WO2017201854A1 - 导电性涂胶 - Google Patents

导电性涂胶 Download PDF

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Publication number
WO2017201854A1
WO2017201854A1 PCT/CN2016/091015 CN2016091015W WO2017201854A1 WO 2017201854 A1 WO2017201854 A1 WO 2017201854A1 CN 2016091015 W CN2016091015 W CN 2016091015W WO 2017201854 A1 WO2017201854 A1 WO 2017201854A1
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WO
WIPO (PCT)
Prior art keywords
parts
conductive coating
coating adhesive
butanediol
methoxyphenol
Prior art date
Application number
PCT/CN2016/091015
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English (en)
French (fr)
Inventor
黄金生
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黄金生
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Publication date
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Publication of WO2017201854A1 publication Critical patent/WO2017201854A1/zh

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/02Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonates or saturated polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04Acids; Metal salts or ammonium salts thereof
    • C08F220/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52Amides or imides
    • C08F220/54Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56Acrylamide; Methacrylamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • C14C11/003Surface finishing of leather using macromolecular compounds

Definitions

  • the invention relates to the technical field of chemical products, in particular to conductive coating.
  • Gluing has a very large role in production and life. It is widely used in various fields.
  • the coating film formed by gluing can play a role in decoration, protection and labeling.
  • Most of the coatings on the market are simple to make and sell. It is cheap but has certain toxic and side effects. As a household, it will cause certain harm to the human body.
  • the glue application function is relatively simple, and the scope of application is not wide. It cannot be used in many fields, and its limitations are very large.
  • the conductive coating 40 to 60 parts of methacrylic acid, 12 to 24 parts of benzoyl peroxide, 10 to 20 parts of dibutyl phthalate, and 8 to 16 parts of polyester, 20 to 30 parts of glycol acrylate, 4 to 6 parts of trimethylolpropane, 10 to 20 parts of butanediol, 10 to 20 parts of methoxyphenol, 8 to 12 parts of acrylamide, and 10 to 20 parts of styrene. 18 to 24 parts of ethanol and 12 to 18 parts of xylene.
  • the conductive coating provided by the invention has the advantages of simple preparation, non-toxicity of the raw materials used, good use effect and environmental protection, and the surface coating of the leather can form a strong bright coating film.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

一种导电性涂胶,甲基丙烯酸40~60份,过氧化苯甲酰12~24份,邻苯二甲酸二丁酯10~20份,聚酯8~16份,丁二醇丙烯酸酯20~30份,三羟甲基丙烷4~6份,丁二醇10~20份,甲氧基苯酚10~20份,丙烯酰胺8~12份,苯乙烯10~20份,乙醇18~24份,二甲苯12~18份。该导电性涂胶,制作简单,采用的生产原料选择无毒性的,涂胶的使用效果好,环保,作用于皮革表面涂饰可形成坚固的光亮涂膜。

Description

导电性涂胶 技术领域
本发明涉及一种化学用品的技术领域,具体涉及导电性涂胶。
背景技术
涂胶在生产和生活中的作用非常大,广泛应用与各个领域,涂胶形成的涂膜可对物体起到装饰、保护和标致作用,目前市面上的大部分涂胶虽然制作简单、售价便宜但同时带有一定的毒副作用,作为家用的话会对人体产生一定危害,且涂胶功能比较单一,适用范围不广,不能用于很多领域,局限性很大。
发明内容
本发明的目的提供导电性涂胶,解决上述现有技术问题中的一个或者多个。
根据本发明的一个方面,导电性涂胶,甲基丙烯酸40~60份,过氧化苯甲酰12~24份,邻苯二甲酸二丁酯10~20份,聚酯8~16份,丁二醇丙烯酸酯20~30份,三羟甲基丙烷4~6份,丁二醇10~20份,甲氧基苯酚10~20份,丙烯酰胺8~12份,苯乙烯10~20份,乙醇18~24份,二甲苯12~18份。
本发明提供的导电性涂胶,制作简单,采用的生产原料选择无毒性的,的使用效果好,环保,作用于皮革表面涂饰可形成坚固的光亮涂膜。
具体实施方式
实施例1
将甲基丙烯酸40份,过氧化苯甲酰12份,邻苯二甲酸二丁酯10份,聚酯8份,丁二醇丙烯酸酯20份,三羟甲基丙烷4份,丁二醇10份,甲氧基苯酚10份,丙烯酰胺8份,苯乙烯10份,乙醇18份,二甲苯12~18份 放入反应器中,不断搅拌,混合完全后加热至65℃,以16m/min的速度在200W/cm的紫外灯下通过反应两次后,即得产品。
实施例2
将甲基丙烯酸40~60份,过氧化苯甲酰18份,邻苯二甲酸二丁酯15份,聚酯12份,丁二醇丙烯酸酯25份,三羟甲基丙烷5份,丁二醇15份,甲氧基苯酚15份,丙烯酰胺10份,苯乙烯15份,乙醇21份,二甲苯15份放入反应器中,不断搅拌,混合完全后加热至65℃,以16m/min的速度在200W/cm的紫外灯下通过反应两次后,即得产品。
实施例3
将甲基丙烯酸60份,过氧化苯甲酰24份,邻苯二甲酸二丁酯20份,聚酯16份,丁二醇丙烯酸酯30份,三羟甲基丙烷6份,丁二醇20份,甲氧基苯酚20份,丙烯酰胺12份,苯乙烯20份,乙醇24份,二甲苯18份放入反应器中,不断搅拌,混合完全后加热至65℃,以16m/min的速度在200W/cm的紫外灯下通过反应两次后,即得产品。
以上所述仅是本发明的优选方式,应当指出,对于本领域普通技术人员来说,在不脱离本发明创造构思的前提下,还可以做出若干相似的变形和改进,这些也应视为本发明的保护范围之内。

Claims (1)

  1. 导电性涂胶,其特征在于:包括如下重量份的组分,甲基丙烯酸40~60份,过氧化苯甲酰12~24份,邻苯二甲酸二丁酯10~20份,聚酯8~16份,丁二醇丙烯酸酯20~30份,三羟甲基丙烷4~6份,丁二醇10~20份,甲氧基苯酚10~20份,丙烯酰胺8~12份,苯乙烯10~20份,乙醇18~24份,二甲苯12~18份。
PCT/CN2016/091015 2016-05-21 2016-07-22 导电性涂胶 WO2017201854A1 (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610343665.1A CN105969030A (zh) 2016-05-21 2016-05-21 导电性涂胶
CN201610343665.1 2016-05-21

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7579048B2 (en) * 2003-03-15 2009-08-25 Basf Coatings Method for improving the adhesion of the intermediate layer in a multi-paint finish
CN102993857A (zh) * 2012-10-30 2013-03-27 苏州市德莱尔建材科技有限公司 一种水下快速固化涂料
CN104194511A (zh) * 2014-09-19 2014-12-10 苏州洛特兰新材料科技有限公司 一种聚苯乙烯多彩涂料
CN104513511A (zh) * 2014-12-23 2015-04-15 姜云华 一种光学光敏涂料
CN104530794A (zh) * 2014-12-23 2015-04-22 姜云华 非膨胀型乳胶防火涂料
CN104559379A (zh) * 2014-12-23 2015-04-29 姜云华 一种导电发热涂料
CN104559369A (zh) * 2014-12-23 2015-04-29 姜云华 一种防霉涂料及其制备方法
CN104559378A (zh) * 2014-12-23 2015-04-29 姜云华 皮革用水性涂料
CN105086847A (zh) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 一种绿色环保无毒害胶水
CN105086849A (zh) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 一种抗静电环保胶水

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011096464A1 (ja) * 2010-02-04 2011-08-11 株式会社ブリヂストン 導電性エンドレスベルト
CN103753939B (zh) * 2014-01-17 2015-11-11 苏州斯贝孚光电科技有限公司 淋涂纳米金属油墨制备薄膜的方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7579048B2 (en) * 2003-03-15 2009-08-25 Basf Coatings Method for improving the adhesion of the intermediate layer in a multi-paint finish
CN102993857A (zh) * 2012-10-30 2013-03-27 苏州市德莱尔建材科技有限公司 一种水下快速固化涂料
CN104194511A (zh) * 2014-09-19 2014-12-10 苏州洛特兰新材料科技有限公司 一种聚苯乙烯多彩涂料
CN104513511A (zh) * 2014-12-23 2015-04-15 姜云华 一种光学光敏涂料
CN104530794A (zh) * 2014-12-23 2015-04-22 姜云华 非膨胀型乳胶防火涂料
CN104559379A (zh) * 2014-12-23 2015-04-29 姜云华 一种导电发热涂料
CN104559369A (zh) * 2014-12-23 2015-04-29 姜云华 一种防霉涂料及其制备方法
CN104559378A (zh) * 2014-12-23 2015-04-29 姜云华 皮革用水性涂料
CN105086847A (zh) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 一种绿色环保无毒害胶水
CN105086849A (zh) * 2015-09-22 2015-11-25 启东寅昶精密铸造有限公司 一种抗静电环保胶水

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