WO2017146306A1 - Vegetation mat using shells - Google Patents

Vegetation mat using shells Download PDF

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Publication number
WO2017146306A1
WO2017146306A1 PCT/KR2016/005725 KR2016005725W WO2017146306A1 WO 2017146306 A1 WO2017146306 A1 WO 2017146306A1 KR 2016005725 W KR2016005725 W KR 2016005725W WO 2017146306 A1 WO2017146306 A1 WO 2017146306A1
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WO
WIPO (PCT)
Prior art keywords
layer
seed
vegetation mat
shell
net
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PCT/KR2016/005725
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French (fr)
Korean (ko)
Inventor
여중훈
Original Assignee
(주)호정산업
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Priority to CN201680076741.5A priority Critical patent/CN108471707A/en
Publication of WO2017146306A1 publication Critical patent/WO2017146306A1/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • A01G13/02Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/02Receptacles, e.g. flower-pots or boxes; Glasses for cultivating flowers
    • A01G9/029Receptacles for seedlings

Definitions

  • the present invention relates to a vegetation mat using shells, and more specifically, to recycle seed shells (shell shells, oyster shells, etc.) classified as industrial wastes, to prevent seed germination during warming, moisturizing, feeding, and storing.
  • the present invention relates to a vegetation mat using a shell to improve the structure of the mat to significantly increase the shell recycling throughput.
  • shells generated during the processing of shellfish and aquatic products are separated into industrial waste, and the amount currently waiting for disposal reaches 480,000 tons, and 130,000 tons of new waste are generated annually, resulting in odor and leachate problems.
  • It is applied to various fields such as soundproofing, heat insulation, heat storage materials, etc. by using shells, but in reality, consumption is extremely low, and in recent years, vegetation mat field is used to utilize calcium and various organic substances contained in shells as natural fertilizers. The range of use is being expanded to.
  • the crushed powder on the top surface of the nonwoven layer It is configured to form a compost layer by coating the nutrient supply composition including shell powder, sawdust, starch, water, and after the vegetation of the plant, it is possible to supply stable moisture and nutrients so that the stable growth of the plant is possible. It has been pre-registered.
  • the conventional technology is applied to the vegetation layer containing the shell, the vegetation mat, or in detail the mixing ratio constituting the compost layer 20% by weight, 30% by weight ocher, 20% by weight of shell powder, sawdust 10% by weight, 10% by weight starch, 10% by weight of water, the use of the shell is extremely insufficient, the situation is not able to fully exhibit the function of industrial waste recycling and natural fertilizer.
  • the shell is recycled in powder form to shorten the time to decompose and increase the rate of absorption.
  • the shell is mixed with water to form a compost layer, which makes the manufacturing process and equipment complicated. In particular, when the moisture contained in the compost layer and the internal humidity of the mat in the rainy season are high, the seeds germinate early in a short time, so many difficulties in securing the inventory.
  • the present invention has been conceived to solve the above problems, while recycling the shell classified as industrial waste, while the dehumidification function to prevent early germination of seeds during warming, moisturizing, nutrition and storage is added, the mat structure It is an object of the present invention to provide a vegetation mat using shells that can be improved to significantly increase shell recycling throughput.
  • a feature of the present invention is configured by laminating a moisturizing layer (1), a seed layer (2), a seed protecting layer (3), an insulating layer (4) and a protective net (5), and protecting the seed.
  • a pocket network layer 20 is formed with a plurality of compartments 22 to store the shell powder 10
  • the pocket network layer 20 is formed on the top of the network
  • Side wall compartments of compartments 22 are formed by the inclined lines
  • compartments in the height direction 22 are formed by the inclination thickness
  • the upper and lower compartments of the compartments 22 are formed by the insulating layer 4 and the seed protection layer 3.
  • the laminated each layer is characterized in that it is formed integrally by being processed by the sewing line (30).
  • the pocket mesh layer 20 is formed of jute mesh, straw straw mat, or formed of a biodegradable yarn network structure formed of polylactic acid (PLA) resin, PBS resin, inorganic material 10 to 14 months after construction Characterized in that it is provided to be disassembled.
  • PLA polylactic acid
  • the moisturizing layer (1) is formed by the other surface of the biodegradable yarn formed of polylactic acid (PLA) resin, PBS-based resin, inorganic material
  • the seed layer (2) is a moisturizing layer (1) It is formed by applying seeds to the top, the insulating layer 4 finishes the top of the seed layer (2), at least any one of natural materials including coir fiber, coco peat, bark, jute, straw, deciduous leaves It is formed on the other side, the protective net (5) is installed on the insulating layer 4 is characterized in that it is provided to integrally support the moisturizing layer (1), the seed layer (2), the insulating layer (4).
  • the seed protective layer (3) is characterized in that it is formed of a pulp or biodegradable film in which the air holes are formed.
  • the shell powder is contained in the compartment of the pocket net layer to prevent the shell powder loss and tipping during transportation and installation work, and in particular, by recycling the shell powder classified as industrial waste, to keep warm
  • the compartment size is elastically expanded according to the thickness of the pocket mesh layer, the inclination thickness, and the tissue density, thereby significantly increasing the shell recycling throughput.
  • the present invention has an excellent shelf life and prevents the early germination of the rainy season seed due to the dehumidification function when the pocket net layer made of shell powder in the form of roll prevents the high availability and secure a large inventory for the high season There is.
  • FIG. 1 is a block diagram showing the vegetation mat as a whole using a shell according to an embodiment of the present invention.
  • Figure 2 is a block diagram showing an enlarged pocket mesh layer of the vegetation mat using a shell according to an embodiment of the present invention.
  • Figure 3 is a block diagram showing a state in which the rolled vegetation mat using the shell according to an embodiment of the present invention in a roll shape.
  • a vegetation mat composed of a moisturizing layer (1), a seed layer (2), a seed protection layer (3), an insulating layer (4), and a protective net (5) in order to improve the mat structure so that the shell recycling throughput can be significantly increased.
  • a pocket mesh layer 20 in which the compartment 22 is formed.
  • the vegetation mat according to the present invention is constructed by laminating a moisturizing layer 1, a seed layer 2, a seed protective layer 3, a thermal insulation layer 4 and a protective net 5.
  • the moisturizing layer 1 is formed on the other surface of a biodegradable yarn formed of a polylactic acid (PLA) resin, a PBS-based resin, and an inorganic substance.
  • Moisturizing layer (1) is in contact with the ground to absorb moisture, supply the absorbed moisture to the seed to promote early germination and to prevent necrosis by drought.
  • PLA resin refers to the entire polymer composed of lactic acid (Lactic acid) as a monomer
  • PLA resin is thermal properties according to the isomer D-Lactide, L-Lactide content and arrangement (random copolymerization, block copolymerization) And physical properties may vary.
  • the melt index (MI) of the polylactic acid (PLA) resin is preferably 10 to 50 g / 10 min (230 ° C., 2.16 kg load), and the melting point (Tm) measured by DSC is preferably 145 to 230 ° C. .
  • the melt index of the PBS resin is preferably 1 to 20g / 10min (190 °C, 2.16kg load). As the melt index is lower, the stiffness and low elongation of the fiber can be imparted, but since the viscosity is lowered, the workability becomes worse. If the melt index is too high, the rigidity of the fiber is not only lowered, but the spinning is difficult.
  • the PBS resin is preferably melted alone or mixed with PBS (Polybutylene Succinate), PBSA (Polybutylene Succinate-co-adipate) or PBSF (Polybutylene succinate fumaric).
  • PBS Polybutylene Succinate
  • PBSA Polybutylene Succinate-co-adipate
  • PBSF Polybutylene succinate fumaric
  • the polylactic acid (PLA) resin and the PBS-based resin mixture is melted by injecting inorganic materials at the time of melting, such as inorganic minerals such as mica, gold mica, barium sulfate, titanium dioxide, talc, calcium carbonate (CaCO3), and the like.
  • inorganic minerals such as mica, gold mica, barium sulfate, titanium dioxide, talc, calcium carbonate (CaCO3), and the like.
  • One or more particles may be mixed.
  • the inorganic material is mixed to produce a fiber, there is an effect of controlling the filler or crystallization.
  • the ratio of the mixture at the time of melting the mixture is 50 to 92% by weight, 7 to 45% by weight and 1 to 5% by weight of the polylactic acid (PLA) resin, PBS-based resin and inorganic. Fibers produced in the above range is characterized by excellent physical properties and carding properties when manufacturing nonwoven fabrics.
  • the biodegradable yarn is prepared in the form of yarn or cotton, it is cut and put into the combiner to inflate and release the lump form and is supplied to the hopper using a back sulfur.
  • the biodegradable yarn supplied to the hopper is quantitatively supplied to the other cotton machine, and then is burnt in an unfolded state to form a moisturizing layer 1.
  • the moisturizing layer (1) delays natural decomposition for two to four years when the roots of the seeds are activated, thereby preventing soil loss and premature revelation of the construction surface, and absorbs and supplies moisture from the ground. As the growth is accelerated, the roots grow, and the biodegradable yarns that make up the moisturizing layer are released, the roots of the plant easily pass through the moisturizing layer and stick to the ground without damage. It will provide nutrients.
  • the seed layer (2) is formed by applying the seed on top of the moisturizing layer (1), this process is carried out by the automated process to form a moisturizing layer (1) on the conveyor line and then seed is applied to the seed It is made in such a way that the layer 2 is formed.
  • the seed layer 2 is closed by the seed protection layer 3, the seed protection layer 3, the seed protection layer 3 is a function to prevent the flow of the seed (detaching of the seed and transport to one side during transport or construction) And, it is formed of a pulp or biodegradable film in which a vent hole is formed so as to prevent loss of shell powder stored in the pocket network layer to be described later, and to allow dehumidification inside the seed layer.
  • the insulating layer 4 is formed by finishing at least one kind of natural material including the top of the seed layer 2, coir fiber, coco peat, bark, jute, straw, and fallen leaves. Insulating layer (4) is to cut the vegetable natural material and put it into the combiner to inflate, release the lump form and supply it to the hopper using the back sulfur, and the natural material supplied to the hopper is fed to the other cotton machine in the unfolded state ( ⁇ ) Is formed.
  • coir fiber, coco peat, bark, jute are items that depend on imports, so the price fluctuations are difficult and inventory is difficult to secure, it is possible to replace the straw, falling leaves that can be easily secured around the main raw material.
  • the insulating layer (4) to prevent germination of the warmth and water until the germination after covering the seed after construction, as well as tissues are easily expanded when sprouts of the seed is prevented, sprout damage after seed germination 1 Naturally decomposes in ⁇ 2 years and functions as natural nutrient
  • the protective net (5) is provided on the insulating layer 4 is provided to support the moisturizing layer (1), the seed layer (2), the insulating layer (4) integrally.
  • the protective net (5) is formed by weaving the same yarn as the biodegradable yarn forming the moisturizing layer (1) in a net form, and overlaps the vegetation mat to secure the entire vegetation mat in a manner of fixing the protective net (5) at the top Bonded to the ground.
  • the pocket net layer 20 is provided so that a plurality of compartments 22 are formed so that the shell powder 10 is stored between the seed protection layer 3 and the insulating layer 4.
  • Pocket net layer 20 is formed of jute mesh, straw straw mat, or biodegradable yarn network formed by polylactic acid (PLA) resin, PBS-based resin, inorganic material is provided to be naturally decomposed 10-14 months after construction do. That is, the pocket network layer 20 is a space in which the mesh eye of the mesh is formed constitutes the compartment 22.
  • the pocket network layer 20 is a compartment 22 sidewall compartment by the inclination line above the network structure. Is formed, the partition in the height direction compartment 22 is formed by the thickness of the inclination, and the upper and lower compartments 22 are provided by the insulating layer 4 and the seed protection layer 3 to be finished.
  • the yarn 22 is processed in a slanted direction by using the straw as the weft to form a compartment 22 in the gap between the straw and the straw.
  • the seed layer 2 and the seed protection layer 3 are continuously formed while the moisturizing layer 1 is transported through the transfer conveyor, and then the pocket net layer 20 is formed on the seed protection layer 3.
  • the lower portion of the compartment 22 of the pocket net layer 20 is kept closed by the seed protection layer 3, and then the shell powder 10 supplied to the upper pocket net layer 20 is the compartment ( 22) is stored between, wherein the shell powder 10 is added as much as the thickness of the pocket network layer (20).
  • the thermal insulation layer 4 and the protection net 5 are stacked on the pocket net layer 20 in the laminated state by the sewing line 30 to form an integral vegetation mat.
  • the sewing line 30 is bound to support each layer of vegetation mat with the protective net 5 as a whole, in particular the pocket net layer ( Along with the inclination of 20, the sewing line 30 subdivides the compartment 22 in the inclined direction to improve the shell powder oil compartment and the compartment 22 durability.
  • the shell powder 10 is accommodated and stored in the plurality of compartments 22 formed in the pocket network layer 20, and the thermal insulation layer after the site construction by forming the natural powder layer 21 in the vegetation mat interior space
  • the moisturizing layer (1) to delay the moisture evaporation of the ground while absorbing moisture in the rain to help drought, and then is naturally decomposed and used as plant nutrition supply manure .
  • the recycling throughput of the shell classified as industrial waste has a significant increase.
  • the shell powder (10) stored in the compartment 22 is dried in the form of rolls after forming the vegetation mat due to the pores that have the shell itself while forming a number of pores between the particles to absorb moisture during storage
  • the inside of the mat is kept dry at all times, thus preventing the early germination of the rainy season seeds, and having excellent storage properties, thus providing a large amount of inventory for the high season.

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
  • Cultivation Of Plants (AREA)

Abstract

The present invention relates to a vegetation mat using shells, and in order to significantly increase a processing capacity for recycling shells by improving a mat structure, while adding a dehumidifying function for preventing seeds from germinating early during heat retention, moisture retention, nutrition supply, and storage, by recycling shells classified as industrial waste, the vegetation mat using shells consists of a vegetation mat and a pocket net layer (20) as main elements, wherein the vegetation mat is constituted of a water retaining layer (1), a seed layer (2), a seed protecting layer (3), a heat retaining layer (4), and a protecting net (5), and compartments (22) are formed in the pocket net layer (20).

Description

패각을 이용한 식생매트Vegetation mat using shell
본 발명은 패각을 이용한 식생매트에 관한 것으로, 보다 상세하게는 산업폐기물로 분류되는 패각(조개껍데기, 굴껍질 등)을 재활용하여 보온, 보습, 영양공급 및 보관 중 종자 조기 발아현상을 방지하는 제습기능이 부가되면서, 매트구조를 개선하여 패각 재활용 처리량이 획기적으로 증대되도록 하는 패각을 이용한 식생매트에 관한 것이다.The present invention relates to a vegetation mat using shells, and more specifically, to recycle seed shells (shell shells, oyster shells, etc.) classified as industrial wastes, to prevent seed germination during warming, moisturizing, feeding, and storing. As the function is added, the present invention relates to a vegetation mat using a shell to improve the structure of the mat to significantly increase the shell recycling throughput.
통상적으로 패류(貝類)수산물 가공 처리과정에서 발생하는 패각은 산업폐기물로 분리되어, 현재 처분을 기다리는 양이 48만 톤에 이르며, 매년 13만 톤의 폐기물이 신규로 발생되어 악취와 침출수 문제로 처리에 어려움을 격고 있다. 이에 패각을 활용하여 방음, 단열, 축열재 등 건축용 내외장재로 다양한 분야에 적용되고 있으나, 사실상 소비량이 극히 미비한 실정이고, 근자에는 패각에 포함된 칼슘 및 각종 유기물을 천연비료로 활용하기 위해 식생매트 분야로까지 사용범위가 확대되고 있다.Usually, shells generated during the processing of shellfish and aquatic products are separated into industrial waste, and the amount currently waiting for disposal reaches 480,000 tons, and 130,000 tons of new waste are generated annually, resulting in odor and leachate problems. Are having difficulty. It is applied to various fields such as soundproofing, heat insulation, heat storage materials, etc. by using shells, but in reality, consumption is extremely low, and in recent years, vegetation mat field is used to utilize calcium and various organic substances contained in shells as natural fertilizers. The range of use is being expanded to.
종래에 게시된 패각이 적용된 식생매트를 살펴보면, 특허등록번호 제10-1142191호에서 부직포층, 종자층, 코아솜매트층, 제1생분해네트층으로 이루어진 식생매트에서, 부직포층 상면에 축분, 황통, 패각분말, 톱밥, 전분, 물을 포함하는 영양공급조성물을 코팅하여 퇴비층을 형성하도록 구성되어, 식물의 식생 후에는 안정된 수분 및 영양분의 공급이 가능하여 식물의 안정된 생육이 가능하도록 하는 기술이 선등록된바 있다.Looking at the vegetation mat applied to the conventionally published shell, in the vegetation mat consisting of a nonwoven fabric layer, seed layer, coasome mat layer, the first biodegradation net layer in the patent registration No. 10-1142191, the crushed powder on the top surface of the nonwoven layer It is configured to form a compost layer by coating the nutrient supply composition including shell powder, sawdust, starch, water, and after the vegetation of the plant, it is possible to supply stable moisture and nutrients so that the stable growth of the plant is possible. It has been pre-registered.
그러나, 상기 종래기술은 패각이 포함된 퇴비층을 식생매트에 적용한 기술이나, 퇴비층을 구성하는 혼합 혼합비율을 상세하게 살며보면 축분 20중량% , 황토 30중량%, 패각분말 20중량%, 톱밥 10중량%, 전분 10중량%, 물 10중량%로 혼합된 것으로, 패각 사용량이 극히 미비함에 따라 산업폐기물 재활용 효과 및 천연비료로서의 기능을 십분 발휘하지 못하는 실정이다.However, the conventional technology is applied to the vegetation layer containing the shell, the vegetation mat, or in detail the mixing ratio constituting the compost layer 20% by weight, 30% by weight ocher, 20% by weight of shell powder, sawdust 10% by weight, 10% by weight starch, 10% by weight of water, the use of the shell is extremely insufficient, the situation is not able to fully exhibit the function of industrial waste recycling and natural fertilizer.
뿐만 아니라, 패각은 자연분해 시간단축 및 흡수율을 높이기 위해 분말형태로 재활용됨에 따라 식생매트에 적용시 유실을 방지하기 위한 수단으로 물과 함께 혼합하여 퇴비층을 코팅형성하므로, 제조공정 및 설비가 복잡하고, 특히 퇴비층에 포함된 수분 및 장마철 매트 내부습도가 높아지면 종자가 단시간에 조기 발아되므로 재고확보에 많은 어려움이 따랐다.In addition, the shell is recycled in powder form to shorten the time to decompose and increase the rate of absorption. As a means to prevent loss when applied to vegetation mats, the shell is mixed with water to form a compost layer, which makes the manufacturing process and equipment complicated. In particular, when the moisture contained in the compost layer and the internal humidity of the mat in the rainy season are high, the seeds germinate early in a short time, so many difficulties in securing the inventory.
이에 따라 본 발명은 상기한 문제점을 해결하기 위해 착안된 것으로서, 산업폐기물로 분류되는 패각을 재활용하여 보온, 보습, 영양공급 및 보관 중 종자 조기 발아현상을 방지하는 제습기능이 부가되면서, 매트구조를 개선하여 패각 재활용 처리량이 획기적으로 증대되도록 하는 패각을 이용한 식생매트를 제공하는 것에 그 목적이 있다.Accordingly, the present invention has been conceived to solve the above problems, while recycling the shell classified as industrial waste, while the dehumidification function to prevent early germination of seeds during warming, moisturizing, nutrition and storage is added, the mat structure It is an object of the present invention to provide a vegetation mat using shells that can be improved to significantly increase shell recycling throughput.
이러한 목적을 달성하기 위해 본 발명의 특징은, 보습층(1), 종자층(2), 종자보호층(3), 보온층(4) 및 보호망(5)을 적층하여 구성되고, 상기 종자보호층(3)과 보온층(4) 사이에는 패각분말(10)이 저장되도록 복수의 격실(22)이 형성되는 포켓망층(20)이 구비되며, 상기 포켓망층(20)은 망조직의 위,경사 라인에 의해 격실(22) 측벽구획이 형성되고, 위, 경사 굵기에 의해 높이방향 격실(22) 구획이 형성되며, 보온층(4)과 종자보호층(3)에 의해 격실(22) 상하부가 마감되도록 구비되며, 상기 적층된 각 층은 봉재라인(30)에 의해 합포처리되어 일체형으로 형성되는 것을 특징으로 한다.In order to achieve this object, a feature of the present invention is configured by laminating a moisturizing layer (1), a seed layer (2), a seed protecting layer (3), an insulating layer (4) and a protective net (5), and protecting the seed. Between the layer 3 and the thermal insulation layer 4 is provided with a pocket network layer 20 is formed with a plurality of compartments 22 to store the shell powder 10, the pocket network layer 20 is formed on the top of the network, Side wall compartments of compartments 22 are formed by the inclined lines, and compartments in the height direction 22 are formed by the inclination thickness, and the upper and lower compartments of the compartments 22 are formed by the insulating layer 4 and the seed protection layer 3. Is provided to be finished, the laminated each layer is characterized in that it is formed integrally by being processed by the sewing line (30).
이때, 상기 포켓망층(20)은 황마망, 볏짚매트로 형성되거나, 폴리락트산(PLA) 수지 및 PBS계 수지, 무기물을 포함하여 형성되는 생분해성원사 망조직으로 형성되어 시공후 10~14개월 후 자연분해되도록 구비되는 것을 특징으로 한다.At this time, the pocket mesh layer 20 is formed of jute mesh, straw straw mat, or formed of a biodegradable yarn network structure formed of polylactic acid (PLA) resin, PBS resin, inorganic material 10 to 14 months after construction Characterized in that it is provided to be disassembled.
또한, 상기 보습층(1)은 폴리락트산(PLA) 수지 및 PBS계 수지, 무기물을 포함하여 형성되는 생분해성 원사를 타면(打綿)하여 형성되고, 종자층(2)은 보습층(1) 상부에 종자를 도포하여 형성되며, 보온층(4)은 종자층(2) 상부를 마감하고, 코이어섬유, 코코피트, 바크, 황마, 짚, 낙엽을 포함하는 천연소재 중 적어도 어느 1종을 타면하여 형성되며, 보호망(5)은 보온층(4) 상부에 설치되어 보습층(1) 및 종자층(2), 보온층(4)을 일체로 지지하도록 구비되는 것을 특징으로 한다.In addition, the moisturizing layer (1) is formed by the other surface of the biodegradable yarn formed of polylactic acid (PLA) resin, PBS-based resin, inorganic material, the seed layer (2) is a moisturizing layer (1) It is formed by applying seeds to the top, the insulating layer 4 finishes the top of the seed layer (2), at least any one of natural materials including coir fiber, coco peat, bark, jute, straw, deciduous leaves It is formed on the other side, the protective net (5) is installed on the insulating layer 4 is characterized in that it is provided to integrally support the moisturizing layer (1), the seed layer (2), the insulating layer (4).
또한, 상기 종자보호층(3)은 통기공이 형성되는 펄프 또는 생분해성 필름으로 형성되는 것을 특징으로 한다.In addition, the seed protective layer (3) is characterized in that it is formed of a pulp or biodegradable film in which the air holes are formed.
이상의 구성 및 작용에 의하면, 본 발명은 포켓망층의 격실에 패각분말이 격리 수용되어 운반 및 설치작업 중에 패각분말 유실 및 쏠림현상이 방지되고, 특히 산업폐기물로 분류되는 패각분말을 재활용하여 보온, 보습, 영양공급기능을 복합적으로 가지면서, 포켓망층의 위,경사 굵기 및 조직밀도에 따라 격실 사이즈가 탄력적으로 확장되어 패각 재활용 처리량이 획기적으로 증대되는 효과가 있다.According to the above configuration and operation, the shell powder is contained in the compartment of the pocket net layer to prevent the shell powder loss and tipping during transportation and installation work, and in particular, by recycling the shell powder classified as industrial waste, to keep warm In addition, it has a nutritional supply function, and the compartment size is elastically expanded according to the thickness of the pocket mesh layer, the inclination thickness, and the tissue density, thereby significantly increasing the shell recycling throughput.
그리고, 본 발명은 패각분말로 이루어진 포켓망층이 식생매트를 롤형태로 보관시 제습기능으로 인해 장마철 종자의 조기 발아현상이 방지됨에 따라 보관성이 우수하면서 성수기를 대비하여 대량의 재고확보가 가능한 효과가 있다.In addition, the present invention has an excellent shelf life and prevents the early germination of the rainy season seed due to the dehumidification function when the pocket net layer made of shell powder in the form of roll prevents the high availability and secure a large inventory for the high season There is.
도 1은 본 발명의 일 실시예에 따른 패각을 이용한 식생매트를 전체적으로 나타내는 구성도.1 is a block diagram showing the vegetation mat as a whole using a shell according to an embodiment of the present invention.
도 2는 본 발명의 일 실시예에 따른 패각을 이용한 식생매트의 포켓망층을 확대하여 나타내는 구성도.Figure 2 is a block diagram showing an enlarged pocket mesh layer of the vegetation mat using a shell according to an embodiment of the present invention.
도 3은 본 발명의 일 실시예에 따른 패각을 이용한 식생매트를 롤형태로 말아서 보관하는 상태를 나타내는 구성도.Figure 3 is a block diagram showing a state in which the rolled vegetation mat using the shell according to an embodiment of the present invention in a roll shape.
*도면의 주요부분에 대한 부호의 설명** Description of the symbols for the main parts of the drawings *
10: 패각분말 20: 포켓망층10: shell powder 20: pocket network layer
22: 격실22: compartment
이하, 첨부된 도면을 참조하여 본 발명의 바람직한 실시예를 상세히 설명한다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.
본 발명에 따른 패각을 이용한 식생매트에 관련되며, 이때 패각을 이용한 식생매트는 산업폐기물로 분류되는 패각을 재활용하여 보온, 보습, 영양공급 및 보관 중 종자 조기 발아현상을 방지하는 제습기능이 부가되면서, 매트구조를 개선하여 패각 재활용 처리량이 획기적으로 증대되도록 하기 위해 보습층(1), 종자층(2), 종자보호층(3), 보온층(4), 보호망(5)으로 구성되는 식생매트 및 격실(22)이 형성되는 포켓망층(20)을 포함하여 주요구성으로 이루어진다.Related to the vegetation mat using the shell according to the present invention, wherein the vegetation mat using the shell is added to the dehumidification function to prevent early germination of seeds during warming, moisturizing, nutrition and storage by recycling the shell classified as industrial waste , A vegetation mat composed of a moisturizing layer (1), a seed layer (2), a seed protection layer (3), an insulating layer (4), and a protective net (5) in order to improve the mat structure so that the shell recycling throughput can be significantly increased. And a pocket mesh layer 20 in which the compartment 22 is formed.
본 발명에 따른 식생매트는 보습층(1), 종자층(2), 종자보호층(3), 보온층(4) 및 보호망(5)을 적층하여 구성된다. 상기 보습층(1)은 폴리락트산(PLA) 수지 및 PBS계 수지, 무기물을 포함하여 형성되는 생분해성 원사를 타면(打綿)하여 형성된다. 보습층(1)은 지면과 접촉되어 수분을 흡수하고, 흡수된 수분을 종자로 공급하여 초기 발아를 촉진시킴은 물론 가뭄에 의한 괴사를 방지하게 된다.The vegetation mat according to the present invention is constructed by laminating a moisturizing layer 1, a seed layer 2, a seed protective layer 3, a thermal insulation layer 4 and a protective net 5. The moisturizing layer 1 is formed on the other surface of a biodegradable yarn formed of a polylactic acid (PLA) resin, a PBS-based resin, and an inorganic substance. Moisturizing layer (1) is in contact with the ground to absorb moisture, supply the absorbed moisture to the seed to promote early germination and to prevent necrosis by drought.
여기서 폴리락트산(PLA) 수지라 함은 락트산(Lactic acid)을 단량체로 구성한 폴리머 전체를 지칭하며, PLA 수지는 이성질체 D-Lactide, L-Lactide 함량 및 배열(랜덤공중합, 블럭공중합)에 따라 열특성 및 물리적특성 등이 달라질 수 있다.Here, polylactic acid (PLA) resin refers to the entire polymer composed of lactic acid (Lactic acid) as a monomer, PLA resin is thermal properties according to the isomer D-Lactide, L-Lactide content and arrangement (random copolymerization, block copolymerization) And physical properties may vary.
그리고 폴리락트산(PLA)수지의 용융지수(MI) 10 내지 50g/10min(230℃, 2.16kg의 하중)인 것이 바람직하고, DSC로 측정한 융융점(Tm)이 145 내지 230℃인 것이 바람직하다. 또한, 상기 PBS계 수지의 용융지수는 1 내지 20g/10min (190℃,2.16kg의 하중)인 것이 바람직하다. 상기 용융지수가 낮을수록 섬유의 강성, 낮은 신율을 부여할 수 있지만 점도가 저하되므로 가공성이 나빠지게 되며, 용융지수가 너무 높으면 섬유의 강성이 저하될 뿐만 아니라, 방사가 어려운 문제점이 있다.The melt index (MI) of the polylactic acid (PLA) resin is preferably 10 to 50 g / 10 min (230 ° C., 2.16 kg load), and the melting point (Tm) measured by DSC is preferably 145 to 230 ° C. . In addition, the melt index of the PBS resin is preferably 1 to 20g / 10min (190 ℃, 2.16kg load). As the melt index is lower, the stiffness and low elongation of the fiber can be imparted, but since the viscosity is lowered, the workability becomes worse. If the melt index is too high, the rigidity of the fiber is not only lowered, but the spinning is difficult.
또, PBS계 수지는 PBS (Polybutylene Succinate), PBSA (Polybutylene Succinate-co-adipate) 또는 PBSF (Polybutylene succinate fumaric)을 단독 또는 1이상 혼합 용융하는 것이 바람직하다.In addition, the PBS resin is preferably melted alone or mixed with PBS (Polybutylene Succinate), PBSA (Polybutylene Succinate-co-adipate) or PBSF (Polybutylene succinate fumaric).
그리고, 상기 폴리락트산(PLA)수지와 PBS계 수지 혼합물을 용융시에 무기물을 투입하여 용융시키는 데, 백운모, 금운모, 황산바륨, 이산화티타늄, 탈크 (Talc), 탄산칼슘(CaCO3)등의 무기 입자를 1이상 혼합할 수 있다. 상기 무기물이 혼합되어 섬유를 제조할 경우 필러(Filler) 또는 결정화를 제어할 수 있는 효과가 있다.In addition, the polylactic acid (PLA) resin and the PBS-based resin mixture is melted by injecting inorganic materials at the time of melting, such as inorganic minerals such as mica, gold mica, barium sulfate, titanium dioxide, talc, calcium carbonate (CaCO3), and the like. One or more particles may be mixed. When the inorganic material is mixed to produce a fiber, there is an effect of controlling the filler or crystallization.
상기 혼합물 용융시에 혼합되는 비율은 폴리락트산(PLA) 수지, PBS계 수지 및 무기물이 각각 50 내지 92 중량%, 7 내지 45 중량% 및 1 내지 5 중량%로 혼합된다. 상기 범위내에서 제조된 섬유가 물성이 우수하며 부직포 제조시 카딩성이 우수한 특징이 있다. The ratio of the mixture at the time of melting the mixture is 50 to 92% by weight, 7 to 45% by weight and 1 to 5% by weight of the polylactic acid (PLA) resin, PBS-based resin and inorganic. Fibers produced in the above range is characterized by excellent physical properties and carding properties when manufacturing nonwoven fabrics.
상기에서 생분해성 원사는 원사 또는 솜형태로 준비되고, 이를 절개하여 조합기에 투입하여 부풀리면서 덩어리형태를 풀어 후황을 이용하여 호퍼로 공급된다. 호퍼로 공급된 생분해성 원사는 타면기로 정량공급되어 펼쳐진 상태로 타면(打綿)되어 보습층(1)을 형성하게 된다.The biodegradable yarn is prepared in the form of yarn or cotton, it is cut and put into the combiner to inflate and release the lump form and is supplied to the hopper using a back sulfur. The biodegradable yarn supplied to the hopper is quantitatively supplied to the other cotton machine, and then is burnt in an unfolded state to form a moisturizing layer 1.
이에 보습층(1)은 종자의 뿌리 활착이 활성화되는 2~4년간 자연분해가 지연되어 시공면의 토사유실 및 조기분개현상을 방지함과 더불어 지면으로부터 수분을 흡수하여 공급하므로 종자의 초기 발아율 및 생육이 촉진되고, 뿌리가 성장함과 더불어 보습층을 구성하는 생분해성 원사가 풀어지면서 식물의 뿌리가 보습층을 쉽게 통과하여 손상없이 지중에 활착되고, 뿌리 활착이 활성화된 후에는 자연분해되어 식물에 영양분을 공급하게 된다.The moisturizing layer (1) delays natural decomposition for two to four years when the roots of the seeds are activated, thereby preventing soil loss and premature revelation of the construction surface, and absorbs and supplies moisture from the ground. As the growth is accelerated, the roots grow, and the biodegradable yarns that make up the moisturizing layer are released, the roots of the plant easily pass through the moisturizing layer and stick to the ground without damage. It will provide nutrients.
또한, 상기 종자층(2)은 보습층(1) 상부에 종자를 도포하여 형성되는바, 이러하는 공정은 자동화 공정에 의해 컨베이어라인을 타고 보습층(1)이 형성되면 이어서 종자가 도포되어 종자층(2)을 형성하는 방식으로 이루어진다.In addition, the seed layer (2) is formed by applying the seed on top of the moisturizing layer (1), this process is carried out by the automated process to form a moisturizing layer (1) on the conveyor line and then seed is applied to the seed It is made in such a way that the layer 2 is formed.
이때 상기 종자층(2)은 종자보호층(3)에 의해 상부가 마감되되, 여기서 종자보호층(3)은 종자의 유동(운반 또는 시공중 종자의 이탈 및 일측으로 쏠리는 현상)을 방지하는 기능과, 후술하는 포켓망층에 저장된 패각분말 유실이 방지되는 기능과, 종자층 내부 제습이 가능하도록 통기공이 형성되는 펄프 또는 생분해성 필름으로 형성된다.At this time, the seed layer 2 is closed by the seed protection layer 3, the seed protection layer 3, the seed protection layer 3 is a function to prevent the flow of the seed (detaching of the seed and transport to one side during transport or construction) And, it is formed of a pulp or biodegradable film in which a vent hole is formed so as to prevent loss of shell powder stored in the pocket network layer to be described later, and to allow dehumidification inside the seed layer.
또한, 상기 보온층(4)은 종자층(2) 상부를 마감하고, 코이어섬유, 코코피트, 바크, 황마, 짚, 낙엽을 포함하는 천연소재 중 적어도 어느 1종을 타면하여 형성된다. 보온층(4)은 식물성 천연소재를 절개하여 조합기에 투입하여 부풀리면서 덩어리형태를 풀어 후황을 이용하여 호퍼로 공급하고, 호퍼로 공급된 천연소재는 타면기로 정량공급되어 펼쳐진 상태로 타면(打綿)되어 형성된다.In addition, the insulating layer 4 is formed by finishing at least one kind of natural material including the top of the seed layer 2, coir fiber, coco peat, bark, jute, straw, and fallen leaves. Insulating layer (4) is to cut the vegetable natural material and put it into the combiner to inflate, release the lump form and supply it to the hopper using the back sulfur, and the natural material supplied to the hopper is fed to the other cotton machine in the unfolded state (펼쳐) Is formed.
이때, 코이어섬유, 코코피트, 바크, 황마는 수입에 의존하는 품목으로서 가격변동이 심하고 재고 확보가 곤란하므로, 주변에서 쉽게 확보할 수 있는 짚, 낙옆을 주원료로 대체가능하다.At this time, coir fiber, coco peat, bark, jute are items that depend on imports, so the price fluctuations are difficult and inventory is difficult to secure, it is possible to replace the straw, falling leaves that can be easily secured around the main raw material.
이에 보온층(4)은 시공후 종자를 덮은 상태로 발아되기 까지 보온 및 수분 과다증발을 방지함은 물론 종자의 새싹이 올라오면 조직이 쉽게 확장되어 새싹 손상이 방지되고, 또 종자가 발아 후 1~2년사이에 자연분해되어 천연영양분으로 기능을 수행하게 된다.The insulating layer (4) to prevent germination of the warmth and water until the germination after covering the seed after construction, as well as tissues are easily expanded when sprouts of the seed is prevented, sprout damage after seed germination 1 Naturally decomposes in ~ 2 years and functions as natural nutrient
또한, 상기 보호망(5)은 상기 보온층(4) 상부에 설치되어 보습층(1) 및 종자층(2), 보온층(4)을 일체로 지지하도록 구비된다. 보호망(5)은 상기 보습층(1)을 형성하는 생분해성 원사와 동일한 원사를 그물형태로 직조하여 형성되고, 식생매트를 겹쳐서 시공시 상부에서 보호망(5)을 고정하는 방식으로 식생매트 전체를 지면에 결박하게 된다.In addition, the protective net (5) is provided on the insulating layer 4 is provided to support the moisturizing layer (1), the seed layer (2), the insulating layer (4) integrally. The protective net (5) is formed by weaving the same yarn as the biodegradable yarn forming the moisturizing layer (1) in a net form, and overlaps the vegetation mat to secure the entire vegetation mat in a manner of fixing the protective net (5) at the top Bonded to the ground.
또한, 본 발명에 따른 포켓망층(20)은 종자보호층(3)과 보온층(4) 사이에서 패각분말(10)이 저장되도록 복수의 격실(22)이 형성되도록 구비된다. 포켓망층(20)은 황마망, 볏짚매트로 형성되거나, 폴리락트산(PLA) 수지 및 PBS계 수지, 무기물을 포함하여 형성되는 생분해성원사 망조직으로 형성되어 시공후 10~14개월 후 자연분해되도록 구비된다. 즉 포켓망층(20)은 망의 메쉬눈이 형성되는 공간이 격실(22)을 구성하는바, 일실시예로서 포켓망층(20)은 망조직의 위,경사 라인에 의해 격실(22) 측벽구획이 형성되고, 위, 경사 굵기에 의해 높이방향 격실(22) 구획이 형성되며, 보온층(4)과 종자보호층(3)에 의해 격실(22) 상하부가 마감되도록 구비된다.In addition, the pocket net layer 20 according to the present invention is provided so that a plurality of compartments 22 are formed so that the shell powder 10 is stored between the seed protection layer 3 and the insulating layer 4. Pocket net layer 20 is formed of jute mesh, straw straw mat, or biodegradable yarn network formed by polylactic acid (PLA) resin, PBS-based resin, inorganic material is provided to be naturally decomposed 10-14 months after construction do. That is, the pocket network layer 20 is a space in which the mesh eye of the mesh is formed constitutes the compartment 22. As an example, the pocket network layer 20 is a compartment 22 sidewall compartment by the inclination line above the network structure. Is formed, the partition in the height direction compartment 22 is formed by the thickness of the inclination, and the upper and lower compartments 22 are provided by the insulating layer 4 and the seed protection layer 3 to be finished.
한편, 상기 포켓망층(20)을 볏짚매트로 형성시에는, 볏짚을 위사로 하여 경사방향으로 봉재처리하여 볏짚과 볏짚사이에 틈새에 격실(22)을 형성하게 된다.On the other hand, when the pocket mesh layer 20 is formed of straw straw mat, the yarn 22 is processed in a slanted direction by using the straw as the weft to form a compartment 22 in the gap between the straw and the straw.
제조공정에 있어서, 보습층(1)이 이송컨베이어를 타고 이송되는 중에 종자층(2)과 종자보호층(3)이 연속 형성되고, 이어서 종자보호층(3) 상부에 포켓망층(20)이 형성되는바, 이때 포켓망층(20)의 격실(22) 하부는 종자보호층(3)에 의해 마감된 상태로 유지되고, 이후 포켓망층(20) 상부로 공급되는 패각분말(10)이 격실(22)에 사이사이에 저장되고, 이때 패각분말(10)은 포켓망층(20) 두께 만큼 투입된다. 이어서 포켓망층(20) 상부에 보온층(4) 및 보호망(5)이 적층된 상태로 봉재라인(30)에 의해 합포처리되어 일체형 식생매트를 구성하게 된다.In the manufacturing process, the seed layer 2 and the seed protection layer 3 are continuously formed while the moisturizing layer 1 is transported through the transfer conveyor, and then the pocket net layer 20 is formed on the seed protection layer 3. At this time, the lower portion of the compartment 22 of the pocket net layer 20 is kept closed by the seed protection layer 3, and then the shell powder 10 supplied to the upper pocket net layer 20 is the compartment ( 22) is stored between, wherein the shell powder 10 is added as much as the thickness of the pocket network layer (20). Subsequently, the thermal insulation layer 4 and the protection net 5 are stacked on the pocket net layer 20 in the laminated state by the sewing line 30 to form an integral vegetation mat.
이때, 상기 봉재라인(30)을 형성하는 봉재원사는 상기 생분해성원사를 사용하는 것이 바람직하고, 봉재라인(30)이 보호망(5)과 함께 식생매트 각 층을 전체적으로 결속지지하고, 특히 포켓망층(20)의 경사와 함께 봉재라인(30)이 경사방향으로 격실(22)을 세분화하여 패각분말 유실 및 격실(22) 내구성을 향상시키기 된다.In this case, it is preferable to use the biodegradable yarns for forming the sewing line 30, the sewing line 30 is bound to support each layer of vegetation mat with the protective net 5 as a whole, in particular the pocket net layer ( Along with the inclination of 20, the sewing line 30 subdivides the compartment 22 in the inclined direction to improve the shell powder oil compartment and the compartment 22 durability.
이처럼, 상기 포켓망층(20)에 형성되는 복수의 격실(22) 내부로 패각분말(10)이 수용저장되어, 식생매트 내부공간에 천연분말층(21)을 형성함에 따라 현장시공 후 상기 보온층(4)과 함께 동절기 보온효과를 향상시키고, 또 보습층(1)과 함께 지면 수분증발을 지연시키면서 우천시 수분을 흡수보유하여 가뭄해갈에 도움을 주고, 이후 자연분해되어 식물 영양공급 거름으로 활용된다.As such, the shell powder 10 is accommodated and stored in the plurality of compartments 22 formed in the pocket network layer 20, and the thermal insulation layer after the site construction by forming the natural powder layer 21 in the vegetation mat interior space In addition to (4) to improve the winter warming effect, and with the moisturizing layer (1) to delay the moisture evaporation of the ground while absorbing moisture in the rain to help drought, and then is naturally decomposed and used as plant nutrition supply manure .
그리고, 상기 격실(22)은 포켓망층(20)의 위,경사 굵기 및 조직밀도에 따라 사이즈가 탄력적으로 확장되므로 산업폐기물로 분류되는 패각의 재활용 처리량이 획기적으로 증대되는 이점이 있다.In addition, since the size of the compartment 22 elastically expands according to the inclination thickness and the tissue density of the pocket network layer 20, the recycling throughput of the shell classified as industrial waste has a significant increase.
특히, 상기 격실(22)에 저장된 패각분말(10)은 건조된 상태로 입자 사이에 수많은 기공을 형성하면서 패각 자체적으로 가지는 기공들로 인해 식생매트를 제조 후 롤형태로 말아서 보관시 수분을 흡수하는 제습기능을 수행하여 매트내부가 항상 건조한 상태로 유지되는 내습성을 가짐에 따라 장마철 종자의 조기 발아현상이 방지됨과 더불어 보관성이 우수하여 성수기를 대비한 대량의 재고확보가 가능한 이점이 있다.In particular, the shell powder (10) stored in the compartment 22 is dried in the form of rolls after forming the vegetation mat due to the pores that have the shell itself while forming a number of pores between the particles to absorb moisture during storage By performing the dehumidification function, the inside of the mat is kept dry at all times, thus preventing the early germination of the rainy season seeds, and having excellent storage properties, thus providing a large amount of inventory for the high season.

Claims (4)

  1. 보습층(1), 종자층(2), 종자보호층(3), 보온층(4) 및 보호망(5)을 적층하여 구성되고,It is configured by laminating the moisturizing layer (1), the seed layer (2), the seed protective layer (3), the insulating layer (4) and the protective net (5),
    상기 종자보호층(3)과 보온층(4) 사이에는 배치되어 복수의 격실(22)이 형성되는 포켓망층(20)이 구비되며,A pocket net layer 20 is disposed between the seed protection layer 3 and the insulating layer 4 to form a plurality of compartments 22.
    상기 포켓망층(20)은 망조직의 위,경사 라인에 의해 격실(22) 측벽구획이 형성되고, 위, 경사 굵기에 의해 높이방향 격실(22) 구획이 형성되며, 보온층(4)과 종자보호층(3)에 의해 격실(22) 상하부가 마감되도록 구비되며,The pocket mesh layer 20 has compartment 22 sidewall compartments formed by the inclination lines on the network, and the compartment 22 in the height direction is formed by the inclined thickness, and the insulation layer 4 and the seed are formed. The upper and lower parts of the compartment 22 are closed by the protective layer 3,
    상기 격실(22) 내부에 건조된 패각분말이 수용저장되어, 식생매트를 롤형태로 말아서 보관시 수분을 흡수보유하여 종자 조기 발아현상을 방지하도록 구비되는 천연분말층(21);The shell powder dried in the compartment 22 is accommodated and stored, the natural powder layer 21 is provided to prevent the early germination of seeds by absorbing moisture when the vegetation mat is rolled in the form of a roll;
    상기 적층된 각 층은 봉재라인(30)에 의해 합포처리되어 일체형으로 형성되는 것을 특징으로 하는 패각을 이용한 식생매트.Each layer of the laminated vegetation mat using a shell, characterized in that formed by integrally processed by the sewing line (30).
  2. 제 1항에 있어서,The method of claim 1,
    상기 포켓망층(20)은 황마망, 볏짚매트로 형성되거나, 폴리락트산(PLA) 수지 및 PBS계 수지, 무기물을 포함하여 형성되는 생분해성원사 망조직으로 형성되어 시공후 10~14개월 후 자연분해되도록 구비되는 것을 특징으로 하는 패각을 이용한 식생매트.The pocket net layer 20 is formed of jute net, straw straw mat, or a biodegradable yarn net tissue formed of polylactic acid (PLA) resin, PBS resin, and inorganic material to be naturally decomposed after 10 to 14 months after construction. Vegetation mat using a shell, characterized in that provided.
  3. 제 1항에 있어서,The method of claim 1,
    상기 보습층(1)은 폴리락트산(PLA) 수지 및 PBS계 수지, 무기물을 포함하여 형성되는 생분해성 원사를 타면(打綿)하여 형성되고, 종자층(2)은 보습층(1) 상부에 종자를 도포하여 형성되며, 보온층(4)은 종자층(2) 상부를 마감하고, 코이어섬유, 코코피트, 바크, 황마, 짚, 낙엽을 포함하는 천연소재 중 적어도 어느 1종을 타면하여 형성되며, 보호망(5)은 보온층(4) 상부에 설치되어 보습층(1) 및 종자층(2), 보온층(4)을 일체로 지지하도록 구비되는 것을 특징으로 하는 패각을 이용한 식생매트.The moisturizing layer 1 is formed on the other surface of a biodegradable yarn formed of a polylactic acid (PLA) resin, a PBS-based resin, and an inorganic substance, and the seed layer 2 is formed on the moisturizing layer 1. It is formed by applying the seed, the insulating layer (4) finishes the top of the seed layer (2), the surface of at least any one of natural materials including coir fiber, coco peat, bark, jute, straw, fallen leaves It is formed, the guard net (5) is installed on top of the insulating layer (4) vegetation mat using a shell, characterized in that provided to support the moisturizing layer (1), seed layer (2), the insulating layer (4) integrally .
  4. 제 1항에 있어서,The method of claim 1,
    상기 종자보호층(3)은 통기공이 형성되는 펄프 또는 생분해성 필름으로 형성되는 것을 특징으로 하는 패각을 이용한 식생매트.The seed protection layer (3) is a vegetation mat using a shell, characterized in that formed with a pulp or biodegradable film in which the ventilation holes are formed.
PCT/KR2016/005725 2016-02-22 2016-05-30 Vegetation mat using shells WO2017146306A1 (en)

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