WO2017169205A1 - Method for manufacturing meat-like dry protein processed food - Google Patents
Method for manufacturing meat-like dry protein processed food Download PDFInfo
- Publication number
- WO2017169205A1 WO2017169205A1 PCT/JP2017/005273 JP2017005273W WO2017169205A1 WO 2017169205 A1 WO2017169205 A1 WO 2017169205A1 JP 2017005273 W JP2017005273 W JP 2017005273W WO 2017169205 A1 WO2017169205 A1 WO 2017169205A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- meat
- protein
- processed food
- weight
- dried
- Prior art date
Links
- 108090000623 proteins and genes Proteins 0.000 title claims abstract description 93
- 102000004169 proteins and genes Human genes 0.000 title claims abstract description 93
- 235000021067 refined food Nutrition 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000001035 drying Methods 0.000 claims description 22
- 235000011194 food seasoning agent Nutrition 0.000 claims description 16
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- 235000015278 beef Nutrition 0.000 description 9
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- 239000000843 powder Substances 0.000 description 9
- 239000003760 tallow Substances 0.000 description 9
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 8
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 8
- 238000010411 cooking Methods 0.000 description 8
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- 230000000052 comparative effect Effects 0.000 description 5
- 239000008157 edible vegetable oil Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 244000068988 Glycine max Species 0.000 description 4
- 235000010469 Glycine max Nutrition 0.000 description 4
- 108010064851 Plant Proteins Proteins 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 235000013372 meat Nutrition 0.000 description 4
- 235000021118 plant-derived protein Nutrition 0.000 description 4
- 210000001519 tissue Anatomy 0.000 description 4
- 108010073771 Soybean Proteins Proteins 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
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- 239000007787 solid Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 235000000346 sugar Nutrition 0.000 description 3
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000013555 soy sauce Nutrition 0.000 description 2
- 235000019710 soybean protein Nutrition 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000005135 Micromeria juliana Nutrition 0.000 description 1
- YBHQCJILTOVLHD-YVMONPNESA-N Mirin Chemical compound S1C(N)=NC(=O)\C1=C\C1=CC=C(O)C=C1 YBHQCJILTOVLHD-YVMONPNESA-N 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 240000002114 Satureja hortensis Species 0.000 description 1
- 235000007315 Satureja hortensis Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 101710172711 Structural protein Proteins 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- 235000013736 caramel Nutrition 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 210000004177 elastic tissue Anatomy 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 238000003168 reconstitution method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/22—Working-up of proteins for foodstuffs by texturising
- A23J3/26—Working-up of proteins for foodstuffs by texturising using extrusion or expansion
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/14—Vegetable proteins
- A23J3/16—Vegetable proteins from soybean
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/14—Vegetable proteins
- A23J3/18—Vegetable proteins from wheat
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/22—Working-up of proteins for foodstuffs by texturising
- A23J3/225—Texturised simulated foods with high protein content
- A23J3/227—Meat-like textured foods
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L11/00—Pulses, i.e. fruits of leguminous plants, for production of food; Products from legumes; Preparation or treatment thereof
- A23L11/05—Mashed or comminuted pulses or legumes; Products made therefrom
- A23L11/07—Soya beans, e.g. oil-extracted soya bean flakes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/03—Organic compounds
- A23L29/035—Organic compounds containing oxygen as heteroatom
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/30—Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P30/00—Shaping or working of foodstuffs characterised by the process or apparatus
- A23P30/20—Extruding
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Definitions
- the present invention relates to a method for producing a meat-like dried protein processed food.
- Patent Document 1 is a technique for producing a food having a texture similar to livestock meat from a material mainly composed of plant protein, and a kneaded mixture of a protein substance mainly composed of plant protein and water is subjected to high temperature pressure.
- a method for producing a protein food comprising: immersing a textured or structural protein extruded into a lump, sheet or rod through a seasoning liquid comprising a seasoning, a spice, etc. Is described.
- Patent Document 2 is a technique related to a method for producing an instant food ingredient, seasoning a flat material protein obtained by extruding from a slit-shaped die that opens at the tip barrel wall of an extruder after pressurization and heating. A method for producing an instant food ingredient characterized by drying to 10% or less is described.
- the object of the present invention is to provide a method for producing a meat-like dried protein processed food having meat-like flavor and texture as ingredients for instant food.
- a dry ingredient having a meat-like texture and flavor as a substitute for meat as an ingredient for instant food.
- the textured protein material produced by extruding by extruding and extruding plant protein as a main ingredient which is usually used as a main ingredient, in terms of flavor and texture, was far away.
- the inventors seasoned the porous textured protein material, adjusted the amount of edible oil and fat, and then heated and dried with hot air to shrink the protein.
- the present inventors have found that a meat-like dried protein processed food excellent in meat-like flavor and texture can be provided when the porous structure is controlled and reconstituted with hot water.
- a textured protein material produced by extrusion into a block or flat sheet using an extruder is rehydrated, dehydrated, and the obtained textured protein material is seasoned, and then edible fats and oils
- the dried meat-like processed protein product is characterized in that the fat and oil content after drying is added to 10 to 20% by weight and dried with hot air at 100 to 120 ° C. so that the water content becomes 5 to 12% by weight. It is a manufacturing method.
- the temperature of the hot air in the present invention is preferably 105 to 115 ° C.
- the amount of edible oil / fat in the present invention is preferably added so that the fat / oil content after drying is 12 to 16% by weight.
- the present invention can provide a method for producing a meat-like dried protein processed food having meat-like flavor and texture as ingredients for instant food.
- the textured protein material according to the present invention is prepared by kneading plant-derived powder material such as defatted soybean powder, soybean protein powder, wheat protein powder and starch with water, and using a twin screw extruder at high temperature and high pressure. It is made by being extruded through a die under normal pressure. At this time, the textured protein material has a porous structure by being released at once from high pressure to normal pressure. In addition, by changing the shape of the die, a massive or sheet-like tissue protein material can be obtained. The obtained textured protein material may be used as it is, but can be stored for a long time by drying or freezing.
- plant-derived powder material such as defatted soybean powder, soybean protein powder, wheat protein powder and starch with water
- the prepared textured protein material in water and rehydrate.
- the water reconstitution method There is no particular limitation on the water reconstitution method, but by immersing it in water for about one night, the whole tissue-like protein material spreads moisture, resulting in a moderately elastic tissue.
- the rehydrated tissue protein material is dehydrated to remove unnecessary moisture. By dehydrating, not only can unnecessary components be removed, but also odors such as soybean odor and wheat protein odor can be reduced.
- the textured protein material can be formed by pressing the dehydrated textured protein material with a roll or a cutting blade roll or by providing a kerf. Since the material has elasticity and fiber orientation, it has a more meaty texture. In addition, through this process, not only the seasoning liquid and edible fats and oils are easily penetrated into the entire textured protein material when seasoning treatment described later and edible fats and oils are added, but also the restorability at the time of eating Get better.
- the textured protein material When the textured protein material is crushed by a roll or a cutting blade roll or provided with a kerf, it is preferably passed through the roll or cutting blade roll in the same direction as the textured protein material extruded by the biaxial extruder. . Passing through a roll or cutting blade roll in a direction perpendicular to the extruded direction is not preferable because the directionality of the fiber is destroyed.
- the raw material used for the seasoning process may be changed according to the intended instant food, and is not particularly limited. For example, salt, mirin, sake, sugar, reducing sugar, soy sauce, sodium glutamate, protein hydrolyzate, nucleic acid, meat extract, juice or powder of onions and ginger, spices, pigments, fragrances, antioxidants, etc. What is necessary is just to perform a seasoning process by immersing a tissue-like protein raw material in the seasoning liquid which mixes directly with a proteinaceous protein raw material or melt
- the method of immersing in the seasoning liquid is not particularly limited, and the immersion may be performed only by immersing in the seasoning liquid or while heating or heating.
- the textured protein material immersed in the seasoning liquid is drained to remove unnecessary seasoning liquid and used in the next step.
- the edible fats and oils to be added are not particularly limited, but liquid oil having a melting point of 20 ° C. or higher, preferably a semisolid or solid at 30 ° C. to 50 ° C. so that the oil does not elute from the meat-like dried protein processed food produced during storage. It is preferable to use oil. Examples of such oils include palm oil, cacao oil, lard, and beef tallow. Moreover, when melting
- the amount of edible oil / fat added varies depending on the moisture content of the textured protein material before the addition of edible oil / fat, so it should be added to 10-20% by weight with respect to the weight of the dried meat-like dried protein processed food. Is preferred. If it is less than 10% by weight, it will be subjected to the flavor of meat-like oil, the restorability will be improved and the texture will be soft. On the other hand, if it exceeds 20% by weight, it not only has an oily flavor but also has poor restorability and a hard texture. More preferably, it is 12 to 16% by weight.
- the method for adding edible fats and oils is not particularly limited, and it may be sprayed directly on seasoned textured protein material, or may be added by mixing with a mixer or the like. Edible fats and oils may be added with an oil can, but deoiling treatment is required. In addition, when the temperature of the edible fat increases, the textured protein material surface is hardened or the porous structure of the textured protein material is strengthened.
- the moisture after drying by heating is higher than 12% by weight because the storage stability is insufficient.
- the content is less than 5% by weight, the textured protein material becomes hard, and the textured protein material breaks during storage or transportation. More preferably, it is 6 to 10% by weight.
- the dried textured protein material can be used as an ingredient for instant foods as a meat-like dried protein processed food through sieving and a foreign matter sorting process.
- the porous textured protein material produced by extruding by extruding under pressure with an extruder is rehydrated, dehydrated, seasoned, added with oil, and 100 to 100- It can be heated and dried with hot air at 120 ° C to shrink the protein and control the porous structure, so that the restorability can be controlled, and the meat-like flavor and texture are excellent when reconstituted in hot water.
- a dried protein processed product can be provided.
- Example 1 Examination of fat content (Example 1-1)
- Raw material powder consisting of 80% by weight of defatted soybeans, 10% by weight of separated soy protein, 9.4% by weight of corn starch and 0.4% by weight of calcium sulfate is mixed, and water is added to 5% by weight with respect to the weight of the raw material powder. While adding water and mixing, saturated steam flows in 1.5% by weight with respect to the weight of the raw material powder, and the diameter of the outlet is 110 ° C with a biaxial extruder under the heating and pressurizing conditions of 3.5 Maps.
- a textured protein sheet was prepared by extrusion from a 1 ⁇ 30 mm slit die.
- the prepared textured protein sheet was cut to a length of about 25 mm and dried with hot air at 60 ° C. to a moisture content of 8% by weight to obtain a textured protein material.
- the dried textured protein material was soaked in water overnight, rehydrated and dehydrated.
- the dehydrated tissue protein material is immersed in a seasoning solution consisting of 20% by weight of soy sauce, 35% by weight of sugar, 5% by weight of salt, 2% by weight of caramel pigment, and 38% by weight of water, heated until boiling, The fire was turned off and allowed to stand for 5 minutes, then drained and seasoned.
- a seasoning solution consisting of 20% by weight of soy sauce, 35% by weight of sugar, 5% by weight of salt, 2% by weight of caramel pigment, and 38% by weight of water, heated until boiling, The fire was turned off and allowed to stand for 5 minutes, then drained and seasoned.
- the textured protein material to which beef tallow was added was heated and dried with a hot air dryer at 110 ° C. until the water content became 8% by weight, and then cooled to obtain a meat-like dried protein processed food sample (oil content 10% by weight).
- the measuring method of fats and oils was performed by the ether extraction method described in the food labeling standard attachment (analytical methods such as nutrients, etc. 2 lipid (1)).
- the method for measuring moisture is the atmospheric pressure drying method described in the food labeling standard attachment (analytical methods for nutrients, etc. 5 carbohydrates, moisture (3)), the heating temperature is 105 ° C., and the time is 4 Went in time.
- Example 1-2 A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1 except that the amount of beef tallow added was 15% by weight (oil content 12% by weight).
- Example 1-3 A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1 except that the amount of beef tallow added was 20% by weight (oil content 14% by weight).
- Example 1-4 A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1 except that the amount of beef tallow added was 30% by weight (oil content 16% by weight).
- Example 1-5 A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1 except that the amount of beef tallow added was 50% by weight (oil content 20% by weight).
- Example 1-2 A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1, except that it was soaked in beef tallow heated to 110 ° C. instead of adding fat and heat and dried until the water content reached 8% by weight. (Oil content 30% by weight).
- the evaluation of the flavor after hot water cooking is ⁇ with a good cooking odor and oil flavor feeling very good, ⁇ with cooking odor and oil flavor good, weak cooking odor or oil flavor Or, a fat product was marked with ⁇ , and a cooking odor or oil flavor was extremely weak, or a burnt odor or too greasy was marked with ⁇ .
- Example 2 Heating and drying temperature (Example 2-1) A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3, except that the heating and drying temperature was 100 ° C.
- Example 2-2 A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3, except that the heating and drying temperature was 105 ° C.
- Example 2-3 A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3 except that the heat drying temperature was 115 ° C.
- Example 2-4 A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3 except that the heating and drying temperature was 120 ° C.
- the prepared meat-like dried protein processed food sample was evaluated in the same manner as in Experiment 1.
- the evaluation results of Experiment 2 are shown in Table 2.
Abstract
Description
本発明に係る組織状蛋白素材は、脱脂大豆粉、大豆タンパク粉、小麦タンパク粉及び澱粉等の植物由来の粉末素材と水とを混練し、二軸エクストルーダを用いて高温高圧下でダイを通して常圧下に押出されることで作製される。このとき、高圧下から常圧下に一気に開放されることで組織状蛋白素材は多孔質構造を有するようになる。また、ダイの形状を変えることにより、塊状やシート状の組織状蛋白素材が得られる。得られた組織状蛋白素材は、そのまま使用してもよいが、乾燥するか、冷凍することで長期保存することが可能となる。 1. Preparation of textured protein material The textured protein material according to the present invention is prepared by kneading plant-derived powder material such as defatted soybean powder, soybean protein powder, wheat protein powder and starch with water, and using a twin screw extruder at high temperature and high pressure. It is made by being extruded through a die under normal pressure. At this time, the textured protein material has a porous structure by being released at once from high pressure to normal pressure. In addition, by changing the shape of the die, a massive or sheet-like tissue protein material can be obtained. The obtained textured protein material may be used as it is, but can be stored for a long time by drying or freezing.
本発明においては、必ずしも本工程を行う必要はないが、脱水した組織状蛋白素材を、ロールや切刃ロールにより圧扁するまたは、切り溝を付けることにより、組織状蛋白素材に弾力性や繊維の配向性が出るため、より肉らしい食感となる。また、本工程を経ることにより、後述する味付け処理をする際や食用油脂を添加する際に組織状蛋白素材全体に調味液や食用油脂が浸透しやすくなるだけでなく、喫食時の復元性もよくなる。 2. Textured protein material processing step In the present invention, although it is not always necessary to perform this step, the textured protein material can be formed by pressing the dehydrated textured protein material with a roll or a cutting blade roll or by providing a kerf. Since the material has elasticity and fiber orientation, it has a more meaty texture. In addition, through this process, not only the seasoning liquid and edible fats and oils are easily penetrated into the entire textured protein material when seasoning treatment described later and edible fats and oils are added, but also the restorability at the time of eating Get better.
次いで、組織状蛋白素材に味付け処理を行う。味付け処理に用いる原料としては、目的とする即席食品に合わせて変えればよく、特に限定しない。例えば、食塩、みりん、酒、砂糖、還元糖、醤油、グルタミン酸ナトリウム、蛋白加水分解物、核酸、畜肉エキス、玉ねぎやショウガなどの搾汁または粉末、香辛料、色素、香料、酸化防止剤等を組織状蛋白素材と直接混合するか、または溶解した調味液に組織状蛋白素材を浸漬し、味付け処理を行えばよい。 3. Seasoning process Next, the textured protein material is seasoned. The raw material used for the seasoning process may be changed according to the intended instant food, and is not particularly limited. For example, salt, mirin, sake, sugar, reducing sugar, soy sauce, sodium glutamate, protein hydrolyzate, nucleic acid, meat extract, juice or powder of onions and ginger, spices, pigments, fragrances, antioxidants, etc. What is necessary is just to perform a seasoning process by immersing a tissue-like protein raw material in the seasoning liquid which mixes directly with a proteinaceous protein raw material or melt | dissolved.
味付けした組織状蛋白素材に食用油脂を添加する。添加する食用油脂は特に限定しないが、保存中に製造した肉様乾燥蛋白加工食品から油が溶出しないように、融点が20℃以上の液油、好ましくは30℃~50℃の半固形または固形油を用いることが好ましい。このような油としては、例えば、パーム油、カカオ油、ラード及び牛脂等が挙げられる。また、食用油脂の融点が高すぎると喫食時の油の風味が悪く、舌触りも悪くなる。半固形または固形油を用いる場合には、融解して液体状にしてから組織状蛋白素材に添加する。 4). Add edible fat to the textured protein material seasoned with edible fat. The edible fats and oils to be added are not particularly limited, but liquid oil having a melting point of 20 ° C. or higher, preferably a semisolid or solid at 30 ° C. to 50 ° C. so that the oil does not elute from the meat-like dried protein processed food produced during storage. It is preferable to use oil. Examples of such oils include palm oil, cacao oil, lard, and beef tallow. Moreover, when melting | fusing point of edible fats and oils is too high, the flavor of the oil at the time of eating will be bad, and a touch will also worsen. When semi-solid or solid oil is used, it is melted to form a liquid and then added to the tissue protein material.
次いで油脂を添加した組織状蛋白素材を100~120℃の熱風で水分が5~12重量%となるまで加熱乾燥する。高温の熱風で乾燥処理することでタンパク質を収縮させながら多孔質構造をコントロールして乾燥させることにより、喫食時に適度な弾力を有する肉様の触感となり、加熱調理された風味が出る。100℃未満の場合、多孔質構造の収縮が弱く、復元性が良すぎるため柔らかく弾力の欠ける食感となり、また、加熱調理された風味に欠けるため好ましくない。また、120℃を超えると乾燥中に組織状蛋白素材の一部に焦げが発生するため好ましくない。より好ましくは、105~115℃である。 5). Heat drying followed by heating and drying the textured protein material to which fats and oils have been added with hot air at 100 to 120 ° C. until the water content becomes 5 to 12 wt%. By drying with high-temperature hot air, the porous structure is controlled and dried while shrinking the protein, resulting in a meat-like tactile sensation with an appropriate elasticity at the time of eating, resulting in a cooked flavor. When the temperature is lower than 100 ° C., the porous structure is weakly contracted, the restorability is too good, and the texture is soft and lacks elasticity, and the cooked flavor is lacking. Moreover, when it exceeds 120 degreeC, since a part of textured protein raw material will generate | occur | produce during drying, it is unpreferable. More preferably, it is 105 to 115 ° C.
乾燥した組織状蛋白素材は、篩がけや異物選別工程を経て肉様乾燥蛋白加工食品として即席食品用の具材に使用することができる。 6). In addition, the dried textured protein material can be used as an ingredient for instant foods as a meat-like dried protein processed food through sieving and a foreign matter sorting process.
(実施例1-1)
脱脂大豆80重量%、分離ダイズ蛋白10重量%、コーンスターチ9.4重量%、硫酸カルシウム0.4重量%からなる原料粉を混合し、そこに水を原料粉の重量に対して5重量%となるように加水して混捏しながら、飽和蒸気を原料粉の重量に対して1.5重量%流入して、二軸エクストルーダで110℃、3.5Mapsの加温加圧条件で出口の口径が1x30mmのスリットダイから押出して組織状蛋白シートを作製した。 <Experiment 1> Examination of fat content (Example 1-1)
Raw material powder consisting of 80% by weight of defatted soybeans, 10% by weight of separated soy protein, 9.4% by weight of corn starch and 0.4% by weight of calcium sulfate is mixed, and water is added to 5% by weight with respect to the weight of the raw material powder. While adding water and mixing, saturated steam flows in 1.5% by weight with respect to the weight of the raw material powder, and the diameter of the outlet is 110 ° C with a biaxial extruder under the heating and pressurizing conditions of 3.5 Maps. A textured protein sheet was prepared by extrusion from a 1 × 30 mm slit die.
牛脂の添加量を15重量%とする以外は、実施例1-1と同様の方法で肉様乾燥蛋白加工食品サンプルとした(油脂含量12重量%)。 Example 1-2
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1 except that the amount of beef tallow added was 15% by weight (oil content 12% by weight).
牛脂の添加量を20重量%とする以外は、実施例1-1と同様の方法で肉様乾燥蛋白加工食品サンプルとした(油脂含量14重量%)。 (Example 1-3)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1 except that the amount of beef tallow added was 20% by weight (oil content 14% by weight).
牛脂の添加量を30重量%とする以外は、実施例1-1と同様の方法で肉様乾燥蛋白加工食品サンプルとした(油脂含量16重量%)。 (Example 1-4)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1 except that the amount of beef tallow added was 30% by weight (oil content 16% by weight).
牛脂の添加量を50重量%とする以外は、実施例1-1と同様の方法で肉様乾燥蛋白加工食品サンプルとした(油脂含量20重量%)。 (Example 1-5)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1 except that the amount of beef tallow added was 50% by weight (oil content 20% by weight).
牛脂を添加しない以外は、実施例1-1と同様の方法で肉様乾燥蛋白加工食品サンプルとした。 (Comparative Example 1-1)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1 except that beef tallow was not added.
油脂添加及び加熱乾燥の代わりに110℃に加温した牛脂に浸漬して水分が8重量%となるまで油ちょうする以外は実施例1-1と同様の方法で肉様乾燥蛋白加工食品サンプルとした(油脂含量30重量%)。 (Comparative Example 1-2)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-1, except that it was soaked in beef tallow heated to 110 ° C. instead of adding fat and heat and dried until the water content reached 8% by weight. (Oil content 30% by weight).
(実施例2-1)
加熱乾燥温度を100℃とする以外は実施例1-3と同様の方法で肉様乾燥蛋白加工食品サンプルとした。 <Experiment 2> Heating and drying temperature (Example 2-1)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3, except that the heating and drying temperature was 100 ° C.
加熱乾燥温度を105℃とする以外は実施例1-3と同様の方法で肉様乾燥蛋白加工食品サンプルとした。 (Example 2-2)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3, except that the heating and drying temperature was 105 ° C.
加熱乾燥温度を115℃とする以外は実施例1-3と同様の方法で肉様乾燥蛋白加工食品サンプルとした。 (Example 2-3)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3 except that the heat drying temperature was 115 ° C.
加熱乾燥温度を120℃とする以外は実施例1-3と同様の方法で肉様乾燥蛋白加工食品サンプルとした。 (Example 2-4)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3 except that the heating and drying temperature was 120 ° C.
加熱乾燥温度を70℃とする以外は実施例1-3と同様の方法で肉様乾燥蛋白加工食品サンプルとした。 (Comparative Example 2-1)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3 except that the heating and drying temperature was 70 ° C.
加熱乾燥温度を90℃とする以外は実施例1-3と同様の方法で肉様乾燥蛋白加工食品サンプルとした。 (Comparative Example 2-2)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3 except that the heating and drying temperature was 90 ° C.
加熱乾燥温度を130℃とする以外は実施例1-3と同様の方法で肉様乾燥蛋白加工食品サンプルとした。 (Comparative Example 2-3)
A meat-like dried protein processed food sample was prepared in the same manner as in Example 1-3 except that the heat drying temperature was 130 ° C.
Claims (3)
- エクストルーダにより加圧加熱されて塊状または偏平なシート状に押出されて作製された組織状蛋白素材を、水戻し後、脱水し、
得られた前記組織状蛋白素材に味付け処理を行った後、
食用油脂を乾燥後の油脂含量が10~20重量%となるように添加し、
100~120℃の熱風で水分が5~12重量%となるように乾燥することを特徴とする肉様乾燥蛋白加工食品の製造方法。 After reconstitution, the dehydrated tissue protein material produced by extruding into a lump or flat sheet by being heated under pressure by an extruder,
After performing a seasoning process on the obtained textured protein material,
Add the edible fat and oil so that the fat content after drying is 10 to 20% by weight,
A method for producing a meat-like dried protein processed food, characterized by drying with hot air at 100 to 120 ° C. so that the water content is 5 to 12% by weight. - 前記熱風の温度が105~115℃であることを特徴とする請求項1記載の肉様乾燥蛋白加工食品の製造方法。 The method for producing a meat-like dried protein processed food according to claim 1, wherein the temperature of the hot air is 105 to 115 ° C.
- 前記食用油脂の添加量が、乾燥後の油脂含量が12~16重量%となるように添加することを特徴とする請求項1または2記載の肉様乾燥蛋白加工食品の製造方法。 3. The method for producing a meat-like dried protein processed food according to claim 1 or 2, wherein the edible fat is added so that the fat content after drying is 12 to 16% by weight.
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WO2023171303A1 (en) * | 2022-03-11 | 2023-09-14 | 富士フイルム株式会社 | Protein food material and alternative molded meat |
WO2023171304A1 (en) * | 2022-03-11 | 2023-09-14 | 富士フイルム株式会社 | Production method for protein food ingredient, and protein food ingredient |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60203145A (en) * | 1984-03-26 | 1985-10-14 | Japan Tobacco Inc | Production of soybean protein-like instant food |
JPH01277469A (en) * | 1988-04-30 | 1989-11-07 | Fuji Oil Co Ltd | Production of thawable dried food fried without coating |
JP2004041041A (en) * | 2002-07-10 | 2004-02-12 | Fuji Oil Co Ltd | Method for producing dry food |
WO2014002180A1 (en) * | 2012-06-26 | 2014-01-03 | 太陽化学株式会社 | Dry processed protein and process for producing same |
JP2014161299A (en) * | 2013-02-27 | 2014-09-08 | Fuji Oil Co Ltd | Non-fried snack-like food and manufacturing method thereof |
WO2014156948A1 (en) * | 2013-03-28 | 2014-10-02 | 不二製油株式会社 | Textured vegetable protein material and substitute for thin meat slices using same |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1565226A (en) * | 2003-06-13 | 2005-01-19 | 不二制油株式会社 | Meat-like foodstuff and meat-like food producing using same |
CN102551075B (en) * | 2010-12-14 | 2013-07-03 | 山东莱州大家乐食品有限公司 | Protein-compounded jerky and preparation method thereof |
CN104041657A (en) * | 2013-03-12 | 2014-09-17 | 高级食品系统公司 | Texturized vegetable protein block as meat substituent, preparation method, and composition |
CN104012883A (en) * | 2014-06-27 | 2014-09-03 | 天津春发生物科技集团有限公司 | Incense pot beef vegetarian diet and preparation method thereof |
-
2016
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2017
- 2017-02-14 BR BR112018069847-4A patent/BR112018069847B1/en active IP Right Grant
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60203145A (en) * | 1984-03-26 | 1985-10-14 | Japan Tobacco Inc | Production of soybean protein-like instant food |
JPH01277469A (en) * | 1988-04-30 | 1989-11-07 | Fuji Oil Co Ltd | Production of thawable dried food fried without coating |
JP2004041041A (en) * | 2002-07-10 | 2004-02-12 | Fuji Oil Co Ltd | Method for producing dry food |
WO2014002180A1 (en) * | 2012-06-26 | 2014-01-03 | 太陽化学株式会社 | Dry processed protein and process for producing same |
JP2014161299A (en) * | 2013-02-27 | 2014-09-08 | Fuji Oil Co Ltd | Non-fried snack-like food and manufacturing method thereof |
WO2014156948A1 (en) * | 2013-03-28 | 2014-10-02 | 不二製油株式会社 | Textured vegetable protein material and substitute for thin meat slices using same |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022265019A1 (en) * | 2021-06-14 | 2022-12-22 | 株式会社J-オイルミルズ | Texturized-protein food ingredient |
WO2023171303A1 (en) * | 2022-03-11 | 2023-09-14 | 富士フイルム株式会社 | Protein food material and alternative molded meat |
WO2023171304A1 (en) * | 2022-03-11 | 2023-09-14 | 富士フイルム株式会社 | Production method for protein food ingredient, and protein food ingredient |
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