CN102070297A - Extra-high aluminosilicate plate with high impact resistance and high bending resistance and process thereof - Google Patents
Extra-high aluminosilicate plate with high impact resistance and high bending resistance and process thereof Download PDFInfo
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- CN102070297A CN102070297A CN201010107103XA CN201010107103A CN102070297A CN 102070297 A CN102070297 A CN 102070297A CN 201010107103X A CN201010107103X A CN 201010107103XA CN 201010107103 A CN201010107103 A CN 201010107103A CN 102070297 A CN102070297 A CN 102070297A
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Abstract
The invention relates to an extra-high aluminosilicate plate with high impact resistance and high bending resistance. The extra-high aluminosilicate plate is characterized by comprising the following components by weight percent: 16%-45% of alumina (AI2O3), 5.5%-15% of magnesium oxide (MgO), 6.1%-15% of sodium oxide (Na2O), 10%-18% of calcium oxide (CaO), 35%-70% of silicon oxide (SiO2) and 0-10% of zinc oxide (ZnO).
Description
Technical field
The present invention relates to a kind of a kind of high impact-resistant and the extra-high-speed aluminosilicate sheet material of high anti-folding and processing method of making this board product as finishing material.
Background technology
Modern clear plate glass goods, its difference of hardness, not wear-resisting, folding strength is very low, and shock resistance is poorer, and toughness is also very poor; And be the toughened glass of material with the float glass, have from sudden and violent defective, its shock resistance and fracture resistance have raising than ordinary plate glass, but its poor toughness, difference of hardness, not wear-resisting, and can not cut, in application, limited to, thus aircraft forward and about window on to add very thickly, so just strengthened weight, what influence aircraft influences the sharpness of sight line from escheat, in the application of vehicle glass, splinter-proof glass, on the anti-folding of the bending resistance of existing glassy product, the shock resistance, also can not reach very high request; And in the application of construction and decoration, because of the limitation of the performance of existing glassy product, its use range also is subjected to great limitation.
A kind of throwing vitreous brick in the existing market and for example, its lower floor is the glaze pattern and the tile panel of printing, and the upper strata is the frit transparent, and it is very not wear-resisting, so substantially can not be in big the using as market, mansion, hotel ground of flow of the people.
Also have, in the prior art:
(1) for the glass of high aluminium content, mainly contain the base plate glass of a kind of PDP of being used for of Japan, to count as weight percents, its alumina content is at 7%-11%, and potassium oxide content is at 7%-11%.Because of worrying going mouldy of glass, do not contain any sodium oxide composition in its prescription, this just is that cooling and homogenization of glass have formed difficulty, forms the goods unfairness.So its goods generally will carry out second polishing again behind floating process, the cost height, waste is big, efficient is low.
(2) various glass such as P0200 that carries out for the relevant company of Japanese rising sun Xiao Zi and Corning Incorporated and Germany and Cs25, it has strengthened the content of aluminum oxide for strain point is raise, aluminum oxide reaches 7%-28% in the major ingredient, and sodium oxide only is 2%-6%; In order to dwindle degree of deformation, the rising strain point, crooked speed when reducing thermal expansion and being controlled at 550 ℃-600 ℃, also added certain Vanadium Pentoxide in FLAKES, zinc oxide, strontium oxide, compositions such as barium oxide, this has just strengthened technology difficulty, if especially it is in the production of glass, count as weight percents, when aluminum oxide is risen to 15%-28%, fixed has only sodium oxide 2%-6% by it is that ten minutes is difficult to melting temperature control is hanged down, this is its selection after comprehensive various technology purposes, generally is subjected to process technology limit, mostly needs second polishing because of unfairness, and especially added tantalum oxide, produced the loose of structure, so strength degradation is anti-folding, resistance to impact shock is also not really strong, and the softening temperature of its technology is too low in addition, viscosity is too big again, it is flat to have had a strong impact on dropping down of floating process, draw thin quality and efficient, output also is significantly less than general floatation glass production line, and limitation is very big.
(3) technology of other base plate glass of the U.S., count as weight percents, alumina content reaches 1%-10% or 10%-20%, only added sodium oxide 1%-15% and other as Vanadium Pentoxide in FLAKES, zinc oxide, strontium oxide, barium oxide, tantalum oxide compositions such as (having produced loose, the strength degradation of structure), but do not add the potassium oxide composition, main worry fusing point rises, thereby can influence the homogenization process and the product planeness of glass, influences the intensity of product.And other base plate glass technology have only the alumina content of 6%-11%, mainly worry to influence homogenization process and goods planeness.And in order to add hard intensity, so added the potassium oxide of 6%-12% and the sodium oxide of 2.5%-3.15% only, very big to the intensity effect of its goods, intensity is very poor.
More than three class glass because technology purpose difference, meter as weight percents all is not added to the content of 5.5%-15% on magnesian deal, the brute force that can not form magnesium, silicon, calcium is fluxed; Perhaps the deal of sodium oxide is less than 6%, and added the boron oxide of 6%-25%, general its seldom adds sodium oxide, mainly worries mouldy and is unsuitable for the characteristics of liquid crystal and various display screens, so when high alumina content, when especially alumina content reaches 16%-45% or 30%-45%, be not enough to cooling, will inevitably have the glass muscle of float glass to occur because of excess stickiness, must carry out second polishing, and cost is high.
(4) about a folding strength 60Mpa of the common low aluminium of float glass process (general alumina content is 1-2% only) sheet glass, and the folding strength of the prepared goods of technology of the present invention can reach minimum 90-150Mpa, also can reach 150-200Mpa, in application, exclusive stronger advantage be arranged.
Because the defective of above-mentioned prior art, the inventor is based on being engaged in many years of experience and the knowledge that this type of product design research is made, actively studied innovation, in the hope of defective and the deficiency that overcomes prior art, after solution, design to innovation a kind of high impact-resistant and the extra-high-speed aluminosilicate sheet material of high anti-folding and the present invention of processing method finally through a large amount of challenges.
Summary of the invention
First goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding are provided, especially adopted or the constituent structure of the prescription of efficiently the fluxing of high alumina sodium or high alumina and magnesium, calcium, silicon, viscosity reduction degree, high impact-resistant and high fracture resistance float glass process silicate board material products are achieved, and have overcome prior art many defectives are arranged.The present invention is to be main purpose with the anti-folding, bending resistance, the resistance to impact shock that improve glass, fully with reference to the technology of ceramic tire porcelain structure, innovates again.Because there is not the technology purpose of the deflection of very tight requirement in the present invention, there is not the technology purpose that adapts to thermal strain point, there are not the strict thermal expansion of electric substrate glass control and the strict crooked rate-controlling problem under specific temperature conditions, so not only can save the compositions such as strontium oxide, barium oxide, Vanadium Pentoxide in FLAKES, zinc oxide, boron oxide of unnecessary higher cost.And, in the composition ratio that improves aluminum oxide is aspect the product strength rising, given prominence to and made alumina content be increased to the scope of unprecedented 16%-45% or 30%-45%, form one and be different from the float glass process calcium soda glass of all prior aries, the prescription model of electric substrate glass, created the feature of the formula range of an extra-high-speed lead glass that high strength, shock resistance characteristic are arranged that is different from the remarkable novelty of having of aforementioned various prior art glass, creativeness and practicality, that is: (1) alumina content is 16%-45% or 30%-45%; (2) especially strengthen magnesian content and reach 5.5%-15% or 8%-15% or 10%-15%, form aluminium, calcium, magnesium cooling eutectic; (3) content of sodium oxide is increased to 6.1%-15%.This prescription makes the goods formed intensity of existing high aluminium content and fold resistance in floating process, again can be in the polishing of floating process, draw the thin stage, its viscosity is little, and can not produce glass muscle phenomenon (because if the problem of glass muscle is arranged, display screen glass as first technology, just need second polishing, this makes the production cost height, and breakage is also big.) so formula range of the present invention helps improving the anti-folding of goods or shock resistance or the like greatly, more helps especially the viscosity below 1300 ℃, flowability, molten pancake temperature, the better quality of planeness again.The purpose of the present patent application is that the folding strength, the resistance to impact shock that make goods have substantially exceeded existing float glass process soda-lime glass and electronic console base plate glass (also differ certainly and have many other special functional requirements of base plate glass surely fully), and on technical recipe, can form glass metal homogenizing, the selection (substantially exceeding the softening point temperature of all electronic console base plate glass) of clarifying and drawing thin significant softening temperature, except 700 ℃-890 ℃ selection, can also select softening temperature to be: 890 ℃-1100 ℃; 980 ℃-1100 ℃; 1100 ℃-1200 ℃.The cooperation of these prescriptions is formed, and the insider knows that also it can produce the high impact-resistant that does not need second polishing that does not have the glass muscle, the goods of high fracture resistance.
Make the aluminum oxide composition total content of mixing raw material reach 16%-45% or 30%-45% again because the present invention has creatively broken through the temperature range of various existing float glasses, and in technology with on filling a prescription; Make softening point temperature that three kinds of selections be arranged on prescription: first kind is 700 ℃-890 ℃, or second kind be 980 ℃-1100 ℃, or the third is 1100 ℃-1200 ℃.Owing in goods, strengthened the content of aluminum oxide and adopted relevant suitable Recipe, can be by processing requirement and the necessary requirement that the strength of glass of peak performance is arranged, molten bath, tin kiln and cooling annealing furnace to traditional float glass technology, carrying out refractory materials and various liftings, is that crucial technical scheme promotes invention.The insider knows, exceed equally under the higher temperature condition of all existing electronic console base plate glass and float glass, just can guarantee in the goods technical process homogenizing, suitable viscosity, flowability, planeness, draw book, annealed to finish, the planeness of goods, quality parameter just have and differently fully significantly rise.Goods of the present invention, under the secure prerequisite of the transparency:
(1) bending resistance folding strength and anti-impact are pressed the existing strong several times of float flat glass of strength ratio, can be stronger behind tempering than existing toughened glass, be better than all base plate glass more greatly, also can not produce the certainly sudden and violent phenomenon as existing toughened glass, and can be by arbitrarily cutting or punching of processing requirement;
(2) especially on toughness, the folding strength (can reach 90-150Mpa or 120-200MPa), also obvious advantages is arranged than existing float glass (being generally 50-60MPa), ceramic tile (being generally 40-50MPa) etc.;
(3) if plate product of the present invention is carried out tempering again, can make the relatively more existing float glass of bending resistance, folding strength is the tempering product rising several times of base material.So, as being used in before and after the front windshield of aircraft and side window glass or the automobile and the side glass for vehicle window is used, its security can be risen 2-8 doubly; Be used in splinter-proof glass or the naval vessel is on glass, also can be doubly than original performance rising 2-8; It is on glass to be used in Highrise buildings, also can security promote 2-8 doubly.Thus, this is the constituent structure and the manufacturing process thereof of the extra-high-speed aluminosilicate board product of the revolutionary original innovation of a new functional materials, integrate innovations a kind of high impact-resistant and high anti-folding.This is one of the goal of the invention place of novelty of the present invention, creativeness and practicality.
Second goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding is provided, and its goods can replace the market of many ceramic products.Because its manufacturing process is different from international and domestic advanced ceramics production-line technique equipment technology fully, especially do not adopt water law ball milling operation wherein, the link of spray high energy consumptions such as operation, ceramic press operation, polishing process, high pollution, high water consumption; Also because the innovation and the maturity of technology can be produced the only ultra-thin product of 2-5mm thickness, abandoned the product of the technology that the modern architecture ceramic tile can only 10-15mm thickness.So, can 1. energy-conservation [oil, electricity, coal] reach 60%-80%; 2. since product only thick for 2-5mm, to polish the advanced ceramics product of the 10mm that grinds off 1mm thickness than traditional technology, 50-80% saves material; 3. water saving reaches 80%; 4. the GDP Carbon emission reduces 70-80%; 5. save the market path logistics cost 50-70% of transportation raw material and product; 6. GDP energy loss-rate decline 8-10 doubly; 7. the rising of GDP value of the product adds the productivity ratio decline of land used, and land utilization ratio rising 8-10 doubly; 8. owing to can adopt the stone material of big plate, the big wooden frame or the metal frame packing of glass, carton, the bubble chamber of pottery are saved packing cost more than 50% relatively now; 9. in environmental requirement, the insider knows, owing to do not have water law ball milling, the spraying operation of present Production of Ceramics, the water law polishing process, in important indicators such as dust, dischargings, be better than tens of times of modern architecture ceramic production lines greatly, if in big city, Chinese developed regions and developed country set up factory or transform float glass factory, in high-level environmental requirement, all can be fully up to standard.This is two places of the goal of the invention of novelty of the present invention, creativeness and practicality.
The 3rd goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding are provided, because the shock resistance of goods of the present invention, fracture resistance, toughness, be better than existing float glass several times, even goods sheet material of the present invention is tempering not, also be better than unidimensional pottery greatly, about about 3 times of stone material product, so product of 3mm thickness of the present invention, its intensity, toughness just is equivalent to the conventional ceramic and the float glass product of 10mm thickness, just can make various board-like furnitures and kitchen cabinet, sliding window, desk, the meeting platform, veneers such as house ornamentation and hotel's dinner table are used, and are that collection is firm, various aesthetic pattern can be arranged, the smooth bright and clean grade of minute surface is the novel material product of advantage all over the body.This is three places of novelty of the present invention, creativeness and practicality goal of the invention.
The 4th goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding are provided, owing in technical process, improved strain point temperature and promoted prescription, can form than liquid crystal with boron glass, than salic PDP substrate for 7%-11% with folding strength, the resistance to impact shock of glass folding strength, the resistance to impact shock of the high strength glass that is used for liquid crystal or PDP TV screen of 2-4 0.5mm-1mm thickness doubly that significantly rise, and significantly reduce costs such as transportation, breakage and packing.Especially when adopting high Mg content, as counting as weight percents, content of magnesia reaches 7%-15%, the shortcoming of going mouldy that not only can not have the composition of sodium and cause, and can be minimum because of low temperature viscosity, good fluidity can not have the glass muscle fully, need not also need to polish again the technology of 0.5-1mm as Japanese PDP, can on the LCD TV plate, adopt fully.Its thermal strain point also reaches 620 ℃-700 ℃, be lower than the purpose of strain point temperature when reaching the indicating meter welding, the production of extremely low-expansion goods of especially indeformable high alumina, magnesium, calcium, silicon, can on thermal deformation coefficient, be better than existing boron glass substrate patented product and PDP substrate patented product.This is four places of novelty of the present invention, creativeness and practicality goal of the invention.
The 5th goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding is provided, and can adopt following innovation pattern formation method:
As adopting: (1) piece bulk goods technology, the filament wire that extrude (2), strip, block material technology, (3) particulate material technology, (4) are to bar, block color spray packing technology, (5) micro mist technology, (6) free distributing technique.
The color raw material of the different character shape that above technology occurs, be mixed into same material container after, the method that enters same molten bath again is a kind of brand-new novel process.200810027295.6) and other all two or two above molten baths of prior arts employing or smelting furnaces relatively the inventor's has application for a patent for invention (application number: earlier, not homochromy liquation is flowed in the molten tin bath of float glass process mixes the technology that forms pattern, the present invention will: (1) is suitable for more and is practical; (2) handled easily and save a large amount of new several molten baths build resource (cost of building in each molten bath reaches more than one hundred million yuans); (3) can not change the equipment (with regard to cost, transform the float glass process production line that a cost reaches several hundred million Renminbi, need more than one hundred million Renminbi expensive at least, but also want stop work and production, cause a large amount of losses) that has float glass process production line molten bath kiln and tin kiln now; (4) and processing method of the present invention be adopt not homochromy piece, grain equal-volume form since the fusion stage with regard to the congruent melting of longer time and the effect that forms, relatively prior art proposal is taked the polychrome glass metal inflow at weld pool surface, the method for sneaking into, the present invention also can produce better three-D pattern effect, especially after fusing, be in mobile state because of the raw material powder, slight or local flow can form the pattern effect of nature flowability and the friendship of district of all kinds limit portion and sneak out the natural effect that crosses in the molten bath.This is five places of novelty of the present invention, creativeness and practicality goal of the invention.
The 6th goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding is provided.Because the alumina content of common calcium soda glass is lower, its fragility is big, poor toughness, after pattern is burnt till in the appearance glazing, can not make the especially high-rise metope of wall face at all and paste materials used, intensity difference also can not the glaze ornament layer after the printing be polished, because will produce breakage because of pressurized once polishing.And the high silicate-base sheet material of the intensity of goods of the present invention, be the sheet material of structure that has adopted the composition of high alumina or high magnesium, calcium, silicone content, or contain the very fine and close sheet material that forms through melting technology and floating process again of the abundant homogenizing of crystalline and structure, its folding strength can reach 80-180Mpa, and is more much higher than the 40-50Mpa of the 50-60Mpa of common soda glass and conventional ceramic brick.So the present invention can produce thin colored glaze polished product, and the stickup that can enter into ground and exterior wall is used, that is to say that the present invention has adopted the high substrate of intensity and increased safe, the frivolous 2-5mm of the effect of the ornamental replacement stone material pattern of the glaze layer of intensity after the moulding or the combination of the goods of 2-3mm.This is six places of the goal of the invention of novelty of the present invention, creativeness and practicality.
The 7th goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding is provided.Because existing all ceramic products are because of the water-intake rate height, in case too thin, if northerly have fog season, moisture content enters the after that freezes behind the ceramic plate, will make the local spalling of sheet material, security is very poor, and all ceramic technologies not can manufacture the ceramic plate of 2-3mm thickness now.And the colored glaze pattern article of the float glass process silicate sheet material of 2-5mm that the present invention produces or 2-3mm thickness, in the metope market of widely applying, substitute the conventional ceramic product of 12-15mm thickness, to in the low-carbon economy development, bigger positive effect be arranged to economizing on resources, reduce on the energy consumption.This is seven places of the goal of the invention of novelty of the present invention, creativeness and practicality.
The 8th goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding are provided, in technology is made, employing has added or quartz crystal, or mullite crystal, or alpha-alumina crystals, or diopside crystal, or willemite crystal, or diopside crystalline composition reaches the glaze of 5%-50%, the extra-high-speed aluminosilicate sheet material top layer of high impact-resistant and high anti-folding is applied this colored glaze pattern decorative layer of 2 kinds or 3-10 kind color, form abundant, meticulous colored glaze pattern, because the existence of crystal composition, can make the fastness to rubbing of goods promote greatly, intensity rises greatly, and the scope of application will improve greatly; Make its printed matter have very high toughness, folding strength and shock resistance simultaneously.This is eight places of the goal of the invention of novelty of the present invention, creativeness and practicality.
The 9th goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding are provided, it can make the 2-5mm ultrathin, under the state that the surface stress that does not carry out tempering is handled, its folding strength reaches the high impact-resistant of 70-180Mpa and the extra-high-speed aluminosilicate sheet material of high anti-folding, and be used for and the metal sheet of thin layer is compounded to form novel composite sheet with it, with gently, thin, high-intensity, nondiscoloration, the purpose that the minute surface decorative effect can be arranged, reach and satisfy better functional user demand, and the limit portion of surface silicon hydrochlorate sheet material that adopts the 2-4 bar limit proportion poststack of the bottom surface sheet metal the make composite sheet distance of stretching out 10-30mm, the easy mounting means that punches and afterwards adopt screw directly to hammer into body of wall or use in the limit portion that this stretches out with the metope of the hard-wired innovation of body of wall keel frame, the breakage rate that fractures is reduced greatly, ensured that the purpose of following each big function realizes.(1), can make the product as 1200mm * 2400mm size of big plate face, whole world ceramic product technology all not can manufacture the product of the 1200mm * 2400mm size of 2-5mm ultrathin now, and thick its folding strength of product of the thickness that has only is 40-50MPa; (2), with the present invention's 2-5mm ultrathin, under the state that the surface stress that does not carry out tempering is handled, its folding strength reaches the surperficial sheet material of the silicate board of 70-180Mpa as composite sheet, and the insider understands that it can be the decorative effect that the polishing of minute surface planeness is arranged; (3), because of the 2-5mm ultrathin, under the state that the surface stress that does not carry out tempering is handled, its folding strength reaches the well-pressed straight feature (insider understands) of the silicate board of 70-180Mpa, can make composition board of the present invention than aluminium-plastic panel and the complete well-pressed planeness of aluminium sheet, and never distortion, the finishing effect utmost point is improved grade; (4), the present invention 2-5mm ultrathin of producing, under the state that the surface stress that does not carry out tempering is handled, the silicate board that its folding strength reaches 70-180Mpa can be inorganic color, can be anti-aging, will never fade, stone material pattern or other various pattern effects of inorganic glaze or base substrate can also appear; (5), existing ceramic plate is in wall surface dry-hang, must reach more than the 12-15mm by its thickness of national standard requirement, lithotome is because intensity difference, the national standard of wall surface dry-hang requires its thickness must reach 25-30mm, and goods ability 2-5mm thickness of the present invention or selection 2-3mm thickness, so on the meaning of energy-saving and environmental protection, low-carbon economy development effect, (comparable conventional ceramic plate or lithotome reduce 6-8 doubly greatly) gone up in the load-bearing load reduction of buildings, profound significance all arranged; (6) though, dull and stereotyped float glass can be made into 2-3mm thickness, but its intensity is very poor, and because the building glass sodium content reaches 13%, so the insider knows, corner after the fragmentation is very sharp, do not paste and use so dare to be used for exterior wall, and the toughened glass behind its tempering be because can not cut (this also is that the insider is known) again, can not solve so it is used for the stdn plate and cut that to use be a unresolved difficult problem of using.The above is nine places of the goal of the invention of novelty of the present invention, creativeness and practicality.
The tenth goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding are provided, it can make the 2-5mm ultrathin, under the state that the surface stress that does not carry out tempering is handled, its folding strength reaches the high impact-resistant of 70-180Mpa and the extra-high-speed aluminosilicate sheet material of high anti-folding, and be used for and the metal sheet of thin layer is compounded to form novel composite sheet with it, with gently, thin, high-intensity, nondiscoloration, the purpose that the minute surface decorative effect can be arranged, reach and satisfy better functional user demand, and adopt the distance that the limit facial planes stretches out or the bending an angle of 90 degrees stretches out 10-30mm of surface silicon hydrochlorate sheet material of the 2-4 bar limit proportion poststack of the bottom surface sheet metal make composite sheet, at the limit portion that this stretches out easy mounting means that the back adopts screw directly to hammer into body of wall or use with the metope of the hard-wired innovation of body of wall keel frame that punches.The new type composite board of this structure, the mode that adopts punching to install, should be for current the safest, save most, the easiest metope mounting means, the matrix material of new feature is provided, several expansion screws of its usefulness (or screw) just can be installed in sheet material on the metope firmly.And because the 2-5mm of top layer silicate product or the thickness of 2-3mm are arranged, the head that is pressed in the expansion screw on the metal sheet fully can floating by joint seal glue (a kind of tack thickness of tack expansion screw 1.5mm thickness).This is why the present invention can reach novelty, creativeness and the practicality place as cladding great innovation attractive in appearance, we can say the great revolution that can form outer wall board and installation.Gently, the NEW TYPE OF COMPOSITE sheet material of the present invention of thin, magnificent outward appearance, high strength, high-flatness, not only link plate weight saving (alleviating 80-90%) than the porcelain plate of 12-15mm thickness and the stone material plate of 25-30mm thickness for building, and put up etc. at the keel of installation costs, man-hour and saving, can save altogether that (intermediary keel and mounting cost are generally 180-500 yuan/m more than 90%
2, and 4 expansion screws of the present invention and a mounting cost 10-20 unit).So this also will have far reaching to improve to the national standard of the exterior wall cladding thickness of ceramic plate 12mm, the stone material plate 25mm of China and the effect of innovation.The above is ten places of the goal of the invention of novelty of the present invention, creativeness and practicality.
The 11 goal of the invention of the present invention is, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant and high anti-folding is provided, and can form the combination of colourful transparent and opaque color, forms the goods as the high-end decorative effect of beautiful texture such as jadeite jade.This is 11 places of the goal of the invention of novelty of the present invention, creativeness and practicality.
In a word, goods of the present invention and processing method are a novel material and a processing method that special advantage function is arranged, and the meaning of integrated innovation and original innovation and novelty and practicality has been contained in the present invention.
The object of the invention to solve the technical problems realizes by the following technical solutions.According to a kind of high impact-resistant of the present invention's proposition and the extra-high-speed aluminosilicate sheet material of high anti-folding, it is characterized in that: count as weight percents, contain the aluminum oxide (Al of 16%-45% in its goods
2O
3), contain the magnesium oxide (MgO) of 5.5%-15%, contain the sodium oxide (Na of 6.1%-15%
2O), contain the calcium oxide (CaO) of 10%-18%, contain the silicon oxide (SiO of 35%-70%
3), contain the zinc oxide (ZnO) of 0-10%.
The object of the invention to solve the technical problems also adopts following technical measures further to realize.
The extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding is characterized in that: count as weight percents, contain the aluminum oxide (Al of 30%-45% in its goods
2O
3).
The extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding is characterized in that: count as weight percents, contain the magnesium oxide (MgO) of 8%-15% in its goods.
The extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding, it is characterized in that: the folding strength of its goods when not carrying out the tempering autofrettage reaches 90-200MPa.
The extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding, it is characterized in that: the folding strength of its goods when not carrying out the tempering autofrettage reaches 120-200MPa.
The extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding is characterized in that: contain in its goods or mullite crystal or corundum crystal or diopside crystal or enstatite crystal or wollastonite crystal or cordierite crystal or rutile crystal or forsterite crystal.
The extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding is characterized in that: the pattern that the three-dimensional space of its goods or top layer are made up of a kind or 2-10 kind color.
The extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding, it is characterized in that: the top layer of the extra-high-speed aluminosilicate sheet material of its described high impact-resistant and high anti-folding, the ornament layer that has one deck to form by the colored glaze of a kind or 2-10 kind color, and can also contain in the glaze of this layer ornament layer or quartz crystal or mullite crystal or corundum crystal or diopside crystal or wollastonite crystal or willemite crystal.
The extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding, it is characterized in that: the extra-high-speed aluminosilicate sheet material with described high impact-resistant and high anti-folding is surperficial sheet material, pass through bonding material layer, paste composition metal plate at its back side, can form the composite sheet of the trilaminate material of a kind of high impact-resistant and the high anti-extra-high-speed aluminosilicate sheet material of rolling over and bonding material layer and sheet metal.
The extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding, it is characterized in that: its described extra-high-speed aluminosilicate sheet material with high impact-resistant and high anti-folding is surperficial sheet material, pass through bonding material layer, the composite sheet that forms at its back side stickup composition metal plate, the distance that 10-30mm stretches out in the limit portion of the surface silicon hydrochlorate sheet material of the 2-4 bar limit proportion poststack of the metal sheet of its back of the body bottom surface.
The processing method of the extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding is characterized in that:
Count as weight percents, 1. alumina content at 16%-45% or 30%-45%, and 2. sodium oxide 6.1%-15%, 3. silicon oxide 35%-70%, 4. calcium oxide 10%-18%, 5. zinc oxide 0-10%, 6. magnesium oxide or select 5.5%-15% or select the silicate starting materials of the content of 8%-15% to prepare add or do not add tinting material by processing requirement;
On prescription, make softening point temperature: or be chosen as 700 ℃-890 ℃, perhaps be chosen as 890 ℃-1100 ℃, perhaps be chosen as 1000 ℃-1200 ℃;
To mix the raw material of forming then, put into resistant to elevated temperatures molten bath or smelting furnace, and, make above-mentioned raw materials all be molten into vitreous state through 1400 ℃ of-1600 ℃ of temperature or through 1600 ℃ of-1800 ℃ of temperature;
Enter the float glass process molding procedure again, promptly on the tin face of the molten tin bath that forms the flowable liquid molten body inflow of remollescent floating process, through drop down flat moulding, polish, draw thin, and edge machine is in the traction of drawing with tractor of leading of the direction of process stipulation, pull out molten tin bath, and after entering the cooling refrigerating work procedure of back segment,, promptly obtain transparent or painted a kind of high impact-resistant and high anti-extra-high-speed aluminosilicate board product of rolling over as the big plate of float glass through cutting.
The processing method of the extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding is characterized in that:
On prescription, make softening point temperature: or be chosen as 700 ℃-890 ℃, perhaps be chosen as 890 ℃-1100 ℃, perhaps be chosen as 1000 ℃-1200 ℃;
The processing method of the extra-high-speed aluminosilicate sheet material of aforesaid a kind of high impact-resistant and high anti-folding is characterized in that:
On prescription, softening point temperature is chosen as: 700 ℃-890 ℃, perhaps be chosen as 890 ℃-1100 ℃, perhaps be chosen as: 1000 ℃-1200 ℃;
In sum, the extra-high-speed aluminosilicate sheet material and the processing method of a kind of high impact-resistant of the present invention and high anti-folding, have above-mentioned many advantages and practical value, and in like product and production method, do not see have similar design and method to publish or use and really genus innovation, no matter it is at product structure, great improvement is all arranged on production method or the function, great progress is arranged technically, and produced handy and practical effect, and more existing glass, porcelain brick technology and goods all have the multinomial effect of enhancement, thereby be suitable for practicality more, and have the extensive utility value of industry, really be a novelty, progressive, practical new design.
Above-mentioned explanation only is the general introduction of technical solution of the present invention, for can clearer understanding technique means of the present invention, and can be implemented according to the content of specification sheets, and for above-mentioned and other purposes, feature and advantage of the present invention can be become apparent, below especially exemplified by preferred embodiment, and conjunction with figs., be described in detail as follows.
Description of drawings
Fig. 1 is the floor map of a kind of high impact-resistant of the present invention and the goods of the employing floating process moulding of high anti-extra-high-speed aluminosilicate sheet material of rolling over and processing method embodiment.
Fig. 2 is the schematic flow sheet of the employing floating process moulding of a kind of high impact-resistant of the present invention and high anti-extra-high-speed aluminosilicate sheet material of rolling over and processing method embodiment.
Fig. 3 is the side diagrammatic cross-section of a kind of high impact-resistant of the present invention and the state of the employing floating process moulding of high anti-extra-high-speed aluminosilicate sheet material of rolling over and processing method embodiment.
Fig. 4 is that the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant of the present invention and high anti-folding and the top layer of processing method embodiment are the extra-high-speed aluminosilicate sheet material of high impact-resistant and high anti-folding, the back side is the aluminium sheet that overlapping back portion does not exceed the top layer silicate board, the NEW TYPE OF COMPOSITE sheet material cross-sectional view of pasting compound composition by tackiness agent mutually.
Fig. 5 is that the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant of the present invention and high anti-folding and the employing top layer of processing method embodiment are the extra-high-speed aluminosilicate sheet material of high impact-resistant and high anti-folding, the back side is to have 2 limits to stretch out the aluminium sheet of 10-30mm distance separately than top layer silicate board after overlapping, paste the NEW TYPE OF COMPOSITE sheet material of compound composition mutually, and after the punching of the predetermined position of 10-30mm extension, can carry out the upright two dimensional structure synoptic diagram that the metope screw is installed.
What the Reference numeral in the accompanying drawing was represented is explained as follows:
1: the extra-high-speed aluminosilicate sheet material of high impact-resistant and high anti-folding
2: the feed bin opening for feed
3: feed bin
4: the mixing raw material of predetermined preparation
5: raw material enters the molten bath kilneye in molten bath
6: the molten bath kiln
7: diversion trench
8: molten tin bath
9: the transition roller platform
10: annealing furnace
11: the cutting portioning station
12: float glass process production line matrix
13: the tackiness agent that expression is predetermined
140: represent that overlapping back portion does not exceed the aluminium sheet of top layer silicate board
14: represent to have after overlapping up and down 2 limits to stretch out the aluminium sheet of 10-30mm distance separately than top layer silicate board
15: aluminium sheet stretches out screw open holes in the limit portion of 10-30mm than top layer silicate board at the bottom of the back of the body of expression composite sheet
The detailed description of accompanying drawing
Reach technological means and the effect that predetermined goal of the invention is taked for further setting forth the present invention, below in conjunction with accompanying drawing and preferred embodiment, the extra-high-speed aluminosilicate sheet material that a kind of high resistance is impacted and high resistance is rolled over that foundation the present invention is proposed and the implementation of process are described in detail as follows with structure, technology, prescription, step, feature and the effect thereof of the goods of floating process moulding.
Seeing also shown in Figure 1ly, is the goods floor map of the employing floating process moulding of a kind of high resistance of the present invention is impacted and high resistance is rolled over extra-high-speed aluminosilicate sheet material and process embodiment. From scheming as seen the label 1 extra-high-speed aluminosilicate sheet material that the expression high resistance is impacted and high resistance is rolled over.
Seeing also shown in Figure 2ly, is the schematic flow sheet of the employing floating process moulding of a kind of high resistance of the present invention is impacted and high resistance is rolled over extra-high-speed aluminosilicate sheet material and process embodiment. From scheming as seen; the flow process of its moulding process is that the raw material of predetermined preparation is put into the charging storehouse; from the charging storehouse, raw material is transported to then and entered the molten bath in the kiln of molten bath and carry out melting and discharge bubble by predetermined temperature; it then is liquid molten mass; enter into molten tin bath (next door of molten tin bath is provided with the protective gas station of nitrogen hydrogen to molten tin bath input protection gas); tin face at molten tin bath drops down flat; through drawing the limit; traction; form the smooth semi-finished product band of polishing; enter into annealing kiln from transition roller table and carry out cooling down; and obtain goods; on cutting packing platform, enter again the cutting packing of preliminary dimension, obtain finished product.
Fig. 3 is the side generalized section of state of the employing floating process moulding of a kind of high resistance of the present invention is impacted and high resistance is rolled over extra-high-speed aluminosilicate sheet material and process embodiment. From scheming as seen, label 2 expression feed bin charging apertures, label 3 expression feed bins, the mixing raw material of the predetermined preparation of label 4 expressions, label 5 expressions mix the molten bath kilneye (the mixing raw material of the predetermined preparation shown in the label 4 is transported in the molten bath of molten bath kiln thus) that raw material enters the molten bath, label 12 expression float glass line matrixes, label 6 expression molten bath kilns, liquid fused raw material body in the label 7 expression baths enters the guiding gutter of molten tin bath, the molten tin bath of label 8 expression floating process, the semi-finished product band that forms in the label 9 expression molten tin baths enters the transition roller table of annealing kiln, label 10 expression annealing kilns, and the cutting packing platform of packing is cut the moulding goods in label 11 expressions.
See also shown in Figure 4, that the extra-high-speed aluminosilicate sheet material of a kind of high resistance impact of the present invention and high resistance folding and the top layer of process embodiment are the extra-high-speed aluminosilicate sheet material that high resistance is impacted and high resistance is rolled over, the back side is the aluminium sheet that overlapping back section does not exceed the top layer silicate board, mutually pastes the composite board section structural representation of compound composition by adhesive. From scheming as seen, label 1 expression high resistance is impacted and the extra-high-speed aluminosilicate sheet material of high resistance folding, and the predetermined adhesive of label 13 expressions, label 140 represent that overlapping back section does not exceed the aluminium sheet of top layer silicate board.
See also shown in Figure 5, that the extra-high-speed aluminosilicate sheet material of a kind of high resistance impact of the present invention and high resistance folding and the employing top layer of process embodiment are the extra-high-speed aluminosilicate sheet material that high resistance is impacted and high resistance is rolled over, the back side is to have 2 limits to stretch out separately the aluminium sheet of 10-30mm distance than top layer silicate board after overlapping, mutually paste the composite board of compound composition, after the punching of the precalculated position of 10-30mm extension, carry out the vertical planar structure schematic diagram that the metope screw is installed. From scheming as seen, the ultra-thin high resistance folding of label 1 expression silicate board, have up and down 2 limits stretch out separately the aluminium sheet of 10-30mm distance than top layer silicate board after label 14 expression is overlapping, the back end aluminium sheet of label 15 expression composite boards stretch out screw installing hole in the limit section of 10-30mm than top layer silicate board.
Below be the preferred embodiment of embodiment:
Now with the goods making of the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant of the present invention and high anti-folding and processing method, processing method, with and goods be applied to the composite sheet that forms with aluminium sheet and install at metope and be applied as embodiment and be described further, its manufacturing processed comprises following steps:
(1), the making and the processing method thereof of the goods of the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant of the present invention and high anti-folding:
(1), at first, with reference to the ceramic matrix prescription, and the increasing alumina content, meter is pressed the 25-40% of total amount to the potassium felspar sand of salic amount about 18% or albite raw material as weight percents, and contain quartz sand, mud raw material 10-30% by total amount, mix, be mixed with compound (wherein make the total content of aluminum oxide account for the 16-45% of total amount, the about 40-60%[of silicon oxide has different quartz contents because of in the various raw materials], the about 10-18% of calcium oxide, the about 7-12% of magnesium oxide);
And make the softening point temperature of compound that three kinds of selections be arranged on technology and prescription: first kind is 700 ℃-890 ℃, or second kind be 980 ℃-1100 ℃, or the third is 1100 ℃-1200 ℃;
(2), be ready to the float glass process production line that comprises facilities such as former feed bin, molten bath kiln, the tin kiln that contains tin liquor and edge machine, tractor, transition roller platform, annealing furnace cooling system, cutting portioning station of floating process as shown in Figure 3.
(3), by Production Flow Chart shown in Figure 3 and that press floating process shown in Figure 2, the compound of the predetermined preparation shown in the label 4 of (1) step preparation, from the feed bin opening for feed shown in the label 2 of Fig. 3, be conveyed in the former feed bin shown in the label 3 in raw material conveying belt mode, again through the molten bath kilneye shown in the label 5, (1) step prepared mixture is sent in the molten bath of the predetermined resistant to elevated temperatures molten bath kiln shown in the label 6, progressively at 1300 ℃-1600 ℃ or form the liquid melting body of good fluidity during 1300 ℃ of-1800 ℃ of humidity provinces, progressively discharge bubble in the liquid raw material through the high-temperature zone, promptly formed the mixing raw material liquid molten body that the flowability that can enter molding procedure contains a large amount of aluminum oxide preferably.
(4), by the Production Flow Chart of floating process shown in Figure 2 and shown in Figure 3, the flowable that makes (3) step is mixing raw material liquid molten body preferably, from the folder mouth of the molten bath kiln shown in the label 6 through the diversion trench shown in the label 7, flow on the tin face of the molten tin bath (also can be described as the tin kiln) shown in the label 8 of float glass process production line, again through dropping down flat moulding, polishing, draw thin, and by the processing requirement of producing 5mm thickness, draw the traction of limit and tractor through edge machine, polishing is thrown flat on the tin liquor face, after formation work in-process band goes out the tin kiln by the transition roller platform shown in the label 9, enter the annealing furnace cooling of the cooling cooling system of the roller-way shown in the label 10, enter into the cutting portioning station shown in the label 11 again, through cutting, packing promptly obtains as shown in Figure 1 a kind of high impact-resistant of the present invention and high anti-extra-high-speed aluminosilicate board product of rolling over.
(2), make aluminium sheet at the bottom of the overlapping back and have 2 limits to stretch out the NEW TYPE OF COMPOSITE sheet material that 10mm is of a size of the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant of the present invention of 1220mm * 2440mm and high anti-folding, and the installation method of using this NEW TYPE OF COMPOSITE sheet material at metope than the extra-high-speed aluminosilicate sheet material of top layer high impact-resistant and high anti-folding.
(A), make the composite sheet of board product of the present invention and aluminium plate:
(1), preparing thickness is that 3mm is of a size of a kind of high impact-resistant of the present invention shown in the label 1 of 1220mm * 2440mm and the extra-high-speed aluminosilicate sheet material of high anti-folding, a kind of thickness is that 0.5mm is of a size of thin aluminum sheet shown in the label 14 of 1240mm * 2440mm, and go back the oxygen tackiness agent shown in the label 13 that do to paste uses, and as the means of production equipment and the place of bonding construction;
(2), the tackiness agent shown in the label 13 is evenly applied one deck on high impact-resistant shown in the label 1 and the high surface that resists the back side of the extra-high-speed aluminosilicate sheet material of rolling over or be applied to the side that is used to paste of the thin aluminum sheet shown in the label 14;
(3), be bonded in the surface of aluminum plate central authorities of bottom 1240mm * 2440mm then by top layer 1220mm * 2440mm silicate board, making the bottom aluminium sheet have two limits to be scheduled to that separately 10mm is arranged is the mode of stretching out outside the silicate board corresponding edge portion of top layer, paste the extra-high-speed aluminosilicate sheet material and the aluminium sheet shown in the label 14 of high impact-resistant shown in the label 1 and high anti-folding compound, along with the curing of going back the oxygen tackiness agent shown in the label 13, make the aluminium sheet shown in anti-folding silicate board of the ultra-thin height shown in the label 1 and the label 14 paste tightly and be combined with each other.
Thereby obtaining a kind of bottom material of carrying on the back is the thin aluminum sheet that 0.5mm thickness is of a size of 1240mm * 2440mm, the top layer is that 3mm thickness is of a size of the high impact-resistant of 1220mm * 2440mm and the extra-high-speed aluminosilicate sheet material of high anti-folding, paste by predetermined tackiness agent, and the NEW TYPE OF COMPOSITE sheet material of the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant that forms and high anti-folding.(as shown in Figure 5)
(and if the aluminium sheet that adopts lower floor is the mode that overlapping back portion does not exceed the size of top layer silicate board, then can make the upper strata is that aluminium sheet, the middle layer that limit portion does not exceed the upper strata silicate board is a kind of NEW TYPE OF COMPOSITE board product of predetermined binder layer for float glass process three-dimensional color pattern silicate sheet material of the present invention, lower floor, as shown in Figure 4.)
(B), the innovation mounting means (as shown in Figure 5) of the above-mentioned NEW TYPE OF COMPOSITE sheet material of the embodiment of the invention is installed at metope:
The above, only be for preferable preferred embodiment of the present invention is described, yet it is not to be limitation of the present invention, any personnel that are familiar with this technology may utilize the technology contents of above-mentioned prompting to be changed or be modified to the equivalent embodiment of equivalent variations, can implement to make a kind of high impact-resistant and high extra-high-speed aluminosilicate sheet material and the processing method that resists folding by the performance of difference requirement.As seen, hold within the every content that does not break away from technical solution of the present invention, the especially claim, to any simple modification that above embodiment did, equivalent variations and modification all still belong in the scope of technical solution of the present invention according to technical spirit of the present invention.
Claims (13)
1. the extra-high-speed aluminosilicate sheet material of a high impact-resistant and high anti-folding is characterized in that: count as weight percents, contain the aluminum oxide (Al of 16%-45% in its goods
2O
3), contain the magnesium oxide (MgO) of 5.5%-15%, contain the sodium oxide (Na of 6.1%-15%
2O), contain the calcium oxide (CaO) of 10%-18%, contain the silicon oxide (SiO of 35%-70%
2), contain the zinc oxide (ZnO) of 0-10%.
2. the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 1 and high anti-folding is characterized in that: count as weight percents, contain the aluminum oxide (Al of 30%-45% in its goods
2O
3).
3. the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 1 and high anti-folding is characterized in that: count as weight percents, contain the magnesium oxide (MgO) of 8%-15% in its goods.
4. the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 1 and high anti-folding, it is characterized in that: the folding strength of its goods when not carrying out the tempering autofrettage reaches 90-200MPa.
5. the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 1 and high anti-folding, it is characterized in that: the folding strength of its goods when not carrying out the tempering autofrettage reaches 120-200MPa.
6. the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 1 and high anti-folding is characterized in that: contain in its goods or mullite crystal or corundum crystal or diopside crystal or enstatite crystal or wollastonite crystal or cordierite crystal or rutile crystal or forsterite crystal.
7. the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 1 and high anti-folding is characterized in that: the pattern that the three-dimensional space of its goods or top layer are made up of a kind or 2-10 kind color.
8. the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 1 and high anti-folding, it is characterized in that: the top layer of the extra-high-speed aluminosilicate sheet material of its described high impact-resistant and high anti-folding, the ornament layer that has one deck to form by the colored glaze of a kind or 2-10 kind color, and can also contain in the glaze of this layer ornament layer or quartz crystal or mullite crystal or corundum crystal or diopside crystal or wollastonite crystal or willemite crystal.
9. the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 1 and high anti-folding, it is characterized in that: the extra-high-speed aluminosilicate sheet material with described high impact-resistant and high anti-folding is surperficial sheet material, pass through bonding material layer, paste composition metal plate at its back side, can form the composite sheet of the trilaminate material of a kind of high impact-resistant and the high anti-extra-high-speed aluminosilicate sheet material of rolling over and bonding material layer and sheet metal.
10. the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 1 and high anti-folding, it is characterized in that: its described extra-high-speed aluminosilicate sheet material with high impact-resistant and high anti-folding is surperficial sheet material, pass through bonding material layer, the composite sheet that forms at its back side stickup composition metal plate, the distance that 10-30mm stretches out in the limit portion of the surface silicon hydrochlorate sheet material of the 2-4 bar limit proportion poststack of the metal sheet of its back of the body bottom surface.
11. the processing method of the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 1 and high anti-folding is characterized in that:
Count as weight percents, 1. alumina content at 16%-45% or 30%-45%, and 2. sodium oxide 6.1%-15%, 3. silicon oxide 35%-70%, 4. calcium oxide 10%-18%, 5. zinc oxide 0-10%, 6. magnesium oxide or select 5.5%-15% or select the silicate starting materials of the content of 8%-15% to prepare add or do not add tinting material by processing requirement;
On prescription, make softening point temperature: or be chosen as 700 ℃-890 ℃, perhaps be chosen as 890 ℃-1100 ℃, perhaps be chosen as 1000 ℃-1200 ℃;
To mix the raw material of forming then, put into resistant to elevated temperatures molten bath or smelting furnace, and, make above-mentioned raw materials all be molten into vitreous state through 1400 ℃ of-1600 ℃ of temperature or through 1600 ℃ of-1800 ℃ of temperature;
Enter the float glass process molding procedure again, promptly on the tin face of the molten tin bath that forms the flowable liquid molten body inflow of remollescent floating process, through drop down flat moulding, polish, draw thin, and edge machine is in the traction of drawing with tractor of leading of the direction of process stipulation, pull out molten tin bath, and after entering the cooling refrigerating work procedure of back segment,, promptly obtain transparent or painted a kind of high impact-resistant and high anti-extra-high-speed aluminosilicate board product of rolling over as the big plate of float glass through cutting.
12. the processing method of the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 11 and high anti-folding is characterized in that:
Step 1, count as weight percents, 1. alumina content at 16%-45% or 30%-45%, and 2. sodium oxide 6.1%-15%, 3. silicon oxide 35%-70%, 4. calcium oxide 10%-18%, 5. zinc oxide 0-10%, 6. magnesium oxide or select 5.5%-15% or select the silicate starting materials of the content of 8%-15% to prepare;
On prescription, make softening point temperature: or be chosen as 700 ℃-890 ℃, perhaps be chosen as 890 ℃-1100 ℃, perhaps be chosen as 1000 ℃-1200 ℃;
Step 2 has been mixed with 2-10 kind the colorful one batching respectively with the high temperature resistant chromogen material of 2-10 kind look respectively again with the raw material of above-mentioned preparation; Perhaps raw material of all kinds is adopted different fusing point prescriptions;
Step 3, the batching of each color of the 2-10 kind of step 2 adopted (1) or extrusion moulding, (2) or extrusion forming, (3) respectively or be broken into fritter grain, (4) again or be extruded into formulation, (5) or ceramic pattern process, (6) or ceramic free distributing technique that diameter is the filament strip of the long 15mm-500mm of 0.5mm-5mm, (7) or, make it each self-forming 0.1cm the loose raw material powder of different predetermined colors with extrusion device
3-0.2m
3Or 0.2m
3-1m
3The raw material body of volume is inserted on the transfer limes again;
Step 4, again with the formulation of the 2-10 kind look of step 3 by predetermined mixed, and the processing requirement of pressing selected softening temperature, this mixed preparing material is put into resistant to elevated temperatures same molten bath or smelting furnace, through 1400 ℃-1600 ℃ or 1600 ℃ of-1800 ℃ of high temperature, flow in the molten tin bath again, through dropping down flat moulding, polishing, draw thin, again through the effect of edge machine and tractor, pull out molten tin bath, after entering cooling zone and cutting area, formed predetermined 2-10 kind look or grain, or silk, or line, or long piece bar, or shape raw material such as bulk through softening and flow after changed, the extra-high-speed aluminosilicate board product of a kind of high impact-resistant and the high anti-folding of mobile pattern characteristic is arranged.
13. the processing method of the extra-high-speed aluminosilicate sheet material of a kind of high impact-resistant according to claim 11 and high anti-folding is characterized in that:
Step 1, count as weight percents, 1. alumina content at 16%-45% or 30%-45%, and 2. sodium oxide 6.1%-15%, 3. silicon oxide 35%-70%, 4. calcium oxide 10%-18%, 5. zinc oxide 0-10%, 6. magnesium oxide or select 5.5%-15% or select the silicate starting materials of the content of 8%-15% to prepare;
On prescription, softening point temperature is chosen as: 700 ℃-890 ℃, perhaps be chosen as 890 ℃-1100 ℃, perhaps be chosen as: 1000 ℃-1200 ℃;
Step 2 has been mixed with 2-10 kind the colorful one batching respectively with the high temperature resistant chromogen material of 2-10 kind look respectively again with the mixing raw material of above-mentioned preparation;
Step 3, select the material of the described 2-5 kind of step 2 look, respectively batching is made the less 2-5 kind look of volume or grain or piece, or adopt the raw material of micro mist pattern process that the insider knows, the small volume pattern characteristics that 2-5 kind look is arranged that free distributing technique was handled with 2-5 kind look; (calling small volume color lump formulation in the following text)
Step 4, the small volume color lump formulation that contains each color of 2-5 kind with step 3, requirement by the different large volume color lumps of predetermined 2-10 kind, adopt (1) or extrusion moulding, (2) or extrusion forming, (3) respectively or be broken into the fritter grain again or the material of piece or strip, formed not homochromy big or piece of the 2-10 kind of small volume color lump formulation of the 2-5 kind look that contains step 3 or bar or granulous large volume color lump material, (4) or, made it each self-forming 0.1cm the loose raw material powder of different predetermined colors
3-0.2m
3Or 0.2m
3-1m
3The raw material body of volume (calling large volume color lump formulation in the following text);
Step 5, again that the 2-10 kind of step 4 is not homochromy large volume color lump formulation, by predetermined mixed, and the processing requirement of pressing selected softening temperature, this mixed preparing material is put into resistant to elevated temperatures same molten bath or smelting furnace, through 1400 ℃-1600 ℃ or 1600 ℃ of-1800 ℃ of high temperature, flow in the molten tin bath, drop down flat moulding, polishing, draw thin, again through the effect of edge machine and tractor, pull out molten tin bath, and after entering cooling zone and cutting area, formed the piece of predetermined 2-10 kind look, bar, large volume shape pattern such as granular, and these pieces, bar, all contain the little of 2-5 kind color or grain in the granulous large volume pattern again respectively, or silk, or line, or long piece bar, or the small volume pattern of the shape of bulk, and after flowing in technology, each pattern has formed again and has changed to some extent, and the extra-high-speed aluminosilicate board product of a kind of high impact-resistant and the high anti-folding of mobile pattern characteristic is arranged.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010107103XA CN102070297A (en) | 2009-11-19 | 2010-02-09 | Extra-high aluminosilicate plate with high impact resistance and high bending resistance and process thereof |
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|---|---|---|---|
| CN200910194005 | 2009-11-19 | ||
| CN200910194005.1 | 2009-11-19 | ||
| CN201010107103XA CN102070297A (en) | 2009-11-19 | 2010-02-09 | Extra-high aluminosilicate plate with high impact resistance and high bending resistance and process thereof |
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| CN102070297A true CN102070297A (en) | 2011-05-25 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103304158A (en) * | 2012-03-13 | 2013-09-18 | 祝茂昌 | Process for producing silicate plate in molten metal forming tank by utilizing molten state slag |
| CN104843997A (en) * | 2015-06-01 | 2015-08-19 | 临沂市金立机械有限公司 | Tempered glass for electro-tricycles |
| CN104909551A (en) * | 2015-06-01 | 2015-09-16 | 临沂市金立机械有限公司 | Preparation process of tempered glass for electric four-wheelers |
| CN108516665A (en) * | 2018-03-15 | 2018-09-11 | 南安市创培电子科技有限公司 | A kind of lead-free electronic glass preparation method |
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2010
- 2010-02-09 CN CN201010107103XA patent/CN102070297A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103304158A (en) * | 2012-03-13 | 2013-09-18 | 祝茂昌 | Process for producing silicate plate in molten metal forming tank by utilizing molten state slag |
| CN104843997A (en) * | 2015-06-01 | 2015-08-19 | 临沂市金立机械有限公司 | Tempered glass for electro-tricycles |
| CN104909551A (en) * | 2015-06-01 | 2015-09-16 | 临沂市金立机械有限公司 | Preparation process of tempered glass for electric four-wheelers |
| CN108516665A (en) * | 2018-03-15 | 2018-09-11 | 南安市创培电子科技有限公司 | A kind of lead-free electronic glass preparation method |
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