WO2017174423A1 - Euv collector for use in an euv projection exposure apparatus - Google Patents

Euv collector for use in an euv projection exposure apparatus Download PDF

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Publication number
WO2017174423A1
WO2017174423A1 PCT/EP2017/057485 EP2017057485W WO2017174423A1 WO 2017174423 A1 WO2017174423 A1 WO 2017174423A1 EP 2017057485 W EP2017057485 W EP 2017057485W WO 2017174423 A1 WO2017174423 A1 WO 2017174423A1
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WO
WIPO (PCT)
Prior art keywords
light
euv
collector
extraneous
embodied
Prior art date
Application number
PCT/EP2017/057485
Other languages
French (fr)
Inventor
Holger Kierey
Johannes Zellner
Original Assignee
Carl Zeiss Smt Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carl Zeiss Smt Gmbh filed Critical Carl Zeiss Smt Gmbh
Priority to EP17714716.2A priority Critical patent/EP3440490A1/en
Priority to JP2018552243A priority patent/JP2019516129A/en
Publication of WO2017174423A1 publication Critical patent/WO2017174423A1/en
Priority to US16/136,453 priority patent/US10578972B2/en

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70008Production of exposure light, i.e. light sources
    • G03F7/70033Production of exposure light, i.e. light sources by plasma extreme ultraviolet [EUV] sources
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B19/00Condensers, e.g. light collectors or similar non-imaging optics
    • G02B19/0004Condensers, e.g. light collectors or similar non-imaging optics characterised by the optical means employed
    • G02B19/0019Condensers, e.g. light collectors or similar non-imaging optics characterised by the optical means employed having reflective surfaces only (e.g. louvre systems, systems with multiple planar reflectors)
    • G02B19/0023Condensers, e.g. light collectors or similar non-imaging optics characterised by the optical means employed having reflective surfaces only (e.g. louvre systems, systems with multiple planar reflectors) at least one surface having optical power
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B19/00Condensers, e.g. light collectors or similar non-imaging optics
    • G02B19/0033Condensers, e.g. light collectors or similar non-imaging optics characterised by the use
    • G02B19/0047Condensers, e.g. light collectors or similar non-imaging optics characterised by the use for use with a light source
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B19/00Condensers, e.g. light collectors or similar non-imaging optics
    • G02B19/0033Condensers, e.g. light collectors or similar non-imaging optics characterised by the use
    • G02B19/0095Condensers, e.g. light collectors or similar non-imaging optics characterised by the use for use with ultraviolet radiation
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/42Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect
    • G02B27/4233Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect having a diffractive element [DOE] contributing to a non-imaging application
    • G02B27/425Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect having a diffractive element [DOE] contributing to a non-imaging application in illumination systems
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/42Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect
    • G02B27/4294Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect in multispectral systems, e.g. UV and visible
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/08Mirrors
    • G02B5/0891Ultraviolet [UV] mirrors
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/18Diffraction gratings
    • G02B5/1814Diffraction gratings structurally combined with one or more further optical elements, e.g. lenses, mirrors, prisms or other diffraction gratings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/18Diffraction gratings
    • G02B5/1838Diffraction gratings for use with ultraviolet radiation or X-rays
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/18Diffraction gratings
    • G02B5/1861Reflection gratings characterised by their structure, e.g. step profile, contours of substrate or grooves, pitch variations, materials
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70058Mask illumination systems
    • G03F7/7015Details of optical elements
    • G03F7/70175Lamphouse reflector arrangements or collector mirrors, i.e. collecting light from solid angle upstream of the light source
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70483Information management; Active and passive control; Testing; Wafer monitoring, e.g. pattern monitoring
    • G03F7/7055Exposure light control in all parts of the microlithographic apparatus, e.g. pulse length control or light interruption
    • G03F7/70575Wavelength control, e.g. control of bandwidth, multiple wavelength, selection of wavelength or matching of optical components to wavelength

Definitions

  • EUV collector for use in an EUV projection exposure apparatus
  • the invention relates to an EUV collector for use in an EUV projection exposure apparatus. Further, the invention relates to an illumination system comprising such a collector, an optical system comprising such an illumination system, a projection exposure apparatus comprising such an optical system, a method for producing a microstructured or nanostructured component and a microstructured or nanostructured component produced by this method.
  • the extraneous light radiation may be pump light reflected by the plasma source region, said pump light serving to generate a plasma in the plasma source region.
  • the extraneous light radiation relates to radiation components of the pump light. According to the invention, it has been identified that it is not necessary to design an entire used light portion of the overall impingement surface of the collector to also suppress extraneous light. In particular, it is not necessary to provide an entire collector surface with a diffraction grating for extraneous light suppression.
  • the production costs of the EUV collec- tor may also be reduced by virtue of not the entire used light portion of the overall impingement surface of the collector also being designed for extraneous light suppression.
  • the diversion of the extraneous light portion may be carried out by guiding the extraneous light to an extraneous light trap, by guiding the extraneous light to a different extraneous light use and by absorbing or dissipating the extraneous light.
  • the extraneous light portion embodied as diffraction grating for the extraneous light radiation may be embodied as a laminar grating.
  • the diffraction grating may be embodied as a blazed grating.
  • the diffraction grating may be produced by material- ablating processing or by etching, in particular by mask etching.
  • a diffrac- tion efficiency of the diffraction grating may be very low in the zero order.
  • a suppression of the diffraction grating i.e. a ratio between a diffraction efficiency in the zero order and a diffraction efficiency in higher orders, may be less than 1/100 and, in particular, may be 1/1000.
  • An extent ratio according to Claim 2 ensures a particularly high collector efficiency.
  • An extent ratio between the extraneous light portion and the used light portion may be at most 25%, may be at most 20%, may be at most 15% and may also be even smaller.
  • An extraneous light portion embodied as a sub-portion of the used light portion according to Claim 3 constitutes a sub-portion of the overall impingement surface and, at the same time, serves to guide the EUV used light and to be impinged upon by extraneous light radiation.
  • the re- maining overall impingement surface outside of the extraneous light portion in particular, is embodied exclusively to guide the EUV used light and may have a particularly high reflection efficiency there.
  • the extraneous light portion is not used to guide the EUV used light in the case of a separation between the extraneous light portion and the used light portion according to Claim 5. There is no need to consider a reflection efficiency for the used light there, which reduces the production costs. In particular, there is no need for a reflection grating at the location of the extraneous light portion.
  • the extraneous light portion may be embodied as an opening in the used light portion. Such an embodiment of the extraneous light portion as opening in the used light portion leads to a particularly cost-effective collector.
  • the extraneous light portion may then constitute a passage opening for the extraneous light radiation.
  • the extraneous light radiation may then be di- verted after passage through this passage opening by way of an extraneous light trap.
  • the used light portion may be distributed among at least two separate col- lector components, with the extraneous light portion being embodied as interstice between the at least two collector components.
  • Such an extraneous light portion embodied as interstice between at least two collector components increases the design options when designing the collector.
  • An embodiment of the extraneous light portion as portion of the overall impingement surface absorbing the extraneous light according to Claim 6 likewise leads to a collector which is producible in a cost-effective manner.
  • the extraneous light portion may also be realized by a stop on the overall impingement surface or by an extraneous light scattering portion on the overall impingement surface or by an extraneous light reflection portion on the overall impingement surface.
  • An embodiment of the used light portion according to Claim 7 leads to a collector which is producible in a comparatively cost-effective manner and which is also referred to as normal incidence (NI) collector.
  • the collector may be embodied as an NI collector.
  • a pump light passage opening according to Claim 8 simplifies pump light coupling into the plasma source region.
  • the pump light passage opening may be embodied within an extraneous light portion embodied as an open- ing in the used light portion and may then e.g. form part of an extraneous light passage opening.
  • An extraneous light portion in the region of a pump light impact zone ac- cording to Claim 9 leads to particularly efficient arrangement since extraneous light is diverted where it mainly is incident on the EUV collector during the operation thereof.
  • the extraneous light portion may be arranged in a non- rotationally symmetric manner in relation to this axis of symmetry.
  • a cen- troid of the extraneous light portion may then have a lateral offset in relation to an intersection point of the axis of symmetry with the overall im- pingement surface or the used light portion.
  • An efficient extraneous light diversion applies, in particular, to a configuration of the extraneous light portion according to Claim 10.
  • the advantages of an illumination system according to Claim 1 1 , of an optical system according to Claim 12, of a projection exposure apparatus according to Claim 13, of a production method according to Claim 14 and of a microstmctured or nanostmctured component according to Claim 15 correspond to those which have already been explained above with reference to the collector according to the invention.
  • a semiconductor component for example a memory chip
  • a projection exposure apparatus for example a projection exposure apparatus.
  • Exemplary embodiments of the invention are explained in more detail below on the basis of the drawing. In detail:
  • Figure 1 schematically shows a projection exposure apparatus for
  • Figure 2 shows details of a light source of the projection exposure apparatus in the surroundings of an EUV collector for guiding EUV used light from a plasma source region to a field facet mirror of an illumination optical unit of the pro jection exposure apparatus, with the EUV collector being depicted in a meridional section;
  • Figure 3 schematically shows beam guiding of pump light from a pump light source of the EUV light source of the projection exposure apparatus
  • Figure 4 shows a plan view of the EUV collector, as seen from the direction of view IV in Figure 3;
  • Figure 5 shows, in an illustration similar to Figure 4, a further embodiment of an EUV collector
  • Figure 6 shows, in an illustration similar to Figure 4, a further embodiment of an EUV collector
  • Figures 7 to 9 show, in illustrations similar to Figures 4 to 6, further embodiments of an EUV collector;
  • Figure 10 shows, in a meridional section, a further embodiment of an EUV collector comprising two separate collector components, with beam guiding for the pump light additionally being depicted;
  • FIG 1 1 shows, in an illustration similar to Figure 10, a further embodiment of the EUV collector, including beam guiding of the pump light.
  • a projection exposure apparatus 1 for microlithography comprises a light source 2 for illumination light and/or imaging light 3, which will be explained in yet more detail below.
  • the light source 2 is an EUV light source, which produces light in a wavelength range of e.g. between 5 nm and 30 nm, in particular between 5 nm and 15 nm.
  • the illumination light and/or imaging light 3 is also referred to as EUV used light below.
  • the light source 2 may be a light source with a wavelength of 13.5 nm or a light source with a wavelength of 6.9 nm. Other EUV wavelengths are also possible.
  • a beam path of the illumination light 3 is depicted very schematically in Figure 1.
  • An illumination optical unit 6 serves to guide the illumination light 3 from the light source 2 to an object field 4 in an object plane 5.
  • Said illumination optical unit comprises a field facet mirror FF depicted very schematically in Figure 1 and a pupil facet mirror PF disposed downstream in the beam path of the illumination light 3 and likewise depicted very schematically.
  • a field- forming mirror 6b for grazing incidence (GI mirror; grazing incidence mirror) is arranged in the beam path of the illumination light 3 between the pupil facet mirror PF, which is arranged in a pupil plane 6a of the illumina- tion optical unit, and the object field 4.
  • GI mirror grazing incidence mirror
  • Pupil facets (not depicted in any more detail) of the pupil facet mirror PF are part of a transfer optical unit, which transfer, and in particular image, field facets (likewise not depicted) of the field facet mirror FF into the object field 4 in a manner superposed on one another.
  • a transfer optical unit which transfer, and in particular image, field facets (likewise not depicted) of the field facet mirror FF into the object field 4 in a manner superposed on one another.
  • An embodiment known from the prior art may be used for the field facet mirror FF on the one hand and the pupil facet mirror PF on the other hand.
  • such an illumination optical unit is known from DE 10 2009 045 096 Al .
  • the object field 4 is imaged into an image field 8 in an image plane 9 with a predetermined reduction scale.
  • Projection optical units which may be used to this end are known from e.g. DE 10 2012 202 675 Al .
  • a Cartesian xyz-coordinate system is indicated in the drawing, from which system the respective positional relationship of the components illustrated in the figures is evident.
  • the x-direction runs perpendicular to the plane of the drawing into the latter.
  • the y-direction extends to the left in Figure 1 and the z-direction extends upward in Figure 1.
  • the object plane 5 extends parallel to the xy-plane.
  • the object field 4 and the image field 8 are rectangular. Alternatively, it is also possible for the object field 4 and the image field 8 to have a bent or curved embodiment, that is to say, in particular, a partial ring shape.
  • the object field 4 and the image field 8 have an x/y-aspect ratio of greater than 1. Therefore, the object field 4 has a longer object field dimension in the x- direction and a shorter object field dimension in the y-direction. These object field dimensions extend along the field coordinates x and y.
  • One of the exemplary embodiments known from the prior art may be used for the projection optical unit 7. What is imaged in this case is a section of a reflection mask 10, also referred to as reticle, coinciding with the object field 4.
  • the reticle 10 is carried by a reticle holder 10a.
  • the reticle holder 10a is displaced by a reticle displacement drive 10b.
  • the imaging by way of the projection optical unit 7 is implemented on the surface of a substrate 1 1 in the form of a wafer, which is carried by a substrate holder 12.
  • the substrate holder 12 is displaced by a wafer or substrate displacement drive 12a.
  • Figure 1 schematically illustrates, between the reticle 10 and the projection optical unit 7, a ray beam 13 of the illumination light 3 that enters into said projection optical unit and, between the projection optical unit 7 and the substrate 1 1, a ray beam 14 of the illumination light 3 that emerges from the projection optical unit 7.
  • An image field-side numerical aperture (NA) of the projection optical unit 7 is not reproduced to scale in Figure 1.
  • the projection exposure apparatus 1 is of the scanner type. Both the reticle 10 and the substrate 1 1 are scanned in the y-direction during the operation of the projection exposure apparatus 1.
  • Figure 2 shows details of the light source 2.
  • the light source 2 is an LPP (laser produced plasma) source.
  • LPP laser produced plasma
  • tin droplets 15 are generated as a continuous droplet sequence by a tin droplet generator 16.
  • a trajectory of the tin droplets 15 extends transversely to a main beam direction 17 of the EUV used light 3.
  • the tin droplets 15 drop freely between the tin droplet generator 16 and a tin capturing device 18, with said droplets passing through a plasma source region 19.
  • the EUV used light 3 is emitted by the plasma source region 19.
  • the pump light source 21 may be an infrared laser source in the form of e.g. a CO 2 laser.
  • a different I laser source is also possible, in particular a solid-state laser, for example an Nd:YAG laser.
  • the pump light 20 is transferred into the plasma source region 19 by way of a mirror 22, which may be a mirror that is tiltable in a controllable fashion, and by way of a focusing lens 23.
  • a plasma emitting the EUV used light 3 is generated by the pump light impingement from the tin droplet 15 arriving in the plasma source region 19.
  • a beam path of the EUV used light 3 is depicted in Figure 2 between the plasma source region 19 and the field facet mirror FF, to the extent that the EUV used light is reflected by a collector mirror 24, which is also referred to as EUV collector 24 below.
  • the EUV collector 24 comprises a central passage opening 25 for the pump light 20 focussed towards the plasma source region 19 by way of the focusing lens 23.
  • the collector 24 is embodied as an ellipsoid mirror and trans- fers the EUV used light 3 emitted by the plasma source region 19, which is arranged in an ellipsoid focus, to an intermediate focus 26 of the EUV used light 3, which is arranged in the other ellipsoid focus of the collector 24.
  • the field facet mirror FF is disposed downstream of the intermediate focus
  • the EUV collector 24 and further components of the light source 2, which may be the tin droplet generator 16, the tin capturing device 18 and the focusing lens 23, are arranged in a vacuum housing 27.
  • the vacuum housing 27 The vacuum housing
  • Figure 3 shows a beam path of the pump light 20 between the focusing lens 23 and the passage opening 28 in the vacuum housing 27 only partly depicted in Figure 3.
  • the pump light 20 focussed by the focusing lens 23 is partly reflected in the plasma source region 19 in the form of a pump light component 31 by the tin droplet 15 entering into this plasma source region 19 and, possibly, by already created plasma.
  • This tin droplet 15 is present in a form which does not reflect the pump light component 31 reflected by the tin droplet back into itself.
  • the reflected pump light component 31 leaves the tin droplet with an angle of reflection which may lie in the range between 5° and 35° and which is approximately 20° in the exemplary embodiment depicted in Figure 3.
  • the pump light component 31 reflected by the tin droplet 15 is incident on the EUV collector 24 in a pump light impact zone 32 which is decentred in relation to the pump light passage opening 25.
  • An optical diffraction grating 33 for the pump light 20 is applied to the EUV collector 24 in a manner completely covering said pump light impact zone 32.
  • an overall impingement surface 34 of the collector 24, which is em- bodied for impingement with radiation emitted by the plasma source region 19, comprises a used light portion 35 on the one hand and an extraneous light portion 36 on the other hand.
  • the used light portion 35 of the overall impingement surface 34 of the collector 24 is embodied to guide the EUV used light 3 and coincides with the overall impingement surface 34 of the collector 24 in the embodiment according to Figure 4.
  • the extraneous light portion 36 of the overall impingement surface 34 is embodied for impingement with extraneous light radiation, i.e. for impingement with radiation, in particular having the wavelength of the pump light 20, which differs from the wavelength of the EUV used light 3.
  • the pump light compo- nent 31 is an example of this extraneous light radiation.
  • the extraneous light portion 36 coincides with the extent of the diffraction grating 33.
  • the used light portion 35 and the extraneous light portion 36 are not con- gruent since the extraneous light portion 36 only covers part of the used light portion 35.
  • the extraneous light portion 36 has an area of extent which is at most 50% of the area of extent of the used light portion 35. This ratio of extent may also be smaller and, for example, be 25% or 10%.
  • the extraneous light portion 36 i.e. an edge contour of the diffraction grating 33, has an elliptic embodiment and covers the pump light passage opening 25 over the entire circumference thereof and, at the other end, extends up to the edge of the overall impingement surface 34.
  • a different course of the edge contour of the diffraction grating 33 is also possible, in particular as is still to be explained in conjunction with the following collector embodiments.
  • the overall impingement surface 34 is embodied without diffraction grating and, in particular, as an unstructured reflection surface for the EUV used light.
  • the diffraction grating 33 is embodied as a laminar grating, i.e. as a grating with a right-angled profile structure, with profile troughs having the same extent as profile peaks.
  • the diffraction grating 33 may also be embodied as a blazed grating, but this is not depicted in the drawing.
  • the function of the diffraction grating 33 is indicated in Figure 3.
  • the pump light component 31 reflected by the tin droplet 15 is diffracted by the diffraction grating 33.
  • Figure 3 depicts the beam path of a + l st order 37 of the diffracted pump light and a -1st order 38 of the defracted pump light component 31.
  • These diffracted pump light components 37, 38 do not pass through the used light passage opening 28 but are diverted as extraneous light and absorbed by absorber structures 39 attached in the vacuum housing 27.
  • pump light exit openings may also be attached to the vacuum housing 27 in the region of the absorber structure 39, with the diffracted pump light components 37, 38 then being diverted in a targeted fashion after exit according to these pump light exit windows.
  • Figure 3 also schematically depicts the beam path of a 0th order of diffraction 40.
  • the diffraction efficiency of the diffraction grating 33 at this 0th order of diffraction 40 is lower by several orders of magni- tude than the diffraction efficiency in the +/- 1 st orders 37, 38.
  • a suppression ratio may lie at 1/100 up to 1/1000.
  • the diffracted pump light component passing through the used light passage opening 28 is negligibly small.
  • the diffraction grating 33 may be produced with the aid of material- ablating processing or by an etching method, in particular by mask etching.
  • the material-ablating method may be a turning method, in which a cutting tool is brought into engagement with the collector workpiece in the region of the diffraction grating 33 in a manner which is controlled and synchronized to the rotation of said workpiece, and otherwise disengaged again.
  • Lithographic methods or laser material processing by direct writing of the diffraction pattern using a material processing laser are further possible methods for producing the diffraction grating 33.
  • the lithographic methods may also include local moulding of a master structure by direct bringing into contact with the collector main body at the location of the diffraction grating 33.
  • the extraneous light portion 36 constitutes a sub-portion of the used light portion 35. Therefore, this sub- portion of the overall impingement surface 34 serves simultaneously to guide the EUV used light 3 and to be impinged upon by the pump light component 31, i.e. by the extraneous light radiation.
  • the remaining overall impingement surface 34 is embodied exclusively to guide the EUV used light. This avoids used light reflection losses on account of, in particular, an imperfection of the diffraction grating 33.
  • the collector 24 is embodied as a mirror for substantially perpendicular incidence (normal incidence mirror; NI mirror) of the EUV used light 3.
  • the used light portion 35 is embodied for incidence of the EUV used light 3 with an angle of incidence of at most 45°.
  • the collector 24 constitutes an illumination system of the projection exposure apparatus.
  • the illumination system constitutes an optical system of the projection exposure apparatus 1.
  • the extraneous light portion 36 is likewise present as a diffraction grating 33 in the form of a central stripe portion of the collector 24 which is round overall.
  • the used light portion 35 also includes an upper segment-shaped used light region 35a and a lower, likewise segment-shaped used light region 35b.
  • the stripe-shaped extraneous light portion 36 covers possible extraneous light impact zones which are indicated in a dashed fashion at 32a and 32b in Figure 5.
  • a further embodiment for the EUV collector 24, which may be used instead of the embodiment described above, is explained in the following text on the basis of Figure 6. Components and functions corresponding to those which were used above with reference to the embodiment according to Figures 1 to 5 have the same reference signs and are not discussed again in detail.
  • the extraneous light portion 36 once again embodied as a laminar diffraction grating 33, has a sector- shaped embodiment and covers a quarter of the overall impingement sur- face 34, i.e. an azimuth angle of 90°.
  • the extraneous light portion 41 is embodied as an opening in the used light portion 35.
  • the extraneous light portion 41 constitutes a passage opening for the pump light component 31, i.e. for the extraneous light radiation.
  • the pump light component 31 may then be diverted or dissipated by way of an extraneous light trap (cf. the extraneous light trap 42 in Figure 3 indicated by dashed lines) arranged downstream of the EUV collector 24.
  • This passage opening of the extraneous light portion 41 according to Figure 7 has an elliptic inner contour which corresponds to the elliptic edge contour of the diffraction grating 33 of the extraneous light portion 36 of the EUV collector 24 according to Figure 4.
  • the used light portion 35 is distributed among two separate collector components 24a, 24b, which each have a segment form and, in respect of the arrangement thereof, correspond to the used light portions 35a, 35b of the EUV collector 24 according to Figure 5.
  • the extraneous light portion 36 is embodied as a circular-sector-shaped cut-out in the otherwise round EUV collector 24.
  • the arrangement and the extent of the extraneous light portion 41 according to Figure 9 corresponds to that of the extraneous light portion according to Figure 6.
  • Figure 10 shows a further embodiment of an EUV collector 24 which comprises two collector components 24a and 24b which, together, form an ellipsoid mirror.
  • Components and functions corresponding to those which were used above with reference to the embodiment according to Figures 1 to 9 have the same reference signs and are not discussed again in detail.
  • the tin droplet 15 which has entered into the plasma source region 19 is depicted in the focus closer to the mirror surface.
  • the extraneous light portion 41 is also embodied as an interstice between the two collector components 24a and 24b in the case of the EUV collector 24 according to Figure 10.
  • the pump light 20 is radiated inwards in such a way relative to the chief ray direction 17 of the EUV collector 24, i.e. a connecting line between the plasma source region 19 and the intermediate focus 26, that an angle bisector between the incident pump light 20 and the pump light component 31 reflected by the tin droplet 15 includes an angle with the chief ray direction 17 that is greater than 70°.
  • the collector components 24a, 24b have such an embodiment that, togeth- er, they cover a large solid angle range around the plasma source region 19, in particular a solid angle range which is greater than ⁇ , which is greater than 2 ⁇ and which may also be greater than 2.5 ⁇ .
  • FIG 1 1 shows a further embodiment of an EUV collector 24 which may be used in place of one of the variants of the EUV collector 24 described above.
  • Components and functions corresponding to those which were used above with reference to the embodiment according to Figures 1 to 10 have the same reference signs and are not discussed again in detail.
  • an extraneous light portion 43 is embodied as an absorbing portion of the overall impingement surface 34 of the EUV collector 24. From the tin droplet 15, which enters into the plasma source region 19, the pump light component 31 of the incident pump light 20 is reflected to the extraneous light portion 43 and absorbed there.
  • the extraneous light portion 43 may be thermally decoupled from the collector 24. Then, it is possible to dispense with complicated cooling of the collector 24.
  • a main body of the EUV collector 24 may be manufactured from aluminium. Alternative materials for this main body are copper, alloys containing copper and/or aluminium or alloys of copper and aluminium oxide produced by powder metallurgy.
  • the projection exposure apparatus 1 is used as follows: First, the reflection mask 10 or the reticle and the substrate or the wafer 1 1 are provided. Subsequently, a structure on the reticle 10 is projected onto a light-sensitive layer of the wafer 1 1 with the aid of the projection exposure apparatus 1. Then, a micro structure or nanostmcture on the wafer 1 1 , and hence the microstructured component, is produced by developing the light-sensitive layer.

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Abstract

An EUV collector (24) serves for use in an EUV projection exposure apparatus. The collector (24) is embodied to guide EUV used light, which is emitted by a plasma source region. An overall impingement surface (34) of the collector (24) is embodied for impingement with radiation (3, 31) emitted by the plasma source region consisting of both the EUV light and pump laser light. A used light portion (35) of the overall impingement surface (34) is embodied to guide the EUV used light (3). An extraneous light portion (36) of the overall impingement surface (34) is embodied to be impinged upon by extraneous pump laser light radiation reflected from the plasma source (31), the wavelength of which differs from that of the used light (3). The used light portion (35) and the extraneous light portion (36) are not congruent. This results in an EUV collector, the collector efficiency of which is increased and the production costs of which are possibly reduced. The zone fro reflection of laser light is covered by a suitable diffractive grating structure.

Description

EUV collector for use in an EUV projection exposure apparatus
The content of the German Patent Application DE 10 2016 205 893.2 is incorporated by reference herein.
The invention relates to an EUV collector for use in an EUV projection exposure apparatus. Further, the invention relates to an illumination system comprising such a collector, an optical system comprising such an illumination system, a projection exposure apparatus comprising such an optical system, a method for producing a microstructured or nanostructured component and a microstructured or nanostructured component produced by this method.
An EUV collector of the type set forth at the outset is known from
US 2013/0335816 Al and US 7 084 412 B2.
It is an object of the present invention to develop an EUV collector of the type set forth at the outset in such a way that the collector efficiency thereof is improved. Moreover, where possible, the production costs for the EUV collector should be reduced compared to the prior art.
According to the invention, this object is achieved by an EUV collector comprising the features specified in Claim 1. The extraneous light radiation may be pump light reflected by the plasma source region, said pump light serving to generate a plasma in the plasma source region. In particular, the extraneous light radiation relates to radiation components of the pump light. According to the invention, it has been identified that it is not necessary to design an entire used light portion of the overall impingement surface of the collector to also suppress extraneous light. In particular, it is not necessary to provide an entire collector surface with a diffraction grating for extraneous light suppression. Instead, it is sufficient to embody an extraneous light portion of the overall impinge- ment surface, which is not embodied congruent with the used light portion and which has the purpose of diverting extraneous light radiation and, in particular, of being impinged upon by extraneous light radiation. This increases a collector efficiency and, in particular, a used light throughput which may be obtained by the collector. This increased used light through- put may be obtained without an unwanted reduction of an extraneous light suppression by the collector. It is possible to avoid unwanted losses in the used light throughput, which emerge on account of imperfections of an extraneous light suppression by way of a diffraction grating embodied completely over the collector surface. The production costs of the EUV collec- tor may also be reduced by virtue of not the entire used light portion of the overall impingement surface of the collector also being designed for extraneous light suppression. The diversion of the extraneous light portion may be carried out by guiding the extraneous light to an extraneous light trap, by guiding the extraneous light to a different extraneous light use and by absorbing or dissipating the extraneous light. The extraneous light portion embodied as diffraction grating for the extraneous light radiation may be embodied as a laminar grating. The diffraction grating may be embodied as a blazed grating. The diffraction grating may be produced by material- ablating processing or by etching, in particular by mask etching. A diffrac- tion efficiency of the diffraction grating may be very low in the zero order. A suppression of the diffraction grating, i.e. a ratio between a diffraction efficiency in the zero order and a diffraction efficiency in higher orders, may be less than 1/100 and, in particular, may be 1/1000. An extent ratio according to Claim 2 ensures a particularly high collector efficiency. An extent ratio between the extraneous light portion and the used light portion may be at most 25%, may be at most 20%, may be at most 15% and may also be even smaller.
An extraneous light portion embodied as a sub-portion of the used light portion according to Claim 3 constitutes a sub-portion of the overall impingement surface and, at the same time, serves to guide the EUV used light and to be impinged upon by extraneous light radiation. Then, the re- maining overall impingement surface outside of the extraneous light portion, in particular, is embodied exclusively to guide the EUV used light and may have a particularly high reflection efficiency there.
In a configuration of the collector according to Claim 4, reflection losses of the EUV used light are minimized.
The extraneous light portion is not used to guide the EUV used light in the case of a separation between the extraneous light portion and the used light portion according to Claim 5. There is no need to consider a reflection efficiency for the used light there, which reduces the production costs. In particular, there is no need for a reflection grating at the location of the extraneous light portion. The extraneous light portion may be embodied as an opening in the used light portion. Such an embodiment of the extraneous light portion as opening in the used light portion leads to a particularly cost-effective collector. The extraneous light portion may then constitute a passage opening for the extraneous light radiation. The extraneous light radiation may then be di- verted after passage through this passage opening by way of an extraneous light trap.
The used light portion may be distributed among at least two separate col- lector components, with the extraneous light portion being embodied as interstice between the at least two collector components. Such an extraneous light portion embodied as interstice between at least two collector components increases the design options when designing the collector. An embodiment of the extraneous light portion as portion of the overall impingement surface absorbing the extraneous light according to Claim 6 likewise leads to a collector which is producible in a cost-effective manner. The extraneous light portion may also be realized by a stop on the overall impingement surface or by an extraneous light scattering portion on the overall impingement surface or by an extraneous light reflection portion on the overall impingement surface.
An embodiment of the used light portion according to Claim 7 leads to a collector which is producible in a comparatively cost-effective manner and which is also referred to as normal incidence (NI) collector. Overall, the collector may be embodied as an NI collector. Alternatively, it is possible to design at least one sub-unit of the collector as an NI unit, wherein at least one further sub-unit is then also embodied as a sub-unit for the incidence of the EUV used light with an angle of incidence greater than 45° (grazing incidence impingement; GI unit).
A pump light passage opening according to Claim 8 simplifies pump light coupling into the plasma source region. The pump light passage opening may be embodied within an extraneous light portion embodied as an open- ing in the used light portion and may then e.g. form part of an extraneous light passage opening.
An extraneous light portion in the region of a pump light impact zone ac- cording to Claim 9 leads to particularly efficient arrangement since extraneous light is diverted where it mainly is incident on the EUV collector during the operation thereof.
To the extent that the overall impingement surface or the used light portion of the collector has a rotationally symmetric embodiment in respect of an axis of symmetry, the extraneous light portion may be arranged in a non- rotationally symmetric manner in relation to this axis of symmetry. A cen- troid of the extraneous light portion may then have a lateral offset in relation to an intersection point of the axis of symmetry with the overall im- pingement surface or the used light portion.
An efficient extraneous light diversion applies, in particular, to a configuration of the extraneous light portion according to Claim 10. The advantages of an illumination system according to Claim 1 1 , of an optical system according to Claim 12, of a projection exposure apparatus according to Claim 13, of a production method according to Claim 14 and of a microstmctured or nanostmctured component according to Claim 15 correspond to those which have already been explained above with reference to the collector according to the invention.
In particular, a semiconductor component, for example a memory chip, may be produced using the projection exposure apparatus. Exemplary embodiments of the invention are explained in more detail below on the basis of the drawing. In detail:
Figure 1 schematically shows a projection exposure apparatus for
EUV microlithography;
Figure 2 shows details of a light source of the projection exposure apparatus in the surroundings of an EUV collector for guiding EUV used light from a plasma source region to a field facet mirror of an illumination optical unit of the pro jection exposure apparatus, with the EUV collector being depicted in a meridional section;
Figure 3 schematically shows beam guiding of pump light from a pump light source of the EUV light source of the projection exposure apparatus;
Figure 4 shows a plan view of the EUV collector, as seen from the direction of view IV in Figure 3;
Figure 5 shows, in an illustration similar to Figure 4, a further embodiment of an EUV collector;
Figure 6 shows, in an illustration similar to Figure 4, a further embodiment of an EUV collector;
Figures 7 to 9 show, in illustrations similar to Figures 4 to 6, further embodiments of an EUV collector; Figure 10 shows, in a meridional section, a further embodiment of an EUV collector comprising two separate collector components, with beam guiding for the pump light additionally being depicted; and
Figure 1 1 shows, in an illustration similar to Figure 10, a further embodiment of the EUV collector, including beam guiding of the pump light. A projection exposure apparatus 1 for microlithography comprises a light source 2 for illumination light and/or imaging light 3, which will be explained in yet more detail below. The light source 2 is an EUV light source, which produces light in a wavelength range of e.g. between 5 nm and 30 nm, in particular between 5 nm and 15 nm. The illumination light and/or imaging light 3 is also referred to as EUV used light below.
In particular, the light source 2 may be a light source with a wavelength of 13.5 nm or a light source with a wavelength of 6.9 nm. Other EUV wavelengths are also possible. A beam path of the illumination light 3 is depicted very schematically in Figure 1.
An illumination optical unit 6 serves to guide the illumination light 3 from the light source 2 to an object field 4 in an object plane 5. Said illumination optical unit comprises a field facet mirror FF depicted very schematically in Figure 1 and a pupil facet mirror PF disposed downstream in the beam path of the illumination light 3 and likewise depicted very schematically. A field- forming mirror 6b for grazing incidence (GI mirror; grazing incidence mirror) is arranged in the beam path of the illumination light 3 between the pupil facet mirror PF, which is arranged in a pupil plane 6a of the illumina- tion optical unit, and the object field 4. Such a GI mirror 6b is not mandatory.
Pupil facets (not depicted in any more detail) of the pupil facet mirror PF are part of a transfer optical unit, which transfer, and in particular image, field facets (likewise not depicted) of the field facet mirror FF into the object field 4 in a manner superposed on one another. An embodiment known from the prior art may be used for the field facet mirror FF on the one hand and the pupil facet mirror PF on the other hand. By way of example, such an illumination optical unit is known from DE 10 2009 045 096 Al .
Using a projection optical unit or imaging optical unit 7, the object field 4 is imaged into an image field 8 in an image plane 9 with a predetermined reduction scale. Projection optical units which may be used to this end are known from e.g. DE 10 2012 202 675 Al .
In order to facilitate the description of the projection exposure apparatus 1 and the various embodiments of the projection optical unit 7, a Cartesian xyz-coordinate system is indicated in the drawing, from which system the respective positional relationship of the components illustrated in the figures is evident. In Figure 1 , the x-direction runs perpendicular to the plane of the drawing into the latter. The y-direction extends to the left in Figure 1 and the z-direction extends upward in Figure 1. The object plane 5 extends parallel to the xy-plane.
The object field 4 and the image field 8 are rectangular. Alternatively, it is also possible for the object field 4 and the image field 8 to have a bent or curved embodiment, that is to say, in particular, a partial ring shape. The object field 4 and the image field 8 have an x/y-aspect ratio of greater than 1. Therefore, the object field 4 has a longer object field dimension in the x- direction and a shorter object field dimension in the y-direction. These object field dimensions extend along the field coordinates x and y. One of the exemplary embodiments known from the prior art may be used for the projection optical unit 7. What is imaged in this case is a section of a reflection mask 10, also referred to as reticle, coinciding with the object field 4. The reticle 10 is carried by a reticle holder 10a. The reticle holder 10a is displaced by a reticle displacement drive 10b.
The imaging by way of the projection optical unit 7 is implemented on the surface of a substrate 1 1 in the form of a wafer, which is carried by a substrate holder 12. The substrate holder 12 is displaced by a wafer or substrate displacement drive 12a.
Figure 1 schematically illustrates, between the reticle 10 and the projection optical unit 7, a ray beam 13 of the illumination light 3 that enters into said projection optical unit and, between the projection optical unit 7 and the substrate 1 1, a ray beam 14 of the illumination light 3 that emerges from the projection optical unit 7. An image field-side numerical aperture (NA) of the projection optical unit 7 is not reproduced to scale in Figure 1.
The projection exposure apparatus 1 is of the scanner type. Both the reticle 10 and the substrate 1 1 are scanned in the y-direction during the operation of the projection exposure apparatus 1. A stepper type of the projection exposure apparatus 1, in which a stepwise displacement of the reticle 10 and of the substrate 1 1 in the y-direction is effected between individual exposures of the substrate 1 1, is also possible. These displacements are effected synchronously to one another by an appropriate actuation of the displacement drives 10b and 12a.
Figure 2 shows details of the light source 2.
The light source 2 is an LPP (laser produced plasma) source. For the purposes of producing plasma, tin droplets 15 are generated as a continuous droplet sequence by a tin droplet generator 16. A trajectory of the tin droplets 15 extends transversely to a main beam direction 17 of the EUV used light 3. Here, the tin droplets 15 drop freely between the tin droplet generator 16 and a tin capturing device 18, with said droplets passing through a plasma source region 19. The EUV used light 3 is emitted by the plasma source region 19. When the tin droplet 15 arrives in the plasma source region 19, it is impinged upon there by pump light 20 from a pump light source 21. The pump light source 21 may be an infrared laser source in the form of e.g. a CO2 laser. A different I laser source is also possible, in particular a solid-state laser, for example an Nd:YAG laser.
The pump light 20 is transferred into the plasma source region 19 by way of a mirror 22, which may be a mirror that is tiltable in a controllable fashion, and by way of a focusing lens 23. A plasma emitting the EUV used light 3 is generated by the pump light impingement from the tin droplet 15 arriving in the plasma source region 19. A beam path of the EUV used light 3 is depicted in Figure 2 between the plasma source region 19 and the field facet mirror FF, to the extent that the EUV used light is reflected by a collector mirror 24, which is also referred to as EUV collector 24 below. The EUV collector 24 comprises a central passage opening 25 for the pump light 20 focussed towards the plasma source region 19 by way of the focusing lens 23. The collector 24 is embodied as an ellipsoid mirror and trans- fers the EUV used light 3 emitted by the plasma source region 19, which is arranged in an ellipsoid focus, to an intermediate focus 26 of the EUV used light 3, which is arranged in the other ellipsoid focus of the collector 24. The field facet mirror FF is disposed downstream of the intermediate focus
26 in the beam path of the EUV used light 3, in the region of a far field of the EUV used light 3.
The EUV collector 24 and further components of the light source 2, which may be the tin droplet generator 16, the tin capturing device 18 and the focusing lens 23, are arranged in a vacuum housing 27. The vacuum housing
27 comprises a passage opening 28 in the region of the intermediate focus 26. In the region of an entrance of the pump light 20 into the vacuum housing 27, the latter comprises a pump light entrance window 29.
Figure 3 shows a beam path of the pump light 20 between the focusing lens 23 and the passage opening 28 in the vacuum housing 27 only partly depicted in Figure 3. The pump light 20 focussed by the focusing lens 23 is partly reflected in the plasma source region 19 in the form of a pump light component 31 by the tin droplet 15 entering into this plasma source region 19 and, possibly, by already created plasma. This tin droplet 15 is present in a form which does not reflect the pump light component 31 reflected by the tin droplet back into itself. The reflected pump light component 31 leaves the tin droplet with an angle of reflection which may lie in the range between 5° and 35° and which is approximately 20° in the exemplary embodiment depicted in Figure 3. The pump light component 31 reflected by the tin droplet 15 is incident on the EUV collector 24 in a pump light impact zone 32 which is decentred in relation to the pump light passage opening 25. An optical diffraction grating 33 for the pump light 20 is applied to the EUV collector 24 in a manner completely covering said pump light impact zone 32.
Thus, an overall impingement surface 34 of the collector 24, which is em- bodied for impingement with radiation emitted by the plasma source region 19, comprises a used light portion 35 on the one hand and an extraneous light portion 36 on the other hand. The used light portion 35 of the overall impingement surface 34 of the collector 24 is embodied to guide the EUV used light 3 and coincides with the overall impingement surface 34 of the collector 24 in the embodiment according to Figure 4. The extraneous light portion 36 of the overall impingement surface 34 is embodied for impingement with extraneous light radiation, i.e. for impingement with radiation, in particular having the wavelength of the pump light 20, which differs from the wavelength of the EUV used light 3. The pump light compo- nent 31 is an example of this extraneous light radiation. In the embodiment according to Figure 4, the extraneous light portion 36 coincides with the extent of the diffraction grating 33.
The used light portion 35 and the extraneous light portion 36 are not con- gruent since the extraneous light portion 36 only covers part of the used light portion 35. The extraneous light portion 36 has an area of extent which is at most 50% of the area of extent of the used light portion 35. This ratio of extent may also be smaller and, for example, be 25% or 10%. In the embodiment of the collector 24 according to Figure 4, the extraneous light portion 36, i.e. an edge contour of the diffraction grating 33, has an elliptic embodiment and covers the pump light passage opening 25 over the entire circumference thereof and, at the other end, extends up to the edge of the overall impingement surface 34. A different course of the edge contour of the diffraction grating 33 is also possible, in particular as is still to be explained in conjunction with the following collector embodiments.
Outside of the region of the diffraction grating 33, i.e. outside of the extra- neous light portion 36, the overall impingement surface 34 is embodied without diffraction grating and, in particular, as an unstructured reflection surface for the EUV used light.
The diffraction grating 33 is embodied as a laminar grating, i.e. as a grating with a right-angled profile structure, with profile troughs having the same extent as profile peaks. As an alternative to the design as a laminar grating, the diffraction grating 33 may also be embodied as a blazed grating, but this is not depicted in the drawing. The function of the diffraction grating 33 is indicated in Figure 3. The pump light component 31 reflected by the tin droplet 15 is diffracted by the diffraction grating 33. Figure 3 depicts the beam path of a + l st order 37 of the diffracted pump light and a -1st order 38 of the defracted pump light component 31. These diffracted pump light components 37, 38 do not pass through the used light passage opening 28 but are diverted as extraneous light and absorbed by absorber structures 39 attached in the vacuum housing 27. Alternatively, pump light exit openings may also be attached to the vacuum housing 27 in the region of the absorber structure 39, with the diffracted pump light components 37, 38 then being diverted in a targeted fashion after exit according to these pump light exit windows.
Additionally, Figure 3 also schematically depicts the beam path of a 0th order of diffraction 40. The diffraction efficiency of the diffraction grating 33 at this 0th order of diffraction 40 is lower by several orders of magni- tude than the diffraction efficiency in the +/- 1 st orders 37, 38. Here, a suppression ratio may lie at 1/100 up to 1/1000. Thus, the diffracted pump light component passing through the used light passage opening 28 is negligibly small.
The pump light 20, which has a wavelength which differs from that of the EUV pump light, is subsequently also referred to as extraneous light. Other radiation, the wavelength of which differs from the pump light wavelength and, at the same time, from the used light wavelength, may also constitute extraneous light which is suppressed by means of the collector 24.
The diffraction grating 33 may be produced with the aid of material- ablating processing or by an etching method, in particular by mask etching. The material-ablating method may be a turning method, in which a cutting tool is brought into engagement with the collector workpiece in the region of the diffraction grating 33 in a manner which is controlled and synchronized to the rotation of said workpiece, and otherwise disengaged again.
Lithographic methods or laser material processing by direct writing of the diffraction pattern using a material processing laser are further possible methods for producing the diffraction grating 33. The lithographic methods may also include local moulding of a master structure by direct bringing into contact with the collector main body at the location of the diffraction grating 33.
In the embodiment according to Figure 4, the extraneous light portion 36 constitutes a sub-portion of the used light portion 35. Therefore, this sub- portion of the overall impingement surface 34 serves simultaneously to guide the EUV used light 3 and to be impinged upon by the pump light component 31, i.e. by the extraneous light radiation. The remaining overall impingement surface 34 is embodied exclusively to guide the EUV used light. This avoids used light reflection losses on account of, in particular, an imperfection of the diffraction grating 33.
The collector 24 is embodied as a mirror for substantially perpendicular incidence (normal incidence mirror; NI mirror) of the EUV used light 3. Thus, the used light portion 35 is embodied for incidence of the EUV used light 3 with an angle of incidence of at most 45°.
With the illumination optical unit 6, the collector 24 constitutes an illumination system of the projection exposure apparatus. Together with the projection optical unit 7, the illumination system constitutes an optical system of the projection exposure apparatus 1.
A further embodiment for the EUV collector 24, which may be used instead of the embodiment described above, is explained in the following text on the basis of Figure 5. Components and functions corresponding to those which were used above with reference to the embodiment according to Figures 1 to 4 have the same reference signs and are not discussed again in detail.
In the EUV collector 24 according to Figure 5, the extraneous light portion 36 is likewise present as a diffraction grating 33 in the form of a central stripe portion of the collector 24 which is round overall. In addition to this stripe-shaped diffraction grating 33, the used light portion 35 also includes an upper segment-shaped used light region 35a and a lower, likewise segment-shaped used light region 35b. The stripe-shaped extraneous light portion 36 covers possible extraneous light impact zones which are indicated in a dashed fashion at 32a and 32b in Figure 5. A further embodiment for the EUV collector 24, which may be used instead of the embodiment described above, is explained in the following text on the basis of Figure 6. Components and functions corresponding to those which were used above with reference to the embodiment according to Figures 1 to 5 have the same reference signs and are not discussed again in detail.
In the EUV collector 24 according to Figure 6, the extraneous light portion 36, once again embodied as a laminar diffraction grating 33, has a sector- shaped embodiment and covers a quarter of the overall impingement sur- face 34, i.e. an azimuth angle of 90°.
Below, three further exemplary embodiments of EUV collectors 24, which are alternatives to one another in each case, are described on the basis of Figures 7 to 9; said exemplary embodiments may be used in place of the EUV collector according to Figures 4 to 6. Components and functions corresponding to those which were used above with reference to the embodiment according to Figures 1 to 6 have the same reference signs and are not discussed again in detail. In the EUV collector variants according to Figures 7 to 9, the respective extraneous light portion 41 constitutes a portion of an overall impingement surface 34 of the collector 24 which is separate from the used light portion 35 in each case. In the case of the EUV collectors 24 according to Figures 7 to 9, the extraneous light portion 41 is not used to guide the EUV used light 3 in each case. In the EUV collector 24 according to Figure 7, the extraneous light portion 41 is embodied as an opening in the used light portion 35. In this embodiment, the extraneous light portion 41 constitutes a passage opening for the pump light component 31, i.e. for the extraneous light radiation. The pump light component 31 may then be diverted or dissipated by way of an extraneous light trap (cf. the extraneous light trap 42 in Figure 3 indicated by dashed lines) arranged downstream of the EUV collector 24. This passage opening of the extraneous light portion 41 according to Figure 7 has an elliptic inner contour which corresponds to the elliptic edge contour of the diffraction grating 33 of the extraneous light portion 36 of the EUV collector 24 according to Figure 4. In the embodiment of the EUV collector according to Figure 8, the used light portion 35 is distributed among two separate collector components 24a, 24b, which each have a segment form and, in respect of the arrangement thereof, correspond to the used light portions 35a, 35b of the EUV collector 24 according to Figure 5.
In the EUV collector 24 according to Figure 9, the extraneous light portion 36 is embodied as a circular-sector-shaped cut-out in the otherwise round EUV collector 24. The arrangement and the extent of the extraneous light portion 41 according to Figure 9 corresponds to that of the extraneous light portion according to Figure 6.
In an illustration similar to Figure 3, Figure 10 shows a further embodiment of an EUV collector 24 which comprises two collector components 24a and 24b which, together, form an ellipsoid mirror. Components and functions corresponding to those which were used above with reference to the embodiment according to Figures 1 to 9 have the same reference signs and are not discussed again in detail. The tin droplet 15 which has entered into the plasma source region 19 is depicted in the focus closer to the mirror surface. In a manner comparable to the embodiment according to Figure 8, the extraneous light portion 41 is also embodied as an interstice between the two collector components 24a and 24b in the case of the EUV collector 24 according to Figure 10.
In the case of the EUV collector 24 according to Figure 10, the pump light 20 is radiated inwards in such a way relative to the chief ray direction 17 of the EUV collector 24, i.e. a connecting line between the plasma source region 19 and the intermediate focus 26, that an angle bisector between the incident pump light 20 and the pump light component 31 reflected by the tin droplet 15 includes an angle with the chief ray direction 17 that is greater than 70°.
The collector components 24a, 24b have such an embodiment that, togeth- er, they cover a large solid angle range around the plasma source region 19, in particular a solid angle range which is greater than π, which is greater than 2π and which may also be greater than 2.5π.
Figure 1 1 shows a further embodiment of an EUV collector 24 which may be used in place of one of the variants of the EUV collector 24 described above. Components and functions corresponding to those which were used above with reference to the embodiment according to Figures 1 to 10 have the same reference signs and are not discussed again in detail. In the EUV collector 24 according to Figure 1 1 , an extraneous light portion 43 is embodied as an absorbing portion of the overall impingement surface 34 of the EUV collector 24. From the tin droplet 15, which enters into the plasma source region 19, the pump light component 31 of the incident pump light 20 is reflected to the extraneous light portion 43 and absorbed there.
The extraneous light portion 43 may be thermally decoupled from the collector 24. Then, it is possible to dispense with complicated cooling of the collector 24. A main body of the EUV collector 24 may be manufactured from aluminium. Alternative materials for this main body are copper, alloys containing copper and/or aluminium or alloys of copper and aluminium oxide produced by powder metallurgy. In order to produce a microstructured or nanostructured component, the projection exposure apparatus 1 is used as follows: First, the reflection mask 10 or the reticle and the substrate or the wafer 1 1 are provided. Subsequently, a structure on the reticle 10 is projected onto a light-sensitive layer of the wafer 1 1 with the aid of the projection exposure apparatus 1. Then, a micro structure or nanostmcture on the wafer 1 1 , and hence the microstructured component, is produced by developing the light-sensitive layer.

Claims

Patent Claims
1. EUV collector (24) for use in an EUV projection exposure apparatus (1),
- wherein the collector (24) is embodied to guide EUV used light
(3), which is emitted by a plasma source region (19),
wherein an overall impingement surface (34) of the collector (24) is embodied for impingement with radiation (3, 31) emitted by the plasma source region (19),
- wherein a used light portion (35) of the overall impingement surface (34) is embodied to guide the EUV used light (3),
wherein an extraneous light portion (36; 41 ; 43) of the overall impingement surface (34) is embodied to divert extraneous light radiation (31), the wavelength of which differs from that of the used light (3),
wherein the used light portion (35) and the extraneous light portion (36; 41 ; 43) are not congruent,
wherein the extraneous light portion (36) is embodied as a diffraction grating (33) for the extraneous light radiation (31).
2. Collector according to Claim 1, characterized in that the extraneous light portion (36; 41 ; 43) has an extent which is at most 50% of the used light portion (35).
3. Collector according to Claim 1 or 2, characterized in that the extraneous light portion (36) constitutes a sub-portion of the used light portion (35).
4. Collector according to one of Claims 1 to 3, characterized in that the used light portion (35) has such an embodiment that the EUV used light (3) guided therewith is not reflected more than once at said location.
5. Collector according to one of Claims 1, 2 and 4, characterized in that the extraneous light portion (41) constitutes a portion of the overall impingement surface (34) which is separate from the used light portion (35).
6. Collector according to one of Claims 1, 2 and 5, characterized in that the extraneous light portion (43) is embodied as a portion of the overall impingement surface (34) which absorbs the extraneous light (31).
7. Collector according to one of Claims 1 to 6, characterized in that at least one region of the used light portion (35) is embodied for incidence of the EUV used light (3) with an angle of incidence of at most 45°.
8. Collector according to one of Claims 1 to 7, characterized by a pump light passage opening (25) for the passage of incident pump light (20) from a pump light source (21).
9. Collector according to one of Claims 1 to 8, characterized in that the extraneous light portion (36; 43) is arranged in the region of a pump light impact zone (32) of the overall impingement surface (34), wherein the pump light impact zone (32) is the zone into which pump light (20) is reflected during the operation of the EUV collector from a plasma generation material (15) arranged in a plasma source region (19).
10. Collector according to Claim 9, characterized in that the extraneous light portion (36; 43) completely covers the pump light impact zone
(32).
1 1. Illumination system comprising an EUV collector (24) according to one of Claims 1 to 10 and comprising an illumination optical unit (6) for illuminating an object field (4), in which an object (10) to be imaged is arrangeable, with the EUV used light (3).
12. Optical system comprising an illumination system according to Claim 1 1 and comprising a projection optical unit (7) for imaging the object field (4) into an image field (8), in which a substrate (1 1) is arrangeable, on which a portion of the object (10) to be imaged is to be imaged.
13. Projection exposure apparatus comprising an optical system according to Claim 12 and comprising an EUV light source (2).
14. Method for producing a structured component, comprising the following method steps:
providing a reticle (10) and a wafer (1 1),
projecting a structure on the reticle (10) onto a light-sensitive layer of the wafer (1 1) with the aid of the projection exposure apparatus according to Claim 13,
producing a micro structure and/or nanostructure on the wafer (1 1). Structured component, produced according to a method according Claim 14.
PCT/EP2017/057485 2016-04-08 2017-03-30 Euv collector for use in an euv projection exposure apparatus WO2017174423A1 (en)

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US16/136,453 US10578972B2 (en) 2016-04-08 2018-09-20 EUV collector for use in an EUV projection exposure apparatus

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EP3440490A1 (en) 2019-02-13
US10578972B2 (en) 2020-03-03
DE102016205893A1 (en) 2017-10-12
US20190033723A1 (en) 2019-01-31
TW201802533A (en) 2018-01-16
JP2019516129A (en) 2019-06-13

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