WO2017178729A1 - Highly lightweight and thermally insulating mortar composition - Google Patents

Highly lightweight and thermally insulating mortar composition Download PDF

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Publication number
WO2017178729A1
WO2017178729A1 PCT/FR2017/050781 FR2017050781W WO2017178729A1 WO 2017178729 A1 WO2017178729 A1 WO 2017178729A1 FR 2017050781 W FR2017050781 W FR 2017050781W WO 2017178729 A1 WO2017178729 A1 WO 2017178729A1
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composition according
weight
composition
mixing
chosen
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PCT/FR2017/050781
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French (fr)
Inventor
Daniel Comoy
Michaël PERRAT DIT GENTON
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Saint-Gobain Weber
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Priority to EP17719658.1A priority Critical patent/EP3442929A1/en
Priority to BR112018068834A priority patent/BR112018068834A2/en
Publication of WO2017178729A1 publication Critical patent/WO2017178729A1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • C04B28/065Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00637Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00663Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00663Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
    • C04B2111/00672Pointing or jointing materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/10Compositions or ingredients thereof characterised by the absence or the very low content of a specific material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/60Flooring materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Definitions

  • the present invention relates to a thermally insulating lightened mortar composition, the low density of the dough after kneading remains stable during the plastic phase of the mortar (that is to say before the hardened phase). This stability of the dough makes it possible to obtain cured products of low density whatever the method of implementation (manual, by casting or by pumping) and whatever the machine used (machine or mortar pump, continuous mixing or discontinuous).
  • the present invention also relates to the use of this composition in the field of construction, in particular for the thermal insulation of floors, ceilings and / or walls and the filling of insulating blocks or interstitial voids, for example wall cavities. .
  • insulating mortars Today we try to lighten as much as possible insulating mortars, both for facade type solutions and in particular for external thermal insulation systems (ITE or ETICS in English) as for materials for the soil in order to form lightened screeds.
  • leaching loads such as, for example, mineral fillers such as perlite, vermiculite, expanded clays, or with synthetic organic fillers such as expanded polystyrene beads.
  • leaching loads such as, for example, mineral fillers such as perlite, vermiculite, expanded clays, or with synthetic organic fillers such as expanded polystyrene beads.
  • these lightening loads does not achieve very low densities while maintaining the desired maneuverability for the desired applications.
  • Patent FR 2 955 103 proposes mineral foams obtained by adding a conventional air-entraining agent and a complex foaming adjuvant comprising a modified starch ether, a stabilizer comprising at least one polyacrylamide and a film-forming polymer.
  • the apparent densities of the cured product that are the lowest attainable with these formulations and measured at 28 days are of the order of 370 kg / m 3 , which remains densities considered high to reach thermal conductivities of less than 55 mW / m. K.
  • the present invention relates to a mortar composition for obtaining products whose paste densities after mixing are very low and remain stable over time, and which have in the state cured satisfactory mechanical strengths.
  • the present invention also relates to a method of preparing building material from said mortar composition. The building material obtainable by mixing such a composition or from this preparation process and its use are also objects of the present invention.
  • the inventors have discovered that by combining certain inorganic hydraulic binders with leaching loads a large amount of air could be introduced by addition of a conventional air-entraining agent and thus obtain a very important relief, while keeping a very good stability of the volume density of the dough and very good handling in the fresh state.
  • the amount of air entrained by the formulation proposed in the present invention is such as to halve the density relative to a formulation that would conventionally use lightening loads, and this with perfect stability and a very advantageous cost.
  • composition according to the present invention is a pre-mixed dry composition ready for use in the sense that its constituents are already premixed and where it is sufficient to mix it with the mixing water. It is not necessary to add other stabilizer to the dry composition when preparing the mortar on site.
  • the mortar obtained from the composition according to the present invention has a thermal conductivity less than or equal to 55 mW / m. K. and a compressive strength at 28 days of at least 0.40 MPa, which makes it possible to classify it in type CS 1 mortars according to standard NF EN 998-1, relating to industrial mortars. It also has improved acoustic properties, especially in terms of sound absorption.
  • An object of the present invention is a thermally insulating mortar composition which is free of siliceous or calcareous aggregates of a size greater than 100 ⁇ , and which comprises a mixture of at least:
  • a mineral binder chosen from sulfo-aluminous cements, aluminous cements and / or binary or ternary binders comprising at least one aluminous or sulfoaluminous cement,
  • a surfactant-type air entrainment agent chosen from organic fatty acids, sulphated compounds, sulphonated compounds and / or natural wood resins, and
  • a viscosing agent chosen from polyvinyl alcohols, starch ethers, cellulose ethers, guar ethers or clays such as bentonite. Unless otherwise indicated, the percentages of the various constituents of the dry composition are given in percentages by weight and relate to the total composition of the composition.
  • the bulk density of a granular filler is the mass per unit volume taking into account voids present in or between grains. It is given in kg / m 3 .
  • the composition according to the present invention does not comprise siliceous aggregates, limestone and / or silico-limestone having a particle size greater than 100 ⁇ .
  • the absence of coarse aggregates advantageously makes it possible to obtain the desired lightening.
  • the composition according to the present invention comprises less than 5% of siliceous fillers, limestone and / or silico-limestone having a particle size less than 100 ⁇ .
  • the composition is free of siliceous, calcareous and / or silico-calcareous fillers having a particle size of less than 100 ⁇ .
  • the mortar composition according to the present invention comprises at least 40% by weight of lightening mineral fillers whose bulk density is less than 200 kg / m 3 . These charges are in particular of spherical shape and have an average diameter less than or equal to 80 ⁇ .
  • the mineral lightening fillers are chosen from expanded perlite, expanded vermiculite, expanded glass beads, hollow glass microspheres, cenospheres, expanded clays, expanded shales, pumice stones, expanded silicates and / or aerogels. .
  • the mineral lightening fillers are chosen from expanded perlite, expanded vermiculite, expanded glass beads, hollow glass microspheres, cenospheres, expanded clays, expanded shales, pumice stones and / or silicates. expanded.
  • the lightening mineral fillers are perlite, which may be hydrophobic. Hydrophobized perlite may be advantageous in formulations intended to improve thermal insulation.
  • the composition according to the present invention comprises at least 50% by weight of lightening mineral fillers and more preferably at least 60% by weight.
  • the composition according to the present invention comprises a hydraulic mineral binder chosen from sulfo-aluminous cements, aluminous cements and / or binary or ternary binders comprising at least one aluminous or sulfoaluminous cement.
  • This type of binder advantageously makes it possible to contribute to the stability of the lightened dough produced.
  • Aluminous cements are based on calcium aluminate.
  • the sulfo-aluminous cements consist of a mixture of sulfo-aluminous clinker and calcium sulphates hydrate (gypsum, semi-hydrate) or not (anhydrite).
  • compositions which have in common the presence of calcium sulfoaluminate Mention may be made, for example, of alitic sulphoaluminous cement, of alumitic cement, of belitic sulpho-aluminous cements.
  • Binary or ternary binder is used when the hydraulic binder consists of a mixture of several binders.
  • the binary or ternary binders within the meaning of the present invention comprise a mixture of at least one aluminous or sulfo-aluminous cement, with respectively one or two other binders such as Portland cements, slags, natural or artificial lime and / or sources of calcium sulphate such as plaster or hemihydrate, gypsum and / or anhydrite.
  • the binary or ternary binder comprises less than 30% by weight of Portland cement and / or lime with respect to the total weight of binder. Too much Portland cement and / or lime in the binder could cause an increase in pH, which appears to be detrimental to the stability of the entrained air. The amount of binders whose pH is greater than or equal to 12.4 should not be too great in the composition according to the present invention.
  • the composition according to the present invention advantageously comprises a large amount of air entraining agent. It comprises at least 0.3% by weight of air entraining agent. Thus, with such a quantity, it becomes possible to entrain a lot of air during the mixing with water of the dry composition under usual mixing conditions and thus to significantly reduce the final product.
  • said composition comprises at least 0.5% by weight of air-entraining agent. Contrary to what was known, thanks to the particular choices of the constituents of said composition, it becomes possible to entrain more air, while maintaining the stability of the relief obtained.
  • the coaching agent of air is chosen from alkyl sulphates, alkyl sulphonates and alkyl aryl sulphates, alone or as a mixture.
  • the air-entraining agent is sodium lauryl sulphate.
  • a significant improvement in lightening therefore becomes possible, by judiciously choosing the various constituents of the composition according to the present invention, and by using an air entrainment agent considered as simple and therefore cheap.
  • the composition according to the present invention also comprises a viscosing agent which is chosen from polyvinyl alcohols, starch ethers, cellulose ethers, guar ethers or clays.
  • a viscosing agent which is chosen from polyvinyl alcohols, starch ethers, cellulose ethers, guar ethers or clays.
  • the viscosing agent is a cellulose ether such as ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxyethylmethylcellulose or hydroxypropylmethylcellulose.
  • This agent plays in particular on the rheology of the composition in the fresh state, and in particular on the retention of water. It is a simple viscosifying agent, usually used in mortar formulations.
  • the composition further comprises a polymeric additive which is a copolymer of vinyl type, of acrylic type and / or of carboxylic acid derivative and more preferably a copolymer of vinyl acetate, of vinyl versatate and of methacrylic acid and / or ester, maleic ester, olefin and / or vinyl chloride.
  • a polymeric additive which is a copolymer of vinyl type, of acrylic type and / or of carboxylic acid derivative and more preferably a copolymer of vinyl acetate, of vinyl versatate and of methacrylic acid and / or ester, maleic ester, olefin and / or vinyl chloride.
  • composition according to the present invention may also further comprise rheological agents such as plasticizers or superplasticizers, water-retaining agents, thickening agents, biocidal and / or fungicidal protection, dispersing agents, pigments, accelerators and / or retarders, water-repellent agents, fibers.
  • rheological agents such as plasticizers or superplasticizers, water-retaining agents, thickening agents, biocidal and / or fungicidal protection, dispersing agents, pigments, accelerators and / or retarders, water-repellent agents, fibers.
  • rheological agents such as plasticizers or superplasticizers, water-retaining agents, thickening agents, biocidal and / or fungicidal protection, dispersing agents, pigments, accelerators and / or retarders, water-repellent agents, fibers.
  • the respective amount of these agents depends on their nature. They are generally between 0.01% and 2% by weight. It is possible to introduce, for example, larger amounts of certain
  • composition according to the present invention when mixed with mixing water can be manually applied, cast or can be mechanically sprayed onto a support.
  • Another object of the present invention is a method of preparing by projection of a building material from the mortar composition described hereinbefore.
  • the method according to the present invention comprises the steps of:
  • the composition according to the present invention can advantageously be pumped and used in a mortar spraying process.
  • This type of process is generally critical for lightweight mortar compositions. It is indeed common for a mortar composition to have the desired lightening before projection but once introduced into the projection device and projected on the support, it loses its lightening properties. Surprisingly, the composition according to the present invention retains lightening properties, even once it is pumped and transferred to the spraying lance.
  • the paste obtained is projected onto the support, generally by successive passages.
  • the support is thus covered with several centimeters of mortar; the thickness depending on the nature of the support and / or type of finish sought.
  • the method according to the invention optionally comprises a finishing step, consisting of making the surface homogeneous and smooth. For an application as a facade, this finishing step is mandatory: it allows in particular to obtain a flat surface for the application of the finishing coating necessary for increase the surface hardness and ensure the protection, including waterproofing, of the facade.
  • the mixing step in the blender of the blasting device varies from a few seconds for a continuous blending machine to several minutes in the case of batch blending machine.
  • the mixing time in the mixer of the projection device is between 15 seconds and
  • the process according to the present invention can be carried out with a batch mixing mortar machine, in the sense that a defined quantity of dough is spun and then sprayed.
  • a batch mixing mortar machine in the sense that a defined quantity of dough is spun and then sprayed.
  • machines that are conventionally used such as the Putzmeister SP1 1 projection machines.
  • An object of the invention relates to a lightweight construction material that can be obtained by the method described above, or after mixing a composition as described above.
  • Said material has a thermal conductivity less than or equal to 55 mW / m. K. and a compressive strength at 28 days of at least 0.40 MPa.
  • the material according to the present invention is a lightened material, very good thermal insulator and sufficiently mechanically resistant for the desired application. The performances obtained in terms of mechanical strength allow it to be classified in the category CS 1 mortars according to standard NF 998-1.
  • the present invention also relates to the use of the material described above and having a thermal conductivity less than or equal to 55 mW / m. K. and a 28-day compressive strength of at least 0.40 MPa as screed, wall underlayment, ceilings, insulating masonry block filler material or interstitial void fillers and wall cavities.
  • the examples below illustrate the invention without limiting its scope.
  • compositions C1 to C8 are compositions in accordance with the invention, whereas compositions C9 based on Portland cement and C10 based on aerial lime are given for comparison and are not in accordance with the invention.
  • Tackle retardant agent 0.1
  • composition C9 is kneaded with water with a mixing rate of 170% in a kneader described above for a period of 90 seconds.
  • the same measurement carried out after a time of 30 min (ie t30) is worth 600 kg / m 3 , demonstrating a very clear instability of the air entrained in this mortar formulation since the difference between the densities measured at t0 and at t30 is well above 100 kg / m 3 .
  • composition C10 based on aerial lime is mixed with water at an identical mixing rate (170%).
  • the apparent density values measured respectively at t0 and t30 are 450 kg / m 3 and 750 kg / m 3 , again demonstrating a very high instability of the entrained air.
  • composition C1 is compared with an identical composition without air-entraining agent, comprising 29.4% by weight of ALI PRE® sulfo-aluminous cement.
  • the bulk density of this slurry without air-entraining is close to 700 kg / m3 with a satisfactory stability at 30 min.
  • the addition of 0.6% of air entrainer (composition C1) makes it possible to reduce the apparent density of the pulp up to 350 kg / m 3 .
  • Pasta is prepared with compositions C1 to C7 by kneading for 90 seconds before being placed in molds.
  • compositions according to the present invention make it possible to obtain lightened mortars whose density remains low after hardening, attesting to good stability of the dough over time.
  • the compressive strengths at 28 days of the C2, C5 and C6 mortars were measured and are respectively 0.46 MPa, 0.67 MPa and 0.61 MPa.
  • composition close to the composition C2 thus based on ALICEM® sulfoaluminous cement is prepared by mixing:
  • This composition is spoiled (mixing rate of 160%) in the kneader described above.
  • the mixing time is varied so as to vary the amount of entrained air.
  • Apparent density measurements of the paste at 100, as well as the hardened mortar at 28 days are shown in Table 3 below.
  • the compressive strength at 28 days is also indicated in MPa.
  • Example 4 The composition of Example 4 is spoiled (mixing rate of 155%) and kneaded for 5 min before being projected onto a wall of breeze blocks with a Putzmeister SP1 type 1 machine. This mixing gives a paste whose bulk density is 350 kg / m 3 in the tank, 356 kg / m 3 at the projection lance outlet and 170 kg / m 3 after curing after 28 days.
  • the compressive strength measured on a sample of 4 * 4 * 4 cm after 28 days is 0.52 MPa and the thermal conductivity is 52 mW / m. K.
  • composition C8 is spoiled (mixing rate of 147%) and kneaded for 5 min before being projected onto a wall of blocks with a Putzmeister SP1 type machine 1.
  • This mixing gives a paste whose bulk density is 380 kg / m 3 tank, 320 kg / m 3 by spraying lance outlet and 155 kg / m 3 after curing at 28 days.
  • the compressive strength measured on a sample of 4 * 4 * 4 cm after 28 days is 0.42 MPa and the thermal conductivity is 49 mW / m. K.
  • Example 7 Example 7
  • Example 4 The composition of Example 4 is projected with a continuous mixing machine of the Mtec M330 type.
  • the water flow is 250 l / h.
  • the bulk density of the slurry measured at the outlet of lance is 380 kg / m 3, which is quite comparable with the values obtained with batch mixing machines.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Ceramic Products (AREA)

Abstract

The present invention relates to a thermally insulating mortar composition devoid of siliceous, calcareous and/or siliceous/calcareous aggregates with a particle size of greater than 100 µm and comprising a mixture of at least: - 40% of inorganic lightening fillers, the bulk density of which is less than 200 kg/m3, - an inorganic binder chosen from sulfoaluminate cements, high-alumina cements and/or binary or ternary binders comprising at least one high-alumina or sulfoaluminate cement, - an air-entraining agent of surfactant type chosen from organic fatty acids, sulfate compounds, sulfonate compounds and/or natural wood resins, and - a viscosifying agent chosen from polyvinyl alcohols, starch ethers, cellulose ethers, guar ethers or clays, such as bentonite. This composition can be used in a spraying device operating in continuous or noncontinuous mode and makes it possible to obtain lightweight hardened mortars by virtue of a very good stability of the paste. The present invention also relates to a process for the preparation of a construction material, to the material thus obtained and to the use thereof in the construction field.

Description

COMPOSITION DE MORTIER FORTEMENT ALLÉGÉ ET ISOLANT THERMIQUE  STRONGLY LIGHT MORTAR COMPOSITION AND THERMAL INSULATION
La présente invention porte sur une composition de mortier allégé isolant thermiquement, dont la faible masse volumique de la pâte après malaxage reste stable pendant la phase plastique du mortier (c'est-à-dire avant la phase durcie). Cette stabilité de la pâte permet d'obtenir des produits durcis de faible densité quelle que soit la méthode de mise en œuvre (manuelle, par coulage ou par pompage) et quelle que soit la machine utilisée (machine ou pompe à mortier, à gâchage continu ou discontinu). La présente invention porte également sur l'utilisation de cette composition dans le domaine de la construction, notamment pour l'isolation thermique des planchers, plafonds et/ou des murs et le remplissage des blocs isolants ou des vides interstitiels, par exemple des cavités murales. The present invention relates to a thermally insulating lightened mortar composition, the low density of the dough after kneading remains stable during the plastic phase of the mortar (that is to say before the hardened phase). This stability of the dough makes it possible to obtain cured products of low density whatever the method of implementation (manual, by casting or by pumping) and whatever the machine used (machine or mortar pump, continuous mixing or discontinuous). The present invention also relates to the use of this composition in the field of construction, in particular for the thermal insulation of floors, ceilings and / or walls and the filling of insulating blocks or interstitial voids, for example wall cavities. .
On cherche aujourd'hui à alléger le plus possible les mortiers isolants, aussi bien pour des solutions de type façade et en particulier pour les systèmes d'isolation thermique par l'extérieur (ITE ou ETICS en langue anglaise) que pour des matériaux pour le sol dans le but de former des chapes allégées. Traditionnellement, l'allégement des mortiers isolants est obtenu par l'emploi de charges allégeantes comme par exemple des charges minérales telles que la perlite, la vermiculite, les argiles expansées, ou avec des charges synthétiques organiques comme les billes de polystyrène expansé. Toutefois, le simple ajout de ces charges allégeantes ne permet pas d'atteindre des densités très basses tout en gardant la maniabilité souhaitée pour les applications recherchées. En augmentant trop la quantité de charges allégeantes dans les formulations, on se trouve confronté à des problématiques liées d'une part à des trop fortes concentrations de particules granulaires (empilement granulaire maximum atteint) et d'autre part à des problèmes de pompabilité ou de maniabilité des pâtes obtenues à partir de ces formulations. La seule façon d'améliorer encore l'allégement est d'utiliser des formulations moussées et donc d'ajouter des additifs spécifiques permettant d'augmenter la quantité d'air occlus, c'est-à-dire la quantité d'air contenu dans la pâte ou dans le mortier une fois durci. Certains de ces additifs peuvent générer des gaz in-situ et donc former des mousses en générant des bulles. D'autres sont du type entraîneur d'air et permettent d'entraîner de l'air lors des phases de préparation des compositions, en particulier pendant le malaxage avec l'eau de gâchage. L'usage de ces types d'entraineurs d'air reste cependant limité car il est difficile d'obtenir la stabilité de l'air entraîné soit dans le temps, soit lors du passage dans les outils de projection qui sollicitent fortement la pâte, notamment par d'importants cisaillements. Il est en effet important que les mortiers, même de faible masse volumique, possèdent une bonne ouvrabilité ou maniabilité et qu'une fois durcis, ils aient les propriétés de résistance mécanique attendues. L'air entraîné lors du malaxage doit rester stable dès la formation des bulles qui a lieu pendant le malaxage et également pendant la mise en œuvre de la pâte et jusqu'au démarrage de la phase de durcissement. On considère que l'air entraîné est stable lorsque la différence entre les masses volumiques de la pâte mesurées à tO, c'est-à-dire immédiatement après le malaxage et à t30, soit 30 minutes après le malaxage, est inférieure à 100 kg/m3 (conformément à la certification CSTB). Le brevet FR 2 955 103 propose des mousses minérales obtenues par ajout d'un agent entraîneur d'air classique et d'un adjuvant moussant complexe comprenant un éther d'amidon modifié, un stabilisant comprenant au moins un polyacrylamide et un polymère filmogène. Les masses volumiques apparentes du produit durci les plus faibles atteignables avec ces formulations et mesurées à 28 jours sont de l'ordre de 370 kg/m3, ce qui reste des masses volumiques considérées comme élevées pour atteindre des conductivités thermiques inférieures à 55 mW/m. K. Aujourd'hui, il est encore très difficile d'obtenir des mortiers très allégés, c'est-à-dire dont la masse volumique apparente est inférieure à 250 kg/m3 à l'état durci, et maniables par l'utilisation d'additifs entraîneurs d'air. En effet, les bulles générées lors du malaxage du mortier avec l'eau de gâchage collapsent très rapidement. Les densités faibles mesurées juste après le malaxage ne sont pas pérennes et ont tendance à augmenter très rapidement dans les minutes qui suivent le malaxage. De plus, l'éclatement des bulles créées lors du malaxage entraîne une dégradation de la maniabilité du produit qui perd alors de son onctuosité. Today we try to lighten as much as possible insulating mortars, both for facade type solutions and in particular for external thermal insulation systems (ITE or ETICS in English) as for materials for the soil in order to form lightened screeds. Traditionally, the lightening of insulating mortars is obtained by the use of leaching loads such as, for example, mineral fillers such as perlite, vermiculite, expanded clays, or with synthetic organic fillers such as expanded polystyrene beads. However, the simple addition of these lightening loads does not achieve very low densities while maintaining the desired maneuverability for the desired applications. By increasing the amount of leaching loads in the formulations too much, we are confronted with problems related on the one hand to too high concentrations of granular particles (maximum granular stacking achieved) and on the other hand to problems of pumpability or workability of pasta obtained from these formulations. The only way to further improve the relief is to use foamed formulations and thus add specific additives to increase the amount of air occluded, that is to say the amount of air contained in the paste or in the mortar once hardened. Some of these additives can generate in-situ gases and thus form foams generating bubbles. Others are of the air-entraining type and make it possible to entrain air during the preparation phases of the compositions, in particular during mixing with the mixing water. The use of these types of air entrainers remains however limited because it is difficult to obtain the stability of the air entrained either in time, or when passing in the projection tools that strongly urge the dough, in particular by significant shears. It is indeed important that mortars, even of low density, have good workability or workability and that once hardened, they have the expected strength properties. The air entrained during the mixing must remain stable as soon as the bubbles form during mixing and also during the operation of the dough and until the start of the curing phase. It is considered that the entrained air is stable when the difference between the densities of the dough measured at t0, that is to say immediately after kneading and at 30, 30 minutes after kneading, is less than 100 kg. / m 3 (according to CSTB certification). Patent FR 2 955 103 proposes mineral foams obtained by adding a conventional air-entraining agent and a complex foaming adjuvant comprising a modified starch ether, a stabilizer comprising at least one polyacrylamide and a film-forming polymer. The apparent densities of the cured product that are the lowest attainable with these formulations and measured at 28 days are of the order of 370 kg / m 3 , which remains densities considered high to reach thermal conductivities of less than 55 mW / m. K. Today, it is still very difficult to obtain very light mortars, that is to say ones whose apparent density is less than 250 kg / m 3 in the hardened state, and manageable by the use of air-entraining additives. Indeed, the bubbles generated during the mixing of the mortar with the mixing water collapse very quickly. The low densities measured just after mixing are not perennial and tend to increase very rapidly within minutes of mixing. In addition, the bursting of the bubbles created during the mixing causes a degradation of the workability of the product which then loses its creaminess.
Les solutions connues actuellement pour obtenir des produits durcis dont les masses volumiques apparentes à l'état durci sont inférieures à 250 kg/m3 utilisent notamment des compositions à base de billes de polystyrène. Ces charges, en raison de leur nature organique, présentent notamment de mauvaises propriétés en termes de résistance au feu. Solutions currently known to obtain cured products whose apparent densities in the cured state are less than 250 kg / m 3 use in particular compositions based on polystyrene beads. These charges, because of their organic nature, have in particular poor properties in terms of fire resistance.
Les seules solutions connues à ce jour qui permettent d'obtenir des mortiers ou des pâtes dont la masse volumique à l'état durci est inférieure à 250 kg/m3 consistent à ajouter, dans la pâte ou dans le mortier, de la mousse préalablement générée à l'aide d'un générateur ou encore d'introduire une quantité d'air, ou de gaz, dans la pâte ou le mortier encore frais non durci. Cependant, les techniques de génération de mousse et leur introduction dans une pâte ou mortier cimentaire, même si en usine elles peuvent être contrôlées et maîtrisées, restent très complexes et souvent non compatibles avec les consignes d'application sur chantier notamment à cause des temps de préparation trop long. Un autre inconvénient des mortiers ou pâtes moussées, bullées, ou gazéifiées, reste la stabilité des bulles créées ou introduites pendant les phases de pompage et de projection. The only solutions known to date which allow to obtain mortars or pastes having a density in the cured state is less than 250 kg / m 3 consist in adding, in the pulp or in the mortar, foam previously generated by a generator or to introduce a quantity of air, or gas, in the dough or the still fresh uncured mortar. However, foam generation techniques and their introduction into a cementitious paste or mortar, even if in the factory they can be controlled and controlled, remain very complex and often not compatible with the on-site application instructions, particularly because of preparation too long. Another disadvantage of foams or foams, bubbled, or gasified, remains the stability of the bubbles created or introduced during the pumping and projection phases.
Il n'existe pas aujourd'hui de formulation de produits de masse volumique apparente très basse (inférieure à 250 kg/m3) qui soient à base de charges allégeantes minérales, qui soient projetables avec des machines de projection classiques fonctionnant en continu ou en discontinu, dans des conditions de malaxage habituelles c'est-à-dire avec des durées de malaxage usuelles pour l'homme de l'art (quelques secondes pour une machine continue et de l'ordre de 5 minutes pour une machine discontinue), et qui possèdent la maniabilité et les résistances suffisantes. C'est dans ce cadre que s'inscrit la présente invention qui porte sur une composition pour mortier permettant d'obtenir des produits dont les densités de pâte après malaxage sont très faibles et restent stables dans le temps, et qui possèdent à l'état durci des résistances mécaniques satisfaisantes. La présente invention porte également sur un procédé de préparation de matériau de construction à partir de ladite composition de mortier. Le matériau de construction susceptible d'être obtenu par gâchage d'une telle composition ou à partir de ce procédé de préparation ainsi que son utilisation sont également des objets de la présente invention. There is currently no formulation of products of very low apparent density (less than 250 kg / m 3 ) which are based on mineral lightening loads, which can be projected with conventional projection machines operating continuously or discontinuous, under usual mixing conditions that is to say with kneading times customary for those skilled in the art (a few seconds for a continuous machine and of the order of 5 minutes for a discontinuous machine), and who have sufficient maneuverability and resistance. It is in this context that the present invention relates to a mortar composition for obtaining products whose paste densities after mixing are very low and remain stable over time, and which have in the state cured satisfactory mechanical strengths. The present invention also relates to a method of preparing building material from said mortar composition. The building material obtainable by mixing such a composition or from this preparation process and its use are also objects of the present invention.
De façon très surprenante, les inventeurs ont découvert qu'en combinant certains liants hydrauliques minéraux avec des charges allégeantes minérales, il était possible d'introduire une quantité importante d'air par ajout d'un agent entraîneur d'air classique et ainsi d'obtenir un très important allégement, tout en gardant une très bonne stabilité de la densité volumique de la pâte et une très bonne maniabilité à l'état frais. Ainsi, la quantité d'air entraîné par la formulation proposée dans la présente invention est telle qu'elle permet de diviser par deux la densité par rapport à une formulation qui utiliserait de façon classique des charges allégeantes, et ceci avec une parfaite stabilité et à un coût très avantageux. Surprisingly, the inventors have discovered that by combining certain inorganic hydraulic binders with leaching loads a large amount of air could be introduced by addition of a conventional air-entraining agent and thus obtain a very important relief, while keeping a very good stability of the volume density of the dough and very good handling in the fresh state. Thus, the amount of air entrained by the formulation proposed in the present invention is such as to halve the density relative to a formulation that would conventionally use lightening loads, and this with perfect stability and a very advantageous cost.
La composition selon la présente invention est une composition sèche pré-mixée prête à l'emploi dans le sens où ses constituants sont déjà prémélangés et où il suffit de la mélanger avec l'eau de gâchage. Il n'est pas nécessaire d'ajouter d'autre stabilisant à la composition sèche lors de la préparation du mortier sur chantier.  The composition according to the present invention is a pre-mixed dry composition ready for use in the sense that its constituents are already premixed and where it is sufficient to mix it with the mixing water. It is not necessary to add other stabilizer to the dry composition when preparing the mortar on site.
Le mortier obtenu à partir de la composition selon la présente invention a une conductivité thermique inférieure ou égale à 55 mW/m. K. et une résistance en compression à 28 jours d'au moins 0,40 MPa, ce qui permet de le classer dans les mortiers de type CS 1 selon la norme NF EN 998-1 , portant sur les mortiers industriels. Il présente également des propriétés acoustiques améliorées, notamment en termes d'absorption phonique.  The mortar obtained from the composition according to the present invention has a thermal conductivity less than or equal to 55 mW / m. K. and a compressive strength at 28 days of at least 0.40 MPa, which makes it possible to classify it in type CS 1 mortars according to standard NF EN 998-1, relating to industrial mortars. It also has improved acoustic properties, especially in terms of sound absorption.
Un objet de la présente invention est une composition pour mortier isolant thermiquement qui est exempte de granulats siliceux ou calcaires d'une taille supérieure à 100 μιτι, et qui comprend un mélange d'au moins:  An object of the present invention is a thermally insulating mortar composition which is free of siliceous or calcareous aggregates of a size greater than 100 μιτι, and which comprises a mixture of at least:
- 40% en poids de charges allégeantes minérales dont la masse volumique apparente est inférieure à 200 kg/m3, 40% by weight of mineral lightening fillers whose bulk density is less than 200 kg / m 3 ,
- un liant minéral choisi parmi les ciments sulfo-alumineux, les ciments alumineux et/ou les liants binaires ou ternaires comprenant au moins un ciment alumineux ou sulfoalumineux,  a mineral binder chosen from sulfo-aluminous cements, aluminous cements and / or binary or ternary binders comprising at least one aluminous or sulfoaluminous cement,
- un agent entraîneur d'air de type tensioactifs choisi parmi les acides gras organiques, les composés sulfatés, les composés sulfonatés et/ou les résines naturelles du bois, et  a surfactant-type air entrainment agent chosen from organic fatty acids, sulphated compounds, sulphonated compounds and / or natural wood resins, and
- un agent viscosant choisi parmi les alcools polyvinyliques, les éthers d'amidon, les éthers de cellulose, les éthers de guar ou les argiles telles que la bentonite. Sauf indication contraire, les pourcentages des différents constituants de la composition sèche sont donnés en pourcentages pondéraux et sont relatifs à la composition totale de la composition. a viscosing agent chosen from polyvinyl alcohols, starch ethers, cellulose ethers, guar ethers or clays such as bentonite. Unless otherwise indicated, the percentages of the various constituents of the dry composition are given in percentages by weight and relate to the total composition of the composition.
La masse volumique apparente d'une charge granulaire est la masse par unité de volume en tenant compte des vides présents dans ou entre les grains. Elle est donnée en kg/m3. The bulk density of a granular filler is the mass per unit volume taking into account voids present in or between grains. It is given in kg / m 3 .
La composition selon la présente invention ne comprend pas de granulats siliceux, calcaire et/ou silico-calcaires présentant une granulométrie supérieure à 100 μητι. L'absence de granulats grossiers permet avantageusement d'obtenir l'allégement recherché. De façon préférée, la composition selon la présente invention comprend moins de 5% de fillers siliceux, calcaires et/ou silico-calcaires présentant une granulométrie inférieure à 100 μητι. Encore plus préférentiellement, la composition est exempte de fillers siliceux, calcaires et/ou silico-calcaires présentant une granulométrie inférieure à 100 μητι.  The composition according to the present invention does not comprise siliceous aggregates, limestone and / or silico-limestone having a particle size greater than 100 μητι. The absence of coarse aggregates advantageously makes it possible to obtain the desired lightening. Preferably, the composition according to the present invention comprises less than 5% of siliceous fillers, limestone and / or silico-limestone having a particle size less than 100 μητι. Even more preferentially, the composition is free of siliceous, calcareous and / or silico-calcareous fillers having a particle size of less than 100 μητι.
La composition pour mortier selon la présente invention comprend au moins 40% en poids de charges minérales allégeantes dont la masse volumique apparente est inférieure à 200 kg/m3. Ces charges sont notamment de forme sphérique et possèdent un diamètre moyen inférieur ou égal à 80 μητι. Les charges allégeantes minérales sont choisies parmi la perlite expansée, la vermiculite expansée, les billes de verre expansé, les microsphères creuses de verre, les cénosphères, les argiles expansées, les schistes expansés, les pierres ponces, les silicates expansés et/ou les aérogels. De façon préférée, les charges allégeantes minérales sont choisies parmi la perlite expansée, la vermiculite expansée, les billes de verre expansé, les microsphères creuses de verre, les cénosphères, les argiles expansées, les schistes expansés, les pierres ponces et/ou les silicates expansés. De façon encore plus préférée, les charges minérales allégeantes sont de la perlite, éventuellement hydrophobe. La perlite hydrophobée peut être avantageuse dans des formulations destinées à améliorer l'isolation thermique. The mortar composition according to the present invention comprises at least 40% by weight of lightening mineral fillers whose bulk density is less than 200 kg / m 3 . These charges are in particular of spherical shape and have an average diameter less than or equal to 80 μητι. The mineral lightening fillers are chosen from expanded perlite, expanded vermiculite, expanded glass beads, hollow glass microspheres, cenospheres, expanded clays, expanded shales, pumice stones, expanded silicates and / or aerogels. . In a preferred manner, the mineral lightening fillers are chosen from expanded perlite, expanded vermiculite, expanded glass beads, hollow glass microspheres, cenospheres, expanded clays, expanded shales, pumice stones and / or silicates. expanded. Even more preferably, the lightening mineral fillers are perlite, which may be hydrophobic. Hydrophobized perlite may be advantageous in formulations intended to improve thermal insulation.
De façon préférée, la composition selon la présente invention comprend au moins 50% en poids de charges minérales allégeantes et plus préférentiellement au moins 60% en poids. La composition selon la présente invention comprend un liant minéral hydraulique choisi parmi les ciments sulfo-alumineux, les ciments alumineux et/ou les liants binaires ou ternaires comprenant au moins un ciment alumineux ou sulfoalumineux. Ce type de liant permet avantageusement de contribuer à la stabilité de la pâte allégée produite. Les ciments alumineux sont à base d'aluminate de calcium. Les ciments sulfo-alumineux sont constitués d'un mélange de clinker sulfo-alumineux et de sulfates de calcium hydratés (gypse, semi-hydrate) ou non (anhydrite). Cette appellation recouvre de nombreuses compositions qui ont pour point commun la présence de sulfoaluminate de calcium. On peut citer par exemple le ciment sulfo- alumineux alitique, le ciment ye'elimitique, les ciments sulfo-alumineux bélitiques. On parle de liant binaire ou ternaire lorsque le liant hydraulique est constitué d'un mélange de plusieurs liants. Les liants binaires ou ternaires au sens de la présente invention comprennent un mélange d'au moins un ciment alumineux ou sulfo-alumineux, avec respectivement un ou deux autres liants comme les ciments Portland, les laitiers, la chaux naturelle ou artificielle et/ou les sources de sulfate de calcium telle que le plâtre ou hémihydrate, le gypse et/ou l'anhydrite. Selon la présente invention, le liant binaire ou ternaire comprend moins de 30% en poids de ciment Portland et/ou de chaux par rapport au poids total de liant. Une quantité trop importante de ciment Portland et/ou de chaux dans le liant pourrait provoquer une augmentation du pH, ce qui semble être défavorable à la stabilité de l'air entraîné. La quantité de liants dont le pH est supérieur ou égal à 12,4 ne doit pas être trop importante dans la composition selon la présente invention. Preferably, the composition according to the present invention comprises at least 50% by weight of lightening mineral fillers and more preferably at least 60% by weight. The composition according to the present invention comprises a hydraulic mineral binder chosen from sulfo-aluminous cements, aluminous cements and / or binary or ternary binders comprising at least one aluminous or sulfoaluminous cement. This type of binder advantageously makes it possible to contribute to the stability of the lightened dough produced. Aluminous cements are based on calcium aluminate. The sulfo-aluminous cements consist of a mixture of sulfo-aluminous clinker and calcium sulphates hydrate (gypsum, semi-hydrate) or not (anhydrite). This name covers many compositions which have in common the presence of calcium sulfoaluminate. Mention may be made, for example, of alitic sulphoaluminous cement, of alumitic cement, of belitic sulpho-aluminous cements. Binary or ternary binder is used when the hydraulic binder consists of a mixture of several binders. The binary or ternary binders within the meaning of the present invention comprise a mixture of at least one aluminous or sulfo-aluminous cement, with respectively one or two other binders such as Portland cements, slags, natural or artificial lime and / or sources of calcium sulphate such as plaster or hemihydrate, gypsum and / or anhydrite. According to the present invention, the binary or ternary binder comprises less than 30% by weight of Portland cement and / or lime with respect to the total weight of binder. Too much Portland cement and / or lime in the binder could cause an increase in pH, which appears to be detrimental to the stability of the entrained air. The amount of binders whose pH is greater than or equal to 12.4 should not be too great in the composition according to the present invention.
La composition selon la présente invention comprend avantageusement une quantité importante d'agent entraîneur d'air. Elle comprend au moins 0,3% en poids d'agent entraîneur d'air. Ainsi, avec une telle quantité, il devient possible d'entraîner beaucoup d'air lors du malaxage avec l'eau de la composition sèche dans des conditions de gâchage habituelles et donc d'alléger de façon notable le produit final. Préférentiellement, ladite composition comprend au moins 0,5% en poids d'agent entraîneur d'air. Contrairement à ce qui était connu, grâce aux choix particuliers des constituants de ladite composition, il devient possible d'entraîner plus d'air, tout en maintenant la stabilité de l'allégement obtenu. L'agent entraîneur d'air est choisi parmi les alkylsulfates, les alkylsulfonates, les alkylarylsulfates, seuls ou en mélange. Ces agents sont ceux utilisés classiquement dans les formulations de mortier allégé. De façon préférée, l'agent entraîneur d'air est du laurylsulfate de sodium. Une amélioration notable de l'allégement devient par conséquent possible, en choisissant de façon judicieuse les différents constituants de la composition selon la présente invention, et en utilisant un agent entraîneur d'air considéré comme simple donc bon marché. The composition according to the present invention advantageously comprises a large amount of air entraining agent. It comprises at least 0.3% by weight of air entraining agent. Thus, with such a quantity, it becomes possible to entrain a lot of air during the mixing with water of the dry composition under usual mixing conditions and thus to significantly reduce the final product. Preferably, said composition comprises at least 0.5% by weight of air-entraining agent. Contrary to what was known, thanks to the particular choices of the constituents of said composition, it becomes possible to entrain more air, while maintaining the stability of the relief obtained. The coaching agent of air is chosen from alkyl sulphates, alkyl sulphonates and alkyl aryl sulphates, alone or as a mixture. These agents are those conventionally used in lightened mortar formulations. Preferably, the air-entraining agent is sodium lauryl sulphate. A significant improvement in lightening therefore becomes possible, by judiciously choosing the various constituents of the composition according to the present invention, and by using an air entrainment agent considered as simple and therefore cheap.
La composition selon la présente invention comprend également un agent viscosant qui est choisi parmi les alcools polyvinyliques, les éthers d'amidon, les éthers de cellulose, les éthers de guar ou les argiles. La présence d'un tel agent dans une quantité comprise entre 0,01% et 2% en poids participe à la stabilité de l'air entraîné. De façon préférée, l'agent viscosant est un éther de cellulose tels que l'éthylcellulose, l'hydroxyéthylcellulose, l'hydroxypropylcellulose, l'hydroxyéthylméthylcellulose ou l'hydroxypropylméthylcellulose. Cet agent joue notamment sur la rhéologie de la composition à l'état frais, et en particulier sur la rétention d'eau. Il s'agit d'un agent viscosant simple, usuellement utilisé dans les formulations de mortier. Aucun mélange complexe comme ceux décrits dans l'art antérieur n'est nécessaire pour obtenir une pâte stable. L'agent viscosant participe notamment au piégeage des bulles d'air créées grâce à l'agent entraîneur d'air et à leur stabilité statique et dynamique dans le temps en augmentant le seuil d'écoulement ainsi que la viscosité dynamique du fluide interstitiel entre les particules solides et les bulles d'air. Préférentiellement, la teneur en agent viscosant dans la composition est préférentiellement comprise entre 0,1% et 1% en poids.  The composition according to the present invention also comprises a viscosing agent which is chosen from polyvinyl alcohols, starch ethers, cellulose ethers, guar ethers or clays. The presence of such an agent in an amount of between 0.01% and 2% by weight contributes to the stability of the entrained air. Preferably, the viscosing agent is a cellulose ether such as ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxyethylmethylcellulose or hydroxypropylmethylcellulose. This agent plays in particular on the rheology of the composition in the fresh state, and in particular on the retention of water. It is a simple viscosifying agent, usually used in mortar formulations. No complex mixture such as those described in the prior art is necessary to obtain a stable paste. The viscosifying agent participates notably in the trapping of the air bubbles created by the air-entraining agent and in their static and dynamic stability over time by increasing the flow threshold as well as the dynamic viscosity of the interstitial fluid between the solid particles and air bubbles. Preferably, the content of viscosity agent in the composition is preferably between 0.1% and 1% by weight.
Selon un mode de réalisation, la composition comprend en outre un additif polymérique qui est un copolymère de type vinylique, de type acrylique et/ou dérivé d'acide carboxylique et plus préférentiellement un copolymère d'acétate de vinyle, de versatate de vinyle et d'acide et/ou ester méthacrylique , d'ester maléique, d'oléfine et/ou de chlorure de vinyle.  According to one embodiment, the composition further comprises a polymeric additive which is a copolymer of vinyl type, of acrylic type and / or of carboxylic acid derivative and more preferably a copolymer of vinyl acetate, of vinyl versatate and of methacrylic acid and / or ester, maleic ester, olefin and / or vinyl chloride.
La composition selon la présente invention peut également comprendre en outre des agents rhéologiques tels que les plastifiants ou les superplastifiants, des agents rétenteurs d'eau, des agents épaississants, des agents de protection biocides et/ ou fongicides, des agents dispersants, des pigments, des accélérateurs et/ou retardateurs de prise, des agents hydrofuges, des fibres. La quantité respective de ces agents dépend de leur nature. Ils sont généralement compris entre 0,01 % et 2% en poids. Il est possible d'introduire par exemple des quantités plus importantes de certains additifs, et notamment des fibres. The composition according to the present invention may also further comprise rheological agents such as plasticizers or superplasticizers, water-retaining agents, thickening agents, biocidal and / or fungicidal protection, dispersing agents, pigments, accelerators and / or retarders, water-repellent agents, fibers. The respective amount of these agents depends on their nature. They are generally between 0.01% and 2% by weight. It is possible to introduce, for example, larger amounts of certain additives, and in particular fibers.
La composition selon la présente invention, une fois mélangée avec de l'eau de gâchage peut être appliquée manuellement, être coulée ou peut être projetée mécaniquement sur un support.  The composition according to the present invention, when mixed with mixing water can be manually applied, cast or can be mechanically sprayed onto a support.
Un autre objet de la présente invention est un procédé de préparation par projection d'un matériau de construction à partir de la composition pour mortier décrite ci -avant. Le procédé selon la présente invention comprend les étapes de :  Another object of the present invention is a method of preparing by projection of a building material from the mortar composition described hereinbefore. The method according to the present invention comprises the steps of:
-mélange de ladite composition avec l'eau de gâchage dans le mélangeur d'un dispositif de projection pour obtenir une pâte,  mixing said composition with the mixing water in the mixer of a projection device to obtain a paste,
-pompage de la pâte ainsi obtenue jusqu'à la lance du dispositif de projection, puis  -pumping of the dough thus obtained to the lance of the projection device, then
-projection sur le support.  -projection on the support.
La composition selon la présente invention peut avantageusement être pompée et mise en œuvre dans un procédé de projection de mortier. Ce type de procédé est généralement critique pour les compositions de mortier allégé. Il est en effet courant qu'une composition de mortier ait l'allégement souhaité avant projection mais qu'une fois introduite dans le dispositif de projection et projetée sur le support, elle perde ses propriétés d'allégement. De façon très surprenante, la composition selon la présente invention garde les propriétés d'allégement, même une fois qu'elle est pompée et transférée jusqu'à la lance de projection. La pâte obtenue est projetée sur le support, généralement par passages successifs. Le support est ainsi recouvert de plusieurs centimètres de mortier ; l'épaisseur dépendant de la nature du support et/ou du type de finition recherchée. Le procédé selon l'invention comprend éventuellement une étape de finition, consistant à rendre la surface homogène et lisse. Pour une application en tant que façade, cette étape de finition est obligatoire : elle permet notamment d'obtenir une surface plane pour l'application de l'enduit de finition nécessaire pour augmenter la dureté de surface et assurer la protection, notamment l'imperméabilisation, de la façade. The composition according to the present invention can advantageously be pumped and used in a mortar spraying process. This type of process is generally critical for lightweight mortar compositions. It is indeed common for a mortar composition to have the desired lightening before projection but once introduced into the projection device and projected on the support, it loses its lightening properties. Surprisingly, the composition according to the present invention retains lightening properties, even once it is pumped and transferred to the spraying lance. The paste obtained is projected onto the support, generally by successive passages. The support is thus covered with several centimeters of mortar; the thickness depending on the nature of the support and / or type of finish sought. The method according to the invention optionally comprises a finishing step, consisting of making the surface homogeneous and smooth. For an application as a facade, this finishing step is mandatory: it allows in particular to obtain a flat surface for the application of the finishing coating necessary for increase the surface hardness and ensure the protection, including waterproofing, of the facade.
L'étape de mélange dans le mélangeur du dispositif de projection varie de quelques secondes pour une machine à gâchage continu à plusieurs minutes dans le cas de machine à gâchage discontinu. La durée de malaxage dans le mélangeur du dispositif de projection est comprise entre 15 secondes et The mixing step in the blender of the blasting device varies from a few seconds for a continuous blending machine to several minutes in the case of batch blending machine. The mixing time in the mixer of the projection device is between 15 seconds and
10 minutes. 10 minutes.
Le procédé selon la présente invention peut être mis en œuvre avec une machine à mortier à gâchage discontinu, dans le sens où une quantité définie de pâte est gâchée puis projetée. Il s'agit de machines utilisées de façon classique, comme par exemple les machines de projection Putzmeister SP1 1 . The process according to the present invention can be carried out with a batch mixing mortar machine, in the sense that a defined quantity of dough is spun and then sprayed. These are machines that are conventionally used, such as the Putzmeister SP1 1 projection machines.
11 peut également être mise en œuvre de façon continue, par exemple avec une machine à mortier de type Mtec M330. It can also be implemented continuously, for example with a Mtec M330 type mortar machine.
Un objet de l'invention porte sur un matériau de construction allégé susceptible d'être obtenu par le procédé décrit ci-avant, ou après gâchage d'une composition telle que décrite ci-avant. Ledit matériau possède une conductivité thermique inférieure ou égale à 55 mW/m. K. et une résistance en compression à 28 jours d'au moins 0,40 MPa. Le matériau selon la présente invention est un matériau allégé, très bon isolant thermique et suffisamment résistant mécaniquement pour l'application souhaitée. Les performances obtenues en termes de résistance mécanique lui permettent d'être classé dans la catégorie des mortiers CS 1 selon la norme NF 998- 1 .  An object of the invention relates to a lightweight construction material that can be obtained by the method described above, or after mixing a composition as described above. Said material has a thermal conductivity less than or equal to 55 mW / m. K. and a compressive strength at 28 days of at least 0.40 MPa. The material according to the present invention is a lightened material, very good thermal insulator and sufficiently mechanically resistant for the desired application. The performances obtained in terms of mechanical strength allow it to be classified in the category CS 1 mortars according to standard NF 998-1.
La présente invention porte également sur l'utilisation du matériau décrit ci-dessus et présentant une conductivité thermique inférieure ou égale à 55 mW/m. K. et une résistance en compression à 28 jours d'au moins 0,40 MPa en tant que chape, sous-enduit mural, plafonds, matériau de remplissage de blocs de maçonnerie isolant ou matériau de remplissage de vides interstitiels et de cavités murales. Les exemples ci-après illustrent l'invention sans en limiter la portée.  The present invention also relates to the use of the material described above and having a thermal conductivity less than or equal to 55 mW / m. K. and a 28-day compressive strength of at least 0.40 MPa as screed, wall underlayment, ceilings, insulating masonry block filler material or interstitial void fillers and wall cavities. The examples below illustrate the invention without limiting its scope.
Plusieurs compositions pour mortier sont préparées en mélangeant les différents constituants dans un mélangeur à poudre classique et sont données de façon détaillée dans le tableau 1 ci-après. Lors des préparations de la pâte, ces formulations sont mélangées avec de l'eau de gâchage. Le taux de gâchage est donné en pourcentage : un taux de gâchage de 170% indique que 170 kg d'eau sont ajoutés à 100 kg de poudre sèche. Lorsque les formulations sont gâchées au laboratoire, le malaxage a lieu dans un malaxeur planétaire de type Rilem à une vitesse de 60 tours/ min pendant une durée de 90 secondes. Several mortar compositions are prepared by mixing the various constituents in a conventional powder mixer and are given in detail in Table 1 below. During the preparation of the dough, these formulations are mixed with mixing water. The mixing rate is given as a percentage: a mixing rate of 170% indicates that 170 kg of water are added to 100 kg of dry powder. When the formulations are spoiled in the laboratory, the mixing takes place in a Rilem type planetary mixer at a speed of 60 rpm for a period of 90 seconds.
Dans les exemples ci-après, la mesure de la masse volumique apparente de la pâte est effectuée à l'aide d'un récipient cylindrique d'un volume de V de un litre, préalablement taré et d'une masse M0. Ce récipient est rempli de pâte en deux fois et tassé par chocs (3 chocs à mi-hauteur et 3 chocs récipient plein), puis arasé et pesé. La masse mesurée est notée Mi . La masse volumique de la pâte en kg/ m3 est égale à la différence entre Mi et M0 rapportée au volume V exprimé en m3. Les compositions C1 à C8 sont des compositions conformes à l'invention, alors que les compositions C9 à base de ciment Portland et C10 à base de chaux aérienne sont données à titre de comparaison et sont non conformes à l'invention. In the examples below, the measurement of the bulk density of the paste is carried out using a cylindrical container with a volume of V of one liter, previously tared and a mass M 0 . This container is filled with paste twice and tamped by shocks (3 shocks at mid-height and 3 shocks full container), then trimmed and weighed. The measured mass is noted Mi. The density of the pulp in kg / m 3 is equal to the difference between Mi and M 0 relative to the volume V expressed in m 3 . Compositions C1 to C8 are compositions in accordance with the invention, whereas compositions C9 based on Portland cement and C10 based on aerial lime are given for comparison and are not in accordance with the invention.
C1 C2 C3 C4 C5 C6 C7 C8 C9 C10C1 C2 C3 C4 C5 C6 C7 C8 C9 C10
Perlite Silcell 42 BC d'un 65 65 65 65 65 65 65 70 65 65 diamètre moyen de 45 m Perlite Silcell 42 BC 65 65 65 65 65 65 65 70 65 65 average diameter 45 m
et de masse volumique and density
apparente d'environ 130 apparent about 130
kg/m3 kg / m 3
Ciment sulfoalumineux ALI 28.8  Sulphoaluminous cement ALI 28.8
PRE® (Italcementi) PRE® (Italcementi)
Ciment sulfoalumineux ALI 28.8 28.86 28.16 33.8 23.66  Sulphoaluminous cement ALI 28.8 28.86 28.16 33.8 23.66
CEM® (Italcementi) CEM® (Italcementi)
Ciment alumineux ISTRA 40 28.8 21.36  Aluminous cement ISTRA 40 28.8 21.36
(Calucem) (Calucem)
Ciment Portland 2.8 29.3 CEM I 52.5 (Calcia)  Portland Cement 2.8 29.3 CEM I 52.5 (Calcia)
Chaux aérienne (Boran) 29.3 Aerial lime (Boran) 29.3
Plâtre Molda 3 Normal 4 Molda Plaster 3 Normal 4
(Placo) (Placo)
Résine type copolymère 5 5 5 5 5 5 0 5 5 5 d'acétate de vinyle, de  Resin copolymer type 5 5 5 5 5 5 5 5 5 5 vinyl acetate,
versatate de vinyle et vinyl versatate and
d'ester maléique (Hexion) Maleic ester (Hexion)
Methylhydroxyéthylcellulose 0.6 0.6 0.6 0.6 0.5 0.7 0.6 0.6 0.6 0.6 de grade 100 000 mPa.s  Methylhydroxyethylcellulose 0.6 0.6 0.6 0.6 0.5 0.7 0.6 0.6 0.6 0.6 of grade 100 000 mPa.s
(Shinetsu) (Shinetsu)
Laurylsulafte de sodium 0.6 0.6 0.6 0.6 0.5 1 0.6 0.6 0.6 0.6 (Unger)  Sodium lauryl sulphate 0.6 0.6 0.6 0.6 0.5 1 0.6 0.6 0.6 0.6 (Unger)
Agent accélérateur de 0.14 0.14 0.14 0.14  Agent accelerator of 0.14 0.14 0.14 0.14
prise : carbonate de lithium taken: lithium carbonate
Agent accélérateur de 0.4  Agent accelerator of 0.4
prise : Na2C03 taken: Na 2 C03
Agent retardateur de prise : 0.1  Tackle retardant agent: 0.1
Acide citrique Citric acid
total 100 100 100 100 100 100 100 100 100 100 total 100 100 100 100 100 100 100 100 100 100
Tableau 1  Table 1
5 Exemple 1 5 Example 1
La composition C9 est malaxée avec de l'eau avec un taux de gâchage de 170% dans un malaxeur décrit ci-dessus pendant une durée de 90 secondes.  The composition C9 is kneaded with water with a mixing rate of 170% in a kneader described above for a period of 90 seconds.
La masse volumique apparente du mortier obtenu mesurée au temps t=0 (soit tO) est de 420 kg/m3. La même mesure effectuée après un temps de 30 min (soit t30) vaut 600 kg/m3, démontrant une très nette instabilité de l'air entraîné dans cette formulation de mortier puisque la différence entre les masses volumiques mesurées à tO et à t30 est largement supérieure à 100 kg/m3. The apparent density of the mortar obtained measured at time t = 0 (ie t0) is 420 kg / m 3 . The same measurement carried out after a time of 30 min (ie t30) is worth 600 kg / m 3 , demonstrating a very clear instability of the air entrained in this mortar formulation since the difference between the densities measured at t0 and at t30 is well above 100 kg / m 3 .
De la même manière que précédemment, la composition C10 à base de chaux aérienne est malaxée avec de l'eau à un taux de gâchage identique (170%). Les valeurs de masse volumique apparente mesurées respectivement à tO et à t30 valent 450 kg/m3 et 750 kg/m3, démontrant là encore une très forte instabilité de l'air entraîné. In the same manner as above, the composition C10 based on aerial lime is mixed with water at an identical mixing rate (170%). The apparent density values measured respectively at t0 and t30 are 450 kg / m 3 and 750 kg / m 3 , again demonstrating a very high instability of the entrained air.
A titre de comparaison, le même test a été réalisé avec une composition de mortier selon l'invention identique aux compositions C9 et C10, à ceci près que le ciment Portland ou la chaux ont été remplacés par un ciment sulfo-alumineux ALI PRE®. La masse volumique apparente mesurée à t=0 vaut 405 kg/m3 et vaut 450 kg/m3 après un temps de 30 min. Avec ce type particulier de liant, l'air entraîné présente une bonne stabilité. For the sake of comparison, the same test was carried out with a mortar composition according to the invention identical to compositions C9 and C10, except that the Portland cement or lime was replaced by ALI PRE® sulfo-aluminous cement. The apparent density measured at t = 0 is 405 kg / m 3 and is 450 kg / m 3 after a time of 30 min. With this particular type of binder, the entrained air has good stability.
Exemple 2 Example 2
La composition C1 est comparée avec une composition identique sans agent entraîneur d'air, comprenant 29,4% en poids de ciment sulfo-alumineux ALI PRE®. La masse volumique apparente de cette pâte sans entraîneur d'air est proche de 700 kg/m3 avec une stabilité satisfaisante à 30 min. L'ajout de 0,6 % d'entraineur d'air (composition C1 ) permet de diminuer la masse volumique apparente de la pâte jusqu'à 350 kg/m3. Exemple 3 Composition C1 is compared with an identical composition without air-entraining agent, comprising 29.4% by weight of ALI PRE® sulfo-aluminous cement. The bulk density of this slurry without air-entraining is close to 700 kg / m3 with a satisfactory stability at 30 min. The addition of 0.6% of air entrainer (composition C1) makes it possible to reduce the apparent density of the pulp up to 350 kg / m 3 . Example 3
Des pâtes sont préparées avec les compositions C1 à C7 par malaxage pendant 90 secondes avant d'être placées dans des moules. Les taux de gâchage utilisés sont indiqués dans le tableau 2 ci-après qui résume également les valeurs de masse volumique apparente mesurées à t=0 (sur la pâte fraîche) et sur le mortier durci après 28 jours. Pasta is prepared with compositions C1 to C7 by kneading for 90 seconds before being placed in molds. The mixing rates used are shown in Table 2 below which also summarizes the apparent density values measured at t = 0 (on the fresh dough) and on the cured mortar after 28 days.
Figure imgf000014_0001
Figure imgf000014_0001
Tableau 2  Table 2
Les données ci-dessus montrent que les compositions selon la présente invention permettent d'obtenir des mortiers allégés dont la densité reste faible après durcissement, attestant d'une bonne stabilité de la pâte dans le temps. The above data show that the compositions according to the present invention make it possible to obtain lightened mortars whose density remains low after hardening, attesting to good stability of the dough over time.
Les résistances en compression à 28 jours des mortiers C2, C5 et C6 ont été mesurées et valent respectivement 0,46 MPa, 0 ,67MPa et 0,61 MPa.  The compressive strengths at 28 days of the C2, C5 and C6 mortars were measured and are respectively 0.46 MPa, 0.67 MPa and 0.61 MPa.
Exemple 4 Example 4
Une composition proche de la composition C2 donc à base de ciment sulfoalumineux ALICEM® est préparée en mélangeant :  A composition close to the composition C2 thus based on ALICEM® sulfoaluminous cement is prepared by mixing:
-43 % en poids de perlite Silcell 42/ 18 (perlite hydrophobée d'un diamètre moyen d'environ 45 μητι et de masse volumique apparente d'environ 130 kg/m3) -43% by weight of Silcell 42/18 perlite (hydrophobic perlite with an average diameter of approximately 45 μητι and an apparent density of approximately 130 kg / m 3 )
-22 % en poids de perlite Silcell 42 BC (perlite non hydrophobée d'un diamètre moyen d'environ 45 μητι et de masse volumique apparente d'environ 130 kg/m3) -22% by weight of Silcell 42 BC perlite (non-hydrophobized perlite with an average diameter of approximately 45 μm and a bulk density of approximately 130 kg / m 3 )
-28.66% en poids de ciment sulfoalumineux ALICEM®  -28.66% by weight of ALICEM® sulfoaluminous cement
-5% en poids de résine type copolymère d'acétate de vinyle, de versatate de vinyle et d'ester maléique (Hexion)  -5% by weight of resin type copolymer of vinyl acetate, vinyl versatate and maleic ester (Hexion)
-0.6 % en poids de méthylhydroxyéthylcellulose de grade 100 000 mPa.s (Shinetsu)  -0.6% by weight of methylhydroxyethylcellulose grade 100 000 mPa.s (Shinetsu)
-0.6% en poids de laurylsulfate de sodium -0.14 % en poids de carbonate de lithium -0.6% by weight of sodium lauryl sulphate -0.14% by weight of lithium carbonate
Cette composition est gâchée (taux de gâchage de 160%) dans le malaxeur décrit ci-avant. On fait varier la durée de malaxage de façon à faire varier la quantité d'air entraîné. Des mesures de masse volumique apparente de la pâte à tO, ainsi que sur le mortier durci à 28 jours sont consignées dans le tableau 3 ci-dessous. La résistance en compression à 28 jours est également indiquée en MPa. This composition is spoiled (mixing rate of 160%) in the kneader described above. The mixing time is varied so as to vary the amount of entrained air. Apparent density measurements of the paste at 100, as well as the hardened mortar at 28 days are shown in Table 3 below. The compressive strength at 28 days is also indicated in MPa.
Figure imgf000015_0001
Figure imgf000015_0001
Tableau 3  Table 3
Ainsi on constate que plus le malaxage est prolongé, plus la quantité d'air entraîné est augmentée, tout en conservant une bonne stabilité de l'air entraîné dans le temps, même pour des durées de malaxage plus longues. Thus it is found that the longer the mixing is extended, the more the amount of entrained air is increased, while maintaining a good stability of the air entrained over time, even for longer mixing times.
Exemple 5 Example 5
La composition de l'exemple 4 est gâchée (taux de gâchage de 155%) et malaxée pendant 5 min avant d'être projetée sur un mur de parpaings avec une machine de type Putzmeister SP1 1 . Ce malaxage procure une pâte dont la masse volumique apparente est de 350 kg/m3 en cuve, de 356 kg/m3 en sortie de lance de projection et de 170 kg/m3 après durcissement au bout de 28 jours. La résistance en compression mesurée sur un échantillon de 4*4*4 cm après 28 jours est de 0.52 MPa et la conductivité thermique est de 52 mW/m. K. The composition of Example 4 is spoiled (mixing rate of 155%) and kneaded for 5 min before being projected onto a wall of breeze blocks with a Putzmeister SP1 type 1 machine. This mixing gives a paste whose bulk density is 350 kg / m 3 in the tank, 356 kg / m 3 at the projection lance outlet and 170 kg / m 3 after curing after 28 days. The compressive strength measured on a sample of 4 * 4 * 4 cm after 28 days is 0.52 MPa and the thermal conductivity is 52 mW / m. K.
Exemple 6 Example 6
La composition C8 est gâchée (taux de gâchage de 147%) et malaxée pendant 5 min avant d'être projetée sur un mur de parpaings avec une machine de type Putzmeister SP1 1 . Ce malaxage procure une pâte dont la masse volumique apparente est de 380 kg/m3 en cuve, de 320 kg/m3 en sortie de lance de projection et de 155 kg/m3 après durcissement au bout de 28 jours. La résistance en compression mesurée sur un échantillon de 4*4*4 cm après 28 jours est de 0.42 MPa et la conductivité thermique est de 49 mW/m. K. Exemple 7 The composition C8 is spoiled (mixing rate of 147%) and kneaded for 5 min before being projected onto a wall of blocks with a Putzmeister SP1 type machine 1. This mixing gives a paste whose bulk density is 380 kg / m 3 tank, 320 kg / m 3 by spraying lance outlet and 155 kg / m 3 after curing at 28 days. The compressive strength measured on a sample of 4 * 4 * 4 cm after 28 days is 0.42 MPa and the thermal conductivity is 49 mW / m. K. Example 7
La composition de l'exemple 4 est projetée avec une machine à gâchage continu de type Mtec M330. Le débit d'eau est de 250 l/h. La masse volumique apparente de la pâte mesurée en sortie de lance est de 380 kg/m3, ce qui est tout à fait comparable avec les valeurs obtenues avec des machines à gâchage discontinu. The composition of Example 4 is projected with a continuous mixing machine of the Mtec M330 type. The water flow is 250 l / h. The bulk density of the slurry measured at the outlet of lance is 380 kg / m 3, which is quite comparable with the values obtained with batch mixing machines.

Claims

REVENDICATIONS
Composition pour mortier isolant thermiquement caractérisée en ce qu'elle est exempte de granulats siliceux, calcaires et/ou silico- calcaires d'une granulométrie supérieure à 100 m et en ce qu'elle comprend un mélange d'au moins : Thermally insulating mortar composition characterized in that it is free of siliceous, calcareous and / or silico-calcareous granules with a particle size greater than 100 m and comprises a mixture of at least:
- 40% de charges allégeantes minérales dont la masse volumique apparente est inférieure à 200 kg/m3, - 40% of mineral lightening loads whose apparent density is less than 200 kg / m 3 ,
- un liant minéral choisi parmi les ciments sulfo-alumineux, les ciments alumineux et/ou les liants binaires ou ternaires comprenant au moins un ciment alumineux ou sulfoalumineux,  a mineral binder chosen from sulfo-aluminous cements, aluminous cements and / or binary or ternary binders comprising at least one aluminous or sulfoaluminous cement,
- un agent entraîneur d'air de type tensioactif choisi parmi les acides gras organiques, les composés sulfatés, les composés sulfonatés et/ou les résines naturelles du bois et  a surfactant-type air-entraining agent chosen from organic fatty acids, sulphated compounds, sulphonated compounds and / or natural resins of wood and
- un agent viscosant choisi parmi les alcools polyvinyliques, les éthers d'amidon, les éthers de cellulose, les éthers de guar ou les argiles. Composition selon la revendication précédente caractérisée en ce qu'elle comprend moins de 5 % en poids de fillers siliceux, calcaires et/ou silico-calcaires de granulométrie inférieure à 100 μιτι, ou plus préférentiellement est exempte de fillers siliceux, calcaires et/ ou silico-calcaires de granulométrie inférieure à 100 m.  a viscosing agent chosen from polyvinyl alcohols, starch ethers, cellulose ethers, guar ethers or clays. Composition according to the preceding claim characterized in that it comprises less than 5% by weight of siliceous fillers, limestone and / or silico-limestone particle size less than 100 μιτι, or more preferably is free of siliceous fillers, limestone and / or silico -calcium of particle size less than 100 m.
Composition selon l'une des revendications précédentes caractérisée en ce que les charges allégeantes minérales sont sphériques et ont un diamètre moyen inférieur ou égal à 80 m.  Composition according to one of the preceding claims, characterized in that the mineral lightening fillers are spherical and have an average diameter less than or equal to 80 m.
Composition selon l'une des revendications précédentes caractérisée en ce que les charges allégeantes sont choisies parmi la perlite, la vermiculite, les billes de verre expansé, les microsphères creuses de verre, les cénosphères, les silicates expansés, et/ou les aérogels.  Composition according to one of the preceding claims, characterized in that the lightening fillers are chosen from perlite, vermiculite, expanded glass beads, hollow glass microspheres, cenospheres, expanded silicates, and / or aerogels.
Composition selon l'une des revendications précédentes caractérisée en ce qu'elle comprend au moins 50% en poids de charges allégeantes minérales, préférentiellement au moins 60% en poids. Composition according to one of the preceding claims characterized in that it comprises at least 50% by weight of mineral lightening fillers, preferably at least 60% by weight.
6. Composition selon l'une des revendications précédentes caractérisée en ce que le liant binaire ou ternaire comprend moins de 30% en poids de ciment Portland et/ou de chaux par rapport au poids total de liant.6. Composition according to one of the preceding claims characterized in that the binary or ternary binder comprises less than 30% by weight of Portland cement and / or lime based on the total weight of binder.
7. Composition selon l'une des revendications précédentes caractérisée en ce qu'elle comprend au moins 0,3% en poids d'agent entraîneur d'air. 7. Composition according to one of the preceding claims characterized in that it comprises at least 0.3% by weight of air entraining agent.
8. Composition selon l'une des revendications précédentes caractérisée en ce l'agent entraîneur d'air est choisi parmi les alkylsulfates, les alkylsulfonates, les alkylarylsulfates, seuls ou en mélange.  8. Composition according to one of the preceding claims, characterized in that the air-entraining agent is chosen from alkyl sulphates, alkyl sulphonates, alkyl aryl sulphates, alone or as a mixture.
9. Composition selon la revendication précédente caractérisée en ce que l'agent entraîneur d'air est du laurylsulfate de sodium. 9. Composition according to the preceding claim characterized in that the air-entraining agent is sodium lauryl sulphate.
10. Composition selon l'une des revendications précédentes caractérisée en ce qu'elle comprend en outre un additif polymérique qui est un copolymère de type vinylique, de type acrylique et/ou dérivé d'acide carboxylique et plus préférentiellement un copolymère d'acétate de vinyle, de versatate de vinyle et d'acide et/ou ester méthacrylique , d'ester maléique, d'oléfine et/ou de chlorure de vinyle.  10. Composition according to one of the preceding claims characterized in that it further comprises a polymeric additive which is a copolymer of vinyl type, acrylic type and / or carboxylic acid derivative and more preferably a copolymer of acetate of vinyl, vinyl versatate and methacrylic acid and / or ester, maleic ester, olefin and / or vinyl chloride.
1 1 . Composition selon l'une des revendications précédentes caractérisée en ce que la quantité d'agent viscosant est comprise entre 0,01 % et 2% en poids.  1 1. Composition according to one of the preceding claims characterized in that the amount of viscosity agent is between 0.01% and 2% by weight.
12. Composition selon l'une des revendications précédentes caractérisée en ce qu'elle comprend en outre des agents rhéologiques tels que les plastifiants ou les superplastifiants, des agents rétenteurs d'eau, des agents épaississants, des agents de protection biocides et/ ou fongicides, des agents dispersants, des pigments, des accélérateurs et/ou retardateurs de prise, des agents hydrofuges, des fibres, de préférence dans une quantité comprise entre 0,01 % et 2% en poids. 12. Composition according to one of the preceding claims characterized in that it further comprises rheological agents such as plasticizers or superplasticizers, water-retaining agents, thickening agents, biocidal and / or fungicidal protective agents. , dispersing agents, pigments, accelerators and / or set retarders, water-repellent agents, fibers, preferably in an amount of between 0.01% and 2% by weight.
13. Procédé de préparation d'un matériau de construction à partir de la composition pour mortier selon l'une des revendications 1 à 12 caractérisé en ce qu'il comprend les étapes de : 13. Process for preparing a building material from the mortar composition according to one of claims 1 to 12, characterized in that it comprises the steps of:
-mélange de ladite composition avec l'eau de gâchage dans le mélangeur d'un dispositif de projection pour obtenir une pâte,  mixing said composition with the mixing water in the mixer of a projection device to obtain a paste,
-pompage de la pâte ainsi obtenue jusqu'à la lance du dispositif de projection, puis -projection sur le support. -pumping of the dough thus obtained to the lance of the projection device, then -projection on the support.
14. Procédé selon la revendication précédente caractérisé en ce que la durée de malaxage dans le mélangeur du dispositif de projection est comprise entre 15 secondes et 10 minutes.  14. Method according to the preceding claim characterized in that the mixing time in the mixer of the projection device is between 15 seconds and 10 minutes.
15. Matériau de construction allégé susceptible d'être obtenu par le procédé selon l'une des revendications 13 ou 14 ou par gâchage avec de l'eau de la composition selon l'une des revendications 1 à 12 et possédant une conductivité thermique inférieure ou égale à 55 mW/m. K. et une résistance en compression à 28 jours d'au moins 0,40 MPa.  15. Lightened construction material obtainable by the method according to one of claims 13 or 14 or by mixing with water of the composition according to one of claims 1 to 12 and having a lower thermal conductivity or equal to 55 mW / m. K. and a compressive strength at 28 days of at least 0.40 MPa.
16. Utilisation du matériau selon la revendication précédente en tant que chape, sous-enduit mural, plafond, matériau de remplissage de blocs de maçonnerie isolant, matériau de remplissage de vides interstitiels ou de cavités murales.  16. Use of the material according to the preceding claim as a screed, under-wall, ceiling, insulating masonry block filling material, interstitial voids filling material or wall cavities.
PCT/FR2017/050781 2016-04-13 2017-04-04 Highly lightweight and thermally insulating mortar composition WO2017178729A1 (en)

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BR112018068834A BR112018068834A2 (en) 2016-04-13 2017-04-04 highly reduced weight mortar composition and thermal insulator

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FR1653255A FR3050203B1 (en) 2016-04-13 2016-04-13 COMPOSITION OF HIGHLY LIGHTWEIGHT MORTAR AND THERMAL INSULATION

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108249868A (en) * 2018-04-24 2018-07-06 王亮 Thermal insulation mortar for building
CN112441808A (en) * 2020-11-17 2021-03-05 国佳新材湖北环保凝胶产业园有限公司 Aerogel building block and preparation method thereof

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FR3096365B1 (en) * 2019-05-24 2021-09-03 Saint Gobain Weber Dry composition of mortar, especially adhesive mortar for tile adhesive
DE202019103866U1 (en) * 2019-07-12 2020-09-09 Franken Maxit Mauermörtel Gmbh & Co Dry plaster mixture for sprayable insulation
CN111825391B (en) * 2020-07-07 2022-04-15 中建商品混凝土有限公司 Light high-strength self-insulation concrete for prefabricated building
CN113735495A (en) * 2021-08-20 2021-12-03 上海隆振建筑工程股份有限公司 Colored high-strength thermal insulation mortar
CN113735543A (en) * 2021-08-26 2021-12-03 苏州弗克技术股份有限公司 Lightweight plastering gypsum mortar and preparation method thereof
CN114195450B (en) * 2021-12-08 2022-07-26 亚士创能科技(上海)股份有限公司 Waterproof leveling mortar and preparation method and application thereof
CN114804718A (en) * 2022-04-25 2022-07-29 苏州北清力生纳米新材料科技有限公司 Nano aerogel building material and preparation method thereof
CN115849847A (en) * 2022-11-18 2023-03-28 贵州开磷集团股份有限公司 Anti-cracking phosphogypsum-based light material
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10314879A1 (en) * 2003-04-01 2004-10-14 Heinrich, Jörg Lightweight concrete and process for its manufacture
CN102093020A (en) * 2010-12-03 2011-06-15 吉林省志惠防腐保温工程有限公司 Special light-weight fireproof waterproof thermal-insulation slurry for polyurethane (PU)
FR2955103A1 (en) 2010-01-13 2011-07-15 Parexlanko FOAMING ADJUVANT FOR THE PREPARATION OF MINERAL FOAMS OF COATINGS, MORTARS AND CONCRETES, FOAMS OBTAINED THEREBY AND CURED PRODUCTS MADE THEREFROM
FR2955102A1 (en) * 2010-01-11 2011-07-15 Parexlanko INSULATING COATING BASED ON XEROGEL SILICA.
WO2013150148A1 (en) * 2012-04-06 2013-10-10 Lafarge Insulating mineral foam

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10314879A1 (en) * 2003-04-01 2004-10-14 Heinrich, Jörg Lightweight concrete and process for its manufacture
FR2955102A1 (en) * 2010-01-11 2011-07-15 Parexlanko INSULATING COATING BASED ON XEROGEL SILICA.
FR2955103A1 (en) 2010-01-13 2011-07-15 Parexlanko FOAMING ADJUVANT FOR THE PREPARATION OF MINERAL FOAMS OF COATINGS, MORTARS AND CONCRETES, FOAMS OBTAINED THEREBY AND CURED PRODUCTS MADE THEREFROM
CN102093020A (en) * 2010-12-03 2011-06-15 吉林省志惠防腐保温工程有限公司 Special light-weight fireproof waterproof thermal-insulation slurry for polyurethane (PU)
WO2013150148A1 (en) * 2012-04-06 2013-10-10 Lafarge Insulating mineral foam

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 201152, Derwent World Patents Index; AN 2011-J26219, XP002764719 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108249868A (en) * 2018-04-24 2018-07-06 王亮 Thermal insulation mortar for building
CN112441808A (en) * 2020-11-17 2021-03-05 国佳新材湖北环保凝胶产业园有限公司 Aerogel building block and preparation method thereof

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BR112018068834A2 (en) 2019-01-22
FR3050203B1 (en) 2021-07-23
EP3442929A1 (en) 2019-02-20
FR3050203A1 (en) 2017-10-20

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