WO2016054872A1

WO2016054872A1 - Application of fire-proof explosion-proof plate glass having high softening point, low differential high-temperature region thermal expansion coefficient, and low crystallisation speed

Info

Publication number: WO2016054872A1
Application number: PCT/CN2015/000508
Authority: WO
Inventors: 杨德宁
Original assignee: 杨德宁
Priority date: 2014-10-10
Filing date: 2015-07-15
Publication date: 2016-04-14

Abstract

Application of fire-proof explosion-proof plate glass having a high softening point, a low differential high-temperature region thermal expansion coefficient, and a low crystallisation speed, comprising, according to percentage by weight, 0.01%-39% aluminium oxide content, 7%-20% magnesium oxide content, silicon oxide content being 2.51-4.8 times that of calcium oxide content, and the calcium oxide content being 1.0-1.8 times that of the magnesium oxide content; the difference in thickness of the plate glass under 20mm is less than 0.01-0.4mm.

Description

A high softening point, low difference of thermal expansion coefficient in high temperature zone, low crystallization rate, application of fireproof and explosion-proof flat glass

Technical field

The invention belongs to the field of flat glass, and relates to a special flat glass, in particular to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass.

The invention mainly belongs to a new use invention of a chemical product;

A. In new applications, new glass products [low crystallization rate] material properties have been discovered, which are unclear in common knowledge and cannot be inferred from common sense.

B. Known for the known compounds [difference in the coefficient of thermal expansion of the high temperature region] and [softening point] properties and [bending strength properties] and the unexpected technical effects produced by these new properties, there is substantial Improvements and improvements; this is also not clear in common sense and cannot be inferred from common sense.

C. Application range in new applications, such as: 1. Glass for construction; 2. Glass for automobile; 3. Glass for ship; 4. Glass for railway car; 5 aircraft glass; 6. Glass for fireproof and explosion-proof; ; 8. Wall-mounted glazed glass decorative panels and other application products; and various combinations of inventions such as: 1. High-performance glazed glass furniture, 2. High-performance cars, 3. High-performance solar aircraft, 4. High The performance of the solar power generation device, the combined use of the terminal product of the invention, the new properties discovered by the present invention and the unexpected technical effects resulting from these new properties. It represents a technological development trend in the field of application applications; the present invention also overcomes the technical problems in the above-mentioned fields of use that people are eager to solve but have never succeeded.

Background technique

(1) First Comparative Technology 1: The inventor's prior invention: application and related components of flat glass with high annealing point, high strength, high flatness and low viscosity characteristics with environmental protection, energy saving and emission reduction, Patent No. 201110060944.4,

(2) First Invention 2: The inventor's 201510161553.61, a flat glass having a low coefficient of thermal expansion and a preparation process thereof.

(3) Inventive 3: Inventor's 201410408822.3, a flat glass produced by a cooling portion anti-crystallization method,

(4), prior invention 4: The inventor's: 201110060913.9, a high annealing temperature and high intensity environmental protection and energy-saving low melting point glaze decorative flat glass,

(5) There is a comparison technology 5:

First of all, the scope of the technical solution of the Japanese International Publication No. 01/034531 is not the same as the scope of the technical solution of the present invention.

(6), prior to the comparison of technology 6:

Proportional relationship to the patented technology of the comparative US005925583A:

Scope of the technical solution and the technical scope of the present invention, the technical solution is different from the description of the present invention:

(7) First invention:

U.S. Patent No. 3,929,497 (December 30, 1975) patent.

The patent name is: crystallizable glass for fiber production

Equipment and methods for testing the nature of products:

(A) Method for testing the softening point: a Japanese TAS-100 type comprehensive thermal analyzer was used.

(B) A method for testing the low difference in the coefficient of thermal expansion of the high temperature zone, the coefficient of expansion of the glass is determined in accordance with the standard GB/T7320.1-2000. It is currently measured using the world's best thermal resistance instrument from the German company Nitz; the result is from 60 ° C to 800 ° C, a thermal expansion value of E-06 / ° C per 10 ° C, or from 60 ° C It has a thermal expansion value of E-06/°C per 10°C at 740°C; from which the difference in thermal expansion rate in the more severe high temperature range of 650°C-700°C is within 0.1-0.99 parts per million, at a more severe high temperature. The difference in thermal expansion coefficient between 700 ° C and 740 ° C in the high temperature region of 1-5.9 or 6-8 is a comparison of the lower differential coefficients of the prior art.

(C) Using the temperature-measuring ladder temperature furnace, the on-line [highest point] and the lower line [lowest point] of the crystallization temperature of various glass materials to be measured were measured.

(D) Using a glass melting furnace, the crystallization rate of different glasses is tested at the upper line [ie, the highest point] of the crystallization temperature region of the glass, and the temperature is gradually lowered: (not inspired by the prior art) The test purpose characteristics and test equipment and test methods of the new material properties of the glass crystallization rate are also defects caused by the crystallization of the unique technical weakness of the type products of the present invention, and the original First):

In the specification of the present invention, the magnitude of the minute value of all the crystallization rates, and thus the speed of the crystallization rate, are determined by the same glass melting furnace specified in the lower part, and the analysis of the different glasses specified in the lower part. The data obtained from the test method of crystal velocity is based on:

a. The characteristics of the selected glass melting furnace are:

1. The glass melting furnace is provided with a display for accurately measuring the temperature inside the furnace for observing and recording temperature changes.

2. The overall thermal insulation performance of the selected glass melting furnace should be good. The temperature in the furnace should be kept at least 1500-850 °C for a period of 150 minutes or more; that is, the glass liquid is in the furnace. It is sufficient time for the temperature inside to remain at least 150 minutes or more to complete the natural temperature lowering process of the furnace temperature of 1300-850 °C. (Because the upper line range of the glass crystallization temperature zone of the product of the invention is mostly within the range of 1300--850 ° C, for example, the upper line range of the glass crystallization temperature zone of a product is: 1230--920 ° C)

b. Test purpose:

Since the product of the present invention has the characteristic that the upper line [highest point] of the crystallization temperature is higher than the molding temperature, in order to study the selective use of glass having a relatively slow crystallization rate in large production, it is advantageous to form before molding in large production. Especially in the cooling work part, the glass liquid cooling process stage, reducing the risk of devitrification of the glass liquid; in particular, in the cooling work part of the liquid line edge and corners and bottoms, which are easy to devitrify, add some heating control devices, and add The temperature is controlled to be higher than the crystallization temperature on the line 50-80 ° C;

However, the actual state is that in the corners and bottom of the cooling working part, due to the slow flow of some areas of the molten glass, some products, in some areas with slower flow, the temperature of the molten glass drops faster. The apex of the crystal temperature began to drop, and in only 31 minutes, the glass of such products produced local crystallization. This will make such products, in large production, after entering the molding stage, is prone to the risk of product failure of the partial devitrification of the flat glass.

Therefore, in large production, the glass product having the relatively slow crystallization rate of the present invention should be selectively used, because of its relatively slow crystallization rate: 60-90 when the temperature of the glass liquid starts to fall from the apex of the crystallization temperature. No crystallization occurred within minutes or 60-150 minutes. The slow crystallization rate of the glass liquid of the glass material discovered by the invention can be beneficial to solve the problem of local devitrification in the corners and bottom of the cooling working part, and in some slow-flowing areas; Slow, so in some flow In the slower area, it is possible to overcome the risk of unqualified products which tend to cause local crystallization and devitrification during the forming stage of the flat glass.

c. Test method for crystallization rate of different glasses:

In the first step, the temperature of the crystal ladder is measured first, and the on-line [highest point] and the lower line [lowest point] of the crystallization temperature of various glass materials to be measured are measured.

The second step,

Put the glass raw material into the melting pot;

2. Put it in a glass melting furnace;

3. Turn off the power after melting to make the glass melting furnace cool naturally;

4. According to the upper line [highest point] of the crystallization temperature of the glass to be measured (for example, 1230--920 °C), the temperature of the internal temperature of the furnace is observed to be more accurate (for example, 1230 ° C) Time to the time period required for the measurement;

5. If the melting pot is taken out after 20 minutes, the glass liquid will be quickly cooled to glass and observed for crystallization. Thus, the glass to be measured is obtained from the upper line of the crystallization temperature [highest point]. Naturally cool down the nature of the crystallization rate for 20 minutes; or take out the melting pot after 45 minutes; or remove the melting pot after 60 minutes; or remove the melting pot after 90 minutes; or remove the melting pot after 120 minutes; or 150 minutes After that, the melting pot was taken out; the nature of the crystallization rate of the glass to be measured, which was naturally lowered from the upper line [highest point] of the crystallization temperature of 20, 45, 60, 90, 120, and 150 minutes.

(E) A method for testing the viscosity temperature using a US THETA rotary high temperature viscometer.

(F) For the test flexural strength, the sample was cut into 50 mm × 50 mm × 5 mm strips and measured by a flexural strength tester according to the standard GB/T3810, 4-2006.

Summary of the invention

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of a fireproof and explosion-proof flat glass, characterized in that the alumina content is 0.01% - 39% by weight, magnesium oxide The content is 7%-20%, the silicon oxide content is 2.51-4.8 times of the calcium oxide content, the calcium oxide content is 1.0-1, 8 times of the magnesium oxide content, and the thickness difference of the flat glass within the thickness of 20 mm is 0.01 mm-0.4. Mm.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 0.01% - 39% by weight, sodium oxide The content is 0.001%-18%, the magnesium oxide content is 7%-20%, the silica content is 2.51-4.8 times of the calcium oxide content, the calcium oxide content is 1.0-1,8 times of the magnesium oxide content, and the thickness is less than 20mm. The thickness of the flat glass is between 0.01 mm and 0.4 mm.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 0.01% - 39% by weight, sodium oxide The content is 0.001%-0.9% or 0.91-8.8% or 8.9-18%, the magnesium oxide content is 7%-20%, and the silica content is 2.51-4.09 times or 3.61-4.09 times or 3.61-4.8 of the calcium oxide content. Times. The calcium oxide content is 1.0-1, 8 times of the magnesium oxide content, and the thickness difference of the flat glass within the thickness of 20 mm is 0.01 mm-0.4 mm.

The invention relates to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the softening point is 750 ° C - 860 ° C; The folding strength is 60-240Mpa.

A flat glass according to claim 1, wherein the low temperature expansion rate in the high temperature region is characterized by a difference in thermal expansion rate within 1.2 parts per million in a high temperature region of 550 ° C to 600 ° C. In the high temperature range of 600 ° C to 650 ° C, the difference in thermal expansion rate is within 0.1-0.99 parts per million, and in the high temperature range 650 ° C - 700 ° C, the difference in thermal expansion rate is within 0.1-0.99 parts per million.

A flat glass according to claim 1, wherein the difference in thermal expansion rate is in the range of 1-5.9 or 6-8 parts per million in the high temperature region of 700 ° C to 710 ° C.

The invention relates to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass according to claim 1, characterized in that the alumina content is 4% by weight. --8% or 8.1-12% or 12.1-23% or 23.1-32% or 32.1-39%,

The method for preparing a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass according to any one of claims 1 to 6, wherein:

Step 1. Various types of glass formulation configurations according to any one of claims 1-6

The predetermined component and the predetermined raw material of the composition of the specific ratio between the silicon oxide, the calcium oxide and the magnesium oxide are mixed and stirred, and melted at a melting temperature corresponding to each glass formulation to form a glass liquid having a predetermined viscosity, and then To clarify, discharge bubbles, and form a flowable melt;

In step 2, the glass is formed by a float process, a flat pull process, a lattice process, a calendering process, an overflow process, or any one of the processes.

The method for preparing a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion proof flat glass according to claim 7, wherein:

The step 1 includes:

The various raw materials prepared are placed in the respective raw material containers, and the various raw materials are passed through the raw material conveying line, and after being metered, they are sent to the raw material mixing and stirring device in the required proportion, stirred and mixed, and then loaded into the raw materials.

In the bulk material or silo containing the ingredients;

The matched raw materials are introduced into the molten pool and melted at a melting temperature corresponding to each glass formulation to form

a predetermined viscosity of the molten glass, which is homogenized, clarified, and discharged to form a flowable melt;

The float process is used in step 2: in the process, the tin kiln must be prepared in advance, and after the step of step 1, the flowable melt at the tail of the molten pool is poured into the tin kiln for flattening, polishing, and thinning. The process, and the pulling of the puller in the direction specified by the process and the traction of the tractor, pull out the tin bath, and through the upper line range of the glass crystallization temperature zone, under the condition of gradually cooling, annealing, waiting After cooling, the glass is obtained by cutting.

Effect of the Invention According to the present invention, it is possible to provide a high softening point, a low crystallization rate, a special aluminum-free alkali-free, fire-proof and explosion-proof flat glass. In addition, a preparation method suitable for the high softening point, low crystallization rate, special aluminum non-alkali, fireproof and explosion-proof flat glass can be provided.

A high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 4% to -29% by weight, and oxidation The sodium content is 0.011-0.99%, the magnesium oxide content is 7%-20%, the silica content is 2.52-4,08 times of the calcium oxide content, and the calcium oxide content is 1,0-1,8 times of the magnesium oxide content. .

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 16.1 to 35% by weight percent, and the sodium oxide content is 1 to 18%, the boron oxide content is 0.0001 to 3%, the magnesium oxide content is 7% to 20%, the silicon oxide content is 2.53 to 4.09 times the calcium oxide content, and the calcium oxide content is 1.0 to 1.8 times the magnesium oxide content.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 16.1 to 35% by weight percent, and the sodium oxide content is 1 to 13%, the magnesium oxide content is 7% to 20%, characterized in that the content of silicon oxide is 2.52 to 4.08 times of the content of calcium oxide, and the content of calcium oxide is 1.0 to 1.8 times of the content of magnesium oxide.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 4%-29%, and the sodium oxide content is 0.011-0.99 %, the content of lithium oxide is 0.0001 to 3%, the content of boron oxide is 0.0001 to 3%, the content of magnesium oxide is 7% to -20%, the content of silicon oxide is 2.53-4, 09 times of the content of calcium oxide, and the content of calcium oxide is The magnesium oxide content is 1.0-1.8 times.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the silicon oxide content is 2.6-4.09 times of the calcium oxide content,

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 6-29%.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 8-29%.

A high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 10-29%.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 16.1-29%.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 25-39%.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 23-29%.

A high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the sodium oxide content is 0.001-0.99% or 0.001-2.99% or 3-9%.

A high softening point, a low difference in thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the sodium oxide content is 0.001-0.45%.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of a fireproof and explosion-proof flat glass, characterized in that the thickness of the glass is 0.1-0.2 mm.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass, characterized in that the thickness of the glass is 0.51-0.7 mm.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the thickness of the glass is 0.21-0.5 mm.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the thickness of the glass is 0.31-0.4 mm.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass, characterized in that the thickness of the glass is 0.71-1.5 mm.

A high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass

It is characterized in that the thickness of the glass is 1.5-2 mm.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass, characterized in that the thickness of the glass is 2.1-5 mm.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass, characterized in that the thickness of the glass is 5.1-8 mm.

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the thickness of the glass is 8.1-20 mm.

The following 41 types of high softening point, low differential coefficient of thermal expansion coefficient in low temperature zone, low crystallization rate, and application of the composite combination of fireproof and explosion-proof flat glass, first because of a high softening point, low temperature coefficient of thermal expansion Difference, low crystallization rate, fireproof and explosion-proof flat glass, in the use of flat glass:

New [a. low crystallization rate] material properties were found; well known to known compounds [b. difference in thermal expansion coefficient in high temperature zone] and [c. high softening point] and [d. low viscosity and The properties of the eutectic of aluminum, silicon, calcium and magnesium at high aluminum content] and the various effects produced are substantially improved and improved.

These material properties and technical effects are integrated into each of the combination inventions, forming an interrelated and supportive support for each of the 42 categories of crust combinations; for the corresponding 42 categories of traditional products, New unanticipated functions and unpredictable technical effects; all of the 42 traditional products that have never been revealed, and the non-obvious technical effects that have never been revealed; and because of these non-obvious technical effects, they are also known. Common sense is not clear and cannot be inferred from common sense; therefore, there is substantial progress and creativity.

It is also possible to combine the properties of these materials with each new type of knot formed, and judge that it is an invention of a change in the relationship of the elements; in the invention, the relationship between the different elements of each of the 42 types of the combination is changed for the corresponding 42 In the case of traditional products, new and unpredictable functions and unexpected technical effects are produced. It is also unclear in common sense and cannot be inferred from common sense; therefore, there is substantial progress. And creativity.

(Class A) Decorative Building Materials Dependent Claims Application Use Invention and Combination Invention Terminal Product Category 3 Scarf Combination Application Invention:

(Class A) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 1:

A high-performance color glazed flat glass, characterized in that the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, the substrate thereof The surface of the glass has a glaze layer of 1-10 colors.

Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thus, the high-quality fire-proof and explosion-proof flat glass of the present invention without any crystallization due to the influence of light transmittance is produced.

Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the [higher softening point] of the flat glass of the present invention, [better thermal expansion difference in high temperature region, [high performance such as higher strength], the shape of the glass can be maintained, and fire, fire, and separation can be achieved. The non-obvious technical effect of the heat wave; the invention has special fireproof and explosion-proof effects of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.

Non-obvious technical effects [3]: Controllable economy, standardization and ease of construction design of glazed flat glass:

The invention can be printed into a large one because of the characteristics of a high softening point and a low thermal expansion rate in a high temperature region.

2400 × 1200mm ultra-thin thickness of 1-4mm standard board, providing the suitability and convenience of transportation and use of decorative materials; (this is impossible to achieve such as ceramics and stone products).

Non-obvious technical effects [4]: According to the present invention, the first comparative technique [1][2][3][4] has a flexural strength vertex from 180 MPa, substantial improvement and improvement to a bending strength apex of 240 MPa; Compared with the prior art [1][2][3][4], the flexural strength is substantially improved and increased by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; The flexural strength of the touch screen glass containing 12-15% of aluminum is increased by about 2.4 times, and the bending strength of the calcium sodium glass is increased by about 5 times.

In the field of application, the flexural strength; can be substantially improved and improved by 1/4 compared with the prior art [1][2][3][4]; the flexural strength of the existing boron-containing glass is 80Mpa. It is increased by about 3 times; it is about 2.4 times higher than the existing 20-15% touch screen glass flexural strength 100Mpa; it is about 5 times higher than the calcium sodium glass bending strength 50Mpa.

It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It can also be edged and cut like a tile to ensure the defect-free pattern and standardization of the product board and the use of cutting convenience. It can replace the high-energy thick tile (8-15mm) and the 15-25 stone wall with the 1-4mm thick product of the invention, and the product is 5 times lighter and thinner.

The high-strength, light-thinning replacement of existing ceramic products, resulting in several times lighter and thinner energy, resources, logistics, and warehousing, can produce 4-8 times less energy-saving non-obvious technical effects.

[1] wear resistance to ceramics and stone , [2] non-slip performance, [3] extremely low water and antifouling properties, [4] high strength and ultra-thin properties, [5] ultra-light oversized panel products Features, [6] upper wall and dry hanging method, etc., have six revolutionary advantages; can overcome the difficulties of efficiency, energy saving and environmental protection of the entire traditional ceramic process equipment; and can overcome the high energy consumption, high pollution and high of ceramic industry Difficulties in dust emissions, high water consumption, and low output efficiency; there are non-obvious technical effects.

(Class A 2) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 2:

A high-performance wear-resistant color glaze flat plate glass, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass The surface of the substrate glass has a glaze layer of 1-10 colors, and the glaze layer of the surface layer contains 15-70% quartz crystal or alumina crystal.

Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.

Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.

Non-obvious technical effect [3]: Since the product of the invention can sinter the colored glaze layer below 650-740 ° C, the printing glaze layer can be sintered, and a large amount of various crystals such as 30-80% can be added to the glaze layer, especially Low-cost quartz or steel jade crystal powder or granules, forming an unprecedented hardness of 0.2-3mm wear-resistant surface layer (quartz up to 7 grade hardness, while steel jade can reach grade 9 hardness), and this is in ceramic production Can not be done, because the ceramic firing temperature is 1100 ° C -1200 ° C, at this time the ceramic surface of the quartz or steel jade can only become the glass phase, and below 730 ° C, quartz or steel jade crystals can remain crystal Phase; this can also form an unprecedented decorative glass polished quartz crystal with a hardness of 7 grade wear surface; with non-obvious technical effects.

Non-obvious technical effect [4]: The quartz surface layer can be polished due to the hardness of 7 grade, which becomes the optimal surface quartz glaze combination polishing and wear-resistant product; while the 9-grade hardness of steel jade is not polished, but Unexpectedly, it is an optimal durable anti-slip or wear-resistant steel jade enamel layer combination application invention product, so the invention can form an alternative upgrade technology of energy saving, environmental protection, low cost and high quality wear resistance. It also poses an alternative challenge to the ceramic industry's high energy consumption, high pollution, high dust emissions, high water consumption, low output, low quality products and the entire equipment process system. Has a non-obvious technical effect.

Non-obvious technical effect [5]: The present invention compares the apex of the first comparative technique [1][2][3][4] from 180Mpa, substantial improvement and improvement to the apex of bending strength 240Mpa; Compared with the prior art [1][2][3][4], the flexural strength is substantially improved and increased by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; The flexural strength of the touch screen glass containing 12-15% of aluminum is increased by about 2.4 times, and the bending strength of the calcium sodium glass is increased by about 5 times.

In this field of application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is lighter than the existing TFT boron-containing glass. 1/3; lighter than calcium sodium glass, 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.

Therefore, it can make a high-performance wear-resistant glaze layer flat glass, instead of high-energy thick and wear-resistant ceramic tile (8-15mm) and 15-25 stone ground products, it is 5-6 times lighter and thinner. The high-strength, light-thinning replacement of ceramic products, resulting in several times lighter and thinner energy, resources, logistics, and warehousing, can produce 4-8 times less energy-saving non-obvious technical effects.

Non-obvious technical effect [6]: a. 2-5mm thick can be equal to 10-25mm thick calcium soda glass strength]; b.160cm x240cm 200cm x 300cm or 300cm x 400cm large size of the high performance wear-resistant glaze layer of the present invention Flat glass products, used to design and replace all kinds of carpets, not only high strength, light and convenient installation and transportation, but also can be printed by computer, which guarantees the formation of various realistic carpet textures such as wool, chemical fiber and silk material; c. Among them, the quartz surface layer can be polished due to the hardness of 7 grade, which becomes the best surface quartz glazed combination polishing and wear-resistant product, or becomes the best durable non-slip matte carpet pattern with wear-resistant steel jade enamel layer. Application of the invention.

(Class A 3) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 3:

A high-performance ultra-thin wall-faced glazed flat glass, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof For the application of flat glass, the surface of the substrate glass has a glaze layer of 1-10 colors, and the thickness thereof is 0.5-1.5 mm.

Non-obvious technical effect: In the application place, the present invention compares the prior art [1][2][3][4] in the case of fire or high temperature, in the state of high temperature zone, due to the invention Flat glass [higher softening point], [better high temperature zone thermal expansion difference, [higher strength and other high performance], can maintain the shape of the glass, can play fire, fire, heat wave Non-obvious technical effects; The invention has special fireproof and explosion-proof effects of building materials, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technical effect.

The invention has the prior art [1][2][3][4] bending strength apex from 180Mpa, substantial improvement and improvement to the bending strength apex 240Mpa;

Therefore, a high-performance ultra-thin veneer glazed flat glass can achieve a strength of 2.5-7.5 mm calcium soda glass under a very lightweight condition of 0.5-1.5 mm.

So to replace the traditional decorative wall paper:

Non-obvious technical effects [1]: a high-performance ultra-thin veneer glazed flat glass, a. using electrospray process to make all decorative wall paper patterns; b. using matt inorganic glaze materials, in glass The surface can be used to make a pattern of all decorative wall paper without reflection; c. or use the prior art to create a higher level of pattern pattern than any decorative wall paper, such as gold, silver, silver gray;

Non-obvious technical effect [2]: A high-performance ultra-thin veneer glazed flat glass: a. The flatness of the veneer can be like a mirror surface, and the flatness of the traditional decorative wall paper is incomparable; b. Basically flat, laminated with a thin layer of tile adhesive, the base is simpler than the decorative wall paper, saving labor time; c. Now using the decorative wall paper 100cm x 350cm or 200cm x 350cm size, can be used in continuous wall stitching, More accurate alignment of the pattern than the soft decorative wall paper, which has a better overall wall surface than the decorative wall paper; d. It can be more convenient than the soft decorative wall paper when the continuous wall is spliced. e. A high-performance ultra-thin veneer glazed flat glass, in the use of alternative decorative wall paper, has better characteristics of not easy to accumulate dust, easy to clean and care; f. decorative wall paper for 2-3 years The seam is easy to roll up, the quality cycle is only about 3 years, and the wallpaper has a service life of 3-6 years. The high-performance ultra-thin veneer glazed flat glass of the invention can never be used. The left and right seams are easy to roll. High-performance inorganic glaze layer and enamel strength glass life of 100-300 years On.

Non-obvious technical effect [3]: A high-performance ultra-thin veneer glazed flat glass, especially suitable for wood interior wall applications of wooden building villas: a. because it can be very thick in 0.5-1.0mm Under light conditions, it can overcome the problem that the total support of the wooden building villa and the inner wall of the wooden board can not bear too much weight; b. can also reach the strength of 2.5-6mm calcium soda glass; c. can reach the inner wall of the wooden building villa The surface is unprecedentedly more than the overall sense of the decorative wall paper plane, and the mirror flatness; d. It can reach and exceed the pattern texture effect of all the decorative wall paper of the traditional decorative wall paper.

However, the present invention provides a high-performance ultra-thin veneer glazed flat glass instead of decorative wall paper. In order to adapt to the wooden building villa which has a long history of the house, the inner wall of the wooden board has a slightly modified application; or to prevent new The wall surface of the wooden board has been slightly modified after many years. The countermeasures are: [1] the improvement of the softness characteristics of the traditional porcelain glue; [2] the double-sided glue on the inner wall of the board is set in the ultra-thin veneer The structure of the back surface of the glazed flat glass can greatly increase the sticking convenience and efficiency; [3] in the mounting size of a high performance ultra-thin veneer glazed flat glass of the present invention, from 100cm x 350cm or 200cm x 350cm Dimensions, changed to 60cm x 60cm or 90cm x 90cm or 120cm x 120cm or 150cm x 150cm size: to achieve a. can adapt to the inner wall of the board with a slightly modified application; b. installation can not only save labor, but also reach When splicing the wall continuously, it can accurately align the pattern with the soft decorative wall paper, and it can have the effect of never rolling up the upper, lower, left and right seams;

(Class B) Construction and industrial supporting deep processing, dependent claims Application use Invention and structure knot combination application invention 10 products:

(Class B 1) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 4:

The utility model relates to a high performance marine glazing structure, characterized in that the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass. A resin frame or a metal frame support device is mounted on the periphery of the four sides.

Non-obvious technical effect [2]: In the application place, the present invention is compared with the prior art 1.2.3 in the high temperature state in the case of fire or high temperature, due to the higher softening of the flat glass of the present invention. High performance, such as difference in thermal expansion between high temperature zones and higher strength, can have the shape of maintaining glass, and can achieve non-obvious technical effects of fireproof, fireproof and heat insulation waves; The fireproof and explosion-proof effect of the building materials will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.

Non-obvious technical effects [3]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .

It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.

Since the invention can manufacture the special-strength 5-6mm thick bullet-proof and explosion-proof glass, the ballistic performance can also be better than the conventional 25mm thick F79-class full glass bulletproof glass (the steel core bullet for the pistol), and the invention is also thin and light. 5 times. Since the invention can manufacture a full glass bulletproof glass with a special strength of only 8-9 mm, the ballistic performance can also be superior to the conventional 40 mm thick F56 grade (anti-56/AK47 submachine gun or 81 rifle steel core projectile) full glass bulletproof glass; It is also five times lighter and thinner, which is a new material property that is impossible for all existing existing glass. Therefore, especially in the door and window of the cab of the ship, the marine glass window structure of the invention is used, and the anti-pirate robbery boat mooring has the effect of preventing and increasing the response time. Has a non-obvious technical effect.

(Class B 2) Inventions in which the dependent claims and the combination of the invention apply the changes in the elements, 5:

A high performance aircraft glazing structure, characterized in that: the window glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass. A resin frame or a metal frame support device is mounted on the periphery of the four sides.

Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; There are TFT boron-containing glass, which is 1/3 lighter and thinner than calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.

The glazing structure of the invention: [a] with a covering product, a higher strength of 4-5 times the geometric multiple, will be against the flying aircraft, which is extremely demanding for such safety. The sudden change of pressure inside and outside of the aircraft caused the aircraft glass to rupture. Due to the increased strength of several times, it can prevent man-made damage to the aircraft side window and other accidents, provide new flight safety guarantees, and have non-obvious technical effects; [b] The more lightweight and thinner aircraft glazing products with 4-5 times the geometric multiples provide the option of reducing the weight of the aircraft and saving energy while ensuring safety. Has a non-obvious technical effect.

(Class B 3) Inventions in which the dependent claims and the combination are applied to the invention or the elements are changed, 6:

A high-performance glazing structure for an automobile, characterized in that: the automobile glazing is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass The application has a resin frame or a metal frame support device mounted on the periphery thereof.

Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of fire or high temperature, in the state of high temperature region, The higher softening point of the flat glass of the invention, the better high temperature zone thermal expansion difference, higher strength and the like, can have the shape of maintaining the glass, and can be used for fire prevention, fire insulation and heat insulation. Technical effect; The invention has special fireproof and explosion-proof effect of building materials, and greatly enhances the ability of bursting in the high temperature region when the glass volume is rapidly increased, and has non-obvious technical effects.

Non-obvious technical effects [3]: The present invention has a special fire and explosion-proof effect: it will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased. It can help to avoid people or cars from escaping from the fire area when it comes to fire outside the car. It has non-obvious technical effects.

Non-obvious technical effects [4]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; Existing TFT boron-containing glass, light and thin 1/3; ratio Calcium soda glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.

(Class B 4) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 7:

A high-performance building glazing structure, characterized in that: the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass A resin frame or a metal frame support device is mounted on the periphery of the four sides.

Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.

Non-obvious technical effects [3]: The invention has special fire and explosion-proof effects of buildings:

[a] In the present invention, since the sodium content is low, the softening point is higher [from 780 ° C to 860 ° C], the more the shape of the glass can be maintained in a high temperature region when fire or high temperature is encountered, and fireproofing and separation can be achieved. The role of fire and heat insulation waves;

[b] The present invention has a much lower difference in thermal expansion rate than other glasses in a high temperature region, so that when the glass is exposed to fire or high temperature, the less likely it is to burst due to the rapid increase in the volume of the glass in the high temperature region; It greatly enhances the ability to resist bursting when the volume of glass in the high temperature zone is rapidly increased; it can prevent or greatly delay the fire from being extinguished by other floors through the external window glass to accelerate the overall fire of the whole building; or can prevent or greatly delay the fire Extinguish the transfer from other indoors to the outer wall to speed up the overall fire of the whole building; it can produce good indoor fire safety for human beings and gain confidence in long-term escape and rescue; it can be beneficial when it comes to building fires. It is good for people to escape from the fire area for a long time; it has non-obvious technical effects.

(Class B 5) Inventions in which the dependent claims and the combination of the invention apply the changes in the elements, 8:

A high-performance insulating glass characterized in that: the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass; A support device is attached to the periphery; there is a 3-50 mm vacuumed isolation space between the layers of glass.

Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.

The invention can create a new energy-saving market, and form a super-high-strength and light-thin 3-5 layer hollow efficiency energy-saving glass for building covering: the traditional hollow energy-saving glass is limited to 6mm glass + vacuum insulation layer +6mm due to strength limitation. Glass, only one layer of vacuum insulation layer; and the invention can be 1.2mm glass + vacuum insulation layer +1.2mm glass + vacuum insulation layer +1.2mm glass + vacuum insulation layer +1.2mm glass, equal to three layers of vacuum The temperature insulation layer, but the total thickness of the glass is only 4.8mm, which is not only lighter than the total thickness of the traditional two-layer glass hollow energy-saving product, but also has a heat insulation effect of 3-5 layers of vacuum insulation layer than the traditional one. The effect of the layer vacuum insulation layer is too good, which can create a new history of efficiency and energy saving of insulating glass, and has non-obvious technical effects.

(Class B 6) Inventions in which the dependent claims and the combination of the invention apply the invention or the elements, 9:

A high-performance building glass curtain wall, characterized in that: the glass curtain wall is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass. It is fixed to the upper metal support device.

[a] In the present invention, since the content of the oxidizing pot is low, the softening point is greatly increased; and the higher the softening point of the present invention [from 780 ° C to 860 ° C], the more likely it is in the high temperature region when it hits a fire or a high temperature. Keeping the shape of the glass, it can play the role of fire prevention, fire separation and heat insulation;

[b] The present invention has a much lower difference in thermal expansion rate than other glasses in a high temperature region, so that when the glass is exposed to fire or high temperature, the less likely it is to burst due to the rapid increase in the volume of the glass in the high temperature region;

Therefore, it will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased; it can prevent or greatly delay the fire from being extinguished by other floors through the external window glass to accelerate the overall fire of the whole building; or can prevent or greatly Delaying the fire from the other indoors to the external wall to speed up the overall fire of the whole building; can produce good indoor fire safety and strive for greater escape and rescue confidence; can help when the building hits the fire, It has a long time to help people escape from the fire zone; it has non-obvious technical effects.

Non-obvious technical effects [4]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables the high-performance building glass curtain wall strength to be five times higher than the existing calcium soda glass strength at the same weight.

(Class B 7) Inventions in which the dependent claims and the combination are applied to the invention or the elements are changed, 10:

A high-performance super-large area thin glass window or glass curtain wall, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass Application; the thickness of the glass is 4-10mm, the size of the glass is 3-40 square meters, or the thickness of the glass is 10.1-20mm, and the size of the glass is 15.1-80 square meters;

Non-obvious technical effects [1]: In the field of this application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight. It also enables the strength of the glass to be five times higher than the strength of the existing calcium soda glass at the same weight.

The technical effect of the coating of the invention is that the glass materials for construction are all sodium soda glass, the strength is only 50Mpa; and the performance glass of the invention can reach 180-240Mpa, and the geometric multiple of 4-5 times is higher. The strength can make the building glass anti-collision, explosion-proof, anti-shock performance, etc., and the safety is increased by 4 times to 5 times; it can be designed as an unobstructed panorama of the super-large board without being divided by the aluminum alloy skeleton. Architectural glass, especially in various office buildings, hotel and apartment buildings, and indoor visuals of buildings and villas, can display a wide range of beautiful panoramic views of the window (such as garden, mountain, water, sea, city) Scenery), creating a new functional life experience of the covered window building, can also cover the façade of the super-large glass of various buildings, create a new consumer market, create a new history of architectural design value; Business and users bring new value with non-obvious technical effects:

A. The present invention can withstand high temperature for a long time because there is no traditional aluminum alloy window frame in the use of large-area windows or curtain walls (because the softening point of the glass of the invention reaches 780 ° C - 880 ° C, much higher than aluminum alloy The frame softening point is 400-450 ° C), so increasing the glass area can improve the overall fire, fire and heat insulation of the building, and has non-obvious technical effects.

B. The present invention has a 4-5 times higher strength than the soda lime glass [fracture strength of only 45-50 Mpa], and will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technique. effect.

C. The invention can prevent or greatly delay the fire from being extinguished by other floors through the outer wall window glass to accelerate the overall fire of the whole building; or can prevent or greatly delay the fire from being transferred from other indoors to the external wall to accelerate the whole building as a whole Fire; can generate good indoor fire safety for humans and strive for longer escapes and Rescuing confidence is a life experience with the effect of human security. It can create new consumer markets and create a new history of building fireproof glass with non-obvious technical effects.

D. It has 4-5 times higher strength than the existing calcium-sodium architectural glass; it can be designed as an unobstructed panoramic architectural glass with no large plate surface, especially in various office buildings and hotels. And the indoor vision of the apartment building, and the buildings such as the house and the villa, can display a large range of beautiful panoramic views of the window (such as garden, mountain, water, sea, city), creating new windows The functional life experience can also cover the façade of the super-large glass of various buildings, create a new history of architectural design value, and bring new value to builders and users, with non-obvious technical effects.

Non-obvious technical effects [3]: Discovered low crystallization rate crystal velocity properties, resulting in high quality, large production technical effects.

Non-obvious technical effects [4]: In the application place, the present invention is especially in comparison with the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.

(Class B 8) Inventions in which the dependent claims and the combination are applied to the invention or the elements are changed, 11:

A high-performance tempered glass characterized in that the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass, chemically tempered or Made of physical tempering.

Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thereby producing a high quality flat glass of the invention without any crystallization due to crystallization;

Non-obvious technical effects [2]: In the application place, the present invention compares with the prior art [1][2][3][4] in the state of high temperature when encountering fire or high temperature, Due to the flat glass of the present invention High softening point, better high temperature zone thermal expansion difference, higher strength and other high performance, can maintain the shape of the glass, can play a non-obvious technical effect of fire, fire, heat wave; The invention has special fireproof and explosion-proof effects of building materials, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.

Non-obvious technical effect [3]: The invention has special fireproof and explosion-proof effects of building materials, and the glass of the invention is strengthened, which greatly enhances the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technology. effect.

Non-obvious technical effects [4]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.

(Class B 9) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 12:

A high-performance glass, or tempered glass, or a glass-top furniture of laminated glass, characterized in that the glass table top is a low difference and a low coefficient of thermal expansion coefficient of a high softening point and a high temperature zone according to claim 1. The crystallization rate, fireproof and explosion-proof flat glass are made, and the lower part of the table has support means.

Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables the strength of high-performance glass countertops to be five times higher than the existing calcium soda glass at the same thickness and weight.

(Class B 10) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 13:

A high-performance laminated glass, characterized in that the glass thereof is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, the layers thereof There is a layer of resin material between the glass.

Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables the performance of high-performance laminated glass to be five times higher than the strength of existing calcium-sodium laminated glass at the same thickness and weight.

(Class B 11) The invention of the invention or the change of the elements of the dependent claims and the combination of the following, 14:

The utility model relates to a high performance bulletproof and explosion-proof glass, which comprises: bulletproof explosion-proof glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, a fireproof and explosion-proof flat glass Application; each of the glass sheets is bonded by a resin sheet.

[1] In the present invention, since the content of sodium oxide is low, the softening point is greatly increased; and the higher the softening point of the present invention, the more the shape of the glass can be maintained in a high temperature region when it hits a fire or a high temperature. Play a role in fire prevention, fire separation, and heat insulation;

[2] The present invention has a much lower difference in thermal expansion rate than other glasses in a high temperature region, so that when the glass is exposed to fire or high temperature, the less likely it is to burst due to the rapid increase in the volume of the glass in the high temperature region;

Moreover, since the invention can manufacture a 6-7 mm thick bulletproof and explosion-proof glass composed of three layers of glass with special strength, the ballistic performance can also be superior to the conventional 25 mm thick F79 class full glass bulletproof glass composed of three layers of glass ( The steel core of the pistol), the invention is also 4-5 times thinner. Since the present invention can manufacture a full-glass bulletproof glass of only 8-9 mm thick composed of three layers of glass, the ballistic performance can also be superior to the conventional 40 mm thick F56 grade consisting of three layers of glass (anti-56/AK47 submachine gun or 81 rifle steel core bullet) full glass bulletproof glass; also thin and light 4-5 times, which is the new material nature of other existing existing glass. Therefore, for bulletproof and explosion-proof glass of transparent armored ships, ships, yachts, buildings, residences, etc.;

Specially safer trains and downstream end users such as high-speed rail glass: aircraft manufacturers, shipbuilders, car manufacturers, bank and financial owners, jewellery owners, security owners, etc., can form top technology The unique support of the non-obvious technical effect.

(Class C) Furniture 4 category dependent claims and knot combination invention invention or element change invention, combined invention terminal product:

(C Category 1) Inventions in which the invention or the element change is applied in a dependent claim and a combination of the following:

The invention relates to a high-performance color glazed glass plate combination cabinet, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass There are 1-10 kinds of color glaze layer on the surface or back surface, and the flat glass is surrounded by a metal frame to form a composite board; there is a metal connecting device between the metal frames, making it a glazed glass plate combination cupboard.

(C Category 2) Inventions in which the invention or element changes are applied in the dependent claims and the combination of the elements, 16:

A high-performance sliding door cabinet glass panel furniture, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass There are 1-10 colors of glaze on the surface or back, surrounded by metal frames, and the metal frame has rollers on the top and bottom.

(C Class 3) Inventions in which the invention or the element change is applied in the dependent claims and the combination, 17:

The utility model relates to a high-performance color glazed glass plate combined wardrobe, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass a glaze layer of 1-10 colors on the surface or the back surface; the flat glass is surrounded by a metal frame to form a composite panel; and a metal coupling device is formed between the metal frames to make it a glazed glass Board combination wardrobe.

(C Category 4) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 18:

A high-performance color glazed countertop glass furniture, characterized in that: the countertop glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and a fireproof and explosion-proof flat glass Application: There are 1-10 colors of glaze layer on the surface or back of the table top, and there are support devices on the lower part of the table.

The above four types of structural knots are combined with the invention of furniture, and the low crystallization rate of the crystal speed property is found, resulting in the technical effect of high quality and large production. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thereby producing a high quality fire-proof and explosion-proof flat glass of the invention without any crystallization due to crystallization;

The above furniture invention, compared with traditional wood, composite board, multi-layer board, fiber board, glass type furniture, has non-obvious technical effects:

Non-obvious technical effects [1]: In the application place of furniture, the present invention compares the prior comparative techniques [1][2][3][4] in the high temperature zone when it encounters fire or high temperature. Next, due to the [higher softening point] of the flat glass of the present invention, [better high temperature zone thermal expansion difference, [higher strength and other high performance], it can have the shape of holding glass, and can be fireproof and fireproof. The non-obvious technical effect of the heat-insulating wave; the invention has special fire-proof and explosion-proof effect of the furniture, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.

Non-obvious technical effects [2]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass.

It can also make the strength of various high-performance glazed glass furniture 5 times higher than the existing calcium-sodium tempered glass strength at the same thickness and weight.

[a], such as 15cm thick wood material and 6-8mm calcium soda glass strength; the invention can only use 1.5-1.8mm products can be comparable to 15cm thick wood material; lighter than wood products 2-3

Non-obvious technical effects [3], various high-performance glazed glass homes have: a., the appearance of high-simulated wood grain, stone arteology and appropriate product design entry point; b. brand new inorganic type The unique technical characteristics of the sturdy and wear-resistant high-strength glass of the glaze combination; c. sturdy and suitable, convenient and environmentally friendly, can lead to the change of the global invention of timber board, fiberboard products and wood furniture combination The trend of high chemical pollution and dust pollution in the production of products overcomes its historical difficulties and benefits the international community;

d. For the assembly of thin aluminum alloy frame and safety glazed glass, all production processes are easier to design a highly automated combination, standardized production of assembled production online; e. Especially including assembly production in various end markets close to high labor costs To achieve the difficulty of improving assembly efficiency, significantly reducing costs, and no environmental problems, especially to solve the employment of personnel.

Classified as: 1, safe glazed glass countertop furniture; 2, safety countertop transparent glass countertop furniture; 3, safe glazed glass and thin aluminum alloy frame design of panel combination furniture, and cabinet furniture, and cabinet countertops Furniture; 4, safe glazed glass and thin aluminum alloy frame design of the sliding door cabinet furniture;

Non-obvious technical effect [4]: The invention has special furniture fireproof and explosion-proof effect: and the glass of the invention can be strengthened for a longer period of time after being strengthened; it will greatly enhance the bursting resistance when the glass volume in the high temperature region is rapidly increased. Ability.

[D] New energy category 2 dependent claims and scar tissue combination invention invention or element change invention, combined invention terminal products:

(Class D 1) Invention of the invention or element change in the dependent claims and the combination, 19:

A high-performance photovoltaic solar device, comprising: a solar cell, and a glass substrate or a cover plate; the glass substrate or the cover plate is a low difference between a high softening point and a high temperature region thermal expansion coefficient according to claim 1. Low crystallization rate, application of fireproof and explosion-proof flat glass.

Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better high temperature zone thermal expansion difference, higher strength and the like, high performance, the shape of the glass can be maintained to prevent fire, fire, and heat waves. Technical effects; The invention has a special fireproof and explosion-proof effect, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technical effect.

Non-obvious technical effects [3]: High-performance photovoltaic solar installations in applications, due to their glass, can also be light and thin at the same intensity, compared with the prior art [1][2][3][4] Light and thin is 3/4; lighter than 1/3 of the existing TFT boron-containing glass; lighter than 1/5 of calcium soda glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.

1. Therefore, the support frame and the frame body can also greatly reduce the weight; especially suitable for the roof installation of the wooden villa with poor carrying capacity, which has non-obvious technical effects.

2. Because of its glass, it can also be thinned at the same strength, so it can increase the transmittance of sunlight and improve the efficiency of solar energy. It has non-obvious technical effects.

(Class D 2) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 20:

A high performance thin film solar device comprising: a thin film solar cell; and a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass according to claim 1 .

Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better high temperature zone thermal expansion difference, higher strength and the like, high performance, the shape of the glass can be maintained, which can greatly enhance the production of the solar cell film, the present invention The ability to resist bursting when the glass volume in the high temperature region is rapidly increased has a non-obvious technical effect.

Non-obvious technical effects [3]: High-performance thin-film solar devices can be used at the same intensity due to their glass, and they are lighter and thinner than the prior art [1][2][3][4] Light and thin is 3/4; lighter than 1/3 of the existing TFT boron-containing glass; lighter than 1/5 of calcium soda glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.

Non-obvious technical effects 4]: The perfect combination of high-quality life and environmental protection concepts: [a] thin film solar technology can be successfully grafted with cars; [b] large-scale off-grid power supply can be realized by using solar energy rapid power station; Thin-film solar enclosures can be used to mobilely charge electronic devices; [d] Thin-film solar energy can be used in ships and urban buildings with non-obvious technical effects.

(E-Class 9) Electronic Display Class Dependent Claims and Scarf Combination Inventions Inventions or elements change inventions, semi-finished products or combined invention terminal products:

(E-Class 1) Inventions in which the invention or element change is applied in a dependent claim and a combination of the following, 21:

A roll-to-roll process for producing a film transistor on a glass substrate, and a liquid crystal display produced thereby, including

LCD screen, the LCD screen includes:

An array substrate comprising a substrate and a pixel structure produced on the substrate by a roll-to-roll process, wherein the substrate has a high softening point, a low difference in thermal expansion coefficient of a high temperature region, and a low resolution according to claim 1. Crystal speed, fireproof and explosion-proof flat glass;

a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;

a liquid crystal layer interposed between the array substrate and the color filter substrate;

Backlight system.

The existing TFT-LCD liquid crystal display panel roll-to-roll production process is in a difficult development period; the present invention can solve a variety of difficult problems in the development period, and make the TFT-LCD liquid crystal display panel roll-to-roll production. The process enters a high-quality, high-yield, high-yield production capacity, and low-cost large-scale production stage [see the production process of the panel roll-to-roll of the invention].

A touch display screen produced on a glass substrate by a roll-to-roll process, comprising: a substrate glass according to claim 1 having a high softening point, a low difference in thermal expansion coefficient of a high temperature region, and a low resolution The application of crystal speed, fireproof and explosion-proof flat glass is provided with a conductive film thereon;

LCD screen, the LCD screen includes:

An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;

Backlight system.

(Class E 2) Inventions in which the invention or element changes are applied in the dependent claims and the combination of the elements, 22:

A high performance roll-to-roll flat glass for a liquid crystal screen or touch screen, comprising:

The glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and a fireproof and explosion-proof flat glass according to claim 1; wherein the thickness of the flat glass is 0.05-3.5 mm, and the glass can be collected. The inner roll of the roll has a diameter of 20-80 cm and a length of 200 cm-2000 cm or 2001-10000 cm.

(Class E 3) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 23:

A high performance low temperature polysilicon display screen comprising:

LCD screen, the LCD screen includes:

a low temperature polysilicon array substrate comprising a substrate and a pixel structure produced on the substrate by a low temperature polysilicon process, wherein the base glass has a high softening point and a low difference in thermal expansion coefficient of a high temperature region according to claim 1. Crystallization speed, fireproof and explosion-proof flat glass;

Backlight system.

The invention can solve the problem of the new process of the low-temperature polysilicon technology for the liquid crystal display product [see the new process part of the low-temperature polysilicon technology for the purpose of the invention].

(E-Class 4) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 24:

A flat glass for high performance low temperature polysilicon display, characterized by comprising:

The base glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass;

(E-Class 5) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 25:

A high performance wear resistant and high strength liquid crystal display comprising:

An array substrate comprising a substrate and a pixel structure on the substrate, wherein the substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof explosion-proof plate according to claim 1. Application of glass;

Backlight system.

Non-obvious technical effects [2]: In the application place, the present invention is especially useful in comparison with the prior art [1][2][3][4]: high temperature region in the process of TFT thin film transistor In the state, due to the higher softening point of the flat glass of the invention, better thermal expansion difference in the high temperature region, higher strength, etc. Performance, can have the shape of the glass; especially the difference in thermal expansion in the high temperature zone, which will greatly enhance the color alignment accuracy of the phase element and the beam splitter, which can produce 2-5 times higher than the prior art 2 Non-obvious technical effects of the resolution display; the present invention enables precise component positioning and efficient panel production due to its excellent overall pitch deviation performance;

It can better withstand the harsh high temperature process used in the production of the most advanced HD display; it can expand the temperature range of the process control platform under high temperature process conditions, not only the dimensional stability, but also the quality assurance. At the same time increase production.

(E-Class 6) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 26:

A high-performance wear-resistant and high-strength touch display screen comprising: a substrate glass according to claim 1 having a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass Application with a conductive film attached thereto;

LCD screen, the LCD screen includes:

Backlight system.

Non-obvious technical effect [2]: For example, when the upper glass of the two-layer TFT glass is subjected to the composite touch screen process by using the cover glass layer, the high aluminum glass content in the patent range of the alkali-free glass of the present invention can be obtained. The rise is 25-39%; the first is that the cover glass and processing can be omitted, thereby reducing the cost and thinning the mobile phone, tablet, and notebook products; the second is that it is not very resistant to chemical strengthening and is also very high. Strength and drop resistance;

Non-obvious technical effects [3]: In the application place, the present invention is especially useful in comparison with the prior art [1][2][3][4]: in the process of thin film transistor or touch conductive film In the high temperature zone state, due to the higher softening point of the flat glass of the invention, the better thermal expansion difference in the high temperature zone, and higher High performance such as strength, can maintain the shape of the glass; especially the difference in thermal expansion of the high temperature region, which will greatly enhance the color alignment accuracy of the phase element and the beam splitter, which can produce a higher 2 than the prior art 2 -5 times the resolution of the display's non-obvious technical effects;

It can also better withstand the harsh high temperature process used in the production of the most advanced HD display; it can also expand the temperature range of the process control platform under high temperature process conditions, not only the dimensional stability, but also the quality assurance. At the same time increase production.

(E-Class 7) Invention in which a dependent claim and a scar combination are applied to an invention or a change in the element, 27:

A high performance wear resistant and high intensity touch display mobile phone, or a touch display tablet computer, or a touch display notebook computer, or a touch display television, comprising:

The substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion proof flat glass according to claim 1, and a conductive film is attached thereon;

Backlight system;

Display edge device and support device.

Non-obvious technical effect [1]: For example, when the upper glass of the two-layer TFT glass is subjected to the composite touch screen process by using the cover glass layer, the high aluminum glass content in the patent range of the alkali-free glass of the present invention can be obtained. The rise is 25-39%; the first is that the cover glass and processing can be omitted, thereby reducing the cost and thinning the mobile phone, tablet, and notebook products; the second is that it is not very resistant to chemical strengthening and is also very high. Strength and drop resistance;

Non-obvious technical effects [2]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thereby producing a high quality fire-proof and explosion-proof flat glass of the invention without any crystallization due to crystallization;

Non-obvious technical effects [3]: In the application place, the present invention is especially useful in comparison with the prior art [1][2][3][4]: in the process of thin film transistor or touch conductive film In the high temperature zone state, due to the higher softening point of the flat glass of the invention, better high temperature zone thermal expansion difference, higher strength and the like, the shape of the glass can be maintained; especially the better thermal expansion in the high temperature zone The value will greatly enhance the color alignment accuracy of the phase element and the beam splitter, which can produce a higher 2-5 times resolution of the non-obvious technical effect of the display than the prior art 2; it can also withstand better The harsh high-temperature process used in the production of the most advanced high-definition display; under the high-temperature process conditions, the temperature range of the process control platform can be expanded, not only the dimensional stability is good, but also the production is improved while ensuring the quality.

Non-obvious technical effect [4]: In the ultra-high aluminum scratch-resistant and tough glass material of the present invention, the alumina content can reach 25-39%, and the alumina chemical bond is a prior art float method or a down-draw method. Or the continuous bonding chemical bond with the highest tensile strength in the flat glass material such as the turbulence method, so the scratch-resistant strength and toughness characteristics of the ultra-high aluminum scratch-resistant and tough glass material of the present invention are much better, as explained below;

According to the theory of irregular network of glass composition, the role of glass composition oxides (changes in chemical and physical properties of nanoscale size) in glass structures can generally be divided into three categories: network formers, network exosomes and intermediates. Therefore, it is necessary to understand the characteristics of scratch resistance and toughness from the point of view of the chemical physics of glass products and from the point of view of irregular network theory:

In the existing flat glass materials such as float or down-draw or turbulent flow, the chemical bond of the tetrahedron formed by alumina in the glass network structure has the highest tensile strength, so the tetrahedron and alumina formed by alumina The continuous bonding of SiO4 tetrahedrons with chemical bonds constitutes a continuous network structure, which is the highest tensile strength of the network structure in the glass materials such as the float method or the down-draw method or the turbulence method (the tensile strength is not the hardness), so The tetrahedron formed by alumina and the SiO4 tetrahedron form a continuous network structure, which is the most fragile, least crackable, most scratch-resistant, and most wear-resistant nanometer in flat glass materials such as float or down-draw or turbulent flow. Grade size chemical and physical properties materials; in the display glass, comparing the scratch resistance to the toughness is to compare the degree of damage of the glass network structure after repeatedly scraping the surface of the glass with a resin pen tip;

First of all, we must understand that the hardness index is only one scratch test; while the scratch test is worn several times, and the cover glass of the mobile phone is adapted to several times of metal hard scratching;

In order to understand the nano-scale chemical and physical properties of tensile strength, that is, toughness and wear resistance, another example is as follows: just as the toughness of organic polymer resin materials is based on the principle of different organic polymer resin materials. [Different nanoscale size] The higher the tensile strength of the chemical bond of the molecular bond, the better the toughness and wear resistance; the various modified polyester materials used for sports soles, polytetrafluoroethylene materials, modification Polyacetal materials, etc., are all chemically bonded to the molecular bond, and the mechanical strength is high, so the wear resistance is good; while the polyvinyl chloride resin material has good hardness, the chemical bond resistance of the molecular connection is very strong. Low, so it is fragile, easy to crack, easy to scratch, not wearable, so it is not suitable for sports soles.

The tetrahedral formed by alumina and the SiO4 tetrahedron form a continuous network structure of alumina chemical bonds, and have the highest tensile tensile mechanical strength of flat glass materials such as the float method or the down-draw method or the turbulent flow method, and In the invention of the ultra-high aluminum scratch-resistant low alkali glass material, 25% of the alumina tetrahedron is combined with a 25% SiO4 tetrahedron continuously bonded by the alumina chemical bond to form a continuous network structure.

From the three-dimensional space, there are 50 structures per unit length; 50 structures in the plane width; and 50 structures in the depth direction. Therefore, there are 50X 5 0X 50 per unit three-dimensional space. According to the invention, there are 75,000 network structure points consisting of SiO4 tetrahedrons continuously bonded by alumina chemical bonds per three-dimensional space unit. In the prior art, aluminum glass has only 8% alumina tetrahedron and 8% SiO4 tetrahedron continuously bonded by alumina chemical bonds to form a continuous network structure. From the perspective of three-dimensional space, there are 16 structures per unit length; 16 structures in the plane width; and 16 structures in the depth direction. Therefore, there are 16 X 16 X 16 in the three-dimensional space per unit. Only 4096 medium-aluminum glass has a network structure point consisting of SiO4 tetrahedrons continuously bonded by alumina chemical bonds; therefore, the invention has 75,000 per cubic space units of only 4096 aluminum glass. The network structure consisting of SiO4 tetrahedrons continuously bonded by alumina chemical bonds is 18 times more.

It can be seen that the ultra-high aluminum scratch-resistant low-alkali glass material of the present invention compares the three-dimensional density of the tough continuous network structure of the existing low-aluminum medium-low alkali glass material (such as GORILLA scratch-resistant glass). Therefore, judging from the basics, the ultra-high aluminum scratch-resistant low-alkali glass material of the present invention has the most non-fragile, most non-cracking, most scratch-resistant, most wear-resistant, most scratch-resistant, strong toughness characteristics. It will be better than the existing low-aluminum medium-low alkali glass materials (such as medium-aluminum glass scratch-resistant glass) several times. (There will be accurate wear test comparison data in the future)

In particular, the size of the tetrahedron formed by alumina and SiO4 in the network structure is less than 1 nm, and the naked eye can only see 50 micrometers or more under special light and angle (ie, 0,05 mm = 50000 nm).

Scratches; therefore, the tetrahedral and SiO4 tetrahedrons formed by a finer 50,000 times smaller than 50 micrometers constitute a continuous network structure of the fracture (nano-scale chemical and physical properties change), not only invisible to the naked eye, general microscope and 30000 The electron microscope below the magnification is not visible.

Therefore, in comparison, it is necessary to scratch the network structure of the high tensile network structure which destroys the ultra-alkali glass material of the present invention and accounts for more than 50% of the entire glass volume in the ultra-high aluminum scratch-resistant low-alkali glass material, so that the square of more than 50,000 layers is required. The network structure of the three-dimensional space of the surface is completely broken, so that it can be seen with the naked eye that all the continuous network structures are broken (destructive changes of the chemical and physical properties of the nano-scale size), and visible scratches can be seen by the naked eye, and the non-obvious technical effect is obtained. ;

However, there is a contrast-resistant aluminum scratch-resistant glass. The high tensile network structure only accounts for 16-20% of the total glass volume. The scratch-resistant protection level is far away, and it is prone to visible scratches and fractures.

The characteristics of the sag of the flat glass are determined by the flexural strength; the higher the flexural strength, the smaller the downward sag of the same weight and the same thickness of the flat glass; the higher the flexural strength, the better it is. In the process flow of the TFT panel, the damage rate is reduced in the process of the large-sized surface, and the non-obvious technical effect is obtained.

(E-Class 8) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 28:

A liquid crystal display screen produced by a process of first printing and re-sintering a thin film transistor, which comprises

LCD screen, the LCD screen includes:

An array substrate comprising a glass substrate, and a pixel structure produced by a process for printing a thin film transistor raw material on a glass substrate and then sintering the thin film transistor on the glass substrate; the glass substrate is the one according to claim 1. High softening point, low difference of thermal expansion coefficient in high temperature zone, low crystallization rate, application of fireproof and explosion-proof flat glass;

Backlight system.

The process of first printing a thin film transistor raw material and then sintering the thin film transistor is the latest technology research and development direction.

Representing the development trend of electronic liquid crystal display glass technology, the pixel structure produced by the process of printing thin film transistor raw materials on a glass substrate and then sintering the thin film transistor on the glass substrate, in the printing and sintering technology, people have been hoping to solve And there is no problem with success.

Non-obvious technical effect [1]: The 髙 performance electronic glass of the present invention has a difference in thermal expansion rate in the more severe high temperature region of 650 ° C to 700 ° C within 0.1-0.99 parts per million, in a more severe high temperature area 700 The difference in thermal expansion rate at °C-740 °C is within 1-5.9 or 6-8 parts per million. This increases the controllable range of the high temperature process; because of the poor thermal expansion rate of all the high temperature regions of the glass, the sintering temperature cannot be increased by 70 ° C; therefore, the present invention can use the film transistor raw material printed on the roll-to-roll glass substrate first. The pixel structure produced by the process of sintering the thin film transistor on the glass substrate; the process is much more efficient, lower in cost, and higher in yield than the production process of etching the thin film transistor by high temperature magnetron sputtering. Non-obvious technical effects; while the thin film transistor panel processing of the conventional TFT liquid crystal glass uses the high-temperature magnetron sputtering to reprint the etched thin film transistor production process, the production efficiency is low, the cost is relatively high, and the yield rate is not high.

Non-obvious technical effect [2]: The present invention can achieve a thin film transistor that overcomes the prior art printing technology by increasing the sintering temperature of the thin film transistor, because the thermal expansion coefficient of the high temperature region of the glass is poor, and the sintering temperature cannot be raised. The film transistor is not sufficiently sintered, resulting in poor precision, poor quality and low yield; the prior art also has a problem that the glass is too thin after thermal expansion, the precision is poor, the quality is poor, and the yield is low;

(E-Class 9) Inventions in which the invention or element change is applied in the dependent claims and the combination, 29:

A high performance curved liquid crystal display comprising:

The substrate glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass;

Backlight system;

Non-obvious technical effects [2]: In the application place, the invention is in the zone, especially comparing the prior art of comparison [1][2][3][4]: in the process of thin film transistor or touch conductive film In the high temperature zone state, due to the higher softening point of the flat glass of the invention, better high temperature zone thermal expansion difference, higher strength and the like, the shape of the glass can be maintained; especially the better thermal expansion in the high temperature zone The value will greatly enhance the color registration accuracy of the phase element and the beam splitter, which can produce a higher 2-5 times resolution of the non-obvious technical effect of the display than the prior art 2;

Non-obvious technical effects [3]: Existing LEDs can make curved mobile phones and TVs with a certain degree of curvature, but since the substrate glass is too thick to 0,5-0,7mm, the strength is poor, so the 0 of the present invention cannot be produced. , 1-0, 3mm high-strength substrate glass; this new material invention, because the invention can produce the latest ultra-thin high tensile strength characteristics, has excellent Young's modulus of elasticity (previous material description), Provides high-strength substrate glass material properties of 0,1-0,3mm that are impossible for other TFT electronic glasses. It can produce more curved surfaces and the most rupture, 髙髙 yield, more ergonomic Curved phones and TVs with a higher curved curvature. Therefore, the invention can support the development direction of the curved touch screen industry such as mobile phones, tablet computers, notebook computers, and liquid crystal televisions, and has non-obvious technical effects.

Non-obvious technical effect [4]: For example, in the case of adopting a cover glass layer, only the upper glass of the two-layer TFT glass is subjected to the composite touch screen process, the high aluminum glass content in the patent range of the alkali-free glass of the present invention can be obtained. The rise is 25-39%; the first is that the cover glass and processing can be omitted, thereby reducing the cost and thinning the mobile phone, tablet, and notebook products; the second is that it is not very resistant to chemical strengthening and is also very high. Strength and drop resistance;

Non-obvious technical effects [5]: The curved liquid crystal display is more in line with the physiological principles of the human eye, enabling people to see the screen more clearly.

(E-Class 10) Inventions in which the invention or element change is applied in the dependent claims and the combination, 30:

A high-performance OLED organic light-emitting display screen comprising: a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass;

And organic electroluminescent devices.

Non-obvious technical effect [1]: The upper line range of the crystallization temperature zone of the present invention and the natural temperature drop condition of the specified instrument, after 45 minutes - 2 hours, will be in the upper line range of the glass crystallization temperature zone. Under the conditions of gradual cooling, crystallization is started under the conditions, and the crystallization rate is slow; this can form extremely important precision in the cooling part and the forming part, especially for the float process and various flat glass processes. There are much better process control parameters for contrast technology, so that you can control large production with precise and precise control. Thereby producing a high quality ultra-high strength, thinner electronic flat glass of the invention without any crystallization due to crystallization;

The OLED organic light-emitting display has the advantages of being lighter and thinner, requiring no backlight, more power saving, better color effect, and faster response.

Non-obvious technical effects [1]:

First, there is a comparison bottleneck 2 if it is the biggest bottleneck of the electronic glass roll-to-roll process: 1. In particular, the current market requires terminal display products to become more and more light and thin; 2 prior art 2 tensile strength is lower than the difficulty of the present invention, resulting in an electronic glass base In the roll-to-roll process, thinner glass is more likely to be deformed or broken, which also affects the accuracy of alignment and affects the resolution of circuit line width and line spacing.

Non-obvious technical effects [2]:

The fireproof and explosion-proof flat electronic glass of the invention has an alumina content of 25-39% and a detonation strength of 150-240 MPa, so the present invention has the strength ability to resist deformation and cracking of too thin glass.

A. It can be used to resist the deformation or rupture of the ultra-thin thickness of the roll-to-roll electronic glass during the winding and unwinding movements.

B. In conventional flat glass substrates for OLEDs, there are also better strengths against deformation and cracking of too thin glass than prior art 2 and all prior art comparisons:

(E Class 11) Inventions in which the invention or the element change is applied in the dependent claims and the combination, 31:

A high-performance wear-resistant and high-strength mobile phone, or a transparent glass back casing of a tablet computer or a notebook computer or a desktop computer, characterized in that the transparent glass back casing is according to claim 1. The high softening point, the low difference of the thermal expansion coefficient of the high temperature zone, the low crystallization rate, and the application of the fireproof and explosion-proof flat glass.

Non-obvious technical effects: a wearable and high-strength mobile phone, or a transparent glass back casing of a tablet or laptop or desktop computer; can be combined with a transparent display of a mobile phone or a tablet computer to form a transparent and wear-resistant And high-strength mobile phones that are resistant to falling, or products of tablet computers.

[F] Durable terminal industrial product type combination application invention:

(Class F) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 32:

A high performance bulletproof and explosion proof vehicle comprising:

1-3 layers of glass of 1-10 windows, the bulletproof glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass; Each piece of glass plate is bonded by a resin sheet;

There is a bulletproof structure in the metal plate or metal frame around the car;

And power unit; instrument panel; direction controller; car shell; car chassis; car brakes;

Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. Technical effect.

Non-obvious technical effect [3]: The invention has special fireproof and explosion-proof effects: if the so-called strontium-potassium fire-resistant glass with thick soda-lime glass is used, it can resist 1000 ° C high temperature for a certain period of time; and after the glass of the invention is chemically strengthened, It can withstand high temperatures of 1000 ° C for a longer period of time; it will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased.

Non-obvious technical effects [4]: It can help to prevent people or cars from escaping from the fire zone when the vehicle is hit by fire. It increases the safety of the people inside the vehicle and prolongs the chance of driving away.

Has a non-obvious technical effect.

Non-obvious technical effects [5]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .

Non-obvious technical effect [6]: Since the present invention can manufacture a 5-6 mm thick bulletproof and explosion-proof glass made of 3-layer glass with special strength, the ballistic performance can also be superior to the conventional 25 mm thick composed of 3 layers of glass. The F79 grade full glass bulletproof glass (steel core bullet for anti-pistol), the invention is also light and thin 4-5 times. Since the present invention can manufacture a full-glass bulletproof glass of only 8-9 mm thick composed of three layers of glass, the ballistic performance can also be superior to the conventional 40 mm thick F56 grade consisting of three layers of glass (anti-56/AK47 submachine gun or 81 rifle steel core bullet) full glass bulletproof glass ; also thin and light 4-5 times, which is the new material nature of other existing existing glass.

Therefore, we can creatively produce a new comprehensive function car combination invention terminal that is bulletproof, explosion-proof, anti-robbery theft and anti-injury, anti-rolling injury, anti-collision damage, and overwhelming safety level plus gorgeous and light. The product has a new comprehensive function car combination with anti-ballistic, explosion-proof, anti-robbery theft and anti-injury, anti-rolling damage, gorgeous and lightweight, anti-collision, inventing the terminal product, and the light and beautiful car life experience also has both Preventing theft, burglary, and robbing of the window of the window due to the axe or steel hammer hitting is a kind of peace of mind and the feeling of driving and riding life experience (people only need to be in the car) Not afraid of being robbed, not afraid of being injured by the robbers, not afraid of being shot, not afraid of being blown up by grenades)

Non-obvious technical effect [7]: The invention discloses a new comprehensive function automobile combination end product with explosion-proof, anti-robbery theft and anti-injury, anti-rolling damage, gorgeous and light, anti-collision, which is caused by anti-rolling Characteristics of the damage function: Because the strength of the explosion-proof glass of the invention is 4-5 times that of the conventional ordinary automobile glass [the thickness is 2 times] is equal to 4-5 X2=8-10 times, and the toughness is good, and the rolling force and the impact force can be absorbed. And there is also the mechanical effect of the standing timber support, which is equal to the upper, lower, left and right direction supporting force of ordinary glass and 4-5 X2=8-10 times of front and rear or up, down, left and right directions. Anti-collision force', so The support force of the A, B, and C columns can be greatly increased when the conventional automobile is tumbling, so the anti-vehicle tumbling damage function of the present invention has a non-obvious technical effect.

(Class F 2) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 33:

A high-performance anti-robbery, anti-theft, explosion-proof, anti-collision, anti-rolling injury car, which includes:

1-3 layers of glass of 1-10 windows, bulletproof glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass;

Non-obvious technical effect [1]: The invention has a gorgeous, lightweight and anti-collision new integrated function automobile combination invention terminal product, which is light and attractive, and has a gorgeous car life experience, and also has protection against an axe or a steel hammer. Strike, destroy the anti-stolen, anti-robbery, anti-robbery function of the window of the car window, is a kind of peace of mind and the feeling of driving and riding life experience (people are not afraid of being robbed in the car, not afraid Personal being injured by the robbers)

Non-obvious technical effects [6]: Therefore, we can creatively produce new types of anti-robbing theft and anti-injury, anti-rolling damage, anti-collision and injury, and a level of safety plus gorgeous and lightweight. The functional car combination invents the terminal product, which has the characteristics of explosion-proof, anti-robbery theft and anti-injury, anti-rolling and being damaged (because of the anti-rolling damage function): the strength of the explosion-proof glass of the invention is the traditional ordinary automobile glass [thickness is 2 times] equals 4-5 X2=8-10 times, and has good toughness, which can absorb rolling force and impact force; and there is also the mechanical effect of 'standing wood to support kilograms, which means equal to the upper, lower and left sides of ordinary glass. The right direction support force and the front and back or the upper, lower, left and right directions [thickness is 2 times] is equal to 4-5 X2=8-10 times anti-collision force', so only A, B, C columns can be rolled than conventional cars. The support force is greatly increased, so the anti-vehicle tumbling damage function of the present invention has a non-obvious technical effect.)

Non-obvious technical effects [6]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.

(G class 1) The invention of the invention or the change of the element is applied in the dependent claims and the combination, 34:

A high performance solar aircraft having a propeller power for propelling flight, a wing, a driving control system device, and a thin film solar device comprising: a thin film solar cell; a substrate glass on a thin film solar device, According to the invention as claimed in claim 1, a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass are provided.

Non-obvious technical effect [2]: A solar powered aircraft of the present invention can be filled with a machine due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in a high temperature region, higher strength, and the like. The solar glass panel of the wing is more heat and temperature resistant than all existing solar glass panels.

Non-obvious technical effect [4]: The solar aircraft of the present invention can reduce the solar glass panel covered with the fuselage wing to only 1/4-1 due to the 4-5 times improvement in strength. /5, can also make the frame supporting the solar glass plate light and thin to only 1/4-1/5; can also greatly reduce the design of the fuselage support supporting the solar glass plate; and because the above part of the traditional solar aircraft occupies A large portion of the total weight, which produces the solar powered aircraft of the present invention,:

(1) Or because the innovative total weight of the solar aircraft of the present invention is greatly reduced, so the same solar power can achieve longer air flight time;

(2) The solar energy of the invention may be greatly reduced due to the innovation, so that the same solar power can achieve faster air flight speed;

(3) Or because of the innovative solar powered aircraft of the present invention, when the total weight is the same as that of the conventional solar powered aircraft, a larger area of the thin and light solar panel of the present invention can be designed to obtain more solar power and achieve faster air flight. Speed and longer air flight time.

[H] Durable terminal industrial products type combination application invention:

Exterior wall building decoration type combination application invention:

(Class H) The invention in which the invention or the element change is applied in the dependent claims and the combination of the combination, 35:

The utility model relates to a composite board of high-performance color glaze flat glass and metal layer, wherein the glass composition is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof explosion-proof The flat glass has a glaze layer of 1-10 colors on the surface of the substrate glass, a metal plate with a thickness of 0.1-5 mm, and a layer of adhesive material between the glass plate and the metal plate.

Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. Technical effect There is a special building material fireproof and explosion-proof effect, which will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.

Non-obvious technical effects [3]: In the installation of interior and exterior walls of buildings, it has the convenience and lightness of construction and use of aluminum-plastic composite panels and aluminum panels; it also has many times more strength and flatness than aluminum-plastic composite panels. And the pattern texture of stone and wood that does not change color for hundreds of years. Has a non-obvious technical effect. It represents a new trend in decorative materials in the installation of interior and exterior walls of buildings.

Non-obvious technical effects [4]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .

Non-obvious technical effects [5]: In the above-mentioned better quality with the prior art and the strength can be 4-5 times higher than the existing flat glass, the discovery and production of this new product property makes color The combined invention of the glaze layer produces a [composite board product of high performance glazed flat glass and metal layer] capable of producing a thickness of 1-3 mm [equal to the strength of calcium-sodium silicate glass of 5-15 mm], for the current country Standard external wall hanging board 12mm thick ceramic products and 25mm thickness stone product standard, the invention of high strength, thin and light [4-25 times] replacement, resulting in energy, resources, logistics, storage 4-25 times savings Unexpected effect.

Non-obvious technical effect [6]: a. A high-performance color glaze flat glass and metal layer composite board product, which can overcome the expansion and contraction deformation of the aluminum-plastic panel after being used for the outer wall due to the plastic plate being exposed to the sun for one year. Defects with poor flatness; b. It can overcome the printing of aluminum-plastic plate pattern as organic material, and can not be used as the outer wall defect in the outer wall for 1-2 years; c. The composite plate with aluminum film layer of the invention has fine patterns. Never fade, the flatness is excellent, and the life expectancy is 50-80 years.

Non-obvious technical effect [7]: A high-performance color glaze flat glass and metal layer composite board product, which can be installed as easy as aluminum-plastic board;

Non-obvious technical effect [8]: A high-performance color glaze flat glass and metal layer composite board product: a. It can be installed as easy as the external wall dry hanging aluminum plate; b. There is also an external wall dry hanging aluminum plate Less than Flatness and appearance of fine stone or wood grain pattern; c. or external wall dry hanging aluminum plate can not be used, all kinds of 300 years of non-fading inorganic color glaze yellow, blue, gray, white, black and other monochrome Decorative effect

(Class H 2) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 36:

Exterior wall building decoration type combination application invention:

A high-performance glazed glass composite material board having a simple structure installed on a wall surface, the structural composition thereof is that the glass is a low difference between a high softening point and a high temperature region thermal expansion coefficient according to claim 1. , low crystallization rate, application of fireproof and explosion-proof flat glass, the surface of the substrate glass has 1-10 colors of glaze layer, 0.1-5mm thickness of metal plate, there is a layer of bonding material between the glass plate and the metal plate The layer is characterized in that: 2-4 sides of the metal plate on the back bottom surface of the composite board of the product, and the edge of the surface glazed decorative flat glass product of the specific gravity protrudes by a distance of 10-30 mm.

Non-obvious technical effects [5]: In the above-mentioned better quality with the prior art and the strength can be 4-5 times higher than the existing flat glass, the discovery and production of this new product property makes color The combined invention of the glaze layer produces a sufficient strength to produce a thickness of 1-2 mm [equivalent to 5-15 mm of calcium soda glass strength] [a high-performance, glazed glass composite with a simple structure installed on the wall surface) Material board Product], for the current national standard external wall hanging board 12mm thick ceramic products and 25mm thickness stone product standard, the invention is high-strength, light and thin [6-25 times] replacement, generating energy, resources, logistics, warehousing Unexpected results of 6-25 times savings.

Non-obvious technical effect [6]: a. A high-performance, glazed glass composite board product with a simple structure installed on the wall surface, which can overcome the use of aluminum-plastic composite panels on the outer wall after the plastic panels are exposed to the sun. 1 year, the expansion and contraction deformation, the flatness is very poor; b. can overcome the aluminum-plastic plate pattern printing as an organic material, the outer wall 1-2 years discoloration can not be used as the outer wall defect; c. the invention of the aluminum film layer The composite board has the advantages of fine pattern, never fade, excellent flatness and long life of 50-80 years.

Non-obvious technical effect [7]: A high-performance, glazed glass composite board with a simple structure installed on the wall: a. It has the same advantages as the dry hanging aluminum panel on the outer wall; b. There is also the effect that the outer wall can not be used for hanging aluminum plates, the surface is flat and has the effect of fine stone or wood grain pattern; c. or the outer wall can not be used for hanging aluminum plates, all kinds of inorganic glazes that are not faded for 300 years. Monochrome decorative effects such as yellow, blue, gray, white, and black;

Non-obvious technical effects [8]:

a. It is much easier to install than aluminum-plastic composite panels and dry-hanging aluminum panels, and it is also easier to omit the dry hanging dragon skeleton and complicated installation process and save a lot of installation costs;

b. Use 4-6 strips of 10cm wide ceramic tile glue on the back to level, and then [the 2-4 sides of the bottom metal sheet of the composite sheet protrudes by 10-30mm from the edge of the overlapped surface glass. In this outstretched side] after several punching, use the expansion boring nail to directly nail into the wall, fix it on the wall, and then glue on the side seam to form the dry hanging decoration effect of the stone.

c. In a certain external wall twist [such as 4-60M], the tile and stone construction is not allowed to be pasted; and the present invention is a high-performance, glazed glass composite material having a simple structure installed on the wall surface. The board, the safe and firm wall used for construction, is directly nailed into the wall with the expansion boring nail, and the 4-6 strips of 4-8cm wide on the back are used to level the way [ie safe and secure, labor-saving and efficient way) Mainly, a small amount of tile adhesive is leveled and pasted as an auxiliary method];

Therefore, the present invention can solve the problem that when the decorative panel is pasted and installed in a certain degree of external wall [such as 4-60M]:

1. The pasting method is quick and easy, but the problem is not safe, and the invention can be overcome;

2. The traditional dry hanging dragon skeleton process of stone, ceramic tile and aluminum plate must be safe, but it has complicated installation process, occupying long construction time and having a large installation cost problem, and the invention can be overcome.

Non-obvious technical effect [3]: The thin and light-colored glazed decorative flat glass has a side extending 10-30mm away, and is punched directly into the wood or brick after the perforated side is punched. The material or the concrete wall; or the innovative installation fixed with the wall dragon skeleton, the characteristics of the inner and outer wall applications are: [1] the installation method is very simple and quick and effective; [2] the product is more than the stone and the tile Light and thin 6-20 times; [3] The safety after installation is much higher than that of the stone and tile attached to the wall, and will never fall; [4] There is also a stone with strong strength and flatness and no discoloration for hundreds of years. And wood pattern texture; [5] is particularly suitable for interior and exterior wall applications in wooden villas or low-rise buildings; with non-obvious technical effects. It represents a new trend in decorative materials in the installation of interior and exterior walls of buildings.

[I] Invented indoor floor decoration type knot combination application invention:

The invention of the invention or the change of the elements is applied in the dependent claims and the combination, 37:

A high-performance, glazed glass composite floor with an easy-to-assemble structure:

A high-performance, glazed glass composite flooring with easy-to-assemble structure, including: [1] surface glazed glass substrate, [2] adhesive layer, [3] bottom layer, features It is: the surface layer of glazed glass material substrate is a high softening point, low differential coefficient of thermal expansion coefficient, low crystallization rate, fireproof and explosion-proof flat glass; 1-2 sides of the bottom layer, the bottom layer has protruding glass The outer edge of the face is 1-25mm; the other 1-2 sides of the bottom layer, the bottom layer has a feature of 1-25mm concave edge of the glass surface; the thickness of the bottom layer of the convex or concave glass surface is the material of the bottom layer 10%-90% of the thickness.

A high-performance, glazed glass composite flooring with an easy-to-assemble structure, the bottom layer: either a wood board; or a metal material board; or a wood board composite board; or a wood powder composite board; or It is a resin material board.

Non-obvious technical effects [1]: The low crystallization rate properties found, resulting in the technical effects of high quality and large production.

Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the invention, better high temperature zone thermal expansion difference, higher strength and the like, high performance, the shape of the glass can be maintained, and the non-obvious technical effect of fireproofing and fireproofing can be achieved. The invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and the ability to prolong the fireproof and explosion-proof time and prolong the ignition time, and has a non-obvious technical effect.

The product of the invention solves the technical problem that the wood floor and the wood composite floor material are eager to solve without successful fireproofing, fireproofing, prolonging the fireproof and explosion-proof time and prolonging the ignition time, and represents a high level of ground decoration. The development trend of material technology.

Non-obvious technical effects [3]: advantages over wood flooring and wood composite flooring:

The invention compares the apex of the first comparative technique [1][2][3][4] from 180Mpa, substantially improves and improves to the apex of the flexural strength 240Mpa; compared with the prior art [1][2 ][3][4] The flexural strength is substantially improved and improved by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; compared with the existing aluminum-containing 12-15% touch screen glass The flexural strength of 100 Mpa is increased by about 2.4 times; it is about 5 times higher than that of calcium sodium glass.

Therefore, in the field of use, it has higher strength; more light and thin effect: wood floor and wood type composite floor are generally 18mm thick; the invention can be only 4-5mm thick when the resisting strength is higher than wood;

The product of the invention solves the technical problem of the high-strength and light-weight effect which is solved by the people who are eager to solve the wooden floor and the wooden composite floor material, and represents the development of the high-level floor decoration material technology. trend.

Non-obvious technical effects [4]: advantages over wood flooring and wood composite flooring:

More wear resistance: Since the product of the invention can sinter the color glaze layer below 650-740 ° C, the printing glaze layer can be sintered, and a large amount of various crystals such as 30-80% can be added to the glaze layer, especially the low cost. Quartz or steel jade crystal powder or granules, forming an unprecedented hardness of 0.2-3mm wear-resistant surface layer (quartz can reach 7 grade hardness, while adding steel jade can reach 9 grade hardness), and this is not in ceramic production As a result, since the firing temperature of the ceramic is between 1100 ° C and 1200 ° C, the quartz or steel jade of the ceramic surface can only become the glass phase, and below 730 ° C, the quartz or steel jade crystal can maintain the crystal phase; It can also form an unprecedented decorative glass polished quartz crystal with a hardness of 7 grade wear surface; it has non-obvious technical effects.

The product of the invention solves the technical problems of the high-level floor decoration material technology in the materials of the wooden floor and the wood composite floor, which people are eager to solve without successful abrasion resistance and easy drawing.

Non-obvious technical effects [5], advantages over wood flooring and wood composite flooring:

Because the surface substrate material is floated, it is more flat.

The non-obvious technical effect [6] is better than the pattern of wood flooring and wood composite flooring:

The product of the invention is used for designing and replacing all kinds of wood grain and stone grain and carpet products, not only has high strength, but is light and convenient to install and transport, and can also be printed by computer to ensure various wood grain and stone grain, and Carpet products such as wool, chemical fiber, silk material and other realistic carpet patterns;

Non-obvious technical effects [7], advantages over wood flooring and wood composite flooring:

a. In the glass surface of the invention and the bottom layer of the resin material, it is not afraid of complete water intrusion, and has the advantages that the traditional all-wood floor and the wood-type composite floor are incomparable;

b. In the complete water intrusion state, the invention adopts the wooden material floor layer, and does not cause the glass edge to be winged or deformed from the whole wood floor and the wood composite floor, and has the traditional full wood floor and wood composite. Unmatched advantages of the floor;

c. In the side of each glass surface of the invention, the waterproof glue can be used for the purpose of completely waterproofing the invention, and has the advantages that the traditional wooden floor and the wooden composite floor are incomparable;

Solving the technical problems of wood flooring and wood composite flooring, people are eager to solve and have not succeeded in water intrusion, representing the development trend of high-level floor decoration materials technology.

Non-obvious technical effects [8]:

The invention compares the installation manner of wood grain tile, various tiles and stone paste on the ground;

a. The invention has the characteristics of innovative combination structure, so that the non-obvious technical effect of the installation is easy, and the installation method is as convenient as the wooden floor, the time is cheap, the labor is saved, the installation is 50-60 square meters for one day; the wood grain tile, Tiles, stone 50-60 square meters installation maintenance to 3-5 days.

b, the present invention compares wood grain tiles, various tiles, stone installation methods, cleaner, hygienic, environmentally friendly; and no excess sand, cement, please remove and transport;

The invention not only has the above-mentioned 7 kinds of technical effects, but also has the technical effect of convenient installation of the wooden floor; the invention solves the wood grain tile and various ceramic tiles which are desired to be solved without success in the floor decoration material. The installation of stone is time-consuming, labor-intensive, and environmentally-friendly. It represents the development trend of high-level floor decoration materials technology.

Non-obvious technical effects [9]:

The invention compares the way of wood grain tiles, various tiles, and stone paste on the ground:

a. When the invention is dismantled: due to the innovative features of the combined structure, a non-obvious technical effect that facilitates folding and facilitating secondary decoration is produced, which is as convenient as a wooden floor: (50-60 square meters, for use) 2 hours to complete)

b. Wood grain tiles, various tiles, stone, when dismantling:

The joint with the ground should be dismantled with a large drill or a sledgehammer, and 50-60 square meters should be dismantled, and 3-5 days may not be completed; the building is highly destructive, and the waste cargo is large and environmentally friendly;

Wood grain tiles, all kinds of tiles, stone and ground bonding parts, should be removed by large drills or sledge hammers, the sound is very loud, because it is very scratching the people, and the reaction is strong.

The invention not only has the above-mentioned 7 kinds of technical effects, but also has the technical effect of dismantling conveniently like a wooden floor; and solves the wood grain tile, various ceramic tiles and stone removal technology which are desired and solved without success in the floor decoration material. The problem represents the technical development trend of high-level floor decoration materials.

Non-obvious technical effects [10]:

Comparing wood grain tiles, various tiles, and the way the stone is directly attached to the concrete floor will produce a feeling of being too hard under the feet;

The invention has a layer below: either a wood board; or a wood board composite board; or a wood powder composite board; or a bottom layer of a resin material; but since it is installed like a wooden floor, there is a layer of bottoming a layer of wood or a wooden strip; that is, a combination of a 'recessed outer lower portion of the bottom layer' and a layer of bottomed wood or wooden strip, which is formed by a number of small nails (ie, wood) The installation method of the floor) and the pressure of the floor layer; this can produce the same elasticity under the feet as the wooden floor.

Non-obvious technical effects [11]:

For tiles or stone floors that are inconvenient to be dismantled, the invention can also be assembled directly on the surface quickly; the installation construction is cleaner than cement, high efficiency, convenient, and can also produce high simulation wood texture or stone texture. Decorative effect.

Non-obvious technical effects [12]:

The invention is not only used for the imitation wood grain product, especially when used in various ground products with high embellished stone pattern ornate decorative effect, comparing the tile, stone product and directly pasting on the cement floor: non-obvious technology The effect is:

It can be used, such as 45x45cm; 30x60cm, 40x80cm, 60x60cm, 90x90cm and other high-simulation stone pattern gorgeous decorative ground products, using the invention, on the home floor, often changing the commercial facade, department store floor, hotel Ground, chain store ground and other places; installation and demolition construction are cleaner than cement paste construction, to achieve rapid and direct assembly, high efficiency and convenient technical effect;

For traditional stone and tile cement paste construction and demolition construction methods: [1] large workload, complicated, chaotic, and unclean; [2] long installation time and low efficiency; [3] and demolition construction is more labor-intensive , complicated, chaotic, and unclean; [4] long and inefficient to dismantle construction;

Therefore, the problem of the traditional stone and porcelain cement paste floor installation and installation method can be effectively overcome. Has a non-obvious technical effect.

Moreover, the present invention, in the use of a high-performance, glazed glass composite flooring having an easy-to-assemble structure, utilizes these new properties and utilizes the combined inventive functional features of the easy-to-assemble structure to produce Unexpected technical effects are also unclear in common sense and cannot be inferred from common sense. The nature of these new discoveries and the unpredictable technical effects of using these new properties have not been disclosed by all prior art.

According to the technical solution of the present invention, the invention of the invention or the change of the element is applied in the combination

'A high-performance, glazed glass composite flooring with easy-to-assemble structure', because of the discovery of new material properties, and the use of these properties and the use of these combined functional features with easy-to-assemble structures, The above 12 kinds of unexpected technical effects are produced; therefore, it should be judged that the technical solution of the present invention has substantial progress and creativity.

[J]High-performance glass wash basin type bathroom decoration type knot combination application invention:

</ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt;

A high-performance glass wash basin produced by a thermal deformation process, which is a high-performance glass wash basin produced by a thermal deformation process for a flat glass material from a desired wash basin-shaped mold, characterized in that: The flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass.

The invention in which the dependent claims and the combination are applied to the invention or the element change, 39:

A high-performance glazed glass wash basin produced by a thermal deformation process, which is a high-performance glass wash basin produced by a thermal deformation process for a flat glass material from a desired wash basin-shaped mold. The utility model is characterized in that: the flat glass material is a high softening point, a low difference of a thermal expansion coefficient in a high temperature zone, a low crystallization rate, a fireproof and explosion-proof flat glass; and a color shaft layer is attached to the glass.

</ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt;

A high-performance glazed glass lifting panel and a combined wash basin produced by a thermal deformation process, the structural features of which are: 1. a flat-shaped lifting panel; 2. another part of the joint is a flat panel Glass material consists of a desired wash basin-shaped mold, a glass wash basin produced by a thermal deformation process; 3. The flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, and a low resolution Crystal speed, fireproof and explosion-proof flat glass; 4. The glass surface is attached with a color shaft layer.

The invention of the invention or the change of the elements is applied in the dependent claims and the combination, 41:

A high-performance glazed glass washbasin countertop for a bathroom, characterized in that: 1. The countertop glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature zone, and a low analysis Crystal speed, application of fireproof and explosion-proof flat glass; 2. glazed layer of 1-10 colors on the surface or back of the table; 3. There is a hole for installing the wash basin on the surface of the table; 4. Supporting device at the lower part of the table .

The above four types of high-performance glass wash basins are designed to be combined with the invention. Compared with the traditional soda-lime glass washbasin products, they have non-obvious technical effects:

Non-obvious technical effects [1]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it is exposed to fire or high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the furniture, which greatly enhances the ability of bursting in the high temperature region when the glass volume is rapidly increased, and has non-obvious technical effects.

It also enables the strength of various high-performance glasses to be five times higher than the strength of existing calcium-sodium tempered glass at the same thickness and weight.

Non-obvious technical effects [3], various high-performance glazed glass lifting panels: a., the appearance of high-simulation wood grain, stone artefact and appropriate product design entry point; b. brand new inorganic Glaze set The unique technical characteristics of the sturdy and wear-resistant of the high-strength glass; c. It is stronger than the traditional stone or artificial stone lifting panel, high strength, light and thin, easy to install, and very environmentally friendly.

The invention in which the dependent claims and the combination are applied to the invention or the element change, 42:

An ultra-long glass plate for a balcony protection barrier, the glass thereof is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass. It is characterized in that the length of the glass plate of the balcony protection barrier is 3-8 m.

Non-obvious technical effect: In the field of this application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior comparison technology [1][2][3][4]; compared with the existing TFT Boron-containing glass, light and thin 1/3; lighter than calcium sodium glass, 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight. It also enables the strength of the glass to be five times higher than the strength of the existing calcium soda glass at the same weight.

The technical effect of the coating of the invention is that the glass materials for construction are all sodium soda glass, the strength is only 50Mpa; and the performance glass of the invention can reach 180-240Mpa, and the geometric multiple of 4-5 times is higher. The strength of the building glass can be prevented from impact, explosion-proof, anti-shock performance, etc., and the safety is increased by 4 times -5 times;

The length of the glass plate which can be designed as a balcony protection barrier is 3-8m in length, not all in the length of 3-8m, and is divided and blocked by the erect aluminum alloy frame; it is an unobstructed panoramic building balcony glass, When sitting on the curtain of the balcony, the eyesight is only about 70cm. The height of the glass plate of the balcony protection barrier can be designed to be 0.9m-1.3m. If there is a horizontal protection armrest with a length of 3-8m, it is also designed to be 0.9m-1.3m);

The new functional life experience of the resident owners sitting on the raft on the balcony:

1] Not only can visually display a large range of beautiful landscapes outside the balcony (such as garden, mountain, water, sea, city), but also in the outdoor nature of the air, creating a balcony building New functional life experience;

2]Because it can create a new functional life experience, the balcony building space can have: outdoor scenery + tea bar for family members or guests, or outdoor scenery + coffee bar or family for family, or guests; Or the outdoor beauty + bar with the guests; or the family, or the outdoor scenery + reading bar with the guests; or the family, or the outdoor beauty + computer bar with the guests; innovative balcony building space function;

3] It can cover the overall appearance of the façade of various types of balcony protection building glass;

4] can create a new balcony architectural design consumer market, create a new history of architectural design value; more bring new value to builders and users, with non-obvious technical effects:

DRAWINGS

1 is a schematic plan view showing a high softening point, a low crystallization rate, a special aluminum non-alkali, fireproof and explosion-proof flat glass according to the present invention;

2 is a schematic flow chart of a float process for preparing a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a preparation process of fireproof and explosion proof flat glass;

3 is a side cross-sectional view showing a state in which a high softening point, a low crystallization rate, a special aluminum non-alkali, and a fireproof and explosion-proof flat glass are prepared by a float process.

4 is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of the fireproof and explosion proof flat glass. The size of the embodiment is 1220 mm × 2440 mm and the thickness is about 2-5 mm. The color glaze of the three color zones forms a plan view of a glazed flat glass article whose surface layer is a predetermined glaze pattern decorative layer of about 0.1-1 mm thickness.

Figure 5 is a high softening point, low crystallization rate, special aluminum non-alkali, fireproof and explosion-proof flat glass of the present invention, the back side is an aluminum plate with overlapping rear side without exceeding the size of the surface silicate glaze decorative glass, through the sticking

Schematic diagram of the cross-sectional structure of a new composite sheet composed of a mixture of adhesives.

Figure 6 is a high softening point, low temperature coefficient of thermal expansion coefficient of low temperature, low crystallization rate, application of fireproof and explosion-proof flat glass, the back is overlapped with two sides than the surface silicate glaze decoration The glass sizes are each extended.

10-30mm aluminum plate, a new composite sheet composed of a composite of 10-30mm, extending at 10-30mm

After the predetermined position on the hole is punched, a schematic diagram of the vertical plane structure of the wall nail mounting can be performed.

7 is a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and the application of fireproof and explosion-proof flat glass, the back side has two sides than the surface silicate glaze decorative glass size An aluminum plate with a distance of 10-30 mm is extended, and a cross-sectional structure diagram of a new composite plate composed of a composite material is adhered to each other.

Description of the reference numerals

1: a high softening point, low differential coefficient of thermal expansion coefficient in high temperature zone, low crystallization rate, application of fireproof and explosion-proof flat glass

2: silo inlet

3: silo

4: Scheduled mixed raw materials

5: The raw material enters the molten pool kiln mouth of the molten pool

6: molten pool kiln

7: diversion channel

8: Tin bath

9: Transition Roller

10: Annealing kiln

11: Cutting and dispensing station

12: float production line substrate

13: High-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass with colored glaze layer

14: An aluminum plate with a low-melting-point glaze decorative flat glass edge that does not exceed the surface layer high annealing temperature and high strength

15: indicates a predetermined adhesive

16: indicates that the backing aluminum plate of the composite sheet has a higher annealing temperature than the surface layer, and the environmentally-friendly and energy-saving low-melting glaze decorative flat glass protrudes from the side of the 10-30 mm side.

21: the slashed line indicates the printed first color glaze pattern area

31: The crosshair portion indicates the printed second color area glaze pattern area

41: The small black dot portion indicates the printed third color area glaze pattern area

141: It means that there are two sides of the low-melting glaze decorative flat glass with two sides that are higher than the surface layer and have a high annealing temperature and high strength.

detailed description

Inventive Example 1: (preferably an alkali-free product example)

In terms of weight percent, the alumina content is 29.2%, the sodium oxide content is 0.1%, the silica content is 47.2%, the calcium oxide content is 13%, and the magnesium oxide content is 10.5%, which is characterized by: the silica content is oxidized. The calcium content is 3.6 times and the calcium oxide content is 1.2 times the magnesium oxide content.

In the present example, the actual melting time is 10 ^1.5 (Pa·s) viscosity temperature 1540 ° C; in this example, when the glass bubbles are discharged, the glass temperature is 10 ² (Pa·s) and the viscosity temperature is 1390 ° C. The anti-analytical strength is 192 MPa.

The crystallization rate of the present invention will be relatively slow, and the crystallization will start after 60-120 minutes under the condition that the upper line range of each glass crystallization temperature zone is gradually lowered.

This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the prior art 2 has a difference in thermal expansion rate between 550 ° C and 600 ° C in the high temperature region and 600 ° C to 650 ° C in the high temperature region. Values range from 1-2.8 or 1-3 parts per million.

In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is within 2-5 parts per million in the high temperature region of 700 ° C to 740 ° C. The difference in thermal expansion rate of the other glass in the high temperature region is much lower;

This example of the invention has a high softening point of up to 825 °C.

Inventive Example 2: (preferably an alkali-free product example)

In terms of weight percent, the alumina content is 23.9%, the sodium oxide content is 0.1%, the silica content is 53%, the calcium oxide content is 15.5%, and the magnesium oxide content is 9.5%, which is characterized by: the silica content is oxidized. The calcium content is 3.9 times and the calcium oxide content is 1.4 times the magnesium oxide content.

In the present example, the actual melting time is 10 ^1.5 (Pa·s) viscosity temperature 1570 ° C; in this example, the actual glass discharge bubble viscosity temperature 10 ² (Pa·s) 1435 ° C. The analytical strength is 172 MPa.

Under the condition that the upper line range of the crystallization temperature zone of the invention is naturally cooled, crystallization is started after 60-90 minutes under the condition of gradually lowering the upper line range of each glass crystallization temperature zone.

In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 2-5.5 parts per million in the high temperature range of 700 ° C to 740 ° C.

The present invention has a high softening point of up to 825 ° C;

Inventive Example 3 (preferably an alkali-free product example):

In terms of weight percent, the alumina content is 36.5%, the sodium oxide content is 0.2%, the silica content is 40.3%, the calcium oxide content is 12%, and the magnesium oxide content is 11%, which is characterized by: the silica content is oxidized. The calcium content is 3.35 times and the calcium oxide content is 1.1 times the magnesium oxide content.

In the present example, the actual melting time was 10 ^1.5 (Pa·s) viscosity temperature of 1660 ° C; in this example, the bubble temperature of 10 ² (Pa·s) was 1475 ° C. The anti-analytical strength is 228 MPa.

In the invention, since the crystallization rate is relatively slow, and the upper line range of the crystallization temperature zone is naturally cooled, the upper line range of each glass crystallization temperature zone is gradually lowered under the condition of 60-120 minutes. Start crystallization.

This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.

In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is within 2-4 parts per million in the high temperature range of 700 ° C to 740 ° C. The difference in thermal expansion rate of the other glass in the high temperature region is much lower;

The present invention is greatly increased in softening point by 840 ° C;

This example also has a very wide range of special glass, electronic glass, architectural glass, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increasing, and can be used in the display of electronic glass display products. The nature of the resolution level can be substantially improved and improved.

Inventive Example 4: (preferably an alkali-free product example)

In terms of weight percent, the alumina content is 16.5%, the sodium oxide content is 0.1%, the silica content is 52%, the calcium oxide content is 18%, and the magnesium oxide content is 15.4%, which is characterized in that the silica content is oxidized. The calcium content is 2.9 times and the calcium oxide content is 1.2 times the magnesium oxide content.

In the present example, the actual melting time is 10 ^1.5 (Pa·s) and the viscosity temperature is 1460 ° C. In this example, when the glass bubbles are discharged, the glass temperature is 10 ² (Pa·s) and the viscosity temperature is 1360 ° C. The analytical strength is 126 Mpa.

In the invention, since the crystallization rate is relatively slow, and the upper line range of the crystallization temperature zone is naturally cooled, the upper line range of each glass crystallization temperature zone is gradually lowered under the condition of 60-90 minutes. Start crystallization.

In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is within 6-8 parts per million in the high temperature region of 700 ° C to 740 ° C. The difference in thermal expansion rate of the other glass in the high temperature region is much lower;

The softening point of the present invention is as high as 785 ° C;

Embodiment 5 of the present invention:

In terms of weight percent, the alumina content is 24%, the sodium oxide content is 3.4%, the silica content is 49.6%, the calcium oxide content is 15%, and the magnesium oxide content is 10%, which is characterized by: the silicon oxide content is oxidized. The calcium content is 3.8 times and the calcium oxide content is 1.3 times that of the magnesium oxide.

In the present example, the actual melting time is 10 ^1.5 (Pa·s) viscosity temperature 1520 ° C; in this example, when the glass bubbles are discharged, the glass temperature is 10 ² (Pa·s) and the viscosity temperature is 1400 ° C. The anti-analytical strength is 161 MPa.

In the present invention, since the content ratio of calcium oxide is much lower, and the content ratio of silicon oxide is higher, the crystallization rate of the present invention is relatively slow, and the upper line range of the crystallization temperature zone is naturally cooled under the condition of 60-120 minutes. After that, crystallization will begin under the conditions of the upper line of the glass crystallization temperature zone and the gradual cooling.

In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million 0.1-0.99 Within the high temperature region of 700 ° C - 740 ° C, the difference in thermal expansion rate is within 1-5.9 or 6-8 parts per million. The difference in thermal expansion rate of the other glass in the high temperature region is much lower; in addition, the softening point of the present invention is greatly increased to 765 ° C;

Embodiment 6 of the present invention:

In terms of weight percent, the alumina content is 20.8%, the sodium oxide content is 3.2%, the silica content is 53%, the calcium oxide content is 15.5%, and the magnesium oxide content is 9.5%, which is characterized by: the silica content is oxidized. The calcium content is 3.9 times and the calcium oxide content is 1.4 times the magnesium oxide content.

In this example, the actual melting time is 10 ^1.5 (Pa·s) viscosity temperature 1510 ° C; in this example, the actual glass discharge bubble viscosity temperature 10 ² (Pa·s) 1385 ° C. The analytical strength is 148 MPa.

In the present invention, since the crystallization rate is relatively slow, and the upper line range of the crystallization temperature zone is naturally cooled, crystallization is started after 60-90 minutes.

The present invention has a high softening point of 775 ° C;

In the high temperature range of 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, and the difference between the thermal expansion rates of 650 ° C and 700 ° C in the high temperature range is in parts per million. Within 0.1-0.99, in the high temperature zone 700 ° C - 740 ° C, the difference in thermal expansion rate is within 1-5.9 or 6-8 parts per million. The difference in thermal expansion rate of the other glass in the high temperature region is much lower;

Embodiment 7 of the present invention:

In terms of weight percent, the alumina content is 35.4%, the sodium oxide content is 2.1%, the silica content is 42%, the calcium oxide content is 12%, and the magnesium oxide content is 8.5%, which is characterized by: the silica content is oxidized. The calcium content is 3.5 times and the calcium oxide content is 1.4 times the magnesium oxide content.

In the present example, the actual melting time is 10 ^1.5 (Pa·s) viscosity temperature 1580 ° C; in this example, the bubble temperature is 10 ² (Pa·s) viscosity temperature 1425 ° C. The anti-segregation strength is 213 MPa.

The present invention has a much lower content ratio of calcium oxide (the content of calcium oxide is too high, and the crystallization rate is accelerated), and the content ratio of silicon oxide is higher, so the crystallization rate of the present invention is relatively slow.

Under the condition that the upper line of the crystallization temperature zone is naturally cooled, crystallization will start after 60-90 minutes.

The softening point of the present invention is as high as 820 ° C;

In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 or 6-8 in the high temperature range of 700 ° C to 740 ° C. The difference in thermal expansion rate is much lower than that of other glasses in the high temperature region.

Embodiment 8 of the present invention:

In terms of weight percent, the alumina content is 36.5%, the sodium oxide content is 2.2%, the silica content is 40.3%, the calcium oxide content is 12%, and the magnesium oxide content is 9%, which is characterized by: the silica content is oxidized. The calcium content is 3.35 times and the calcium oxide content is 1.3 times the magnesium oxide content.

In the present example, the actual melting time is 10 ^1.5 (Pa·s) viscosity temperature 1630 ° C; in this example, the bubble temperature is 10 ² (Pa·s) viscosity temperature 1415 ° C. The analytical strength is 221 MPa.

The crystallization rate of the invention will be relatively slow, and the crystallization of the upper line of the crystallization temperature zone will naturally begin after 60-150 minutes.

The softening point of the present example of the present invention is as high as 830 °C.

In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 parts per million in the high temperature range of 700 ° C to 740 ° C. The difference in thermal expansion rate is much lower than that of other glasses in the high temperature region.

Inventive Example 9: (preferably an alkali-free product example)

In terms of weight percent, the alumina content is 16.6%, the sodium oxide content is 0.3%, the silica content is 59.3%, the calcium oxide content is 13.8%, and the magnesium oxide content is 10%, which is characterized by: the silica content is oxidized. The calcium content is 4.3 times and the calcium oxide content is 1.38 times the magnesium oxide content.

In this example, the actual melting time is 10 ^1.5 (Pa·s) viscosity temperature 1580 ° C; in this example, 10 ² (Pa·s) viscosity temperature is 1460 ° C; the anti-segregation strength is 134 Mpa.

The softening point of this example of the present invention is very high, up to 810 °C.

Inventive Example 10: (preferably an alkali-free product example)

In terms of weight percent, the alumina content is 17.8%, the sodium oxide content is 0.3%, the silica content is 59.3%, the calcium oxide content is 12.51%, and the magnesium oxide content is 10%, which is characterized by: the silica content is oxidized. The calcium content is 4.7 times and the calcium oxide content is 1.26 times the magnesium oxide content.

In the present example, the actual melting time is 10 ^1.5 (Pa·s) viscosity temperature 1620 ° C; in this example, 10 ² (Pa·s) viscosity temperature is 1480 ° C; the anti-segregation strength is 138 Mpa.

From the above-described 10 embodiments of the present invention, it is analyzed how the present invention discovers new properties, produces technical effects, and overcomes the drawbacks of the prior art [1].[2].[3].

There is a comparative technique [1].[2].[3] whose composition is different from the present invention and is not identical:

(1), prior contrast technology [1]: The inventor's prior invention: the application of high-strength, high-level, low-viscosity flat glass with high annealing point and environmental protection and energy saving, and related components, patent number 201110060944.4 ,

(2) First comparative technology [2]: The inventor's 201510161553.61, a flat glass having a low coefficient of thermal expansion and a preparation process thereof.

(3), prior art [3]: Inventor's 201410408822.3, a flat glass produced by the anti-crystallization method of the cooling portion,

Including the present invention and the glass materials of [1].[2].[3], both of which have different characteristics of the properties of the two-sided glass material:

On the one hand, the glass of this specific composition has sharp crystallization peaks in the DSC curve at the strong crystallization temperature range, and the conversion time of the glass from liquid to crystallization devitrification is short and fast, and there is a technical difficulty in crystallization and devitrification in the cooling process.

On the other hand, there are a variety of excellent glass material features to varying degrees.

In the first comparative technology [1] technical solution: the content of silicon oxide is 1.9 times -4.1 times the content of calcium oxide, and the content of calcium oxide is 1.0 times -1.8 times the content of magnesium oxide;

In the prior art [2] technical solution: the content of silicon oxide is 4.11 times - 5.48 times of the content of calcium oxide, and the content of calcium oxide is 0.8 times - 1.99 times of the content of magnesium oxide;

In the prior art [3] technical solution: the content of silicon oxide is 1.6-5.8 times that of calcium oxide, and the content of calcium oxide is 0.8--2.1 times of magnesium oxide;

The invention belongs to a new use invention of a chemical product: in the technical solution, the content of silicon oxide is 2.51 times to 4.8 times of the content of calcium oxide, and the content of calcium oxide is 1.0 times to 1.8 times of the content of magnesium oxide;

It can be seen that the composition of the prior art [1].[2].[3] is intersected and not identical to the present invention:

[1] The difference is: 1.9 times -4.1 times the front end of the technique [2] 1.9-2.5 times and 1.6-5.8 times the front end of the contrast technique [4] 1.6-2.5 times, outside the scope of the present invention.

[2] The difference is: 4.11 times - 5.48 times of the back end of technology 3 is 4.81 times - 5.48 times, and the back end of the technique 4 is 4.81 times - 5.8 times of 1.6 - 5.8 times, which is outside the scope of the present invention.

[3] The difference is: in the technical solution of Comparative Technology 3.4: the content of calcium oxide is 0.8 times to 1.99 times of magnesium oxide; 0.8--2.1 times; both the front and the back end are larger than the range of 1.0 times to 1.8 times of the present invention.

The invention belongs to a new invention invention of chemical products:

It was found that in the technical solution, especially when the silica is 2.51 to 4.8 times that of calcium oxide; the calcium oxide is 1.0 to 1.8 times of the magnesium oxide; a new [a. low crystallization rate] material property is produced. Known to known compounds [b. difference in thermal expansion coefficient in high temperature zone] and [c. softening point] and [d. co-melt of aluminum, silicon, calcium and magnesium at low viscosity and high aluminum content The nature] and the various effects produced. Compared with the prior art [1].[2].[3], there are substantial improvements and improvements. (See Examples 1-10)

For the technical solution of the present invention, when the silicon oxide is 2.51 times to 4.8 times that of calcium oxide; when the calcium oxide is 1.0 times to 1.8 times of the magnesium oxide, the above four properties of abcd are found, and The nature of the production, there are substantial improvements and improve various effects; first comparative technology [1]. [2]. [3], technical solutions, no discovery and disclosure.

However, in the prior art [1].[2].[3], in the technical solution, in the technical solution of the present invention, the silicon oxide is 2.51 times-4.8 times that of calcium oxide; the calcium oxide is 1.0 times of magnesium oxide- The technical solutions other than the front and back ends of the 1.8-fold range cannot have [the formation of the above four properties of abcd and the various effects produced, and substantial improvements and improvements], and there are several defects:

[a] such as:

First, there is a comparative technology [1].[2].[3], in the technical solution: 4.11 times - 5.48 times of the back end of the comparison technology [2] 4.81 times - 5.48 times, compared with 1.6 of the comparison technology [3] 5.8 times the back end of 4.81 times -5.8 times, outside the scope of the present invention, may result in: [d. the low viscosity and high aluminum content of the aluminum, silicon, calcium, magnesium co-melt properties are not present;

See Comparative Example 2:

Comparative Example 2: The technical content of the comparative technique [3] has a silica content of 4.11 times to 5.48 times of the calcium oxide content of 4.11 times to 5.48 times, and a back end of 1.6 to 5.8 times of the comparative technique [4]. In the range of 4.81 times to 5.8 times: Comparative Example 2 [Comparative Example of SiO2 content which is 5.3 times of calcium oxide content]. The silica content of the present invention is outside the range of 2.51 to 4.8 times the calcium oxide content.

Comparative Example 2: In terms of weight percent, the alumina content was 20%, the sodium oxide content was 1%, the silica content was 58%, the calcium oxide content was 11%, and the magnesium oxide content was 10%, which was characterized by: [The content of silicon oxide is 5.3 times that of calcium oxide], and the content of calcium oxide is 1.1 times that of magnesium oxide. When the actual melting time is 10 ^1.5 (Pa·s), the viscosity temperature is too high, which can not be measured by the US THETA rotary high-temperature viscometer; in this example, the bubble temperature is 10 ² (Pa·s) viscosity temperature is 1610 ° C [than calcium sodium glass row When the bubble is 10 ² (Pa·s), the viscosity temperature is 1430 ° C and 髙 180 ° C; it is difficult to discharge bubbles during large production;

It can be seen that the viscosity temperature of Comparative Example 2 at an alumina content of only 20% is so poor that there is no eutectic property of aluminum, silicon, calcium, and magnesium at a high aluminum content. It is also impossible to add the alumina content to 25-39% to achieve large production; it is impossible to achieve the 180-240 MPa strength.

[b]如:

The first comparison technology [1].[2].[3], the technical solution: such as 1.9 times -4.1 times the front end of the comparison technology 2 1.9-2.5 times and the front end of the comparative technology 4 1.6-5.8 times 1.6- 2.5 times, outside the scope of the present invention, results in a known knowledge of known compounds [a. faster crystallization rate of material properties];

See Comparative Example 1:

Comparative Example 1: This is the prior art [2] technical solution, the silicon oxide content is 1.9 times -4.1 times the front end of the calcium oxide content is 1.9-2.5 times, and the front end of the comparative technology [4] is 1.6-5.8 times. In the range of 1.9-2.5 times in the range of 1.6-2.5 times, [the silica content is a comparative example of 2.0 times the calcium oxide content]. The silica content of the present invention is outside the range of 2.51 to 4.8 times the calcium oxide content.

Comparative Example 1: In terms of weight percent, the alumina content was 20%, the sodium oxide content was 8%, the silica content was 38%, the calcium oxide content was 19%, and the magnesium oxide content was 15%, which was characterized by: [The content of silicon oxide is 2.0 times that of calcium oxide], and the content of calcium oxide is 1.3 times that of magnesium oxide.

The actual melting time is 10 ^1.5 (Pa·s) viscosity temperature 1440 ° C; in this example, 10 ² (Pa·s) viscosity temperature is 1330 ° C;

The anti-semination strength is 136 Mpa.

In Comparative Example 1, the softening point was very low at 710 °C.

Comparative Example 1: The crystallization rate will be relatively fast, and in the upper line range of the glass crystallization temperature zone, under gradual cooling conditions, crystallization will begin within 10 to 31 minutes. Therefore, it has great difficulties in large production; because of the bottom of the cooling part, the corners, or the glass area before the molding, the heating device and the temperature measuring device are added. However, due to the difference in heating time from the temperature point to the start of heating and the instability of the fluidity of the molten glass, in the large production, the crystallization rate is too fast, causing local crystallization, which also causes difficulty in producing flat glass. .

Comparative Example 1: In the high temperature region 550 ° C - 600 ° C, the difference in thermal expansion rate at 600 ° C - 650 ° C is 1-2.8 or 1-3 parts per million.

Compared with the present invention, in the high temperature region of 600 ° C - 650 ° C, the difference between the thermal expansion rates of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, and in the high temperature range 650 ° C - 700 ° C, the difference in thermal expansion rate is Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 parts per million in the high temperature range of 700 ° C to 740 ° C. The difference in thermal expansion rate of the flat glass in the high temperature region is much lower than that of the present invention.

Therefore, the technical effect of the flat glass in the application of fireproof, fireproof and heat insulating waves cannot be improved.

Therefore, it cannot be improved, and it is applied to various display electronic glass, display low-temperature polysilicon process, and roll-to-roll electronic glass process which have extremely high temperature resistance requirements for glass, because the glass volume in the high temperature region is rapidly increasing. The technical effect of bursting.

Therefore, it cannot be upgraded and is applied to electronic glass products such as mobile phones, tablet computers, laptop computers, desktop computers, televisions, and the like, and the technical effects of higher resolution levels in the use of electronic glass and combined invention terminal products.

The invention belongs to a new invention invention of chemical products:

It can be seen from the foregoing 10 examples of the present invention that a new [a. low crystallization rate] material property is found; a known compound is known [b. difference in thermal expansion coefficient in a high temperature region] and [c. high softening Point] and [d. properties of eutectic of aluminum, silicon, calcium, and magnesium at low viscosity and high aluminum content] and various effects produced. Compared with the prior comparative techniques [1].[2].[3], there are substantial improvements and improvements, as summarized below:

A. In the new application of the present invention, a new glass product [low crystallization rate] material property is found, which is not clear in common knowledge and cannot be inferred from common sense;

Because the product of the present invention and the prior comparative techniques [1][2][3][4] have the characteristics that the upper line [highest point] of the crystallization temperature is higher than the molding temperature; it is a glass material having two-sided characteristics: one side is The glass of this specific composition has sharp crystal peaks in the DSC curve at the strong crystallization temperature range, and the glass transition from liquid to crystallization devitrification is shorter and faster than other glasses; but the other side has low viscosity and high Aluminum and silicon, calcium, magnesium eutectic properties and other excellent characteristics; so in order to study the selective use of glass with slow crystallization rate in large production, it is beneficial to cool the glass in the cooling working part before molding. Process stage to reduce the risk of crystallization;

Because it is necessary to cool the temperature of the glass in the working part, the process must be controlled by the crystallization temperature, and some heating control will be added especially in the liquid crystal edge and the corner and bottom which are easy to devitrify in the cooling working part. The device; however, in the glass liquid at the corners and bottom of the cooling working part, there will also be some products that flow slowly in the upper line range of the glass crystallization temperature zone, and the product with faster crystallization rate under the condition of gradual cooling, (such as There are comparative techniques [1][2][3][4]), the glass will produce partial crystallization within 10 to 31 minutes, there will be the risk of unqualified products entering the forming stage and causing partial devitrification of the flat glass. ;

Therefore, in the large-scale production, the material properties of the present invention should be selectively used: [the glass liquid having a relatively slow crystallization rate after 60-150 minutes, the upper line range of the inner glass crystallization temperature zone, under the condition of gradual cooling, The crystallization of the glass material is 5 times slower than that of the prior art prior art [1][2][3][4], which can be especially used in the cooling section and the forming section. And a variety of flat glass processes, forming extremely important and precise process control parameters that are much better than the prior art, so as to accurately control the large production; thus overcoming the partial devitrification of the flat glass during the forming stage. The risk of a qualified product; thereby producing a high quality sheet glass of the present invention without any crystallization due to its influence on light transmittance;

B. The present invention has substantial improvements and improvements in the known properties of the known compounds [difference in the coefficient of thermal expansion of the high temperature region] and [softening point] properties and effects;

Prior to the comparison technique [1] [2] [3] [4] in the high temperature zone 550 ° C -600 ° C, the difference in thermal expansion rate between 600 ° C and 650 ° C is 1-2.8 parts per million or 1-3 When it is in the high temperature region of 550 ° C - 600 ° C, the difference in thermal expansion rate between 600 ° C and 650 ° C is 1-2.8 or 1-3 parts per million. Moreover, it cannot withstand the high temperature zone at 650 ° C - 700 ° C and the high temperature zone of 700 ° C - 740 ° C;

The invention has a difference in thermal expansion rate between 1500 ° C and 600 ° C in a high temperature region of from 1500 ° C to 650 ° C within a range of from 0.1 to 0.99 parts per million; and a thermal expansion rate in a more severe high temperature region of from 650 ° C to 700 ° C. The difference is between 0.1-0.99 parts per million, and the difference in thermal expansion rate is between 1-5.9 parts per million in the harsher high temperature zone 700 °C-740 °C;

The softening point disclosed by the prior art [1] [2] [3] [4] is only 720 ° C; the softening point disclosed in the present invention is only 750-860 ° C.

The present invention is substantially improved and improved in view of the [difference in the coefficient of thermal expansion of the high temperature region] and the [softening point] properties and effects.

Therefore, the glass of the invention is applied to: [1] automotive glass; architectural glass; marine glass; railway car glass; aircraft glass; fireproof, explosion-proof glass; special glass; [2] wall ground with glazed glass decoration Plate; [3] various glass furniture; [4] solar glass application products and other fields of use, when encountering fire or high temperature, it is not easy to burst due to the rapid increase of the glass volume in the high temperature zone, can be in the high temperature zone state The shape of the glass cannot be maintained; the comparative technology [1][2][3][4] has the effect of improving the technical effect of fire prevention, fire separation and heat insulation;

It is applied to various display electronic glass, display low-temperature polysilicon process, and roll-to-roll electronic glass process, which have extremely high resistance to severe high temperature. The comparison technology is first [1][2][3][ 4], it is not easy to cause bursting due to the rapid increase of the glass volume in the high temperature zone; it has the effect of improving the technical level of the technical effect.

C. Because the present invention is directed to the [difference in the coefficient of thermal expansion of the high temperature region] and the [softening point] properties and effects, there are substantial improvements and improvements in the comparison techniques [1][2][3][4].

Therefore, it provides a fundamental high-resolution technical support for the use of electronic glass and combined invention terminal products for liquid crystal display products such as mobile phones, tablet computers, laptop computers, desktop computers, and televisions with higher resolution levels.

The invention represents a technical development trend of electronic liquid crystal display glass and combined invention terminal products with high resolution level.

[D]. The present invention provides substantial improvements and improvements in the properties of the eutectic of aluminum, silicon, calcium, and magnesium at low viscosity and high aluminum content.

Prior art [1] [2] [3] [4] In the examples, it has never been revealed that the present invention is 2.51 to 4.8 times that of silicon oxide as calcium oxide; calcium oxide is 1.0 to 1.8 times that of magnesium oxide. In the range, the alumina exceeds 25% or 28%, and the technical effect of the flexural strength of 180-240 MPa has never been revealed.

Comparing any of the prior art techniques [1] [2] [3] [4] of the present inventors and its dozens of samples did not reveal that the flexural strength exceeded 180 MPa; therefore, there was a comparative technique [1] [ 2][3][4] does not reveal that the present invention has substantially improved and improved [excellent properties and strength properties of eutectic of aluminum, silicon, calcium and magnesium at low viscosity temperature and high aluminum content] After that, the present invention discloses an embodiment (see 10 in the embodiment of the present invention for this range; 4 of them exceed the flexural strength of the prior comparative technique [1][2][3][4] by 60-180 MPa. ; up to 192Mpa, or 221Mpa, or 213Mpa, or 228Mpa); so the invention will be first Than the technique [1][2][3][4] the flexural strength apex from 180Mpa, substantial improvement and improvement to the flexural strength apex 240Mpa.

Therefore, the product of the present invention in the application of flat glass is also substantially improved and improved by 1/3 times compared with the inventors of the prior art [1][2][3][4]; The flexural strength of the boron-containing glass is increased by about 3 times, which is about 3 times higher than that of the existing aluminum-containing 12-15% touch screen glass, and about 5 times higher than the calcium-sodium glass bending strength of 50 MPa.

The same strength of the present invention is also 1/3 times lighter than the prior art [1][2][3][4]; it is 3 times lighter than the existing TFT boron-containing glass; compared with the conventional soda lime glass bottle Light and thin 5 times;

a. It can overcome the major defects of the products in the traditional flat glass application that are too heavy and too thick to be easy to use;

b. In the application of the invented product of the flat glass and the terminal of the present invention, the flexural strength is substantially improved and improved, and in a very wide range of flat glass applications, various non-obvious technical effects are expressed in the Summary of the Invention.

(4) Prior Invention 4: The inventor's: 201110060913.9, a high-annealing high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass.

This prior art does not indicate the [softening point property] found by the present invention; nor does it indicate the substantial improvement and improvement of the [difference in the coefficient of thermal expansion of the high temperature region] found in the present invention; nor does it indicate the findings of the present invention [ Substantial improvements and improvements in the flexural strength properties; nor the various unexpected technical effects of the present invention in the use of glazed flat glass.

(5) There is a comparison technology 5:

(6), prior to the comparison of technology 6:

(7) First invention:

U.S. Patent No. 3,929,497 (December 30, 1975) patent.

The patent name is: crystallizable glass for fiber production

(4), the first invention 4:

There are comparative techniques (5).(6).(7), the composition of which differs from the present invention in some other compositions;

The main thing is that if there is a prior art, it can be used as a chemical product close to this new invention; but because the invention discovers the nature of the new product and its original properties are substantial. Improvements and improvements; and the resulting non-obvious technical effects. Therefore, the present invention is substantially inventive.

The present invention pertains to a novel use of a chemical product; an overview of the inventive features and objects of the invention:

In these different fields of use, new properties are discovered, and the technical effects that are produced using these properties are briefly described as follows:

(One)

The invention represents a trend in the development of the technology of the end product of the electronic liquid crystal display glass and the electronic liquid crystal display combination invention with high resolution level.

The present invention has found substantial improvements and improvements - [difference in coefficient of thermal expansion in high temperature regions] (i.e., difference in thermal expansion at high temperatures) and [material properties at high softening points]; thereby utilizing these properties, In the use of electronic glass and combined invention terminal products for liquid crystal display products such as mobile phones, tablets, laptops, desktop computers, and televisions with higher resolution levels, there is an unexpected technical effect of improving the product resolution level.

The nature of these new discoveries and the unpredictable technical effects of using these new properties are also unclear in common sense and cannot be inferred from common sense.

It has not been disclosed by all prior art comparison techniques (including those not disclosed by the prior art [1][2][3][4];

Therefore, it should be judged that the present invention is substantially progressive and inventive.

1. Difficulties in the prior art: the difference in thermal expansion rate of the TFT-LCD substrate glass in the high temperature region of 550 ° C to 630 ° C is generally about 6 parts per million; but the thermal expansion of the soda lime glass high temperature region at 550 ° C to 600 ° C The difference in rate is 20 parts per million; if the 40-inch diagonal TFT-LCD color LCD screen produces an improper shrinkage of 6-20 parts per million, it will change due to its viscosity and elastic characteristics. Large and curved, irregular Shape, and heat shrinkage; there will be problems with certain pixel points on the surface of the TFT-LCD substrate glass and the front color filter film and polarizer, resulting in quality problems with several black spots on the LCD screen.

TFT-LCD liquid crystal glass is very demanding both internal and external performance and inch requirements. TFT-LCD has the same requirements as integrated circuit chip, even more stringent than IC chip. Since the circuit and the semiconductor are formed on the surface of the substrate glass, it is required to have the same or higher precision as the silicon wafer. The smaller the difference in the thermal expansion coefficient of the high temperature region of the substrate glass, the higher the yield and the higher the resolution display product. On the contrary, because the difference in the coefficient of thermal expansion of the high temperature region is greater, the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; some pixel points on the surface of the TFT-LCD substrate glass are generated. The front color filter film and the polarizer produce a problem that is not good, resulting in a quality problem of several black spots on the liquid crystal panel.

However, regardless of the advanced low-temperature polysilicon process, and all TFT-LCD processes, the processing of diodes on the surface of the substrate glass, thin film transistors and the like provide a switching process for each phase, and the final temperature of the heating process is 625 ° C. This poses a very high difficulty for the existing conventional substrate glass, because the difference in thermal expansion rate of the conventional TFT-LCD substrate glass in the high temperature region of 550 ° C to 630 ° C is generally about 6 parts per million for heating. The final temperature of the process is 625 ° C, which provides only a narrow process control range. Only provides technical support for display products that can produce low-level resolution with a resolution of approximately [100-200 ppi - that is, about 100-200 pixels per square inch of thin film transistors);

Moreover, since only a narrow process control range of 550 ° C - 630 ° C is provided, a diode, a thin film transistor, etc. are provided on the surface of the substrate glass to provide a switching process for each phase, so the production efficiency and the yield are not so good.

2. Prior Art Difficulties: The prior art inventors have prior art in 2011. Difficulties in prior art: The prior art has the above difficulties in comparison with the prior art 2, with a little progress, mainly taking the material properties of the high temperature zone from 550 ° C. -630 ° C rose to 600 ° C -650 ° C; and the difference in thermal expansion rate from about 6 parts per million, to 2-3 parts per million range. Therefore, compared with the conventional technology, the newly provided process control range is improved; because the thin film transistor of the conductive layer is sintered above the TFT-LCD liquid crystal glass surface after the rapid heating between 600-650 ° C, the high temperature is provided. The smaller difference in the coefficient of thermal expansion of the region can produce higher definition resolution, and the resolution [about 400-600 ppi - that is, the pixel position of the thin film transistor per square inch is about 400-600] Technical effect of support; but since it can only provide process control range from 600 °C to 650 °C, The substrate glass surface processing diode, thin film transistor, etc. provide a switching process for the 400-600 ppi-phase position, so the production efficiency and the yield are defective.

3. The present invention, because of the difference in the coefficient of thermal expansion in the high temperature region and the material properties of the high softening point, there is substantial improvement and improvement, and new effects in new applications:

Because TFT-LCD liquid crystal glass is very demanding both internal and external performance and inch requirements, TFT-LCD has the same requirements as integrated circuit chip, even more stringent than IC chip. Since the circuit and the semiconductor are formed on the surface of the substrate glass, it is required to have the same or higher precision as the silicon wafer. The smaller the difference property of the thermal expansion coefficient of the high temperature region of the substrate glass is, the smaller the total pitch deviation performance property is, the higher the yield can be, and the higher the resolution display product can be produced.

On the contrary, because the difference in the coefficient of thermal expansion of the high temperature region is greater, the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; some pixel points on the surface of the TFT-LCD substrate glass are generated. The front color filter film and the polarizer produce a problem that is not good, resulting in a quality problem of several black spots on the liquid crystal panel.

In the use of electronic glass, since it is a preferred non-alkali product of the TFT in the present technology, the difference in thermal expansion coefficient of the high temperature region, that is, the difference in thermal expansion rate in the more severe high temperature region of 650 ° C to 700 ° C is Within 0.1-0.99 parts per million, the difference in thermal expansion rate between 700 °C and 740 °C is within 1-5.9 parts per million, which has higher performance than all prior art comparison techniques;

[1] An advancement in the range of process control newly provided by the present invention: since a thin film transistor of a conductive layer is sintered onto a TFT-LCD liquid crystal glass surface by a rapid heating between 650-700 ° C or 700-740 ° C At the time, a smaller difference property is provided which provides a coefficient of thermal expansion in a higher temperature zone, the prior art is about 6 parts per million; the total pitch deviation performance of the present invention is 0.1-0.9 parts per million; compared with the prior art The difference in thermal expansion is several times smaller (ie, the total pitch deviation performance is stable); therefore, it is possible to produce high definition, resolution [about 800-1600 ppi--that is, the pixel position of the thin film transistor per square inch is about 800-1600]. The technical support of the product, non-obvious high definition, high resolution, produces non-obvious technical effects.

[2] The present invention can have excellent total pitch deviation performance (i.e., thermal expansion difference performance at high temperature) under severe temperature conditions of 650-700 ° C and 700-740 ° C, and the prior art is in parts per million. 6 or so; the total pitch deviation performance of the present invention is 0.1-0.9 parts per million; several times smaller than the difference of the prior art thermal expansion (ie, The total pitch deviation performance is stable); therefore, the control range of the process is increased; the production rhythm can be accelerated, the production capacity of the panel can be improved, and the non-obvious technical effect is obtained with a higher yield.

Therefore, it provides the fundamental technical support and electronic liquid crystal display glass technology representing high resolution level for the use of electronic glass and combined invention terminal products of liquid crystal display products such as mobile phones, tablet computers, desktop computers and televisions with higher resolution levels. development trend.

The invention has the technical effect that the material property of the crystallization rate is slow, which is not obvious: the upper line range of the crystallization temperature zone of the invention is under the condition of natural cooling in the designated instrument, and the analysis starts after 45 minutes - 1 hour and 5 hours. Crystal, which has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, which are much more important than the prior art. In order to accurately control the large production. Thus, the high-quality electronic liquid crystal display glass plate glass of the present invention without any crystallization due to the influence of crystallization is produced; and a non-obvious technical effect is produced.

(two)

The invention represents the technical development trend of the thin and light, high-strength, high-wear-resistant electronic liquid crystal display glass and the combined invention terminal product.

The present invention has found substantial improvements and enhancements in the properties of the flexural strength material; thereby utilizing these properties, in touch screen electronic glass and TFT electronic glass, and mobile phones, tablet computers, laptop computers, desktop computers, televisions, etc., liquid crystal In the use of the combined invention terminal product shown, the substantial improvement and the technical effect of the light weight, high strength and high wear resistance are not improved.

As a result of the present invention, the prior art, [1] [2] [3] [4] flexural strength apex is improved from 180 Mpa, and substantially improved to a flexural strength apex of 240 MPa.

Therefore, the product of the present invention in the application of flat glass is also substantially improved and improved by 1/3 times compared with the inventors of the prior art [1][2][3][4]; Boron-containing glass bending strength 80 Mpa is increased by about 3 times; it is about 2.4 times higher than the existing 12-15% aluminum touch screen glass flexural strength 100Mpa; it is about 2.4 times higher than the existing aluminum-containing 12-15% touch screen glass bending strength 100Mpa. ;

The invention is also lighter and thinner than the prior art [1][2][3][4] at the same intensity; it is 3 times lighter than the existing TFT boron-containing glass; lighter than the existing touch screen glass 2.4 times;

In touch screen electronic glass and TFT electronic glass, and mobile phone, tablet computer, laptop computer, desktop computer, TV, etc., the combination of liquid crystal display and invention terminal products, substantial improvement and improvement of lightness, high strength and high resistance Grinding technology effect.

(three)

The invention is a new process of roll-to-roll liquid crystal display in a difficult development period, solving the fundamental problem:

The present invention has found substantial improvement and improvement of [difference in coefficient of thermal expansion coefficient in high temperature region] and material properties of [high softening point] and [reduction strength]; thereby utilizing these properties, it is difficult to develop during development The difficulty of the new process of roll-to-roll liquid crystal display can be overcome, and the production process of the panel roll-to-roll which can make the panel production mode change and the high efficiency, cost reduction, lightness and thinness and high branching rate are produced. It can enter the large production stage of high finished product qualification rate, and there are unexpected technical effects.

The production process of the existing TFT-LCD liquid crystal display panel roll-to-roll is in a difficult development period.

To achieve a critical heating process in the harsher high temperature region, when the thin film transistor of the conductive layer is sintered onto the thin glass-to-roll glass surface of the TFT-LCD 0.1-0.2 mm, the major problem to be solved is :

a. The existing liquid crystal glass material can not withstand the severe high temperature properties. After the thin film transistor of the conductive layer is sintered onto the thin liquid crystal glass surface of the TFT-LCD 0.1-0.2mm, it will be due to the long distance winding pair. The strong tension of the roll retracting process is modified. After the roll-to-roll winding is completed, when the lower process is unwound to cut the flat product, the thin film transistor of the conductive layer has been sintered to the liquid crystal glass of the TFT-LCD, which is also unqualified due to the planar deformation, and cannot enter the liquid crystal panel production of the next process. Major problem

b. Sintering a thin film transistor of a conductive layer in a roll-to-roll long-distance roll-to-roll process It is on the thin LCD glass surface of 0.1-0.2mm of TFT-LCD; however, it is difficult to achieve the technical quality of the display product of about 200 resolutions per square inch of the thin film transistor, which is a major problem;

c requires a very thin 0.1-0.2mm roll-to-roll after the roll-to-roll process, the thin film transistor of the conductive layer has been sintered to a thin liquid crystal glass of 0.1-0.2mm TFT-LCD Above the surface of the liquid crystal glass; [1] or because of the large difference in expansion and contraction in the coil (the prior art is about 6 parts per million), so the severe sintering temperature is close to the conversion point temperature of the prior art glass. The viscosity is generated, and the elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage. [2] Or because the softening point of the glass is low, it becomes soft when heated, and it is deformed by the strong tension in the roll-to-roll retracting process. [3] Or the part of the variant is fractured due to the difference in strength of the glass.

Therefore, after the liquid crystal glass roll is wound up, the thin glass of 0.1-0.2 mm in the roll which is generated by the winding in the roll is tight, and the deformation is not smooth and under the normal pressure of winding. Partial fracturing of the variant. Therefore, there is a major problem in the formation of a normal production process.

However, the present invention has substantial improvement and improvement in material properties of [difference in coefficient of thermal expansion in high temperature region] and [high softening point] and [strength], and in the roll-to-roll application, it is possible to overcome the above three items. Difficult new technology effects:

this invention:

[1] For the roll-to-roll process production, the thin roll of 0.1-0.2mm after the roll-to-roll is wound has been

The thin film transistor of the conductive layer is sintered to the liquid crystal glass above the very thin liquid crystal glass surface of the TFT-LCD 0.1-0.2 mm, and the present invention can overcome or have a large difference due to expansion and contraction in the coil (the prior art is 6 parts per million) The total pitch deviation performance of the present invention is 0.1-0.9 parts per million); the present invention does not cause viscosity due to the severe sintering temperature, which is close to the conversion point temperature of the prior art glass, and the elastic characteristics vary greatly. Bending, irregular deformation, and heat shrinkage; can overcome the major problem of the production of liquid crystal panels that cannot pass the material into the next process.

[2] and there is a much higher than the first comparative technology, up to 800-860 ° C softening point properties (and first

The technical heating temperature is only 630 ° C, the invention is that the rising heating temperature is 650-700-740 ° C, and is also much lower than the softening point of 800-860 ° C; therefore, it is not because of the strong tension of the long-distance roll-to-roll retracting process. The modification or the low softening point of the glass is softened when heated, and is changed by the strong tension in the roll-to-roll retracting process; and the major problem of the liquid crystal panel of the transmitted material can be overcome.

[3] Substantial improvement and improvement due to the material properties of the [flexural strength] of glass: more than traditional

For the strength of only 100 mpa of the trial-produced TFT glass, the inventors' prior art [2] has a strength of up to 180 mpa; and the present invention can reach a strength of 240 mpa; therefore, the present invention can overcome the winding in the roll. A very thin glass of 0.1-0.2 mm in a tightly produced roll, which is not flattened due to the deformation, is a major problem of fracturing the deformed portion under normal pressure of winding.

Therefore, it is possible to overcome the above problems in the roll-to-roll process in the development stage:

a. The invention can be overcome: when there is a roll-to-roll winding, when the lower process is unwinding into a flat product, the thin film transistor which has been sintered to the TFT-LCD liquid crystal glass is also unqualified due to the planar deformation, and cannot A major problem in the production of liquid crystal panels entering the next process; producing non-obvious technical effects.

b. The invention can be overcome: after the liquid crystal glass roll is wound up, the thin glass of 0.1-0.2 mm in the roll which is generated due to the tight winding in the roll, is not flattened due to the deformation. Under normal pressure, the deformed part is fractured, so there is a major problem that cannot be formed in a normal production process; a non-obvious technical effect is produced.

The present invention overcomes the above-mentioned problems in the roll-to-roll process at the development stage:

c. Sintering a thin film transistor of a conductive layer in a roll-to-roll long-winding roll-to-roll process

It is on the thin LCD glass surface of 0.1-0.2mm of TFT-LCD; however, it is difficult to achieve the technical quality of the display product of about 200 resolutions per square inch of the thin film transistor, which is a major problem;

In the roll-to-roll process, the thin film transistor of the conductive layer must be sintered to the liquid crystal glass of the TFT-LCD by means of a heating process, but the temperature of this process of the prior art is 600-630 ° C, which is according to the prior art. The total pitch deviation performance of the liquid crystal glass of the TFT-LCD (ie, the difference in thermal expansion at high temperature) is determined by 550-630 ° C;

On the contrary, because the difference in the coefficient of thermal expansion of the high temperature region is greater, the viscosity and elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage; some images on the surface of the TFT-LCD substrate glass are generated. The prime point and the front color filter film and the polarizer produce a problem that does not occur, resulting in a quality problem of several black spots on the liquid crystal panel.

Because the temperature of the process, such as 髙 630 ° C, will exceed the total pitch deviation performance of the prior art liquid crystal glass (that is, the difference in thermal expansion at a high temperature of 630 ° C is about 6 parts per million), resulting in high temperature The total pitch deviation performance of the liquid crystal glass with thermal expansion coefficient [the coefficient of thermal expansion coefficient is not up to standard], the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; TFT-LCD substrate glass is produced. Some of the pixels on the surface are inconsistent with the front color filter film and the polarizer, resulting in quality problems with several black spots on the LCD screen.

The present invention, because of the difference in thermal expansion coefficient of the high temperature region, the material properties of the liquid crystal glass material: the present invention can be more 650-700 ° C and at a temperature of 550-630 ° C or 600-650 ° C than the conventional technology. Working at 700-740 ° C under severe temperature conditions; the present invention can overcome or have a large difference in expansion shrinkage due to expansion in the coil (the prior art is about 6 parts per million; the total pitch deviation performance of the present invention is in parts per million) 0.1-0.9) has a better total pitch deviation performance than the prior art thermal expansion difference (that is, the total pitch deviation performance is stable); therefore, the present invention is not close to the prior art due to the severe sintering temperature. The transformation point temperature of the glass produces viscosity, and the elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage; therefore, the invention not only has a wider control range but also has the property of being able to withstand certain severe high temperatures. In the roll-to-roll long-winding roll-to-roll process, the thin film transistor of the conductive layer is sintered onto the thin liquid crystal glass surface of 0.1-0.2mm of TFT-LCD, which can achieve the flatness of the thin film transistor. The square inch pixel position is about 200 resolutions. The technical quality of the product is designed to achieve a more ambiguous level of pixel quality per square inch of 800-1600 resolution. The invention overcomes major problems; it produces non-obvious technical effects.

The main non-obvious technical effects produced by the present invention are:

The invention can make the production process of the TFT-LCD display panel roll-to-roll in the difficult development period overcome the major problems and carry out the large production stage; the invention can make the panel production mode change, generate high efficiency and reduce cost. The new panel production method with light weight and high distribution rate represents the technical development trend of the invention of high-level electronic liquid crystal display glass and liquid crystal display combined terminal products.

(four)

The invention can be a new technology of low temperature polysilicon liquid crystal display technology and solve major problems:

The present invention finds substantial improvement and improvement of [difference in thermal expansion coefficient in high temperature region] and material properties of [high softening point] and [reduction strength]; thereby utilizing these properties, it can be a low temperature polycrystalline silicon liquid crystal display technology The new technology solves the problem that the total pitch deviation performance of the liquid crystal glass of the TFT-LCD is poor, the flat glass is deformed after the laser irradiation, the yield is not high, and the resolution of the liquid crystal display technology is not bad, and there is an unexpected technology. effect.

a. Low-temperature polysilicon technology new process problem 1:

In the new process of low-temperature polysilicon technology, it is necessary to use a laser irradiation process to transform the amorphous silicon structure on the glass substrate into a polysilicon structure. However, the temperature of this process of the prior art is 600-630 ° C, which is determined according to the total pitch deviation performance of the liquid crystal glass of the TFT-LCD of the prior art (ie, the thermal expansion difference performance at high temperature) of 550-630 ° C. ;

However, in the laser irradiation process which is necessary to convert the amorphous silicon structure on the glass substrate into the polycrystalline silicon structure, the temperature of 630 ° C does not convert the amorphous silicon structure on the glass substrate into a polycrystalline silicon structure, or is generated. After uniform laser irradiation, the effect of the conversion of the amorphous silicon structure into the polysilicon structure cannot be formed due to insufficient thermal energy. Low yield is the main problem.

b. Low-temperature polysilicon technology new process problem 2:

In the new process of low-temperature polysilicon technology, in the laser irradiation process necessary to convert the amorphous silicon structure on the glass substrate into a polycrystalline silicon structure, the softening of the liquid crystal glass of the prior art TFT-LCD The low point, a large number of problems with flat glass modification after laser irradiation, is another major problem of low yield.

c. Low-temperature polysilicon technology new process problem 3:

In the new process of low-temperature polysilicon technology, the thin film transistor of the conductive layer is sintered to the liquid crystal glass.

Above the surface, the total pitch deviation performance (that is, the thermal expansion difference performance at high temperature) due to the conventional technology at a high temperature of 550-630 ° C is only about 6 parts per million, and can only reach the pixel position per square inch of the thin film transistor. The technical quality of the product of about 200 resolutions is a major problem;

However, the present invention has substantial improvement and improvement due to the difference in the coefficient of thermal expansion of the high temperature region and the material properties of the high softening point. In the use of the low temperature polysilicon technology, a new technical effect capable of overcoming the above three difficulties is produced:

a. The present invention, because of the difference in thermal expansion coefficient between the high temperature region and the material properties of the high softening point of the liquid crystal glass

Glass material: [1] The invention can work under the conditions of 550-630 ° C or 600-650 ° C of the conventional technology, and has a more severe 650-700 ° C and 700-740 ° C harsh temperature process conditions, and Better overall pitch deviation performance (ie, thermal expansion difference performance at high temperatures), several times smaller than the prior art thermal expansion difference (ie, total pitch deviation performance is stable); [2] and there is a comparison technique Very much 750-860 ° C softening point properties;

Therefore, in the new process of low-temperature polysilicon technology, it is necessary to use a laser irradiation process to convert the amorphous silicon structure on the glass substrate into a polysilicon structure, but the temperature of the prior art process is 600-630. °C, rise to 700-740 ° C, can be determined according to the total pitch deviation performance of the liquid crystal glass of the TFT-LCD according to the present technology (ie, thermal expansion difference performance at high temperature) 700-740 ° C;

Since the temperature of the process is 700-740 ° C, it does not exceed the total pitch deviation performance of the liquid crystal glass of the present invention (that is, the difference in thermal expansion at a high temperature of 700-740 ° C is 1-5.9 parts per million), The total pitch deviation performance of the liquid crystal glass due to the thermal expansion coefficient of the high temperature zone [the coefficient of thermal expansion coefficient difference is not required], and the viscosity and elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage; Certain pixel points on the surface of the TFT-LCD substrate glass are incompatible with the front color filter film and the polarizer, resulting in quality problems of appearing black spots on the liquid crystal panel;

Therefore, in the laser irradiation process which is necessary to convert the amorphous silicon structure on the glass substrate into the polycrystalline silicon structure, the temperature of 700-740 ° C can change the amorphous silicon structure on the glass substrate into the polysilicon junction. After the uniform distribution of the laser light is irradiated, the thermal energy is greatly increased to form a good yield effect of converting the amorphous silicon structure into the polycrystalline silicon structure. Overcoming the main problems; the discovered material properties of the present invention have produced a non-obvious technical effect that greatly increases the yield of low temperature polysilicon technology. It represents the high-level electronic liquid crystal display glass and low-temperature polysilicon technology, and the liquid crystal display combination invention technology development trend of the terminal products.

b. Because the softening point of the liquid crystal glass of the TFT-LCD of the present invention has a softening point property of 750-860 ° C which is much higher than that of the prior art, so in the new process of low-temperature polysilicon technology, it is necessary to make the glass In the laser irradiation process in which the amorphous silicon structure on the substrate is converted into the polycrystalline silicon structure, the plate glass of the present invention does not have a problem of deformation after being irradiated by the laser at a temperature of 700-740 ° C under severe temperature, and the yield can be greatly increased. Can overcome another new low-temperature polysilicon technology process problem 2, resulting in non-obvious technical effects.

c. The present invention, because of the difference in thermal expansion coefficient of the high temperature region, the material properties of the liquid crystal glass material: the present invention can be more 650-700 ° C and 700-740 at a temperature of 550-630 ° C than the conventional technology. °C work under severe temperature conditions, and has better overall pitch deviation performance (ie, differential thermal expansion performance at high temperatures), which is several times smaller than the difference in thermal expansion of the prior art (ie, the total pitch deviation performance is stable) Therefore, the invention not only has a larger control range of the process, but also has the requirement of being able to withstand a certain severe high temperature, and the thin film transistor of the conductive layer is sintered on the thin liquid crystal glass surface of the TFT-LCD 0.1-0.4 mm. And can achieve the technical quality of the thin film transistor with a resolution of about 200 resolutions per square inch of the pixel product, and achieve a more advanced level of pixel resolution of 800-1600 resolution per square inch of the product For technical quality purposes, the present invention can overcome the new process problem of low temperature polysilicon technology 3; and produce a non-obvious technical effect of the lower resolution of low temperature polysilicon technology. It represents a high-level electronic liquid crystal display glass and liquid crystal display combination invention technology product development trend.

The discovered material properties of the present invention and the resulting 髙 resolution technical effects,

(4) According to the present invention, the first comparative technique [1][2][3][4] has a flexural strength apex from 180 MPa, substantial improvement and improvement to a flexural strength apex of 240 MPa; compared with the prior art [1] ][2][3][4] The flexural strength is substantially improved and improved by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; 12-15% than the existing aluminum containing aluminum The touch screen glass has a flexural strength of 100 Mpa which is increased by about 2.4 times; it is about 5 times higher than that of the calcium sodium glass.

Therefore, it can provide a higher strength product for the electronic glass product, or provide a light and thin 5 times, or a light and thin 2.5 times, or a light and thin 1/4 when the strength is the same;

Therefore, it can provide higher strength or lighter and thinner effects for the use of a liquid crystal display combination of a mobile phone, a tablet computer, a laptop computer, a desktop computer, a television, and the like;

The technical effect of the present invention represents a technical development trend of a high level of electronic liquid crystal display glass and liquid crystal display combined invention terminal products.

(Wu)

Improve the high temperature fireproof and explosion-proof performance of flat glass materials and end products.

The present invention has found substantial improvement and improvement of the [difference in the coefficient of thermal expansion of the high temperature zone] and the material properties of the [high softening point]; thereby utilizing these properties, it is possible to improve the resistance of the flat glass material and the end product application. High temperature fireproof, explosion-proof performance, there are unexpected technical effects.

The present invention, because of the difference in thermal expansion coefficient of the high temperature region and the material properties of the high softening point:

a. Because of the difference in thermal expansion coefficient between the high temperature zone and the material properties of the high softening point of 750-860 ° C, there is substantial improvement and improvement: the difference in thermal expansion rate in the more severe high temperature zone 650 ° C -700 ° C is in the millions Within 0.1-0.99, the difference in thermal expansion rate in the more severe high temperature range of 700 ° C - 740 ° C is within 1-5.9 or 6-8 parts per million. Its non-obvious new technology effects are:

The invention has been greatly improved as 1. glass for construction; 2. glass for automobile; 3. glass for ship; 4. glass for railway car; 5 aircraft glass; 6. glass for fireproofing and explosion-proof; High temperature resistant fireproof and explosion proof performance;

And various combinations of invention terminal products such as: 1. high-performance glazed glass furniture, 2. high-performance automotive, 3. high-performance solar aircraft, 4. high-performance solar power generation equipment, and other combined invention end products for high temperature and fire resistance applications Explosion-proof performance.

b. The present invention has a material having a slow crystallization rate: a non-obvious technical effect [1]: the upper line range of the crystallization temperature zone of the present invention and under the condition of natural cooling in a specified instrument, at 45 minutes -1, After 5 hours, the crystallization will start under the condition of the upper line of the glass crystallization temperature zone and gradually lowering the temperature, and the crystallization rate is slow; this can be especially in the cooling part and the forming part, especially the float process and various The flat glass process creates extremely important and precise process control parameters that are much better than the prior art, so that precise production can be controlled with precision and confidence. Thus, the high-quality flat glass of the above seven uses of the present invention, which does not have any crystallinity and which affects the light transmittance, is produced, and provides acceptable product support for the application of the above-mentioned four types of combined invention terminal products.

(six)

The present invention has been found to have substantial improvements and improved [softening point] properties - "softening point up to 750-860 ° C", and [difference in the coefficient of thermal expansion of the high temperature zone] - "in the more severe The difference in thermal expansion between 650 ° C and 700 ° C in the high temperature range is within 0.1-0.99 parts per million, and the difference in thermal expansion rate in the more severe high temperature range of 700 ° C to 740 ° C is 1-5.9 or 6 parts per million. Within -8";

By utilizing the properties of this material, unexpected use of technical effects has been produced in the use of various glazed flat glass applications and in the use of various combinations of invented end products. Such as:

(1) A combination of high-performance color glazed flat glass in the application of the invention; a combination of high-performance wear-resistant glaze flat glass for the application of the invention; a high-performance ultra-thin wall veneer Combination of glazed plate glass for the application of the invention; a combination of a high performance glazed glass plate combination cabinet for the application of the invention; a combination of a high performance sliding door cabinet glazed glass panel furniture; A combination of high-performance color glazed glass panel combination wardrobes for the application of the invention; a combination of high-performance glazed countertop glass furniture for the application of the invention; a combination of a high-performance glazed flat glass and a metal layer composite panel In the use of the invention; a high-performance, color-friendly structure with a simple structure installed on the wall A combination of glazed glass composite panels for use in applications; a high performance, easy to assemble and disassemble, glazed glass composite flooring combination application; a high performance produced by a thermal deformation process Combination of a glazed glass wash basin for the application of the invention; a combination of a high performance glazed glass lifting panel produced by a thermal modification process and a combined wash basin; the use of the invention for a bathroom The combination of high-performance glazed glass washbasin countertops is used in the application of the invention; because of the substantial improvement and improvement of the [softening point property] of the product, and the improvement and improvement of the [difference in the coefficient of thermal expansion of the high temperature zone].

Therefore, there is an unexpected technical effect: in the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of fire or high temperature, in the high temperature zone state. According to the [higher softening point] of the flat glass of the present invention, [better thermal expansion difference in high temperature region], [high performance such as higher strength], the shape of the glass can be maintained, and fireproofing and separation can be achieved. The non-obvious technical effect of fire and heat insulation wave; the invention has special fireproof and explosion-proof effect of building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has non-obvious technical effects.

(2) In the use of glazed flat glass, it can overcome the decorative layer of colored glaze and the difficulty in sintering in flat glass:

A. That is, the lower the softening point of the flat glass, the lower the thermal stability of the glass, the easier it is to sinter the colored glaze layer in the process stage of the flat glass, and the flat glass is deformed, which will cause deformation or crack or crack. Quality defect

B. Since the softening point of the flat glass is lower, the more difficult it is to provide the colored glaze raw material below the lower modification temperature, the more costly it is.

C. Since the softening point of the flat glass is lower, in order to provide the colored glaze raw material below the deformation temperature, it is difficult to emit good quality red, blue, green, yellow and the like, and the lower the temperature of the colored glaze raw material is. The higher the cost.

The softening point of the existing soda-lime plate glass is only 525 ° C; the material properties of the soft glass having a softening point of up to 720 ° C have only been found in the prior invention of the flat glass in the comparative document. However, the present invention has found a material having a softening point of 750-860 ° C, so that in all the use of glazed flat glass, it can produce unexpected materials:

1) The invention can make the color glaze flat glass without quality defects of cracking or cracking, and has unexpected technical effects;

2) The invention can overcome the glaze raw materials, because the temperature is low and the cost is more difficult, and there is a technical effect that the production cost is not expected;

3) The invention can overcome the raw materials of the colored glaze, because the lower the temperature, the more difficult it is to emit the color of red, blue, green, yellow, etc., and the lower the temperature of the raw material of the colored glaze, the higher the cost of color development. Difficulties; the unexpected technical effects of red, blue, green, yellow and other colors that produce better quality, and the unexpected technical effects of reducing the cost of glaze raw materials.

Prior Invention 4 which is closer to the present invention: Comparative Document The present inventor: 201110060913.9, a low-melting-point glaze decorative flat glass with high annealing temperature and high strength and environmental protection and energy saving type. This prior art does not indicate a substantial improvement and improvement of the [high softening point property] found by the present invention; nor does it indicate a substantial improvement and improvement of the [difference in the coefficient of thermal expansion of the high temperature region] found by the present invention; Substantial improvements and improvements in the [fracture strength properties] found by the present invention are not indicated;

It also does not reveal the new properties of the present invention using [high softening point properties], [difference in thermal expansion coefficient in high temperature regions], and in the use of glazed flat glass applications and in the use of more than 10 combined invention applications, Unprecedented technical effects.

Moreover, the use of the chemical product is invented in various new applications of colored glazed flat glass, and in the application of various combinations of invented end products, using the discovered substantial improvements and improved softening point new properties, resulting in the preparation The technical effects that are not available are also unclear in common sense and cannot be inferred from common sense.

The nature of these new discoveries and the unpredictable technical effects of using these new properties have not been disclosed by all prior art techniques (including those that have not been preceded by comparative techniques [1][2][3][ 4][4] has been published);

(Seven)

Improvements and improvements in the flexural strength and thinning properties of flat glass materials and end products.

The present invention has been found to have substantial improvements and improved [fracture strength] material properties; thereby utilizing these properties, it is possible to improve the lightness and thinness properties of flat glass materials and end products applications, and there are unexpected technologies. effect.

The above-mentioned abc technical effects of the present invention represent a high level, thereby greatly improving the invention for use as architectural glass; automotive glass; marine glass; railway car glass; aircraft glass; fireproof, explosion-proof glass; The technical development trend of products such as photovoltaic solar glass; glazed glass decorative panels for wall and floor applications.

Representing high-tech, such as high-performance glazed glass furniture, high-performance cars, high-performance solar aircraft, high-performance solar power plants, and other applications, the technical development trend of the combined invention of end products.

(Eight)

The present invention discloses new material properties that reduce the crystallization rate of glass in production.

The present invention has discovered a new material property with substantial improvements and improved [glass crystallization rate]; thus utilizing these properties, a non-obvious unique technical effect is produced: especially prior comparison The technology [1][2][3][4] can overcome the defects caused by the crystallization of the unique technical weakness of the product of the invention, and can carry out a better level of process quality control and improve production. Feasibility and product quality rate.

(Not by the prior art, even the test purpose characteristics and test equipment and test methods of the new material properties of the glass crystallization rate are also the crystallization of the technical weaknesses unique to the large-scale production according to the type of the invention. The resulting defects, while original and original):

Because the product of the present invention has the characteristic that the upper line [highest point] of the crystallization temperature is higher than the molding temperature, in order to study the selective use of glass having a relatively slow crystallization rate in large production, it is advantageous for cooling before molding. The working temperature of the glass liquid cooling process in the working part reduces the risk of crystallization; because it is required to cool the temperature of the glass in the working part, the process must be controlled by the crystallization temperature, especially in the liquid line edge of the cooling working part. Corners and bottoms are easy to devitrify some heating control devices; but in the corners of the cooling work and the bottom of the glass, there will be some slower flow in the glass crystallization temperature range, the gradual cooling conditions Next, (if there is a comparative technique [1] [2] [3] [4]), the glass liquid will be partially devitrified within 10 to 31 minutes, and there will be a partial devitrification of the flat glass in the molding stage. The risk of substandard products;

Therefore, the material properties of the present invention should be selectively used in large-scale production: [the upper-line range of the inner glass crystallization temperature zone after the glass liquid having a relatively slow crystallization rate is 45-60 minutes or 60-150 minutes, and the condition of gradually lowering the temperature Underneath, there is no crystallization of the glass material, which is 5 times slower than the prior art prior art [1][2][3][4], thus overcoming the forming stage to make the flat glass appear locally. The risk of devitrified substandard products.

(nine)

The inventiveness of the invention in the new use of flat glass:

In the new application of the flat glass, the invention finds: (1) the difference of the thermal expansion coefficient in the high temperature zone and (2) the softening point of the crucible, (3) the more flexural strength property; (4) in the flat glass In new applications, new glass products [low crystallization rate] material properties were found; these (1).(2).(3).(4) properties, substantial improvements and improvements, and the use of these (1). (2). (3). (4) The nature of the class has produced unexpected technical effects.

However, in the new use of the above-mentioned invention in the flat glass, the new properties of the parts (1), (2), (3) (4) found, cannot be used in 'chemical products, whether new products or known products, The performance is a reference to the principle of the product itself, and it is concluded that the [new properties discovered by the present invention] are easily identifiable by those skilled in the art and can be inferred; The substance of progress and creativity.

Because the use of this chemical product is invented in the new use of flat glass, the properties and effects of (1).(2).(3).(4) found are substantially improved compared with various prior art. improve. It is not clear in common knowledge, and it cannot be inferred from common sense.

Moreover, the use of the chemical product in the new use of flat glass, the use of these new properties, the resulting unpredictable technical effects, is also not clear in the common sense and can not be derived from common sense. The nature of these new discoveries and the unpredictable technical effects of using these new properties have not been disclosed by all prior art techniques (including those that have not been preceded by comparative techniques [1][2][3][ 4] published);

The technical solution of claim 1 of the present invention, in the new use of flat glass, known properties (1). (2). (3) have substantial improvements and improvements; also found glass products (4) [low crystallization The new material properties of speed], and the use of these properties, produce unexpected technical effects; therefore, it should be judged that the technical solution of claim 1 of the present invention, and the technical solution of the dependent claims of the present invention, in the new flat glass Among the uses, there is substantial progress and creativity.

Moreover, as long as the properties of the (1).(2).(3).(4) of the present invention are substantially improved and improved as long as one of them is of a nature, and one of these new properties is utilized, Any of the specifications relates to unexpected technical effects of improving product performance, or yield quality, or increasing throughput; it is to be judged that the present invention is substantially progressive and inventive.

If it is found that there are other prior art comparison techniques, it can be used as a know-how chemical product close to the invention of this new use; but due to the invention of new uses of this chemical product, the newly discovered various product properties and various new discoveries The various unpredictable technical effects produced by the nature of the product illustrate the invention of the application of the chemical product, which is non-obvious, with outstanding substantive features and significant technological advancement and creativity.

The above description is only for the purpose of illustrating the preferred embodiments of the present invention, but it is not intended to limit the invention, and any person skilled in the art may change or modify the equivalents of the above-disclosed technical contents. In the embodiment, the high softening point, the low difference of the thermal expansion coefficient of the high temperature zone, the low crystallization rate, and the application of the fireproof and explosion-proof flat glass can be implemented according to different requirements and performances. It can be seen that any simple modifications, equivalent changes and modifications made to the above embodiments in accordance with the technical spirit of the present invention are still within the scope of the technical solutions of the present invention without departing from the technical scope of the present invention. .

Claims

A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of a fireproof and explosion-proof flat glass, characterized in that the alumina content is 0.01% - 39% by weight, magnesium oxide The content is 7%-20%, the silicon oxide content is 2.51-4.8 times of the calcium oxide content, the calcium oxide content is 1.0-1, 8 times of the magnesium oxide content, and the thickness difference of the flat glass within the thickness of 20 mm is 0.01 mm-0.4. Mm.
A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 0.01% - 39% by weight, sodium oxide The content is 0.001%-18%, the magnesium oxide content is 7%-20%, the silica content is 2.51-4.8 times of the calcium oxide content, the calcium oxide content is 1.0-1, 8 times of the magnesium oxide content, and the thickness is 20 mm. The thickness of the flat glass is within the range of 0.01 mm to 0.4 mm.
The invention relates to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the softening point is 750 ° C - 860 ° C; The folding strength is 60-240Mpa.
A flat glass according to claim 1, wherein the low temperature expansion rate in the high temperature region is characterized by: in the high temperature region 550 ° C - 600 ° C, the difference in thermal expansion rate is within 1.2 parts per million, In the high temperature range of 600 ° C to 650 ° C, the difference in thermal expansion rate is within 0.1-0.99 parts per million, and in the high temperature range 650 ° C - 700 ° C, the difference in thermal expansion rate is within 0.1-0.99 parts per million.
A flat glass according to claim 1, wherein the difference in thermal expansion rate is in the range of 1-5.9 or 6-8 parts per million in the high temperature region of 700 ° C to 740 ° C.
The invention relates to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass according to claim 1, characterized in that the alumina content is 4% by weight. --8% or 8.1-12% or 12.1-23% or 23.1-32% or 32.1-39%,
The method for preparing and preparing a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass according to any one of claims 1-6, characterized in that:

Step 1. The various predetermined components required for the glass formulation configuration according to any one of claims 1-6, and predetermined components of a specific ratio between silicon oxide, calcium oxide and magnesium oxide. The raw materials, after mixing and stirring, are melted at a melting temperature corresponding to each glass formulation to form a glass liquid of a predetermined viscosity, and then homogenized, clarified, and discharged to form a flowable melt;

In step 2, the glass is formed by a float process, a flat pull process, a lattice process, a calendering process, an overflow process, or any one of the processes.
The method for preparing and preparing a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, a fireproof and explosion proof flat glass according to claim 7, wherein:

The step 1 includes:

The various raw materials prepared are placed in the respective raw material containers, and the various raw materials are passed through the raw material conveying line, and after being metered, they are fed into the raw material mixing and stirring device at a desired ratio, and after mixing and mixing, the raw materials are loaded. In the magazine or silo;

Putting the matched raw materials into the molten pool, melting at a melting temperature corresponding to each glass formulation, forming a molten glass of a predetermined viscosity, homogenizing, clarifying, discharging bubbles, and forming a flowable melt;

The float process is used in step 2: in the process, the tin kiln must be prepared in advance, and after the step of step 1, the flowable melt at the tail of the molten pool is poured into the tin kiln for flattening, polishing, and thinning. The process, and the pulling of the puller in the direction specified by the process and the traction of the tractor, pull out the tin bath, and after annealing in the upper line range of the glass crystallization temperature zone, gradually cool down, to be cooled Thereafter, the glass is obtained by cutting.
A high-performance color glazed flat glass, characterized in that the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, the substrate thereof The surface of the glass has a glaze layer of 1-10 colors.
A high-performance wear-resistant color glaze flat plate glass, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass The surface of the substrate glass has a glaze layer of 1-10 colors, and the glaze layer of the surface layer contains 15-70% quartz crystal or alumina crystal.
A high-performance ultra-thin wall-faced glazed flat glass, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof For the application of flat glass, the surface of the substrate glass has a glaze layer of 1-10 colors, and the thickness thereof is 0.5-1.5 mm.
The utility model relates to a high performance marine glazing structure, characterized in that the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass. A resin frame or a metal frame support device is mounted on the periphery of the four sides.
A high performance aircraft glazing structure, characterized in that: the window glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass. A resin frame or a metal frame support device is mounted on the periphery of the four sides.
A high-performance glazing structure for an automobile, characterized in that: the automobile glazing is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass The application has a resin frame or a metal frame support device mounted on the periphery thereof.
A high-performance building glazing structure, characterized in that: the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass A resin frame or a metal frame support device is mounted on the periphery of the four sides.
A high-performance insulating glass characterized in that: the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass; A support device is attached to the periphery; there is a 3-50 mm vacuumed isolation space between the layers of glass.
A high-performance building glass curtain wall, characterized in that: the glass curtain wall is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass. It is fixed to the upper metal support device.
A high-performance super-large area thin glass window or glass curtain wall, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass Application; the thickness of the glass is 4-10mm, the size of the glass is 3-40 square meters, or the thickness of the glass is 10.1-20mm, and the size of the glass is 15.1-80 square meters;
A high-performance tempered glass characterized in that the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass, chemically tempered or Made of physical tempering.
A high-performance glass, or tempered glass, or a glass-top furniture of laminated glass, characterized in that the glass table top is a low difference and a low coefficient of thermal expansion coefficient of a high softening point and a high temperature zone according to claim 1. The crystallization rate, fireproof and explosion-proof flat glass are made, and the lower part of the table has support means.

A high-performance glass, or tempered glass, or a glass-top furniture of laminated glass, characterized in that the glass table top is a low difference and a low coefficient of thermal expansion coefficient of a high softening point and a high temperature zone according to claim 1. The crystallization rate, fireproof and explosion-proof flat glass are made, and the lower part of the table has support means.
A high-performance laminated glass, characterized in that the glass thereof is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, the layers thereof There is a layer of resin material between the glass.
The utility model relates to a high performance bulletproof and explosion-proof glass, which comprises: bulletproof explosion-proof glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, a fireproof and explosion-proof flat glass Application; each of the glass sheets is bonded by a resin sheet.
The invention relates to a high-performance color glazed glass plate combination cabinet, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass There are 1-10 kinds of color glaze layer on the surface or back surface, and the flat glass is surrounded by a metal frame to form a composite board; there is a metal connecting device between the metal frames, making it a glazed glass plate combination cupboard.
A high-performance sliding door cabinet glass panel furniture, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass There are 1-10 colors of glaze on the surface or back, surrounded by metal frames, and the metal frame has rollers on the top and bottom.
The utility model relates to a high-performance color glazed glass plate combined wardrobe, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass a glaze layer of 1-10 colors on the surface or the back surface; the flat glass is surrounded by a metal frame to form a composite panel; and a metal coupling device is formed between the metal frames to make it a glazed glass Board combination wardrobe.
A high-performance color glazed countertop glass furniture, characterized in that: the countertop glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and a fireproof and explosion-proof flat glass Application: There are 1-10 colors of glaze layer on the surface or back of the table top, and there are support devices on the lower part of the table.
A high-performance photovoltaic solar device, comprising: a solar cell, and a glass substrate or a cover plate; the glass substrate or the cover plate is a low difference between a high softening point and a high temperature region thermal expansion coefficient according to claim 1. Low crystallization rate, application of fireproof and explosion-proof flat glass.
A high performance thin film solar device comprising: a thin film solar cell; and a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass according to claim 1 .
A roll-to-roll process for producing a film transistor on a glass substrate, and a liquid crystal display produced thereby, including

LCD screen, the LCD screen includes:

An array substrate comprising a substrate and a pixel structure produced on the substrate by a roll-to-roll process, wherein the substrate has a high softening point, a low difference in thermal expansion coefficient of a high temperature region, and a low resolution according to claim 1. Crystal speed, fireproof and explosion-proof flat glass;

a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;

a liquid crystal layer interposed between the array substrate and the color filter substrate;

Backlight system.
A touch display screen produced on a glass substrate by a roll-to-roll process, comprising: a substrate glass according to claim 1 having a high softening point, a low difference in thermal expansion coefficient of a high temperature region, and a low resolution The application of crystal speed, fireproof and explosion-proof flat glass is provided with a conductive film thereon;

LCD screen, the LCD screen includes:

An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;

a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;

a liquid crystal layer interposed between the array substrate and the color filter substrate;

Backlight system.
A high-performance liquid crystal screen or flat glass for a touch display screen produced by a roll-to-roll process, comprising:

The glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and a fireproof and explosion-proof flat glass according to claim 1; wherein the thickness of the flat glass is 0.05-3.5 mm, and the glass can be collected. The roll has an inner diameter of 20-80 cm and a length of 200 cm-2000 cm or 2001-10000 cm.
A high performance low temperature polysilicon display screen comprising:

LCD screen, the LCD screen includes:

a low temperature polysilicon array substrate comprising a substrate and a pixel structure produced on the substrate by a low temperature polysilicon process, wherein the base glass has a high softening point and a low difference in thermal expansion coefficient of a high temperature region according to claim 1. Crystallization speed, fireproof and explosion-proof flat glass;

a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;

a liquid crystal layer interposed between the array substrate and the color filter substrate;

Backlight system.
A flat glass for high performance low temperature polysilicon display, characterized by comprising:

The base glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass;
A high performance wear resistant and high strength liquid crystal display comprising:

An array substrate comprising a substrate and a pixel structure on the substrate, wherein the substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof explosion-proof plate according to claim 1. Application of glass;

a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;

a liquid crystal layer interposed between the array substrate and the color filter substrate;

Backlight system.
A high-performance wear-resistant and high-strength touch display screen comprising: a substrate glass according to claim 1 having a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass Application with a conductive film attached thereto;

LCD screen, the LCD screen includes:

An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;

a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;

a liquid crystal layer interposed between the array substrate and the color filter substrate;

Backlight system.
A high performance wear resistant and high intensity touch display mobile phone, or a touch display tablet computer, or a touch display notebook computer, or a touch display television, comprising:

The substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion proof flat glass according to claim 1, and a conductive film is attached thereon;

An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;

a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;

a liquid crystal layer interposed between the array substrate and the color filter substrate;

Backlight system;

Display edge device and support device.
A liquid crystal display screen produced by a process of first printing and re-sintering a thin film transistor, which comprises

LCD screen, the LCD screen includes:

An array substrate comprising a glass substrate, and a pixel structure produced by a process for printing a thin film transistor raw material on a glass substrate and then sintering the thin film transistor on the glass substrate; the glass substrate is the one according to claim 1. High softening point, low difference of thermal expansion coefficient in high temperature zone, low crystallization rate, application of fireproof and explosion-proof flat glass;

a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;

a liquid crystal layer interposed between the array substrate and the color filter substrate;

Backlight system.
A high performance curved liquid crystal display comprising:

The substrate glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass;

An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;

a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;

a liquid crystal layer interposed between the array substrate and the color filter substrate;

Backlight system;
A high-performance OLED organic light-emitting display screen comprising: a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass;

And organic electroluminescent devices.
A high-performance wear-resistant and high-strength mobile phone, or a transparent glass back casing of a tablet computer or a notebook computer or a desktop computer, characterized in that the transparent glass back casing is according to claim 1. A high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass.
A high performance bulletproof and explosion proof vehicle comprising:

1-3 layers of glass of 1-10 windows, the bulletproof glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass; Each piece of glass plate is bonded by a resin sheet;

There is a bulletproof structure in the metal plate or metal frame around the car;

And power unit; instrument panel; direction controller; car shell; car chassis; car brakes;
A high-performance anti-robbery, anti-theft, explosion-proof, anti-collision, anti-rolling injury car, which includes:

1-3 layers of glass of 1-10 windows, bulletproof glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass;

And power unit; instrument panel; direction controller; car shell; car chassis; car brakes;
A high performance solar aircraft having a propeller power for propelling flight, a wing, a driving control system device, and a thin film solar device comprising: a thin film solar cell; a substrate glass on a thin film solar device, According to the invention as claimed in claim 1, a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass are provided.
The utility model relates to a composite board of high-performance color glaze flat glass and metal layer, wherein the glass composition is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof explosion-proof The flat glass has a glaze layer of 1-10 colors on the surface of the substrate glass, a metal plate with a thickness of 0.1-5 mm, and a layer of adhesive material between the glass plate and the metal plate.
A high-performance glazed glass composite material board having a simple structure installed on a wall surface, the structural composition thereof is that the glass is a low difference between a high softening point and a high temperature region thermal expansion coefficient according to claim 1. , low crystallization rate, application of fireproof and explosion-proof flat glass, the surface of the substrate glass has 1-10 colors of glaze layer, 0.1-5mm thickness of metal plate, there is a layer of bonding material between the glass plate and the metal plate Layer, which is characterized by:

The 2-4 sides of the metal plate on the back surface of the composite board of the product, the edge of the surface glazed decorative flat glass product of the specific gravity protrudes by a distance of 10-30 mm.
A high-performance, glazed glass composite flooring with easy-to-assemble structure, including: [1] surface glazed glass substrate, [2] adhesive layer, [3] bottom layer, features It is: the surface layer of glazed glass material substrate is a high softening point, low differential coefficient of thermal expansion coefficient, low crystallization rate, fireproof and explosion-proof flat glass; 1-2 sides of the bottom layer, the bottom layer has protruding glass The outer edge of the face is 1-25mm; the other 1-2 sides of the bottom layer, the bottom layer has a feature of 1-25mm concave edge of the glass surface; the thickness of the bottom layer of the convex or concave glass surface is the material of the bottom layer 10%-90% of the thickness.
A high-performance glass wash basin produced by a thermal deformation process, which is a high-performance glass wash basin produced by a thermal deformation process for a flat glass material from a desired wash basin-shaped mold, characterized in that: The flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass.
A high-performance glazed glass wash basin produced by a thermal deformation process, which is a high-performance glass wash basin produced by a thermal deformation process for a flat glass material from a desired wash basin-shaped mold. It is: the flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass; a color shaft layer is attached to the glass.
A high-performance glazed glass lifting panel and a combined wash basin produced by a thermal deformation process, the structural features of which are: 1. a flat-shaped lifting panel; 2. another part of the joint is a flat panel Glass material consists of a desired wash basin-shaped mold, a glass wash basin produced by a thermal deformation process; 3. The flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, and a low resolution Crystal speed, fireproof and explosion-proof flat glass; 4. The glass surface is attached with a color shaft layer.
A high-performance glazed glass washbasin countertop for a bathroom, characterized in that: 1. The countertop glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature zone, and a low analysis Crystal speed, application of fireproof and explosion-proof flat glass; 2. glazed layer of 1-10 colors on the surface or back of the table; 3. There is a hole for installing the wash basin on the surface of the table; 4. Supporting device at the lower part of the table .
An ultra-long glass plate for a balcony protection barrier, the glass thereof is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass. It is characterized in that the length of the glass plate of the balcony protection barrier is 3-8 m.