位置を定めた。具体的には、中央領域100Cと周辺領域100Pとの境界線Bが、十字のマークMの縦棒及び横棒の中心をそれぞれ通るように配置した。周辺領域100Pの幅aは1mmであった。 In Comparative Example 1, the central region 100C and the peripheral region 100P are set so that SC / (SP + SC) = 0.95, and the position of the mark M is such that a part of the cross mark M exists in the central region 100C. Determined. Specifically, the boundary line B between the central region 100C and the peripheral region 100P is arranged so as to pass through the center of the vertical bar and horizontal bar of the cross mark M, respectively. The width a of the peripheral region 100P was 1 mm.
 比較例2、3、実施例1、2では、それぞれ、SC/(SP+SC)を、0.86、0.78、0.70、0.63とする以外は、比較例1と同様とした。周辺領域100Pの幅aは、それぞれ、3mm、5mm、7mm、9mmであった。 Comparative Examples 2 and 3 and Examples 1 and 2 were the same as Comparative Example 1 except that SC / (SP + SC) was 0.86, 0.78, 0.70, and 0.63, respectively. The width a of the peripheral region 100P was 3 mm, 5 mm, 7 mm, and 9 mm, respectively.
 平板上に載置した各比較例及び実施例の積層フィルムを、上方からカメラで撮影し、十字のマークMの形状を正しく認識できるか否かを確認した。結果を表1に示す。











The laminated films of the comparative examples and examples placed on the flat plate were photographed with a camera from above, and it was confirmed whether or not the shape of the cross mark M could be correctly recognized. The results are shown in Table 1.











Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 十字のマークMがひずみ無く認識できた場合を○、十字のマークMがややひずんで認識された場合には△を、十字のマークが大きくひずんで認識された場合を×で示す。
 SC/(SP+SC)が0.7以下となる中央領域100Cにマークがあると、マークが高い精度で認識できることが確認された。
A case where the cross mark M can be recognized without distortion is indicated by ◯, a case where the cross mark M is recognized slightly distorted, and a case where the cross mark M is recognized largely distorted by x.
It was confirmed that the mark can be recognized with high accuracy when there is a mark in the central region 100C where SC / (SP + SC) is 0.7 or less.
 10…偏光板、20…着色層、21…凹み、22…貫通孔、90、100…積層フィルム、8…仮保護フィルム、100P…周辺領域、100C…中央領域、M…マーク。 DESCRIPTION OF SYMBOLS 10 ... Polarizing plate, 20 ... Colored layer, 21 ... Depression, 22 ... Through-hole, 90, 100 ... Laminated film, 8 ... Temporary protective film, 100P ... Peripheral area | region, 100C ... Center area | region, M ... Mark.

Claims (7)

  1.  偏光板、及び、前記偏光板の一方の面に設けられた仮保護フィルムを備える積層フィルムであって、
     前記積層フィルムは、前記積層フィルムの端面から一定幅の周辺領域と、前記周辺領域より内側の中央領域と、を備え、
     前記周辺領域の面積をSP、前記中央領域の面積をSCとしたときに、SC/(SP+SC)≦0.7を満たすように前記一定幅が定められ、
     前記中央領域はマークを有する、積層フィルム。
    A laminated film comprising a polarizing plate and a temporary protective film provided on one surface of the polarizing plate,
    The laminated film comprises a peripheral region having a constant width from an end surface of the laminated film, and a central region inside the peripheral region,
    When the area of the peripheral region is SP and the area of the central region is SC, the constant width is determined so as to satisfy SC / (SP + SC) ≦ 0.7,
    The said center area | region has a mark, Laminated film.
  2.  前記マークは、前記積層フィルムを貫通する貫通孔である、請求項1記載の積層フィルム。 The laminated film according to claim 1, wherein the mark is a through-hole penetrating the laminated film.
  3.  前記マークは、前記仮保護フィルムの表面に設けられた凹み、前記仮保護フィルムに設けられた貫通孔、前記仮保護フィルム内に設けられた染色部、及び、前記仮保護フィルムの表面に設けられた着色層からなる群から選択される少なくとも1つである、請求項1記載の積層フィルム。 The mark is provided on the surface of the temporary protective film, a recess provided on the surface of the temporary protective film, a through hole provided in the temporary protective film, a dyed portion provided in the temporary protective film, and the surface of the temporary protective film. The laminated film according to claim 1, which is at least one selected from the group consisting of a colored layer.
  4.  前記マークの形状は、線状、十字、矢印、楕円、多角形からなる群から選択される少なくとも1つである、請求項1~3のいずれか1項に記載の積層フィルム。 The laminated film according to any one of claims 1 to 3, wherein a shape of the mark is at least one selected from the group consisting of a line, a cross, an arrow, an ellipse, and a polygon.
  5.  前記積層フィルムの外形形状は、円形、又は、正多角形である、請求項1~4のいずれか1項記載の積層フィルム。 The laminated film according to any one of claims 1 to 4, wherein an outer shape of the laminated film is a circle or a regular polygon.
  6.  偏光板、及び、前記偏光板の一方の面に設けられた仮保護フィルムを備える積層フィルムにマークを設ける工程を有し、
     前記積層フィルムは、前記積層フィルムの端面から一定幅の周辺領域と、前記周辺領域より内側の中央領域と、を備え、
     前記周辺領域の面積をSP、前記中央領域の面積をSCとしたときに、SC/(SP+SC)≦0.7を満たすように前記一定幅が定められ、
     前記マークを設ける工程では前記マークを前記中央領域内に設ける、マーク付き積層フィルムの製造方法。
    A step of providing a mark on a laminated film including a polarizing plate and a temporary protective film provided on one surface of the polarizing plate;
    The laminated film comprises a peripheral region having a constant width from an end surface of the laminated film, and a central region inside the peripheral region,
    When the area of the peripheral region is SP and the area of the central region is SC, the constant width is determined so as to satisfy SC / (SP + SC) ≦ 0.7,
    In the step of providing the mark, the mark is provided in the central region.
  7.  前記マークを参照して画像表示パネルに対して請求項1~5のいずれか1項に記載の積層フィルムの光軸を位置合わせする工程と、
     位置合わせされた前記積層フィルムを前記画像表示パネルに貼り合わせる工程と、を備える、画像表示装置の製造方法。
    The step of aligning the optical axis of the laminated film according to any one of claims 1 to 5 with respect to the image display panel with reference to the mark;
    Bonding the laminated film aligned to the image display panel. A method for manufacturing an image display device.
PCT/JP2017/020187 2016-06-06 2017-05-31 Layered film, method for manufacturing layered film provided with mark, and method for manufacturing image display device WO2017212989A1 (en)

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JP2003014934A (en) * 2001-07-04 2003-01-15 Nitto Denko Corp Polarizing plate with protective film, and marking system for polarizing plate with protective film
JP2004337714A (en) * 2003-05-14 2004-12-02 Denki Kagaku Kogyo Kk Marking method
JP2008197159A (en) * 2007-02-08 2008-08-28 Nitto Denko Corp Optical film body and manufacturing method of the optical film body
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Publication number Priority date Publication date Assignee Title
JP2001125092A (en) * 1999-10-26 2001-05-11 Matsushita Electric Ind Co Ltd Liquid crystal display device and method of producing the same
JP2003014934A (en) * 2001-07-04 2003-01-15 Nitto Denko Corp Polarizing plate with protective film, and marking system for polarizing plate with protective film
JP2004337714A (en) * 2003-05-14 2004-12-02 Denki Kagaku Kogyo Kk Marking method
JP2008197159A (en) * 2007-02-08 2008-08-28 Nitto Denko Corp Optical film body and manufacturing method of the optical film body
JP2014211568A (en) * 2013-04-19 2014-11-13 三菱電機株式会社 Optical film member for liquid display device, liquid display device, and manufacturing method of liquid display device

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