WO2017133053A1 - Slimy bath bomb - Google Patents

Slimy bath bomb Download PDF

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Publication number
WO2017133053A1
WO2017133053A1 PCT/CN2016/075830 CN2016075830W WO2017133053A1 WO 2017133053 A1 WO2017133053 A1 WO 2017133053A1 CN 2016075830 W CN2016075830 W CN 2016075830W WO 2017133053 A1 WO2017133053 A1 WO 2017133053A1
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WO
WIPO (PCT)
Prior art keywords
bathing
viscous
cartridge according
cartridge
composition
Prior art date
Application number
PCT/CN2016/075830
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French (fr)
Chinese (zh)
Inventor
富利乐⋅马勒
Original Assignee
富利乐科技(深圳)有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 富利乐科技(深圳)有限公司 filed Critical 富利乐科技(深圳)有限公司
Priority to CN201680001888.8A priority Critical patent/CN106794133A/en
Publication of WO2017133053A1 publication Critical patent/WO2017133053A1/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/88Polyamides

Definitions

  • the present invention relates to the technical field of compositions for bathing, and more particularly to a slimy bath bomb which generates bubbles and a viscous effect by a fizzing action.
  • the bath composition may contain one or more functional ingredients such as natural salt, natural sea salt, minerals and essential oils, and even trace elements such as iron, calcium, selenium, magnesium, and other elements that are desirable to humans. Long-term use of these compositions can improve the health of the body, such as eliminating melanin in the skin, gradually reducing the skin's whitening, smoothness, elasticity, and eliminating facial acne or pigmentation.
  • European Patent No. 1,917,514 B1 discloses a bath composition for peeling off skin keratin and softening the skin, comprising sodium polyacrylate powder as an active ingredient or a reagent dispersed in an oil-based solution.
  • the composition is particularly suitable for use in cosmetics, spa and beauty products.
  • the composition is applied to the skin to produce exfoliation and softening effects using hydrazine.
  • the skin is then rinsed with water, and the sodium polyacrylate powder swells and turns into a soft gel, allowing the oil base to be released into the skin to soften and moisturize the skin. Oil-based and other additives soften and even moisturize rough-type skin and give the skin a soft peeling sensation. Therefore, the composition according to EP1791514B1 is capable of achieving peeling and softening of the skin in a sequential treatment.
  • the present invention provides a viscous bathing cartridge comprising a bath composition comprising polyacrylamide
  • the slip-slip bath of the present invention comprises polyacrylamide, sodium bicarbonate, citric acid monohydrate and a binder, and forms a solid block. Therefore, the viscous bathing bomb of the present invention is in contact with water, and can assist the polyacrylamide to absorb moisture through a special foaming action, and form a viscous gelatinous mass (gel -like mass), which improves the fun of bathing.
  • FIG. 1 is a schematic structural view of a slip-slip bathing cartridge according to an embodiment of the present invention.
  • the present invention provides a viscous bathing cartridge comprising a bath composition comprising polyacrylamide, sodium bicarbonate, citric acid monohydrate and a binder which bonds all components Together form a solid block.
  • the bath composition having the above four components forms a solid block, for example, by compressing to form a solid block, which substantially realizes the "clam effect" of the present invention, and the generated carbon dioxide gas forms bubbles, which contributes to the polypropylene.
  • the amide absorbs moisture and forms a slippery gelatinous mass, which increases the viscosity of the water and provides a sticky feeling to the body.
  • the slip-slip cartridge comprises a bath composition comprising, by weight percent, 30-40% polyacrylamide, 25-30% sodium bicarbonate, 20-30% citric acid monohydrate, and 15-25% binder, which binds all components together to form a solid block.
  • the composition and ratio of the composition in the slip-slip bath are appropriate, and carbon dioxide bubbles (C02 bubbles) are generated to the utmost, and the gas is released from the gas due to the solid block shape.
  • C02 bubbles carbon dioxide bubbles
  • a special "sputum effect" is produced, and not only the amount of bubbles is increased, but also the viscosity of the formed gel-like mass is remarkably improved.
  • the stick-slip cartridge is formed into a solid block shape, which is critical for achieving the object of the present invention, and therefore it is necessary to bond all the components together using an adhesive.
  • adhesives There are many options for such adhesives. From a safety point of view, the adhesive should be harmless to the human body.
  • Such adhesives can be selected from sugar, glucose, lactose, sucrose and corn. a mixture of corn starch, or lactose monohydrate (lactose)
  • a mixture of monohydrate), povidone, crospovidone and corn starch in any combination and ratio may not be strictly limited.
  • the viscous bathing cartridge of the present invention does not generate a bubble by a general "foaming action", but the "clam effect” is due to the bubble
  • the stick-slip bathing bomb exists in the form of a solid block, which is very important for the realization of the effect of the present invention.
  • the reaction releases gas, which helps the polyacrylamide absorb moisture and form a sticky, slip-like agglomerate. This converts the viscosity of the bath water (specifically, increases the viscosity), giving the body a sticky feeling.
  • the larger the solid block-shaped viscous bathing bomb the larger the volume of water can be converted into higher viscosity bath water. It is calculated that a solid block-shaped sticky-sliding bomb in the range of 0.01 g to 0.005 g can convert 1 liter of water into slippery bath water.
  • a solid block-shaped sticky-sliding bomb in the range of 0.01 g to 0.005 g can convert 1 liter of water into slippery bath water.
  • the control bath composition has a polyacrylamide content of 30-40%, sodium bicarbonate at 25-30%, citric acid monohydrate at 20-30%, and a binder at 15-25%. It is important to further efficiently generate bubbles and obtain a sticky feeling. According to this ratio, the ratio of sodium hydrogencarbonate and citric acid monohydrate used for the reaction is appropriate, a large amount of bubbles can be generated, and the momentum of the bubbles is large, thereby efficiently assisting the polyacrylamide to absorb moisture. If the ratio of sodium bicarbonate to citric acid monohydrate is high, although the amount of bubbles is large, the proportion of polyacrylamide is correspondingly reduced, which results in the formation of a slippery gelatinous mass that is small and has insufficient slip.
  • the proportion of polyacrylamide is too high, the ratio of the corresponding sodium bicarbonate to citric acid monohydrate will be low, resulting in insufficient and long-lasting reaction, which will not help the absorption of water by polyacrylamide, and will also cause the formation of slippery
  • the proportion of the mixture is also important.
  • the excessive proportion of the binder causes the other components to decrease, which has an adverse effect.
  • the adhesion of the solid block may be too large, which may affect the reaction progress and the release of the gas. , which in turn affects the slipperiness; too little of the adhesive may cause insufficient adhesion, and the reaction is too fast, which causes the solid block to disintegrate rapidly and also affects the slip.
  • the percentage of polyacrylamide may be 31-38%, 32-37%, 33-36%, or 34-35%, such as 31.5%, based on the total weight of the composition. 33.5%, 35%, 35.5%, 37%, 38% or 39%.
  • the percentage of sodium bicarbonate may be 25.5-29.5 %, 26-29%, 26.5-28.5%, 26-28%, 26.5-27.5%, based on the total weight of the composition. Or 26-27%, such as 25.8%, 26.2%, 27.1%, 28.4% or 29.3 ⁇ 3 ⁇ 4.
  • the percentage of citric acid monohydrate may be 21-29%, 22-28%, 23-27% or 24-26%, such as 21.5, based on the total weight of the composition. %, 23.5%, 25.5%, 27.5% or 29.5%»
  • the percentage of binder may be 16-24%, 17-23%, 18-22%, or 19-21%, such as 16.5 ⁇ 3 ⁇ 4, based on the total weight of the composition. , 18.5%, 20.5%, 22.5% or 24.5 ⁇ 3 ⁇ 4.
  • At least one preservative may be added in order to extend the shelf life of the product.
  • the preservative is present in an amount of from 0.1% to 0.5% by weight based on the total weight of the bath composition, for example 0.1 ⁇ 3 ⁇ 4, 0.2%, 0.3%, 0.4% or 0.5 ⁇ 3 ⁇ 4.
  • the total percentage of each component is 100%.
  • Preservatives should be harmless or less harmful to humans.
  • Such preservatives may be selected from diazolidinium imidazolium (Germall).
  • Methyl Paraben Methyl Paraben, Propyl paraben or a combination thereof.
  • At least one colorant may be included for better visual perception.
  • the colorant is present in an amount of from 0.2% to 0.5% by weight, such as 0.2%, 0.3%, 0.4% or 0.5% by weight based on the total weight of the bath composition.
  • the total percentage of each component is 100%.
  • a colorant of any color can be used in the present invention, and correspondingly, the viscous bathing cartridge has a plurality of colors including, but not limited to, green, light blue or pink.
  • the bath composition may further comprise at least one flash Light material (glitter material).
  • the flashing material is present in an amount of from 0.5 to 2% by weight based on the total weight of the bath composition, such as 0.5%, 0.7%, 0.9%, 1.2%, 1.5%, 1.7% or 1.9%.
  • the total percentage of each component is 100%.
  • Any glittering material can be used in the present invention, and the glittering material can impart a dazzling visual characteristic to the product of the present invention.
  • the bath composition may further comprise at least one glow pigment.
  • the glow pigment is present in an amount of from 1% to 8% by weight based on the total weight of the bath composition, for example 1%, 2%, 3%, 4%, 5%, 6% or 7 ⁇ 3 ⁇ 4. In the case of containing a glow pigment, the total percentage of each component is 100%. Any of the glow pigments can be used in the present invention, and the glow pigment can impart a luminescent characteristic to the product of the present invention.
  • the bath composition may further comprise at least one color change pigment.
  • the color-changing pigment is present in an amount of from 3 to 8% by weight based on the total weight of the bath composition, for example 3%, 4%, 5%, 6% or 7%.
  • the total percentage of each component is 100%.
  • Any color change pigment can be used in the present invention, and it is preferred that the color varies with temperature, for example, the color changes as the temperature of the bath water is lowered, so that the color change and the cockroach can be used to remind the bather that especially the child's water temperature has been lowered, and the need to end Bathing.
  • the preservative, the colorant, the glittering material, the glow pigment, and the color-changing pigment may be arbitrarily added as needed, and the combination thereof is not particularly limited.
  • the viscous bath sponge of the present invention is realized by four basic components of polyacrylamide, sodium hydrogencarbonate, citric acid monohydrate and a binder, and the other components impart their unique characteristics.
  • the viscous bathing cartridge of the present invention may have any or a variety of shapes, such as a wheel sphere, a cube, a sphere or an ellipsoid, and the like.
  • the viscous bathing cartridge of the present invention can have any pleasant scent and increase bathing fun.
  • the stick-slip cartridge may also include an outer casing or package for packaging.
  • an outer casing or package for packaging As shown in Fig. 1, the structure of a viscous slack bomb of one embodiment is shown, comprising a casing 1 and a solid block-like bath composition 2, and a solid block-like bath composition 2 is placed in the casing 1, as a solid block.
  • the bathing composition 2 is taken out from the outer casing 1 and placed in the water, and the solid block-shaped bathing composition 2 (ie, the body of the bathing bomb) converts the water into a foaming and sticking material by "squeezing action", the child can Playing in it
  • the solid block-shaped bathing composition 2 ie, the body of the bathing bomb

Abstract

Disclosed is a slimy bath bomb, comprising a bath composition. The bath composition comprises a polyacrylamide, a sodium bicarbonate, a citric acid monohydrate, and an adhesive. The adhesive adheres and holds every part of the composition together to form a solid block. When in contact with water, slimy bath bomb can, through a special fizzing action, help the polyacrylamide absorb water to form a slimy gel-like mass, thereby improving the enjoyment of bathing.

Description

说明书 发明名称:一种黏滑洗浴弹  Instruction manual Name of the invention: a sticky sliding bath
技术领域  Technical field
[0001] 本发明涉及洗浴用的组合物技术领域, 尤其涉及一种通过起泡作用 (fizzing action) 产生气泡和黏滑效果的黏滑洗浴弹 (slimy bath bomb) 。  [0001] The present invention relates to the technical field of compositions for bathing, and more particularly to a slimy bath bomb which generates bubbles and a viscous effect by a fizzing action.
[0002]  [0002]
[0003] 背景技术  BACKGROUND
[0004] 日常洗浴过程通常用到各种洗浴组合物。 不同的洗浴组合物能够提供不同的功 能并且给人不同的感受。 洗浴组合物可能含有一种或多种功能性成分, 例如天 然盐、 自然海盐、 矿物质和精油等成分, 甚至一些微量元素, 如铁、 钙、 硒、 镁, 以及人所需要的其它元素。 长期使用这些组合物可改善人体的健康, 例如 消除皮肤黑色素, 使皮肤逐渐恢复细白、 嫩滑、 富有弹性, 祛除面部痤疮或色 斑。  [0004] Various bath compositions are commonly used in the daily bathing process. Different bath compositions can provide different functions and give different feelings. The bath composition may contain one or more functional ingredients such as natural salt, natural sea salt, minerals and essential oils, and even trace elements such as iron, calcium, selenium, magnesium, and other elements that are desirable to humans. Long-term use of these compositions can improve the health of the body, such as eliminating melanin in the skin, gradually reducing the skin's whitening, smoothness, elasticity, and eliminating facial acne or pigmentation.
[0005] 欧洲专利 EP1791514B1公幵了一种用于剥离皮肤角质并软化皮肤的洗浴用组合 物, 含有聚丙烯酸钠粉末作为活性成分或试剂, 其分散于油基溶液中。 该组合 物特别适用于化妆品、 水疗和美容产品。 在使用吋, 将该组合物施加到皮肤上 以产生去角质和软化效果。 然后用水冲洗皮肤, 聚丙烯酸钠粉末溶胀并变成软 凝胶, 使得油基释放进入皮肤, 取得软化和滋润皮肤的效果。 油基和其它添加 剂能够软化甚至滋润粗糙类型的皮肤, 并对皮肤产生柔软剥落感觉。 因此, 根 据 EP1791514B1的组合物能够在依次处理中实现对皮肤的剥落和软化作用。  [0005] European Patent No. 1,917,514 B1 discloses a bath composition for peeling off skin keratin and softening the skin, comprising sodium polyacrylate powder as an active ingredient or a reagent dispersed in an oil-based solution. The composition is particularly suitable for use in cosmetics, spa and beauty products. The composition is applied to the skin to produce exfoliation and softening effects using hydrazine. The skin is then rinsed with water, and the sodium polyacrylate powder swells and turns into a soft gel, allowing the oil base to be released into the skin to soften and moisturize the skin. Oil-based and other additives soften and even moisturize rough-type skin and give the skin a soft peeling sensation. Therefore, the composition according to EP1791514B1 is capable of achieving peeling and softening of the skin in a sequential treatment.
[0006] 然而, 目前仍然缺乏能够产生大量气泡和黏滑感的洗浴组合物, 以提高洗浴乐 趣, 尤其是提高婴儿或儿童的洗浴乐趣。 [0006] However, there is still a lack of a bath composition capable of generating a large amount of air bubbles and a sticky feeling to enhance the pleasure of bathing, especially to improve the bathing fun of infants or children.
[0007]  [0007]
[0008] 发明内容  SUMMARY OF THE INVENTION
[0009] 本发明提供一种黏滑洗浴弹, 包括洗浴组合物, 该洗浴组合物包括聚丙烯酰胺  The present invention provides a viscous bathing cartridge comprising a bath composition comprising polyacrylamide
(polyacrylamide) , 碳酉爱氢钠 (sodium hydrogen carbonate) , 梓檬酉爱一 7_ 合物 (citric acid monohydrate) , 以及粘合剂 (binder) , 该粘合剂将所有组分粘合 在一起形成固体块。 (polyacrylamide), sodium hydrogen carbonate, citric acid monohydrate, and binder, which bonds all components Together form a solid block.
[0010] 本发明的黏滑洗浴弹包括聚丙烯酰胺、 碳酸氢钠、 柠檬酸一水合物和粘合剂, 并且形成固体块。 因此, 本发明的黏滑洗浴弹与水接触吋, 能够通过一种特别 的起泡作用一 "嘶嘶作用" (fizzing action) 帮助聚丙烯酰胺吸收水分, 形成黏 滑的胶状团块 (gel-like mass) , 提高了洗浴乐趣。  [0010] The slip-slip bath of the present invention comprises polyacrylamide, sodium bicarbonate, citric acid monohydrate and a binder, and forms a solid block. Therefore, the viscous bathing bomb of the present invention is in contact with water, and can assist the polyacrylamide to absorb moisture through a special foaming action, and form a viscous gelatinous mass (gel -like mass), which improves the fun of bathing.
[0011]  [0011]
[0012] 附图说明  BRIEF DESCRIPTION OF THE DRAWINGS
[0013] 图 1为本发明一个实施方案的黏滑洗浴弹的结构示意图。  1 is a schematic structural view of a slip-slip bathing cartridge according to an embodiment of the present invention.
[0014] 其中: 1-外壳; 2-固体块状的洗浴组合物。  [0014] wherein: 1-shell; 2-solid block-shaped bath composition.
[0015]  [0015]
[0016] 具体实施方式  DETAILED DESCRIPTION
[0017] 下面通过具体实施方式结合附图对本发明作进一步详细说明。  [0017] The present invention will be further described in detail below with reference to the accompanying drawings.
[0018] 本发明提供的黏滑洗浴弹, 包括洗浴组合物, 该洗浴组合物包括聚丙烯酰胺、 碳酸氢钠、 柠檬酸一水合物以及粘合剂, 该粘合剂将所有组分粘合在一起形成 固体块。  [0018] The present invention provides a viscous bathing cartridge comprising a bath composition comprising polyacrylamide, sodium bicarbonate, citric acid monohydrate and a binder which bonds all components Together form a solid block.
[0019] 具有上述四种成分的洗浴组合物, 形成固体块, 例如通过压缩形成固体块, 就 能基本上实现本发明的"嘶嘶作用", 产生的二氧化碳气体形成气泡, 有助于聚丙 烯酰胺吸收水分, 形成黏滑的胶状团块, 增加水的粘度, 给人体全身提供黏滑 感。  [0019] The bath composition having the above four components forms a solid block, for example, by compressing to form a solid block, which substantially realizes the "clam effect" of the present invention, and the generated carbon dioxide gas forms bubbles, which contributes to the polypropylene. The amide absorbs moisture and forms a slippery gelatinous mass, which increases the viscosity of the water and provides a sticky feeling to the body.
[0020] 依据本发明的一个优选的实施方案, 黏滑洗浴弹包括洗浴组合物, 该洗浴组合 物按重量百分数计, 包括 30-40%的聚丙烯酰胺, 25-30%的碳酸氢钠, 20-30%的 柠檬酸一水合物, 以及 15-25%的粘合剂, 该粘合剂将所有组分粘合在一起形成 固体块。  [0020] According to a preferred embodiment of the present invention, the slip-slip cartridge comprises a bath composition comprising, by weight percent, 30-40% polyacrylamide, 25-30% sodium bicarbonate, 20-30% citric acid monohydrate, and 15-25% binder, which binds all components together to form a solid block.
[0021] 在上述优选的实施方案中, 黏滑洗浴弹中组合物的原料和配比恰当, 能够最大 限度的产生二氧化碳气泡 (C02 bubbles) , 并且由于呈固体块状, 气体从中释 放出来的吋候产生特别的"嘶嘶作用", 不但气泡量增大, 而且所形成的胶状团块 的黏滑度明显提高。  [0021] In the above preferred embodiment, the composition and ratio of the composition in the slip-slip bath are appropriate, and carbon dioxide bubbles (C02 bubbles) are generated to the utmost, and the gas is released from the gas due to the solid block shape. A special "sputum effect" is produced, and not only the amount of bubbles is increased, but also the viscosity of the formed gel-like mass is remarkably improved.
[0022] 本发明的黏滑洗浴弹中, 碳酸氢钠和柠檬酸一水合物在不使用吋处于不反应的 稳定状态, 当与水接触吋发生中和反应产生大量二氧化碳, 帮助聚丙烯酰胺吸 收水分, 形成黏滑的胶状团块, 增加了洗浴乐趣。 [0022] In the viscous bathing cartridge of the present invention, sodium hydrogencarbonate and citric acid monohydrate are inactive without being used. Stable state, when it comes into contact with water, the neutralization reaction produces a large amount of carbon dioxide, which helps the polyacrylamide absorb moisture and form a sticky, slippery clump, which increases the fun of bathing.
[0023] 本发明中, 黏滑洗浴弹形成固体块状, 对于实现本发明的目的很关键, 因此需 要使用粘合剂将所有组分粘合在一起。 这样的粘合剂有多种选择, 从安全的角 度考虑, 粘合剂应当对人体无害, 这样的粘合剂可以选择蔗糖 (sugar) , 葡萄 糖 (glucose) , 乳糖 (lactose) , 蔗糖和玉米淀粉 (corn starch) 的混合物, 或 者乳糖一水合物 (lactose  [0023] In the present invention, the stick-slip cartridge is formed into a solid block shape, which is critical for achieving the object of the present invention, and therefore it is necessary to bond all the components together using an adhesive. There are many options for such adhesives. From a safety point of view, the adhesive should be harmless to the human body. Such adhesives can be selected from sugar, glucose, lactose, sucrose and corn. a mixture of corn starch, or lactose monohydrate (lactose)
monohydrate) 、 聚维酮 (povidone) 、 交聚维酮 (crospovidone) 和玉米淀粉以 任意组合和比例混合形成的混合物。 其中, 蔗糖和玉米淀粉的混合物中组分的 比例可以没有严格限定。  A mixture of monohydrate), povidone, crospovidone and corn starch in any combination and ratio. Among them, the ratio of the components in the mixture of sucrose and corn starch may not be strictly limited.
[0024] 需要特别强调的是, 本发明的黏滑洗浴弹不是通过一般的起泡作用, 而是通过 一种特别的"嘶嘶作用"产生气泡, 这种"嘶嘶作用"是由于气泡从固体块的表面和 内部释放出来产生的。 因此, 黏滑洗浴弹以固体块形式存在, 对于本发明效果 的实现很重要, 当与水接触吋, 由于反应释放气体, 有助于聚丙烯酰胺吸收水 分, 形成黏滑的胶状团块, 从而转化了洗浴水的粘度 (具体是增加粘度) , 给 人体全身提供一种黏滑的感觉。 一般而言, 固体块状的黏滑洗浴弹体积越大越 能将大体积的水转化成粘度较高的洗浴水。 经计算, 在 0.01克至 0.005克范围内 的固体块状的黏滑洗浴弹可以将 1升水转化成黏滑的洗浴水。 粉末状的组合物与 水接触吋, 不具有本发明特有的"嘶嘶作用", 难以取得本发明的效果。 [0024] It is particularly emphasized that the viscous bathing cartridge of the present invention does not generate a bubble by a general "foaming action", but the "clam effect" is due to the bubble The surface and interior of the solid block are released. Therefore, the stick-slip bathing bomb exists in the form of a solid block, which is very important for the realization of the effect of the present invention. When it is in contact with water, the reaction releases gas, which helps the polyacrylamide absorb moisture and form a sticky, slip-like agglomerate. This converts the viscosity of the bath water (specifically, increases the viscosity), giving the body a sticky feeling. In general, the larger the solid block-shaped viscous bathing bomb, the larger the volume of water can be converted into higher viscosity bath water. It is calculated that a solid block-shaped sticky-sliding bomb in the range of 0.01 g to 0.005 g can convert 1 liter of water into slippery bath water. When the powdery composition is in contact with water, it does not have the "sputum effect" peculiar to the present invention, and it is difficult to obtain the effects of the present invention.
[0025] 本发明中, 控制洗浴组合物中聚丙烯酰胺在 30-40%、 碳酸氢钠在 25-30%、 柠 檬酸一水合物在 20-30%以及粘合剂在 15-25%, 对于进一步高效地产生气泡并获 得黏滑感比较重要。 按照这种比例, 用于发生反应的碳酸氢钠和柠檬酸一水合 物的比例适当, 能够大量产生气泡, 并且气泡的冲力较大, 从而高效地帮助聚 丙烯酰胺吸收水分。 如果碳酸氢钠和柠檬酸一水合物的比例偏高, 虽然气泡量 较大, 但是聚丙烯酰胺的占比相应降低, 会导致形成的黏滑的胶状团块偏小、 黏滑度不够, 并且可能容易解体。 如果聚丙烯酰胺的比例偏高, 相应的碳酸氢 钠和柠檬酸一水合物的比例会偏低, 导致反应不够剧烈、 持久, 对聚丙烯酰胺 吸收水分的帮助不足, 也会造成形成的黏滑的胶状团块黏滑度不够的问题。 粘 合剂的比例也比较重要, 过多比例的粘合剂, 一方面造成其它成分减少, 带来 不利影响, 另一方面可能会使得固体块的粘合力过大, 而影响反应进行和气体 的释放, 进而影响黏滑度; 过少比例的粘合剂, 可能造成的粘合力不够, 反应 过快, 导致固体块迅速解体, 也会影响黏滑度。 [0025] In the present invention, the control bath composition has a polyacrylamide content of 30-40%, sodium bicarbonate at 25-30%, citric acid monohydrate at 20-30%, and a binder at 15-25%. It is important to further efficiently generate bubbles and obtain a sticky feeling. According to this ratio, the ratio of sodium hydrogencarbonate and citric acid monohydrate used for the reaction is appropriate, a large amount of bubbles can be generated, and the momentum of the bubbles is large, thereby efficiently assisting the polyacrylamide to absorb moisture. If the ratio of sodium bicarbonate to citric acid monohydrate is high, although the amount of bubbles is large, the proportion of polyacrylamide is correspondingly reduced, which results in the formation of a slippery gelatinous mass that is small and has insufficient slip. And it may be easy to disintegrate. If the proportion of polyacrylamide is too high, the ratio of the corresponding sodium bicarbonate to citric acid monohydrate will be low, resulting in insufficient and long-lasting reaction, which will not help the absorption of water by polyacrylamide, and will also cause the formation of slippery The problem of insufficient adhesion of the gelatinous mass. Sticky The proportion of the mixture is also important. The excessive proportion of the binder causes the other components to decrease, which has an adverse effect. On the other hand, the adhesion of the solid block may be too large, which may affect the reaction progress and the release of the gas. , which in turn affects the slipperiness; too little of the adhesive may cause insufficient adhesion, and the reaction is too fast, which causes the solid block to disintegrate rapidly and also affects the slip.
[0026] 在一些实施例中, 聚丙烯酰胺的百分含量按组合物的总重量计, 可以是 31-38% , 32-37% , 33-36%或 34-35%, 例如 31.5%, 33.5% , 35% , 35.5% , 37% , 38%或 39%。  [0026] In some embodiments, the percentage of polyacrylamide may be 31-38%, 32-37%, 33-36%, or 34-35%, such as 31.5%, based on the total weight of the composition. 33.5%, 35%, 35.5%, 37%, 38% or 39%.
[0027] 在一些实施例中, 碳酸氢钠的百分含量按组合物的总重量计, 可以是 25.5-29.5 % , 26-29% , 26.5-28.5% , 26-28% , 26.5-27.5%或 26-27%, 例如 25.8%, 26.2% , 27.1% , 28.4%或 29.3<¾。  [0027] In some embodiments, the percentage of sodium bicarbonate may be 25.5-29.5 %, 26-29%, 26.5-28.5%, 26-28%, 26.5-27.5%, based on the total weight of the composition. Or 26-27%, such as 25.8%, 26.2%, 27.1%, 28.4% or 29.3<3⁄4.
[0028] 在一些实施例中, 柠檬酸一水合物的百分含量按组合物的总重量计, 可以是 21 -29% , 22-28% , 23-27%或 24-26%, 例如 21.5%, 23.5% , 25.5% , 27.5%或 29.5%»  [0028] In some embodiments, the percentage of citric acid monohydrate may be 21-29%, 22-28%, 23-27% or 24-26%, such as 21.5, based on the total weight of the composition. %, 23.5%, 25.5%, 27.5% or 29.5%»
[0029] 在一些实施例中, 粘合剂的百分含量按组合物的总重量计, 可以是 16-24%, 17 -23% , 18-22%或 19-21%, 例如 16.5<¾, 18.5% , 20.5% , 22.5%或 24.5<¾。 [0029] In some embodiments, the percentage of binder may be 16-24%, 17-23%, 18-22%, or 19-21%, such as 16.5<3⁄4, based on the total weight of the composition. , 18.5%, 20.5%, 22.5% or 24.5<3⁄4.
[0030] 在本发明的一个优选的实施方案中, 为了延长产品的保质期, 可以添加至少一 种防腐剂 (preservative) 。 优选地, 防腐剂的含量按重量百分数计, 可以占洗浴 组合物总重量的 0.1-0.5%, 例如 0.1<¾, 0.2% , 0.3% , 0.4%或 0.5<¾。 在含有隱 剂的情况下, 各种组分的总百分含量是 100%。 防腐剂应该对人体无害或者危害 较小, 这样的防腐剂可以选自重氮烷基咪唑脲 (Germall  [0030] In a preferred embodiment of the invention, at least one preservative may be added in order to extend the shelf life of the product. Preferably, the preservative is present in an amount of from 0.1% to 0.5% by weight based on the total weight of the bath composition, for example 0.1 < 3⁄4, 0.2%, 0.3%, 0.4% or 0.5 < 3⁄4. In the case of a cryptic agent, the total percentage of each component is 100%. Preservatives should be harmless or less harmful to humans. Such preservatives may be selected from diazolidinium imidazolium (Germall).
II) 、 尼泊金甲酯 (Methyl Paraben) 、 尼泊金丙酯 (Propyl paraben) 或它们的 组合。  II), Methyl Paraben, Propyl paraben or a combination thereof.
[0031] 在本发明的另一个优选的实施方案中, 为了更好的视觉感受, 可以包含至少一 种着色剂 (colomnt) 。 优选地, 着色剂的含量按重量百分数计, 可以占洗浴组 合物总重量的 0.2-0.5%, 例如 0.2%, 0.3% , 0.4%或 0.5%。 在含有着色剂的情况 下, 各种组分的总百分含量是 100%。 任何颜色的着色剂均可用于本发明中, 相 应地, 黏滑洗浴弹具有多种颜色, 包括并不限于绿色、 浅蓝色或粉红色。  [0031] In another preferred embodiment of the invention, at least one colorant may be included for better visual perception. Preferably, the colorant is present in an amount of from 0.2% to 0.5% by weight, such as 0.2%, 0.3%, 0.4% or 0.5% by weight based on the total weight of the bath composition. In the case of a coloring agent, the total percentage of each component is 100%. A colorant of any color can be used in the present invention, and correspondingly, the viscous bathing cartridge has a plurality of colors including, but not limited to, green, light blue or pink.
[0032] 在本发明的另一个优选的实施方案中, 洗浴组合物可以进一步包括至少一种闪 光材料 (glitter material) 。 优选地, 闪光材料的含量按重量百分数计, 可以占洗 浴组合物总重量的 0.5-2%, 例如 0.5%, 0.7% , 0.9% , 1.2% , 1.5% , 1.7%或 1.9%[0032] In another preferred embodiment of the invention, the bath composition may further comprise at least one flash Light material (glitter material). Preferably, the flashing material is present in an amount of from 0.5 to 2% by weight based on the total weight of the bath composition, such as 0.5%, 0.7%, 0.9%, 1.2%, 1.5%, 1.7% or 1.9%.
。 在含有闪光材料的情况下, 各种组分的总百分含量是 100%。 任何闪光材料均 可用于本发明中, 闪光材料能够赋予本发明的产品一种耀眼的视觉特征。 . In the case of a glittering material, the total percentage of each component is 100%. Any glittering material can be used in the present invention, and the glittering material can impart a dazzling visual characteristic to the product of the present invention.
[0033] 在本发明的另一个优选的实施方案中, 洗浴组合物可以进一步包括至少一种辉 光颜料 (glow pigment) 。 优选地, 辉光颜料的含量按重量百分数计, 可以占洗 浴组合物总重量的 1-8%, 例如 1%, 2% , 3% , 4% , 5% , 6%或 7<¾。 在含有辉光 颜料的情况下, 各种组分的总百分含量是 100%。 任何辉光颜料均可用于本发明 中, 辉光颜料能够赋予本发明的产品一种发光特征。  In another preferred embodiment of the invention, the bath composition may further comprise at least one glow pigment. Preferably, the glow pigment is present in an amount of from 1% to 8% by weight based on the total weight of the bath composition, for example 1%, 2%, 3%, 4%, 5%, 6% or 7<3⁄4. In the case of containing a glow pigment, the total percentage of each component is 100%. Any of the glow pigments can be used in the present invention, and the glow pigment can impart a luminescent characteristic to the product of the present invention.
[0034] 在本发明的另一个优选的实施方案中, 洗浴组合物可以进一步包括至少一种颜 色变化颜料 (color change pigment) 。 优选地, 颜色变化颜料的含量按重量百分 数计, 可以占洗浴组合物总重量的 3-8%, 例如 3%, 4% , 5% , 6%或 7%。 在含有 颜色变化颜料的情况下, 各种组分的总百分含量是 100%。 任何颜色变化颜料均 可用于本发明中, 优选颜色随温度变化的颜料, 比如随着洗浴用水温度降低颜 色发生变化, 这样能够通过颜色变化及吋提醒洗浴者尤其儿童水温已经降低, 需要及吋结束洗浴。  [0034] In another preferred embodiment of the invention, the bath composition may further comprise at least one color change pigment. Preferably, the color-changing pigment is present in an amount of from 3 to 8% by weight based on the total weight of the bath composition, for example 3%, 4%, 5%, 6% or 7%. In the case of a color-changing pigment, the total percentage of each component is 100%. Any color change pigment can be used in the present invention, and it is preferred that the color varies with temperature, for example, the color changes as the temperature of the bath water is lowered, so that the color change and the cockroach can be used to remind the bather that especially the child's water temperature has been lowered, and the need to end Bathing.
[0035] 需要说明的是, 防腐剂、 着色剂、 闪光材料、 辉光颜料和颜色变化颜料, 可以 根据需要任意添加其中一种或多种, 其组合并没有特别限制。 本发明的黏滑洗 浴弹是依赖于聚丙烯酰胺、 碳酸氢钠、 柠檬酸一水合物以及粘合剂这四种基本 组分实现的, 其它组分赋予它各自独特的特性。  [0035] It is to be noted that the preservative, the colorant, the glittering material, the glow pigment, and the color-changing pigment may be arbitrarily added as needed, and the combination thereof is not particularly limited. The viscous bath sponge of the present invention is realized by four basic components of polyacrylamide, sodium hydrogencarbonate, citric acid monohydrate and a binder, and the other components impart their unique characteristics.
[0036] 本发明的黏滑洗浴弹可以具有任何或多种形状, 比如轮球体、 立方体、 球体或 椭圆体等。 本发明的黏滑洗浴弹可以具有任何悦人的气味, 增加洗浴乐趣。  [0036] The viscous bathing cartridge of the present invention may have any or a variety of shapes, such as a wheel sphere, a cube, a sphere or an ellipsoid, and the like. The viscous bathing cartridge of the present invention can have any pleasant scent and increase bathing fun.
[0037] 在本发明的另一个优选的实施方案中, 黏滑洗浴弹还可以包括一个用于包装的 外壳或包装袋。 如图 1所示, 示出了一个实施方案的黏滑洗浴弹的结构, 包括外 壳 1和固体块状的洗浴组合物 2, 固体块状的洗浴组合物 2置于外壳 1中, 当固体 块状的洗浴组合物 2从外壳 1中取出并放入水中吋, 固体块状的洗浴组合物 2 (即 洗浴弹本体) 通过"嘶嘶作用"将水转化成起泡的黏滑材料, 儿童可以在其中玩耍 以上内容是结合具体的实施方式对本发明所作的进一步详细说明, 不能认定本 发明的具体实施只局限于这些说明。 对于本发明所属技术领域的普通技术人员 来说, 在不脱离本发明构思的前提下, 还可以做出若干简单推演或替换, 都应 当视为属于本发明的保护范围。 [0037] In another preferred embodiment of the invention, the stick-slip cartridge may also include an outer casing or package for packaging. As shown in Fig. 1, the structure of a viscous slack bomb of one embodiment is shown, comprising a casing 1 and a solid block-like bath composition 2, and a solid block-like bath composition 2 is placed in the casing 1, as a solid block. The bathing composition 2 is taken out from the outer casing 1 and placed in the water, and the solid block-shaped bathing composition 2 (ie, the body of the bathing bomb) converts the water into a foaming and sticking material by "squeezing action", the child can Playing in it The above is a further detailed description of the present invention in connection with the specific embodiments, and the specific implementation of the invention is not limited to the description. It will be apparent to those skilled in the art that the present invention may be made without departing from the spirit and scope of the invention.
技术问题 technical problem
问题的解决方案 Problem solution
发明的有益效果 Advantageous effects of the invention

Claims

权利要求书 Claim
一种黏滑洗浴弹, 其特征在于, 包括洗浴组合物, 所述洗浴组合物包 括聚丙烯酰胺, 碳酸氢钠, 柠檬酸一水合物, 以及粘合剂, 所述粘合 剂将所有组分粘合在一起形成固体块。 A viscous bathing cartridge characterized by comprising a bath composition comprising polyacrylamide, sodium hydrogencarbonate, citric acid monohydrate, and a binder, the binder comprising all components Bonded together to form a solid block.
根据权利要求 1所述的黏滑洗浴弹, 其特征在于, 所述洗浴组合物按 重量百分数计, 包括 30-40%的聚丙烯酰胺, 25-30%的碳酸氢钠, 20- 30%的柠檬酸一水合物, 以及 15-25%的粘合剂。 The viscous bathing cartridge according to claim 1, wherein the bathing composition comprises, by weight percent, 30-40% polyacrylamide, 25-30% sodium hydrogencarbonate, 20-30% Citric acid monohydrate, and 15-25% binder.
根据权利要求 1所述的黏滑洗浴弹, 其特征在于, 所述粘合剂选自蔗 糖, 葡萄糖, 乳糖, 蔗糖和玉米淀粉的混合物, 或者乳糖一水合物、 聚维酮、 交聚维酮和玉米淀粉以任意组合和比例混合形成的混合物。 根据权利要求 2或 3所述的黏滑洗浴弹, 其特征在于, 所述洗浴组合物 按重量百分数计还包括 0.1-0.5%的至少一种防腐剂, 并且所有组分的 百分比总和为 100%。 The viscous bathing cartridge according to claim 1, wherein the binder is selected from the group consisting of sucrose, glucose, lactose, a mixture of sucrose and corn starch, or lactose monohydrate, povidone, crospovidone And a mixture of corn starch mixed in any combination and ratio. The viscous bathing cartridge according to claim 2 or 3, wherein the bathing composition further comprises 0.1-0.5% by weight of at least one preservative, and the total percentage of all components is 100%. .
根据权利要求 4所述的黏滑洗浴弹, 其特征在于, 所述防腐剂选自重 氮烷基咪唑脲、 尼泊金甲酯、 尼泊金丙酯或它们的组合。 The viscous bathing cartridge according to claim 4, wherein the preservative is selected from the group consisting of diazolidinium imidazole, methyl paraben, propyl paraben or a combination thereof.
根据权利要求 2或 3所述的黏滑洗浴弹, 其特征在于, 所述洗浴组合物 按重量百分数计还包括 0.2-0.5%的至少一种着色剂, 并且所有组分的 百分比总和为 100%。 The viscous bathing cartridge according to claim 2 or 3, wherein the bathing composition further comprises 0.2-0.5% by weight of at least one coloring agent, and the total percentage of all components is 100%. .
根据权利要求 6所述的黏滑洗浴弹, 其特征在于, 所述着色剂是任意 颜色的着色剂, 相应地, 所述黏滑洗浴弹具有多种颜色。 The viscous bathing cartridge according to claim 6, wherein the coloring agent is a coloring agent of any color, and accordingly, the viscous bathing cartridge has a plurality of colors.
根据权利要求 2或 3所述的黏滑洗浴弹, 其特征在于, 所述洗浴组合物 按重量百分数计还包括 0.5-2%的至少一种闪光材料, 并且所有组分的 百分比总和为 100%。 The viscous bathing cartridge according to claim 2 or 3, wherein the bathing composition further comprises 0.5-2% by weight of at least one glittering material, and the total percentage of all components is 100%. .
根据权利要求 2或 3所述的黏滑洗浴弹, 其特征在于, 所述洗浴组合物 按重量百分数计还包括 1-8%的至少一种辉光颜料, 并且所有组分的 百分比总和为 100%。 The viscous bathing cartridge according to claim 2 or 3, wherein the bathing composition further comprises 1-8% by weight of at least one glow pigment, and the total percentage of all components is 100. %.
根据权利要求 2或 3所述的黏滑洗浴弹, 其特征在于, 所述洗浴组合物 分的百分比总和为 100%。 The viscous bathing cartridge according to claim 2 or 3, wherein the bathing composition The sum of the points is 100%.
[权利要求 11] 根据权利要求 2或 3所述的黏滑洗浴弹, 其特征在于, 所述黏滑洗浴弹 具有多种形状。 [Claim 11] The viscous bathing cartridge according to claim 2 or 3, wherein the viscous bathing cartridge has a plurality of shapes.
[权利要求 12] 根据权利要求 2或 3所述的黏滑洗浴弹, 其特征在于, 所述黏滑洗浴弹 还包括一个用于包装的外壳或包装袋。  [Claim 12] The viscous bathing cartridge according to claim 2 or 3, wherein the viscous bathing cartridge further comprises an outer casing or a packaging bag for packaging.
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