WO2017114304A1 - Durable construction fiberboard - Google Patents

Durable construction fiberboard Download PDF

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Publication number
WO2017114304A1
WO2017114304A1 PCT/CN2016/111690 CN2016111690W WO2017114304A1 WO 2017114304 A1 WO2017114304 A1 WO 2017114304A1 CN 2016111690 W CN2016111690 W CN 2016111690W WO 2017114304 A1 WO2017114304 A1 WO 2017114304A1
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Prior art keywords
parts
fiber
fiberboard
construction
durable construction
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PCT/CN2016/111690
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French (fr)
Chinese (zh)
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王丽萍
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王丽萍
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Publication of WO2017114304A1 publication Critical patent/WO2017114304A1/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F289/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/04Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonamides, polyesteramides or polyimides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04Ingredients characterised by their shape and organic or inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/524Esters of phosphorous acids, e.g. of H3PO3
    • C08K5/526Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/10Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L13/00Compositions of rubbers containing carboxyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L13/00Compositions of rubbers containing carboxyl groups
    • C08L13/02Latex

Definitions

  • the present invention relates to a durable fiberboard for construction.
  • Fiberboard is well utilized in China, especially in the construction industry.
  • the construction enterprises in our city have experienced a long-term development process from small to large, from weak to strong. They have entered a new stage of development and become a pillar industry in the economic development of the city. Therefore, China has developed into the world's largest fiberboard production and consumption country, and has become the fastest growing fiberboard country in the world, gradually transforming from a large fiber importing country to a major exporting country.
  • As a good substitute for wood, fiberboard is now widely used in furniture, wood flooring, construction, decoration and other industries. Compared with other similar products, the quality and performance are better. In the context of shortage of forest resources, the market demand for fiberboard is rising. .
  • the problem to be solved by the present invention is to provide a durable fiberboard for construction, which has good antibacterial property, moisture resistance, good impact resistance, good durability, and improved life. Effectively reduce costs.
  • the technical solution of the present invention is a durable construction fiberboard made of the following raw materials by weight: 15-26 parts of wood fiber, 3-5 parts of carboxylated nitrile rubber , Inorganic aluminum salt anti- 7j agent 2-6 parts, softener 0.4-0.8 parts, aramid pulp fiber 15-22 parts, accelerator 0.2-0.4 parts, active monomer 12-16 parts, thickener 6-9 4-7 parts of auxiliary materials, 16-24 parts of fly ash, 51-2 parts of light silicon fiber cracking enhancer, 16-18 parts of aggregate, 1.5-2.6 parts of sodium fluorosilicate, bisphenol A
  • the ester is 2-4 parts, ethyl acrylate 15-2 0 parts, mannitol 1.2-2.3 parts, silane coupling agent 2-7 parts, and polytetrafluoroethylene fiber 3-9 parts.
  • a durable construction fiberboard made of the following parts by weight of raw materials: 21 parts of wood fiber, 4 parts of carboxylated nitrile rubber, 4 parts of inorganic aluminum salt water repellent, 0.6 parts of softener, 17 parts of aramid pulp fiber, 0.3 parts of accelerator, 14 parts of reactive monomer, 7.5 parts of thickener, 5.5 parts of auxiliary material, 20 parts of fly ash, 9 parts of light silicon fiber cracking enhancer, 17 parts of aggregate, 2 parts of sodium fluorosilicate, 3 parts of bisphenol A phosphite, 18 parts of ethyl acrylate, 1.9 parts of mannitol, 4.5 parts of silane coupling agent, and 6 parts of polytetrafluoroethylene fiber.
  • the invention has the beneficial effects that the durable construction fiberboard of the invention has good antibacterial property, moisture resistance, good impact resistance, good durability, improved life and effective cost reduction.
  • a durable construction fiberboard made of the following parts by weight of raw materials: 15 parts of wood fiber, 3 parts of carboxylated nitrile rubber, 2 parts of inorganic aluminum salt water repellent, 0.4 part of softener, aramid pulp 15 parts of rayon fiber, 0.2 parts of accelerator, 12 parts of active monomer, 6 parts of thickener, 4 parts of auxiliary materials, 16 parts of fly ash, 5 parts of light silicon fiber crack inhibitor, 16 parts of aggregate, fluorosilicic acid 1.5 parts of sodium, 2 parts of bisphenol A phosphite, 15 parts of ethyl acrylate, 1.2 parts of mannitol, 2 parts of silane coupling agent, and 3 parts of polytetrafluoroethylene fiber.
  • a durable construction fiberboard made of the following parts by weight of raw materials: 26 parts of wood fiber, 5 parts of carboxylated nitrile rubber, 6 parts of inorganic aluminum salt water repellent, 0.8 parts of softener, aramid pulp 22 parts of ray fiber, 0.4 parts of accelerator, 16 parts of active monomer, 9 parts of thickener, 7 parts of auxiliary materials, 24 parts of fly ash, 12 parts of light silicon fiber crack inhibitor, 18 parts of aggregate, fluorosilicic acid 2.6 parts of sodium, 4 parts of bisphenol A phosphite, 20 parts of ethyl acrylate, 2.3 parts of mannitol, 7 parts of silane coupling agent, and 9 parts of polytetrafluoroethylene fiber.
  • a durable construction fiberboard made of the following parts by weight of raw materials: 21 parts of wood fiber, 4 parts of carboxylated nitrile rubber, 4 parts of inorganic aluminum salt water repellent, 0.6 parts of softener, aramid pulp 17 parts of ray fiber, 0.3 parts of accelerator, 14 parts of active monomer, 7.5 parts of thickener, 5.5 parts of auxiliary material, 20 parts of fly ash, 9 parts of light silicon fiber crack inhibitor, 17 parts of aggregate, fluorosilicic acid 2 parts of sodium, 3 parts of bisphenol A phosphite, 18 parts of ethyl acrylate, 1.9 parts of mannitol, 4.5 parts of silane coupling agent, 6 parts of polytetrafluoroethylene fiber

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

A durable construction fiberboard, which is made from the following raw materials in terms of parts by weight: 15-26 parts of wood fiber, 3-5 parts of carboxyl nitrile rubber, 2-6 parts of an inorganic aluminum salt waterproofing agent, 0.4-0.8 parts of a softener, 15-22 parts of aramid pulp fiber, 0.2-0.4 parts of an accelerant, 12-16 parts of an active monomer, 6-9 parts of a thickener, 4-7 parts of an excipient, 16-24 parts of fly ash, 5-12 parts of a light silicon fiber crack resistance enhancer, 16-18 parts of a construction aggregate, 1.5-2.6 parts of sodium fluorosilicate, 2-4 parts of bisphenol A phosphite ester, 15-20 parts of ethyl acrylate, 1.2-2.3 parts of mannitol, 2-7 parts of a silane coupling agent, and 3-9 parts of polytetrafluoroethylene fiber. The beneficial effect of the present invention is such that the durable construction fiberboard of the present invention has great bacteria resistance, moisture resistance, impact resistance, weatherability, increased service life, and effectively reduced costs.

Description

说明书 发明名称:一种耐久的建筑用纤维板  Instruction manual Title: A durable construction fiberboard
技术领域  Technical field
[0001] 本发明涉及一种耐久的建筑用纤维板。  [0001] The present invention relates to a durable fiberboard for construction.
背景技术  Background technique
[0002] 纤维板在我国的到了很好的利用, 尤其在建筑业。 目前, 我市建筑企业从小到 大, 从弱到强, 经历了长期发展过程, 目前已进入了新的发展阶段, 成为我市 经济发展中的一个支柱产业。 所以我国已发展成为世界纤维板生产和消费第一 大国, 且已成为世界上纤维板增长最快的国家,从纤维板的进口大国逐步转变为 出口大国。 作为木材的良好替代品, 现如今纤维板广泛应用在家具、 木地板、 建筑、 装饰等行业, 相比其他同类产品品质、 性能更加优良, 在林木资源短缺 的背景下, 纤维板的市场需求量不断上升。 但随着建筑业的发展, 竞争的激烈 , 对建材的使用要求也在不断地提升, 在控制成本的基础上, 还要提高其性能 , 如今市场上需要一种抗冲击性好, 表面韧性好、 防水, 不易幵裂, 使用寿命 长, 且成本不高的建筑用纤维板。  [0002] Fiberboard is well utilized in China, especially in the construction industry. At present, the construction enterprises in our city have experienced a long-term development process from small to large, from weak to strong. They have entered a new stage of development and become a pillar industry in the economic development of the city. Therefore, China has developed into the world's largest fiberboard production and consumption country, and has become the fastest growing fiberboard country in the world, gradually transforming from a large fiber importing country to a major exporting country. As a good substitute for wood, fiberboard is now widely used in furniture, wood flooring, construction, decoration and other industries. Compared with other similar products, the quality and performance are better. In the context of shortage of forest resources, the market demand for fiberboard is rising. . However, with the development of the construction industry, the competition is fierce, and the requirements for the use of building materials are constantly improving. On the basis of cost control, the performance must be improved. Nowadays, the market needs a good impact resistance and good surface toughness. , Fiberboard for construction, waterproof, not easy to chapped, long service life, and low cost.
技术问题  technical problem
[0003] 针对现有技术的不足, 本发明要解决的问题是, 提供一种耐久的建筑用纤维板 , 具有很好的抗菌性、 防潮性, 抗冲击性好, 耐久性佳, 提高了寿命, 有效降 低了成本。  [0003] In view of the deficiencies of the prior art, the problem to be solved by the present invention is to provide a durable fiberboard for construction, which has good antibacterial property, moisture resistance, good impact resistance, good durability, and improved life. Effectively reduce costs.
问题的解决方案  Problem solution
技术解决方案  Technical solution
[0004] 为解决上述技术问题, 本发明的技术方案是, 一种耐久的建筑用纤维板, 其由 以下重量份数的原料制成: 木质纤维 15-26份, 羧基丁腈橡胶 3-5份, 无机铝盐防 7j剂 2-6份, 软化剂 0.4-0.8份, 芳纶浆粕纤维 15-22份, 促进剂 0.2-0.4份, 活性单 体 12-16份, 增稠剂 6-9份, 辅料 4-7份, 粉煤灰 16-24份, 轻硅纤维阻裂增强剂 5-1 2份, 骨料 16-18份, 氟硅酸钠 1.5-2.6份, 亚磷酸双酚 A酯 2-4份, 丙烯酸乙酯 15-2 0份, 甘露醇 1.2-2.3份, 硅烷偶联剂 2-7份, 聚四氟乙烯纤维 3-9份。 [0005] 优化的, 一种耐久的建筑用纤维板, 其由以下重量份数的原料制成: 木质纤维 21份, 羧基丁腈橡胶 4份, 无机铝盐防水剂 4份, 软化剂 0.6份, 芳纶浆粕纤维 17 份, 促进剂 0.3份, 活性单体 14份, 增稠剂 7.5份, 辅料 5.5份, 粉煤灰 20份, 轻硅 纤维阻裂增强剂 9份, 骨料 17份, 氟硅酸钠 2份, 亚磷酸双酚 A酯 3份, 丙烯酸乙 酯 18份, 甘露醇 1.9份, 硅烷偶联剂 4.5份, 聚四氟乙烯纤维 6份。 [0004] In order to solve the above technical problem, the technical solution of the present invention is a durable construction fiberboard made of the following raw materials by weight: 15-26 parts of wood fiber, 3-5 parts of carboxylated nitrile rubber , Inorganic aluminum salt anti- 7j agent 2-6 parts, softener 0.4-0.8 parts, aramid pulp fiber 15-22 parts, accelerator 0.2-0.4 parts, active monomer 12-16 parts, thickener 6-9 4-7 parts of auxiliary materials, 16-24 parts of fly ash, 51-2 parts of light silicon fiber cracking enhancer, 16-18 parts of aggregate, 1.5-2.6 parts of sodium fluorosilicate, bisphenol A The ester is 2-4 parts, ethyl acrylate 15-2 0 parts, mannitol 1.2-2.3 parts, silane coupling agent 2-7 parts, and polytetrafluoroethylene fiber 3-9 parts. [0005] Optimized, a durable construction fiberboard made of the following parts by weight of raw materials: 21 parts of wood fiber, 4 parts of carboxylated nitrile rubber, 4 parts of inorganic aluminum salt water repellent, 0.6 parts of softener, 17 parts of aramid pulp fiber, 0.3 parts of accelerator, 14 parts of reactive monomer, 7.5 parts of thickener, 5.5 parts of auxiliary material, 20 parts of fly ash, 9 parts of light silicon fiber cracking enhancer, 17 parts of aggregate, 2 parts of sodium fluorosilicate, 3 parts of bisphenol A phosphite, 18 parts of ethyl acrylate, 1.9 parts of mannitol, 4.5 parts of silane coupling agent, and 6 parts of polytetrafluoroethylene fiber.
发明的有益效果  Advantageous effects of the invention
有益效果  Beneficial effect
[0006] 本发明的有益效果是, 本发明的耐久的建筑用纤维板, 具有很好的抗菌性、 防 潮性, 抗冲击性好, 耐久性佳, 提高了寿命, 有效降低了成本。  [0006] The invention has the beneficial effects that the durable construction fiberboard of the invention has good antibacterial property, moisture resistance, good impact resistance, good durability, improved life and effective cost reduction.
本发明的实施方式 Embodiments of the invention
[0007] 实施例 1 Embodiment 1
[0008] 一种耐久的建筑用纤维板, 其由以下重量份数的原料制成: 木质纤维 15份, 羧 基丁腈橡胶 3份, 无机铝盐防水剂 2份, 软化剂 0.4份, 芳纶浆粕纤维 15份, 促进 剂 0.2份, 活性单体 12份, 增稠剂 6份, 辅料 4份, 粉煤灰 16份, 轻硅纤维阻裂增 强剂 5份, 骨料 16份, 氟硅酸钠 1.5份, 亚磷酸双酚 A酯 2份, 丙烯酸乙酯 15份, 甘露醇 1.2份, 硅烷偶联剂 2份, 聚四氟乙烯纤维 3份。  [0008] A durable construction fiberboard made of the following parts by weight of raw materials: 15 parts of wood fiber, 3 parts of carboxylated nitrile rubber, 2 parts of inorganic aluminum salt water repellent, 0.4 part of softener, aramid pulp 15 parts of rayon fiber, 0.2 parts of accelerator, 12 parts of active monomer, 6 parts of thickener, 4 parts of auxiliary materials, 16 parts of fly ash, 5 parts of light silicon fiber crack inhibitor, 16 parts of aggregate, fluorosilicic acid 1.5 parts of sodium, 2 parts of bisphenol A phosphite, 15 parts of ethyl acrylate, 1.2 parts of mannitol, 2 parts of silane coupling agent, and 3 parts of polytetrafluoroethylene fiber.
[0009] 实施例 2  Embodiment 2
[0010] 一种耐久的建筑用纤维板, 其由以下重量份数的原料制成: 木质纤维 26份, 羧 基丁腈橡胶 5份, 无机铝盐防水剂 6份, 软化剂 0.8份, 芳纶浆粕纤维 22份, 促进 剂 0.4份, 活性单体 16份, 增稠剂 9份, 辅料 7份, 粉煤灰 24份, 轻硅纤维阻裂增 强剂 12份, 骨料 18份, 氟硅酸钠 2.6份, 亚磷酸双酚 A酯 4份, 丙烯酸乙酯 20份, 甘露醇 2.3份, 硅烷偶联剂 7份, 聚四氟乙烯纤维 9份。  [0010] A durable construction fiberboard made of the following parts by weight of raw materials: 26 parts of wood fiber, 5 parts of carboxylated nitrile rubber, 6 parts of inorganic aluminum salt water repellent, 0.8 parts of softener, aramid pulp 22 parts of ray fiber, 0.4 parts of accelerator, 16 parts of active monomer, 9 parts of thickener, 7 parts of auxiliary materials, 24 parts of fly ash, 12 parts of light silicon fiber crack inhibitor, 18 parts of aggregate, fluorosilicic acid 2.6 parts of sodium, 4 parts of bisphenol A phosphite, 20 parts of ethyl acrylate, 2.3 parts of mannitol, 7 parts of silane coupling agent, and 9 parts of polytetrafluoroethylene fiber.
[0011] 实施例 3  [0011] Example 3
[0012] 一种耐久的建筑用纤维板, 其由以下重量份数的原料制成: 木质纤维 21份, 羧 基丁腈橡胶 4份, 无机铝盐防水剂 4份, 软化剂 0.6份, 芳纶浆粕纤维 17份, 促进 剂 0.3份, 活性单体 14份, 增稠剂 7.5份, 辅料 5.5份, 粉煤灰 20份, 轻硅纤维阻裂 增强剂 9份, 骨料 17份, 氟硅酸钠 2份, 亚磷酸双酚 A酯 3份, 丙烯酸乙酯 18份, 甘露醇 1.9份, 硅烷偶联剂 4.5份, 聚四氟乙烯纤维 6份 [0012] A durable construction fiberboard made of the following parts by weight of raw materials: 21 parts of wood fiber, 4 parts of carboxylated nitrile rubber, 4 parts of inorganic aluminum salt water repellent, 0.6 parts of softener, aramid pulp 17 parts of ray fiber, 0.3 parts of accelerator, 14 parts of active monomer, 7.5 parts of thickener, 5.5 parts of auxiliary material, 20 parts of fly ash, 9 parts of light silicon fiber crack inhibitor, 17 parts of aggregate, fluorosilicic acid 2 parts of sodium, 3 parts of bisphenol A phosphite, 18 parts of ethyl acrylate, 1.9 parts of mannitol, 4.5 parts of silane coupling agent, 6 parts of polytetrafluoroethylene fiber

Claims

权利要求书 Claim
[权利要求 1] 一种耐久的建筑用纤维板, 其特征在于: 其由以下重量份数的原料制 成: 木质纤维 15-26份, 羧基丁腈橡胶 3-5份, 无机铝盐防水剂 2-6份, 软化剂 0.4-0.8份, 芳纶浆粕纤维 15-22份, 促进剂 0.2-0.4份, 活性单体 12-16份, 增稠剂 6-9份, 辅料 4-7份, 粉煤灰 16-24份, 轻硅纤维阻裂 增强剂 5-12份, 骨料 16-18份, 氟硅酸钠 1.5-2.6份, 亚磷酸双酚 A酯 2-4 份, 丙烯酸乙酯 15-20份, 甘露醇 1.2-2.3份, 硅烷偶联剂 2-7份, 聚四 氟乙烯纤维 3-9份。  [Claim 1] A durable fibrous board for construction, characterized in that it is made of the following raw materials by weight: 15-26 parts of wood fiber, 3-5 parts of carboxylated nitrile rubber, inorganic aluminum salt waterproofing agent 2 -6 parts, softener 0.4-0.8 parts, aramid pulp fiber 15-22 parts, accelerator 0.2-0.4 parts, active monomer 12-16 parts, thickener 6-9 parts, auxiliary materials 4-7 parts, 16-24 parts of fly ash, 5-12 parts of light silicon fiber cracking enhancer, 16-18 parts of aggregate, 1.5-2.6 parts of sodium fluorosilicate, 2-4 parts of bisphenol A phosphite, ethyl acrylate 15-20 parts, 1.2-2.3 parts of mannitol, 2-7 parts of silane coupling agent, and 3-9 parts of polytetrafluoroethylene fiber.
[权利要求 2] 根据权利要求 1所述的耐久的建筑用纤维板, 其特征在于: 其由以下 重量份数的原料制成: 木质纤维 21份, 羧基丁腈橡胶 4份, 无机铝盐 防水剂 4份, 软化剂 0.6份, 芳纶浆粕纤维 17份, 促进剂 0.3份, 活性单 体 14份, 增稠剂 7.5份, 辅料 5.5份, 粉煤灰 20份, 轻硅纤维阻裂增强 齐 1J9份, 骨料 17份, 氟硅酸钠 2份, 亚磷酸双酚 A酯 3份, 丙烯酸乙酯 1 8份, 甘露醇 1.9份, 硅烷偶联剂 4.5份, 聚四氟乙烯纤维 6份。  [Claim 2] The durable construction fiberboard according to claim 1, which is made of the following raw materials by weight: 21 parts of wood fiber, 4 parts of carboxylated nitrile rubber, inorganic aluminum salt waterproofing agent 4 parts, 0.6 parts softener, 17 parts of aramid pulp fiber, 0.3 parts of accelerator, 14 parts of reactive monomer, 7.5 parts thickener, 5.5 parts of auxiliary material, 20 parts of fly ash, light silicon fiber cracking enhancement 1J9 parts, 17 parts of aggregate, 2 parts of sodium fluorosilicate, 3 parts of bisphenol A phosphite, 18 parts of ethyl acrylate, 1.9 parts of mannitol, 4.5 parts of silane coupling agent, 6 parts of polytetrafluoroethylene fiber .
PCT/CN2016/111690 2015-12-30 2016-12-23 Durable construction fiberboard WO2017114304A1 (en)

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CN201511007281.4A CN105504189A (en) 2015-12-30 2015-12-30 Durable fiber board for building
CN201511007281.4 2015-12-30

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