WO2016184842A1 - Composition lubrifiante - Google Patents

Composition lubrifiante Download PDF

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Publication number
WO2016184842A1
WO2016184842A1 PCT/EP2016/060995 EP2016060995W WO2016184842A1 WO 2016184842 A1 WO2016184842 A1 WO 2016184842A1 EP 2016060995 W EP2016060995 W EP 2016060995W WO 2016184842 A1 WO2016184842 A1 WO 2016184842A1
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WO
WIPO (PCT)
Prior art keywords
acid
oil
mixtures
zinc
lubricating composition
Prior art date
Application number
PCT/EP2016/060995
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English (en)
Inventor
Abraham Robert De Kraker
Mark Clift Southby
Sergio Leon DE ROOY
Bassem KHEIREDDIN
Original Assignee
Shell Internationale Research Maatschappij B.V.
Shell Oil Company
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Application filed by Shell Internationale Research Maatschappij B.V., Shell Oil Company filed Critical Shell Internationale Research Maatschappij B.V.
Publication of WO2016184842A1 publication Critical patent/WO2016184842A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/56—Acids of unknown or incompletely defined constitution
    • C10M129/60—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/30—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/30—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms
    • C10M129/32—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/56—Acids of unknown or incompletely defined constitution
    • C10M129/58—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26—Overbased carboxylic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/06—Groups 3 or 13
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/08—Groups 4 or 14
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/10—Groups 5 or 15
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/14—Group 7
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/16—Groups 8, 9, or 10
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/067—Unsaturated Compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/069—Linear chain compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/071—Branched chain compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines

Definitions

  • the present invention relates to a lubricating composition, in particular to a lubricating composition which is suitable for lubricating internal combustion engines and which has improved piston cleanliness properties .
  • Lubricants may be used in machinery to prevent friction between moving parts, such as pistons and cylinders of an engine. As lubricants age due to
  • deposits are formed on hot surfaces in an engine e.g. piston ring/skirt .
  • deposits may form in the lubricants that hinder the movement of engine parts and, therefore, impact the performance of the engine.
  • Lubricants may be configured to reduce the likelihood of such deposits and/or affect the performance of the engine.
  • Lubricants may include a mixture of oils and other additives.
  • the composition of the lubricant may be selected to define properties which can be used to enhance performance of the machinery. For example, various engines may specify the use of a certain viscosity of lubricant under certain conditions, such as outdoor temperature.
  • the composition of the lubricant (and/or its additives) may be selected to control the engine' s tendency to oxidize and form deposits.
  • Antioxidants can delay the onset of deposit formation and detergents can protect metal surfaces against the accumulation of deposits, keeping these species suspended in the lubricant.
  • Current lubricant formulations contain a variety of metal-based detergents which are typically calcium or magnesium salts with phenate, salicylate or sulfonate anions that bear an aromatic ring with alkyl side chain (s) .
  • lubricant components and preferably should provide a synergistic boost in piston cleanliness performance.
  • US5932653 relates to the preparation of a complex reaction product of an oil soluble cobalt soap and an oil soluble overbased calcium soap, which chemical complex serves as a "loss of dry" inhibitor, for oil-based paints.
  • the cobalt soaps used in making the chemical complex include cobalt salts derived from organic monocarboxylic acids having from 6 to 24 carbon atoms.
  • Suitable organic carboxylic acids used in making the calcium salts include 2-ethylhexanoic acid, iso-octanoic acid, nonanoic acid and iso-nonanoic acid.
  • Troymax (RTM) Calcium 10% is mentioned as a compound suitable for use in preparing the chemical complex.
  • EP1243630 discloses a coating composition comprising Troymax 8% Zinc.
  • a lubricating composition comprising (i) base oil and (ii) from 0.1 to 6 wt%, by weight of the lubricating composition, of an oil-soluble metal salt of an organic monocarboxylic acid wherein the organic monocarboxylic acid is selected from straight-chain and branched-chain, saturated and unsaturated, aliphatic and alicyclic monocarboxylic acids having from 5 to 24 carbon atoms, naphthenic acids, tall oil fatty acids, and mixtures thereof, and wherein the metal is selected from cobalt, sodium, calcium, magnesium, zinc, bismuth, lithium, potassium, aluminium, zirconium, tin, vanadium, barium and boron, and mixtures thereof.
  • the metal carboxylates appear to enhance the cleanliness attributes, particularly the piston
  • lubricating compositions in particular when added as a top-treat to lubricating compositions such as passenger car crankcase lubricating compositions .
  • a method for improving the piston cleanliness properties of a lubricating oil composition used to lubricate the crankcase of an internal combustion engine comprising adding to the lubricating oil
  • composition an additive amount of an oil-soluble metal salt of an organic monocarboxylic acid wherein the monocarboxylic acid is selected from straight-chain and branched-chain, saturated and unsaturated, aliphatic or alicyclic monocarboxylic acids having from 5 to 24 carbon atoms and wherein the metal is selected from cobalt, sodium, calcium, magnesium, zinc, bismuth, lithium, potassium, aluminium, zirconium, tin, vanadium, barium and boron, and mixtures thereof.
  • the monocarboxylic acid is selected from straight-chain and branched-chain, saturated and unsaturated, aliphatic or alicyclic monocarboxylic acids having from 5 to 24 carbon atoms and wherein the metal is selected from cobalt, sodium, calcium, magnesium, zinc, bismuth, lithium, potassium, aluminium, zirconium, tin, vanadium, barium and boron, and mixtures thereof.
  • a method for providing improved piston cleanliness of an internal combustion engine comprising lubricating the internal combustion engine with a lubricating composition as described herein.
  • a lubricating composition comprising (i) base oil and (ii) from 0.1 to 6 wt%, by weight of the lubricating composition, of an oil-soluble metal salt of an organic monocarboxylic acid wherein the organic monocarboxylic acid is selected from straight- chain and branched-chain, saturated and unsaturated, aliphatic and alicyclic monocarboxylic acids having from 5 to 24 carbon atoms, naphthenic acids, tall oil fatty acids, and mixtures thereof, and wherein the metal is selected from cobalt, sodium, calcium, magnesium, zinc, bismuth, lithium, potassium, aluminium, zirconium, tin, vanadium, barium and boron, and mixtures thereof.
  • the % improvement in piston cleanliness provided by the lubricating oil compositions herein is at least a 10% improvement in piston cleanliness, more preferably at least a 15% improvement in piston cleanliness, even more preferably at least a 20% improvement in piston cleanliness, compared to the piston cleanliness of an equivalent lubricating oil composition which does not contain an oil-soluble metal salt of an organic monocarboxylic acid as defined herein.
  • the piston cleanliness properties of the lubricating oil composition are measured according to the hot tube deposits test method disclosed in WO2014036110, which reference is incorporated herein by reference in its entirety .
  • oil-soluble when used in relation to the metal salt of an organic monocarboxylic acid means that it soluble in non-aqueous, organic solvent .
  • the lubricating oil composition herein comprises one or more oil-soluble metal salts of an organic monocarboxylic acid, preferably in an amount of from 0.01 wt% to 10 wt%, more preferably in an amount of from 0.25 wt% to 7 wt%, and even more preferably in an amount of from 0.1 wt% to 4 wt%, and especially in an amount of from 0.1 wt% to 2 wt%, by weight of the total lubricating oil composition.
  • Suitable oil-soluble metal salts of an organic monocarboxylic acid for use herein, including preparation details thereof, are disclosed for example in US5932653, US3972825 and US4032354. The relevant disclosures of these patents and applications are incorporated herein by reference .
  • Suitable for use herein is one or more oil-soluble metal salts of an organic monocarboxylic acid wherein the organic monocarboxylic acid is selected from straight- chain and branched-chain, saturated and unsaturated, aliphatic and alicyclic monocarboxylic acids having from 5 to 24 carbon atoms and wherein the metal is selected from cobalt, sodium, calcium, magnesium, zinc, bismuth, lithium, potassium, aluminium, zirconium, tin, vanadium, barium and boron, and mixtures thereof.
  • the monocarboxylic acid is selected from straight-chain and branched-chain, saturated and unsaturated, aliphatic and alicyclic monocarboxylic acids having from 6 to 18 carbon atoms .
  • metal-based detergents which are typically calcium or magnesium salts with phenate, salicylate or sulfonate anions that bear an aromatic ring with alkyl side chain (s) .
  • the oil-soluble metal salts of a monocarboxylic acid used in the present invention are structurally different from said metal-based detergents.
  • Suitable monocarboxylic acids include, but are not limited to, hexanoic acid, n- octanoic acid, 2-ethylhexanoic (octoic) acid, nonanoic acid, isononanoic acid, decanoic acid, isodecanoic acid, neodecanoic acid, lauric acid, myristic acid, stearic acid, arachidic acid, behenic acid, oleic acid, linoleic acid, erucic acid, monobutyl maleate, naphthenic acid, cyclopentanoic acid, cyclohexanoic acid, cycloheptanoic acid, methylcyclohexanoic acid, tall oil acid, and mixtures thereof.
  • the organic monocarboxylic acid for use herein is selected from straight-chain and branched chain,
  • monocarboxylic acids having from 6 to 18 carbon atoms, and mixtures thereof.
  • a preferred organic monocarboxylic acid for use herein is selected from 2-ethylhexanoic acid, iso- octanoic acid, neodecanoic acid, naphthenic acid, oleic acid, nonanoic acid and iso-nonanoic acid, and mixtures thereof .
  • a particularly preferred organic monocarboxylic acid for use herein is 2-ethylhexanoic acid.
  • the metal is selected from calcium and zinc and mixtures thereof.
  • the metal salt of an organic monocarboxylic acid is an overbased calcium salt of 2-ethyl hexanoic acid.
  • the metal salt of an organic monocarboxylic fatty acid is a zinc salt of 2- ethyl hexanoic acid.
  • oil-soluble metal salt of an organic monocarboxylic acid is provided as a solution in an oil- soluble carrier fluid.
  • Suitable oil-soluble carrier fluids for use herein include any base oil which can solubilise the oil-soluble metal salt such that it is soluble in the lubricating composition herein.
  • Suitable oil-soluble carrier fluids include the base oils
  • the oil-soluble carrier fluid can be any base oil which is also used as the base oil in the lubricating
  • suitable oil-soluble carrier fluids for use herein include petroleum oil, esters, Group I base oils, naphthenic base oils, Fischer- Tropsch derived base oils or other Group III base oils.
  • suitable oil-soluble carrier fluids include organic solvents, especially non-polar solvents, selected from the group consisting of aliphatic or cycloaliphatic solvents such as hexane, heptane, octane, isooctane, cyclohexane, and cycloheptane; petroleum distillates such as mineral spirits, gasoline, diesel fuel, and fuel oils; aromatic hydrocarbons such as benzene, toluene, xylene, and ethylbenzene ; glycols such as tripropylene glycol, dipropylene glycol mono methyl ether, or combinations of these non-polar organic solvents.
  • organic solvents especially non-polar solvents, selected from the group consisting of aliphatic or cycloaliphatic solvents such as hexane, heptane, octane, isooctane, cyclohexane, and cycloheptane
  • petroleum distillates such as
  • Examples of commercially available oil-soluble metal salts of an organic monocarboxylic acid for use herein include those compounds commercially available from Troy Corporation under the tradenames Troycat (RTM) Lithium 2, Troymax (RTM) Bismuth 24, Troycat (RTM) Potassium 10, Troymax (RTM) Potassium 15, Troymax (RTM) Calcium Octoate 6 (neutral calcium carboxylate solution containing 6% calcium metal), Troychem (RTM) Zinc 8 (zinc carboxylate solution containing 8% of zinc metal, including zinc salt of 2-ethyl hexanoic acid) , Troymax (RTM) Calcium 10NA (calcium carboxylate solution containing 6% calcium metal) , Troycat (RTM) Zinc 18 (zinc carboxylate solution containing 18% of zinc metal, including zinc salt of 2- ethyl hexanoic acid) , Troymax (RTM) Cobalt 6 (a mineral spirits solution of cobalt-2-ethylhexanoate containing 6% cobalt as
  • base oil used in the lubricating composition there are no particular limitations regarding the base oil used in the lubricating composition herein, and various conventional mineral oils, synthetic oils as well as naturally derived esters such as vegetable oils may be conveniently used.
  • the base oil used in the lubricating compositions herein may conveniently comprise mixtures of one or more mineral oils and/or one or more synthetic oils; thus, according to the present invention, the term "base oil” may refer to a mixture containing more than one base oil.
  • Mineral oils include liquid petroleum oils and solvent- treated or acid-treated mineral lubricating oil of the paraffinic, naphthenic, or mixed paraffinic/naphthenic type which may be further refined by hydrofinishing processes and/or dewaxing.
  • Suitable base oils for use in the lubricating oil composition herein are Group I-III mineral base oils, Group IV poly-alpha olefins (PAOs), Group II-III Fischer-
  • Tropsch derived base oils preferably Group III
  • Group V ester base oils preferably Group V
  • mixtures thereof preferably Group III
  • API American Petroleum Institute
  • Fischer-Tropsch derived base oils are known in the art.
  • Fischer-Tropsch derived is meant that a base oil is, or is derived from, a synthesis product of a Fischer-Tropsch process.
  • a Fischer-Tropsch derived base oil may also be referred to as a GTL (Gas-To-Liquids ) base oil.
  • GTL Gas-To-Liquids
  • Suitable Fischer-Tropsch derived base oils that may be conveniently used as the base oil in the
  • lubricating composition herein are those as for example disclosed in EP0776959, EP0668342, W09721788, WO0015736, WO0014188, WO0014187, WO0014183, WO0014179, WO0008115, W09941332, EP1029029, WO0118156 and WO0157166.
  • Tropsch derived base oil suitably determined by ASTM D 4629, will typically be below 1 wt.%, preferably below 0.5 wt.% and more preferably below 0.1 wt.%.
  • the base oil has a total paraffin content of at least 80 wt.%, preferably at least 85, more preferably at least 90, yet more preferably at least 95 and most preferably at least 99 wt.%. It suitably has a saturates content (as measured by IP-368) of greater than 98 wt.%.
  • the saturates content of the base oil is greater than 99 wt.%, more preferably greater than 99.5 wt.%.
  • the base oil preferably also has a content of naphthenic compounds of from 0 to less than 20 wt.%, more preferably of from 0.5 to 10 wt.%.
  • the Fischer-Tropsch derived base oil or base oil blend has a kinematic viscosity at 100°C (as measured by ASTM D 7042) in the range of from 1 to 30 mm 2 /s (cSt), preferably from 1 to 25 mm 2 /s (cSt), and more preferably from 2 mm 2 /s to 12 mm 2 /s.
  • the Fischer-Tropsch derived base oil has a kinematic viscosity at 100°C (as measured by ASTM D 7042) in the range of from 1 to 30 mm 2 /s (cSt), preferably from 1 to 25 mm 2 /s (cSt), and more preferably from 2 mm 2 /s to 12 mm 2 /s.
  • the Fischer-Tropsch derived base oil has a kinematic viscosity at 100°C (as measured by ASTM D 7042) in the range of from 1 to 30 mm 2 /s (cSt), preferably from 1 to
  • Tropsch derived base oil has a kinematic viscosity at 100°C of at most 5.0 mm 2 /s, preferably at most 4.5 mm 2 /s, more preferably at most 4.2 mm 2 /s (e.g. "GTL 4") .
  • the Fischer- Tropsch derived base oil has a kinematic viscosity at
  • the Fischer-Tropsch derived base oil typically has a kinematic viscosity at 40°C (as measured by ASTM D 7042) of from 10 to 100 mm 2 /s (cSt), preferably from 15 to 50 mm 2 /s .
  • the flash point (as measured by ASTM D92) of the Fischer-Tropsch derived base oil is preferably greater than 120°C, more preferably even greater than 140°C.
  • the Fischer-Tropsch derived base oil preferably has a viscosity index (according to ASTM D 2270) in the range of from 100 to 200.
  • the Fischer-Tropsch derived base oil has a viscosity index of at least 125, preferably 130. Also it is preferred that the viscosity index is below 180, preferably below 150.
  • Fischer-Tropsch derived base oil contains a blend of two or more Fischer-Tropsch derived base oils
  • the above values apply to the blend of the two or more Fischer-Tropsch derived base oils.
  • the lubricating oil composition herein preferably comprises 80 wt% or greater of Fischer-Tropsch derived base oil.
  • Synthetic oils include hydrocarbon oils such as olefin oligomers (including polyalphaolefin base oils;
  • PAOs dibasic acid esters, polyol esters, polyalkylene glycols (PAGs), alkyl naphthalenes and dewaxed waxy isomerates.
  • Synthetic hydrocarbon base oils sold by the Shell Group under the designation "Shell XHVI” (trade mark) may be conveniently used.
  • Poly-alpha olefin base oils PAOs
  • Preferred poly- alpha olefin base oils that may be used in the
  • lubricating compositions herein may be derived from linear C 2 to C 32 , preferably C 6 to Ci 6 , alpha olefins.
  • Particularly preferred feedstocks for said poly-alpha olefins are 1-octene, 1-decene, 1-dodecene and 1- tetradecene .
  • feedstocks for said poly-alpha olefins are 1-octene, 1-decene, 1-dodecene and 1- tetradecene .
  • Fischer- Tropsch derived base oil over a PAO base oil
  • the base oil contains more than 50 wt.%, preferably more than 60 wt.%, more preferably more than
  • the base oil is not a Fischer-Tropsch derived base oil. It is even more preferred that 100 wt% of the base oil is based on one or more Fischer-Tropsch derived base oils.
  • the total amount of base oil incorporated in the lubricating composition herein is preferably in the range of from 60 to 99 wt.%, more preferably in the range of from 65 to 90 wt.% and most preferably in the range of from 70 to 85 wt.%, with respect to the total weight of the lubricating composition.
  • the base oil (or base oil blend) as used in the lubricating composition herein has a kinematic viscosity at 100°C (according to ASTM D445) of above 2.5 cSt and below 5.6 cSt . According to a preferred
  • the base oil has a kinematic viscosity at 100°C (according to ASTM D445) of between 3.5 and 4.5 cSt .
  • the base oil contains a blend of two or more base oils, it is
  • the blend has a kinematic viscosity at 100°C of between 3.5 and 4.5 cSt .
  • the lubricating compositions herein would be utilised in, but not necessarily limited to, SAE J300 viscosity grades OW-20, OW-30, OW-40, 5W-20, 5W-30 and 5W-40 as these are the grades which target fuel economy.
  • SAE J300 viscosity grades are published, with lower viscosities than the current OW-20, the present invention would also be very much applicable to these new viscosity lower grades. It is conceivable that the present invention could also be used with higher
  • the lubricating composition herein preferably has a Noack volatility (according to ASTM D 5800) of below 15 wt . % .
  • the Noack volatility (according to ASTM D 5800) of the composition is between 1 and 15 wt.%, preferably below 14.6 wt.% and more preferably below 14.0 wt . % .
  • the lubricating oil composition has a kinematic viscosity in the range of from 2 to 80 mm 2 /s at 100 °C, more preferably of from 3 to 70 mm 2 /s, most preferably of from 4 to 50 mm 2 /s.
  • the total amount of phosphorus in the lubricating oil composition herein is preferably less than or equal to 0.08 wt%, by weight of the lubricating composition.
  • the lubricating oil composition herein preferably has a sulphated ash content of not greater than 2.0 wt.%, more preferably not greater than 1.0 wt.% and most preferably not greater than 0.8 wt.%, based on the total weight of the lubricating oil composition.
  • the lubricating oil composition herein preferably has a sulphur content of not greater than 1.2 wt.%, more preferably not greater than 0.8 wt.% and most preferably not greater than 0.2 wt.%, based on the total weight of the lubricating oil composition.
  • the lubricating composition herein further comprises one or more additives such as anti-oxidants, anti-wear additives, dispersants, detergents, overbased detergents, extreme pressure additives, friction modifiers, viscosity index improvers, pour point depressants, metal passivators, corrosion inhibitors, demulsifiers , anti-foam agents, seal compatibility agents and additive diluent base oils, etc.
  • additives such as anti-oxidants, anti-wear additives, dispersants, detergents, overbased detergents, extreme pressure additives, friction modifiers, viscosity index improvers, pour point depressants, metal passivators, corrosion inhibitors, demulsifiers , anti-foam agents, seal compatibility agents and additive diluent base oils, etc.
  • Antioxidants that may be conveniently used include those selected from the group of aminic antioxidants and/or phenolic antioxidants.
  • said antioxidants are present in an amount in the range of from 0.1 to 5.0 wt . %, more preferably in an amount in the range of from 0.3 to 3.0 wt . %, and most preferably in an amount in the range of from 0.5 to 1.5 wt . %, based on the total weight of the lubricating oil composition.
  • alkylated diphenylamines phenyl-a-naphthylamines, phenyl--naphthylamines and alkylated a-naphthylamines .
  • Preferred aminic antioxidants include
  • dialkyldiphenylamines such as p, p ' -dioctyl-diphenylamine, p, p ' -di-OC-methylbenzyl-diphenylamine and N-p-butylphenyl- N-p ' -octylphenylamine, monoalkyldiphenylamines such as mono-t-butyldiphenylamine and mono-octyldiphenylamine, bis (dialkylphenyl) amines such as di-(2,4- diethylphenyl) amine and di (2-ethyl-4-nonylphenyl) amine, alkylphenyl-l-naphthylamines such as octylphenyl-1- naphthylamine and n-t-dodecylphenyl-l-naphthylamine, 1- naphthylamine, arylnap
  • Preferred aminic antioxidants include those available under the following trade designations: “Sonoflex OD-3” (ex. Seiko Kagaku Co.), “Irganox L-57” (ex. Ciba).
  • phenolic antioxidants which may be conveniently used include C 7 -C 9 branched alkyl esters of
  • 2.6-di-t-butyl-4-alkoxyphenols such as 2, 6-di-t-butyl-4- methoxyphenol and 2, 6-di-t-butyl-4-ethoxyphenol, 3,5-di-t- butyl-4-hydroxybenzylmercaptooctylacetate, alkyl-3- (3, 5- di-t-butyl-4-hydroxyphenyl) propionates such as n- octadecyl-3- (3, 5-di-t-butyl-4-hydroxyphenyl) propionate, n- butyl-3- (3, 5-di-t-butyl-4-hydroxyphenyl) propionate and 2'- ethylhexyl-3- (3, 5-di-t-butyl-4-hydroxyphenyl) propionate,
  • 2, 6-d-t-butyl-OC-dimethylamino-p-cresol 2,2' -methylene- bis (4-alkyl-6-t-butylphenol) such as 2, 2 ' -methylenebis (4- methyl-6-t-butylphenol, and 2, 2-methylenebis (4-ethyl-6-t- butylphenol) , bisphenols such as 4 , 4 ' -butylidenebis ( 3- methyl-6-t-butylphenol, 4 , 4 ' -methylenebis (2 , 6-di-t- butylphenol) , 4, 4 ' -bis (2, 6-di-t-butylphenol) , 2,2-(di-p- hydroxyphenyl) propane, 2, 2-bis (3, 5-di-t-butyl-4- hydroxyphenyl) propane, 4,4' -cyclohexylidenebis (2, 6-t- butylphenol) , hexamethyleneglycol-bis [3- (3
  • Preferred phenolic antioxidants include those available under the following trade designations: "Irganox
  • the lubricating oil composition herein may comprise mixtures of one or more phenolic antioxidants with one or more aminic antioxidants.
  • Anti-wear additives that may be conveniently used include zinc-containing compounds such as zinc
  • dithiophosphate compounds selected from zinc dialkyl-, diaryl- and/or alkylaryl- dithiophosphates , molybdenum- containing compounds, boron-containing compounds and ashless anti-wear additives such as substituted or unsubstituted thiophosphoric acids, and salts thereof.
  • the lubricating oil composition may comprise a single zinc dithiophosphate or a combination of two or more zinc dithiophosphates as anti-wear additives, the or each zinc dithiophosphate being selected from zinc dialkyl-, diaryl- or alkylaryl- dithiophosphates .
  • Zinc dithiophosphate is a well known additive in the art and may be conveniently represented by general formula II;
  • s s wherein to may be the same or different and are each a primary alkyl group containing from 1 to 20 carbon atoms preferably from 3 to 12 carbon atoms, a secondary alkyl group containing from 3 to 20 carbon atoms, preferably from 3 to 12 carbon atoms, an aryl group or an aryl group substituted with an alkyl group, said alkyl substituent containing from 1 to 20 carbon atoms
  • Zinc dithiophosphate compounds in which to are all different from each other can be used alone or in admixture with zinc dithiophosphate compounds in which R 2 to R 5 are all the same.
  • the or each zinc dithiophosphate used in the present invention is a zinc dialkyl dithiophosphate .
  • Examples of suitable zinc dithiophosphates which are commercially available include those available ex.
  • dithiophosphates such as those available ex. Lubrizol Corporation under the trade designations "Lz 1370" and
  • the lubricating oil composition herein may generally comprise in the range of from 0.4 to 1.2 wt . % of zinc dithiophosphate, based on total weight of the lubricating oil composition.
  • molybdenum-containing compounds may conveniently include molybdenum dithiocarbamates , trinuclear molybdenum compounds, for example as described in WO9826030, sulphides of molybdenum and molybdenum dithiophosphate .
  • Boron-containing compounds that may be conveniently used include borate esters, borated fatty amines, borated epoxides, alkali metal (or mixed alkali metal or alkaline earth metal) borates and borated overbased metal salts.
  • lubricating composition herein include one or more salicylate and/or phenate and/or sulphonate detergents.
  • metal organic and inorganic base salts which are used as detergents can contribute to the sulphated ash content of a lubricating oil composition, in a preferred embodiment of the present invention, the amounts of such additives are minimised.
  • salicylate detergents are preferred.
  • said detergents are preferably used in amounts in the range of 0.05 to 20.0 wt . %, more preferably from 1.0 to 10.0 wt . % and most preferably in the range of from 2.0 to 5.0 wt . %, based on the total weight of the lubricating oil composition .
  • said detergents independently, have a TBN (total base number) value in the range of from 10 to 500 mg.KOH/g, more preferably in the range of from 30 to 350 mg.KOH/g and most preferably in the range of from 50 to 300 mg.KOH/g, as measured by ISO 3771.
  • TBN total base number
  • the lubricating oil compositions herein may
  • an ash-free dispersant which is preferably admixed in an amount in the range of from 5 to 15 wt . %, based on the total weight of the lubricating oil composition.
  • ash-free dispersants examples include the polyalkenyl succinimides and polyalkenyl succininic acid esters disclosed in Japanese Patent Nos . JP1367796, JP1667140, JP1302811 and JP1743435.
  • Preferred dispersants include borated succinimides .
  • viscosity index improvers which may conveniently be used in the lubricating composition herein include the styrene-butadiene stellate copolymers, styrene-isoprene stellate copolymers and the
  • Dispersant- viscosity index improvers may be used in the lubricating composition herein.
  • the composition herein contains less than 1.0 wt.%, preferably less than 0.5 wt.%, of a Viscosity Index improver concentrate (i.e. VI improver plus "carrier oil” or "diluent”), based on the total weight of the composition.
  • a Viscosity Index improver concentrate i.e. VI improver plus "carrier oil” or "diluent
  • the composition is free of Viscosity Index improver
  • Viscosity Modifier as used hereafter is meant to be the same as the above-mentioned term “Viscosity Index improver concentrate”.
  • the composition contains at least 0.1 wt.% of a pour point depressant.
  • a pour point depressant alkylated naphthalene and phenolic polymers, polymethacrylates, maleate/ fumarate copolymer esters may be conveniently used as effective pour point depressants.
  • compounds such as alkenyl succinic acid or ester moieties thereof, benzotriazole-based compounds and thiodiazole-based compounds may be conveniently used in the lubricating composition herein as corrosion inhibitors .
  • polycyclohexane and polyacrylates may be conveniently used in the lubricating composition herein as defoaming agents.
  • seal fix or seal compatibility agents include, for example, commercially available aromatic esters.
  • the above-mentioned additives are typically present in an amount in the range of from 0.01 to 35.0 wt.%, based on the total weight of the lubricating composition, preferably in an amount in the range of from 0.05 to 25.0 wt.%, more preferably from 1.0 to 20.0 wt.%, based on the total weight of the lubricating composition.
  • the composition contains at least 9.0 wt.%, preferably at least 10.0 wt.%, more preferably at least 11.0 wt% of an additive package comprising an anti- wear additive, a metal detergent, an ashless dispersant and an anti-oxidant .
  • the lubricating compositions herein are preferably engines oils for use in the crankcase of an engine.
  • the engine oil may include a heavy duty diesel engine oil, a passenger car motor engine oil, as well as other types of engine oils, such as motor cycle oils and marine engine oils.
  • PCMO Passenger Car Motor Oil
  • a sulphated ash content (according to ASTM D 874) of up to 0.5 wt.%, up to 0.8 wt.% and up to 1.5 wt.%, respectively;
  • a phosphorus content (according to ASTM D 5185) of up to 0.05 wt.%, up to 0.08 wt.% and typically up to 0.1 wt.%, respectively;
  • a sulphur content (according to ASTM D 5185) of up to 0.2 wt.%, up to 0.3 wt.% and typically up to 0.5 wt.%, respectively.
  • a sulphated ash content (according to ASTM D 874) of up to 1 wt.%, up to 1 wt.% and up to 2 wt.%,
  • a phosphorus content (according to ASTM D 5185) of up to 0.08 wt.% (low SAPS) and up to 0.12 wt.% (mid SAPS) , respectively;
  • sulphur content (according to ASTM D 5185) of up to 0.3 wt.% (low SAPS) and up to 0.4 wt.% (mid SAPS), respectively.
  • the lubricating compositions herein may be any suitable lubricating compositions herein.
  • oil-soluble metal salt of a monocarboxylic acid provides reduced piston cleanliness, in particular as measured according to the hot tube deposits test method as described in WO2014036110.
  • a cleanliness merit of 10.0 represents completely clean engine pistons.
  • the lubricating compositions described herein comprising a base oil and one or more oil-soluble metal salts of a monocarboxylic acid preferably provide a hot tube cleanliness merit result in the hot tube deposits test method described in WO2014036110 of 8.0 or above .
  • Lubricating formulations were prepared by top treating a reference lubricant (reference lubricant A which was a passenger car motor oil (PCMO) meeting GF-5 specification) with 3 wt% of an oil-soluble metal salt of a monocarboxylic acid or a conventional antioxidant compound.
  • reference lubricant A which was a passenger car motor oil (PCMO) meeting GF-5 specification
  • Comparative Example 1 consisted of reference lubricant A top treated with 3 wt% of a conventional aminic antioxidant (Infineum C9452 commercially available from Infineum) .
  • Comparative Example 2 consisted of reference lubricant A top treated with 3 wt% of a conventional phenolic antioxidant (Infineum C9454 commercially available from Infineum) .
  • Example 1 consisted of the reference lubricant A top treated with 3 wt% of Troymax (RTM) Calcium Octoate 6
  • Example 2 consisted of reference lubricant A top treated with 3 wt% of Troychem (RTM) Zinc 8 (metal carboxylate solution containing 8% of zinc metal) commercially available from Troy Corporation.
  • RTM Troychem
  • Example 3 consisted of reference lubricant A top treated with 3 wt% of Troymax (RTM) Calcium 10NA (calcium carboxylate solution containing 6% calcium metal) commercially available from Troy Corporation.
  • RTM Troymax
  • Calcium 10NA calcium carboxylate solution containing 6% calcium metal
  • Example 4 consisted of reference lubricant A top treated with 3 wt% of Troycat (RTM) Zinc 18 (metal carboxylate solution containing 18% of zinc metal) commercially available from Troy Corporation.
  • RTM Troycat
  • Zinc 18 metal carboxylate solution containing 18% of zinc metal
  • Examples 1, 2, 3 and 4 had hot tube merit results of 9.3, 8.3, 9.5 and 9.1, respectively. This compared to hot tube merit results of 7.5 and 6.9 for Comparative Example 1 and Comparative Example 2,

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  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
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  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

La présente invention concerne l'utilisation d'une composition lubrifiante comprenant (i) une huile de base et (ii) de 0,1 à 6 % en poids, en poids de la composition lubrifiante, d'un sel métallique oléosoluble d'un acide monocarboxylique organique, l'acide monocarboxylique organique étant choisi parmi des acides monocarboxyliques alicycliques et aliphatiques, à chaînes linéaires et à chaînes ramifiées, saturés et insaturés, ayant de 5 à 24 atomes de carbone, et le métal étant choisi parmi le cobalt, le sodium, le calcium, le magnésium, le zinc, le bismuth, le lithium, le potassium, l'aluminium, le zirconium, l'étain, le vanadium, le baryum et le bore, et des mélanges de ceux-ci, permettant de fournir une meilleure propreté de piston.
PCT/EP2016/060995 2015-05-18 2016-05-17 Composition lubrifiante WO2016184842A1 (fr)

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WO2014036110A2 (fr) 2012-08-30 2014-03-06 Shell Oil Company Système et procédé de test de lubrifiants de moteur
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Cited By (2)

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US10000721B2 (en) 2014-12-30 2018-06-19 Exxonmobil Research And Engineering Company Lubricating oil compositions with engine wear protection
US10781397B2 (en) 2014-12-30 2020-09-22 Exxonmobil Research And Engineering Company Lubricating oil compositions with engine wear protection

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