WO2016173237A1 - 一种耐腐蚀的金属油墨及其制备方法 - Google Patents

一种耐腐蚀的金属油墨及其制备方法 Download PDF

Info

Publication number
WO2016173237A1
WO2016173237A1 PCT/CN2015/094282 CN2015094282W WO2016173237A1 WO 2016173237 A1 WO2016173237 A1 WO 2016173237A1 CN 2015094282 W CN2015094282 W CN 2015094282W WO 2016173237 A1 WO2016173237 A1 WO 2016173237A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
corrosion
metal ink
resistant metal
resin
Prior art date
Application number
PCT/CN2015/094282
Other languages
English (en)
French (fr)
Inventor
张双峰
Original Assignee
张双峰
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 张双峰 filed Critical 张双峰
Publication of WO2016173237A1 publication Critical patent/WO2016173237A1/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/108—Hydrocarbon resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

Definitions

  • the invention relates to the field of ink technology, in particular to a corrosion-resistant metal ink and a preparation method thereof.
  • Metal ink refers to an ink formulated with a metallic pigment and has a metallic luster.
  • gold ink and silver ink are such inks.
  • the pigments of metallic inks are mainly gold powder and silver powder (copper powder and aluminum powder), and other pigments may be added to produce inks with special colors, which are called colored metal inks.
  • Another object of the present invention is to provide a method of preparing a corrosion-resistant metal ink in view of the deficiencies of the prior art.
  • the present invention has been achieved by the following technical solutions.
  • a corrosion-resistant metal ink comprising the following raw materials by weight: 20-30 parts of aqueous polyurethane resin, 33-45 parts of chlorinated polypropylene resin, 25-35 parts of aqueous acrylic resin, glyceryl monostearate 10- 20 parts, 10-25 parts of ethanol, 3-8 parts of chitosan-graphene composite material, 3-8 parts of auxiliary agent, 15-25 parts of metallic pigment, 3-8 parts of hollow glass microbead, walnut shell powder 1- 2 servings.
  • aqueous polyurethane resin comprises the following raw materials by weight: 20-25 parts of aqueous polyurethane resin, 39-45 parts of chlorinated polypropylene resin, 25-30 parts of aqueous acrylic resin, 15-20 parts of glyceryl monostearate, ethanol 10 -18 parts, 3-5 parts of chitosan-graphene composite material, 6-8 parts of auxiliary agent, 15-20 parts of metallic pigment, 3-5 parts of hollow glass microspheres, and 1-2 parts of walnut shell powder.
  • aqueous polyurethane resin comprises the following raw materials by weight: 26-30 parts of aqueous polyurethane resin, 33-38 parts of chlorinated polypropylene resin, 31-35 parts of aqueous acrylic resin, 10-14 parts of glyceryl monostearate, ethanol 19 -25 parts, 6-8 parts of chitosan-graphene composite material, 3-5 parts of auxiliary agent, 21-25 parts of metallic pigment, 6-8 parts of hollow glass microbeads, and 1-2 parts of walnut shell powder.
  • aqueous polyurethane resin comprises the following raw materials by weight: 23-25 parts of aqueous polyurethane resin, 38-42 parts of chlorinated polypropylene resin, 27-33 parts of aqueous acrylic resin, 13-17 parts of glyceryl monostearate, ethanol 14 -19 parts, 5-7 parts of chitosan-graphene composite material, 5-6 parts of auxiliary agent, 18-22 parts of metallic pigment, 5-7 parts of hollow glass microbeads, and 1-2 parts of walnut shell powder.
  • nano-alumina also includes 3-5 parts by weight of nano-alumina.
  • the adjuvant includes an antifoaming agent, a surfactant, and a polyurethane thickener.
  • the antifoaming agent is a silicone defoaming agent or a natural fat;
  • the surfactant is a silicon-based surfactant or a fluorine-based surfactant.
  • a preparation method of a corrosion-resistant metal ink the preparation steps are as follows: according to the above parts by weight, firstly mixing glyceryl monostearate with ethanol, adding water-based polyurethane resin, chlorinated polypropylene resin, water-based acrylic resin under stirring After mixing, disperse, grind, add chitosan-graphene composite material, ultrasonically grind for 30-40 minutes, add the remaining raw materials, and stir evenly to obtain corrosion-resistant metal ink.
  • the corrosion-resistant metal ink of the invention has the following beneficial effects: the corrosion-resistant metal ink of the invention has the following advantages: the polysaccharide-graphene composite material has a large specific surface area, and the synergistic effect between the chitosan and the graphene is enhanced, and the shell
  • the polysaccharide-graphene composite material cooperates with the walnut shell powder and the hollow glass microbeads to make the metal ink have a corrosion-resistant self-protective coating, which effectively inhibits the diffusion of corrosive substances in the metal ink, and has better performance. Corrosion resistance.
  • the raw materials of the invention achieve the purpose of mutual compatibility and have good corrosion resistance.
  • a corrosion-resistant metal ink comprising the following raw materials by weight: 20 parts of aqueous polyurethane resin, 39 parts of chlorinated polypropylene resin, 30 parts of water-based acrylic resin, 20 parts of glyceryl monostearate, 10 parts of ethanol, shell 5 parts of polysaccharide-graphene composite material, 6 parts of auxiliary agent, 15 parts of metallic pigment, 5 parts of hollow glass microbeads, and 1 part of walnut shell powder.
  • the metal pigment is gold powder
  • the auxiliary agent includes 2 parts of antifoaming agent, 2 parts of surfactant, and 2 parts of polyurethane thickener.
  • the antifoaming agent is a silicone defoaming agent (such as polyether modified silicone) or a natural fat; the surfactant is a silicon-based surfactant or a fluorine-based surfactant.
  • a preparation method of a corrosion-resistant metal ink the preparation steps are as follows: according to the above parts by weight, firstly mixing glyceryl monostearate with ethanol, adding water-based polyurethane resin, chlorinated polypropylene resin, water-based acrylic resin under stirring After mixing, disperse, grind, add chitosan-graphene composite material, ultrasonically grind for 30 minutes, add the rest of the raw materials, and stir evenly to obtain corrosion-resistant metal ink.
  • Example 1 differs from Example 1 in that it is a corrosion-resistant metal ink comprising the following raw materials by weight: 25 parts of aqueous polyurethane resin, 45 parts of chlorinated polypropylene resin, 25 parts of water-based acrylic resin, single 15 parts of glyceryl stearate, 18 parts of ethanol, 3 parts of chitosan-graphene composite material, 8 parts of auxiliary agent, 20 parts of metallic pigment, 3 parts of hollow glass microbeads, and 2 parts of walnut shell powder.
  • the metal pigment is silver powder
  • the auxiliary agent includes 2 parts of antifoaming agent and 3 parts of surfactant. 3 parts of polyurethane thickener.
  • a preparation method of a corrosion-resistant metal ink the preparation steps are as follows: according to the above parts by weight, firstly mixing glyceryl monostearate with ethanol, adding water-based polyurethane resin, chlorinated polypropylene resin, water-based acrylic resin under stirring After mixing, disperse, grind, add chitosan-graphene composite material, ultrasonically grind for 33 minutes, add the remaining raw materials, and stir evenly to obtain corrosion-resistant metal ink.
  • Example 1 differs from Example 1 in that it is a corrosion-resistant metal ink comprising the following raw materials by weight: 26 parts of aqueous polyurethane resin, 38 parts of chlorinated polypropylene resin, 31 parts of water-based acrylic resin, single 14 parts of glyceryl stearate, 19 parts of ethanol, 8 parts of chitosan-graphene composite material, 3 parts of auxiliary agent, 22 parts of metallic pigment, 8 parts of hollow glass microbeads, and 1 part of walnut shell powder.
  • the metallic pigment is copper powder
  • the auxiliary agent includes 1 part of antifoaming agent, 1.5 parts of surfactant, and 0.5 part of polyurethane thickener.
  • a preparation method of a corrosion-resistant metal ink the preparation steps are as follows: according to the above parts by weight, firstly mixing glyceryl monostearate with ethanol, adding water-based polyurethane resin, chlorinated polypropylene resin, water-based acrylic resin under stirring After mixing, disperse, grind, add chitosan-graphene composite material, ultrasonically grind for 35 minutes, add the rest of the raw materials, and stir evenly to obtain corrosion-resistant metal ink.
  • Example 1 differs from Example 1 in that it is a corrosion-resistant metal ink comprising the following raw materials by weight: 30 parts of aqueous polyurethane resin, 33 parts of chlorinated polypropylene resin, 35 parts of water-based acrylic resin, single 10 parts of glyceryl stearate, 25 parts of ethanol, 6 parts of chitosan-graphene composite material, 5 parts of auxiliary agent, 25 parts of metallic pigment, 6 parts of hollow glass microbeads, and 2 parts of walnut shell powder.
  • the metallic pigment is a mixture of 15 parts of silver powder and 10 parts of aluminum powder
  • the auxiliary agent includes 1 part of antifoaming agent, 2 parts of surfactant, and 2 parts of polyurethane thickener.
  • a preparation method of a corrosion-resistant metal ink the preparation steps are as follows: according to the above parts by weight, firstly mixing glyceryl monostearate with ethanol, adding water-based polyurethane resin, chlorinated polypropylene resin, water-based acrylic resin under stirring After mixing, disperse, grind, add chitosan-graphene composite material, ultrasonically grind for 38 minutes, add the remaining raw materials, and stir evenly to obtain corrosion-resistant metal ink.
  • Example 1 differs from Example 1 in that it is a corrosion-resistant metal ink comprising the following raw materials by weight: 23 parts of aqueous polyurethane resin, 42 parts of chlorinated polypropylene resin, 27 parts of water-based acrylic resin, single 17 parts of glyceryl stearate, 14 parts of ethanol, 7 parts of chitosan-graphene composite material, 5 parts of auxiliary agent, 18 parts of metallic pigment, 7 parts of hollow glass microbeads, and 1 part of walnut shell powder.
  • the metal pigment is a mixture of 8 parts of gold powder and 10 parts of silver powder
  • the auxiliary agent includes defoaming. 2 parts of the agent, 1 part of the surfactant, and 2 parts of the polyurethane thickener.
  • a preparation method of a corrosion-resistant metal ink the preparation steps are as follows: according to the above parts by weight, firstly mixing glyceryl monostearate with ethanol, adding water-based polyurethane resin, chlorinated polypropylene resin, water-based acrylic resin under stirring After mixing, disperse, grind, add chitosan-graphene composite material, ultrasonically grind for 40 minutes, add the remaining raw materials, and stir evenly to obtain corrosion-resistant metal ink.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

一种耐腐蚀的金属油墨及其制备方法，该金属油墨包括以下重量份的原料：水性聚氨酯树脂20-30份、氯化聚丙烯树脂33-45份、水性丙烯酸树脂25-35份、单硬脂酸甘油酯10-20份、乙醇10-25份、壳聚糖-石墨烯复合材料3-8份、助剂3-8份、金属颜料15-25份、空心玻璃微珠3-8份、核桃壳粉1-2份。

Description

一种耐腐蚀的金属油墨及其制备方法 技术领域
本发明涉及油墨技术领域，尤其涉及一种耐腐蚀的金属油墨及其制备方法。
背景技术
金属油墨指用金属颜料配制的油墨，有金属的光泽，一般说的金墨、银墨即是这类油墨。金属油墨的颜料主要是金粉和银粉(铜粉和铝粉)，也可加人其他颜料以产生具有特殊色彩的油墨，称之为着色金属油墨。
随着人们生活水平的不断进步，对金属油墨本身的耐腐蚀性能要求不断提升，因此现有的金属油墨的耐腐蚀等性能需要提高。
发明内容
本发明的目的是针对现有技术的不足提供一种耐腐蚀性能好的金属油墨。
本发明的另一目的是针对现有技术的不足提供一种耐腐蚀的金属油墨的制备方法。
本发明是通过以下技术方案来实现的。
一种耐腐蚀的金属油墨，它包括以下重量份的原料：水性聚氨酯树脂20-30份、氯化聚丙烯树脂33-45份、水性丙烯酸树脂25-35份、单硬脂酸甘油酯10-20份、乙醇10-25份、壳聚糖-石墨烯复合材料3-8份、助剂3-8份、金属颜料15-25份、空心玻璃微珠3-8份、核桃壳粉1-2份。
具体地，它包括以下重量份的原料：水性聚氨酯树脂20-25份、氯化聚丙烯树脂39-45份、水性丙烯酸树脂25-30份、单硬脂酸甘油酯15-20份、乙醇10-18份、壳聚糖-石墨烯复合材料3-5份、助剂6-8份、金属颜料15-20份、空心玻璃微珠3-5份、核桃壳粉1-2份。
具体地，它包括以下重量份的原料：水性聚氨酯树脂26-30份、氯化聚丙烯树脂33-38份、水性丙烯酸树脂31-35份、单硬脂酸甘油酯10-14份、乙醇19-25份、壳聚糖-石墨烯复合材料6-8份、助剂3-5份、金属颜料21-25份、空心玻璃微珠6-8份、核桃壳粉1-2份。
具体地，它包括以下重量份的原料：水性聚氨酯树脂23-25份、氯化聚丙烯树脂38-42份、水性丙烯酸树脂27-33份、单硬脂酸甘油酯13-17份、乙醇14-19份、壳聚糖-石墨烯复合材料5-7份、助剂5-6份、金属颜料18-22份、空心玻璃微珠5-7份、核桃壳粉1-2份。
具体地，它还包括纳米氧化铝3-5重量份。
具体地，助剂包括消泡剂、表面活性剂、聚氨酯增稠剂。消泡剂为有机硅消泡剂或者天然油脂；表面活性剂是硅系表面活性剂或氟系表面活性剂。
一种耐腐蚀的金属油墨的制备方法，制备步骤如下：按上述重量份，先将单硬脂酸甘油酯与乙醇混合均匀，搅拌状态下加入水性聚氨酯树脂、氯化聚丙烯树脂、水性丙烯酸树脂，混合均匀后，分散、研磨，加入壳聚糖-石墨烯复合材料，超声波研磨30-40分钟，加入其余原料，搅拌均匀后，即得耐腐蚀的金属油墨。
本发明具有以下有益效果：本发明的耐腐蚀的金属油墨，具有以下优点：聚糖-石墨烯复合材料具有较大的比表面积，壳聚糖和石墨烯之间具有增强的协同作用，同时壳聚糖-石墨烯复合材料与核桃壳粉、空心玻璃微珠等协同作用，使得金属油墨有耐腐蚀的自保护涂层，有效的抑制了腐蚀性物质在金属油墨中的扩散，具有较好的耐腐蚀性能。本发明各原料达到互容的目的，耐腐蚀性能好。
具体实施方式
以下结合具体实施方式对本发明进行详细的描述。
实施例1。
一种耐腐蚀的金属油墨，它包括以下重量份的原料：水性聚氨酯树脂20份、氯化聚丙烯树脂39份、水性丙烯酸树脂30份、单硬脂酸甘油酯20份、乙醇10份、壳聚糖-石墨烯复合材料5份、助剂6份、金属颜料15份、空心玻璃微珠5份、核桃壳粉1份。金属颜料为金粉，助剂包括消泡剂2份、表面活性剂2份、聚氨酯增稠剂2份。消泡剂为有机硅消泡剂(如聚醚改性有机硅)或者天然油脂；表面活性剂是硅系表面活性剂或氟系表面活性剂。
一种耐腐蚀的金属油墨的制备方法，制备步骤如下：按上述重量份，先将单硬脂酸甘油酯与乙醇混合均匀，搅拌状态下加入水性聚氨酯树脂、氯化聚丙烯树脂、水性丙烯酸树脂，混合均匀后，分散、研磨，加入壳聚糖-石墨烯复合材料，超声波研磨30分钟，加入其余原料，搅拌均匀后，即得耐腐蚀的金属油墨。
实施例2。
本实施例与实施例1的不同之处在于：一种耐腐蚀的金属油墨，它包括以下重量份的原料：水性聚氨酯树脂25份、氯化聚丙烯树脂45份、水性丙烯酸树脂25份、单硬脂酸甘油酯15份、乙醇18份、壳聚糖-石墨烯复合材料3份、助剂8份、金属颜料20份、空心玻璃微珠3份、核桃壳粉2份。金属颜料为银粉，助剂包括消泡剂2份、表面活性剂3份、 聚氨酯增稠剂3份。
一种耐腐蚀的金属油墨的制备方法，制备步骤如下：按上述重量份，先将单硬脂酸甘油酯与乙醇混合均匀，搅拌状态下加入水性聚氨酯树脂、氯化聚丙烯树脂、水性丙烯酸树脂，混合均匀后，分散、研磨，加入壳聚糖-石墨烯复合材料，超声波研磨33分钟，加入其余原料，搅拌均匀后，即得耐腐蚀的金属油墨。
实施例3。
本实施例与实施例1的不同之处在于：一种耐腐蚀的金属油墨，它包括以下重量份的原料：水性聚氨酯树脂26份、氯化聚丙烯树脂38份、水性丙烯酸树脂31份、单硬脂酸甘油酯14份、乙醇19份、壳聚糖-石墨烯复合材料8份、助剂3份、金属颜料22份、空心玻璃微珠8份、核桃壳粉1份。金属颜料为铜粉，助剂包括消泡剂1份、表面活性剂1.5份、聚氨酯增稠剂0.5份。
一种耐腐蚀的金属油墨的制备方法，制备步骤如下：按上述重量份，先将单硬脂酸甘油酯与乙醇混合均匀，搅拌状态下加入水性聚氨酯树脂、氯化聚丙烯树脂、水性丙烯酸树脂，混合均匀后，分散、研磨，加入壳聚糖-石墨烯复合材料，超声波研磨35分钟，加入其余原料，搅拌均匀后，即得耐腐蚀的金属油墨。
实施例4。
本实施例与实施例1的不同之处在于：一种耐腐蚀的金属油墨，它包括以下重量份的原料：水性聚氨酯树脂30份、氯化聚丙烯树脂33份、水性丙烯酸树脂35份、单硬脂酸甘油酯10份、乙醇25份、壳聚糖-石墨烯复合材料6份、助剂5份、金属颜料25份、空心玻璃微珠6份、核桃壳粉2份。金属颜料为银粉15份、铝粉10份的混合物，助剂包括消泡剂1份、表面活性剂2份、聚氨酯增稠剂2份。
一种耐腐蚀的金属油墨的制备方法，制备步骤如下：按上述重量份，先将单硬脂酸甘油酯与乙醇混合均匀，搅拌状态下加入水性聚氨酯树脂、氯化聚丙烯树脂、水性丙烯酸树脂，混合均匀后，分散、研磨，加入壳聚糖-石墨烯复合材料，超声波研磨38分钟，加入其余原料，搅拌均匀后，即得耐腐蚀的金属油墨。
实施例5。
本实施例与实施例1的不同之处在于：一种耐腐蚀的金属油墨，它包括以下重量份的原料：水性聚氨酯树脂23份、氯化聚丙烯树脂42份、水性丙烯酸树脂27份、单硬脂酸甘油酯17份、乙醇14份、壳聚糖-石墨烯复合材料7份、助剂5份、金属颜料18份、空心玻璃微珠7份、核桃壳粉1份。金属颜料为金粉8份、银粉10份的混合物，助剂包括消泡 剂2份、表面活性剂1份、聚氨酯增稠剂2份。
一种耐腐蚀的金属油墨的制备方法，制备步骤如下：按上述重量份，先将单硬脂酸甘油酯与乙醇混合均匀，搅拌状态下加入水性聚氨酯树脂、氯化聚丙烯树脂、水性丙烯酸树脂，混合均匀后，分散、研磨，加入壳聚糖-石墨烯复合材料，超声波研磨40分钟，加入其余原料，搅拌均匀后，即得耐腐蚀的金属油墨。
应用实施例1-5制备的耐腐蚀的金属油墨进行性能测定，如表1。
表1
Figure PCTCN2015094282-appb-000001
最后应当说明的是，以上实施例仅用以说明本发明的技术方案，而非对本发明保护范围的限制，尽管参照较佳实施例对本发明作了详细地说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的实质和范围。

Claims (7)

  1. 一种耐腐蚀的金属油墨，其特征在于，它包括以下重量份的原料：水性聚氨酯树脂20-30份、氯化聚丙烯树脂33-45份、水性丙烯酸树脂25-35份、单硬脂酸甘油酯10-20份、乙醇10-25份、壳聚糖-石墨烯复合材料3-8份、助剂3-8份、金属颜料15-25份、空心玻璃微珠3-8份、核桃壳粉1-2份。
  2. 根据权利要求1的耐腐蚀的金属油墨，其特征在于，它包括以下重量份的原料：水性聚氨酯树脂20-25份、氯化聚丙烯树脂39-45份、水性丙烯酸树脂25-30份、单硬脂酸甘油酯15-20份、乙醇10-18份、壳聚糖-石墨烯复合材料3-5份、助剂6-8份、金属颜料15-20份、空心玻璃微珠3-5份、核桃壳粉1-2份。
  3. 根据权利要求1的耐腐蚀的金属油墨，其特征在于，它包括以下重量份的原料：水性聚氨酯树脂26-30份、氯化聚丙烯树脂33-38份、水性丙烯酸树脂31-35份、单硬脂酸甘油酯10-14份、乙醇19-25份、壳聚糖-石墨烯复合材料6-8份、助剂3-5份、金属颜料21-25份、空心玻璃微珠6-8份、核桃壳粉1-2份。
  4. 根据权利要求1的耐腐蚀的金属油墨，其特征在于，它包括以下重量份的原料：水性聚氨酯树脂23-25份、氯化聚丙烯树脂38-42份、水性丙烯酸树脂27-33份、单硬脂酸甘油酯13-17份、乙醇14-19份、壳聚糖-石墨烯复合材料5-7份、助剂5-6份、金属颜料18-22份、空心玻璃微珠5-7份、核桃壳粉1-2份。
  5. 根据权利要求1的耐腐蚀的金属油墨，其特征在于，它还包括纳米氧化铝3-5重量份。
  6. 根据权利要求1的耐腐蚀的金属油墨，其特征在于，助剂包括消泡剂、表面活性剂、聚氨酯增稠剂。
  7. 一种权利要求1至6任意一项的耐腐蚀的金属油墨的制备方法，其特征在于，制备步骤如下：按上述重量份，先将单硬脂酸甘油酯与乙醇混合均匀，搅拌状态下加入水性聚氨酯树脂、氯化聚丙烯树脂、水性丙烯酸树脂，混合均匀后，分散、研磨，加入壳聚糖-石墨烯复合材料，超声波研磨30-40分钟，加入其余原料，搅拌均匀后，即得耐腐蚀的金属油墨。
PCT/CN2015/094282 2015-04-29 2015-11-11 一种耐腐蚀的金属油墨及其制备方法 WO2016173237A1 (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201510210906.0A CN104774499A (zh) 2015-04-29 2015-04-29 一种耐腐蚀的金属油墨及其制备方法
CN201510210906.0 2015-04-29

Publications (1)

Publication Number Publication Date
WO2016173237A1 true WO2016173237A1 (zh) 2016-11-03

Family

ID=53616286

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2015/094282 WO2016173237A1 (zh) 2015-04-29 2015-11-11 一种耐腐蚀的金属油墨及其制备方法

Country Status (2)

Country Link
CN (1) CN104774499A (zh)
WO (1) WO2016173237A1 (zh)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774499A (zh) * 2015-04-29 2015-07-15 韦利束 一种耐腐蚀的金属油墨及其制备方法
CN105482026B (zh) * 2016-01-06 2017-06-30 上海墨传新材料科技有限公司 水溶性丙烯酸树脂球形颗粒及其制备方法
CN105860705A (zh) * 2016-04-26 2016-08-17 安徽康瑞鑫电子科技有限公司 一种防锈漆
CN109969548B (zh) * 2017-12-28 2023-10-13 战马（北京）饮料有限公司 一种多触感区域罐体
CN109233457A (zh) * 2018-10-09 2019-01-18 福建师范大学福清分校 一种用于深海工程的抗冻型石墨烯基水性涂料

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002226758A (ja) * 2001-02-01 2002-08-14 Toyo Ink Mfg Co Ltd 水性バインダー、水性インキ組成物及びそのラミネート加工物
CN101457052A (zh) * 2008-09-25 2009-06-17 黄山市新力油墨化工厂 一种凹版透明油墨及其制备方法
CN102061113A (zh) * 2011-01-31 2011-05-18 郑州峰源油墨有限公司 醇溶聚氨酯凹版塑料油墨及其制备方法
CN102250512A (zh) * 2011-01-19 2011-11-23 一可油墨涂料（深圳）有限公司 聚丙烯材料用网印油墨
CN103965688A (zh) * 2014-05-09 2014-08-06 上海锐炽化工科技有限公司 一种轮胎用喷码油墨及其制备方法
CN104774499A (zh) * 2015-04-29 2015-07-15 韦利束 一种耐腐蚀的金属油墨及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0457866A (ja) * 1990-06-26 1992-02-25 Sanei Kagaku Kk 銅スルーホールプリント配線基板製造用の孔埋めインキ
CN101717596B (zh) * 2009-12-08 2012-05-23 湖州杭华油墨科技有限公司 一种高附着力薄膜包装印刷用水性油墨及其制作方法
CN102093781B (zh) * 2011-01-27 2013-10-16 广东天龙油墨集团股份有限公司 一种水性金属油墨及其制备方法
CN102964917B (zh) * 2012-11-23 2014-04-16 东莞市佳烨化工科技有限公司 一种水性胶印防伪油墨及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002226758A (ja) * 2001-02-01 2002-08-14 Toyo Ink Mfg Co Ltd 水性バインダー、水性インキ組成物及びそのラミネート加工物
CN101457052A (zh) * 2008-09-25 2009-06-17 黄山市新力油墨化工厂 一种凹版透明油墨及其制备方法
CN102250512A (zh) * 2011-01-19 2011-11-23 一可油墨涂料（深圳）有限公司 聚丙烯材料用网印油墨
CN102061113A (zh) * 2011-01-31 2011-05-18 郑州峰源油墨有限公司 醇溶聚氨酯凹版塑料油墨及其制备方法
CN103965688A (zh) * 2014-05-09 2014-08-06 上海锐炽化工科技有限公司 一种轮胎用喷码油墨及其制备方法
CN104774499A (zh) * 2015-04-29 2015-07-15 韦利束 一种耐腐蚀的金属油墨及其制备方法

Also Published As

Publication number Publication date
CN104774499A (zh) 2015-07-15

Similar Documents

Publication Publication Date Title
WO2016173237A1 (zh) 一种耐腐蚀的金属油墨及其制备方法
JP2016515154A5 (zh)
JP2012532098A5 (zh)
CN106009976B (zh) 一种纳米抗菌内墙乳胶漆
CN106590252A (zh) 一种石墨烯改性的建筑外墙隔热涂料及其制备方法
WO2014071701A1 (zh) 一种具有3d效果陶瓷涂料及其涂覆方法
WO2016173236A1 (zh) 一种耐水、耐盐雾的塑料油墨及其制备方法
CN105153871A (zh) 一种玻璃用水漆及其制备方法
CN104130658A (zh) 一种抗污防尘外墙涂料
JP2013533923A5 (zh)
CN102558974B (zh) 一种水性裂纹砂岩涂料及其制备方法
DE11716102T1 (de) Antimikrobielle Silikazusammensetzungen
CN106433363A (zh) 一种透明耐沾污耐磨家具保护膜及其制备方法
CN103173082A (zh) 一种水性金属涂料
CN104371408B (zh) 一种水性涂料用发光铝颜料及其制备方法
CN104357599A (zh) 一种高效皮革光亮剂
CN105200494A (zh) 一种易成膜抗菌铝合金阳极氧化膜无镍封孔剂及其制备方法
CN107815150A (zh) 一种石墨烯隔热轻质涂料及其制备方法和应用
CN104293036A (zh) 耐候型建筑物外墙面装饰用水性涂料及其制备方法
CN106833316A (zh) 一种玻璃油漆
CN104789042A (zh) 一种抗uv老化的金属油墨及其制备方法
CN105176339A (zh) 一种家具防白蚁油漆
CN104891887A (zh) 一种瓷砖粘结剂
CN104789043A (zh) 一种耐水煮、耐盐雾的金属油墨及其制备方法
CN107652733A (zh) 一种水性油漆

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 15890612

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 15890612

Country of ref document: EP

Kind code of ref document: A1