WO2017156824A1 - 一种褐煤半焦贫氧燃烧锅炉 - Google Patents
一种褐煤半焦贫氧燃烧锅炉 Download PDFInfo
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- WO2017156824A1 WO2017156824A1 PCT/CN2016/080062 CN2016080062W WO2017156824A1 WO 2017156824 A1 WO2017156824 A1 WO 2017156824A1 CN 2016080062 W CN2016080062 W CN 2016080062W WO 2017156824 A1 WO2017156824 A1 WO 2017156824A1
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- Prior art keywords
- cyclone
- combustion
- coke
- combustion chamber
- cylinder
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- 238000002485 combustion reaction Methods 0.000 title claims abstract description 132
- 239000003077 lignite Substances 0.000 title claims abstract description 37
- 239000000571 coke Substances 0.000 title claims abstract description 31
- 239000001301 oxygen Substances 0.000 title claims abstract description 27
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 27
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 230000002950 deficient Effects 0.000 title abstract 6
- 239000002893 slag Substances 0.000 claims abstract description 52
- 239000000779 smoke Substances 0.000 claims abstract description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 30
- 239000003546 flue gas Substances 0.000 claims description 30
- 239000000446 fuel Substances 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 8
- 230000009471 action Effects 0.000 claims description 6
- 238000002309 gasification Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 230000000153 supplemental effect Effects 0.000 claims description 3
- 239000003344 environmental pollutant Substances 0.000 abstract description 5
- 231100000719 pollutant Toxicity 0.000 abstract description 5
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 12
- 239000003245 coal Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000002956 ash Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000033228 biological regulation Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 239000004449 solid propellant Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000009841 combustion method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L9/00—Passages or apertures for delivering secondary air for completing combustion of fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B31/00—Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements or dispositions of combustion apparatus
- F22B31/02—Installation of water-tube boilers in chimneys, e.g. in converter chimneys
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B31/00—Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements or dispositions of combustion apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C7/00—Combustion apparatus characterised by arrangements for air supply
- F23C7/02—Disposition of air supply not passing through burner
Definitions
- the invention relates to the technical field of boilers, in particular to a lignite semi-coke lean oxygen combustion boiler.
- Lignite is a kind of low-rank coal. China and the world have huge reserves. However, lignite has high water content, high volatile content, easy to spontaneous combustion, and is not conducive to transportation, which restricts the large-scale utilization of lignite. The upgrading of lignite and the comprehensive utilization of grading and grading are of great significance for the development of lignite.
- lignite semi-coke is a better fuel due to the decrease of volatile matter, water loss and heat generation.
- the high-efficiency and low-pollution utilization of lignite semi-coke plays an important role in the comprehensive energy efficiency improvement of lignite classification and utilization.
- Lignite semi-coke can be used to make gas from gasifier raw materials, and can also be used for direct combustion of boiler fuel to produce thermal energy. Among them, the direct combustion of the boiler to heat the working fluid to produce hot water or steam is the most direct use. However, due to the significant reduction of lignite semi-coke volatiles, its ignition performance is affected. It is essential to develop a boiler that burns brown coal and semi-coke with stable combustion performance and low pollutant emissions.
- the pulverized coal furnace is the most important combustion method for power station boilers.
- Cyclone combustion is a stable and controllable high-speed rotating flame of artificial tissue.
- the combustion flame is highly full and the disturbance ability is extremely strong. It is suitable for the combustion process of powder and crumbly solid fuel, which is higher than the general room combustion mode.
- Thermal strength Since the solid fuel has a certain amount of accumulation in the combustion chamber, it has a relatively long residence time in the cyclone furnace, which helps to maintain the continuity of the combustion process.
- the hot slag film accumulates a certain amount of heat and is an extremely stable combustion bed that maintains the stability of the combustion process.
- Cyclone combustion has high combustion intensity, high slag rejection rate, and combustion Stability and other advantages, but due to iron precipitation, hydrogen explosion, slagging difficulties and high emissions of pollutants such as nitrogen oxides, its application is limited.
- coal-fired power plants undertake important power peak-shaving tasks, requiring power station boilers to operate stably and efficiently over a wide range of loads.
- Existing power station boilers often have a contradiction between the high efficiency of combustion stability and the low load operation of the boiler. Therefore, it is necessary to propose a new combustion boiler that can achieve high efficiency and low pollution combustion as well as large load regulation.
- the object of the present invention is to provide a lignite semi-coke lean oxygen combustion boiler, which solves the problems of low combustion intensity, narrow load regulation range and excessive pollutant discharge of the existing pulverized coal fired boiler; the boiler of the invention has high combustion intensity and slag collection High rate, low pollutant emission, wide range of load regulation and so on.
- a lignite semi-coke lean oxygen combustion boiler comprises a plurality of cyclone anaerobic combustion devices and a boiler body; the boiler body comprises a second combustion chamber, a boiler heating surface arranged at the upper portion of the second combustion chamber, and a smoke exhausting port; It is an inverted adiabatic cyclone with a central cylinder; the cyclone lean oxygen combustion device is connected to the second combustion chamber of the boiler body.
- the cyclone lean oxygen combustion device comprises a cyclone cylinder, a central cylinder, a flue gas duct and a secondary air cyclone; the lower side wall of the cyclone cylinder is provided with a primary air outlet; the bottom center of the cyclone cylinder is provided with a through hole, the center The cylinder passes through the through hole at the bottom of the cyclone cylinder and protrudes into the interior of the cyclone cylinder.
- the top of the central cylinder is a through hole and is spaced apart from the inner wall of the top of the cyclone cylinder.
- the central cylinder is sealed with the joint of the cyclone cylinder; the inside of the cyclone cylinder is located below the primary air outlet.
- the bottom of the molten slag pool is provided with a first discharge slag port; the bottom of the central cylinder is provided with a second discharge slag port, one end of the flue gas duct is vertically connected to the central cylinder, and the other end is connected to the second combustion chamber.
- a secondary air cyclone for feeding the supplemental secondary air is provided at the inlet of the flue gas duct and the second combustion chamber.
- the primary air outlet is inclined downwardly.
- each of the side walls of the cyclone is provided with two primary air ports for forming a cyclone in the cyclone.
- the boiler is heated by a tower arrangement.
- the lignite semi-coke powder enters the annular space between the central cylinder and the cyclone from the primary air outlet of the lower part of the cyclone in the tangential or tangential direction by the primary air, and forms a high-temperature combustion gasification zone in the lower part of the annular space.
- This area keeps the excess air coefficient less than 1, and maintains the reaction as an oxygen-poor combustion atmosphere; the generated flue gas is strongly rotated in the cyclone to remove the liquid slag, and then the flue gas enters the flue gas duct between the second combustion chamber and the cyclone.
- the combustion chamber supplements part of the secondary air when entering the second combustion chamber, and rotates the jet into the second combustion chamber; the flue gas is fully combusted in the second combustion chamber and further exothermic, and then the high-temperature flue gas is generated to pass through the tower-arranged boilers respectively.
- the heat receiving surface completes the heat transfer, and the flue gas is lowered to the exhaust gas temperature and discharged from the exhaust port.
- center cylinder and the cyclone cylinder are made of silicon nitride material, and the cyclone combustion chamber formed between the center cylinder and the cyclone cylinder is an adiabatic combustion chamber.
- the combustion performed in the secondary combustion chamber is homogeneous combustion, and the excess air ratio is 1.05 to 1.1.
- the temperature of the reaction zone above the molten slag pool is 100 to 200 ° C higher than the ash fusion temperature.
- cyclone anaerobic combustion device is plural and evenly distributed on the outer circumference of the boiler.
- the cyclone is burned by molten oxygen, which converts most of the fuel nitrogen into nitrogen, and uses the staged air combustion in the second combustion chamber to reduce the emission of nitrogen oxides.
- molten slag in the cyclone chamber space to form a slag pool.
- the molten ash in the slag pool catalyzes and provides a heat source for the coking combustion of the residual coke, maintains the stability of combustion, and improves carbon. Conversion rate.
- Each cyclone has two symmetrically arranged primary air inlets to form a strong swirling airflow in the cyclone cylinder; above the bottom of the cyclone cylinder is a molten slag pool with a certain depth, and the large particles of coal briquettes are rapidly heated in the slag slag pool. Solution and gasification, to achieve high carbon conversion rate; slag discharge hole is opened under the slag pool, the temperature in the cyclone cylinder is maintained above the ash melting temperature, and smooth liquid slagging can be achieved.
- the gasification combustion in the slag pool is mainly an exothermic reaction of carbon and oxygen, so that the local high temperature is maintained at the slag pool, which is beneficial to increase the combustion intensity and improve the fluidity of the molten slag.
- the strong swirling airflow in the combustion chamber of the cyclone cylinder separates the coke from the wall surface to realize the separation of the molten droplets and the flue gas, improves the slag-removing rate, greatly reduces the contamination of the heated surface of the subsequent tower boiler and subsequent Dust burden.
- a second slag separation chamber is arranged in the lower part of the central pipe between the cyclone and the second combustion chamber, and the separated liquid slag is captured into the slag pool in the future, thereby further reducing the fly ash content in the flue gas to realize the liquid slag. Separate from the gas product as much as possible.
- the secondary air with a rotating jet at the inlet of the second combustion chamber maintains the overall excess air coefficient at a lower level, and the secondary combustion in the second combustion chamber is mainly homogeneous combustion, which reduces the formation of nitrogen oxides.
- the cyclone cylinder, the central cylinder and the adiabatic duct are all made of silicon nitride material, which improves the thermal shock resistance of the equipment.
- a boiler can be equipped with multiple cyclone anaerobic combustion equipment.
- FIG. 1 is a schematic structural view of a lignite semi-coke lean oxygen combustion boiler according to the present invention
- Figure 2 is a plan view of Figure 1.
- a lignite semi-coke lean oxygen combustion boiler comprises a plurality of cyclone lean oxygen combustion devices and a boiler body, and the two are arranged in a satellite shape.
- the bottom of the boiler body is a second combustion chamber 5, the upper part of the second combustion chamber 5 is a boiler heating surface 3 arranged in a tower, and the exhaust surface 4 of the boiler heating surface 3 is provided with a smoke exhausting port 4.
- the cyclone lean oxygen combustion device includes a cyclone cylinder 1, a center cylinder 2, a flue gas duct 7 and a secondary air cyclone 6.
- the lower side wall of the cyclone cylinder 1 is provided with a primary air outlet 11 , and the primary air outlet 11 is slightly inclined downward; and each of the side walls of the cyclone cylinder 1 is provided with two primary air outlets 11 for forming a cyclone in the cyclone cylinder 1 .
- the center of the bottom of the cyclone cylinder 1 is provided with a through hole, and the center cylinder 2 is rotated through the center.
- the through hole at the bottom of the air cylinder 1 extends into the interior of the cyclone cylinder 1.
- the top of the central cylinder 2 is a through hole and is spaced apart from the inner wall of the top of the cyclone cylinder 1, and the central cylinder 2 is sealed at the junction with the cyclone cylinder 1.
- a molten slag pool 10 is disposed below the primary tuyere 11 in the cyclone cylinder 1, and a first discharge port 9 is provided at the bottom of the molten slag pool 10.
- the bottom of the central cylinder 2 is provided with a second discharge port 8 , one end of which is vertically connected to the central cylinder 2 , the other end is connected to the second combustion chamber 5 , and the secondary air is provided at the entrance of the flue gas duct 7 and the second combustion chamber 5 .
- the cyclone 6 is used to feed the secondary air of the supplementary combustion.
- the lignite semi-coke powder is sent from the primary air and the recirculated flue gas from the slightly downwardly inclined primary tuyere 11 to the annular region above the molten slag pool 10 in the cyclone cylinder 1, the lignite coke in the intense high temperature slag Rapid pyrolysis and combustion under heating, the excess air ratio of the primary air is maintained in the range of less than 1.
- the small particles are rapidly burned under the action of the air current. Due to the strong turbulent combustion, the ash molten droplets of the small particles merge and grow up and smash into the wall of the cyclone cylinder 1 under the action of centrifugal force, and flow into the molten slag pool under the action of gravity.
- the residence time after 10 is significantly increased, increasing the carbon burnout rate.
- the temperature of the reaction zone above the molten slag pool 10 is controlled by adjusting the excess air ratio and the recycled flue gas rate, and maintaining the temperature higher than the ash melting temperature by 100 to 200 °C.
- the molten slag pool 10 has a large heat capacity and can quickly complete the gasification combustion of the residual coke.
- the stability of the slag pool temperature and the slag flowability are ensured, and the excess slag is discharged from the first slag discharge port 9.
- the generated gaseous product completes the gas-liquid separation from the slag, and the gas is sent from the folded-back zone of the upper portion of the cyclone cylinder 1 down the center cylinder 2 and through the flue gas duct 7 to the second combustion chamber 5.
- the secondary air of the supplemental combustion is sent through the secondary air nozzle 6, and the complete combustion is completed in the second combustion chamber 5 with a small excess air ratio of 1.05 to 1.1.
- the high-temperature flue gas generated after complete combustion passes from the second combustion chamber 5 upward, sequentially passes through the heating surface 3 of each boiler, and the heat exchange temperature of the flue gas and the boiler heating surface 3 is lowered to a certain temperature, and is discharged from the exhaust port 4 to the boiler, and the system is simultaneously set.
- the flue gas recirculation fan introduces a certain amount of exhaust gas into the primary tuyere 11.
- each boiler body can be equipped with a plurality of cyclone-poor combustion devices, and each of the cyclone-poor combustion devices can be operated separately, thereby increasing the load regulation ratio of the lignite semi-coke lean-oxygen combustion boiler.
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Abstract
Description
Claims (10)
- 一种褐煤半焦贫氧燃烧锅炉,其特征在于,包括若干旋风筒贫氧燃烧装置和锅炉本体;锅炉本体包括二燃室(5)、设置于二燃室(5)上部的锅炉受热面(3)和排烟口(4);旋风筒贫氧燃烧装置为一个倒置的带有中心筒的绝热旋风分离器;所述旋风筒贫氧燃烧装置连接锅炉本体的二燃室(5)。
- 根据权利要求1所述的一种褐煤半焦贫氧燃烧锅炉,其特征在于,旋风筒贫氧燃烧装置包括旋风筒(1)、中心筒(2)、烟气导管(7)和二次风旋流器(6);旋风筒(1)的下部侧壁上设有一次风口(11);旋风筒(1)的底部中心开有通孔,中心筒(2)穿过旋风筒(1)底部的通孔伸入旋风筒(1)内部,中心筒(2)顶部为通孔且与旋风筒(1)顶部内壁间隔设置,中心筒(2)与旋风筒(1)连接处密封;旋风筒(1)内位于一次风口(11)的下方设有熔融渣池(10),熔融渣池(10)的底部设有第一排渣口(9);中心筒(2)的底部设有第二排渣口(8),烟气导管(7)一端垂直连接中心筒(2),另一端连接二燃室(5)。
- 根据权利要求2所述的一种褐煤半焦贫氧燃烧锅炉,其特征在于,在烟气导管(7)与二燃室(5)的入口处设有用于送入补燃二次风的二次风旋流器(6)。
- 根据权利要求2所述的一种褐煤半焦贫氧燃烧锅炉,其特征在于,一次风口(11)向下倾斜设置。
- 根据权利要求2所述的一种褐煤半焦贫氧燃烧锅炉,其特征在于,每个旋风筒(1)侧壁上设有两个用于在旋风筒(1)中形成旋风的一次风口(11)。
- 根据权利要求1所述的一种褐煤半焦贫氧燃烧锅炉,其特征在于,锅炉受热面(3)塔式布置。
- 根据权利要求2所述的一种褐煤半焦贫氧燃烧锅炉,其特征在于,褐煤半焦粉在一次空气作用下沿切向或割向从旋风筒下部一次风口(11)进入中心筒和旋风筒之间的环形空间,在环形空间的下部形成为高温燃烧气化区,在这个区域保持过量空气系数小于1,维持反应为 贫氧燃烧氛围;生成烟气在旋风筒内强烈旋转脱除液态熔渣,然后烟气通过二燃室与旋风筒之间的烟气导管(7)进入二燃室,在进入二燃室时补充部分二次空气,以旋转射流进入二燃室;烟气在二燃室内充分燃烧并进一步放热,然后生成高温烟气上行分别通过塔式布置的锅炉各个受热面,完成传热,将烟气降低至排烟温度后从排烟口排出。
- 根据权利要求2所述的一种褐煤半焦贫氧燃烧锅炉,其特征在于,中心筒和旋风筒由氮化硅材料制成,中心筒和旋风筒之间形成的旋风燃烧室为绝热燃烧室。
- 根据权利要求2所述的一种褐煤半焦贫氧燃烧锅炉,其特征在于,二燃室内进行的燃烧为均相燃烧,过量空气系数为1.05~1.1;熔融渣池(10)上方反应区的温度比灰熔融温度高100~200℃。
- 根据权利要求1所述的一种褐煤半焦贫氧燃烧锅炉,其特征在于,旋风筒贫氧燃烧装置为多个且均匀分布于锅炉本体外周。
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CN116086147A (zh) * | 2022-12-19 | 2023-05-09 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种防止钛精矿低温干燥回转窑板结的装置及方法 |
CN116086147B (zh) * | 2022-12-19 | 2024-04-26 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种防止钛精矿低温干燥回转窑板结的装置及方法 |
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