WO2016104516A1 - 農園芸用有害生物防除剤組成物及びその使用方法 - Google Patents

農園芸用有害生物防除剤組成物及びその使用方法 Download PDF

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Publication number
WO2016104516A1
WO2016104516A1 PCT/JP2015/085854 JP2015085854W WO2016104516A1 WO 2016104516 A1 WO2016104516 A1 WO 2016104516A1 JP 2015085854 W JP2015085854 W JP 2015085854W WO 2016104516 A1 WO2016104516 A1 WO 2016104516A1
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Prior art keywords
compound
agricultural
horticultural
disease
composition
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PCT/JP2015/085854
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English (en)
French (fr)
Japanese (ja)
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隆夫 青木
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日本農薬株式会社
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Application filed by 日本農薬株式会社 filed Critical 日本農薬株式会社
Priority to JP2016566395A priority Critical patent/JP6731351B2/ja
Priority to KR1020177018493A priority patent/KR102490488B1/ko
Priority to MYPI2017702090A priority patent/MY190137A/en
Priority to CN201580067884.5A priority patent/CN106998689A/zh
Publication of WO2016104516A1 publication Critical patent/WO2016104516A1/ja
Priority to PH12017501034A priority patent/PH12017501034A1/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/14Ethers
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06Coating or dressing seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G7/00Botany in general
    • A01G7/06Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
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Definitions

  • the present invention provides the following formula [I]:
  • the present invention relates to an agricultural and horticultural pesticide composition characterized by containing as an active ingredient and a method of using the composition.
  • the compound (I) used as an active ingredient in the agricultural and horticultural pest control composition of the present invention is a known compound and has been reported to be useful as an insecticide (see Patent Document 1). Moreover, many compounds are known as a pest control agent (insecticide, fungicide, herbicide) (for example, refer nonpatent literature 1). However, Patent Document 1 discloses a specific combination of compound (I) and one or more compounds selected from compounds having insecticidal activity and / or bactericidal activity and / or herbicidal activity. There are no disclosures regarding technical characteristics.
  • Various pest control agents are used in the cultivation of agricultural crops.
  • This invention makes it a subject to provide the pest control agent composition which has the outstanding control effect with respect to a pest. That is, the problem to be solved by the present invention is that the compound (I) and the compound having insecticidal activity, bactericidal activity or herbicidal activity depend on the type of target pests, growth stage, habitat characteristics, etc. It is that effective control may not be possible for reasons such as difference in effect, development of resistance, restriction on the amount of use and control frequency. Therefore, there is a need for new means and methods for efficiently controlling pests that are impossible or difficult to control by a single treatment.
  • the present inventor has obtained one or more compounds selected from compound (I) and a compound having insecticidal activity and / or fungicidal activity and / or herbicidal activity.
  • the present inventors have found that a plurality of pests can be efficiently controlled by using in combination with a compound, and have further studied and completed the present invention.
  • a pesticide composition for agricultural and horticultural use comprising the compound (I) represented by the formula (I) or a salt thereof and one or more compounds selected from agricultural and horticultural chemicals other than the compound (I), [2]
  • One or more compounds selected from agricultural and horticultural agents other than compound (I) are: a. An organophosphorus compound, b. Carbamate compounds, c. A pyrethroid compound, d. A phenylpyrazole compound, e. Nicotine and neonicotinoid compounds, f. Tetronic acid and tetramic acid derivatives, g. A diamide compound, h. Diacyl-hydrazine compounds, i. A macrolide compound, j.
  • Nereistoxin analogs k. Spinosyn compounds, l. A semicarbazone compound, m. A compound having an insect growth-regulating action, n. Isoprothiolane, thiazinyl, phenoxanyl, cimeconazole and basic copper sulfate, and o.
  • One or more compounds selected from agricultural and horticultural agents other than Compound (I) are acephate, chlorpyrifos, fenobucarb, etofenprox, ethiprole (Ethiprole), fipronil, imidacloprid, dinotefuran, sulfoxaflor, thiamethoxam, triflumezopyrim, spiromesifen, spirotetramat, spirotetramat Chlorantraniliprole, flubendiamide, cyantraniliprole, tebufenozide, methoxyfenozide, abamectin, cartap hydrate ochloride, spinosad, metaflumizone, buprofezin, pymetorozine, flonicamid, pyrifluquinazon, isoprothiolane, thiazinyl fen and oxanil ox
  • the agricultural and horticultural pest control composition according to any one of [1] to [5], [7] In order to protect useful plants from pests, target pests and target useful plants can be obtained by using an effective amount of the agricultural and horticultural pest control composition according to any one of [1] to [5].
  • the present invention relates to a method for using a pesticide composition for agricultural and horticultural use, characterized in that the seed, soil or cultivation carrier of a target useful plant is treated.
  • the pest control composition for agricultural and horticultural use of the present invention, the range of pests and / or weed species to be controlled can be expanded, and the amount of each compound used can be reduced. However, a remarkable effect can be obtained even at a dose that does not provide a sufficient effect. Therefore, the agricultural and horticultural pest control composition of the present invention has a remarkable control effect against pests that could not be controlled with a single control compound and pests that exhibit drug resistance and the like. It is.
  • composition of the present invention is represented by the following formula [I]:
  • medical agents other than compound (I) are contained as an active ingredient.
  • Compound (I) (chemical name: 5- (1,3-dioxan-2-yl) -4- [4- (trifluoromethyl) benzyloxy] pyrimidine (5) contained as an active ingredient in the composition of the present invention -(1,3-dioxan-2-yl) -4- [4- (trifluoromethyl) benzyloxy] pyrimidine), the same applies hereinafter) can be produced by the production method disclosed in Patent Document 1 described above.
  • Examples of the salt of the compound (I) include inorganic acid salts such as hydrochloride, sulfate, nitrate, and phosphate, acetate, fumarate, maleate, oxalate, methanesulfonate, and benzene.
  • examples thereof include organic acid salts such as sulfonate and paratoluenesulfonate, and such salts can also be produced according to a production method known per se.
  • an agricultural and horticultural agent other than the compound (I) contained as an active ingredient in the composition of the present invention it has an insecticidal activity, a bactericidal activity or a herbicidal activity, an agricultural and horticultural insecticide, an agricultural and horticultural fungicide, Alternatively, any drug effective as an agricultural and horticultural herbicide can be used without particular limitation.
  • Diacyl-hydrazine compounds i. A macrolide compound, j. Nereistoxin analogs, k. Spinosyn compounds, l. A semicarbazone compound, m. A compound having an insect growth-regulating action, n. Isoprothiolane, thiazinyl, phenoxanyl, cimeconazole and basic copper sulfate, o. Ingredients such as insecticidal proteins produced by microorganisms can be mentioned.
  • a compound that acts as an acetylcholinesterase (AChE) inhibitor is preferably used.
  • DDVP Dimeton-S-methyl, diazinon, dichlorvos
  • DDVP dicrotophos
  • dimethoate dimethylvinphos
  • ethylthiomethone diisulfoton
  • EPN O-ethyl-O-4-nitrophenylphenylphosphonothioate
  • ethion etoprophos
  • Famful Phenamifos, Fenitrothion (MEP), Fenthione (MPP), Phosphiazate, Heptenofos, Imiciafos, Isophenfos, Isopropyl O- (Methoxyaminothiophosphoryl) salicylate, isoxathione, marathon (malathion), mecarbam, methamidophos, methidathion (DMTP), mevinphos, mono
  • organic phosphorus compound acephate, chlorpyrifos, diazinon, dichlorvos (DDVP), pyrimiphosmethyl, fenitrothion, phentoate (PAP) and the like are more preferably used, and acephate and chlorpyrifos are particularly preferably used.
  • a compound that acts as an acetylcholinesterase (AChE) inhibitor is preferably used.
  • AChE acetylcholinesterase
  • XMC 3,5-Dimethylphenyl Methylcarbamate
  • MPMC xylylcarb
  • BPMC fenobucarb
  • BPMC fenobucarb
  • a compound that acts as a sodium channel modulator is preferably used.
  • acrinatrin, bifenthrin, deltamethrin, etofenprox, lambda-cyhalothrin, zeta-cypermethrin, esfenvalerate and the like are more preferably used, and etofenprox is particularly preferably used.
  • a compound that acts as a GABAergic chloride channel blocker is preferably used, and examples thereof include ethiprol, fipronil, acetoprole, vaniliprole, pyriprole, and pyrafluprolol.
  • ethiprol, fipronil, acetoprole, vaniliprole, pyriprole, and pyrafluprolol examples thereof include ethiprol, fipronil, acetoprole, vaniliprole, pyriprole, and pyrafluprolol.
  • etiprol, fipronil, pyriprole and the like are more preferably used, and etiprol and fipronil are particularly preferably used.
  • nAChR nicotinic acetylcholine receptor
  • Examples of neonicotinoid compounds include imidacloprid, clothianidin, thiamethoxam, dinotefuran, acetamiprid, thiacloprid, nitenpyram and the like.
  • the neonicotinoid compounds include sulfilimine S-oxide compounds such as sulfoxafur, which function as nicotinic acetylcholine receptor (nAChR) competitive modulators, butenolide compounds such as flupiradiflon, triflumezopyrim, Mesoionic compounds such as dichloromesothiaz are also included.
  • the nicotine compound include nicotine sulfate.
  • imidacloprid As the nicotine and neonicotinoid compounds, imidacloprid, acetamiprid, dinotefuran, thiamethoxam, sulfoxafurol, triflumezopyrim, flupiradifuron and the like are more preferably used, and imidacloprid, dinotefuran, thiamethoxam and sulfoxafurol are particularly preferably used.
  • tetronic acid and tetramic acid derivatives compounds that act as acetyl CoA carboxylase inhibitors are preferably used, and examples include spirodiclofen, spiromesifen, and spirotetramat.
  • spirodiclofen, spiromesifen, spirotetramat and the like are more preferably used, and spiromesifen and spirotetramat are particularly preferably used.
  • a compound that acts as a ryanodine receptor modulator is preferably used, and examples thereof include fulvendiamide, chlorantraniliprole, cyantraniliprolol, cyclaniliprol, cyhalodiamide, tetraniprolol and the like.
  • fulvendiamide, chlorantraniliprole, cyantraniliprole, cyclaniliprol, tetraniprolol and the like are more preferably used, and fulbenzamide and cyantraniliprole are particularly preferably used.
  • diacyl-hydrazine compound a compound that acts as a molting hormone (ecdysone) receptor agonist is preferably used.
  • molting hormone ecdysone
  • '-benzoyl-N-tert-butylbenzohydrazide tebufenozide and the like.
  • diacyl-hydrazine compounds tebufenozide, methoxyphenoside, chromafenozide, halofenozide and the like are more preferably used, and tebufenozide and methoxyphenozide are particularly preferably used.
  • the macrolide compound a compound that acts as a glutamatergic chloride ion channel (GluCl) allosteric modulator is preferably used. Is mentioned.
  • GluCl glutamatergic chloride ion channel
  • the macrolide compound abamectin, emamectin benzoate, milbemectin, lepimectin and the like are more preferably used, and abamectin is particularly preferably used.
  • nAChR nicotinic acetylcholine receptor
  • examples thereof include bensultap, cartap hydrochloride, polythiarane, thiocyclam, and thiosultap sodium salt.
  • nAChR nicotinic acetylcholine receptor
  • j a compound that acts as a nicotinic acetylcholine receptor (nAChR) channel blocker
  • examples thereof include bensultap, cartap hydrochloride, polythiarane, thiocyclam, and thiosultap sodium salt.
  • cartap hydrochloride is particularly preferably used.
  • spinosyn compound a compound that acts as a nicotinic acetylcholine receptor (nAChR) allosteric modulator is preferably used, and examples include spinetoram and spinosad.
  • nAChR nicotinic acetylcholine receptor
  • Spinosad is more preferably used as the spinosyn compound.
  • the semicarbazone compound a compound that acts as a voltage-dependent sodium channel blocker is preferably used, and examples thereof include indoxacarb and metaflumizone.
  • examples thereof include indoxacarb and metaflumizone.
  • metaflumizone is more preferably used.
  • Examples of compounds having an insect growth regulating action include benzoylurea compounds such as bistrifluron and chlorfluazuron, thiadiadinone compounds such as buprofezin, compounds acting as stringed organ modulators such as pymetrozine and flonicamid, and pyrifluquinazone.
  • benzoylurea compounds such as bistrifluron and chlorfluazuron
  • thiadiadinone compounds such as buprofezin
  • compounds acting as stringed organ modulators such as pymetrozine and flonicamid
  • pyrifluquinazone pyrifluquinazone
  • Isoprothiolane, thiazinyl, phenoxanyl, simeconazole and basic copper sulfate, malonic acid ester compounds such as isoprothiolane, thiazole compounds such as thiazinyl, phenoxyamide compounds such as phenoxanil, triazole compounds such as simeconazole, basic copper sulfate, etc.
  • isoprothiolane, thiazinyl, phenoxanyl and the like are more preferably used.
  • insecticidal proteins produced by microorganisms include Bacillus thuringiensis, such as Bacillus thuringienses aizawai, Bacillus thuringiensis israelensis, and Bacillus thuringiensis. ⁇ Crystal protein toxins such as Bacillus ⁇ thuringienses japonensis, Bacillus thuringienses kurstaki, Bacillus thuringienses tenebrionis, etc. .
  • composition of the present invention includes the a. Group to o.
  • One group of compounds or components may be selected and used as an agricultural and horticultural agent other than Compound (I), or two or more may be selected and used in combination.
  • the active ingredient group A is (A1) agro-horticultural insecticide group; 3,5-xylyl methylcarbamate (XMC), Bacillus thuringienses (for example, Bacillus thuringiensis) ⁇ Isaiwai (Bacillus thuringienses aizawai), Bacillus thuringiensis israelensis, Bacillus thuringienses japonensis, Bacillus thuringiensis kurstaki, Bacillus thuringienses kurstaki ⁇ Crystal protein toxin (Bt toxin insecticidal compound) produced by tenebrionis (Bacillus thuringienses tenebrionis), fenocarb (Methylcarbamic acid 2-sec-butylphenyl ester
  • the compound or component contained in the active ingredient group A is a known compound or component sold in Japan or overseas or described in Non-Patent Document 1.
  • Preferred combinations of the compound (I) and agricultural and horticultural agents other than the compound (I) include the compound (I) and acephate, the compound (I) and chlorpyrifos, the compound (I) and fenocarb (BPMC), the compound (I ) And etofenprox, compound (I) and ethiprol, compound (I) and fipronil, compound (I) and imidacloprid, compound (I) and dinotefuran, compound (I) and sulfoxafurol, compound (I) and thiamethoxam, compound ( I) and triflumesopyrim, compound (I) and spiromesifen, compound (I) and spirotetramat, compound (I) and chlorantraniliprole, compound (I) and fulvendiamide, compound (I) and cyanide Traniprolol, compound (I) and tebufenozide, compound (I) and methoxyphenozide, Com
  • the agricultural and horticultural agents other than the compound (I) are selected from the a. Group to o. In each group, two or more types may be selected from the same group, or compounds or components selected from different groups may be used in combination. Moreover, you may select 2 or more types from any group of (A1) agricultural and horticultural insecticide group, (A2) agricultural and horticultural fungicide group, and (A3) agricultural and horticultural herbicide group, (A1) It may be a combination of one or more selected from the agricultural and horticultural insecticide group and (A2) one or more selected from the agricultural and horticultural fungicide group.
  • (A1) selected from the agricultural and horticultural insecticide group It may be a combination of one or more and (A3) one or more selected from the group of herbicides for agriculture and horticulture, (A2) one or more selected from the group of fungicide for agriculture and horticulture, and (A3) agriculture It may be a combination with one or more selected from the horticultural herbicide group, (A1) one or more selected from the horticultural insecticide group, (A2) one selected from the horticultural fungicide group One or more combinations selected from the above and (A3) agricultural and horticultural herbicides may be used.
  • the active ingredient is contained in 100 parts by mass of the composition.
  • the amount is usually 0.01 to 80 parts by mass, preferably 0.1 to 50 parts by mass, and more preferably 0.5 to 20 parts by mass.
  • the content ratio of the compound (I) in the active ingredient to one or more compounds selected from agricultural and horticultural drugs other than the compound (I) is such that the compound (I) is 1 part by mass.
  • the amount of one or more compounds selected from agricultural and horticultural agents other than compound (I) is usually 0.05 to 2000 parts by mass, preferably 0.1 to 200 parts by mass. More preferably, it is 0.5 to 20 parts by mass.
  • the composition of the present invention When the composition of the present invention is used, it is generally used as a preparation in a dosage form convenient for use according to a conventional method for agricultural chemical preparations. That is, the compound (I) used in the composition of the present invention and one or more of agricultural and horticultural drugs other than the compound (I) are used as appropriate inert carriers, together with auxiliary agents as necessary. It is mixed in an appropriate ratio and dissolved, dispersed, suspended, mixed, or impregnated, adsorbed or adhered, and an appropriate dosage form such as a suspension, milk suspension, emulsion, liquid, wettable powder, granule, etc.
  • an appropriate dosage form such as a suspension, milk suspension, emulsion, liquid, wettable powder, granule, etc.
  • a wettable powder a granule, a powder agent, a tablet, a pack agent, etc.
  • other dosage forms may be combined, incorporated and mixed.
  • a kneaded granule and an impregnated granule may be mixed
  • a wettable powder and a granular wettable powder may be mixed and solidified as a tablet, or a two-part solution by combining a suspension and a liquid. It can also be used as a pack agent.
  • examples of the inert carrier include a solid carrier and a liquid carrier.
  • examples of the solid carrier include clay minerals such as kaolinite (kaolin), sericite, and talc, and clay (clay) such as bentonite, acid clay, and attapulgite.
  • Minerals such as quartz, pyrophyllite, zeolite, diatomaceous earth; inorganic salts such as calcium carbonate, ammonium sulfate, sodium sulfate, potassium chloride; synthetic silicic acid and synthetic silicates such as precipitated silica, fumed silica, calcium silicate; starch Plant carriers such as cellulose, plant powder (eg sawdust, coconut cob, corn cob, tobacco stem); plastic resin carriers such as polyethylene, polypropylene, polystyrene, polyvinylidene chloride, polyethylene terephthalate; urea-aldehyde resins, etc. Thermosetting tree ; Perlite, porous particulate support of vermiculite; plastic hollow bodies and the like. These may be used alone or in combination of two or more.
  • liquid carrier examples include monohydric alcohols such as methanol, ethanol, propanol, isopropanol, and butanol, and polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol, and glycerin.
  • monohydric alcohols such as methanol, ethanol, propanol, isopropanol, and butanol
  • polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol, and glycerin.
  • Polyhydric alcohol derivatives such as propylene glycol ether; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, and cyclohexanone; ethers such as ethyl ether, dioxane, ethylene glycol monoethyl ether, dipropyl ether, and tetrahydrofuran Aliphatic hydrocarbons such as normal paraffin, naphthene, isoparaffin, kerosene, mineral oil; Aromatic hydrocarbons such as benzene, toluene, xylene, solvent naphtha and alkylnaphthalene; halogenated hydrocarbons such as dichloromethane, chloroform and carbon tetrachloride; ethyl acetate, diisopropyl phthalate, dibutyl phthalate, dioctyl phthalate, dimethyl adipate,
  • Esters include lactones such as ⁇ -butyrolactone; amides such as dimethylformamide, diethylformamide, dimethylacetamide, N-alkylpyrrolidone (N-methylpyrrolidone, etc.); nitriles such as acetonitrile; sulfur compounds such as dimethylsulfoxide And vegetable oils such as soybean oil, rapeseed oil, cottonseed oil and castor oil; and water. These may be used alone or in combination of two or more.
  • auxiliary agents include dispersants, wetting agents, spreading agents, spreading agents, binders, tackifiers, thickeners, coloring agents, stabilizers, disintegrating agents, and drift inhibitors.
  • auxiliary agents include dispersants, wetting agents, spreading agents, spreading agents, binders, tackifiers, thickeners, coloring agents, stabilizers, disintegrating agents, and drift inhibitors.
  • These additive components may be used alone or in combination of two or more.
  • Various surfactants are used as the dispersant.
  • polyhydric alcohols such as glycerin, polyethylene glycol and sorbitol
  • water-soluble polymers such as sodium polyacrylate
  • nonionic surfactants and the like are used.
  • the spreading agent examples include silicone surfactant, cellulose powder, dextrin, modified starch, polyaminocarboxylic acid chelate compound, polyhydric alcohol polymer and half ester of dicarboxylic acid anhydride, and the like.
  • spreading agents include various surfactants, terpenes, polyamide resins, higher fatty acid esters of polyoxyethylene polyoxypropylene glycol, polyacrylates, waxes, polyvinyl alkyl ethers, and the like.
  • surfactant used as the dispersing agent, wetting agent, spreading agent, spreading agent and the like examples include sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, polyoxyethylene fatty acid ester, poly Oxyethylene resin acid ester, polyoxyethylene fatty acid diester, polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether such as polyoxyethylene alkyl phenyl ether, polyoxyethylene dialkyl phenyl ether, polyoxyethylene alkyl phenyl ether formalin condensate, Polyoxyethylene polyoxypropylene block copolymer, polystyrene polyoxyethylene block polymer, alkyl polyoxyethylene polypropylene block Copolymer ether, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene fatty acid bisphenyl ether, polyoxyalkylene benzyl phenyl ether, polyoxyalkylene styryl phen
  • Cationic surfactants such as alkylamine salts such as laurylamine hydrochloride, stearylamine hydrochloride, oleylamine hydrochloride, stearylamine acetate, stearylaminopropylamine acetate, alkyltrimethylammonium chloride, alkyldimethylbenzalkonium chloride; amino acids And amphoteric surfactants such as molds or betaines. These surfactants may be used alone or in combination of two or more.
  • binder or tackifier examples include saccharides such as sucrose; polysaccharides such as dextrin, water-soluble starch, modified starch, gum arabic, xanthan gum, guar gum; cellulose such as cellulose powder, carboxymethyl cellulose and salts thereof, and derivatives thereof.
  • Phospholipids such as cephalin and lecithin; polyacrylic acid salts such as polyvinyl alcohol, polyvinyl alkyl ether, polyvinyl acetate, polyvinyl pyrrolidone, cross-linked polyvinyl pyrrolidone and sodium polyacrylate, polyethylene glycol having an average molecular weight of 6000 to 20000, average molecular weight of 100,000 ⁇ 5 million polyethylene glycol, polyaminocarboxylic acid chelate compound, copolymer of maleic acid and styrene, (meth) acrylic acid copolymer, polyhydric alcohol Rimmer and half ester of a dicarboxylic acid anhydride, water-soluble salts of polystyrene sulfonic acid, a polyamide resin, an alkylphenol formalin condensate, polymers such as a synthetic resin emulsion; paraffin, terpene, wax.
  • polyacrylic acid salts such as polyvinyl alcohol, polyvin
  • thickener examples include polysaccharides such as xanthan gum, guar gum, diyutan gum, and starch derivatives; water-soluble polymers such as carboxymethylcellulose, polyvinylpyrrolidone, carboxyvinyl polymer, and acrylic polymers; high-purity bentonite, fumed silica ( Inorganic fine powders such as fumed (silica, white carbon).
  • polysaccharides such as xanthan gum, guar gum, diyutan gum, and starch derivatives
  • water-soluble polymers such as carboxymethylcellulose, polyvinylpyrrolidone, carboxyvinyl polymer, and acrylic polymers
  • high-purity bentonite fumed silica
  • fumed silica Inorganic fine powders such as fumed (silica, white carbon).
  • the colorant examples include inorganic pigments such as iron oxide, titanium oxide, and Prussian blue; organic pigments such as alizarin dyes, azo dyes, and metal phthalocyanine dyes.
  • stabilizers include sodium benzoate, potassium sorbate, parahydroxybenzoic acid ester, 1,2-benzothiazolin-3-one, and preservatives such as formalin solution; various solvents such as ethylene glycol, diethylene glycol, propylene glycol, and glycerin.
  • Anti-caking agents such as starch, alginic acid, mannose, galactose, etc., polyvinylpyrrolidone, fumed silica (fumed silica, white carbon), ester gum, petroleum resin, etc .; zeolite, quick lime, Decomposition of desiccants such as magnesium oxide, phenolic antioxidants, amine antioxidants, sulfur antioxidants, antioxidants such as phosphoric acid antioxidants, UV absorbers such as benzophenone UV absorbers, etc. An inhibitor etc. are mentioned.
  • Disintegrants include sodium tripolyphosphate, sodium hexametaphosphate, metal stearate, cellulose powder, dextrin, methacrylate copolymer, polyvinylpyrrolidone, polyaminocarboxylic acid chelate compound, sulfonated styrene / isobutylene / maleic anhydride copolymer Coalesced starch, polyacrylonitrile graft copolymer and the like.
  • an anti-drift agent in the case of an emulsion, a water-soluble polymer such as methyl cellulose, polyvinyl alcohol, starch or the like is used, and polyisobutylene is used as an oil agent.
  • a water-soluble polymer such as methyl cellulose, polyvinyl alcohol, starch or the like
  • polyisobutylene is used as an oil agent.
  • the wettable powder polyethylene glycol, polypropylene glycol, glycerin or the like is used, and as the powder, petroleum resin, polystyrene, polyvinyl acetate, epoxy resin or the like is used.
  • activity enhancers such as metabolic degradation inhibitors such as piperonyl butoxide can be used as necessary.
  • the pest control composition of the present invention containing compound (I) and one or more compounds selected from agricultural and horticultural chemicals other than compound (I) includes paddy rice, fruit trees, vegetables, etc.
  • Agricultural crops such as Japanese crops, various agricultural pests that harm useful plants such as horticultural plants such as flowering plants, stored pests for stored grains such as rice and flour, livestock pests that harm livestock, and humans Suitable for pest control such as sanitary pests and nematodes related to animal diseases.
  • Pests for which the pest control composition of the present invention is effective include, for example, Lepidoptera (Lepidoptera), for example, Parasa consocia, Red moth mesogona, Papilio xuthus, Azusa moth (Matsumuraeses azukivora), Azukinomeiga (Ostrinia scapulalis), African clover (Spodoptera mpmpta), American white starfish (Hyphantria cunea), Awanoi moth (Ostrinia furnacalis), Akayotoga (Pseudaletia separata), Iga (Tinea act actlucen) Parnara guttata), rice bran (Marasmia exigua), rice squirrel (Sesamia inferens), red squirrel (Brachmia triannulella), moth moth (Monema flavescens), Iraq saginu wa (Trichoplusia ni),
  • Tamanayaga (Agrotis ipsilon), Chadokuga (Euproctis pseudoconspersa), Chanokakumonmonakiki (Adoxophyes orana), Chanohosoga (Caloptilia theivora), Chahamaki (Homona (Clostera anachoreta), crested saga (Heliothis maritima), maggot (Sparganothis pilleriana), corn borer (Busseola fusca), edible moth (Euproctis subflava), tomon fruit worm (Biston robustum), tomato fruit zea (Heliothis maribusta) leucomelas), Nashiiraga (Narosoideus flavidorsalis), Nashikenmon (Viminia rumicis), Nashichibiga (Bucculatrix pyrivorella), Nashihimeshini (Grapholita molesta), Nashihosoga (Spulerina astaurota), Narimadella
  • Fall army worms (Spodoptera frugiperda), Japanese moths (Ostrinia zaguliaevi), scallops (Naranga aenescens), scallops (Andraca bipunctata), grape squirrel (Paranthrene regalis), grape sparrows (Acosmerytop ⁇ archanis Grape Himehamaki (Endopiza viteana), Grape Hosohamaki (Eupoecillia ambiguella), Velvet Bean Caterpillar (Anticarsia gemmatalis), Hosoba Hiirohamaki (Cnephasia cinereipalpana), Maimaiga (Lymantria dispar), Matsukariha Legumes (Maruca testulalis), Bean peas (Matsumuraeses phaseoli), Bean moth (Caloptilia soyella), Citrus scallop (Phyllocnistis citrella), Miss winged moth (Hadylepta indicata), Midareco chip sap Nkin'u
  • Hemiptera Hemiptera (Hymenoptera), for example, Nezara antennata, Stenotus rubrovittatus, Graphosoma rubrolineatum, Trigonotylus coelestiales maculatus), red beetle turtle (Creontiades pallidifer), red beetle bug (Dysdercustuscingulatus), red beetle aphid (Chrysomphalus ficus), red beetle (Aonidiella aurantii), abazemi (Graptopsaltria Scale insects (Icerya purchasi), Japanese beetle (Piezodorus hybneri), rice beetle (Lagynotomus elongatus), rice beetle (Thaia subrufa), rice beetle (Scotinophara lurida), abirai Sakikamemushi (Stariodes iwasakii), Humpback
  • Grape Leaf Hopper (Erythroneura comes), Black-footed Beetle (Paromius exguus), Black-footed Bug (Duplaspidiotus claviger), Nephotettix nigropictus, Black-headed turtle (Halticielluskinchard) Black Whale (Psylla malivorella), Anomomeura mori, Pseudococcus longispinis, Pseudaulacaspis pentagona, Pulvinaria polywaum (Togo hemipterus), Komikan Aphid (Toxoptera aurantii), sugarcane scale insect (Saccharicoccus sacchari), sugar beetle (Geoica lucifuga), sugar beetle (Numata muiri), Sanjo Zephylla (Comstockaspis perniciosa), Citrus snow scale (Unaspis citri), Potato beetle aphid (Aulacorthum solani), Shiraho
  • Green planthopper (Nilaparvata lugens), Japanese horned leaf lice (Psylla tobirae), Japanese turtle (Eurydema rugosum), Japanese horned beetle (Schizaphis piricola), Japanese horned lice (Psylla pyricola), Nacyclohoshi kaishigashi (Parri Dysmicoccus wistariae), Pepper scale insect (Lepholeucaspis japonica), Pepper aphid (Sappaphis piri), Flounder aphid (Lipaphis erysimi), Nephidrum (Neotoxoptera formosana), ny d ), Haranaga scale insects (Pinnaspis aspidistrae), Hanpachi lice (Psylla alni), Hannoga leafhopper (Speusotettix subfusculus), Hannohime leafhopper (Alnetoidia alneti), Hyoeunka (Sogatella panicicola
  • Leafhopper leafhopper (Macrosteles fascifrons), Spotted beetle (Dolycoris baccarum), Spotted beetle (Adelphocoris triannulatus), Grape aphid (Viteus vitifolii), Greater leaf beetle (Acanthocoris sordidus) Bark beetle (Macropes obnubilus), Bark beetle (Cletus punctiger), Bark beetle (Riptortus clavatus), Potato pirido (Paratrioza cockerelli), Maeki waffle (Aphrophora costalis), L Pinus cricket (Crisicoccus pini), Pin worm (Crisicoccus matsumotoi), bean aphid (Aphis craccivora), beetle (Megacopta punctatissimum), beetle (Eysarcoris guttiger), beetle aphes beckii), citrus leaf pe
  • Coleoptera (Coleoptera), for example, Xystrocera globosa, Blue-tailed scallop (Paederus fuscipes), Ahanamuri (Eucetonia roelofsi), Azuki weevil (Callosobruchus chinensis), Arimodokisium Hypera postica), weevil (Echinocnemus squameus), rice beetle (Oulema oryzae), rice beetle (Donacia provosti), rice weevil (Lissorhoptrus oryzophilus), moss beetle (Colasposoma sipeme tus) (Acanthoscelides obtectus), Western corn rootworm (Diabrotica virgifera virgifera), weevil weevil (Involvulus cupreus), cucumber weevil (Aulacophora femoralis), pea weevil (Bruchus pisorum) Interview Uyah-spotted ladybird
  • Yellow-tailed beetle (Psacothea hilaris), Yellow-tailed beetle (Aeolesthes chrysothrix), Curculio sikkimensis, Carpophilus hemipterus, Oxycetonia jucima, corn root splendens, Sitophilus zeamais, Tribolium castaneum, Sitophilus oryzae, Palorus subdepressus, Melolontha) orpasia Leaf beetle (Leptinotarsa decemlineata), Southern corn root worm (Diabrotica undecimpunctata howardi), Bark beetle (Sphenophorus venatus), Bark beetle (Crioceris quatuordecimpunctata), Green weevil (Conotrachelus enenup) Icon weevil (Ceuthorhynchidius albosuturalis), radish beetle (
  • White-tailed beetle (Adoretus tenuimaculatus), White-tailed rice beetle (Tenebrio molitor), White-footed beetle (Basilepta balyi), Red-footed weevil (Hypera nigrirostris), Tentobi-malyp picea), Epilachna vigintioctopunctata, Northern corn root worm (Diabrotica longicornis), Eurtonia pilifera, Bark beetle (Agriotes spp.), Himetsuobushimushi (Attagenus unicolor japagria), Attagenus unicolor japag signata), Anomala rufocuprea, Palorus ratzeburgii, Alphitobius laevigatus, Anthrenus verbasci, Lyctus brunneus (Lyctus brunneus) usum), Medythia nigrobilineata, grape
  • Pine saw beetle (Monochamus alternatus), bean squirrel (Popillia japonica), bean scorpion (Epicauta gorhami), maize weevil (Sitophilus zeamais), peach chow weevil (Rhynchites heros), moth ), Apple beetle (Phyllobius armatus), Apple beetle (Anthonomus pomorum), Luri beetle (Linaeidea aenea), Cotton weevil (Anthonomus grandis),
  • Diptera for example, Culex pipiens pallens, red winged fly (Pegomya hyoscyami), red winged fly (Liriomyzamyhuidobrensis), Musca domestica, (Hydrellia sasakii), Agromyza oryzae, Bonefly's flyfly (Hydrellia griseola), Ophiomyia phaseoli, Dacus cucurbitae, Dercus cucurbitae, Drosophila ), Fruit flies (Muscina stabulans), flea flies (Phoridae) such as Megaselia spiracularis, giant flies (Clogmia ⁇ ⁇ ⁇ albipunctata), tipula aino,
  • Black flies (Phormia regina), Culex tritaeniorhynchus, Sycaenidae (Anopheles sinensis), Daikon fly (Hylemya brassicae), Soybean fly (Asphondylia sp.), Tanelia flyfish (Delia letura) cerasi), Chikaieka (Culex pipiens molestus Forskal), Ceramitis ⁇ capitata, Bradysia agrestis, Sugar beetle (Pegomya cunicularia), Liriomyzae motivation (Liriomyza Chromatomyia horticola), green winged fly flies (Liriomyza chinensis), Culex quinquefasciatus, Aedes aegypti, Aedes albopictus, winged fly flies (Liriomyza trifolii), Liriomyza tri
  • Hymenoptera for example, Prawns (Pristomyrmex ponnes), Butteridae (Bethylidae), Houseworm (Monomorium pharaosis), Pheidole noda, Athalia rosae, Kurita fusca japonica), hornets (Vespinae), black-backed bee (Athalia infumata), horned bee (Arge pagana), Japanese wasp (Athalia japonica), squirrel (Acromyrmex spp.), fire ant (Solenopsis spp. Arge mali), Ruriari (Ochetellus glaber),
  • Diptera for example, Crested (Homorocoryphus lineosus), Kera (Gryllotalpa sp.), Coago (Oxya hyla intricata), Cobainago (Oxya yezoensis), Tonosama locust (Locusta migraja), Oneaya Homorocoryphus jezoensis), Emmacricket cricket (Teleogryllusmaemma),
  • Thrips for example, Selenothrips rubrocinctus, Rice thrips (Stenchaetothrips Abiformis), Thrips thrips (Haplothrips aculeatus), Thrips thrips (Ponticulothrips diospyrous) , Lithrips floridensis, Thrips simplex, Thrips nigropilosus, Helothripes Leeuwenia pasanii), Shiritakuthamis (Litotetothrips pasaniae), Citrus srips (Scirtothrips citri), Hempothrips chinensis, Soybean thrips (Mycterothrips glycines), Soybean Black thrips (Thrips hawaiiensis), red-eared thrips (Haplothripsrdkurdjumovi), bearded thrips (Chirothrips manicatus), black-e
  • Mite order for example, Leptotrombidium akamushi, Asinoa spider mite (Tetranychus ludeni), American dock ticks (Dermacentor variabilis), Imitani spider mite (Tetranychus truncatus), House mite (Ornithonyssus bacoti), Dick mite viennensis), kanzawa spider mite (Tetranychus kanzawai), chestnut spider tick (Rhipicephalus sanguineus), red winged tick (Dermacentor taiwanicus), black-legged tick (Haemaphysalis longicornis), black-legged tick (Ixodes scapularis), ticks (Ixsodidae), stag beetles (Cheyletus malaccensis), red tick (Tyrophagus putrescentiae), red mite (Dermatophagoides farinae), red tick (Acaphylla theavagrans) ago
  • Termites e.g., Amphi Termites (Reticulitermes Kitemoto termite (Glyptotermes kushimensis), Kushwei termite (Coptotermes guangzhoensis), Kushushi termite (Neotermes koshunensis), Kobayashi termite (Glyptotermes kodamai), Satsuma termite Nakajima termite (Glyptotermes nakajimai), Nitobe termite (Pericapritermes nitobei), Yamato termite (Reticulitermes speratus),
  • Amphi Termites Reticulitermes Kitemoto termite (Glyptotermes kushimensis), Kushwei termite (Coptotermes guangzhoensis), Kushushi termite (Neotermes koshunensis), Kobayashi termite (Glyptotermes kodamai), Satsuma termit
  • Cockroaches for example, Black cockroach (Periplaneta fuliginosa), German cockroach (Blattella germanica), Great cockroach (Blatta orientalis), Greater cockroach (Periplaneta brunnea), Greater cockroach (Blattella lituricollis), americana),
  • Fleas for example, human fleas (Pulex irritans), cat fleas (Ctenocephalides felis), chicken fleas (Ceratophyllus gallinae),
  • Spider eyes for example, Latrodectus hasseltii,
  • Nematodes for example, strawberry nematode (Nothotylenchusrisacris), rice scallop nematode (Aphelenchoides besseyi), red-footed nematode (Pratylenchus penetrans), red-footed nematode (Meloidogyne hapla), sweet potato nematode (Meloidogyne moth geraod) rostochiensis), Java root-knot nematode (Meloidogyne javanica), soybean cyst nematode (Heterodera glycines), Syringa nematode (Pratylenchus coffeae), Mugi-Negusa nematode (Pratylenchus neglectus), Mikanne nematode semipus
  • Mollusks such as Pomacea canaliculata, Achatina fulica, slugs (Meghimatium bilineatum), Lehmannina valentiana, Limacus flavus, Acusta despecta sieb, etc. Can be mentioned.
  • the composition of the present invention is preferably used against stink bugs among the above-mentioned pests.
  • compositions of the present invention belong to a wide variety of filamentous fungi, for example, Phycomycetes, Ascomycota, Deuteromycota and Basidiomycota Not only has an excellent bactericidal effect on filamentous fungi, but also has an excellent effect on phytopathogenic bacteria and plant viruses. Therefore, the composition of the present invention can effectively suppress plant diseases against various useful plants generated by filamentous fungi, phytopathogenic bacteria and plant viruses.
  • plant diseases in which the composition of the present invention is effective include the following.
  • the name of the pathogenic microorganism is shown in parentheses.
  • Rice diseases include, for example, yellow dwarf disease (S. macrospora), seedling blight (F. avenaceum, R. chinensis, T. viride), idiot seedling disease (Gibberella fujikuroi), rice blast disease (M.
  • grisea Pyricularia oryzae
  • coat blight R.solani
  • sesame leaf blight C.miyabeanus
  • brown panicle A.padwiki
  • red rice E.nigrum
  • rice koji C.virens
  • Bacterial blight P.glumae
  • leaf sheath browning P.fuscovaginae
  • brown streak P.avenae
  • seedling blight P.plantarii
  • white blight X.oryzae
  • Corn diseases include, for example, sesame leaf blight (B.maydis, C.heterostrophus), soot spot (E.turcicum), spot disease (P.maydis), smut (U.maydis), etc .:
  • diseases of tobacco include plague (P. nicotianae / parasitica), downy mildew (P. tabacina), powdery mildew (E. cichoracearum), anthrax (C. tabacum), red star disease (A. longipes, A.alternata), soot disease (C. salicinum), yellowing disease (O. brassicae), etc .:
  • tea diseases include erythema carcinoma (N. cinnabarina), leprosy (E. leucospila), anthrax (C. theae-sinensis), and ring spot (P. longiseta, P. theae). , Net blast (E.reticulatum), blast (E.vexans), red fire (P.syringae pv.theae), etc .:
  • Food crop diseases include, for example, sweet potato black spot (C.fimbriata), green mold (P.expansum), root rot (T.basicora); oat crown rust (P.coronata); Blight (S.mori); Oil palm ganoderma disease (G.boninense); Date palm eye spot (S.palmivora), etc .:
  • Examples of the diseases of cruciferous plants include root-knot disease (P. brassicae), white rust disease (A. macrospora), downy mildew (P. brassicae), mycorrhizal disease (S. sclerotiorum), black spot disease ( A. brassicae); cabbage root rot (P.lingam), strain rot (T.cucumeris), black rot (X.campestris pv.campestris); rape white spot (C.brassicicola); Disease (C.brassicicola) etc .:
  • strawberries examples include plague (P.cactorum, P.nicotianae), powdery mildew (S.macularis), anthrax (G.cingulata), black spot (A.alternata), and snake eye disease (M. fragariae) etc .:
  • diseases of solanaceous plants include S. sclerotiorum, powdery mildew (S. furiginea), brown spot (P. vexans), subtilis (M. nattrassii), bacterial wilt ( P. solanacearum); tomato plague (P. infestans), anthrax (C. phomoides), leaf mold (C. fulvum), spot disease (S. lycopersici), ring rot (A. solani), ulcer disease (C. michiganensis), etc .; Pepper spot disease (S. lycopersici); Pepper spot disease (S. lycopersici), etc .:
  • diseases of the cucurbitaceae plants include cucurbits of cucurbits (P. melonis), vine split diseases (F.oxysporum f.sp.cucumerinum, F.oxysporum f.sp. meronis); .cubensis), powdery mildew (S. furiginea), vine blight (M.melonis, D.bryoniae), mycoses (S.sclerotiorum), anthrax (C.lagenarium), brown spot (C.cassiicora) ), Black spot disease (C. cucumerinum), bacterial spot disease (P. syringae pv. Lachrymans); watermelon vine blight (M. melonis, D. bryoniae), etc .:
  • onions and onions include, for example, onion downy mildew (P. destructor), black spot (A. porri), rust (P. allii); onion leaf blight (P. herbarum), fungus Nuclear disease (S. sclerotiorum), gray rot (B. alli), white spotted blight (B. byssoidea, B. squamosa), dry rot (F. oxysporum f. Sp. Cepae), etc .:
  • Root diseases include, for example, carrot black leaf blight (A.dauci); Japanese radish black spot (A.brassicicola):
  • Examples of the diseases of flower buds include rose blight (P. megasperma), powdery mildew (S. pannosa), rust (K. rosae / japonica), black scab (D. rosae); (S.chrysanthemi-indici), spot disease (C.chrysanthemi), white rust (P.horiana); chisha downy mildew (B.lactucae); aster downy mildew (B.lactucae); Root cancer disease (A. tumefaciens), etc .:
  • red rot of grass P.apahanidermatum
  • summer patch M.poae
  • Helmintosporium leaf blight D.poae
  • dollar spot S.homoeocarpa
  • Anthracnose C.graminicora
  • Carbaria leaf blight C.geniculata
  • Large patch R.solani
  • Brown patch R.solani
  • Snow rot Pythium sp., S.borealis, M.nivalis, F.nivale, T.ishikariensis, T.incarnata
  • Pasture black sesame disease P.graminis
  • Clover moth leaf spot P.trifolii
  • Pasture blight E.typhina
  • Alfalfa leaf spot P.medicaginis
  • macular disease P.medicaginis
  • stem blight P.medicaginis
  • wheat diseases include snow rot (Pythium sp., M.nivalis, S.borealis, F.nivale, T.ishikariensis, T.incarnata), red mold (G.zeae, F.avenaceum, F. .graminearum, F. culmorum, M.nivale), ergot disease (C.purpurea), blight (G.graminis), stock rot (C.gramineum), sharp eyespot (C.cereale), powdery mildew ( B.graminis f.sp. Tritici), blight (L. nodorum, S.nodorum), red rust (P.recondita), black rust (P.
  • Barley diseases include, for example, snow rot (Pythium sp., S. borealis, M. nivalis, F. nivale, T.ishikariensis, T.incarnata), red mold (G.zeae, M.nivale, F) .avenaceum, F.graminearum, F. culmorum), ergot disease (C.purpurea), blight (G.graminis, O.graminis), streak disease (C.gramineum), powdery mildew (B.graminis f) sp.
  • Hordei Hordei), reticulum disease (P.teres), leafy leaf disease (P.graminea), spot disease (B.sorokiniana, C.sativus), leaf burn (C.herbarm), cloud disease (R. secaris), black rust (P. graminis), yellow rust (P.striiformis), scab (P. hordei), black scab (U.hordei), etc .:
  • Potato diseases include, for example, powdery scab (S. subterranea), scab (S. scabies), plague (P. infestans), summer plague (A. solani), black bruise (R. solani) ), Ring rot (C. michiganensis), ring lot disease (C. michiganensis), etc .:
  • sugar beet diseases include black root disease (A.cochlioides), leaf rot (T.cucumeris), root rot (T.cucumeris), snake eye disease (P.betae), and brown spot disease (C.beticora). , Spot disease (R.beticora), rust fungus (U.betae), etc .:
  • Examples of the diseases of legumes include sclerotia (S. sclerotiorum); soybean rust (P.pachyrhizi), downy mildew (P.manshurica), purpura (C.kikuchii), and sunspot (D.phaseolorum). var. sojae), black rot (E.glycines), charcoal rot (M.phaseolina), black root rot (C.crotalariae); groundnut rot (C.crotalariae), black astringency (M.personatum) ), Common scab (S. arachidis), black mold (A. niger), brown spot (C. arachidicola); brown bean disease (C. arachidicola), anthracnose (C.
  • apple diseases include powdery mildew (P. leucotricha), rot (V. ceratosperma), white coat (R. necatrix), purple coat (H. mompa), and black spot (V. inaequaris), spotted leaf disease (A.mali), moniliosis (M.mali), anthracnose (G.cingulata), ring rot (Botryosphaeria sp.), blacklot disease (B.obtusa), sunspot disease (M .pomi), brown spot disease (D.mali), red star disease (G.yamadae), cedar-apple rust (G.Juniperi-virginianae), Shirohirotake disease (S.commune), silver leaf disease (C.purpurreum) , Root cancer disease (A. tumefaciens), burn disease (E.amylovora), etc .:
  • Pear diseases include, for example, white coat (R.necatrix), black spot (V.nashicola), black spot (A.kikuchiana), red spot (G.asiaticum), powdery mildew (P.pyri) ), Ring rot (P.piricora), blight (P.fukushii), heart rot (L. sulphureus), root cancer (A.tumefaciens), burn (E.amylovora), etc .:
  • Grape diseases include, for example, white coat (R. necatrix), gray mold (B. cinerea), downy mildew (P. viticola), powdery mildew (U. necator), late rot (G .cingulata), black rot (E.ampelina), brown spot (P.vitis), rust (P.ampelopsidis), blacklot (G.bidwellii), pestarothia vine (P.menezesiana), California Disease (X.fastidiosa), root cancer disease (A.vitis), etc .:
  • the diseases of peach include, for example, T. deformans, M. fructicola, C. carpophilum, Phomopsis sp., Mildew disease (A. niger) ), Spot disease (C.beyerinckii), root cancer disease (A.tumefaciens), perforated bacterial disease (X.campestris pv.pruni), etc .:
  • Citrus diseases include, for example, white feather (R. necatrix), gray mold (B. cinerea), sunspot (D. citri), scab (E. fawcettii), black spot (G. citricarpa), circle star disease (P.beltranii), anthracnose disease (C.gloeosporioides), green mold disease (P.digitatum), blue mold disease (P.icitalicum), plump disease (G.applanatum), soot disease ( C. salicinum), ulcer disease (X.campestris pv.citri), stubborn disease (S.citri), greening disease (C.Liberibacter), etc .:
  • diseases of trees and flowers include powdery mildew (M.akebiae), powdery mildew of alder (M. penicillata), Dutch elm disease (O.ulmi), and round spot disease (G. .ulmi); chestnut blight (E. parasitica); apricot blight (L .. persoonii), cherry black knot (A. morbosa), rust (T. asiatica / prumi-spinosae), Stem heart rot (F. pinicora); pine soot leaf disease, needle blight (R. kalkhoffii); pine species Diplodia blight (S. sapinia), leaf sieving disease (L.
  • Other diseases of fruit trees include, for example, ume powdery mildew (P. tridactyla), black scab (C. carpophilum); oyster lobster (M. nawae), anthrax (G. kaki), leaves Blight (P.diospyri), cutlet leaf (C.kaki), black spot (F.levieri); loquat anthracnose (C.acutatum); banana sigatoka (M.fijiensis / musicola), panama (F.oxysporum f.sp.cubense); mango anthracnose (C. gloeosporioides); white cabbage (R. necatrix) for all fruit trees, root cancer (A. tumefaciens), etc.
  • ume powdery mildew P. tridactyla
  • black scab C. carpophilum
  • oyster lobster M. nawae
  • anthrax G. kaki
  • leaves Blight P.diospyri
  • various seedling diseases P.ultimum, P.apahanidermatum
  • various root rots P.cinnamomi
  • white coat rot R.necatrix
  • rot V.ceratosperma
  • half body Dwarf disease V. dahliae, V. albo-atrum
  • gray mold disease B. cinerea
  • mycorrhizal disease S. sclerotiorum
  • white silk disease S. rolfsii
  • vegetable blight R. solani
  • Purple coat feather H. mompa
  • soft rot E. carotovora, E. aroideae
  • root cancer A. tumefaciens
  • plant diseases caused by phytopathogenic bacteria include cucumber spotted bacterial diseases (P. syringae pv. Lachrymans), rice brown stripe disease (P. avenae), and seedling blight (P. plantarii). ), Bacterial wilt (P.glumae), leaf sheath browning (P.fuscovaginae) and white leaf blight (X.oryzae), solanaceae plant blight (P.solanacearum), tea red burning (P.
  • cucumber spotted bacterial diseases P. syringae pv. Lachrymans
  • rice brown stripe disease P. avenae
  • P. plantarii seedling blight
  • Bacterial wilt P.glumae
  • leaf sheath browning P.fuscovaginae
  • white leaf blight X.oryzae
  • solanaceae plant blight P.solanacearum
  • tea red burning P.
  • composition of the present invention has an excellent bactericidal effect against resistant bacteria.
  • Resistant bacteria include Botrytis cinerea, which is resistant to benzimidazole fungicides such as thiophanate methyl, benomyl and carbendazim, Cercospora beticola, apple black rot (Venturia inaequalis), pear And Venturia nashicola; gray mold fungus (Botrytis cinerea) that is resistant to dicarboximide fungicides (eg, vinclozolin, procymidone, iprodione), and the like.
  • Plant diseases caused by plant viruses include, for example, tomato mosaic disease (tobacco mosaic virus), cucumber green spot mosaic disease (cucumber green spot mosaic virus), tobacco stem rot (tobacco stem virus), and wheat atrophy Disease (wheat dwarf virus), barley spotted mosaic disease (wheat spotted mosaic whis), potato tuber brown ring spot disease (potato mop top virus), sugar beet root disease (beat beetle leaf yellowing virus), tomato Mosaic disease (potato virus X), apple high contact disease (apple stem grooving virus, apple chlorotic leaf spot virus), tomato mosaic disease (potato virus Y), ume ring spot disease (ume ring spot virus), cucumber mosaic disease ( Cucumber mosaic virus, watermelon mosaic virus Zucchini yellow mosaic virus), radish mosaic disease (turnip mosaic virus), soybean mosaic disease (soy mosaic virus), barley stripe dwarf disease (barley stripe dwarf virus), barley yellow dwarf disease (barley yellow dwarf virus), soybean dwarf disease (Soybean dwarf virus), strawberry virus disease (
  • composition of the present invention is also effective as a herbicide.
  • weeds in which the composition of the present invention is effective dicotyledonous plants include the genus Ipomoea, Lindernia, Sesbania, Abbutilon, Matricaria, Inugarashi.
  • Monocotyledonous plants include the genus Azegaya (Leptochloa), the genus Phleum, the strawberry genus (Poa), the genus Festuca, the genus Setaria, the genus Eleusine, the genus Sagittaria, Genus Agropyron, Ischaemum, Cyperus, Avena, Vromus, Panicum, Cynodon, Monochoria, Sparrow Alopecurus genus, Paspalum genus, Commelina genus, Fimbristylis genus, Lolium genus, Brachiaria genus, Agrostis genus, Eleocharis genus, Echinochlona Plants such as the genus, the genus Scirpus, the genus Digitaria, and the sorghum are listed.
  • Milkweed (Asclepias syriaca), Caterpillar (Euphorbia maculata), Psyllium (Plantago asiatica), Carpenter (Amaranthus palmeri), Red fir (Xanthium Sagittaria trifolia, Dutch burro (Erodium cicutarium), Dutch southern primrose (Cerastium glomeratum), Orchard moth (Matricaria matricarioides), Chamomile (Matricaria chamomilla), Carasno pea (Vicia angustifolia), venus romus A venom (Rotala indica Koehne), Ripex japonicus, Yellowbird (Cyperus esculentus), Golden crow (Setaria glauca), Kudu (Pueraria lobata), Eleocharis kuroguwai Ohwi, mulberry (f), Ambrosia tri Nungmarigold (Chrysanthemum segetum), Kogomegatsuri
  • Vulture (Alopecurus aequalis), Portulaca oleracea, Solidago altissima, Sorghum halepense, Brassica juncea, Tanxacum volicensis (Taraxacum officulus) ), Buckwheat (Polygonum convolvulus), Echinochloa oryzicola Vasing, Thaichaeia (Ischaemum rugosum), Veronica arvensis, Cyperus difformis L.
  • Cyperus rotundus Amaranthus spinosus, Hargonde (Polygonum ⁇ persicaria), Papaver rhoeas, Sunflower (Helianthus annuus), manniagi (Lamium purpureum), Himekug Conyza canadensis), Potamogeton distinctus A.
  • Benn Amaranthus tuberculatus, field pansy (Viola arvensis), ragweed (Ambrosia artemisiifolia), black grasshopper (Veronica hederaemocurus) tortuosum, Plantago lanceolata, Spiderfish ( ⁇ Alisma canaliculatum A.
  • Useful plants to which the composition of the present invention can be used are not particularly limited.
  • grains for example, rice, barley, wheat, rye, oats, corn, etc.
  • beans for example, rice, barley, wheat, rye, oats, corn, etc.
  • beans for example, rice, barley, wheat, rye, oats, corn, etc.
  • beans for example, rice, barley, wheat, rye, oats, corn, etc.
  • beans for example, rice, barley, wheat, rye, oats, corn, etc.
  • beans for example, rice, barley, wheat, rye, oats, corn, etc.
  • beans for example, rice, barley, wheat, rye, oats, corn, etc.
  • beans for example, rice, barley, wheat, rye, oats, corn, etc.
  • beans for example, rice, barley, wheat, rye, oats, corn, etc.
  • the composition of the present invention is used as it is to control various pests, or is appropriately diluted with water or the like, or suspended in an amount effective for pest control in a plant that is predicted to generate pests.
  • Used against For example, pests that occur in fruit trees, cereals, vegetables, etc. are sprayed on the foliage. It can also be used for seed treatment, soil or cultivation carrier treatment, addition to paddy fields, addition to nutrient solution in hydroponics, soot, tree injection, application to building materials, etc. Can be used.
  • the present invention provides an agricultural and horticultural pest control agent that treats a target pest, a target useful plant, soil, or a cultivation carrier with an effective amount of the composition of the present invention in order to protect the useful plant from the pest.
  • a method of using the composition (hereinafter also referred to as “the method of the present invention”) is also provided.
  • examples of the target pest include various pests such as the above-mentioned agricultural pests, stored grain pests, livestock pests, sanitary pests, filamentous fungi that become pathogens of plant diseases, bacteria, plant viruses, and the like.
  • useful plants protected from such pests include cereals, beans, fruit trees / fruits, leaves / fruit vegetables, root vegetables, processing crops, pastures, turf, fragrance / spicy plants, flower buds. Plants such as plants, garden trees and timber.
  • the composition of the present invention which is a liquid preparation or wettable powder such as an emulsion or a flowable preparation, or a solid preparation such as a granular wettable powder, is appropriately added with water or the like.
  • a method of diluting and spraying the stems and leaves of useful plants and various pests, a method of injecting them into tree trunks, a method of spraying or smoking the composition of the present invention as a powder, and seeds of target useful plants of the present invention And a method of treating with the composition.
  • Examples of the method for treating seeds of target useful plants include, for example, a method of immersing seeds as a solution or suspension without diluting or diluting the composition of the present invention as a liquid or solid preparation, a solid preparation or a liquid
  • Examples thereof include a method, a method of spraying the composition of the present invention in the vicinity of seeds at the same time as planting.
  • the “seed” for performing the seed treatment means a plant body at an early stage of cultivation used for plant propagation. For example, in addition to seeds, nutrition for bulbs, tubers, seed buds, buds, baskets, bulbs or cuttings cultivation Mention may be made of plants for breeding.
  • “soil” or “cultivation carrier” treated with the composition of the present invention refers to a support for cultivating a target useful plant, particularly a support for growing roots
  • the material is not particularly limited as long as it is a material on which the plant can grow, and may be so-called soil, seedling mat, water, and the like. Specific materials include, for example, sand, pumice, vermiculite, diatomaceous earth, It may be agar, gel material, polymer material, rock wool, glass wool, wood chip, bark or the like.
  • soil or a cultivation carrier includes paddy rice seedling boxes, paddy fields, cultivation carriers used for field crops, nutrient solution for hydroponics and the like.
  • a method for treating soil or a cultivation carrier for example, a method of applying the composition of the present invention as a liquid preparation to a plant source of a target useful plant or a nursery for raising seedlings without diluting in water , A method of spraying the composition of the present invention as a granule on a plant stock or a seedbed for raising seedlings, before sowing or transplanting, the composition of the present invention as a liquid preparation is applied to a nursery for raising seedlings
  • composition of this invention made into a powder agent, a wettable powder, a granular wettable powder, a granule etc. to a planting hole, a crop, etc. before planting a plant body, etc. are mentioned.
  • the dosage form that can be selected for formulation may differ depending on the treatment time such as sowing, greening time, transplanting time, etc. What is necessary is just to process as dosage forms, such as a summing agent and a granule. It can also be processed by mixing with soil, and the soil can be mixed with the composition of the present invention as a powder, granulated wettable powder or granule, for example, mixed with floor soil, mixed with covering soil, mixed into the entire soil, etc.
  • the composition of the present invention in the form of soil and various preparations may be applied alternately in layers.
  • the composition of the present invention as a solid preparation such as a jumbo agent, a pack agent, a granule, a granule wettable powder, a liquid preparation such as a flowable agent, an emulsion, etc.
  • a solid preparation such as a jumbo agent, a pack agent, a granule, a granule wettable powder, a liquid preparation such as a flowable agent, an emulsion, etc.
  • an appropriate preparation can be sprayed and injected into the soil as it is or mixed with fertilizer.
  • the composition of the present invention as an emulsion, a flowable agent, or the like as a source of water flowing into a paddy field such as a water mouth or an irrigation device, it can be processed labor-saving along with the supply of water.
  • Field crops can be treated with seeds or cultivating carriers close to plants during sowing and seedling periods.
  • treatment on the plant source of the plant being cultivated is suitable.
  • a spraying treatment can be performed using the composition of the present invention as a granule, or an irrigation treatment can be performed with a liquid composition of the present invention diluted or not diluted with water. It is also a preferable treatment to mix the composition of the present invention as a granule with a cultivation carrier before sowing and then sow.
  • composition of the present invention is formulated into a dosage form usually employed in the art, for example, an emulsion, a wettable powder, a wettable granule, a flowable, a liquid, a granule, a powder, a smoke or the like.
  • the amount used is compound (I), which is an active ingredient, and the proportion of agricultural and horticultural chemicals other than compound (I), weather conditions, dosage form, time of use, method of use, place of use, target Although it varies depending on the type of pest, the type of target useful plant, etc., usually the amount of active ingredient per 1 are (total amount of agricultural and horticultural drugs other than Compound (I) and Compound (I)) is in the range of 0.1 to 1000 g.
  • the seed treatment it can be used in the range of 0.01% to 50% by weight as the active ingredient amount relative to the seed weight, and can be used in the range of 0.1% to 10% by weight. preferable.
  • concentration used is 0.00001% to 0.1% by weight as the active ingredient.
  • composition of the present invention includes a nuclear polyhedrosis virus (NPV), a granular disease virus (Granulosis virus, GV), a cytoplasmic polyhedrosis virus (Cytoplasmic polyhedrosis virus, CPV), an insect pox virus (Entomopox virus, Virus preparations such as EPV, Monocrosporium phymatophagum, Steinernema carpocapsae, Steinernema kushidai, Pasturia ⁇ ⁇ trima derma Agrobacterium radiobactor, nonpathogenic Erwinia carotovora, Bacillus subtilis, Xanthomonas campestris, Boberia Buron'niati (Beauveria brongniartii) microbial pesticide such as,
  • part means part by mass.
  • the control rate calculated from the evaluation results obtained by treating with the composition of the present invention containing the compound (I) and other agricultural and horticultural chemicals is the active ingredient contained in the composition of the present invention. It can be said that the composition of the present invention exhibits a synergistic effect if it exceeds the expected value (E) calculated from the control rate obtained when treated with a sample contained alone.
  • the evaluation results are shown in Tables 1 to 3.
  • Control rate (%) (1 ⁇ number of surviving insects / number of surviving insects in control group) ⁇ 100
  • test insects (Nilaparvata lugens) (6 males and 6 females) (6 males and 6 females) were released.
  • test insects Naparvata lugens
  • the same amount of water was sprayed instead of the sample, and the test insects were released in the same manner and treated in the same manner.
  • the control rate was calculated according to the above [Equation 1]
  • the expected value (E) was obtained from the above [Equation 2].
  • the composition shown in Table 5 was used as a sample, the number of living insects was measured 41 days after the treatment, and the control rate and expected value (E) were calculated.
  • Test Examples 1 and 2 showed that the control effect of the composition of the present invention is synergistically improved as compared with the case where each agricultural and horticultural agent is used alone.
  • the composition of the present invention containing compound (I) and each of flonicamid, pyrifluquinazone and pymetrozine is used when the concentration of flonicamid, pyrifluquinazone and pymetrozine is 1 ppm. Even in the case of various use ratios, the test insects died 100% after 6 days of treatment, and a synergistic improvement in the control effect was observed.
  • Control effect 4 against brown planthopper (Nilaparvata lugens)
  • the composition of the present invention was prepared by dispersing compound (I) and isoprothiolane in water at respective concentrations shown in Tables 8 and 9. Each concentration of compound (I) and isoprothiolane was dispersed in water alone to prepare a sample.
  • (2) Evaluation of control effect The control effect was evaluated in the same manner as in Test Example 3. However, the number of live and dead insects was measured 12 days after the immersion treatment with the sample, and the mortality rate was calculated. The evaluation results are shown in Tables 8 and 9.
  • Control effect 5 against brown planthopper (Nilaparvata lugens)
  • the composition of the present invention was prepared by dispersing compound (I) and etiprol in water at respective concentrations shown in Tables 10 and 11. Each concentration of Compound (I) and Ethiprole was each dispersed in water alone to prepare a sample.
  • Evaluation of control effect The control effect was evaluated in the same manner as in Test Example 3. However, the number of live and dead insects was measured 12 days after the immersion treatment with the sample, and the mortality rate was calculated. The evaluation results are shown in Tables 10 and 11.
  • Control effect 6 against brown planthopper (Nilaparvata lugens)
  • compound (I) and triflumezopyrim of each concentration were each dispersed in water alone to prepare a sample.
  • (2) Evaluation of control effect The control effect was evaluated in the same manner as in Test Example 3. However, the number of live and dead insects was measured 45 days after the immersion treatment with the sample, and the mortality rate was calculated. The evaluation results are shown in Table 12.
  • Control effect 7 against brown planthopper (Nilaparvata lugens)
  • the composition of the present invention was prepared by dispersing compound (I) and each of methoxyphenozide and etofenprox in water at each concentration shown in Table 13.
  • compound (I), and methoxyphenozide and etofenprox at each concentration were each dispersed in water and used as a sample.
  • Evaluation of control effect The control effect was evaluated in the same manner as in Test Example 2. However, the number of surviving insects was measured 38 days after the treatment with the sample, the control rate was calculated, and the expected value (E) was calculated. The evaluation results are shown in Table 13.
  • a pest control composition for agricultural and horticultural use capable of synergistically improving a pest control effect and efficiently controlling a plurality of pests is provided. Can do.

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