WO2017149908A1 - Polarizing plate - Google Patents
Polarizing plate Download PDFInfo
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- WO2017149908A1 WO2017149908A1 PCT/JP2016/088100 JP2016088100W WO2017149908A1 WO 2017149908 A1 WO2017149908 A1 WO 2017149908A1 JP 2016088100 W JP2016088100 W JP 2016088100W WO 2017149908 A1 WO2017149908 A1 WO 2017149908A1
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- WIPO (PCT)
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- resin
- film
- base material
- polarizing plate
- stretching
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00634—Production of filters
- B29D11/00644—Production of filters polarizing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
Definitions
- the present invention relates to a polarizing plate.
- a method has been proposed in which a polarizing film is obtained by forming a polyvinyl alcohol-based resin layer on a resin substrate and stretching and dyeing the laminate (for example, Patent Document 1). According to such a method, a polarizing film having a small thickness can be obtained, and thus, for example, it has been attracting attention as being able to contribute to the thinning of the image display device.
- the polarizing film can be used as it is laminated on the resin substrate (Patent Document 2).
- Patent Document 2 since a crack may occur in the polarizing plate, improvement in durability is required.
- JP 2000-338329 A Japanese Patent No. 4997833
- the present invention has been made in order to solve the above problems, and its main purpose is a polarizing plate that can be used while the polarizing film is laminated on the resin base material, and has improved durability. It is to provide a polarizing plate.
- a polarizing plate having a resin substrate and a polarizing film having a thickness of 10 ⁇ m or less laminated on one side of the resin substrate.
- the polarizing plate satisfies the following formulas (1) and (2).
- SUB1 and POL1 mean the dimensional change rate (%) of the resin substrate and the dimensional change rate (%) of the polarizing film, respectively, in the absorption axis direction of the polarizing film.
- the resin substrate is a polyester resin substrate.
- the polarizing film is laminated on one side of the resin base material without an adhesive layer.
- the polarizing plate does not have a protective film on the side of the polarizing film opposite to the side on which the resin base material is laminated.
- the polarizing plate has an easy adhesion layer between the resin base material and the polarizing film.
- the manufacturing method of the said polarizing plate is provided. The production method includes forming a polyvinyl alcohol-based resin film on a resin base material to produce a laminate, stretching the laminate, dyeing the polyvinyl alcohol-based resin film, and the resin group. Crystallizing the material.
- the dimensional change rate of the resin substrate and the dimensional change rate of the polarizing film are By controlling so as to satisfy the specific relationship, a polarizing plate can be used with the polarizing film laminated on the resin substrate, and a polarizing plate excellent in durability can be obtained.
- (A) And (b) is a schematic sectional drawing of the polarizing plate in one embodiment of this invention, respectively.
- the polarizing plate of the present invention has a resin substrate and a polarizing film having a thickness of 10 ⁇ m or less laminated on one side of the resin substrate.
- Fig.1 (a) is a schematic sectional drawing of the polarizing plate in one Embodiment of this invention.
- the polarizing plate 10a includes a resin base material 11 and a polarizing film 12 laminated in close contact with one surface of the resin base material 11 (in other words, without an adhesive layer).
- FIG.1 (b) is a schematic sectional drawing of the polarizing plate in another embodiment of this invention.
- the polarizing plate 10 b further includes a protective film 13.
- the protective film 13 is arrange
- the protective film 13 may be laminated on the polarizing film 12 via an adhesive layer, or may be laminated in close contact (without an adhesive layer).
- the resin base material 11 can function as a protective film.
- the polarizing plates 10 a and 10 b may have an easy adhesion layer (not shown) between the resin base material 11 and the polarizing film 12.
- the polarizing plate of the present invention satisfies the following formulas (1) and (2).
- SUB1 and POL1 mean the dimensional change rate (%) of the resin base material in the absorption axis direction of the polarizing film and the dimensional change rate (%) of the polarizing film, respectively
- SUB2 and POL2 Means the dimensional change rate (%) of the resin substrate and the dimensional change rate (%) of the polarizing film in a direction perpendicular to the absorption axis direction, respectively.
- the absorption axis direction of the polarizing film is substantially parallel to the stretching direction of the laminate in the method for producing a polarizing plate described later.
- the “perpendicular direction” includes a case of 90 ° ⁇ 5.0 °, preferably 90 ° ⁇ 3.0 °, more preferably 90 ° ⁇ 1.0 °. is there.
- the “parallel direction” includes the case of 0 ° ⁇ 5.0 °, preferably 0 ° ⁇ 3.0 °, more preferably 0 ° ⁇ 1.0 °.
- the dimensional change rate is measured according to the method described in Examples described later.
- the difference in the dimensional change rate between the resin substrate and the polarizing film in the direction orthogonal to the absorption axis direction of the polarizing film is These differences are approximated so as not to be too large than the difference in dimensional change between the substrate and the polarizing film.
- the distortion generated at the resin substrate / polarizing film interface is prevented from being concentrated in the direction perpendicular to the absorption axis direction of the polarizing film and is dispersed in both directions, so that the generation of cracks can be suppressed.
- the difference in dimensional change rate (absolute value) is preferably 0.8 or less, more preferably 0.5 or less.
- is preferably -1.5 or more, more preferably -1.0 or more, and further preferably -0.5 or more. Even if the formula (1) is satisfied, if the difference in the dimensional change rate between the resin substrate and the polarizing film in the direction orthogonal to the absorption axis direction of the polarizing film is large, the strain is concentrated in that direction. And cracks can occur.
- the difference between the dimensional change rate of the resin substrate and the dimensional change rate of the polarizing film in the direction is within a predetermined range, so that cracks are Generation
- is preferably 4.5 or less, more preferably 4.0 or less.
- is preferably 0 or more.
- concentration in a polarizing film is mentioned, for example.
- the polarizing film is substantially a PVA resin film in which iodine is adsorbed and oriented.
- the thickness of the polarizing film is 10 ⁇ m or less, preferably 7.5 ⁇ m or less, more preferably 5 ⁇ m or less.
- the thickness of the polarizing film is preferably 0.5 ⁇ m or more, more preferably 1.5 ⁇ m or more. If the thickness is too thin, the optical properties of the obtained polarizing film may be deteriorated.
- the polarizing film preferably exhibits absorption dichroism at any wavelength of 380 nm to 780 nm.
- the single transmittance of the polarizing film is preferably 40.0% or more, more preferably 41.0% or more, and further preferably 42.0% or more.
- the polarization degree of the polarizing film is preferably 99.8% or more, more preferably 99.9% or more, and further preferably 99.95% or more.
- any appropriate resin can be adopted as the PVA resin for forming the PVA resin film.
- Examples thereof include polyvinyl alcohol and ethylene-vinyl alcohol copolymer.
- Polyvinyl alcohol is obtained by saponifying polyvinyl acetate.
- the ethylene-vinyl alcohol copolymer can be obtained by saponifying an ethylene-vinyl acetate copolymer.
- the degree of saponification of the PVA-based resin is usually 85 mol% to 100 mol%, preferably 95.0 mol% to 99.95 mol%, more preferably 99.0 mol% to 99.93 mol%. .
- the degree of saponification can be determined according to JIS K 6726-1994. By using a PVA-based resin having such a saponification degree, a polarizing film having excellent durability can be obtained. If the degree of saponification is too high, there is a risk of gelation.
- the average degree of polymerization of the PVA resin can be appropriately selected according to the purpose.
- the average degree of polymerization is usually 1000 to 10,000, preferably 1200 to 4500, and more preferably 1500 to 4300.
- the average degree of polymerization can be determined according to JIS K 6726-1994.
- the polarizing film typically contains boric acid.
- the boric acid concentration in the polarizing film is preferably 10% by weight to 20% by weight, more preferably 12% by weight to 19% by weight. When the boric acid concentration is within this range, the dimensional stability of the polarizing film is improved, and the above formulas (1) and (2) can be preferably satisfied.
- the boric acid concentration in the polarizing film is, for example, changing the boric acid concentration in a stretching bath, an insolubilizing bath, a cross-linking bath, etc., and changing the immersion time in these baths, etc. Can be adjusted.
- the boric acid concentration (% by weight) in the polarizing film can be determined using, for example, a boric acid amount index calculated from total reflection attenuation spectroscopy (ATR) measurement.
- (Boric acid amount index) (Intensity of boric acid peak 665 cm ⁇ 1 ) / (Intensity of reference peak 2941 cm ⁇ 1 )
- (Boric acid concentration) (Boric acid amount index) ⁇ 5.54 + 4.1
- both “5.54” and “4.1” are constants obtained by measuring the fluorescent X-ray intensity of a sample having a known boric acid concentration and creating a calibration curve.
- thermoplastic resin base material Any appropriate thermoplastic resin base material may be employed as the resin base material.
- a polyester resin is preferable.
- the polyester-based resin include polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyethylene naphthalate (PEN), isophthalic acid, cycloaliphatic dicarboxylic acid including cyclohexane ring, and alicyclic diol.
- PET-G polyethylene terephthalate
- PBT polybutylene terephthalate
- PEN polyethylene naphthalate
- isophthalic acid cycloaliphatic dicarboxylic acid including cyclohexane ring
- alicyclic diol Copolymerized PET (PET-G), other polyesters, and copolymers and blends thereof can be used. Among these, it is preferable to use PET or copolymerized PET.
- the glass transition temperature (Tg) of the resin base material is preferably 170 ° C. or lower. By using such a resin base material, it is possible to sufficiently ensure stretchability while suppressing crystallization of the PVA-based resin film. Considering plasticization of the resin base material with water and good stretching in water, it is more preferably 120 ° C. or lower. In one embodiment, the glass transition temperature of the resin substrate is preferably 60 ° C. or higher. By using such a resin base material, when applying and drying a coating solution containing a PVA resin, which will be described later, the resin base material is deformed (for example, generation of unevenness, tarmi, wrinkles, etc.). Can be prevented.
- the laminate can be stretched at a suitable temperature (eg, about 60 ° C. to 70 ° C.).
- a glass transition temperature lower than 60 ° C. may be used as long as the resin base material does not deform when applying and drying a coating solution containing a PVA-based resin.
- the glass transition temperature (Tg) is a value determined according to JIS K 7121.
- the resin base material preferably has a water absorption rate of 0.2% or more, and more preferably 0.3% or more.
- a resin base material absorbs water, and the water can act as a plasticizer to be plasticized.
- the stretching stress can be greatly reduced in stretching in water, and the stretchability can be excellent.
- the water absorption rate of the resin base material is preferably 3.0% or less, more preferably 1.0% or less.
- the thickness of the resin base material is preferably 10 ⁇ m to 200 ⁇ m, more preferably 20 ⁇ m to 150 ⁇ m.
- the crystallinity calculated by the total reflection attenuation spectroscopy (ATR) measurement of the polyester base resin base material is preferably 0.55 to 0.80, more preferably 0. .58 to 0.80, more preferably 0.60 to 0.75.
- the degree of crystallinity of the polyester-based resin substrate is within the range, the dimensional change rate of the resin substrate can be set to a value close to the dimensional change rate of the polarizing film. Therefore, the above formulas (1) and (2) Can be suitably satisfied.
- the degree of crystallization of the polyester resin substrate can be adjusted, for example, by changing the heating temperature and / or the heating time for crystallization.
- crystallinity degree of the said polyester-type resin base material is computed based on the following formula
- equation. (Crystallinity) (Intensity of crystal peak 1340 cm ⁇ 1 ) / (Intensity of reference peak 1410 cm ⁇ 1 )
- Protective film examples of the material for forming the protective film include (meth) acrylic resins, cellulose resins such as diacetyl cellulose and triacetyl cellulose, cycloolefin resins, olefin resins such as polypropylene, and polyethylene terephthalate resins. Examples thereof include ester resins, polyamide resins, polycarbonate resins, and copolymer resins thereof.
- the thickness of the protective film is preferably 10 ⁇ m to 100 ⁇ m.
- the easy-adhesion layer may be a layer formed substantially only from the composition for forming an easy-adhesion layer, and the composition for forming an easy-adhesion layer and the material for forming the polarizing film are mixed (compatible). A layer or region that is included). By forming the easy adhesion layer, excellent adhesion can be obtained.
- the thickness of the easy adhesion layer is preferably about 0.05 ⁇ m to 1 ⁇ m.
- the easy adhesion layer can be confirmed, for example, by observing the cross section of the polarizing plate with a scanning electron microscope (SEM).
- SEM scanning electron microscope
- Adhesive layer is formed of any suitable adhesive or adhesive.
- the pressure-sensitive adhesive layer is typically formed of an acrylic pressure-sensitive adhesive.
- the adhesive layer is typically formed of a vinyl alcohol adhesive.
- the manufacturing method of the polarizing plate of the present invention typically comprises forming a PVA resin film on a resin substrate to produce a laminate, stretching the laminate, Dyeing the PVA resin film and crystallizing the resin substrate.
- a PVA-based resin film is formed by applying a coating liquid containing a PVA-based resin on a resin base material and drying it.
- an easy-adhesion layer forming composition is applied on a resin substrate and dried to form an easy-adhesion layer, and a PVA-based resin film is formed on the easy-adhesion layer.
- the material for forming the resin base material is as described above.
- the thickness of the resin base material is preferably 20 ⁇ m to 300 ⁇ m, more preferably 50 ⁇ m to 200 ⁇ m. If it is less than 20 ⁇ m, it may be difficult to form a PVA resin film. If it exceeds 300 ⁇ m, for example, in stretching in water, it takes a long time for the resin base material to absorb water, and an excessive load may be required for stretching.
- the degree of crystallinity calculated by the total reflection attenuation spectroscopy (ATR) measurement of the resin substrate when used in the production of the laminate may be, for example, 0.20 to 0.50.
- the coating solution is typically a solution obtained by dissolving the PVA resin in a solvent.
- the solvent include water, dimethyl sulfoxide, dimethylformamide, dimethylacetamide, N-methylpyrrolidone, various glycols, polyhydric alcohols such as trimethylolpropane, and amines such as ethylenediamine and diethylenetriamine. These may be used alone or in combination of two or more. Among these, water is preferable.
- the concentration of the PVA resin in the solution is preferably 3 to 20 parts by weight with respect to 100 parts by weight of the solvent. With such a resin concentration, a uniform coating film in close contact with the resin substrate can be formed.
- Additives may be added to the coating solution.
- the additive include a plasticizer and a surfactant.
- the plasticizer include polyhydric alcohols such as ethylene glycol and glycerin.
- the surfactant include nonionic surfactants. These can be used for the purpose of further improving the uniformity, dyeability and stretchability of the resulting PVA resin film.
- an easily bonding component is mentioned, for example. By using the easy-adhesive component, the adhesion between the resin base material and the PVA-based resin film can be improved. As a result, for example, problems such as peeling of the PVA-based resin film from the substrate can be suppressed, and dyeing and underwater stretching described later can be performed satisfactorily.
- modified PVA such as acetoacetyl-modified PVA is used.
- any appropriate method can be adopted as a coating method of the coating solution. Examples thereof include a roll coating method, a spin coating method, a wire bar coating method, a dip coating method, a die coating method, a curtain coating method, a spray coating method, a knife coating method (comma coating method and the like).
- the coating / drying temperature of the coating solution is preferably 50 ° C. or higher.
- the thickness of the PVA resin film is preferably 3 ⁇ m to 20 ⁇ m.
- the resin base material Before forming the PVA-based resin film, the resin base material may be subjected to a surface treatment (for example, corona treatment), or an easy-adhesion layer forming composition is applied (coating treatment) on the resin base material. Also good. By performing such treatment, the adhesion between the resin base material and the PVA-based resin film can be improved. As a result, for example, problems such as peeling of the PVA resin film from the substrate can be suppressed, and dyeing and stretching described below can be performed satisfactorily.
- a surface treatment for example, corona treatment
- an easy-adhesion layer forming composition is applied
- the easy-adhesion layer-forming composition preferably contains a polyvinyl alcohol-based component.
- Any appropriate PVA-based resin can be used as the polyvinyl alcohol-based component.
- Specific examples include polyvinyl alcohol and modified polyvinyl alcohol.
- the modified polyvinyl alcohol include polyvinyl alcohol modified with an acetoacetyl group, a carboxylic acid group, an acrylic group and / or a urethane group.
- acetoacetyl-modified PVA is preferably used.
- a polymer having at least a repeating unit represented by the following general formula (I) is preferably used as the acetoacetyl-modified PVA.
- the ratio of n to l + m + n is preferably 1% to 10%.
- the average degree of polymerization of the acetoacetyl-modified PVA is preferably 1000 to 10,000, and preferably 1200 to 5,000.
- the saponification degree of acetoacetyl-modified PVA is preferably 97 mol% or more.
- the pH of a 4% by weight aqueous solution of acetoacetyl-modified PVA is preferably 3.5 to 5.5.
- the average polymerization degree and saponification degree can be determined according to JIS K 6726-1994.
- the easy-adhesion layer-forming composition may further contain a polyolefin-based component, a polyester-based component, a polyacrylic-based component, or the like depending on the purpose.
- the easily adhesive layer forming composition further includes a polyolefin-based component.
- any appropriate polyolefin resin can be used as the polyolefin component.
- the olefin component that is a main component of the polyolefin resin include olefin hydrocarbons having 2 to 6 carbon atoms such as ethylene, propylene, isobutylene, 1-butene, 1-pentene, and 1-hexene. These may be used alone or in combination of two or more. Among these, olefinic hydrocarbons having 2 to 4 carbon atoms such as ethylene, propylene, isobutylene and 1-butene are preferable, and ethylene is more preferably used.
- the proportion of the olefin component in the monomer component constituting the polyolefin resin is preferably 50% by weight to 95% by weight.
- the polyolefin-based resin preferably has a carboxyl group and / or an anhydride group thereof.
- a polyolefin resin can be dispersed in water, and an easy-adhesion layer can be formed well.
- the monomer component having such a functional group include unsaturated carboxylic acids and anhydrides thereof, half esters and half amides of unsaturated dicarboxylic acids. Specific examples thereof include acrylic acid, methacrylic acid, maleic acid, maleic anhydride, itaconic acid, itaconic anhydride, fumaric acid and crotonic acid.
- the molecular weight of the polyolefin resin is, for example, 5000 to 80000.
- the blending ratio of the polyvinyl alcohol component to the polyolefin component is preferably 5:95 to 60:40, more preferably 20:80 to 50. : 50.
- the peeling force required when peeling the polarizing film from the resin base material may be reduced, and sufficient adhesion may not be obtained.
- the external appearance of the polarizing plate obtained may be impaired.
- the easy-adhesion layer is formed, a problem such as white turbidity of the coating film may occur, which may make it difficult to obtain a polarizing plate having an excellent appearance.
- the easy-adhesion layer-forming composition is preferably aqueous.
- the easily adhesive layer forming composition may contain an organic solvent. Examples of the organic solvent include ethanol and isopropanol.
- the solid content concentration of the easily adhesive layer forming composition is preferably 1.0% by weight to 10% by weight.
- Arbitrary appropriate methods can be employ
- the coating film After application of the easy-adhesion layer-forming composition, the coating film can be dried.
- the drying temperature is, for example, 50 ° C. or higher.
- Stretching Any appropriate method can be adopted as a stretching method of the laminate. Specifically, it may be fixed end stretching (for example, a method using a tenter stretching machine) or free end stretching (for example, a method of uniaxial stretching through a laminate between rolls having different peripheral speeds). Moreover, simultaneous biaxial stretching (for example, a method using a simultaneous biaxial stretching machine) or sequential biaxial stretching may be used.
- the stretching of the laminate may be performed in one stage or in multiple stages. When performed in multiple stages, the draw ratio (maximum draw ratio) of the laminate described later is the product of the draw ratios of the respective stages.
- the stretching treatment may be an underwater stretching method performed by immersing the laminate in a stretching bath, or an air stretching method.
- the underwater stretching treatment is performed at least once, and preferably the underwater stretching treatment and the air stretching treatment are combined.
- the PVA resin film can be stretched at a temperature lower than the glass transition temperature (typically about 80 ° C.) of the resin base material or the PVA resin film while suppressing its crystallization. It can be stretched at a high magnification. As a result, a polarizing film having excellent polarization characteristics can be manufactured.
- any appropriate direction can be selected as the stretching direction of the laminate. In one embodiment, it extends
- the stretching temperature of the laminate can be set to any appropriate value depending on the resin base material, the stretching method, and the like.
- the stretching temperature is preferably equal to or higher than the glass transition temperature (Tg) of the resin substrate, more preferably the glass transition temperature (Tg) of the resin substrate + 10 ° C., and particularly preferably Tg + 15 ° C. That's it.
- the stretching temperature of the laminate is preferably 170 ° C. or lower.
- the liquid temperature of the stretching bath is preferably 40 ° C. to 85 ° C., more preferably 50 ° C. to 85 ° C. If it is such temperature, it can extend
- the glass transition temperature (Tg) of the resin base material is preferably 60 ° C. or higher in relation to the formation of the PVA-based resin film.
- the stretching temperature is lower than 40 ° C., there is a possibility that the stretching cannot be satisfactorily performed even in consideration of plasticization of the resin base material with water.
- the higher the temperature of the stretching bath the higher the solubility of the PVA-based resin film, and there is a possibility that excellent polarization characteristics cannot be obtained.
- the laminate When employing an underwater stretching method, it is preferable to stretch the laminate by immersing it in an aqueous boric acid solution (stretching in boric acid in water).
- an aqueous boric acid solution stretching in boric acid in water.
- boric acid aqueous solution as the stretching bath, the PVA resin film can be provided with rigidity that can withstand the tension applied during stretching and water resistance that does not dissolve in water.
- boric acid can form a tetrahydroxyborate anion in an aqueous solution and crosslink with a PVA resin by hydrogen bonding.
- rigidity and water resistance can be imparted to the PVA-based resin film, the film can be stretched well, and a polarizing film having excellent polarization characteristics can be produced.
- the boric acid aqueous solution is preferably obtained by dissolving boric acid and / or borate in water as a solvent.
- the boric acid concentration is preferably 1 to 10 parts by weight with respect to 100 parts by weight of water. By setting the boric acid concentration to 1 part by weight or more, dissolution of the PVA-based resin film can be effectively suppressed, and a polarizing film having higher characteristics can be produced.
- an aqueous solution obtained by dissolving a boron compound such as borax, glyoxal, glutaraldehyde, or the like in a solvent can also be used.
- iodide is blended in the stretching bath (boric acid aqueous solution).
- the iodide include potassium iodide, lithium iodide, sodium iodide, zinc iodide, aluminum iodide, lead iodide, copper iodide, barium iodide, calcium iodide, tin iodide, and titanium iodide.
- potassium iodide is preferable.
- the concentration of iodide is preferably 0.05 to 15 parts by weight, more preferably 0.5 to 8 parts by weight with respect to 100 parts by weight of water.
- the immersion time of the laminate in the stretching bath is preferably 15 seconds to 5 minutes.
- the underwater stretching process is performed after the dyeing process.
- the draw ratio (maximum draw ratio) of the laminate is preferably 4.0 times or more, more preferably 5.0 times or more with respect to the original length of the laminate. Such a high draw ratio can be achieved, for example, by employing an underwater drawing method (boric acid underwater drawing).
- the “maximum stretch ratio” refers to a stretch ratio immediately before the laminate is ruptured. Separately, a stretch ratio at which the laminate is ruptured is confirmed, and a value that is 0.2 lower than that value. .
- the dyeing of the PVA resin film is typically performed by adsorbing iodine to the PVA resin film.
- adsorption method for example, a method of immersing a PVA resin film (laminated body) in a staining solution containing iodine, a method of applying the staining solution to the PVA resin film, and applying the staining solution to the PVA resin film The method of spraying etc. are mentioned.
- the PVA resin film (laminate) is immersed in the dyeing solution. This is because iodine can be adsorbed well.
- the staining solution is preferably an iodine aqueous solution.
- the amount of iodine is preferably 0.1 to 0.5 parts by weight with respect to 100 parts by weight of water.
- an iodide is added to the aqueous iodine solution. Specific examples of the iodide are as described above.
- the blending amount of iodide is preferably 0.02 to 20 parts by weight, more preferably 0.1 to 10 parts by weight with respect to 100 parts by weight of water.
- the liquid temperature during dyeing of the dyeing liquid is preferably 20 ° C. to 50 ° C. in order to suppress dissolution of the PVA resin.
- the immersion time is preferably 5 seconds to 5 minutes in order to ensure the transmittance of the PVA resin film.
- the staining conditions concentration, liquid temperature, immersion time
- immersion time is set so that the polarization degree of the polarizing film obtained may be 99.98% or more.
- the immersion time is set so that the obtained polarizing film has a single transmittance of 40% to 44%.
- the staining process can be performed at any appropriate timing.
- it performs before an underwater extending
- Crystallization of the resin base material is performed, for example, by heating the resin base material (substantially a laminate). Crystallization is preferably performed after dyeing and stretching the PVA resin film.
- the heating temperature is typically a temperature exceeding the glass transition temperature (Tg) of the resin base material.
- the heating temperature is preferably 90 ° C. or higher, more preferably 100 ° C. or higher.
- the heating temperature is preferably 125 ° C. or lower, more preferably 120 ° C. or lower.
- the heating time can be appropriately set according to the heating temperature and the like. The heating time can be, for example, 3 seconds to 2 minutes.
- the haze value of the resin base material is 2% or less.
- the PVA-based resin film may be appropriately subjected to treatment for forming a polarizing film.
- the treatment for forming the polarizing film include insolubilization treatment, crosslinking treatment, washing treatment, and drying treatment.
- count, order, etc. of these processes are not specifically limited.
- the insolubilization treatment is typically performed by immersing a PVA resin film (laminate) in a boric acid aqueous solution.
- a boric acid aqueous solution By performing the insolubilization treatment, water resistance can be imparted to the PVA resin film.
- the concentration of the boric acid aqueous solution is preferably 1 to 4 parts by weight with respect to 100 parts by weight of water.
- the liquid temperature of the insolubilizing bath (boric acid aqueous solution) is preferably 20 ° C. to 50 ° C.
- the insolubilization treatment is performed before the above-described underwater stretching or the above-described dyeing treatment.
- the cross-linking treatment is typically performed by immersing a PVA resin film (laminate) in an aqueous boric acid solution.
- the concentration of the boric acid aqueous solution is preferably 1 to 5 parts by weight with respect to 100 parts by weight of water.
- blend an iodide it is preferable to mix
- the blending amount of iodide is preferably 1 to 5 parts by weight with respect to 100 parts by weight of water.
- the liquid temperature of the crosslinking bath is preferably 20 ° C. to 60 ° C.
- the crosslinking treatment is performed before the underwater stretching. In a preferred embodiment, air stretching, dyeing treatment and crosslinking treatment are performed in this order.
- the above-described cleaning treatment is typically performed by immersing a PVA resin film (laminated body) in a potassium iodide aqueous solution.
- the drying temperature in the drying treatment is preferably 30 ° C. to 100 ° C.
- the polarizing plate of the present invention can be obtained by forming the polarizing film on the resin substrate and crystallizing the resin substrate.
- the polarizing plate of the present invention can be mounted on, for example, a liquid crystal display device.
- the polarizing film is mounted so as to be disposed closer to the liquid crystal cell than the resin base material. According to such a structure, the influence which the phase difference which a resin base material can have on the image characteristic of the liquid crystal display device obtained can be excluded.
- Example 6 After the temperature was raised in minutes, the dimensional change rate was further measured when held at 100 ° C. for 60 minutes.
- the polarizing film and the resin substrate were isolated in the same procedure from the polarizing plate prepared in the same manner except that the easy-adhesion layer was not formed. The dimensional change of the polarizing film and the resin base material was used.
- Dimensional change rate (%) (Dimension after heat treatment ⁇ Dimension before heat treatment) / Dimension before heat treatment ⁇ 100 ⁇ Crystallinity ⁇
- the polyester-based resin base materials obtained in the examples and comparative examples were subjected to total reflection attenuation spectroscopy (ATR) using a Fourier transform infrared spectrophotometer (FT-IR) (manufactured by Perkin Elmer, trade name “SPECTRUM2000”).
- FT-IR Fourier transform infrared spectrophotometer
- the intensity of the crystal peak (1340 cm ⁇ 1 ) and the intensity of the reference peak (1410 cm ⁇ 1 ) were measured by measurement.
- the crystallinity was calculated by the following formula from the obtained crystal peak intensity and reference peak intensity.
- (Crystallinity) (Intensity of crystal peak 1340 cm ⁇ 1 ) / (Intensity of reference peak 1410 cm ⁇ 1 ) ⁇ Glass transition temperature: Tg ⁇ Measured according to JIS K 7121. ⁇ Boric acid concentration ⁇ Using the Fourier transform infrared spectrophotometer (FT-IR) (manufactured by Perkin Elmer, trade name “SPECTRUM2000”) for the polarizing films obtained in Examples and Comparative Examples, total reflection attenuation using polarized light as measurement light The intensity of the boric acid peak (665 cm ⁇ 1 ) and the intensity of the reference peak (2941 cm ⁇ 1 ) were measured by spectroscopic (ATR) measurement.
- FT-IR Fourier transform infrared spectrophotometer
- the boric acid amount index was calculated from the obtained boric acid peak intensity and the reference peak intensity by the following formula, and the boric acid concentration was determined from the calculated boric acid amount index by the following formula.
- (Boric acid amount index) (Intensity of boric acid peak 665 cm ⁇ 1 ) / (Intensity of reference peak 2941 cm ⁇ 1 )
- (Boric acid concentration) (Boric acid amount index) ⁇ 5.54 + 4.1 ⁇ Crack evaluation ⁇
- the polarizing plates obtained in the examples and comparative examples were heated in an oven at 100 ° C. for 240 hours in a state of being bonded to glass through an adhesive so that the polyester resin substrate was on the surface side. The presence or absence of cracks in the polarizing plate after heating was confirmed and evaluated according to the following criteria. Good: No cracking Defect: There is a crack
- Example 1 As the resin substrate, an amorphous isophthalic acid copolymerized polyethylene terephthalate (IPA copolymerized PET) film (thickness: 100 ⁇ m) having a long water absorption rate of 0.75% and Tg of 75 ° C. was used.
- One side of the resin substrate was subjected to corona treatment, and polyvinyl alcohol (polymerization degree 4200, saponification degree 99.2 mol%) and acetoacetyl-modified PVA (polymerization degree 1200, acetoacetyl modification degree 4.
- the obtained laminate was uniaxially stretched at a free end 1.8 times in the longitudinal direction (longitudinal direction) between rolls having different peripheral speeds in an oven at 120 ° C. (air-assisted stretching).
- the laminate was immersed in an insolubilization bath (a boric acid aqueous solution obtained by blending 4 parts by weight of boric acid with respect to 100 parts by weight of water) for 30 seconds (insolubilization treatment).
- an insolubilization bath a boric acid aqueous solution obtained by blending 4 parts by weight of boric acid with respect to 100 parts by weight of water
- insolubilization treatment a dyeing bath at 30 ° C.
- a boric acid aqueous solution obtained by blending 3 parts by weight of potassium iodide and 3 parts by weight of boric acid with respect to 100 parts by weight of water was immersed for 30 seconds in a crosslinking bath having a liquid temperature of 30 ° C.
- a boric acid aqueous solution obtained by blending 3 parts by weight of potassium iodide and 3 parts by weight of boric acid with respect to 100 parts by weight of water (Crosslinking treatment).
- the laminate is immersed in a boric acid aqueous solution (an aqueous solution obtained by blending 3 parts by weight of boric acid and 5 parts by weight of potassium iodide with respect to 100 parts by weight of water) at a liquid temperature of 70 ° C.
- the laminate was put into an oven at 100 ° C. for 30 seconds to crystallize the resin base material.
- a polarizing plate in which a polarizing film having a thickness of 5 ⁇ m was laminated on the resin base material was obtained.
- Example 2 A polarizing plate was obtained in the same manner as in Example 1 except that the laminate was placed in an oven at 110 ° C. for 30 seconds to crystallize the resin substrate.
- Example 3 A polarizing plate was obtained in the same manner as in Example 1 except that the laminate was placed in an oven at 120 ° C. for 30 seconds to crystallize the resin substrate.
- Example 4 Example 1 except that the amount of boric acid in the stretching bath during stretching in water was 3.5 parts by weight, and the laminate was put into an oven at 110 ° C. for 30 seconds to crystallize the resin substrate. In the same manner, a polarizing plate was obtained.
- Example 5 Example 1 except that the amount of boric acid in the stretching bath during stretching in water was 2.5 parts by weight, and the laminate was put into an oven at 110 ° C. for 30 seconds to crystallize the resin substrate. In the same manner, a polarizing plate was obtained.
- the easy adhesion layer was provided on one side of the resin base material by the following method.
- One side of the resin base material is subjected to corona treatment, and this corona treatment surface is subjected to acetoacetyl-modified PVA (manufactured by Nippon Synthetic Chemical Industry Co., Ltd., trade name “Gosefimer Z200”, polymerization degree 1200, saponification degree 99.0 mol. %, Acetoacetyl modification degree 4.6%) and a modified polyolefin resin aqueous dispersion (manufactured by Unitika Ltd., trade name “Arrow Base SE1030N”, solid content concentration 22%) and pure water were mixed.
- the mixture (solid content concentration 4.0%) was applied so that the thickness after drying was 2000 nm, and dried at 60 ° C. for 3 minutes to form an easy-adhesion layer.
- the solid content mixing ratio of acetoacetyl-modified PVA and modified polyolefin in the mixed solution was 30:70.
- a polarizing plate was obtained in the same manner as in Example 1 except that the surface of the easy-adhesion layer was subjected to corona treatment and a PVA resin layer was formed on the corona-treated surface.
- Example 1 A polarizing plate was obtained in the same manner as in Example 1 except that the laminate was placed in an oven at 85 ° C. for 30 seconds to crystallize the resin substrate.
- Example 2 Example 1 except that the amount of boric acid in the stretching bath during stretching in water was 4.0 parts by weight, and the laminate was put into an oven at 110 ° C. for 30 seconds to crystallize the resin substrate. In the same manner, a polarizing plate was obtained.
- Example 3 A polarizing plate was obtained in the same manner as in Example 1 except that the laminate was put in an oven at 95 ° C. for 30 seconds to crystallize the resin substrate.
- Table 1 shows the production conditions of the polarizing plate and the characteristics of the obtained polarizing plate in Examples and Comparative Examples.
- the polarizing plate of the example satisfying both the expressions (1) and (2) generation of cracks is suppressed.
- the polarizing plate of the comparative example is cracked and inferior in durability to the polarizing plate of the example.
- the polarizing plate of Example 6 is superior in adhesion between the resin base material and the polarizing film (PVA-based resin layer) as compared to the polarizing plates of other examples or comparative examples. Further, undesired peeling or floating of the polarizing film (PVA resin layer) or the resin base material during processing of the polarizing plate (for example, punching) was suitably prevented.
- the polarizing plate of the present invention is suitably used for an image display device, for example.
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Abstract
Description
|SUB2-POL2|-|SUB1-POL1|<1.0 (1)
|SUB2-POL2|<5.0 (2)
(式(1)および(2)において、SUB1およびPOL1はそれぞれ、該偏光膜の吸収軸方向における該樹脂基材の寸法変化率(%)および該偏光膜の寸法変化率(%)を意味し、SUB2およびPOL2はそれぞれ、該吸収軸方向と直交する方向における該樹脂基材の寸法変化率(%)および該偏光膜の寸法変化率(%)を意味する)。
1つの実施形態において、上記樹脂基材が、ポリエステル系樹脂基材である。
1つの実施形態において、上記偏光膜が、上記樹脂基材の片側に接着層を介することなく積層されている。
1つの実施形態においては、上記偏光板は、上記偏光膜の上記樹脂基材が積層される側と反対側に、保護フィルムを有さない。
1つの実施形態においては、上記偏光板は、上記樹脂基材と上記偏光膜との間に易接着層を有する。
本発明の別の局面によれば、上記偏光板の製造方法が提供される。該製造方法は、樹脂基材上にポリビニルアルコール系樹脂膜を形成して積層体を作製すること、該積層体を延伸すること、該ポリビニルアルコール系樹脂膜を染色すること、および、該樹脂基材を結晶化すること、を含む。 According to the present invention, there is provided a polarizing plate having a resin substrate and a polarizing film having a thickness of 10 μm or less laminated on one side of the resin substrate. The polarizing plate satisfies the following formulas (1) and (2).
SUB2-POL2 |-| SUB1-POL1 | <1.0 (1)
SUB2-POL2 | <5.0 (2)
(In formulas (1) and (2), SUB1 and POL1 mean the dimensional change rate (%) of the resin substrate and the dimensional change rate (%) of the polarizing film, respectively, in the absorption axis direction of the polarizing film. , SUB2 and POL2 mean the dimensional change rate (%) of the resin substrate and the dimensional change rate (%) of the polarizing film in the direction orthogonal to the absorption axis direction, respectively).
In one embodiment, the resin substrate is a polyester resin substrate.
In one embodiment, the polarizing film is laminated on one side of the resin base material without an adhesive layer.
In one embodiment, the polarizing plate does not have a protective film on the side of the polarizing film opposite to the side on which the resin base material is laminated.
In one embodiment, the polarizing plate has an easy adhesion layer between the resin base material and the polarizing film.
According to another situation of this invention, the manufacturing method of the said polarizing plate is provided. The production method includes forming a polyvinyl alcohol-based resin film on a resin base material to produce a laminate, stretching the laminate, dyeing the polyvinyl alcohol-based resin film, and the resin group. Crystallizing the material.
本発明の偏光板は、樹脂基材と、該樹脂基材の片側に積層された厚みが10μm以下の偏光膜と、を有する。図1(a)は、本発明の1つの実施形態における偏光板の概略断面図である。偏光板10aは、樹脂基材11と、該樹脂基材11の一方の面に密着して(換言すれば、接着層を介さずに)積層された偏光膜12とを有する。図1(b)は、本発明の別の実施形態における偏光板の概略断面図である。偏光板10bは、保護フィルム13をさらに有する。保護フィルム13は、偏光膜12の樹脂基材11が配置されている側とは反対側に配置されている。保護フィルム13は、偏光膜12に接着層を介して積層されていてもよいし、密着させて(接着層を介さずに)積層されていてもよい。偏光板10a、10bにおいては、樹脂基材11が、保護フィルムとして機能し得る。本発明においては、偏光膜の作製過程における延伸および染色時に用いる樹脂基材を剥離することなく、保護フィルムとして用いることができ、偏光膜の片側にのみ該樹脂基材(保護フィルム)を有する構成(図1(a)の構成)であっても、クラックの発生を抑制し得る。なお、偏光板10a、10bは、樹脂基材11と偏光膜12との間に易接着層(図示せず)を有していてもよい。 A. Polarizing plate The polarizing plate of the present invention has a resin substrate and a polarizing film having a thickness of 10 μm or less laminated on one side of the resin substrate. Fig.1 (a) is a schematic sectional drawing of the polarizing plate in one Embodiment of this invention. The polarizing
|SUB2-POL2|-|SUB1-POL1|<1.0 (1)
|SUB2-POL2|<5.0 (2)
式(1)および(2)において、SUB1およびPOL1はそれぞれ、偏光膜の吸収軸方向における樹脂基材の寸法変化率(%)および偏光膜の寸法変化率(%)を意味し、SUB2およびPOL2はそれぞれ、該吸収軸方向と直交する方向における該樹脂基材の寸法変化率(%)および該偏光膜の寸法変化率(%)を意味する。該偏光膜の吸収軸方向は、実質的に、後述の偏光板の製造方法おける積層体の延伸方向と平行な方向である。なお、本明細書において、「直交する方向」とは、90°±5.0°である場合を包含し、好ましくは90°±3.0°、さらに好ましくは90°±1.0°である。また、「平行な方向」とは、0°±5.0°である場合を包含し、好ましくは0°±3.0°、さらに好ましくは0°±1.0°である。また、寸法変化率は後述の実施例に記載の方法に従って測定される。 The polarizing plate of the present invention satisfies the following formulas (1) and (2).
SUB2-POL2 |-| SUB1-POL1 | <1.0 (1)
SUB2-POL2 | <5.0 (2)
In formulas (1) and (2), SUB1 and POL1 mean the dimensional change rate (%) of the resin base material in the absorption axis direction of the polarizing film and the dimensional change rate (%) of the polarizing film, respectively, and SUB2 and POL2 Means the dimensional change rate (%) of the resin substrate and the dimensional change rate (%) of the polarizing film in a direction perpendicular to the absorption axis direction, respectively. The absorption axis direction of the polarizing film is substantially parallel to the stretching direction of the laminate in the method for producing a polarizing plate described later. In this specification, the “perpendicular direction” includes a case of 90 ° ± 5.0 °, preferably 90 ° ± 3.0 °, more preferably 90 ° ± 1.0 °. is there. The “parallel direction” includes the case of 0 ° ± 5.0 °, preferably 0 ° ± 3.0 °, more preferably 0 ° ± 1.0 °. Further, the dimensional change rate is measured according to the method described in Examples described later.
上記偏光膜は、実質的には、ヨウ素が吸着配向されたPVA系樹脂膜である。偏光膜の厚みは、10μm以下、好ましくは7.5μm以下、より好ましくは5μm以下である。一方、偏光膜の厚みは、好ましくは0.5μm以上、より好ましくは1.5μm以上である。厚みが薄すぎると得られる偏光膜の光学特性が低下するおそれがある。偏光膜は、好ましくは、波長380nm~780nmのいずれかの波長で吸収二色性を示す。偏光膜の単体透過率は、好ましくは40.0%以上、より好ましくは41.0%以上、さらに好ましくは42.0%以上である。偏光膜の偏光度は、好ましくは99.8%以上、より好ましくは99.9%以上、さらに好ましくは99.95%以上である。 A-1. Polarizing film The polarizing film is substantially a PVA resin film in which iodine is adsorbed and oriented. The thickness of the polarizing film is 10 μm or less, preferably 7.5 μm or less, more preferably 5 μm or less. On the other hand, the thickness of the polarizing film is preferably 0.5 μm or more, more preferably 1.5 μm or more. If the thickness is too thin, the optical properties of the obtained polarizing film may be deteriorated. The polarizing film preferably exhibits absorption dichroism at any wavelength of 380 nm to 780 nm. The single transmittance of the polarizing film is preferably 40.0% or more, more preferably 41.0% or more, and further preferably 42.0% or more. The polarization degree of the polarizing film is preferably 99.8% or more, more preferably 99.9% or more, and further preferably 99.95% or more.
(ホウ酸量指数)=(ホウ酸ピーク665cm-1の強度)/(参照ピーク2941cm-1の強度)
(ホウ酸濃度)=(ホウ酸量指数)×5.54+4.1
ここで、「5.54」および「4.1」はいずれも、ホウ酸濃度が既知の試料の蛍光X線強度を測定し、検量線を作成することにより得られる定数である。 The polarizing film typically contains boric acid. The boric acid concentration in the polarizing film is preferably 10% by weight to 20% by weight, more preferably 12% by weight to 19% by weight. When the boric acid concentration is within this range, the dimensional stability of the polarizing film is improved, and the above formulas (1) and (2) can be preferably satisfied. The boric acid concentration in the polarizing film is, for example, changing the boric acid concentration in a stretching bath, an insolubilizing bath, a cross-linking bath, etc., and changing the immersion time in these baths, etc. Can be adjusted. The boric acid concentration (% by weight) in the polarizing film can be determined using, for example, a boric acid amount index calculated from total reflection attenuation spectroscopy (ATR) measurement.
(Boric acid amount index) = (Intensity of boric acid peak 665 cm −1 ) / (Intensity of reference peak 2941 cm −1 )
(Boric acid concentration) = (Boric acid amount index) × 5.54 + 4.1
Here, both “5.54” and “4.1” are constants obtained by measuring the fluorescent X-ray intensity of a sample having a known boric acid concentration and creating a calibration curve.
上記樹脂基材の形成材料としては、任意の適切な熱可塑性樹脂基材が採用され得る。熱可塑性樹脂としては、ポリエステル系樹脂が好ましい。ポリエステル系樹脂としては、例えば、ポリエチレンテレフタレート(PET)、ポリブチレンテレフタレート(PBT)、ポリエチレンナフタレート(PEN)、イソフタル酸、シクロヘキサン環等を含む脂環式のジカルボン酸または脂環式のジオール等を含む共重合PET(PET-G)、その他ポリエステル、および、これらの共重合体やブレンド体等を用いることができる。なかでも、PETまたは共重合PETを用いることが好ましい。これらの樹脂によれば、未延伸状態では非晶で高倍率延伸に適した優れた延伸性を有し、延伸、加熱により結晶化することで、耐熱性および寸法安定性を付与できる。さらに、未延伸の状態でPVA系樹脂を塗布、乾燥することが可能な程度の耐熱性を確保できる。 A-2. Resin Base Material Any appropriate thermoplastic resin base material may be employed as the resin base material. As the thermoplastic resin, a polyester resin is preferable. Examples of the polyester-based resin include polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyethylene naphthalate (PEN), isophthalic acid, cycloaliphatic dicarboxylic acid including cyclohexane ring, and alicyclic diol. Copolymerized PET (PET-G), other polyesters, and copolymers and blends thereof can be used. Among these, it is preferable to use PET or copolymerized PET. According to these resins, in an unstretched state, it is amorphous and has excellent stretchability suitable for high-strength stretching, and heat resistance and dimensional stability can be imparted by crystallization by stretching and heating. Furthermore, the heat resistance of the grade which can apply | coat and dry PVA-type resin in an unstretched state is securable.
(結晶化度)=(結晶ピーク1340cm-1の強度)/(参照ピーク1410cm-1の強度) When the resin base material is a polyester resin base material, the crystallinity calculated by the total reflection attenuation spectroscopy (ATR) measurement of the polyester base resin base material is preferably 0.55 to 0.80, more preferably 0. .58 to 0.80, more preferably 0.60 to 0.75. When the degree of crystallinity of the polyester-based resin substrate is within the range, the dimensional change rate of the resin substrate can be set to a value close to the dimensional change rate of the polarizing film. Therefore, the above formulas (1) and (2) Can be suitably satisfied. The degree of crystallization of the polyester resin substrate can be adjusted, for example, by changing the heating temperature and / or the heating time for crystallization. In addition, the crystallinity degree of the said polyester-type resin base material is computed based on the following formula | equation.
(Crystallinity) = (Intensity of crystal peak 1340 cm −1 ) / (Intensity of reference peak 1410 cm −1 )
上記保護フィルムの形成材料としては、例えば、(メタ)アクリル系樹脂、ジアセチルセルロース、トリアセチルセルロース等のセルロース系樹脂、シクロオレフィン系樹脂、ポリプロピレン等のオレフィン系樹脂、ポリエチレンテレフタレート系樹脂等のエステル系樹脂、ポリアミド系樹脂、ポリカーボネート系樹脂、これらの共重合体樹脂等が挙げられる。保護フィルムの厚みは、好ましくは10μm~100μmである。 A-3. Protective film Examples of the material for forming the protective film include (meth) acrylic resins, cellulose resins such as diacetyl cellulose and triacetyl cellulose, cycloolefin resins, olefin resins such as polypropylene, and polyethylene terephthalate resins. Examples thereof include ester resins, polyamide resins, polycarbonate resins, and copolymer resins thereof. The thickness of the protective film is preferably 10 μm to 100 μm.
易接着層は、実質的に易接着層形成用組成物のみから形成される層であってもよく、易接着層形成用組成物と偏光膜の形成材料とが混合(相溶を含む)した層または領域であってもよい。易接着層が形成されていることにより、優れた密着性が得られ得る。易接着層の厚みは、0.05μm~1μm程度とするのが好ましい。易接着層は、例えば、偏光板の断面を走査型電子顕微鏡(SEM)で観察することにより確認することができる。易接着層形成用組成物については、B項で詳述する。 A-4. Easy-adhesion layer The easy-adhesion layer may be a layer formed substantially only from the composition for forming an easy-adhesion layer, and the composition for forming an easy-adhesion layer and the material for forming the polarizing film are mixed (compatible). A layer or region that is included). By forming the easy adhesion layer, excellent adhesion can be obtained. The thickness of the easy adhesion layer is preferably about 0.05 μm to 1 μm. The easy adhesion layer can be confirmed, for example, by observing the cross section of the polarizing plate with a scanning electron microscope (SEM). The composition for forming an easily adhesive layer will be described in detail in Section B.
接着層は、任意の適切な接着剤または粘着剤で形成される。粘着剤層は、代表的にはアクリル系粘着剤で形成される。接着剤層は、代表的にはビニルアルコール系接着剤で形成される。 A-5. Adhesive layer The adhesive layer is formed of any suitable adhesive or adhesive. The pressure-sensitive adhesive layer is typically formed of an acrylic pressure-sensitive adhesive. The adhesive layer is typically formed of a vinyl alcohol adhesive.
本発明の偏光板の製造方法は、代表的には、樹脂基材上にPVA系樹脂膜を形成して積層体を作製することと、該積層体を延伸することと、該PVA系樹脂膜を染色することと、該樹脂基材を結晶化することと、を含む。 B. Manufacturing method of polarizing plate The manufacturing method of the polarizing plate of the present invention typically comprises forming a PVA resin film on a resin substrate to produce a laminate, stretching the laminate, Dyeing the PVA resin film and crystallizing the resin substrate.
樹脂基材上にPVA系樹脂膜を形成する方法としては、任意の適切な方法が採用され得る。好ましくは、樹脂基材上に、PVA系樹脂を含む塗布液を塗布し、乾燥することにより、PVA系樹脂膜を形成する。1つの実施形態においては、樹脂基材上に、易接着層形成用組成物を塗布し、乾燥することにより、易接着層を形成し、該易接着層上にPVA系樹脂膜を形成する。 B-1. Production of Laminate Any appropriate method can be adopted as a method for forming a PVA-based resin film on a resin substrate. Preferably, a PVA-based resin film is formed by applying a coating liquid containing a PVA-based resin on a resin base material and drying it. In one embodiment, an easy-adhesion layer forming composition is applied on a resin substrate and dried to form an easy-adhesion layer, and a PVA-based resin film is formed on the easy-adhesion layer.
積層体の延伸方法としては、任意の適切な方法を採用することができる。具体的には、固定端延伸(例えば、テンター延伸機を用いる方法)でもよいし、自由端延伸(例えば、周速の異なるロール間に積層体を通して一軸延伸する方法)でもよい。また、同時二軸延伸(例えば、同時二軸延伸機を用いる方法)でもよいし、逐次二軸延伸でもよい。積層体の延伸は、一段階で行ってもよいし、多段階で行ってもよい。多段階で行う場合、後述の積層体の延伸倍率(最大延伸倍率)は、各段階の延伸倍率の積である。 B-2. Stretching Any appropriate method can be adopted as a stretching method of the laminate. Specifically, it may be fixed end stretching (for example, a method using a tenter stretching machine) or free end stretching (for example, a method of uniaxial stretching through a laminate between rolls having different peripheral speeds). Moreover, simultaneous biaxial stretching (for example, a method using a simultaneous biaxial stretching machine) or sequential biaxial stretching may be used. The stretching of the laminate may be performed in one stage or in multiple stages. When performed in multiple stages, the draw ratio (maximum draw ratio) of the laminate described later is the product of the draw ratios of the respective stages.
PVA系樹脂膜の染色は、代表的には、PVA系樹脂膜にヨウ素を吸着させることにより行う。当該吸着方法としては、例えば、ヨウ素を含む染色液にPVA系樹脂膜(積層体)を浸漬させる方法、PVA系樹脂膜に当該染色液を塗工する方法、当該染色液をPVA系樹脂膜に噴霧する方法等が挙げられる。好ましくは、染色液にPVA系樹脂膜(積層体)を浸漬させる方法である。ヨウ素が良好に吸着し得るからである。 B-3. Dyeing The dyeing of the PVA resin film is typically performed by adsorbing iodine to the PVA resin film. As the adsorption method, for example, a method of immersing a PVA resin film (laminated body) in a staining solution containing iodine, a method of applying the staining solution to the PVA resin film, and applying the staining solution to the PVA resin film The method of spraying etc. are mentioned. Preferably, the PVA resin film (laminate) is immersed in the dyeing solution. This is because iodine can be adsorbed well.
樹脂基材の結晶化は、例えば、樹脂基材(実質的には、積層体)を加熱することによって行われる。結晶化は、好ましくはPVA系樹脂膜の染色および延伸後に行われる。 B-4. Crystallization The crystallization of the resin base material is performed, for example, by heating the resin base material (substantially a laminate). Crystallization is preferably performed after dyeing and stretching the PVA resin film.
上記PVA系樹脂膜(積層体)には、延伸および染色以外に、偏光膜とするための処理が、適宜施され得る。偏光膜とするための処理としては、例えば、不溶化処理、架橋処理、洗浄処理、乾燥処理等が挙げられる。なお、これらの処理の回数、順序等は、特に限定されない。 B-5. Other treatments In addition to stretching and dyeing, the PVA-based resin film (laminated body) may be appropriately subjected to treatment for forming a polarizing film. Examples of the treatment for forming the polarizing film include insolubilization treatment, crosslinking treatment, washing treatment, and drying treatment. In addition, the frequency | count, order, etc. of these processes are not specifically limited.
本発明の偏光板は、例えば、液晶表示装置に搭載され得る。この場合、偏光膜が樹脂基材よりも液晶セル側に配置されるように搭載されることが好ましい。このような構成によれば、樹脂基材が有し得る位相差が、得られる液晶表示装置の画像特性に及ぼす影響を排除することができる。 C. Application of Polarizing Plate The polarizing plate of the present invention can be mounted on, for example, a liquid crystal display device. In this case, it is preferable that the polarizing film is mounted so as to be disposed closer to the liquid crystal cell than the resin base material. According to such a structure, the influence which the phase difference which a resin base material can have on the image characteristic of the liquid crystal display device obtained can be excluded.
≪厚み≫
デジタルマイクロメーター(アンリツ社製、製品名「KC-351C」)を用いて測定した。
≪寸法変化率≫
実施例および比較例で得られた偏光板から、偏光膜と樹脂基材とを端部にきっかけを与えることで剥がし、熱機械測定装置(TMA)にて、30℃から100℃に10℃/分で昇温後、さらに100℃で60分間保持した際の寸法変化率を測定した。なお、易接着層を間に挟む実施例6では、易接着層を形成しないこと以外は同様に作製した偏光板から、同様の手順で偏光膜と樹脂基材を単離したものを測定に供し、偏光膜および樹脂基材の寸法変化とした。
寸法変化率(%)=(加熱処理後の寸法-加熱処理前の寸法)/加熱処理前の寸法×100
≪結晶化度≫
実施例および比較例で得られたポリエステル系樹脂基材について、フーリエ変換赤外分光光度計(FT-IR)(Perkin Elmer社製、商品名「SPECTRUM2000」)を用いて、全反射減衰分光(ATR)測定により結晶ピーク(1340cm-1)の強度および参照ピーク(1410cm-1)の強度を測定した。得られた結晶ピーク強度および参照ピーク強度から結晶化度を下記式により算出した。
(結晶化度)=(結晶ピーク1340cm-1の強度)/(参照ピーク1410cm-1の強度)
≪ガラス転移温度:Tg≫
JIS K 7121に準拠し測定した。
≪ホウ酸濃度≫
実施例および比較例で得られた偏光膜について、フーリエ変換赤外分光光度計(FT-IR)(Perkin Elmer社製、商品名「SPECTRUM2000」)を用いて、偏光を測定光とする全反射減衰分光(ATR)測定によりホウ酸ピーク(665cm-1)の強度および参照ピーク(2941cm-1)の強度を測定した。得られたホウ酸ピーク強度および参照ピーク強度からホウ酸量指数を下記式により算出し、さらに、算出したホウ酸量指数から下記式によりホウ酸濃度を決定した。
(ホウ酸量指数)=(ホウ酸ピーク665cm-1の強度)/(参照ピーク2941cm-1の強度)
(ホウ酸濃度)=(ホウ酸量指数)×5.54+4.1
≪クラック評価≫
実施例および比較例で得られた偏光板を、ポリエステル系樹脂基材が表面側に来るように粘着剤を介してガラスに貼り合せた状態で、100℃のオーブンにて240h加熱した。加熱後の偏光板のクラックの有無を確認し、下記の基準に従って評価した。
良: クラック発生なし
不良: クラック発生あり EXAMPLES Hereinafter, although an Example demonstrates this invention concretely, this invention is not limited by these Examples. In addition, the measuring method of each characteristic is as follows. In the following examples and comparative examples, “parts” and “%” represent “parts by weight” and “% by weight”, respectively.
≪Thickness≫
The measurement was performed using a digital micrometer (manufactured by Anritsu Co., Ltd., product name “KC-351C”).
≪Dimension change rate≫
From the polarizing plates obtained in Examples and Comparative Examples, the polarizing film and the resin base material were peeled off by giving a trigger to the end, and the temperature was increased from 30 ° C. to 100 ° C. by 10 ° C. / After the temperature was raised in minutes, the dimensional change rate was further measured when held at 100 ° C. for 60 minutes. In Example 6 with the easy-adhesion layer sandwiched between them, the polarizing film and the resin substrate were isolated in the same procedure from the polarizing plate prepared in the same manner except that the easy-adhesion layer was not formed. The dimensional change of the polarizing film and the resin base material was used.
Dimensional change rate (%) = (Dimension after heat treatment−Dimension before heat treatment) / Dimension before heat treatment × 100
≪Crystallinity≫
The polyester-based resin base materials obtained in the examples and comparative examples were subjected to total reflection attenuation spectroscopy (ATR) using a Fourier transform infrared spectrophotometer (FT-IR) (manufactured by Perkin Elmer, trade name “SPECTRUM2000”). ) The intensity of the crystal peak (1340 cm −1 ) and the intensity of the reference peak (1410 cm −1 ) were measured by measurement. The crystallinity was calculated by the following formula from the obtained crystal peak intensity and reference peak intensity.
(Crystallinity) = (Intensity of crystal peak 1340 cm −1 ) / (Intensity of reference peak 1410 cm −1 )
≪Glass transition temperature: Tg≫
Measured according to JIS K 7121.
≪Boric acid concentration≫
Using the Fourier transform infrared spectrophotometer (FT-IR) (manufactured by Perkin Elmer, trade name “SPECTRUM2000”) for the polarizing films obtained in Examples and Comparative Examples, total reflection attenuation using polarized light as measurement light The intensity of the boric acid peak (665 cm −1 ) and the intensity of the reference peak (2941 cm −1 ) were measured by spectroscopic (ATR) measurement. The boric acid amount index was calculated from the obtained boric acid peak intensity and the reference peak intensity by the following formula, and the boric acid concentration was determined from the calculated boric acid amount index by the following formula.
(Boric acid amount index) = (Intensity of boric acid peak 665 cm −1 ) / (Intensity of reference peak 2941 cm −1 )
(Boric acid concentration) = (Boric acid amount index) × 5.54 + 4.1
≪Crack evaluation≫
The polarizing plates obtained in the examples and comparative examples were heated in an oven at 100 ° C. for 240 hours in a state of being bonded to glass through an adhesive so that the polyester resin substrate was on the surface side. The presence or absence of cracks in the polarizing plate after heating was confirmed and evaluated according to the following criteria.
Good: No cracking
Defect: There is a crack
樹脂基材として、長尺状で、吸水率0.75%、Tg75℃の非晶質のイソフタル酸共重合ポリエチレンテレフタレート(IPA共重合PET)フィルム(厚み:100μm)を用いた。
樹脂基材の片面に、コロナ処理を施し、このコロナ処理面に、ポリビニルアルコール(重合度4200、ケン化度99.2モル%)およびアセトアセチル変性PVA(重合度1200、アセトアセチル変性度4.6%、ケン化度99.0モル%以上、日本合成化学工業社製、商品名「ゴーセファイマーZ200」)を9:1の比で含む水溶液を25℃で塗布および乾燥して、厚み11μmのPVA系樹脂層を形成した。こうして、積層体を作製した。 [Example 1]
As the resin substrate, an amorphous isophthalic acid copolymerized polyethylene terephthalate (IPA copolymerized PET) film (thickness: 100 μm) having a long water absorption rate of 0.75% and Tg of 75 ° C. was used.
One side of the resin substrate was subjected to corona treatment, and polyvinyl alcohol (polymerization degree 4200, saponification degree 99.2 mol%) and acetoacetyl-modified PVA (polymerization degree 1200, acetoacetyl modification degree 4. An aqueous solution containing 6%, a saponification degree of 99.0 mol% or more, manufactured by Nippon Synthetic Chemical Industry Co., Ltd., trade name “Gosefimer Z200”) at a ratio of 9: 1 was applied and dried at 25 ° C., and the thickness was 11 μm. A PVA-based resin layer was formed. Thus, a laminate was produced.
次いで、積層体を、液温30℃の不溶化浴(水100重量部に対して、ホウ酸を4重量部配合して得られたホウ酸水溶液)に30秒間浸漬させた(不溶化処理)。
次いで、液温30℃の染色浴(水100重量部に対して、ヨウ素を0.2重量部配合し、ヨウ化カリウムを1.5重量部配合して得られたヨウ素水溶液)に60秒間浸漬させた(染色処理)。
次いで、液温30℃の架橋浴(水100重量部に対して、ヨウ化カリウムを3重量部配合し、ホウ酸を3重量部配合して得られたホウ酸水溶液)に30秒間浸漬させた(架橋処理)。
その後、積層体を、液温70℃のホウ酸水溶液(水100重量部に対して、ホウ酸を3重量部配合し、ヨウ化カリウムを5重量部配合して得られた水溶液)に浸漬させながら、周速の異なるロール間で縦方向(長手方向)に総延伸倍率が5.5倍となるように一軸延伸を行った(水中延伸)。
その後、積層体を液温30℃の洗浄浴(水100重量部に対して、ヨウ化カリウムを4重量部配合して得られた水溶液)に浸漬させた(洗浄処理)。 The obtained laminate was uniaxially stretched at a free end 1.8 times in the longitudinal direction (longitudinal direction) between rolls having different peripheral speeds in an oven at 120 ° C. (air-assisted stretching).
Next, the laminate was immersed in an insolubilization bath (a boric acid aqueous solution obtained by blending 4 parts by weight of boric acid with respect to 100 parts by weight of water) for 30 seconds (insolubilization treatment).
Next, it is immersed for 60 seconds in a dyeing bath at 30 ° C. (an iodine aqueous solution obtained by blending 0.2 parts by weight of iodine and 1.5 parts by weight of potassium iodide with respect to 100 parts by weight of water). (Staining treatment).
Subsequently, it was immersed for 30 seconds in a crosslinking bath having a liquid temperature of 30 ° C. (a boric acid aqueous solution obtained by blending 3 parts by weight of potassium iodide and 3 parts by weight of boric acid with respect to 100 parts by weight of water). (Crosslinking treatment).
Thereafter, the laminate is immersed in a boric acid aqueous solution (an aqueous solution obtained by blending 3 parts by weight of boric acid and 5 parts by weight of potassium iodide with respect to 100 parts by weight of water) at a liquid temperature of 70 ° C. However, uniaxial stretching was performed between the rolls having different peripheral speeds in the longitudinal direction (longitudinal direction) so that the total stretching ratio was 5.5 times (in-water stretching).
Thereafter, the laminate was immersed in a cleaning bath (an aqueous solution obtained by blending 4 parts by weight of potassium iodide with respect to 100 parts by weight of water) at a liquid temperature of 30 ° C. (cleaning treatment).
このようにして、樹脂基材上に厚み5μmの偏光膜が積層された偏光板を得た。 Next, the laminate was put into an oven at 100 ° C. for 30 seconds to crystallize the resin base material.
Thus, a polarizing plate in which a polarizing film having a thickness of 5 μm was laminated on the resin base material was obtained.
積層体を110℃のオーブンに30秒間投入して樹脂基材を結晶化したこと以外は実施例1と同様にして偏光板を得た。 [Example 2]
A polarizing plate was obtained in the same manner as in Example 1 except that the laminate was placed in an oven at 110 ° C. for 30 seconds to crystallize the resin substrate.
積層体を120℃のオーブンに30秒間投入して樹脂基材を結晶化したこと以外は実施例1と同様にして偏光板を得た。 [Example 3]
A polarizing plate was obtained in the same manner as in Example 1 except that the laminate was placed in an oven at 120 ° C. for 30 seconds to crystallize the resin substrate.
水中延伸時の延伸浴中のホウ酸配合量を3.5重量部としたこと、および、積層体を110℃のオーブンに30秒間投入して樹脂基材を結晶化したこと以外は実施例1と同様にして偏光板を得た。 [Example 4]
Example 1 except that the amount of boric acid in the stretching bath during stretching in water was 3.5 parts by weight, and the laminate was put into an oven at 110 ° C. for 30 seconds to crystallize the resin substrate. In the same manner, a polarizing plate was obtained.
水中延伸時の延伸浴中のホウ酸配合量を2.5重量部としたこと、および、積層体を110℃のオーブンに30秒間投入して樹脂基材を結晶化したこと以外は実施例1と同様にして偏光板を得た。 [Example 5]
Example 1 except that the amount of boric acid in the stretching bath during stretching in water was 2.5 parts by weight, and the laminate was put into an oven at 110 ° C. for 30 seconds to crystallize the resin substrate. In the same manner, a polarizing plate was obtained.
以下の方法で、樹脂基材の片面に易接着層を設けた。
樹脂基材の片面に、コロナ処理を施し、このコロナ処理面に、アセトアセチル変性PVA(日本合成化学工社製、商品名「ゴーセファイマーZ200」、重合度1200、ケン化度99.0モル%以上、アセトアセチル変性度4.6%)の4.0%水溶液と変性ポリオレフィン樹脂水性分散体(ユニチカ社製、商品名「アローベースSE1030N」、固形分濃度22%)と純水を混合した混合液(固形分濃度4.0%)を、乾燥後の厚みが2000nmになるように塗布し、60℃で3分間乾燥し、易接着層を形成した。ここで、混合液におけるアセトアセチル変性PVAと変性ポリオレフィンとの固形分配合比は30:70であった。
該易接着層表面に、コロナ処理を施し、このコロナ処理面にPVA系樹脂層を形成したこと以外は実施例1と同様にして偏光板を得た。 [Example 6]
The easy adhesion layer was provided on one side of the resin base material by the following method.
One side of the resin base material is subjected to corona treatment, and this corona treatment surface is subjected to acetoacetyl-modified PVA (manufactured by Nippon Synthetic Chemical Industry Co., Ltd., trade name “Gosefimer Z200”, polymerization degree 1200, saponification degree 99.0 mol. %, Acetoacetyl modification degree 4.6%) and a modified polyolefin resin aqueous dispersion (manufactured by Unitika Ltd., trade name “Arrow Base SE1030N”, solid content concentration 22%) and pure water were mixed. The mixture (solid content concentration 4.0%) was applied so that the thickness after drying was 2000 nm, and dried at 60 ° C. for 3 minutes to form an easy-adhesion layer. Here, the solid content mixing ratio of acetoacetyl-modified PVA and modified polyolefin in the mixed solution was 30:70.
A polarizing plate was obtained in the same manner as in Example 1 except that the surface of the easy-adhesion layer was subjected to corona treatment and a PVA resin layer was formed on the corona-treated surface.
積層体を85℃のオーブンに30秒間投入して樹脂基材を結晶化したこと以外は実施例1と同様にして偏光板を得た。 [Comparative Example 1]
A polarizing plate was obtained in the same manner as in Example 1 except that the laminate was placed in an oven at 85 ° C. for 30 seconds to crystallize the resin substrate.
水中延伸時の延伸浴中のホウ酸配合量を4.0重量部としたこと、および、積層体を110℃のオーブンに30秒間投入して樹脂基材を結晶化したこと以外は実施例1と同様にして偏光板を得た。 [Comparative Example 2]
Example 1 except that the amount of boric acid in the stretching bath during stretching in water was 4.0 parts by weight, and the laminate was put into an oven at 110 ° C. for 30 seconds to crystallize the resin substrate. In the same manner, a polarizing plate was obtained.
積層体を95℃のオーブンに30秒間投入して樹脂基材を結晶化したこと以外は実施例1と同様にして偏光板を得た。 [Comparative Example 3]
A polarizing plate was obtained in the same manner as in Example 1 except that the laminate was put in an oven at 95 ° C. for 30 seconds to crystallize the resin substrate.
Claims (6)
- 樹脂基材と、該樹脂基材の片側に積層された厚みが10μm以下の偏光膜と、を有する偏光板であって、
以下の式(1)および(2)を満足する、偏光板;
|SUB2-POL2|-|SUB1-POL1|<1.0 (1)
|SUB2-POL2|<5.0 (2)
(式(1)および(2)において、SUB1およびPOL1はそれぞれ、該偏光膜の吸収軸方向における該樹脂基材の寸法変化率(%)および該偏光膜の寸法変化率(%)を意味し、SUB2およびPOL2はそれぞれ、該吸収軸方向と直交する方向における該樹脂基材の寸法変化率(%)および該偏光膜の寸法変化率(%)を意味する)。 A polarizing plate having a resin substrate and a polarizing film having a thickness of 10 μm or less laminated on one side of the resin substrate,
A polarizing plate satisfying the following formulas (1) and (2);
SUB2-POL2 |-| SUB1-POL1 | <1.0 (1)
SUB2-POL2 | <5.0 (2)
(In formulas (1) and (2), SUB1 and POL1 mean the dimensional change rate (%) of the resin substrate and the dimensional change rate (%) of the polarizing film, respectively, in the absorption axis direction of the polarizing film. , SUB2 and POL2 mean the dimensional change rate (%) of the resin substrate and the dimensional change rate (%) of the polarizing film in the direction orthogonal to the absorption axis direction, respectively). - 前記樹脂基材が、ポリエステル系樹脂基材である、請求項1に記載の偏光板。 The polarizing plate according to claim 1, wherein the resin base material is a polyester resin base material.
- 前記偏光膜が、前記樹脂基材の片側に接着層を介することなく積層されている、請求項1または2に記載の偏光板。 The polarizing plate according to claim 1 or 2, wherein the polarizing film is laminated on one side of the resin base material without an adhesive layer.
- 前記偏光膜の前記樹脂基材が積層される側と反対側に、保護フィルムを有さない、請求項1から3のいずれかに記載の偏光板。 The polarizing plate according to any one of claims 1 to 3, wherein the polarizing film does not have a protective film on the side opposite to the side on which the resin base material is laminated.
- 前記樹脂基材と前記偏光膜との間に易接着層を有する、請求項1から4のいずれかに記載の偏光板。 The polarizing plate according to any one of claims 1 to 4, further comprising an easy-adhesion layer between the resin substrate and the polarizing film.
- 樹脂基材上にポリビニルアルコール系樹脂膜を形成して積層体を作製すること、
該積層体を延伸すること、
該ポリビニルアルコール系樹脂膜を染色すること、および
該樹脂基材を結晶化すること、
を含む、請求項1から5のいずれかに記載の偏光板の製造方法。 Forming a polyvinyl alcohol-based resin film on a resin substrate to produce a laminate,
Stretching the laminate,
Staining the polyvinyl alcohol-based resin film; and crystallizing the resin base material;
The manufacturing method of the polarizing plate in any one of Claim 1 to 5 containing these.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SG11201807542VA SG11201807542VA (en) | 2016-03-04 | 2016-12-21 | Polarizing plate |
CN201680083154.9A CN108780171B (en) | 2016-03-04 | 2016-12-21 | Polarizing plate |
KR1020187025234A KR102191636B1 (en) | 2016-03-04 | 2016-12-21 | Polarizer |
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KR (1) | KR102191636B1 (en) |
CN (1) | CN108780171B (en) |
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US11427688B2 (en) * | 2017-04-17 | 2022-08-30 | Eastman Chemical Company | Copolyesters plasticized with polymeric plasticizer |
JP2019053169A (en) * | 2017-09-14 | 2019-04-04 | 日東電工株式会社 | Polarizer, manufacturing method of polarizer and optical laminate including the polarizer |
JP7240091B2 (en) * | 2017-10-03 | 2023-03-15 | 日東電工株式会社 | Polarizing plate, image display device, and method for manufacturing polarizing plate |
JP7083612B2 (en) * | 2017-10-18 | 2022-06-13 | 日東電工株式会社 | Manufacturing method of optical laminate |
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JP2003098345A (en) * | 2001-09-20 | 2003-04-03 | Konica Corp | Polarizing plate, cellulose ester film and method for manufacturing the same |
JP2009037223A (en) * | 2007-07-12 | 2009-02-19 | Sumitomo Chemical Co Ltd | Polarizing plate and optical member |
JP2013140301A (en) * | 2012-01-06 | 2013-07-18 | Dainippon Printing Co Ltd | Optical film, and manufacturing method of optical film and polarizing member |
JP2015215605A (en) * | 2014-04-23 | 2015-12-03 | 富士フイルム株式会社 | Polarizing plate and image display device |
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JP4279944B2 (en) | 1999-06-01 | 2009-06-17 | 株式会社サンリッツ | Manufacturing method of polarizing plate |
JP4979833B1 (en) | 2010-12-02 | 2012-07-18 | 日東電工株式会社 | Manufacturing method of polarizing plate |
JP5616318B2 (en) * | 2011-12-12 | 2014-10-29 | 日東電工株式会社 | Manufacturing method of polarizing film |
JP5889158B2 (en) * | 2012-10-04 | 2016-03-22 | 日東電工株式会社 | Method for producing stretched laminate |
JP5914452B2 (en) * | 2013-12-24 | 2016-05-11 | 日東電工株式会社 | Method for producing optical laminate |
CN105729962B (en) * | 2014-12-24 | 2018-01-05 | 住友化学株式会社 | The manufacture method of polarizing coating, polarizer and polarizing coating |
CN107987213B (en) * | 2017-12-28 | 2020-07-21 | 深圳市华星光电技术有限公司 | Polarizing film material and preparation method thereof, polarizing film and preparation method thereof |
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Patent Citations (4)
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JP2003098345A (en) * | 2001-09-20 | 2003-04-03 | Konica Corp | Polarizing plate, cellulose ester film and method for manufacturing the same |
JP2009037223A (en) * | 2007-07-12 | 2009-02-19 | Sumitomo Chemical Co Ltd | Polarizing plate and optical member |
JP2013140301A (en) * | 2012-01-06 | 2013-07-18 | Dainippon Printing Co Ltd | Optical film, and manufacturing method of optical film and polarizing member |
JP2015215605A (en) * | 2014-04-23 | 2015-12-03 | 富士フイルム株式会社 | Polarizing plate and image display device |
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KR20180107220A (en) | 2018-10-01 |
KR102191636B1 (en) | 2020-12-16 |
JP2017156662A (en) | 2017-09-07 |
TWI645224B (en) | 2018-12-21 |
SG11201807542VA (en) | 2018-10-30 |
CN108780171A (en) | 2018-11-09 |
JP6867105B2 (en) | 2021-04-28 |
CN108780171B (en) | 2020-11-06 |
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