WO2016204355A1 - Apparatus for torrefaction of biomass and removal of foreign materials - Google Patents

Apparatus for torrefaction of biomass and removal of foreign materials Download PDF

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Publication number
WO2016204355A1
WO2016204355A1 PCT/KR2015/011976 KR2015011976W WO2016204355A1 WO 2016204355 A1 WO2016204355 A1 WO 2016204355A1 KR 2015011976 W KR2015011976 W KR 2015011976W WO 2016204355 A1 WO2016204355 A1 WO 2016204355A1
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Prior art keywords
biomass
combustion
foreign matter
semi
exhaust gas
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PCT/KR2015/011976
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French (fr)
Korean (ko)
Inventor
채태영
문태영
최석천
이재욱
양원
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한국생산기술연구원
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Priority to CN201580021768.XA priority Critical patent/CN106488969B/en
Publication of WO2016204355A1 publication Critical patent/WO2016204355A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B04CENTRIFUGAL APPARATUS OR MACHINES FOR CARRYING-OUT PHYSICAL OR CHEMICAL PROCESSES
    • B04CAPPARATUS USING FREE VORTEX FLOW, e.g. CYCLONES
    • B04C5/00Apparatus in which the axial direction of the vortex is reversed
    • B04C5/14Construction of the underflow ducting; Apex constructions; Discharge arrangements ; discharge through sidewall provided with a few slits or perforations
    • B04C5/185Dust collectors
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/447Carbonized vegetable substances, e.g. charcoal, or produced by hydrothermal carbonization of biomass
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K17/00Using steam or condensate extracted or exhausted from steam engine plant
    • F01K17/06Returning energy of steam, in exchanged form, to process, e.g. use of exhaust steam for drying solid fuel or plant
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/04Organic compounds
    • C10L2200/0461Fractions defined by their origin
    • C10L2200/0469Renewables or materials of biological origin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/12Heat utilisation in combustion or incineration of waste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation

Definitions

  • the present invention relates to pulverized coal power generation, and more specifically, to remove foreign substances in biomass used in coal-fired power plants and simultaneously perform carbonization and semi-carbonization of biomass. Relates to a removal device.
  • the pulverized coal power generation system is an important commercial facility that accounts for about half of the domestic and foreign electricity generation. Recently, as the use of renewable energy has become an important issue, many mixed technologies for mixing and burning renewable fuel waste or biomass with existing coal have been commercially applied.
  • a key part of the commercialization of biomass blend technology is the stable supply and demand of biomass fuels. If it is possible to supply various kinds of biomass at high quality at low cost and provide stable supply, it will be much easier to increase the proportion of renewable energy by applying it to existing boilers.
  • the biomass fuel of high quality In order to apply a solid biomass to a coal fired boiler, the biomass fuel of high quality must also come out as a solid phase.
  • a semi-carbonization (torrefaction) process is used. The process mainly aims at minimizing the loss of flammable volatiles through pyrolysis at low temperatures (about 300 ° C) while increasing fuel fineness and energy density.
  • hydrophilic biomass fuel is made hydrophobic so that the moisture concentration does not increase even during long-term storage of the fuel.
  • Prior art 1 is a raw material input unit; Combustion chamber provided with a porous disc and a curved paddle at the bottom; A separation chamber configured to receive ash from the combustion chamber to generate cracked gas and to discharge the generated cracked gas and ash to the outside; And an ash discharge portion for compressing the ash by the screw in the direction of the discharge port and withdrawing the ash. Accordingly, the foreign substances contained in the raw materials are not stagnant and are all discharged, thereby reducing costs and increasing profitability.
  • Prior art 2 is a technique of carbonizing wood-based biomass using the exhaust gas of an incinerator and then removing the foreign matter, heating the biomass with the exhaust gas, but carbonizing the biomass, and separating the biomass and the foreign matter is wind-powered. It is removed by a classification device such as gravity, or centrifugal. Accordingly, the effect of easily separating and removing foreign substances such as metal pieces stuck to building wastes and the like is expected.
  • An object of the present invention for improving the conventional problems as described above, the semi-carbonization and debris removal device of the biomass for producing a high quality biomass fuel with high foreign matter is removed from the mixed biomass of the foreign material.
  • the present invention provides an apparatus for fueling a biomass to be treated with combustion exhaust gas of a heat source, comprising: a combustion chamber inducing combustion by introducing combustion exhaust gas corresponding to an input amount of the biomass; And a cyclone installed downstream of the combustion chamber to collect semi-carbonized biomass fuel and to separate combustible exhaust gas.
  • the combustion chamber is characterized in that it comprises a distribution plate for injecting the incoming combustion exhaust gas through a plurality of nozzles.
  • the combustion chamber is characterized in that it further comprises a sparger to separate the biomass and foreign matter by the density difference.
  • the combustion chamber is characterized in that it is divided into a primary combustion section having an inlet and a secondary combustion section having a circulation port.
  • the secondary combustion unit is characterized in that it is connected to pass the separated foreign matter to the circulation port through the re-separation.
  • the secondary combustion unit is characterized in that it is connected to supply the combustion flue gas intermittently to a plurality of points.
  • the secondary combustion unit is characterized in that the specification of the dispersion plate is applied differently to separate the biomass at a slower speed than the primary combustion unit.
  • FIG. 1 is a schematic view showing the main parts of a device according to the present invention.
  • Figure 2 is a schematic view showing the separation plate according to the present invention
  • FIG. 3 is a block diagram showing main parts of a device according to a modification of the present invention.
  • the present invention proposes an apparatus for fueling a biomass to be treated with combustion exhaust gas of a heat source.
  • the heat source is targeted to the boiler 10 of the coal-fired power plant, but is not necessarily limited thereto.
  • the boiler 10 performs combustion using fuel and air and discharges combustion exhaust gas to the exhaust discharge pipe 15 through a fan or a blower.
  • the biomass to be treated is another fuel of the boiler 10, and is deposited for a long time, and a lot of foreign substances including soil on the site are mixed.
  • the combustion chamber 20 induces combustion by introducing combustion exhaust gas corresponding to the input amount of the biomass.
  • the combustion chamber 20 has a tubular structure having a wind box at the bottom, and has an inlet 21 at one side and an outlet 23 at the bottom.
  • Combustion exhaust gas coming from the boiler 10 at 300 ⁇ 500 °C enters the wind box of the combustion chamber 20 through the exhaust discharge pipe (15).
  • biomass sorting and semi-carbonization may occur simultaneously in the combustion chamber 20.
  • the combustion chamber 20 is characterized by having a distribution plate 25 for injecting the incoming combustion exhaust gas through a plurality of nozzles.
  • the distribution plate 25 has a plurality of nozzles and is installed above the position connected to the exhaust discharge pipe 15.
  • the biomass containing the foreign matter flowing into the inlet 21 shows a low density in the flow of the fluid. Scattered upwards, foreign matter of high density falls to the lower side and is collected in the discharge port (23).
  • Dispersion plate 25 is provided with a through groove so that foreign matter falls down well. 2 illustrates a state in which a plurality of through grooves are formed concentrically on the distribution plate 25.
  • the combustion chamber 20 is characterized in that it further comprises a sparger 26 to separate the biomass and the foreign matter by the density difference.
  • a sparger 26 to separate the biomass and the foreign matter by the density difference.
  • the sparger 26 is installed in the combustion chamber 20 to inject high-temperature combustion flue gas, separation of the biomass and the foreign matter may be more easily caused.
  • 2 illustrates a state in which a plurality of spargers 26 are installed concentrically on the distribution plate 25. The amount of dispersion by the sparger 26 is adjusted to an appropriate range according to physical properties such as density and particle size of the separated foreign matter.
  • a cyclone 40 is installed downstream of the combustion chamber 20 to collect semi-carbonized biomass fuel and to separate flammable exhaust gas.
  • the biomass scattered from the combustion chamber 20 is placed at a high temperature condition of 300 to 400 ° C.
  • semi-carbonization proceeds to increase energy density and make powder fine.
  • the semi-carbonized biomass falls from the cyclone 40 connected to the inlet pipe 42 on the upper side of the combustion chamber 20 and is collected by the fuel outlet 45.
  • the combustible flue gas produced in this process is a gas above the condensation temperature at which volatile components are partially mixed and is then transferred to be used as fuel of the boiler 10 through the exhaust inlet pipe 12.
  • the concentration of NOx which is an air pollutant, may be reduced due to the exhaust gas recirculation effect in the boiler 10.
  • the combustion chamber 20 is characterized in that it is divided into a primary combustion unit 31 having an inlet 21 and a secondary combustion unit 32 having a circulation port 33.
  • the combustion chamber 20 exemplifies a state composed of a primary and a secondary together with each windbox.
  • the primary combustion unit 31 and the secondary combustion unit 32 may be merged so as to be separated from the upper side of the combustion chamber 20. In either case, screening of biomass and foreign material can be done more precisely, depending on the density.
  • the controller 50 controls the flow rate, temperature, and the like entering the primary combustion unit 31 and the secondary combustion unit 32.
  • the secondary combustion unit 32 is characterized in that it is connected to pass through the re-disassembly by transferring the separated foreign matter to the circulation port (33).
  • the foreign matter falling below the windbox can be taken out again by opening the valve 53 at a predetermined cycle. If necessary, the foreign matter enters the secondary combustion unit 32 through the circulation port 33 and removes the remaining biomass. It is processed to extract more.
  • Secondary combustion unit 32 also provides a suitable amount of heat required for biomass semi-carbonization by operating a high temperature in the range of 300 ⁇ 400 °C.
  • the secondary combustion unit 32 is characterized in that it is connected to supply the combustion flue gas intermittently to a plurality of points.
  • a plurality of auxiliary pipes 35 branched from the exhaust discharge pipe 15 are connected to the lower side and the upper side of the distribution plate 25 via respective valves 55.
  • the controller 50 opens and closes the valve 55 to control the combustion exhaust gas input amount corresponding to the biomass input amount.
  • the controller 50 is configured to input a signal such as a temperature sensor, a flow sensor.
  • the secondary combustion unit 32 is characterized in that the different specification of the distribution plate 25 to separate the biomass at a slower speed than the primary combustion unit 31.
  • the dispersion plate 25 applied to the primary combustion unit 31 and the secondary combustion unit 32 maintains the same as in FIG.
  • the sparger 26 installed on the distribution plate 25 includes a plurality of nozzles, and the space between the spargers 26 is a through groove through which foreign substances can fall.
  • the shape of the dispersion plate 25 and the sparger 26 may take the form of a square rather than a circle depending on the cross-sectional shape of the combustion chamber 20.
  • the dispersion plate 25 and the sparger 26 of the secondary combustion unit 32 reduce the installation interval and the size of the nozzle to slow the reaction. Delaying the reaction rate of the secondary combustion unit 32 increases discrimination power, which is advantageous for semi-carbonization of biomass and separation of foreign substances.
  • the present invention can be applied to the apparatus for semi-carbonization and debris removal of biomass that effectively removes debris from filthy biomass mixed with debris and produces high quality biomass fuel with high energy density. have.

Abstract

The present invention relates to an apparatus for changing, into fuel, biomass to be treated, by using combustion exhaust gas of a heat source, the apparatus comprising: a combustion chamber (20) for causing combustion by allowing combustion exhaust gas, which corresponds to the injection amount of the biomass, to flow therein; and a cyclone (40) provided in the downstream of the combustion chamber (20) so as to collect biomass fuel having undergone torrefaction, and simultaneously separating inflammable exhaust gas. Therefore, there is an effect of increasing the applicability of new renewable energy by removing foreign materials from biomass having a large amount of foreign materials mixed therein and stored outdoors, and by producing high-quality biomass fuel having a high energy density.

Description

바이오매스의 반탄화 및 이물질 제거 장치Semi-Carbonization and Foreign Material Removal Device of Biomass
본 발명은 미분탄 발전에 관한 것으로서, 보다 구체적으로는 석탄화력발전소에서 사용되는 바이오매스 내 이물질들을 걸러내는 동시에 바이오매스의 반탄화를 함께 수행하여 바이오매스의 품질을 향상하는 바이오매스의 반탄화 및 이물질 제거 장치에 관한 것이다.The present invention relates to pulverized coal power generation, and more specifically, to remove foreign substances in biomass used in coal-fired power plants and simultaneously perform carbonization and semi-carbonization of biomass. Relates to a removal device.
미분탄 발전 시스템은 국내외 전력 생산의 절반 가량을 차지하고 있는 중요한 상업용 설비이다. 최근 들어 신재생 에너지의 사용 확대가 중요한 이슈가 되면서, 신재생 연료인 폐기물이나 바이오매스를 기존 석탄에 혼합하여 연소하는 혼소 기술이 상업적으로 많이 적용되고 있다.The pulverized coal power generation system is an important commercial facility that accounts for about half of the domestic and foreign electricity generation. Recently, as the use of renewable energy has become an important issue, many mixed technologies for mixing and burning renewable fuel waste or biomass with existing coal have been commercially applied.
바이오매스 혼소 기술의 상업화에 있어 가장 핵심적인 부분은 바이오매스 연료의 안정적인 수급이라고 할 수 있다. 다양한 종류의 바이오매스를 저비용으로 고품질화하여 안정적으로 수급하는 것이 가능하다면 이를 기존의 보일러에 적용하여 신재생 에너지의 비중을 높이는 것이 훨씬 수월해지게 된다. A key part of the commercialization of biomass blend technology is the stable supply and demand of biomass fuels. If it is possible to supply various kinds of biomass at high quality at low cost and provide stable supply, it will be much easier to increase the proportion of renewable energy by applying it to existing boilers.
고체상의 바이오매스를 석탄화력 보일러 등에 적용하기 위해서는 최종적으로 고품질화되는 바이오매스 연료 역시 고체상으로 나와야 된다. 바이오매스의 에너지 밀도를 높이고 미분도 등을 높여 핸들링이 용이하게 하기 위해서 많이 사용되는 방법은 반탄화(torrefaction) 공정이다. 해당 공정은 기본적으로 저온 (약 300℃) 에서의 열분해를 통하여 가연분인 휘발분 손실은 최소화하되 연료의 미분도 및 에너지 밀도를 높이는 것을 주요 내용으로 하고 있다. 또한 친수성인 바이오매스의 연료를 소수성으로 만듦으로서 연료의 장기간 보관에도 수분 농도가 높아지지 않게 하는 특징도 가지고 있다.In order to apply a solid biomass to a coal fired boiler, the biomass fuel of high quality must also come out as a solid phase. In order to increase the energy density of the biomass and to increase the degree of fineness and to facilitate the handling, a semi-carbonization (torrefaction) process is used. The process mainly aims at minimizing the loss of flammable volatiles through pyrolysis at low temperatures (about 300 ° C) while increasing fuel fineness and energy density. In addition, hydrophilic biomass fuel is made hydrophobic so that the moisture concentration does not increase even during long-term storage of the fuel.
이와 동시에 바이오매스 수급을 위해 중요한 이슈로, 현재 러시아 등에서 많은 양이 폐기물 형태로 야적되어 있는 상황을 고려한 바이오매스의 활용성 증대에 대한 것이다. 야적 현장의 흙이 연료에 많이 섞여 있는 경우 수송비를 높임과 동시에 연료로 바로 사용할 수가 없다는 단점을 가지고 있다.At the same time, it is an important issue for the supply and demand of biomass, which is to increase the utilization of biomass in consideration of the situation in which a large amount of waste is deposited in Russia. If the soil of the field is mixed with a lot of fuel, it has a disadvantage that it can not be used immediately as fuel while increasing transportation costs.
이와 관련되는 선행특허문헌으로서 한국 등록특허공보 제0995134호(선행문헌 1), 일본 공개특허공보 제2007-091890호(선행문헌 2) 등이 알려져 있다.As related prior patent documents, Korean Patent Publication No. 0995134 (Prior Document 1), Japanese Laid-Open Patent Publication No. 2007-091890 (Prior Document 2), and the like are known.
선행문헌 1은 원료 투입부; 하단에 다공형 원판 및 만곡패들이 구비된 연소실; 상기 연소실로부터 애쉬를 공급받아서 분해가스를 생성하고, 생성된 분해 가스와 애쉬를 외부로 배출하는 통로를 구비하는 분리 챔버; 및 배출구의 방향으로 스크류에 의해 애쉬를 압축하여 인출하는 애쉬 배출부를 포함한다. 이에 따라, 원료 속에 포함되는 이물질이 정체되지 않고 모두 배출되어 원가가 절감되고 수익성이 증대되는 효과를 기대한다.Prior art 1 is a raw material input unit; Combustion chamber provided with a porous disc and a curved paddle at the bottom; A separation chamber configured to receive ash from the combustion chamber to generate cracked gas and to discharge the generated cracked gas and ash to the outside; And an ash discharge portion for compressing the ash by the screw in the direction of the discharge port and withdrawing the ash. Accordingly, the foreign substances contained in the raw materials are not stagnant and are all discharged, thereby reducing costs and increasing profitability.
선행문헌 2는 목질계 바이오메스를 소각로의 배기가스를 이용하여 탄화한 다음에 이물질을 제거하는 기술로서, 바이오매스를 배기가스로 가열하나 바이오매스를 탄화하며, 바이오매스와 이물질의 분리는 풍력식, 중력식, 또는 원심식 등의 분급 장치에 의해 제거하고 있다. 이에 따라, 건축폐목 등에 고착된 금속편과 같은 이물질을 용이하게 분리하여 제거하는 효과를 기대한다.Prior art 2 is a technique of carbonizing wood-based biomass using the exhaust gas of an incinerator and then removing the foreign matter, heating the biomass with the exhaust gas, but carbonizing the biomass, and separating the biomass and the foreign matter is wind-powered. It is removed by a classification device such as gravity, or centrifugal. Accordingly, the effect of easily separating and removing foreign substances such as metal pieces stuck to building wastes and the like is expected.
그러나, 상기한 선행문헌에 의하면 바이오매스를 탄화하는 과정에서 이물질의 배출과 분리를 요지로 하므로 석탄화력발전 등에 혼소용 연료로 사용되는 바이오매스의 반탄화(torrefaction) 공정에 적용하기에 한계를 보인다.However, according to the above-mentioned prior document, since the discharge and separation of foreign matters are required in the process of carbonizing the biomass, there is a limitation in applying it to the torrefaction process of biomass used as a mixed fuel for coal-fired power generation. .
상기와 같은 종래의 문제점들을 개선하기 위한 본 발명의 목적은, 이물질이 많이 섞인 야적된 바이오매스로부터 이물질들이 제거되고 에너지 밀도가 높은 고품질 바이오매스 연료를 생산하기 위한 바이오매스의 반탄화 및 이물질 제거 장치를 제공하는 데 있다.An object of the present invention for improving the conventional problems as described above, the semi-carbonization and debris removal device of the biomass for producing a high quality biomass fuel with high foreign matter is removed from the mixed biomass of the foreign material. To provide.
상기 목적을 달성하기 위하여, 본 발명은 열원의 연소 배가스로 처리 대상의 바이오매스를 연료화하는 장치에 있어서: 상기 바이오매스의 투입량에 대응하는 연소 배가스를 유입하여 연소를 유발하는 연소챔버; 및 상기 연소챔버의 하류측에 설치되어 반탄화 바이오매스 연료를 포집하는 동시에 가연성 배가스를 분리하는 사이클론;을 포함하여 이루어지는 것을 특징으로 한다.In order to achieve the above object, the present invention provides an apparatus for fueling a biomass to be treated with combustion exhaust gas of a heat source, comprising: a combustion chamber inducing combustion by introducing combustion exhaust gas corresponding to an input amount of the biomass; And a cyclone installed downstream of the combustion chamber to collect semi-carbonized biomass fuel and to separate combustible exhaust gas.
본 발명의 세부 구성으로서, 상기 연소챔버는 유입되는 연소 배가스를 다수의 노즐을 통해 분사하는 분산판을 구비하는 것을 특징으로 한다.As a detailed configuration of the present invention, the combustion chamber is characterized in that it comprises a distribution plate for injecting the incoming combustion exhaust gas through a plurality of nozzles.
본 발명의 세부 구성으로서, 상기 연소챔버는 바이오매스와 이물질을 밀도차로 분리하도록 스파져를 더 구비하는 것을 특징으로 한다.As a detailed configuration of the present invention, the combustion chamber is characterized in that it further comprises a sparger to separate the biomass and foreign matter by the density difference.
본 발명의 변형예로서, 상기 연소챔버는 투입구를 지닌 1차연소부와 순환구를 지닌 2차연소부로 구획되는 것을 특징으로 한다.As a variant of the invention, the combustion chamber is characterized in that it is divided into a primary combustion section having an inlet and a secondary combustion section having a circulation port.
본 발명의 세부 구성으로서, 상기 2차연소부는 분리된 이물질을 순환구로 이송하여 재분리를 거치도록 연결되는 것을 특징으로 한다.As a detailed configuration of the present invention, the secondary combustion unit is characterized in that it is connected to pass the separated foreign matter to the circulation port through the re-separation.
본 발명의 세부 구성으로서, 상기 2차연소부는 다수의 지점에 단속적으로 연소 배가스를 공급하도록 연결되는 것을 특징으로 한다.As a detailed configuration of the present invention, the secondary combustion unit is characterized in that it is connected to supply the combustion flue gas intermittently to a plurality of points.
본 발명의 세부 구성으로서, 상기 2차연소부는 1차연소부에 비하여 느린 속도로 바이오매스를 분리하도록 분산판의 규격을 다르게 적용하는 것을 특징으로 한다.As a detailed configuration of the present invention, the secondary combustion unit is characterized in that the specification of the dispersion plate is applied differently to separate the biomass at a slower speed than the primary combustion unit.
이상과 같이 본 발명에 의하면, 이물질이 많이 섞인 야적된 바이오매스로부터 이물질들이 제거되고 에너지 밀도가 높은 고품질 바이오매스 연료를 생산하여 신재생 에너지의 활용성을 증대하는 효과가 있다.As described above, according to the present invention, foreign substances are removed from the piled-up biomass mixed with foreign substances, thereby producing high quality biomass fuel with high energy density, thereby increasing the utility of renewable energy.
도 1은 본 발명에 따른 장치의 주요부를 개략적으로 나타내는 구성도1 is a schematic view showing the main parts of a device according to the present invention;
도 2는 본 발명에 따른 분산판을 분리하여 나타내는 구성도Figure 2 is a schematic view showing the separation plate according to the present invention
도 3은 본 발명의 변형예에 따른 장치의 주요부를 나타내는 구성도3 is a block diagram showing main parts of a device according to a modification of the present invention;
이하, 첨부된 도면에 의거하여 본 발명의 실시예를 상세하게 설명하면 다음과 같다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.
본 발명은 열원의 연소 배가스로 처리 대상의 바이오매스를 연료화하는 장치에 관하여 제안한다. 열원은 석탄화력발전소의 보일러(10)를 대상으로 하지만 반드시 이에 국한되는 것은 아니다. 통상 보일러(10)는 연료와 공기를 사용하여 연소를 수행하고 연소 배가스를 팬 또는 블로워를 통하여 배기배출관(15)으로 배출한다. 처리 대상의 바이오매스는 보일러(10)의 또 다른 연료로서 장기간 야적되어 현장의 흙을 비롯한 이물질이 많이 혼재된 상태이다.The present invention proposes an apparatus for fueling a biomass to be treated with combustion exhaust gas of a heat source. The heat source is targeted to the boiler 10 of the coal-fired power plant, but is not necessarily limited thereto. Typically, the boiler 10 performs combustion using fuel and air and discharges combustion exhaust gas to the exhaust discharge pipe 15 through a fan or a blower. The biomass to be treated is another fuel of the boiler 10, and is deposited for a long time, and a lot of foreign substances including soil on the site are mixed.
본 발명에 따르면 연소챔버(20)가 상기 바이오매스의 투입량에 대응하는 연소 배가스를 유입하여 연소를 유발하는 구조이다. 연소챔버(20)는 하단에 윈드박스를 지닌 통형 구조로서 일측면에 투입구(21)를 지니고 하단에 배출구(23)를 지닌다. 보일러(10)에서 300~500℃로 나오는 연소 배가스는 배기배출관(15)을 통하여 연소챔버(20)의 윈드박스로 들어간다. 이에 후술하는 것처럼 연소챔버(20)에서 바이오매스 선별과 반탄화가 동시에 일어날 수 있다.According to the present invention, the combustion chamber 20 induces combustion by introducing combustion exhaust gas corresponding to the input amount of the biomass. The combustion chamber 20 has a tubular structure having a wind box at the bottom, and has an inlet 21 at one side and an outlet 23 at the bottom. Combustion exhaust gas coming from the boiler 10 at 300 ~ 500 ℃ enters the wind box of the combustion chamber 20 through the exhaust discharge pipe (15). As described later, biomass sorting and semi-carbonization may occur simultaneously in the combustion chamber 20.
본 발명의 세부 구성으로서, 상기 연소챔버(20)는 유입되는 연소 배가스를 다수의 노즐을 통해 분사하는 분산판(25)을 구비하는 것을 특징으로 한다. 분산판(25)은 다수의 노즐을 지니는 구조로서 배기배출관(15)과 연결되는 위치보다 상측으로 설치된다. 윈드박스에 유입된 연소 배가스가 분산판(25)을 통하여 챔버의 상측으로 빠른 속도로 유입되면, 투입구(21)로 유입되는 이물질이 포함된 바이오매스가 이러한 유체의 흐름에서 낮은 밀도를 보임에 따라 상측으로 비산되고, 고밀도의 이물질은 하측으로 낙하되어 배출구(23)로 수집된다. 분산판(25)은 이물질이 아래로 잘 떨어질 수 있도록 관통홈을 구비한다. 도 2는 분산판(25)에 동심상으로 다수의 관통홈이 형성된 상태를 예시한다.As a detailed configuration of the present invention, the combustion chamber 20 is characterized by having a distribution plate 25 for injecting the incoming combustion exhaust gas through a plurality of nozzles. The distribution plate 25 has a plurality of nozzles and is installed above the position connected to the exhaust discharge pipe 15. When the combustion flue gas flowing into the windbox flows into the upper portion of the chamber through the dispersion plate 25 at high speed, the biomass containing the foreign matter flowing into the inlet 21 shows a low density in the flow of the fluid. Scattered upwards, foreign matter of high density falls to the lower side and is collected in the discharge port (23). Dispersion plate 25 is provided with a through groove so that foreign matter falls down well. 2 illustrates a state in which a plurality of through grooves are formed concentrically on the distribution plate 25.
본 발명의 세부 구성으로서, 상기 연소챔버(20)는 바이오매스와 이물질을 밀도차로 분리하도록 스파져(26)를 더 구비하는 것을 특징으로 한다. 연소챔버(20)에 스파져(26)를 설치하여 고온의 연소 배가스를 분사하면 바이오매스와 이물질의 밀도차에 의한 분리를 더 용이하게 유발할 수 있다. 도 2는 분산판(25) 상에 다수의 스파져(26)를 동심으로 설치한 상태를 예시한다. 분리된 이물질의 밀도, 입도 등의 물성에 따라 스파져(26)에 의한 분산량을 적절한 범위로 조절한다.As a detailed configuration of the present invention, the combustion chamber 20 is characterized in that it further comprises a sparger 26 to separate the biomass and the foreign matter by the density difference. When the sparger 26 is installed in the combustion chamber 20 to inject high-temperature combustion flue gas, separation of the biomass and the foreign matter may be more easily caused. 2 illustrates a state in which a plurality of spargers 26 are installed concentrically on the distribution plate 25. The amount of dispersion by the sparger 26 is adjusted to an appropriate range according to physical properties such as density and particle size of the separated foreign matter.
또, 본 발명에 따르면 사이클론(40)이 상기 연소챔버(20)의 하류측에 설치되어 반탄화 바이오매스 연료를 포집하는 동시에 가연성 배가스를 분리하는 구조이다. 연소챔버(20)에서 비산되는 바이오매스는 300~400℃의 고온 조건에 놓임에 따라 반탄화가 진행되어 에너지 밀도가 높아지고 미분이 쉬워지는 상태로 된다. 반탄화가 된 바이오매스는 연소챔버(20)의 상측에 유입관(42)으로 연결된 사이클론(40)에서 낙하되어 연료배출구(45)로 포집된다. 이 과정에서 생성되는 가연성 배가스는 휘발분이 일부 섞인 응축온도 이상의 가스로서 다시 배기유입관(12)을 통하여 보일러(10)의 연료로 사용되도록 이송된다. 이 경우, 보일러(10)에서 배가스 재순환 효과 등으로 인해 대기오염 물질인 NOx 농도가 감소될 수 있다.In addition, according to the present invention, a cyclone 40 is installed downstream of the combustion chamber 20 to collect semi-carbonized biomass fuel and to separate flammable exhaust gas. As the biomass scattered from the combustion chamber 20 is placed at a high temperature condition of 300 to 400 ° C., semi-carbonization proceeds to increase energy density and make powder fine. The semi-carbonized biomass falls from the cyclone 40 connected to the inlet pipe 42 on the upper side of the combustion chamber 20 and is collected by the fuel outlet 45. The combustible flue gas produced in this process is a gas above the condensation temperature at which volatile components are partially mixed and is then transferred to be used as fuel of the boiler 10 through the exhaust inlet pipe 12. In this case, the concentration of NOx, which is an air pollutant, may be reduced due to the exhaust gas recirculation effect in the boiler 10.
본 발명의 변형예로서, 상기 연소챔버(20)는 투입구(21)를 지닌 1차연소부(31)와 순환구(33)를 지닌 2차연소부(32)로 구획되는 것을 특징으로 한다. 도 3을 참조하면 연소챔버(20)는 각각의 윈드박스와 더불어 1차와 2차로 구성된 상태를 예시한다. 1차연소부(31)와 2차연소부(32)는 연소챔버(20)의 상측에서 구분이 없어지도록 병합될 수 있다. 어느 경우에나 바이오매스와 이물질의 선별을 밀도에 따라 좀 더 정밀하게 수행할 수 있다. 후술하는 것처럼 제어기(50)가 1차연소부(31)와 2차연소부(32) 쪽에 들어가는 유량, 온도 등을 제어한다.As a variant of the invention, the combustion chamber 20 is characterized in that it is divided into a primary combustion unit 31 having an inlet 21 and a secondary combustion unit 32 having a circulation port 33. Referring to FIG. 3, the combustion chamber 20 exemplifies a state composed of a primary and a secondary together with each windbox. The primary combustion unit 31 and the secondary combustion unit 32 may be merged so as to be separated from the upper side of the combustion chamber 20. In either case, screening of biomass and foreign material can be done more precisely, depending on the density. As will be described later, the controller 50 controls the flow rate, temperature, and the like entering the primary combustion unit 31 and the secondary combustion unit 32.
본 발명의 세부 구성으로서, 상기 2차연소부(32)는 분리된 이물질을 순환구(33)로 이송하여 재분리를 거치도록 연결되는 것을 특징으로 한다. 윈드박스 아래로 떨어진 이물질은 정해진 주기에 따라 밸브(53)를 개방하여 다시 인출할 수 있는데, 필요시 해당 이물질이 다시 순환구(33)를 통해 2차연소부(32)로 들어가 남아있는 바이오매스를 더 빼내도록 처리된다. 2차연소부(32) 역시 300~400℃ 범위의 고온을 작용하여 바이오매스 반탄화에 필요한 적절한 열량을 제공한다.As a detailed configuration of the present invention, the secondary combustion unit 32 is characterized in that it is connected to pass through the re-disassembly by transferring the separated foreign matter to the circulation port (33). The foreign matter falling below the windbox can be taken out again by opening the valve 53 at a predetermined cycle. If necessary, the foreign matter enters the secondary combustion unit 32 through the circulation port 33 and removes the remaining biomass. It is processed to extract more. Secondary combustion unit 32 also provides a suitable amount of heat required for biomass semi-carbonization by operating a high temperature in the range of 300 ~ 400 ℃.
본 발명의 세부 구성으로서, 상기 2차연소부(32)는 다수의 지점에 단속적으로 연소 배가스를 공급하도록 연결되는 것을 특징으로 한다. 배기배출관(15)에서 분기되는 다수의 보조관(35)이 각각의 밸브(55)를 개재하여 분산판(25)의 하측과 상측으로 연결된다. 제어기(50)는 밸브(55)를 개폐하여 바이오매스 투입량에 대응한 연소 배가스 투입량을 제어한다. 이를 위해 제어기(50)가 온도센서, 유량센서 등의 신호를 입력하도록 구성한다.As a detailed configuration of the present invention, the secondary combustion unit 32 is characterized in that it is connected to supply the combustion flue gas intermittently to a plurality of points. A plurality of auxiliary pipes 35 branched from the exhaust discharge pipe 15 are connected to the lower side and the upper side of the distribution plate 25 via respective valves 55. The controller 50 opens and closes the valve 55 to control the combustion exhaust gas input amount corresponding to the biomass input amount. To this end, the controller 50 is configured to input a signal such as a temperature sensor, a flow sensor.
본 발명의 세부 구성으로서, 상기 2차연소부(32)는 1차연소부(31)에 비하여 느린 속도로 바이오매스를 분리하도록 분산판(25)의 규격을 다르게 적용하는 것을 특징으로 한다. 1차연소부(31)와 2차연소부(32)에 적용되는 분산판(25)은 전술한 도 2와 동일성을 유지한다. 분산판(25)에 설치되는 스파져(26)는 다수의 노즐을 구비하고, 스파져(26) 사이의 공간은 이물질들이 떨어질 수 있는 관통홈이다. 분산판(25)과 스파져(26)의 모양은 연소챔버(20)의 단면 모양에 따라 원형이 아닌 사각 형태를 띨 수도 있다. As a detailed configuration of the present invention, the secondary combustion unit 32 is characterized in that the different specification of the distribution plate 25 to separate the biomass at a slower speed than the primary combustion unit 31. The dispersion plate 25 applied to the primary combustion unit 31 and the secondary combustion unit 32 maintains the same as in FIG. The sparger 26 installed on the distribution plate 25 includes a plurality of nozzles, and the space between the spargers 26 is a through groove through which foreign substances can fall. The shape of the dispersion plate 25 and the sparger 26 may take the form of a square rather than a circle depending on the cross-sectional shape of the combustion chamber 20.
다만, 2차연소부(32)의 분산판(25)과 스파져(26)는 설치 간격과 노즐의 크기를 축소하여 반응을 늦춘다. 2차연소부(32)의 반응속도를 지연하면 변별력이 증대되어 바이오매스의 반탄화와 이물질 분리에 유리하다.However, the dispersion plate 25 and the sparger 26 of the secondary combustion unit 32 reduce the installation interval and the size of the nozzle to slow the reaction. Delaying the reaction rate of the secondary combustion unit 32 increases discrimination power, which is advantageous for semi-carbonization of biomass and separation of foreign substances.
본 발명은 기재된 실시예에 한정되는 것은 아니고, 본 발명의 사상 및 범위를 벗어나지 않고 다양하게 수정 및 변형할 수 있음은 이 기술의 분야에서 통상의 지식을 가진 자에게 자명하다. 따라서 그러한 변형예 또는 수정예들은 본 발명의 특허청구범위에 속한다 해야 할 것이다.It is apparent to those skilled in the art that the present invention is not limited to the described embodiments, and that various modifications and variations can be made without departing from the spirit and scope of the present invention. Therefore, such modifications or variations will have to belong to the claims of the present invention.
본 발명은 이물질이 많이 섞인 야적된 바이오매스로부터 이물질들이 제거되고 에너지 밀도가 높은 고품질 바이오매스 연료를 생산하여 신재생 에너지의 활용성을 효과적으로 증대시키는 바이오매스의 반탄화 및 이물질 제거 장치에 적용할 수 있다.The present invention can be applied to the apparatus for semi-carbonization and debris removal of biomass that effectively removes debris from filthy biomass mixed with debris and produces high quality biomass fuel with high energy density. have.

Claims (7)

  1. 열원의 연소 배가스로 처리 대상의 바이오매스를 연료화하는 장치에 있어서:In an apparatus for fueling a biomass to be treated with combustion exhaust gas of a heat source:
    상기 바이오매스의 투입량에 대응하는 연소 배가스를 유입하여 연소를 유발하는 연소챔버(20); 및A combustion chamber 20 inducing combustion by introducing combustion exhaust gas corresponding to the input amount of the biomass; And
    상기 연소챔버(20)의 하류측에 설치되어 반탄화 바이오매스 연료를 포집하는 동시에 가연성 배가스를 분리하는 사이클론(40);을 포함하여 이루어지는 것을 특징으로 하는 바이오매스의 반탄화 및 이물질 제거 장치.And a cyclone (40) installed on the downstream side of the combustion chamber (20) to capture semi-carbonized biomass fuel and to separate combustible flue gas.
  2. 청구항 1에 있어서,The method according to claim 1,
    상기 연소챔버(20)는 유입되는 연소 배가스를 다수의 노즐을 통해 분사하는 분산판(25)을 구비하는 것을 특징으로 하는 바이오매스의 반탄화 및 이물질 제거 장치.The combustion chamber 20 is a semi-carbonization and foreign matter removal apparatus of the biomass, characterized in that it comprises a distribution plate 25 for injecting the incoming combustion exhaust gas through a plurality of nozzles.
  3. 청구항 1에 있어서,The method according to claim 1,
    상기 연소챔버(20)는 바이오매스와 이물질을 밀도차로 분리하도록 스파져(26)를 더 구비하는 것을 특징으로 하는 바이오매스의 반탄화 및 이물질 제거 장치.The combustion chamber 20 further comprises a sparger 26 to separate the biomass and the foreign matter in a density difference, characterized in that the semi-carbonization and foreign matter removal apparatus of the biomass.
  4. 청구항 1에 있어서,The method according to claim 1,
    상기 연소챔버(20)는 투입구(21)를 지닌 1차연소부(31)와 순환구(33)를 지닌 2차연소부(32)로 구획되는 것을 특징으로 하는 바이오매스의 반탄화 및 이물질 제거 장치.The combustion chamber 20 is semi-carbonized and foreign matter removing apparatus, characterized in that partitioned into the primary combustion unit 31 having the inlet 21 and the secondary combustion unit 32 having the circulation port (33).
  5. 청구항 4에 있어서,The method according to claim 4,
    상기 2차연소부(32)는 분리된 이물질을 순환구(33)로 이송하여 재분리를 거치도록 연결되는 것을 특징으로 하는 바이오매스의 반탄화 및 이물질 제거 장치.The secondary combustion unit 32 is a semi-carbonization and foreign matter removal apparatus of the biomass, characterized in that the separated foreign matter is transferred to the circulation port 33 is connected to undergo re-separation.
  6. 청구항 4에 있어서,The method according to claim 4,
    상기 2차연소부(32)는 다수의 지점에 단속적으로 연소 배가스를 공급하도록 연결되는 것을 특징으로 하는 바이오매스의 반탄화 및 이물질 제거 장치.The secondary combustion unit 32 is a semi-carbonization and foreign matter removal apparatus of the biomass, characterized in that connected to supply the combustion exhaust gas intermittently to a plurality of points.
  7. 청구항 4에 있어서,The method according to claim 4,
    상기 2차연소부(32)는 1차연소부(31)에 비하여 느린 속도로 바이오매스를 분리하도록 분산판(25)의 규격을 다르게 적용하는 것을 특징으로 하는 바이오매스의 반탄화 및 이물질 제거 장치.The secondary combustion unit 32 is a semi-carbonization and foreign matter removal apparatus of the biomass, characterized in that to apply different specifications of the dispersion plate 25 to separate the biomass at a slower speed than the primary combustion unit (31).
PCT/KR2015/011976 2015-06-15 2015-11-09 Apparatus for torrefaction of biomass and removal of foreign materials WO2016204355A1 (en)

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