WO2017196552A1 - Niobium and chromium low alloy carbon steel for high wear resistant automotive chain link plates - Google Patents

Niobium and chromium low alloy carbon steel for high wear resistant automotive chain link plates Download PDF

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Publication number
WO2017196552A1
WO2017196552A1 PCT/US2017/030000 US2017030000W WO2017196552A1 WO 2017196552 A1 WO2017196552 A1 WO 2017196552A1 US 2017030000 W US2017030000 W US 2017030000W WO 2017196552 A1 WO2017196552 A1 WO 2017196552A1
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WO
WIPO (PCT)
Prior art keywords
approximately
composition
weight percentage
niobium
chain
Prior art date
Application number
PCT/US2017/030000
Other languages
French (fr)
Inventor
Yumin Wang
Matthew E. Junker
Original Assignee
Borgwarner Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borgwarner Inc. filed Critical Borgwarner Inc.
Priority to US16/099,364 priority Critical patent/US20190211415A1/en
Priority to EP17796564.7A priority patent/EP3455383A4/en
Priority to JP2018555243A priority patent/JP2019521242A/en
Priority to CN201780024555.1A priority patent/CN109072388A/en
Publication of WO2017196552A1 publication Critical patent/WO2017196552A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0087—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for chains, for chain links
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • C21D1/20—Isothermal quenching, e.g. bainitic hardening
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • C21D1/22—Martempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16G—BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G13/00—Chains
    • F16G13/02—Driving-chains
    • F16G13/04—Toothed chains
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16G—BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G13/00—Chains
    • F16G13/02—Driving-chains
    • F16G13/06—Driving-chains with links connected by parallel driving-pins with or without rollers so called open links
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16G—BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G13/00—Chains
    • F16G13/02—Driving-chains
    • F16G13/08—Driving-chains with links closely interposed on the joint pins
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16G—BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G15/00—Chain couplings, Shackles; Chain joints; Chain links; Chain bushes
    • F16G15/12—Chain links
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/002—Heat treatment of ferrous alloys containing Cr
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/005—Heat treatment of ferrous alloys containing Mn
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/008—Heat treatment of ferrous alloys containing Si

Definitions

  • the invention pertains to the field of steel compositions. More particularly, the invention pertains to steel compositions for automotive chain link plates.
  • An optimum steel composition for automotive chain link plates has improved wear resistance.
  • the composition is preferably low alloy carbon steel with niobium and chromium.
  • a steel composition includes, by weight percentage, approximately 0.25-0.75% carbon, approximately 0.20-2.0%) chromium, approximately 0.26- 1.5% niobium, and the remainder of the composition is iron and any impurities.
  • This composition may also optionally include one or more of the following: approximately 0.2 to 1.0% manganese, approximately 0.05 to 0.60% silicon, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, or up to approximately 0.03% sulfur.
  • a steel composition includes, by weight percentage, approximately 0.25 to 0.75% carbon, approximately 0.2 to 1.0% manganese,
  • compositions described herein are preferably used for automotive chain link plates.
  • the chain links are preferably heat treated to a hardness in the range of HRc 50 to 60, either by oil quenching and tempering or salt bath austempring and/or martempering preferably by salt bath austempering and/or martempering.
  • Fig. 1 shows an example of a chain link/chain link plate that could be made using the compositions described herein.
  • Fig. 2 shows an example of a silent chain including chain links that could be made using the compositions described herein.
  • Fig. 3 A shows a top view of an example of a roller chain that could be made using the compositions described herein.
  • Fig. 3B shows a side view of the roller chain of Fig. 3 A.
  • Fig. 3C shows a section of the roller chain along line 3C-3C of Fig. 3A.
  • Fig. 4A shows a top view of an example of a bushing chain that could be made using the compositions described herein.
  • Fig. 4B shows a side view of the bushing chain of Fig. 4 A.
  • Fig. 4C shows a section of the bushing chain along line 4C-4C of Fig. 4A.
  • An optimum steel composition for automotive chain link plates has improved wear resistance.
  • the composition is preferably Nb Cr low alloy carbon steel.
  • the chain link plates made with the compositions are preferably used in silent chains, roller chains or bushing chains.
  • the steel composition includes niobium, chromium, carbon, iron, and any impurities.
  • One preferred composition including these components includes, by weight percentage, approximately 0.25%-0.75% carbon, approximately 0.20%-2.0% chromium, approximately 0.26%- 1.5% niobium, and the remaining component of the composition is iron.
  • the amount of iron in the composition is the remainder of the weight percentage of the composition not made of other components in the composition. Trace amounts of impurities may also be present.
  • the composition may also include one or more of the following additional components (by weight percentage): approximately 0.2%-2.0% manganese, approximately 0.05%-0.60% silicon, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, and up to approximately 0.03% sulfur.
  • the amount of iron in the composition is the remainder of the weight percentage of the composition not made of other components in the composition.
  • the chain link plates made using this steel composition are preferably heat treated to a hardness in the range of HRc 50 to 60.
  • heat treatment occurs either by oil quenching and tempering or salt bath austempring and/or martempering preferably by salt bath austempering and/or martempering.
  • the hardness is in the range of HRc 52 to 58.
  • the composition includes the following percentages (wt %) of materials:
  • the percentages of aluminum, phosphorus, and sulfur are preferably maximum amounts of each of these materials.
  • Phosphorus and sulfur are impurities in steel and are preferred to be zero or as close to zero as possible.
  • Aluminum is also an impurity, and should be kept as low as possible except in special applications.
  • the remainder of the steel composition is composed of iron and any other impurities.
  • Steel compositions always have impurities and inclusions including, but not limited to, Sulfides (MnS), Alumina, and Silicate.
  • Sulfides MnS
  • ASTM E45 This standard or other industry standards are used to control the amount of the impurities to an acceptable level.
  • the amount of iron in the composition is the remainder of the weight percentage of the composition not made of other components in the composition.
  • the chain link plates of this steel composition are heat treated to a hardness of HRc 50-60.
  • heat treatment uses either oil quenching and tempering or salt bath austempering and/or martempering by salt bath.
  • the hardness is in the range of HRc 52 to 58.
  • the steel composition for the chain links described herein fill the gap to further improve the wear resistance of the chains.
  • the composition includes carbon, niobium, chromium, and iron.
  • the steel of the composition preferably has a range of carbon from 0.25% to 0.75 wt %, which makes the steel hardenable after heat treatment. In some preferred embodiments, the carbon weight percentage ranges from 0.5-0.6%).
  • the composition also preferably includes a range of chromium from 0.2%-2.0 wt %>, which improves the hardenability of the steel and makes the steel suitable for either oil quenching and tempering or austempering and martempering as hardening options.
  • the chromium weight percentage ranges from 0.4%>-0.6%>.
  • the composition also preferably includes a weight percentage of niobium in the range of 0.26%> to 1.5 wt %>.
  • the niobium content, by weight percentage is between approximately 0.26%> and 0.8%>.
  • the niobium weight percentage in the composition is between 0.5% and 1.5%.
  • the niobium content is between 0.5% and 0.8%.
  • the niobium content in the steel composition not only inhibits the grain growth of the steel and results in a fine grained high strength steel, the niobium also forms nanoscale Niobium Carbide particles after heat treatment. Increased Niobium content results in more Niobium Carbide precipitation, with proper heat treatment. These particles are particularly prevalent if an austempering or martempering process is used for heat treatment, because of the limited solubility of niobium in steel (1.5% max in austerilized iron) and the reduced solubility with reductions of temperature during heat treatment.
  • the composition may also include one or more of the following additional components (by weight percentage): approximately 0.2%-2.0% manganese, approximately 0.05%-0.60% silicon, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, and up to approximately 0.03% sulfur.
  • the amount of iron in the composition is the remainder of the weight percentage of the composition not made of other components in the composition.
  • the composition includes the following percentages (wt %) of materials:
  • the carbon weight percentage ranges from 0.5%- 0.6%), the chromium weight percentage ranges from 0.4%-0.6%, and/or the niobium content, by weight percentage, ranges from 0.26% and 0.8%.
  • the niobium content, by weight percentage is greater than 0.5%.
  • the niobium content, by weight percentage is between 0.5% and 0.8%.
  • the amount of iron in the composition is the remainder of the weight percentage of the composition not made of other components in the composition.
  • Fig. 1 shows an example of a chain link plate 1 that can be made using the compositions described herein.
  • Fig. 2 shows an example of a silent chain 10 including chain links 1 made using the compositions described herein.
  • the chain includes guide or outside links A and inside links B, as well as pins 2. Any component of the silent chain 10 may be made of the compositions described herein.
  • Figs. 3A-3C show an example of a roller chain 20 with bushings 35 that can be made using the compositions described herein.
  • the roller chain 20 includes guide links 30, bushing links 31, rollers 32, pins, 33, 34 and bushings 35. Any component of the roller chain 20 may be made of the compositions described herein.
  • Figs. 4A-4C show an example of a bushing chain 25 with bushings 45 that can be made using the compositions described herein.
  • the bushing chain 25 includes guide links 40, bushing links 41, pins 43, and bushings 45. Any component of the bushing chain 25 may be made of the compositions described herein.
  • compositions described herein are used to make silent chain inside links B, which articulate with the pins 2 and have issues with wear. While it is not necessary to also use the steel compositions described herein for the guide links A, the compositions may also be used for the guide links A.
  • compositions described herein are used to make bushings 35, 45 in a roller chain 20 or a bushing chain 25.
  • the compositions may also or alternatively be used to make the links 30, 31, 40, 41, the rollers 32, and/or other components of these types of chains.
  • the chain link plates made using the steel compositions described herein are preferably heat treated to a hardness in the range of HRc 50 to 60.
  • the composition is heat treated either by oil quenching and tempering or salt bath austempring and/or martempering preferably by salt bath austempering and/or
  • the hardness of the chain link plates is in the range of HRc 52 to 58.
  • chain link plates made with the composition described herein are used in combination with advanced pin technologies including, but not limited to, VC pins or SSN pins.
  • the composition does not include tungsten (W). In some embodiments, the composition does not include any molybdenum (Mo). In some embodiments, the composition does not include titanium (Ti), Nickel (Ni), and/or boron (B).
  • the chain link plate compositions described herein create a more wear resistant chain. Due to the improved wear resistance of the steel compositions described herein, it is unnecessary to coat the chain link plates made with the compositions. This eliminates both the cost and time associated with expensive coating processes.

Abstract

Niobium chromium low allow carbon steel for automotive chain link plates has improved wear resistance. In one preferred embodiment, the steel composition includes niobium, chromium, carbon, iron, and any impurities. One preferred composition including these components includes, by weight percentage, approximately 0.25% to 0.75% carbon, approximately 0.20% to 2.0% chromium, approximately 0.26% to 1.5% niobium, and the remaining component of the composition is iron. Trace amounts of impurities may also be present. In another embodiment, a steel composition includes, by weight percentage, approximately 0.25% to 0.75% carbon, approximately 0.2% to 1.0% manganese, approximately 0.05% to 0.60% silicon, approximately 0.26% to 1.5% niobium, approximately 0.20% to 2.0% chromium, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, up to approximately 0.03% sulfur, and a remainder of the composition being iron and any other impurities.

Description

NIOBIUM AND CHROMIUM LOW ALLOY CARBON STEEL FOR HIGH WEAR RESISTANT AUTOMOTIVE CHAIN LINK PLATES
BACKGROUND OF THE INVENTION
FIELD OF THE INVENTION
The invention pertains to the field of steel compositions. More particularly, the invention pertains to steel compositions for automotive chain link plates.
DESCRIPTION OF RELATED ART
A lot of effort has been put into developing wear resistant chains. One desire is to reduce wear and frictional losses for the next generation of engine timing chains to be used in gasoline direct injection (DI) engines and diesel engines. Current production chains in these types of engines have high wear or chain elongations and friction losses, which result in poor engine fuel efficiency and high emission, or even engine failure due to the malfunction of elongated chains which can cause tooth jump that leads to vehicle safety concerns. The prior art has mainly seen chain pin developments such as vanadium carbide (VC) pins or VC coated pins and stainless steel nitrided (SSN) pin technologies. There is a need in the art for more resistant timing chains for gasoline direct injection and diesel engines.
SUMMARY OF THE INVENTION
An optimum steel composition for automotive chain link plates has improved wear resistance. The composition is preferably low alloy carbon steel with niobium and chromium.
In one embodiment, a steel composition includes, by weight percentage, approximately 0.25-0.75% carbon, approximately 0.20-2.0%) chromium, approximately 0.26- 1.5% niobium, and the remainder of the composition is iron and any impurities. This composition may also optionally include one or more of the following: approximately 0.2 to 1.0% manganese, approximately 0.05 to 0.60% silicon, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, or up to approximately 0.03% sulfur.
In another embodiment, a steel composition includes, by weight percentage, approximately 0.25 to 0.75% carbon, approximately 0.2 to 1.0% manganese,
approximately 0.05 to 0.60% silicon, approximately 0.26-1.5%) niobium, approximately 0.20 to 2.0%) chromium, up to approximately 0.30%> aluminum, up to approximately 0.03%) phosphorus, up to approximately 0.03%> sulfur, and a remainder of the composition being iron and any other impurities.
The compositions described herein are preferably used for automotive chain link plates. The chain links are preferably heat treated to a hardness in the range of HRc 50 to 60, either by oil quenching and tempering or salt bath austempring and/or martempering preferably by salt bath austempering and/or martempering.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 shows an example of a chain link/chain link plate that could be made using the compositions described herein.
Fig. 2 shows an example of a silent chain including chain links that could be made using the compositions described herein.
Fig. 3 A shows a top view of an example of a roller chain that could be made using the compositions described herein.
Fig. 3B shows a side view of the roller chain of Fig. 3 A.
Fig. 3C shows a section of the roller chain along line 3C-3C of Fig. 3A.
Fig. 4A shows a top view of an example of a bushing chain that could be made using the compositions described herein.
Fig. 4B shows a side view of the bushing chain of Fig. 4 A.
Fig. 4C shows a section of the bushing chain along line 4C-4C of Fig. 4A. DETAILED DESCRIPTION OF THE INVENTION
An optimum steel composition for automotive chain link plates has improved wear resistance. The composition is preferably Nb Cr low alloy carbon steel. The chain link plates made with the compositions are preferably used in silent chains, roller chains or bushing chains.
In one preferred embodiment, the steel composition includes niobium, chromium, carbon, iron, and any impurities. One preferred composition including these components includes, by weight percentage, approximately 0.25%-0.75% carbon, approximately 0.20%-2.0% chromium, approximately 0.26%- 1.5% niobium, and the remaining component of the composition is iron. The amount of iron in the composition is the remainder of the weight percentage of the composition not made of other components in the composition. Trace amounts of impurities may also be present.
The composition may also include one or more of the following additional components (by weight percentage): approximately 0.2%-2.0% manganese, approximately 0.05%-0.60% silicon, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, and up to approximately 0.03% sulfur. The amount of iron in the composition is the remainder of the weight percentage of the composition not made of other components in the composition.
The chain link plates made using this steel composition are preferably heat treated to a hardness in the range of HRc 50 to 60. In some embodiments, heat treatment occurs either by oil quenching and tempering or salt bath austempring and/or martempering preferably by salt bath austempering and/or martempering. In some embodiments, the hardness is in the range of HRc 52 to 58.
In one preferred embodiment, the composition includes the following percentages (wt %) of materials:
C Mn Si Nb Cr Al P S
0.25- 0.2- 0.05- 0.26- 0.20- 0.30% 0.03% 0.03%
0.75% 1.0% 0.60% 1.5% 2.0% max max max The percentages of aluminum, phosphorus, and sulfur are preferably maximum amounts of each of these materials. Phosphorus and sulfur are impurities in steel and are preferred to be zero or as close to zero as possible. Aluminum is also an impurity, and should be kept as low as possible except in special applications. The remainder of the steel composition is composed of iron and any other impurities.
Steel compositions always have impurities and inclusions including, but not limited to, Sulfides (MnS), Alumina, and Silicate. There are industry standards to evaluate the inclusions. One of the most common is ASTM E45. This standard or other industry standards are used to control the amount of the impurities to an acceptable level. The amount of iron in the composition is the remainder of the weight percentage of the composition not made of other components in the composition. The chain link plates of this steel composition are heat treated to a hardness of HRc 50-60. In some preferred embodiments, heat treatment uses either oil quenching and tempering or salt bath austempering and/or martempering by salt bath. In some embodiments, the hardness is in the range of HRc 52 to 58.
The steel composition for the chain links described herein fill the gap to further improve the wear resistance of the chains. The composition includes carbon, niobium, chromium, and iron. The steel of the composition preferably has a range of carbon from 0.25% to 0.75 wt %, which makes the steel hardenable after heat treatment. In some preferred embodiments, the carbon weight percentage ranges from 0.5-0.6%).
The composition also preferably includes a range of chromium from 0.2%-2.0 wt %>, which improves the hardenability of the steel and makes the steel suitable for either oil quenching and tempering or austempering and martempering as hardening options. In some preferred embodiments, the chromium weight percentage ranges from 0.4%>-0.6%>. The composition also preferably includes a weight percentage of niobium in the range of 0.26%> to 1.5 wt %>. In some preferred embodiments, the niobium content, by weight percentage, is between approximately 0.26%> and 0.8%>. In other embodiments, the niobium weight percentage in the composition is between 0.5% and 1.5%. In other embodiments, the niobium content, by weight percentage, is between 0.5% and 0.8%. The niobium content in the steel composition not only inhibits the grain growth of the steel and results in a fine grained high strength steel, the niobium also forms nanoscale Niobium Carbide particles after heat treatment. Increased Niobium content results in more Niobium Carbide precipitation, with proper heat treatment. These particles are particularly prevalent if an austempering or martempering process is used for heat treatment, because of the limited solubility of niobium in steel (1.5% max in austerilized iron) and the reduced solubility with reductions of temperature during heat treatment. When the carbides distribute uniformly in the steel matrix in sub-micrometer and nanometer scale particles, the wear resistance of the steel increases greatly without negative impact on its fatigue properties, which are highly desired for the silent chain links. As a result, the wear resistance of the link plates are significantly improved.
The composition may also include one or more of the following additional components (by weight percentage): approximately 0.2%-2.0% manganese, approximately 0.05%-0.60% silicon, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, and up to approximately 0.03% sulfur. The amount of iron in the composition is the remainder of the weight percentage of the composition not made of other components in the composition.
In one preferred embodiment, the composition includes the following percentages (wt %) of materials:
Figure imgf000007_0001
In some of these embodiments, the carbon weight percentage ranges from 0.5%- 0.6%), the chromium weight percentage ranges from 0.4%-0.6%, and/or the niobium content, by weight percentage, ranges from 0.26% and 0.8%. In other embodiments, the niobium content, by weight percentage, is greater than 0.5%. In other embodiments, the niobium content, by weight percentage, is between 0.5% and 0.8%. The amount of iron in the composition is the remainder of the weight percentage of the composition not made of other components in the composition. Fig. 1 shows an example of a chain link plate 1 that can be made using the compositions described herein. Fig. 2 shows an example of a silent chain 10 including chain links 1 made using the compositions described herein. The chain includes guide or outside links A and inside links B, as well as pins 2. Any component of the silent chain 10 may be made of the compositions described herein.
Figs. 3A-3C show an example of a roller chain 20 with bushings 35 that can be made using the compositions described herein. The roller chain 20 includes guide links 30, bushing links 31, rollers 32, pins, 33, 34 and bushings 35. Any component of the roller chain 20 may be made of the compositions described herein.
Figs. 4A-4C show an example of a bushing chain 25 with bushings 45 that can be made using the compositions described herein. The bushing chain 25 includes guide links 40, bushing links 41, pins 43, and bushings 45. Any component of the bushing chain 25 may be made of the compositions described herein.
In preferred embodiments, the compositions described herein are used to make silent chain inside links B, which articulate with the pins 2 and have issues with wear. While it is not necessary to also use the steel compositions described herein for the guide links A, the compositions may also be used for the guide links A.
In other embodiments, the compositions described herein are used to make bushings 35, 45 in a roller chain 20 or a bushing chain 25. The compositions may also or alternatively be used to make the links 30, 31, 40, 41, the rollers 32, and/or other components of these types of chains.
The chain link plates made using the steel compositions described herein are preferably heat treated to a hardness in the range of HRc 50 to 60. In some embodiments, the composition is heat treated either by oil quenching and tempering or salt bath austempring and/or martempering preferably by salt bath austempering and/or
martempering. In some embodiments, the hardness of the chain link plates is in the range of HRc 52 to 58. In some embodiments, chain link plates made with the composition described herein are used in combination with advanced pin technologies including, but not limited to, VC pins or SSN pins.
In some embodiments, the composition does not include tungsten (W). In some embodiments, the composition does not include any molybdenum (Mo). In some embodiments, the composition does not include titanium (Ti), Nickel (Ni), and/or boron (B).
The chain link plate compositions described herein create a more wear resistant chain. Due to the improved wear resistance of the steel compositions described herein, it is unnecessary to coat the chain link plates made with the compositions. This eliminates both the cost and time associated with expensive coating processes.
Accordingly, it is to be understood that the embodiments of the invention herein described are merely illustrative of the application of the principles of the invention.
Reference herein to details of the illustrated embodiments is not intended to limit the scope of the claims, which themselves recite those features regarded as essential to the invention.

Claims

What is claimed is:
1. A steel composition comprising, by weight percentage, approximately 0.25% to 0.75% carbon, approximately 0.26% to 1.5% niobium, approximately 0.20% to 2.0%> chromium, iron and any impurities.
2. The composition of claim 1, wherein the weight percentage of carbon in the
composition ranges from approximately 0.5% to 0.6%.
3. The composition of claim 1, wherein the weight percentage of chromium in the composition ranges from approximately 0.4% to 0.6%.
4. The composition of claim 1, wherein the weight percentage of niobium in the
composition is greater than 0.5%.
5. The composition of claim 1, wherein the weight percentage of niobium in the
composition ranges from approximately 0.26% to 0.8%.
6. The composition of claim 1, wherein the composition further comprises, by weight percentage, approximately 0.2% to 1.0% manganese.
7. The composition of claim 1, wherein the composition further comprises, by weight percentage, approximately 0.05% to 0.60% silicon.
8. The composition of claim 1, wherein the composition further comprises at least one impurity, by weight percentage, selected from the group consisting of: a) up to approximately 0.3% aluminum; b) up to approximately 0.03% phosphorus; c) up to approximately 0.03% sulfur; and d) any combination of up to approximately 0.3% aluminum, up to
approximately 0.03% phosphorus and up to approximately 0.03% sulfur.
9. The composition of claim 1, further comprising approximately 0.2% to 1.0% manganese and approximately 0.05% to 0.60% silicon.
10. The composition of claim 1, wherein the composition is hardened using a method selected from the group consisting of oil quenching and tempering, salt bath austempering, and salt bath martempering.
11. A chain link comprising a steel composition comprising, by weight percentage, approximately 0.25% to 0.75% carbon, approximately 0.26% to 1.5% niobium, approximately 0.20% to 2.0% chromium, iron and any impurities.
12. The chain link of claim 11, wherein the chain link has a hardness of HRc 50 to 60.
13. The chain link of claim 12, wherein the chain link has a hardness of HRc 52 to 58.
14. The chain link of claim 11, wherein the weight percentage of carbon in the
composition ranges from approximately 0.5% to 0.6%.
15. The chain link of claim 11, wherein the weight percentage of chromium in the composition ranges from approximately 0.4% to 0.6%.
16. The chain link of claim 11, wherein the weight percentage of niobium in the
composition is greater than 0.5%.
17. The chain link of claim 11, wherein the weight percentage of niobium in the
composition ranges from approximately 0.26% to 0.8%.
18. The chain link of claim 11, wherein the composition further comprises, by weight percentage, approximately 0.2% to 1.0% manganese.
19. The chain link of claim 11, wherein the composition further comprises, by weight percentage, approximately 0.05% to 0.60% silicon.
20. The chain link of claim 11, wherein the composition further comprises at least one impurity, by weight percentage, selected from the group consisting of: a) up to approximately 0.3% aluminum; b) up to approximately 0.03% phosphorus; c) up to approximately 0.03% sulfur; and d) any combination of up to approximately 0.3% aluminum, up to
approximately 0.03% phosphorus and up to approximately 0.03% sulfur.
21. The chain link of claim 11, wherein the composition further comprises approximately
0.2%) to 1.0% manganese and approximately 0.05% to 0.60% silicon.
22. A chain that includes a plurality of links, each link comprising a steel composition comprising, by weight percentage, approximately 0.25% to 0.75% carbon, approximately 0.26% to 1.5% niobium, approximately 0.20% to 2.0% chromium, iron and any impurities.
23. The chain of claim 22, wherein the links have a hardness of HRc 50 to 60.
24. The chain of claim 23, wherein the links have a hardness of HRc 52 to 58.
25. The chain of claim 23, wherein the weight percentage of carbon in the composition ranges from approximately 0.5% to 0.6%.
26. The chain of claim 23, wherein the weight percentage of chromium in the composition ranges from approximately 0.4% to 0.6%.
27. The chain of claim 23, wherein the weight percentage of niobium in the composition is greater than 0.5%.
28. The chain of claim 23, wherein the weight percentage of niobium in the composition ranges from approximately 0.26% to 0.8%.
29. The chain of claim 23, wherein the composition further comprises, by weight
percentage, approximately 0.2% to 1.0% manganese.
30. The chain of claim 23, wherein the composition further comprises, by weight
percentage, approximately 0.05% to 0.60% silicon.
31. The chain of claim 23, wherein the composition further comprises at least one impurity, by weight percentage, selected from the group consisting of: a) up to approximately 0.3% aluminum; b) up to approximately 0.03% phosphorus; c) up to approximately 0.03% sulfur; and d) any combination of up to approximately 0.3% aluminum, up to
approximately 0.03% phosphorus and up to approximately 0.03% sulfur.
32. The chain of claim 23, further comprising approximately 0.2% to 1.0% manganese and approximately 0.05% to 0.60% silicon.
33. A composition comprising, by weight percentage, approximately 0.25% to 0.75%
carbon, approximately 0.2% to 1.0% manganese, approximately 0.05% to 0.60% silicon, approximately 0.26% to 1.5% niobium, approximately 0.20% to 2.0% chromium, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, up to approximately 0.03% sulfur, and a remainder of the composition being iron and any other impurities.
34. The composition of claim 33, wherein the weight percentage of carbon in the
composition ranges from approximately 0.5% to 0.6%.
35. The composition of claim 33, wherein the weight percentage of chromium in the composition ranges from approximately 0.4% to 0.6%.
36. The composition of claim 33, wherein the weight percentage of niobium in the
composition ranges from approximately 0.26% to 0.8%.
37. A chain link comprising a composition comprising, by weight percentage,
approximately 0.25% to 0.75% carbon, approximately 0.2% to 1.0% manganese, approximately 0.05% to 0.60% silicon, approximately 0.26% to 1.5% niobium, approximately 0.20% to 2.0%> chromium, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, up to approximately 0.03% sulfur, and a remainder of the composition being iron and any other impurities.
38. The chain link of claim 37, wherein the chain link has a hardness of HRc 50 to 60.
39. The chain link of claim 38, wherein the chain link has a hardness of HRc 52 to 58.
40. A chain that includes a plurality of links, each link comprising a steel composition comprising, by weight percentage, approximately 0.25% to 0.75% carbon, approximately 0.2% to 1.0% manganese, approximately 0.05% to 0.60% silicon, approximately 0.26% to 1.5% niobium, approximately 0.20% to 2.0% chromium, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, up to approximately 0.03% sulfur, and a remainder of the composition being iron and any other impurities.
41. The chain of claim 40, wherein the links have a hardness of HRc 50 to 60.
42. The chain of claim 41, wherein the links have a hardness of HRc 52 to 58.
43. A method of producing a chain link, comprising the step of heat treating a steel
composition comprising by weight percentage, approximately 0.25% to 0.75% carbon, approximately 0.2% to 1.0% manganese, approximately 0.05 to 0.60% silicon, approximately 0.26% to 1.5% niobium, approximately 0.20 to 2.0% chromium, up to approximately 0.30% aluminum, up to approximately 0.03% phosphorus, up to approximately 0.03% sulfur, and a remainder of the composition being iron and any other impurities, to a hardness of HRc 50 to 60.
44. The method of claim 43, wherein the heat treating step uses a method selected from the group consisting of oil quenching and tempering, salt bath austempering, and salt bath martempering.
PCT/US2017/030000 2016-05-10 2017-04-28 Niobium and chromium low alloy carbon steel for high wear resistant automotive chain link plates WO2017196552A1 (en)

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US16/099,364 US20190211415A1 (en) 2016-05-10 2017-04-28 Niobium and chromium low alloy carbon steel for high wear resistant automotive chain link plates
EP17796564.7A EP3455383A4 (en) 2016-05-10 2017-04-28 Niobium and chromium low alloy carbon steel for high wear resistant automotive chain link plates
JP2018555243A JP2019521242A (en) 2016-05-10 2017-04-28 Niobium and chromium low alloy carbon steel for high wear resistance automotive chain link plates
CN201780024555.1A CN109072388A (en) 2016-05-10 2017-04-28 Niobium chromium low-alloy carbon steel for high abrasion automobile link plate

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US62/333,950 2016-05-10

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JP2019521242A (en) 2019-07-25
EP3455383A1 (en) 2019-03-20
US20190211415A1 (en) 2019-07-11
EP3455383A4 (en) 2019-11-20

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