WO2017113520A1 - Device and method for treating a melt with high shear and strong electromagnetic stirring - Google Patents

Device and method for treating a melt with high shear and strong electromagnetic stirring Download PDF

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Publication number
WO2017113520A1
WO2017113520A1 PCT/CN2016/077228 CN2016077228W WO2017113520A1 WO 2017113520 A1 WO2017113520 A1 WO 2017113520A1 CN 2016077228 W CN2016077228 W CN 2016077228W WO 2017113520 A1 WO2017113520 A1 WO 2017113520A1
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crucible
electromagnetic stirring
melt
high shear
mandrel
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PCT/CN2016/077228
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French (fr)
Chinese (zh)
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高志华
徐骏
张志峰
张少明
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北京有色金属研究总院
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Priority claimed from CN201511009010.2A external-priority patent/CN106925762B/en
Priority claimed from CN201521116604.9U external-priority patent/CN205237028U/en
Application filed by 北京有色金属研究总院 filed Critical 北京有色金属研究总院
Publication of WO2017113520A1 publication Critical patent/WO2017113520A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/02Use of electric or magnetic effects

Definitions

  • the invention belongs to the technical field of metal materials and processing and forming thereof, and particularly relates to a device and a method for high shear strong electromagnetic stirring melt processing.
  • the refinement and homogenization of solidification structure is the key link to improve the performance and quality of metal materials, and it is the technical basis for realizing the near-final forming process of metal materials.
  • the structure due to the inherent solidification characteristics of the metal material, the structure usually exhibits the distribution characteristics of "tri-crystal zone", and there are problems such as coarse grain, segregation of components, and uneven structure, which is especially obvious for solidification of large-volume alloy melt. Therefore, how to obtain a fine, round, evenly distributed solidification structure has always been a hot issue for material professionals.
  • both domestic and foreign attempts have been made to apply the external field to intervene in the solidification process of the alloy melt.
  • the alloy melt is strongly disturbed, and the temperature field and composition field of the alloy melt are more uniform, and the alloy melt is A large amount of nucleation is simultaneously carried out in the entire melt range, thereby achieving precise control of the solidification structure of the alloy melt, obtaining a fine and uniform solidified structure, and finally refining the grain structure.
  • the electromagnetic stirring method has the advantages of high energy density and cleanliness, superior responsiveness and controllability, easy automation, high energy utilization, etc., so it is the first to achieve industrialization and obtain a wide range of commercial applications.
  • U.S. Patent Nos. 4,344,837 and 4,229, 022, and Chinese Patent No. 200420112702.0, 200510086377.4 and 201220715064.6 all disclose electromagnetic stirring methods for preparing alloy slurries or blanks, the main principle of which is to use a strong electromagnetic stirring to cause the alloy melt to flow to obtain a relatively uniform temperature. The field and the composition field ultimately refine the grain structure of the alloy.
  • 200810116181 proposes a ring-slit electromagnetic stirring device and method for placing a mandrel in a core portion of a melt to form a melt gap, and realizing a slurry in a ring-stitching pulping system with adjustable stirring slit width Stirring.
  • the ring seam not only avoids the part with low magnetic induction intensity, but also effectively avoids the unevenness of the stirring force caused by the electromagnetic induction skin effect, and turns the alternating electromagnetic field skin effect disadvantage into an advantage, making full use of the skin effect layer with high magnetic induction intensity.
  • 5,135,564 also teaches a similar electromagnetic stirring apparatus and method which controls the agitation of the melt mainly by a rotating magnetic field and a mandrel which can be moved up and down, avoiding the place where the melt is less affected by the electromagnetic force and Increasing the heat dissipation of the melt, but the melt agitation effect produced by electromagnetic stirring is moving in the circumferential direction, mainly laminar flow, it is difficult to produce radial and axial flow of the melt, which is also inevitable
  • the temperature gradient and component gradient distributed along the radial and axial directions, the mandrel moving up and down can enhance the flow above and below the melt, but the effect is limited, and the equipment is quite complicated, the operation is difficult, and the production cost is high.
  • the above several electromagnetic stirring devices and methods easily cause disturbance of the surface of the melt while stirring the melt, destroying the oxide film of the surface layer of the melt, causing the melt to slag and thereby contaminating the melt.
  • the device is mainly composed of an electromagnetic stirring device, a preparation crucible and a mandrel.
  • the electromagnetic stirring device comprises a special structure water tank and a special size electromagnetic stirrer; the preparation crucible has a special shape; the mandrel has a special position, shape and material.
  • a high-shear strong electromagnetic stirring melt treatment method which relies on a special structure of the electromagnetic stirring device, a special shape of the preparation of the crucible and a special position, shape and material of the core rod structure to realize the alloy melt only
  • the internal high-shear severe cyclic turbulent disturbance disturbs the surface, which overcomes the uneven agitation caused by the electromagnetic stirring and the skin effect (especially the large-volume alloy melt), and solves the ordinary electromagnetic stirring melt shear.
  • the cutting rate is weak, the stirring strength is low, and the melt is easy to be entangled in the stirring process, and finally the temperature field and the component field uniformly distributed in the entire melt volume are obtained; at the same time, it is difficult to treat the large volume alloy melt by ordinary electromagnetic stirring.
  • a strong shear melt homogenization treatment of a large volume alloy melt is achieved.
  • the utility model relates to a high shear strong electromagnetic stirring melt processing device, which is mainly composed of a crucible, a mandrel installed in a crucible, and an electromagnetic stirring device installed on the periphery of the crucible, the electromagnetic stirring device comprising a water tank and being placed in a magnetic stirrer in the water tank; the shape of the crucible is semi-tapered or cylindrical, the upper end of the shape of the mandrel is a semi-tapered structure or a cylindrical structure, the lower end is a spiral structure, and the middle of the core rod is a hollow structure.
  • the hollow portion is semi-conical or cylindrical in shape; the mandrel is coaxial with the crucible.
  • the outermost wall of any one of the threads of the lower end of the mandrel has the same shortest vertical distance from the inner wall of the crucible, the distance is 5 to 50 mm, the thread height is 5 to 100 mm, the thread pitch is 20 to 150 mm, and the thread cross-sectional shape is Isosceles trapezoid or rectangular, isosceles trapezoidal sharp angle is 45 ⁇ 90 ° (excluding 90 °), that is 45 ° ⁇ isosceles trapezoidal sharp angle ⁇ 90 °; thread can be single thread, double thread or multi-line Thread; the length of the lower end of the mandrel (the entire thread) is between one-fifth and four-fifth of the length of the mandrel.
  • the semi-tapered structure or the cylindrical structure of the upper end of the mandrel has the same longitudinal section and the shape of the longitudinal section, and the longitudinal section thereof is an isosceles trapezoid or a rectangle, and the isosceles trapezoidal bottom angle is 60° to 120° (excluding 90). °), that is, 60 ° ⁇ isosceles trapezoidal bottom angle ⁇ 90 °, or 90 ° ⁇ isosceles trapezoidal bottom angle ⁇ 120 °; semi-conical or cylindrical structure on the outer wall and the shortest vertical of the inner wall of the crucible The distance is the same and the size is 10 ⁇ 150mm.
  • the middle portion of the mandrel is a hollow structure, the inner cavity is semi-conical or cylindrical), the longitudinal section is an isosceles trapezoid or a rectangle, and the angle of the isosceles trapezoidal bottom is 60° to 120° (excluding 90°), that is, 60° ⁇ isosceles trapezoidal bottom angle ⁇ 90°, or 90° ⁇ isosceles trapezoidal bottom angle ⁇ 120°, the same as the escapement section shape, the shortest vertical distance between any position on the inner wall of the mandrel and the inner wall of the crucible is the same, The size is 15 to 155 mm.
  • the distance between the bottom of the mandrel and the bottom of the crucible is 5 to 100 mm, and the distance between the top and the melt liquid surface is 5 to 200 mm.
  • the mandrel is a non-magnetic metal material such as austenitic stainless steel, titanium, molybdenum, cobalt, chromium, nickel or copper, or a non-metallic material such as graphite, ceramic or corundum.
  • a non-magnetic metal material such as austenitic stainless steel, titanium, molybdenum, cobalt, chromium, nickel or copper, or a non-metallic material such as graphite, ceramic or corundum.
  • the shape of the crucible is semi-conical or cylindrical, and the longitudinal section thereof is an isosceles trapezoid or a rectangle, and the angle of the isosceles trapezoidal bottom is 60° to 120° (excluding 90°), that is, 60° ⁇ isosceles trapezoidal bottom. Angle number ⁇ 90° or 90° ⁇ isosceles trapezoidal bottom angle ⁇ 120°.
  • the bottom radius of the crucible is 50-500mm and the height is 50-1000mm.
  • the material is austenitic stainless steel, non-magnetic metal materials such as titanium, molybdenum, cobalt, chromium, nickel or copper, or non-metallic materials such as graphite, ceramic or corundum.
  • the bottom of the crucible is provided with a discharge port, and the slurry can be opened after being processed for slurry injection molding equipment.
  • the upper plate of the water tank is a plate shielding magnetic field, such as an iron-nickel alloy plate, for shielding the magnetic field to be led upward, and only agitating the melt surrounded by the electromagnetic stirrer; and the water tank is connected to the cooling circulating water for cooling and stirring.
  • the coil in the process to avoid overheating.
  • the height of the electromagnetic stirrer has a specific value, and the height value is the same as the height of the spiral portion at the lower end of the mandrel, and is opposite thereto;
  • the stirring coil is a three-phase multi-pole (3, 6, and 9 pairs);
  • the stirring frequency can be not only For low frequency, it can also be power frequency, medium frequency and even high frequency;
  • the stirring current range is 5A ⁇ 500A, to achieve strong turbulent motion of stirring melt strong shear.
  • the present invention provides a method for high shear strong electromagnetic stirring melt processing, comprising the steps of: firstly fixing a mandrel in a concrete manner inside a crucible, and injecting a specific mass of metal melt into the crucible, The electromagnetic stirrer is turned on and the cooling circulating water is introduced into the water tank; the melt is only disturbed by the internal high-shear severe circulation turbulence and the surface is not moved, and the temperature and composition of the whole melt volume are uniformly distributed; after the treatment is completed, the crucible is opened. The bottom discharge port injects the treated melt into the molding apparatus.
  • the apparatus and method of the present invention can not only process a common aluminum alloy melt, but also an alloy melt such as a magnesium alloy, a copper alloy, a zinc alloy, a titanium alloy, and a particle-reinforced metal matrix composite thereof.
  • Treated melt It can be injected into extrusion casting equipment, die casting equipment, semi-continuous casting equipment and other molding equipment.
  • FIG. 1 is a schematic view showing the structure of a high shear strong electromagnetic stirring melt processing apparatus of the present invention.
  • Figure 2 is a schematic diagram of high shear strong electromagnetic stirring melt flow.
  • the apparatus for processing high shear strong electromagnetic stirring melt of the present invention is mainly composed of a preparation crucible 4, a core rod 5 and an electromagnetic stirring device, and the core rod 5 is fixed in the preparation crucible 4, and the electromagnetic stirring device is placed.
  • the electromagnetic stirring device includes a magnetic stirrer 3 and a water tank 1, and the electromagnetic stirrer 3 is placed in the water tank 1.
  • the mandrel 5 is composed of a hollow semi-conical tube or a cylindrical tube and a spiral structure disposed at a lower end thereof.
  • the lower end of the shape of the mandrel 5 has a spiral structure
  • the upper end is a semi-tapered structure or a cylindrical shape
  • the middle of the mandrel 5 is a hollow structure, and the mandrel 5 is coaxial with the preparation crucible 4.
  • each thread 6 of the lower end spiral structure of the mandrel 5 is the same as the shortest vertical distance of the inner wall of the preparation crucible 4, and the shortest vertical distance is 5 to 50 mm, the height of the thread 6 is 5 to 100 mm, and the thread 6 has a pitch of 20 to 150 mm.
  • the cross-sectional shape of the thread 6 is an isosceles trapezoid or a rectangle, the isosceles trapezoidal sharp angle is 45-90° (excluding 90°), and the thread 6 can be a single-thread thread, a double-thread thread or a multi-thread thread; the lower end of the mandrel 5 is entirely
  • the length of the thread 6 is one-fifth to four-fifth of the length of the mandrel 5, for example, the length of the entire thread 6 at the lower end of the mandrel 5 is two-fifths of the length of the mandrel 5.
  • the longitudinal section of the upper semi-tapered or cylindrical structure of the mandrel 5 is the same as the longitudinal section of the preparation ⁇ 4, both of which are isosceles trapezoidal or rectangular, and the two isosceles trapezoids or rectangular shapes are similar, semi-conical or cylindrical
  • the shortest vertical distance from the position on the outer wall of the structure to the inner wall of the preparation crucible 4 is the same, and the size is 10 to 150 mm.
  • the inner cavity is semi-tapered or cylindrical, and the cross section is an isosceles trapezoid or a rectangle, which is the same as the longitudinal section of the preparation crucible 4, and the shortest vertical position from the inner wall to the inner wall of the crucible 4 is prepared.
  • the distance is the same, the size is 15 ⁇ 155mm.
  • the distance between the bottom of the mandrel 5 and the bottom of the preparation crucible 4 is 5 to 100 mm, and the distance from the top of the metal melt 8 is 5 to 200 mm.
  • the mandrel 5 is a non-magnetic metal material such as austenitic stainless steel, titanium, molybdenum, cobalt, chromium, nickel or copper, or a non-metallic material such as graphite, ceramic or corundum.
  • a non-magnetic metal material such as austenitic stainless steel, titanium, molybdenum, cobalt, chromium, nickel or copper, or a non-metallic material such as graphite, ceramic or corundum.
  • the crucible 4 has a special shape and is semi-conical or cylindrical in shape, and its longitudinal section is an isosceles trapezoid or Rectangular, isosceles trapezoidal bottom angle is 60 ° ⁇ 120 ° (excluding 90 °).
  • the crucible has a bottom radius of 50-500 mm and a height of 50-1000 mm.
  • the material is austenitic stainless steel, non-magnetic metal materials such as titanium, molybdenum, cobalt, chromium, nickel or copper, or non-metallic materials such as graphite, ceramic or corundum. .
  • a discharge port 7 is left at the bottom of the preparation crucible 4, and the slurry can be opened after being processed for slurry injection molding equipment.
  • the upper cover 2 of the water tank is an iron-nickel alloy plate shielding magnetic field for shielding the magnetic field to be led upward, and only the metal melt 8 surrounded by the electromagnetic stirrer 3 is agitated; at the same time, the water tank 1 is connected to the cooling circulating water for cooling the stirring process.
  • the coil in the middle to avoid overheating.
  • the height of the electromagnetic stirrer 3 has a specific value, and the height value is the same as the height of the spiral portion at the lower end of the mandrel 5, and is opposite thereto;
  • the stirring coil is a three-phase multi-pole (3, 6, and 9 pairs);
  • the stirring frequency can be not only Low frequency, can also be power frequency, medium frequency and even high frequency;
  • the stirring current range is 5A ⁇ 500A, to achieve the strong turbulent motion of the stirring metal melt 8 strong shear.
  • the high-shear strong electromagnetic stirring melt processing apparatus and the processing method of the present invention will be further described by taking the 7075 aluminum alloy as an example.
  • the height of the mandrel 5 is 250 mm, and the shortest vertical distance between the outermost wall of each thread 6 of the lower end spiral structure and the inner wall of the preparation crucible 4 is 10 mm, and the height of the thread 6 is 30mm, thread 6 pitch 100mm, thread 6 cross-sectional shape is isosceles trapezoid, isosceles trapezoidal sharp angle number is 70°, thread 6 is double thread; the length of the whole thread 6 of the lower end of mandrel 5 is five points of mandrel 5 of two.
  • the longitudinal section of the semi-tapered or cylindrical structure of the upper end of the mandrel 5 is similar to the longitudinal section of the preparation ⁇ 4, and the shortest vertical distance from any position on the outer wall of the semi-tapered or cylindrical structure to the inner wall of the crucible 4 is 40 mm. .
  • the shortest vertical distance from any position on the inner wall of the mandrel 5 to the inner wall of the preparation crucible 4 is 42 mm.
  • the bottom of the mandrel 5 is at a distance of 15 mm from the bottom of the preparation crucible 4.
  • the material of the mandrel 5 is a titanium alloy material.
  • the longitudinal section of the preparation crucible 4 is an isosceles trapezoid, and the isosceles trapezoidal bottom angle is 80°.
  • the crucible 4 has a bottom radius of 80 mm and a height of 350 mm, and is made of a titanium alloy material.
  • the stirring stirrer of the electromagnetic stirrer 3 is three-phase three-pole; the stirring frequency is 50 Hz; the stirring current is 100A.
  • the 7075 aluminum alloy metal melt 8 of 720 ° C is injected into the preparation crucible 4 which has fixed the mandrel 5 in a corresponding manner, and the liquid level of the metal melt 8 is ensured to be 35 mm higher than the top of the mandrel, and the electromagnetic stirrer 3 is activated. Cooling circulating water is introduced into the water tank 1; relying on a special structure of the electromagnetic stirring device, the special shape of the preparation ⁇ 4 and the special position, shape and material of the mandrel 5 structure to realize the metal melt 8 only in the internal high shear cycle The flow is disturbed and the surface is not moving. As shown in Fig.
  • the electromagnetic stirring is overcome due to the circumferential motion characteristics and the skin effect caused by the agitation unevenness (especially the bulk alloy melt), and the common electromagnetic stirring melt shear is solved.
  • the rate is weak, the stirring intensity is low, and the melt is easy to wind up the slag during the stirring process, and finally the temperature field and the component field uniformly distributed in the entire melt volume are obtained.
  • Large volume The strong shear melt of the gold melt is homogenized; after the temperature of the metal melt 8 is lowered to 645 ° C, the bottom discharge port 7 of the crucible 4 is opened, and the treated metal melt 8 is injected into the extrusion casting equipment. forming.
  • the extruded and cast parts treated by the device and method have fine and uniform microstructure, the grain size is reduced by 48%, the chemical composition segregation is greatly reduced, the solidification defects are few, and the mechanical properties are effectively improved.
  • Tensile strength, yield strength and elongation increased by 30%, 26% and 32%, respectively.
  • the material of the mandrel 5 may also be a non-magnetic metal material such as austenitic stainless steel, molybdenum, cobalt, chromium, nickel or copper, or a non-metal material such as graphite, ceramic or corundum; due to the special material of the mandrel 5, the device and The method can not only process the common aluminum alloy melt, but also the alloy melt of magnesium alloy, copper alloy, zinc alloy, titanium alloy and the particle-reinforced metal matrix composite material thereof.
  • a non-magnetic metal material such as austenitic stainless steel, molybdenum, cobalt, chromium, nickel or copper, or a non-metal material such as graphite, ceramic or corundum
  • the temperature field and composition field of the metal melt alloy processed by the invention are very uniform, the microstructure of the formed blank and the parts are uniform and uniform, the composition distribution is uniform, the casting defects are greatly reduced, the performance is greatly improved, the product production efficiency is improved, and the product cost is greatly reduced.
  • the alloy melt is only disturbed by the internal high shear severe cyclic turbulence. Does not move, overcomes the electromagnetic stirring due to circumferential motion characteristics and skin effect caused by uneven mixing (especially large volume alloy melt), solves the ordinary electromagnetic stirring melt shear rate is weak, the stirring strength is low, the melting process is melting.
  • the shortcomings of the easy-volume air-rolling slag finally result in a uniform distribution of the temperature field and the composition field in the entire melt volume. At the same time, it is difficult to handle the large-volume alloy melt by ordinary electromagnetic stirring, and the strong shear of the large-volume alloy melt is realized. Melt homogenization treatment.
  • the temperature field and composition field of the metal melt alloy treated by the device and method of the invention are very uniform, the microstructure of the formed blank and the parts are uniform and uniform, the composition distribution is uniform, the casting defects are greatly reduced, the performance is greatly improved, and the production efficiency is improved, and the production efficiency is greatly reduced.

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Abstract

Provided are a device and method for treating a melt with high shear and strong electromagnetic stirring. The device is mainly composed of a crucible (4), a core rod (5) installed within the crucible (4), and an electromagnetic stirring device installed outside the crucible (4). The electromagnetic stirring device comprises a water tank (1) and an electromagnetic stirrer (3) placed in the water tank. The shape of the crucible (4) is semi-conical or cylindrical. The shape of the core rod (5) is a semi-conical or cylindrical structure at the upper end and a spiral structure at the lower end. The centre of the core rod (5) is a hollow structure, with the shape thereof being semi-conical or cylindrical. The core rod (5) and the crucible (4) are coaxial. The device can be used for treating an alloy melt, such as an aluminium alloy, a magnesium alloy, a copper alloy, a zinc alloy and a titanium alloy, and a particle-reinforced metal based composite material thereof. The temperature field and ingredient field of a metal melt treated by the device are very uniform, and a moulded blank and parts have fine and uniform textures, uniformly distributed ingredients, reduced casting defects and improved properties.

Description

一种高剪切强电磁搅拌熔体处理的装置和方法Device and method for high shear strong electromagnetic stirring melt processing 技术领域Technical field
本发明属于金属材料及其加工成形技术领域,具体涉及一种高剪切强电磁搅拌熔体处理的装置和方法。The invention belongs to the technical field of metal materials and processing and forming thereof, and particularly relates to a device and a method for high shear strong electromagnetic stirring melt processing.
背景技术Background technique
凝固组织的细化、均匀化是提高金属材料性能和品质的关键环节,是实现金属材料短流程近终形成形加工的技术基础。但是受金属材料固有的凝固特性限制,组织通常呈现“三晶带”的分布特点,存在晶粒粗大、成分偏析、组织不均匀等问题,对大体积合金熔体凝固而言尤为明显。因此,如何获得细小、圆整、均匀分布的凝固组织一直是材料学者们研究的热点问题。针对这个科学问题,国内外均尝试采用施加外场干预合金熔体的凝固过程,通过施加外场使合金熔体产生强烈扰动,促使合金熔体的温度场、成分场更加均匀,进而使合金熔体在整个熔体范围内同时大量形核,从而实现对合金熔体凝固组织的精确控制,获得细小均匀的凝固组织,最终细化晶粒组织。The refinement and homogenization of solidification structure is the key link to improve the performance and quality of metal materials, and it is the technical basis for realizing the near-final forming process of metal materials. However, due to the inherent solidification characteristics of the metal material, the structure usually exhibits the distribution characteristics of "tri-crystal zone", and there are problems such as coarse grain, segregation of components, and uneven structure, which is especially obvious for solidification of large-volume alloy melt. Therefore, how to obtain a fine, round, evenly distributed solidification structure has always been a hot issue for material scholars. In response to this scientific problem, both domestic and foreign attempts have been made to apply the external field to intervene in the solidification process of the alloy melt. By applying the external field, the alloy melt is strongly disturbed, and the temperature field and composition field of the alloy melt are more uniform, and the alloy melt is A large amount of nucleation is simultaneously carried out in the entire melt range, thereby achieving precise control of the solidification structure of the alloy melt, obtaining a fine and uniform solidified structure, and finally refining the grain structure.
电磁搅拌法具有能量的高密度性和清洁性、优越的响应性和可控性、易于自动化、能量利用率高等优点,所以率先实现产业化并获得较为广泛的商业应用。美国专利4434837和4229210及中国专利200420112702.0、200510086377.4和201220715064.6都公开了几种制备合金浆料或坯料的电磁搅拌方法,其主要原理是利用强烈的电磁搅拌使合金熔体产生流动,获得相对均匀的温度场和成分场,最终细化合金的晶粒组织。但是由于电磁感应集肤效应的存在导致搅拌作用仅仅集中在表面的一个很小的薄层,而使中心大面积的金属液搅拌效果很差,从而使得金属液无法获得均匀的搅拌,从心部到边部的合金熔体的温度场和成分场分布不均匀,频率越高,集肤效应越明显,距离断面外表层的距离越大,则感应电流的衰减越剧烈。因此大部分电磁搅拌装置和方法均是采取降低频率的方法减弱集肤效应,但是低的频率不仅减弱了搅拌强度,同时需增设变频装置,会增加设备投资成本,增加合金浆料的制备成本。中国专利200810116181提出了一种环缝式电磁搅拌装置和方法,该装置在熔体心部放置一个芯棒,形成熔体缝隙,在搅拌缝隙宽度可调的环缝式制浆系统内实现浆料的搅拌。环缝不仅避开了磁感应强度较低的部分,可有效避免电磁感应趋肤效应导致的搅拌力不均匀性,将交变电磁场趋肤效应劣势转变为优势,充分利用趋肤效应层磁感应强度高的优点,同时增加了熔体心部的散热面积,使浆料获得的更加均匀的温度场和成分场,使用工频电流便可以实现均匀的搅拌,因此 减少了变频设备,减少成本。但由于缝隙的宽度有限,只能处理小体积熔体,熔体处理量有限,同时电磁搅拌的固有特性,电磁力在熔体中是按周向分布的,熔体的流动也是沿周向运动,以层流为主,这就不可避免的产生了沿径向和轴向分布的温度梯度和成分梯度。美国专利5135564也提出了一种类似的电磁搅拌设备和方法,该设备主要是通过旋转的磁场和可上下移动的芯棒来控制熔体的搅拌,避开熔体受电磁力较小的地方和增加熔体的散热,但是电磁搅拌所产生的熔体搅拌效果都是沿周向运动的,以层流为主,很难产生熔体的径向和轴向流动,也就同样不可避免的产生了沿径向和轴向分布的温度梯度和成分梯度,上下移动的芯棒虽说可以增强熔体上下的流动,但是效果有限,同时该设备相当复杂,操作困难,生产成本较高。同时上述几种电磁搅拌装置及方法在搅拌熔体的同时易导致熔体表面的扰动,破坏熔体表层的氧化膜,造成熔体卷气夹渣,进而污染熔体。The electromagnetic stirring method has the advantages of high energy density and cleanliness, superior responsiveness and controllability, easy automation, high energy utilization, etc., so it is the first to achieve industrialization and obtain a wide range of commercial applications. U.S. Patent Nos. 4,344,837 and 4,229, 022, and Chinese Patent No. 200420112702.0, 200510086377.4 and 201220715064.6 all disclose electromagnetic stirring methods for preparing alloy slurries or blanks, the main principle of which is to use a strong electromagnetic stirring to cause the alloy melt to flow to obtain a relatively uniform temperature. The field and the composition field ultimately refine the grain structure of the alloy. However, due to the electromagnetic induction skin effect, the agitation is concentrated only on a small thin layer on the surface, so that the large-area metal liquid stirring effect is poor, so that the molten metal cannot be uniformly stirred from the core. The temperature field and composition field distribution of the alloy melt to the edge are not uniform. The higher the frequency, the more obvious the skin effect. The greater the distance from the outer surface of the section, the more intense the attenuation of the induced current. Therefore, most electromagnetic stirring devices and methods use the method of reducing the frequency to weaken the skin effect, but the low frequency not only weakens the stirring strength, but also needs to add a frequency conversion device, which increases the equipment investment cost and increases the preparation cost of the alloy slurry. Chinese Patent No. 200810116181 proposes a ring-slit electromagnetic stirring device and method for placing a mandrel in a core portion of a melt to form a melt gap, and realizing a slurry in a ring-stitching pulping system with adjustable stirring slit width Stirring. The ring seam not only avoids the part with low magnetic induction intensity, but also effectively avoids the unevenness of the stirring force caused by the electromagnetic induction skin effect, and turns the alternating electromagnetic field skin effect disadvantage into an advantage, making full use of the skin effect layer with high magnetic induction intensity. The advantages of the same, at the same time increase the heat dissipation area of the core of the melt, so that the slurry obtains a more uniform temperature field and composition field, and uniform stirring can be achieved by using the power frequency current. Reduced frequency conversion equipment and reduced costs. However, due to the limited width of the gap, only a small volume of melt can be processed, the amount of melt treatment is limited, and the inherent characteristics of electromagnetic stirring, the electromagnetic force is distributed circumferentially in the melt, and the flow of the melt is also moved in the circumferential direction. The laminar flow dominates, which inevitably produces temperature gradients and compositional gradients distributed along the radial and axial directions. U.S. Patent No. 5,135,564 also teaches a similar electromagnetic stirring apparatus and method which controls the agitation of the melt mainly by a rotating magnetic field and a mandrel which can be moved up and down, avoiding the place where the melt is less affected by the electromagnetic force and Increasing the heat dissipation of the melt, but the melt agitation effect produced by electromagnetic stirring is moving in the circumferential direction, mainly laminar flow, it is difficult to produce radial and axial flow of the melt, which is also inevitable The temperature gradient and component gradient distributed along the radial and axial directions, the mandrel moving up and down can enhance the flow above and below the melt, but the effect is limited, and the equipment is quite complicated, the operation is difficult, and the production cost is high. At the same time, the above several electromagnetic stirring devices and methods easily cause disturbance of the surface of the melt while stirring the melt, destroying the oxide film of the surface layer of the melt, causing the melt to slag and thereby contaminating the melt.
发明内容Summary of the invention
针对以上问题,本发明的目的是提供一种高剪切强电磁搅拌熔体处理的装置和方法。该装置主要由电磁搅拌装置、制备坩埚和芯棒组成,电磁搅拌装置包括特殊结构的水箱和特殊尺寸的电磁搅拌器;制备坩埚具有特殊形状;芯棒具有特殊位置、形状及材质。基于上述装置,提出一种高剪切强电磁搅拌熔体处理的方法,依靠具有特殊结构的电磁搅拌装置、特殊形状的制备坩埚和特殊位置、形状及材质的芯棒结构实现合金熔体只在内部高剪切剧烈循环紊流扰动而表面不动,克服了电磁搅拌由于周向运动特性和趋肤效应引起的搅拌不均匀(尤其是大体积合金熔体),解决了普通电磁搅拌熔体剪切速率弱,搅拌强度低,搅拌过程熔体易卷气夹渣的缺点,最终得到整个熔体体积内均匀分布的温度场和成分场;同时解决了普通电磁搅拌难以处理大体积合金熔体,实现了大体积合金熔体的强剪切熔体均匀化处理。In view of the above problems, it is an object of the present invention to provide an apparatus and method for high shear strong electromagnetic stirring melt processing. The device is mainly composed of an electromagnetic stirring device, a preparation crucible and a mandrel. The electromagnetic stirring device comprises a special structure water tank and a special size electromagnetic stirrer; the preparation crucible has a special shape; the mandrel has a special position, shape and material. Based on the above device, a high-shear strong electromagnetic stirring melt treatment method is proposed, which relies on a special structure of the electromagnetic stirring device, a special shape of the preparation of the crucible and a special position, shape and material of the core rod structure to realize the alloy melt only The internal high-shear severe cyclic turbulent disturbance disturbs the surface, which overcomes the uneven agitation caused by the electromagnetic stirring and the skin effect (especially the large-volume alloy melt), and solves the ordinary electromagnetic stirring melt shear. The cutting rate is weak, the stirring strength is low, and the melt is easy to be entangled in the stirring process, and finally the temperature field and the component field uniformly distributed in the entire melt volume are obtained; at the same time, it is difficult to treat the large volume alloy melt by ordinary electromagnetic stirring. A strong shear melt homogenization treatment of a large volume alloy melt is achieved.
一种高剪切强电磁搅拌熔体处理的装置,该装置主要由坩埚、安装在坩埚内的芯棒、及安装在坩埚外围的电磁搅拌装置组成,所述的电磁搅拌装置包括水箱和放置在水箱中的电磁搅拌器;所述的坩埚的形状为半锥形或圆柱形,所述的芯棒形状上端为半锥形结构或圆柱形结构,下端为螺旋结构,芯棒中间为中空结构,中空部分的形状为半锥形或圆柱形;所述的芯棒与坩埚同轴。The utility model relates to a high shear strong electromagnetic stirring melt processing device, which is mainly composed of a crucible, a mandrel installed in a crucible, and an electromagnetic stirring device installed on the periphery of the crucible, the electromagnetic stirring device comprising a water tank and being placed in a magnetic stirrer in the water tank; the shape of the crucible is semi-tapered or cylindrical, the upper end of the shape of the mandrel is a semi-tapered structure or a cylindrical structure, the lower end is a spiral structure, and the middle of the core rod is a hollow structure. The hollow portion is semi-conical or cylindrical in shape; the mandrel is coaxial with the crucible.
所述的芯棒下端螺旋结构的任何一个螺纹的最外壁与坩埚内壁的最短垂直距离均相同,其距离为5~50mm,螺纹高度为5~100mm,螺纹螺距20~150mm,螺纹横截面形状为等腰梯形或矩形,等腰梯形锐角度数为45~90°(不含90°),即45°≤等腰梯形锐角度数<90°;螺纹可为单线螺纹、双线螺纹或多线螺纹;所述的芯棒下端螺旋结构(整个螺纹)的长度为芯棒长度的五分之一至五分之四。 The outermost wall of any one of the threads of the lower end of the mandrel has the same shortest vertical distance from the inner wall of the crucible, the distance is 5 to 50 mm, the thread height is 5 to 100 mm, the thread pitch is 20 to 150 mm, and the thread cross-sectional shape is Isosceles trapezoid or rectangular, isosceles trapezoidal sharp angle is 45 ~ 90 ° (excluding 90 °), that is 45 ° ≤ isosceles trapezoidal sharp angle < 90 °; thread can be single thread, double thread or multi-line Thread; the length of the lower end of the mandrel (the entire thread) is between one-fifth and four-fifth of the length of the mandrel.
所述的芯棒上端半锥形结构或圆柱形结构的纵截面与坩埚纵截面形状相同,其纵截面为等腰梯形或矩形,等腰梯形底角度数为60°~120°(不含90°),即60°≤等腰梯形底角度数<90°,或90°<等腰梯形底角度数≤120°;半锥形结构或圆柱形结构的外壁上任一位置与坩埚内壁的最短垂直距离均相同,大小为10~150mm。The semi-tapered structure or the cylindrical structure of the upper end of the mandrel has the same longitudinal section and the shape of the longitudinal section, and the longitudinal section thereof is an isosceles trapezoid or a rectangle, and the isosceles trapezoidal bottom angle is 60° to 120° (excluding 90). °), that is, 60 ° ≤ isosceles trapezoidal bottom angle < 90 °, or 90 ° < isosceles trapezoidal bottom angle ≤ 120 °; semi-conical or cylindrical structure on the outer wall and the shortest vertical of the inner wall of the crucible The distance is the same and the size is 10~150mm.
所述的芯棒中部为中空结构,内部空洞为半锥形或圆柱形),纵截面为等腰梯形或矩形,等腰梯形底角度数为60°~120°(不含90°),即60°≤等腰梯形底角度数<90°,或90°<等腰梯形底角度数≤120°,与坩埚纵截面形状相同,芯棒内壁上任一位置与坩埚内壁的最短垂直距离均相同,大小为15~155mm。The middle portion of the mandrel is a hollow structure, the inner cavity is semi-conical or cylindrical), the longitudinal section is an isosceles trapezoid or a rectangle, and the angle of the isosceles trapezoidal bottom is 60° to 120° (excluding 90°), that is, 60° ≤ isosceles trapezoidal bottom angle <90°, or 90° < isosceles trapezoidal bottom angle ≤ 120°, the same as the escapement section shape, the shortest vertical distance between any position on the inner wall of the mandrel and the inner wall of the crucible is the same, The size is 15 to 155 mm.
所述的芯棒底部与坩埚底部之间的距离为5~100mm,顶部与熔体液面之间的距离5~200mm。The distance between the bottom of the mandrel and the bottom of the crucible is 5 to 100 mm, and the distance between the top and the melt liquid surface is 5 to 200 mm.
所述芯棒为奥氏体不锈钢、钛、钼、钴、铬、镍或铜等非磁金属材料,或者石墨、陶瓷或刚玉等非金属材料。The mandrel is a non-magnetic metal material such as austenitic stainless steel, titanium, molybdenum, cobalt, chromium, nickel or copper, or a non-metallic material such as graphite, ceramic or corundum.
所述的坩埚形状为半锥形或圆柱形,其纵截面为等腰梯形或矩形,等腰梯形底角度数为60°~120°(不含90°),即60°≤等腰梯形底角度数<90°或90°<等腰梯形底角度数≤120°。坩埚底部半径为50~500mm,高度为50~1000mm,材质为奥氏体不锈钢、钛、钼、钴、铬、镍或铜等非磁金属材料,或者石墨、陶瓷或刚玉等非金属材料。The shape of the crucible is semi-conical or cylindrical, and the longitudinal section thereof is an isosceles trapezoid or a rectangle, and the angle of the isosceles trapezoidal bottom is 60° to 120° (excluding 90°), that is, 60°≤ isosceles trapezoidal bottom. Angle number <90° or 90° < isosceles trapezoidal bottom angle ≤ 120°. The bottom radius of the crucible is 50-500mm and the height is 50-1000mm. The material is austenitic stainless steel, non-magnetic metal materials such as titanium, molybdenum, cobalt, chromium, nickel or copper, or non-metallic materials such as graphite, ceramic or corundum.
所述坩埚底部设有出料口,浆料处理完可打开,用于浆料注入成型设备。The bottom of the crucible is provided with a discharge port, and the slurry can be opened after being processed for slurry injection molding equipment.
所述的水箱上板为屏蔽磁场的板材,如铁镍合金板材,用来屏蔽磁场向上导出,而只对电磁搅拌器包围的熔体施加搅拌;同时水箱通入冷却循环水,用来冷却搅拌过程中的线圈,避免其过热。The upper plate of the water tank is a plate shielding magnetic field, such as an iron-nickel alloy plate, for shielding the magnetic field to be led upward, and only agitating the melt surrounded by the electromagnetic stirrer; and the water tank is connected to the cooling circulating water for cooling and stirring. The coil in the process to avoid overheating.
所述的电磁搅拌器高度具有特定值,其高度值与芯棒下端螺旋部位高度相同,且与其正对;搅拌线圈为三相多对极(3、6、9对级);搅拌频率不仅可以为低频,还可以为工频、中频甚至高频;搅拌电流范围为5A~500A,实现搅拌熔体强剪切剧烈紊流运动。The height of the electromagnetic stirrer has a specific value, and the height value is the same as the height of the spiral portion at the lower end of the mandrel, and is opposite thereto; the stirring coil is a three-phase multi-pole (3, 6, and 9 pairs); the stirring frequency can be not only For low frequency, it can also be power frequency, medium frequency and even high frequency; the stirring current range is 5A ~ 500A, to achieve strong turbulent motion of stirring melt strong shear.
基于上述装置,本发明提出一种高剪切强电磁搅拌熔体处理的方法,包括如下步骤:首先将芯棒按照特定方式固定在坩埚内部,并将特定质量的金属熔体注入到坩埚中,开动电磁搅拌器并在水箱中通入冷却循环水;使熔体只在内部高剪切剧烈循环紊流扰动而表面不动,整个熔体体积内温度和成分均匀分布;处理完成后,打开坩埚底部出料口,将处理后的熔体注入到成型设备中。Based on the above apparatus, the present invention provides a method for high shear strong electromagnetic stirring melt processing, comprising the steps of: firstly fixing a mandrel in a concrete manner inside a crucible, and injecting a specific mass of metal melt into the crucible, The electromagnetic stirrer is turned on and the cooling circulating water is introduced into the water tank; the melt is only disturbed by the internal high-shear severe circulation turbulence and the surface is not moved, and the temperature and composition of the whole melt volume are uniformly distributed; after the treatment is completed, the crucible is opened. The bottom discharge port injects the treated melt into the molding apparatus.
本发明的装置和方法不仅可以处理常用的铝合金熔体,还可以处理镁合金、铜合金、锌合金、钛合金等合金熔体及其颗粒增强的金属基复合材料。经处理的熔体 可注入挤压铸造设备、压铸设备,半连续铸造设备及其他成型设备等。The apparatus and method of the present invention can not only process a common aluminum alloy melt, but also an alloy melt such as a magnesium alloy, a copper alloy, a zinc alloy, a titanium alloy, and a particle-reinforced metal matrix composite thereof. Treated melt It can be injected into extrusion casting equipment, die casting equipment, semi-continuous casting equipment and other molding equipment.
附图说明DRAWINGS
图1是本发明高剪切强电磁搅拌熔体处理装置的结构示意图。BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing the structure of a high shear strong electromagnetic stirring melt processing apparatus of the present invention.
图2是高剪切强电磁搅拌熔体流动示意图。Figure 2 is a schematic diagram of high shear strong electromagnetic stirring melt flow.
主要附图标记说明:The main reference signs indicate:
1   水箱                     2   水箱上盖1 water tank 2 water tank top cover
3   电磁搅拌器               4   制备坩埚3 Electromagnetic stirrer 4 Preparation 坩埚
5   芯棒                     6   螺纹5 mandrel 6 thread
7   出料口                   8   金属熔体7 discharge port 8 metal melt
具体实施方式detailed description
如图1所示,本发明的高剪切强电磁搅拌熔体处理的装置主要由制备坩埚4、芯棒5和电磁搅拌装置组成,芯棒5固定在制备坩埚4内,电磁搅拌装置置于制备坩埚4外围。电磁搅拌装置包括电磁搅拌器3和水箱1,电磁搅拌器3置于水箱1中。As shown in FIG. 1, the apparatus for processing high shear strong electromagnetic stirring melt of the present invention is mainly composed of a preparation crucible 4, a core rod 5 and an electromagnetic stirring device, and the core rod 5 is fixed in the preparation crucible 4, and the electromagnetic stirring device is placed. Prepare the periphery of 坩埚4. The electromagnetic stirring device includes a magnetic stirrer 3 and a water tank 1, and the electromagnetic stirrer 3 is placed in the water tank 1.
芯棒5由中空的半锥形管或圆柱形管及设置在其下端的螺旋结构所构成。芯棒5形状下端为螺旋结构,上端为半锥形结构或圆柱形,芯棒5中间为中空结构,芯棒5与制备坩埚4同轴。The mandrel 5 is composed of a hollow semi-conical tube or a cylindrical tube and a spiral structure disposed at a lower end thereof. The lower end of the shape of the mandrel 5 has a spiral structure, the upper end is a semi-tapered structure or a cylindrical shape, and the middle of the mandrel 5 is a hollow structure, and the mandrel 5 is coaxial with the preparation crucible 4.
芯棒5下端螺旋结构的每个螺纹6的最外壁与制备坩埚4内壁的最短垂直距离均相同,其最短垂直距离为5~50mm,螺纹6高度为5~100mm,螺纹6螺距20~150mm,螺纹6横截面形状为等腰梯形或矩形,等腰梯形锐角度数为45~90°(不含90°),螺纹6可为单线螺纹、双线螺纹或多线螺纹;芯棒5下端整个螺纹6的长度为芯棒5长度的五分之一至五分之四,例如芯棒5下端整个螺纹6的长度为芯棒5长度的五分之二。The outermost wall of each thread 6 of the lower end spiral structure of the mandrel 5 is the same as the shortest vertical distance of the inner wall of the preparation crucible 4, and the shortest vertical distance is 5 to 50 mm, the height of the thread 6 is 5 to 100 mm, and the thread 6 has a pitch of 20 to 150 mm. The cross-sectional shape of the thread 6 is an isosceles trapezoid or a rectangle, the isosceles trapezoidal sharp angle is 45-90° (excluding 90°), and the thread 6 can be a single-thread thread, a double-thread thread or a multi-thread thread; the lower end of the mandrel 5 is entirely The length of the thread 6 is one-fifth to four-fifth of the length of the mandrel 5, for example, the length of the entire thread 6 at the lower end of the mandrel 5 is two-fifths of the length of the mandrel 5.
芯棒5上端半锥形结构或圆柱形结构的纵截面与制备坩埚4纵截面形状相同,均为等腰梯形或矩形,并且两个等腰梯形或矩形形状相似,半锥形结构或圆柱形结构的外壁上每一位置到制备坩埚4内壁的最短垂直距离均相同,大小为10~150mm。The longitudinal section of the upper semi-tapered or cylindrical structure of the mandrel 5 is the same as the longitudinal section of the preparation 坩埚4, both of which are isosceles trapezoidal or rectangular, and the two isosceles trapezoids or rectangular shapes are similar, semi-conical or cylindrical The shortest vertical distance from the position on the outer wall of the structure to the inner wall of the preparation crucible 4 is the same, and the size is 10 to 150 mm.
芯棒5中部的中空结构中,内部空洞为半锥形或圆柱形,截面为等腰梯形或矩形,与制备坩埚4纵截面形状相同,其内壁上每一位置到制备坩埚4内壁的最短垂直距离均相同,大小为15~155mm。In the hollow structure in the middle of the mandrel 5, the inner cavity is semi-tapered or cylindrical, and the cross section is an isosceles trapezoid or a rectangle, which is the same as the longitudinal section of the preparation crucible 4, and the shortest vertical position from the inner wall to the inner wall of the crucible 4 is prepared. The distance is the same, the size is 15 ~ 155mm.
芯棒5底部与制备坩埚4底部距离为5~100mm,顶部距离金属熔体8液面5~200mm。The distance between the bottom of the mandrel 5 and the bottom of the preparation crucible 4 is 5 to 100 mm, and the distance from the top of the metal melt 8 is 5 to 200 mm.
芯棒5为奥氏体不锈钢、钛、钼、钴、铬、镍或铜等非磁金属材料,或者石墨、陶瓷或刚玉等非金属材料。The mandrel 5 is a non-magnetic metal material such as austenitic stainless steel, titanium, molybdenum, cobalt, chromium, nickel or copper, or a non-metallic material such as graphite, ceramic or corundum.
制备坩埚4具有特殊形状,其形状为半锥形或圆柱形,其纵截面为等腰梯形或 矩形,等腰梯形底角度数为60°~120°(不含90°)。制备坩埚4底部半径为50~500mm,高度为50~1000mm,材质为奥氏体不锈钢、钛、钼、钴、铬、镍或铜等非磁金属材料,或者石墨、陶瓷或刚玉等非金属材料。The crucible 4 has a special shape and is semi-conical or cylindrical in shape, and its longitudinal section is an isosceles trapezoid or Rectangular, isosceles trapezoidal bottom angle is 60 ° ~ 120 ° (excluding 90 °). The crucible has a bottom radius of 50-500 mm and a height of 50-1000 mm. The material is austenitic stainless steel, non-magnetic metal materials such as titanium, molybdenum, cobalt, chromium, nickel or copper, or non-metallic materials such as graphite, ceramic or corundum. .
制备坩埚4底部留有出料口7,浆料处理完可打开,用于浆料注入成型设备。A discharge port 7 is left at the bottom of the preparation crucible 4, and the slurry can be opened after being processed for slurry injection molding equipment.
水箱上盖2为屏蔽磁场的铁镍合金板材,用来屏蔽磁场向上导出,而只对电磁搅拌器3包围的金属熔体8施加搅拌;同时水箱1通入冷却循环水,用来冷却搅拌过程中的线圈,避免其过热。The upper cover 2 of the water tank is an iron-nickel alloy plate shielding magnetic field for shielding the magnetic field to be led upward, and only the metal melt 8 surrounded by the electromagnetic stirrer 3 is agitated; at the same time, the water tank 1 is connected to the cooling circulating water for cooling the stirring process. The coil in the middle to avoid overheating.
电磁搅拌器3高度具有特定值,其高度值与芯棒5下端螺旋部位高度相同,且与其正对;搅拌线圈为三相多对极(3、6、9对级);搅拌频率不仅可以为低频,还可以为工频、中频甚至高频;搅拌电流范围为5A~500A,实现搅拌金属熔体8强剪切剧烈紊流运动。The height of the electromagnetic stirrer 3 has a specific value, and the height value is the same as the height of the spiral portion at the lower end of the mandrel 5, and is opposite thereto; the stirring coil is a three-phase multi-pole (3, 6, and 9 pairs); the stirring frequency can be not only Low frequency, can also be power frequency, medium frequency and even high frequency; the stirring current range is 5A ~ 500A, to achieve the strong turbulent motion of the stirring metal melt 8 strong shear.
下面以7075铝合金为例,进一步说明本发明的高剪切强电磁搅拌熔体处理装置及处理方法。Hereinafter, the high-shear strong electromagnetic stirring melt processing apparatus and the processing method of the present invention will be further described by taking the 7075 aluminum alloy as an example.
采用的高剪切强电磁搅拌熔体处理装置中,芯棒5高度为250mm,其下端螺旋结构的每一个螺纹6的最外壁与制备坩埚4内壁的最短垂直距离均为10mm,螺纹6高度为30mm,螺纹6螺距100mm,螺纹6横截面形状为等腰梯形,等腰梯形锐角度数为70°,螺纹6为双线螺纹;芯棒5下端整个螺纹6的长度为芯棒5的五分之二。芯棒5上端半锥形结构或圆柱形结构的纵截面与制备坩埚4纵截面形状相近似,半锥形结构或圆柱形结构的外壁上任一位置到制备坩埚4内壁的最短垂直距离均为40mm。芯棒5内壁上任一位置到制备坩埚4内壁的最短垂直距离均为42mm。芯棒5底部与制备坩埚4底部距离为15mm。芯棒5材料为钛合金材料。In the high shear strong electromagnetic stirring melt processing device, the height of the mandrel 5 is 250 mm, and the shortest vertical distance between the outermost wall of each thread 6 of the lower end spiral structure and the inner wall of the preparation crucible 4 is 10 mm, and the height of the thread 6 is 30mm, thread 6 pitch 100mm, thread 6 cross-sectional shape is isosceles trapezoid, isosceles trapezoidal sharp angle number is 70°, thread 6 is double thread; the length of the whole thread 6 of the lower end of mandrel 5 is five points of mandrel 5 of two. The longitudinal section of the semi-tapered or cylindrical structure of the upper end of the mandrel 5 is similar to the longitudinal section of the preparation 坩埚4, and the shortest vertical distance from any position on the outer wall of the semi-tapered or cylindrical structure to the inner wall of the crucible 4 is 40 mm. . The shortest vertical distance from any position on the inner wall of the mandrel 5 to the inner wall of the preparation crucible 4 is 42 mm. The bottom of the mandrel 5 is at a distance of 15 mm from the bottom of the preparation crucible 4. The material of the mandrel 5 is a titanium alloy material.
制备坩埚4的纵截面为等腰梯形,等腰梯形底角度数为80°。制备坩埚4底部半径为80mm,高度为350mm,材质为钛合金材料。The longitudinal section of the preparation crucible 4 is an isosceles trapezoid, and the isosceles trapezoidal bottom angle is 80°. The crucible 4 has a bottom radius of 80 mm and a height of 350 mm, and is made of a titanium alloy material.
电磁搅拌器3搅拌线圈为三相3对极;搅拌频率为工频50Hz;搅拌电流为100A。The stirring stirrer of the electromagnetic stirrer 3 is three-phase three-pole; the stirring frequency is 50 Hz; the stirring current is 100A.
首向将720℃的7075铝合金金属熔体8注入到已按照相应方式固定好芯棒5的制备坩埚4中,保证金属熔体8液面高于芯棒顶部35mm,开动电磁搅拌器3并在水箱1中通入冷却循环水;倚靠特殊结构的电磁搅拌装置、特殊形状的制备坩埚4和特殊位置、形状及材质的芯棒5结构实现金属熔体8只在内部高剪切剧烈循环紊流扰动而表面不动,如图2所示,克服了电磁搅拌由于周向运动特性和趋肤效应引起的搅拌不均匀(尤其是大体积合金熔体),解决了普通电磁搅拌熔体剪切速率弱,搅拌强度低,搅拌过程熔体易卷气卷渣的缺点,最终得到整个熔体体积内均匀分布的温度场和成分场;同时解决了普通电磁搅拌难以处理大体积合金熔体,实现了大体积合 金熔体的强剪切熔体均匀化处理;待金属熔体8温度降到645℃,打开制备坩埚4底部出料口7,将处理后的金属熔体8注入到挤压铸造设备中进行成型。相比普通挤压铸造零件,经该装置和方法处理后的挤压铸造零件组织细小均匀,晶粒尺寸减小48%,化学成分偏析大大减少,凝固缺陷很少,力学性能得到有效的提高,抗拉强度、屈服强度和延伸率分别增加30%、26%和32%。Firstly, the 7075 aluminum alloy metal melt 8 of 720 ° C is injected into the preparation crucible 4 which has fixed the mandrel 5 in a corresponding manner, and the liquid level of the metal melt 8 is ensured to be 35 mm higher than the top of the mandrel, and the electromagnetic stirrer 3 is activated. Cooling circulating water is introduced into the water tank 1; relying on a special structure of the electromagnetic stirring device, the special shape of the preparation 坩埚4 and the special position, shape and material of the mandrel 5 structure to realize the metal melt 8 only in the internal high shear cycle The flow is disturbed and the surface is not moving. As shown in Fig. 2, the electromagnetic stirring is overcome due to the circumferential motion characteristics and the skin effect caused by the agitation unevenness (especially the bulk alloy melt), and the common electromagnetic stirring melt shear is solved. The rate is weak, the stirring intensity is low, and the melt is easy to wind up the slag during the stirring process, and finally the temperature field and the component field uniformly distributed in the entire melt volume are obtained. At the same time, it is difficult to treat the large volume alloy melt by ordinary electromagnetic stirring. Large volume The strong shear melt of the gold melt is homogenized; after the temperature of the metal melt 8 is lowered to 645 ° C, the bottom discharge port 7 of the crucible 4 is opened, and the treated metal melt 8 is injected into the extrusion casting equipment. forming. Compared with ordinary extruded casting parts, the extruded and cast parts treated by the device and method have fine and uniform microstructure, the grain size is reduced by 48%, the chemical composition segregation is greatly reduced, the solidification defects are few, and the mechanical properties are effectively improved. Tensile strength, yield strength and elongation increased by 30%, 26% and 32%, respectively.
芯棒5的材质还可以是奥氏体不锈钢、钼、钴、铬、镍或铜等非磁金属材料,或者石墨、陶瓷或刚玉等非金属材料;由于芯棒5的特殊材质,该装置和方法不仅可以处理常用的铝合金熔体,还可以处理镁合金、铜合金、锌合金、钛合金等合金熔体及其颗粒增强的金属基复合材料。The material of the mandrel 5 may also be a non-magnetic metal material such as austenitic stainless steel, molybdenum, cobalt, chromium, nickel or copper, or a non-metal material such as graphite, ceramic or corundum; due to the special material of the mandrel 5, the device and The method can not only process the common aluminum alloy melt, but also the alloy melt of magnesium alloy, copper alloy, zinc alloy, titanium alloy and the particle-reinforced metal matrix composite material thereof.
通过本发明处理得金属熔体合金温度场和成分场非常均匀,成型坯料及零件组织细小均匀、成分分布均匀,铸造缺陷大大减少,性能大幅提高,同时提高产品生产效率,大幅度降低产品成本。The temperature field and composition field of the metal melt alloy processed by the invention are very uniform, the microstructure of the formed blank and the parts are uniform and uniform, the composition distribution is uniform, the casting defects are greatly reduced, the performance is greatly improved, the product production efficiency is improved, and the product cost is greatly reduced.
工业应用性Industrial applicability
与现有技术相比,本发明的优点:Advantages of the present invention compared to the prior art:
与传统的电磁搅拌相比,依靠具有特殊结构的电磁搅拌装置、特殊形状的制备坩埚和特殊位置、形状及材质的芯棒结构实现合金熔体只在内部高剪切剧烈循环紊流扰动而表面不动,克服了电磁搅拌由于周向运动特性和趋肤效应引起的搅拌不均匀(尤其是大体积合金熔体),解决了普通电磁搅拌熔体剪切速率弱,搅拌强度低,搅拌过程熔体易卷气卷渣的缺点,最终得到整个熔体体积内均匀分布的温度场和成分场;同时解决了普通电磁搅拌难以处理大体积合金熔体,实现了大体积合金熔体的强剪切熔体均匀化处理。Compared with the traditional electromagnetic stirring, relying on the electromagnetic stirring device with special structure, the special shape of the preparation crucible and the special position, shape and material of the mandrel structure, the alloy melt is only disturbed by the internal high shear severe cyclic turbulence. Does not move, overcomes the electromagnetic stirring due to circumferential motion characteristics and skin effect caused by uneven mixing (especially large volume alloy melt), solves the ordinary electromagnetic stirring melt shear rate is weak, the stirring strength is low, the melting process is melting The shortcomings of the easy-volume air-rolling slag finally result in a uniform distribution of the temperature field and the composition field in the entire melt volume. At the same time, it is difficult to handle the large-volume alloy melt by ordinary electromagnetic stirring, and the strong shear of the large-volume alloy melt is realized. Melt homogenization treatment.
通过本发明装置和方法处理的金属熔体合金温度场和成分场非常均匀,成型坯料及零件组织细小均匀、成分分布均匀,铸造缺陷大大减少,性能大幅提高,同时提高产品生产效率,大幅度降低产品成本。 The temperature field and composition field of the metal melt alloy treated by the device and method of the invention are very uniform, the microstructure of the formed blank and the parts are uniform and uniform, the composition distribution is uniform, the casting defects are greatly reduced, the performance is greatly improved, and the production efficiency is improved, and the production efficiency is greatly reduced. Product Cost.

Claims (25)

  1. 一种高剪切强电磁搅拌熔体处理的装置,其特征在于:该装置主要由坩埚、安装在坩埚内的芯棒、及安装在坩埚外围的电磁搅拌装置组成,所述的电磁搅拌装置包括水箱和放置在水箱中的电磁搅拌器;所述的坩埚的形状为半锥形或圆柱形,所述的芯棒形状上端为半锥形结构或圆柱形结构,下端为螺旋结构,芯棒中间为中空结构,中空部分的形状为半锥形或圆柱形;所述的芯棒与坩埚同轴。The utility model relates to a high shear strong electromagnetic stirring melt processing device, characterized in that the device is mainly composed of a crucible, a mandrel installed in the crucible, and an electromagnetic stirring device installed on the periphery of the crucible, wherein the electromagnetic stirring device comprises a water tank and a magnetic stirrer placed in the water tank; the shape of the crucible is semi-tapered or cylindrical, and the upper end of the mandrel has a semi-tapered structure or a cylindrical structure, and the lower end is a spiral structure, and the core rod is in the middle In the hollow structure, the shape of the hollow portion is semi-conical or cylindrical; the mandrel is coaxial with the crucible.
  2. 根据权利要求1所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的芯棒螺旋结构的任何一个螺纹的最外壁与坩埚内壁的垂直距离均相同。The apparatus for high shear strong electromagnetic stirring melt processing according to claim 1, wherein the outermost wall of any one of the threads of the mandrel spiral structure has the same vertical distance from the inner wall of the crucible.
  3. 根据权利要求2所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的芯棒半锥形结构或圆柱形结构的纵截面与坩埚纵截面形状相同,所述的半锥形结构或圆柱形结构的外壁上任一位置与坩埚内壁的垂直距离均相同。The apparatus for processing high-shear electromagnetic stirring melt according to claim 2, wherein the longitudinal cross-section of the semi-conical or cylindrical structure of the mandrel is the same as the shape of the longitudinal section, the half The vertical distance between any position on the outer wall of the tapered structure or the cylindrical structure is the same as the inner wall of the crucible.
  4. 根据权利要求3所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的芯棒中空部分的纵截面与坩埚纵截面形状相同,所述的芯棒内壁上任一位置与坩埚内壁的垂直距离均相同。The apparatus for processing high-shear electromagnetic stirring melt according to claim 3, wherein the longitudinal section of the hollow portion of the mandrel has the same shape as the longitudinal section, and any position on the inner wall of the mandrel is The vertical distance of the inner wall of the crucible is the same.
  5. 根据权利要求2所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的芯棒螺旋结构的任何一个螺纹的最外壁与坩埚内壁的最短垂直距离为5~50mm。The apparatus for high-impact strong electromagnetic stirring melt processing according to claim 2, wherein the outermost wall of any one of the threads of the mandrel spiral structure has a shortest vertical distance from the inner wall of the crucible of 5 to 50 mm.
  6. 根据权利要求3所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的芯棒半锥形结构或圆柱形结构的外壁上任一位置与坩埚内壁的最短垂直距离为10~150mm。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 3, wherein the shortest vertical distance between the position of the outer wall of the semi-conical structure or the cylindrical structure of the mandrel and the inner wall of the crucible is 10 ~150mm.
  7. 根据权利要求4所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的芯棒内壁上任一位置与坩埚内壁的最短垂直距离为15~155mm。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 4, wherein the shortest vertical distance between any position on the inner wall of the mandrel and the inner wall of the crucible is 15 to 155 mm.
  8. 根据权利要求5所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的螺纹高度为5~100mm,螺距为20~150mm。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 5, wherein said thread has a height of 5 to 100 mm and a pitch of 20 to 150 mm.
  9. 根据权利要求8所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的螺纹的横截面形状为等腰梯形或矩形。The apparatus for high shear strong electromagnetic stirring melt processing according to claim 8, wherein said thread has a cross-sectional shape of an isosceles trapezoid or a rectangle.
  10. 根据权利要求9所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的等腰梯形锐角度数为大于等于45°且小于90°。The apparatus for high-impact strong electromagnetic stirring melt processing according to claim 9, wherein the isosceles trapezoidal sharp angle number is 45° or more and less than 90°.
  11. 根据权利要求5所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的螺纹为单线螺纹、双线螺纹或多线螺纹。 The apparatus for high shear strong electromagnetic stirring melt processing according to claim 5, wherein the thread is a single thread, a double thread or a multi thread.
  12. 根据权利要求5所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的芯棒螺旋结构的长度为芯棒长度的五分之一至五分之四。The apparatus for high shear strong electromagnetic stirring melt processing according to claim 5, wherein said mandrel spiral structure has a length of from one fifth to four fifths of the length of the mandrel.
  13. 根据权利要求5所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的芯棒底部与坩埚底部之间的距离为5~100mm,顶部与熔体液面之间的距离为5~200mm。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 5, wherein the distance between the bottom of the mandrel and the bottom of the crucible is 5 to 100 mm, and between the top and the melt level. The distance is 5 to 200 mm.
  14. 根据权利要求4所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的坩埚的纵截面为等腰梯形或矩形。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 4, wherein the longitudinal section of the crucible is an isosceles trapezoid or a rectangle.
  15. 根据权利要求14所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的等腰梯形底角度数为大于等于60°且小于90°,或者大于90°且小于等于120°。The apparatus for processing high-shear electromagnetic stirring melt according to claim 14, wherein the number of the isosceles trapezoidal bottom angle is 60° or more and less than 90°, or more than 90° and less than or equal to 120. °.
  16. 根据权利要求13所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的坩埚底部半径为50~500mm,高度为50~1000mm。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 13, wherein said crucible bottom has a radius of 50 to 500 mm and a height of 50 to 1000 mm.
  17. 根据权利要求16所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的坩埚底部设有出料口。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 16, wherein the bottom of the crucible is provided with a discharge opening.
  18. 根据权利要求1所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的芯棒和坩埚的材质为奥氏体不锈钢、钛、钼、钴、铬、镍、铜、石墨、陶瓷或刚玉。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 1, wherein the core rod and the crucible are made of austenitic stainless steel, titanium, molybdenum, cobalt, chromium, nickel, copper, Graphite, ceramic or corundum.
  19. 根据权利要求1所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的水箱上板为屏蔽磁场的板材。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 1, wherein the upper plate of the water tank is a plate material for shielding a magnetic field.
  20. 根据权利要求1所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的电磁搅拌器的高度与芯棒下端螺旋部位高度相同。The apparatus for high shear strong electromagnetic stirring melt processing according to claim 1, wherein the height of the electromagnetic stirrer is the same as the height of the spiral portion at the lower end of the mandrel.
  21. 根据权利要求20所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的电磁搅拌器的搅拌线圈为三相多对极。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 20, wherein the stirring coil of the electromagnetic stirrer is a three-phase multi-pole.
  22. 根据权利要求21所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的电磁搅拌器的搅拌线圈为三相3、6或9对级。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 21, wherein the stirring coil of the electromagnetic stirrer is three-phase three, six or nine pairs.
  23. 根据权利要求22所述的高剪切强电磁搅拌熔体处理的装置,其特征在于:所述的电磁搅拌器的搅拌频率为低频、工频、中频或高频;搅拌电流为5A~500A。The apparatus for processing high shear strong electromagnetic stirring melt according to claim 22, wherein the stirring frequency of the electromagnetic stirrer is low frequency, power frequency, intermediate frequency or high frequency; and the stirring current is 5A to 500A.
  24. 一种高剪切强电磁搅拌熔体处理的方法,采用权利要求1-23中任一项所述的高剪切强电磁搅拌熔体处理的装置,包括如下步骤:首先将芯棒固定在坩埚内部,并将金属熔体注入到坩埚中,开动电磁搅拌器并在水箱中通入冷却循环水;熔体只在内部高剪切循环紊流扰动而表面不动,使整个熔体体积内温度和成分均匀分布;处理完成后,打开坩埚底部出料口,将处理后的熔体注入到成型设备中。A high shear strong electromagnetic stirring melt processing method, using the high shear strong electromagnetic stirring melt processing apparatus according to any one of claims 1 to 23, comprising the steps of: first fixing the mandrel to the crucible Internally, the metal melt is injected into the crucible, the electromagnetic stirrer is turned on and the cooling circulating water is introduced into the water tank; the melt is only disturbed by the internal high shear cycle turbulence and the surface is not moved, so that the entire melt volume temperature And the components are evenly distributed; after the treatment is completed, the bottom discharge port of the crucible is opened, and the treated melt is injected into the molding apparatus.
  25. 权利要求1-23中任一项所述的高剪切强电磁搅拌熔体处理的装置在处理铝 合金、镁合金、铜合金、锌合金或钛合金熔体及其颗粒增强的金属基复合材料中的应用。 The apparatus for processing high shear strong electromagnetic stirring melt according to any one of claims 1 to 23 for treating aluminum Use in alloys, magnesium alloys, copper alloys, zinc alloys or titanium alloy melts and their particle-reinforced metal matrix composites.
PCT/CN2016/077228 2015-12-29 2016-03-24 Device and method for treating a melt with high shear and strong electromagnetic stirring WO2017113520A1 (en)

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CN201511009010.2 2015-12-29
CN201521116604.9 2015-12-29
CN201521116604.9U CN205237028U (en) 2015-12-29 2015-12-29 Device that strong electromagnetic stirring fuse -element of high shear was handled

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