WO2016021053A1 - Dust collection filter and dust collection device using same - Google Patents

Dust collection filter and dust collection device using same Download PDF

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Publication number
WO2016021053A1
WO2016021053A1 PCT/JP2014/071049 JP2014071049W WO2016021053A1 WO 2016021053 A1 WO2016021053 A1 WO 2016021053A1 JP 2014071049 W JP2014071049 W JP 2014071049W WO 2016021053 A1 WO2016021053 A1 WO 2016021053A1
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Prior art keywords
dust collection
collection filter
sample
filter
fume
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PCT/JP2014/071049
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French (fr)
Japanese (ja)
Inventor
水野 善之
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ユーエスウラサキ株式会社
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Priority to PCT/JP2014/071049 priority Critical patent/WO2016021053A1/en
Publication of WO2016021053A1 publication Critical patent/WO2016021053A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/16Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/52Particle separators, e.g. dust precipitators, using filters embodying folded corrugated or wound sheet material

Definitions

  • the present invention relates to a dust collecting filter and a dust collecting device using the dust collecting filter.
  • fume metal fume
  • a dust collector provided with a dust collection filter for collecting fume is known (refer to patent documents 1).
  • the dust attached to the dust collecting filter is removed by blowing pressurized air on the dust collecting filter or applying a mechanical force (for example, vibration) to the dust collecting filter. .
  • the conventional dust collector filter has the following problems.
  • the fume adhering to the dust collection filter contains a little oil component. For this reason, the fumes adhering to the dust collection filter cannot be easily separated from the dust collection filter by pressure air, vibration, or the like, and the fume removal work has become very complicated.
  • One aspect of the present invention is a dust collection filter for collecting fume, and the dust collection filter is made of a fiber having an oil-repellent coating layer formed on a surface thereof, and is formed of AATCC Test Method 118 (AATCC). : American Association of Textile Chemists and Colorists, American Textile Chemical Technology and Dyeing Technology Association) has oil repellency of 6th grade or higher, and JIS B 9927 (JIS: Japan Industrial Standards, rate for Japanese Industrial Standards) The dust collection filter is characterized in that the particle diameter is 0.3% or more.
  • the dust collection filter is composed of fibers having an oil-repellent coating layer formed on the surface.
  • the dust collection filter has characteristics (oil repellency, transmittance) according to the specific test method satisfying the specific conditions. Therefore, after the fume containing oil is collected by the dust collection filter, the adhered fume can be easily separated from the dust collection filter. Thereby, the operation
  • the dust collecting device includes the dust collecting filter. Therefore, after the fume containing oil is collected by the dust collection filter, the adhered fume can be easily separated from the dust collection filter. Thereby, the operation
  • the dust filter preferably has a zeta potential of ⁇ 10 mV or more.
  • the adhesion force of the fumes adhering to the fiber surface of the dust collection filter is reduced, and the fumes can be more easily separated from the dust collection filter.
  • work which removes a fume from a dust collection filter can be raised.
  • FIG. It is explanatory drawing which shows the structure of the dust collector in Embodiment 1.
  • FIG. It is explanatory drawing which shows the structure of the dust collection filter in Embodiment 1.
  • FIG. It is a schematic diagram which shows the fume collected by the conventional dust collection filter. It is a schematic diagram which shows the fume collected by the dust collection filter of Embodiment 1.
  • the dust collector 1 includes a dust collection filter 22 for collecting fumes.
  • the dust collection filter 22 is composed of fibers having an oil-repellent coating layer formed on the surface.
  • the dust collection filter 22 has an oil repellency according to AATCC Test Method 118 (hereinafter simply referred to as “oil repellency” as appropriate) of grade 6 or higher and a transmittance according to JIS B 9927 (hereinafter simply referred to as “transmittance” as appropriate).
  • the particle diameter of the test particles is 0.3 ⁇ m
  • the dust collector 1 and the dust collection filter 22 will be described in detail.
  • the dust collector 1 collects fine particles (hereinafter referred to as fume) in which metal vapor generated during metal processing (welding, fusing) using a laser processing machine is aggregated.
  • the dust collector 1 includes a housing 10 and the like.
  • the housing 10 is partitioned into a dust collection chamber 11, an intake chamber 13, an intermediate chamber 12 that connects the dust collection chamber 11 and the intake chamber 13, and the like.
  • a cylindrical duct 111 is disposed in the dust collection chamber 11.
  • the duct 111 connects the dust collection chamber 11 and the outside of the housing 10.
  • a collection unit 2 is disposed in the dust collection chamber 11.
  • the collection unit 2 collects fumes in the air (atmosphere) in the dust collection chamber 11 and removes the fumes in the air.
  • the direction of the arrow in the figure indicates the flow of air containing fume.
  • An intake fan 131 is disposed in the intake chamber 13.
  • the intake fan 131 guides air containing fume from the outside of the housing 10 into the dust collection chamber 11 through the duct 111.
  • the intermediate chamber 12 is formed between the dust collection chamber 11 and the intake chamber 13.
  • the collection unit 2 includes a cylindrical core member 21, a dust collection filter 22 folded in a bellows shape, and the like.
  • the collection part 2 is comprised by the substantially cylindrical shape.
  • a plurality of through holes 211 are formed in the metal core material 21.
  • the dust collection filter 22 is disposed so as to cover the outside of the core material 21. Details of the dust collection filter 22 will be described later.
  • the one end side in the axial direction of the dust collection filter 22 (core material 21) is closed by a closing body 23. For this reason, the air which passed the dust collection filter 22 distribute
  • air containing fume is guided into the dust collection chamber 11 through a duct 111 by an intake fan 131.
  • the air guided into the dust collection chamber 11 flows from the outside of the collection unit 2 toward the core member 21.
  • fumes are collected by the dust collection filter 22.
  • the fume collected by the dust collection filter 22 is accumulated on the outer peripheral surface side of the dust collection filter 22.
  • the air filtered by the dust collection filter 22 circulates in the core member 21 and is then discharged out of the housing 10 through the intermediate chamber 12 and the intake chamber 13.
  • the dust collection filter 22 is made of a long fiber nonwoven fabric.
  • the dust collection filter 22 of the present embodiment is composed of a spunbond nonwoven fabric (manufactured by Toray Industries Inc., polyester long fiber nonwoven fabric, G2260-1S).
  • a coating layer having oil repellency is formed on the surface of the fibers of the dust collection filter 22.
  • the dust collection filter 22 of this embodiment is a spunbonded nonwoven fabric that has been processed with a fluorine-based water and oil repellent (manufactured by Nikka Chemical, NK Guard S-09). That is, a coating layer made of a fluorine-based water and oil repellent is formed on the surface of the fibers of the dust collection filter 22.
  • the coating layer of this embodiment has water repellency and oil repellency.
  • the dust collection filter 22 has an oil repellency of 6 or higher according to the oil repellency test of AATCC Test Method 118. A detailed test method will be described later.
  • the dust collection filter 22 has a transmittance (test particle size of 0.3 ⁇ m) according to “Clean air filter performance test method” of JIS B 9927 of 70% or more. A detailed test method will be described later.
  • the dust filter 22 has a zeta potential (Z-potential) of ⁇ 10 mV or more on the surface thereof.
  • the zeta potential can be measured using, for example, a zeta potential measuring device.
  • a spunbond nonwoven fabric manufactured by Toray Industries, Inc., polyester long fiber nonwoven fabric: G2260-1S
  • the spunbonded nonwoven fabric has a size of 506 mm ⁇ 2800 mm.
  • the spunbonded nonwoven fabric has a pleated shape, a height of 35 mm, and a number of peaks of 40.
  • the spunbonded nonwoven fabric has a basis weight of 260 g / m 2 and a thickness of 0.62 mm.
  • the spunbonded nonwoven fabric is impregnated with a fluorine-based water and oil repellent (manufactured by Nikka Chemical Co., Ltd., NK Guard S-09).
  • the nonwoven fabric is immersed in the processing liquid (immersion time: 20 minutes).
  • the spunbonded nonwoven fabric is squeezed three times with a mangle (pressure: 34.2 kg / cm 2 , speed: 5 m / min). Thereafter, the spunbonded nonwoven fabric is dried at 130 ° C. for 1 minute and heat treated at 170 ° C. for 1 minute. Thereby, the dust collection filter 22 (refer FIG. 2) is produced.
  • the dust collection filter 22 of the present embodiment is composed of fibers having an oil-repellent coating layer formed on the surface.
  • the dust collection filter 22 has an oil repellency according to AATCC Test Method 118 of 6 or higher and a transmittance according to JIS B 9927 (particle diameter of test particles 0.3 ⁇ m) is 70% or higher.
  • FIG. 3 is a schematic diagram showing the fume 8 collected by the conventional dust collection filter 922.
  • FIG. 4 is a schematic diagram showing the fume 8 collected by the dust collection filter 22 of the present embodiment. 3 and 4 indicate the flow of air containing fume.
  • fumes having a relatively large particle diameter in which fumes having a relatively small particle diameter pass through the gaps of the fibers 221 and the particles are aggregated (81 82) is collected in the gaps of the fibers 221.
  • the fume 8 (81, 82) is collected to the position where it enters the inside from the surface 220 of the dust collection filter 922.
  • the fume 8 (83) blocked by the fume 8 (81, 82) collected in the gap between the fibers 221 is deposited on the surface 220 of the dust collection filter 922.
  • the fume 8 enters the inside from the surface 220 of the dust collection filter 922 and is collected. Therefore, the dust collection filter 922 is clogged by the fume 8, and the fume 8 cannot be easily separated from the dust collection filter 22. This makes it difficult to remove the fume 8 from the dust collection filter 22.
  • the dust collection filter 22 of the present embodiment in the initial stage, fumes having a relatively small particle diameter pass through the gaps of the fibers 221 and the particles are more aggregated.
  • the fumes 8 (81, 82) having a relatively large particle diameter are collected in the gaps between the fibers 221.
  • an oil-repellent coating layer is formed on the surface of the fiber 221, the oil-repellent function is high (oil repellency is 6th or higher), and the transmittance is also high (transmittance). 70% or more).
  • the fume 8 (81, 82) that has entered the dust collection filter 22 is less likely to adhere to the surface of the fiber 221 and easily passes through the gap between the fibers 221.
  • the fume 8 (81, 82) is collected near the surface 220 of the dust collection filter 922.
  • the fume 8 (83) blocked by the fume 8 (81, 82) collected in the gap between the fibers 221 is deposited on the surface 220 of the dust collection filter 922.
  • the fume 8 is collected at a position close to the surface 220 of the dust collection filter 22.
  • an oil-repellent coating layer is formed on the surface of the fiber 221 of the dust collection filter 22. Therefore, the fume 8 attached to the dust collection filter 22 can be easily separated from the dust collection filter 22. Thereby, the operation
  • the dust collection filter 22 of the present embodiment has a high transmittance of 70% or more.
  • the process in which the fume 8 is deposited and collected on the surface 220 of the dust collection filter 22 is a conventional process. Since it is the same as dust collection filter 922 (refer to Drawing 3 and Drawing 4), the collection function of fume 8 does not fall especially. That is, the dust collection filter 22 according to the present embodiment has a function of collecting the fume 8 and can easily remove the fume 8.
  • the dust collection filter 22 has a zeta potential of ⁇ 10 mV or more. Therefore, the adhesion force of the fume adhering to the fiber surface of the dust collection filter 22 is reduced, and the fume can be more easily separated from the dust collection filter 22. Thereby, the efficiency of the operation
  • Example 6 This experimental example is an example in which the characteristics of the dust collection filter of the present invention were evaluated.
  • a plurality of different types of dust collection filters (Sample 1 to Sample 7) were prepared or produced.
  • a dust collection filter (sample 6, sample 7) as an example of the present invention and a dust collection filter (sample 1 to sample 5) as comparative examples were prepared or produced.
  • various evaluation was performed about each sample. Below, the kind and evaluation method of each sample are demonstrated.
  • Sample 1 is a spunbond nonwoven fabric (manufactured by Toray Industries, Inc., polyester long fiber nonwoven fabric: G2260-1S).
  • Sample 2 is a water-repellent spunbond nonwoven fabric (manufactured by Toray Industries, Inc., polyester long fiber nonwoven fabric: G2260-TR).
  • Sample 3 is a spunbond nonwoven fabric (polyester long fiber nonwoven fabric: G2260-TF manufactured by Toray Industries, Inc.) laminated with a PTFE (polytetrafluoroethylene) membrane.
  • PTFE polytetrafluoroethylene
  • Sample 4 is a CVD treatment of cyclic silane 1,3,5,7-tetramethylcyclotetrasiloxane (D 4 H ) on the spunbond nonwoven fabric of sample 1 (polyester long fiber nonwoven fabric: G2260-1S manufactured by Toray Industries, Inc.) And water repellent finish.
  • D 4 H cyclic silane 1,3,5,7-tetramethylcyclotetrasiloxane
  • Sample 5 is obtained by subjecting the spunbond nonwoven fabric of Sample 1 (manufactured by Toray Industries, Inc., polyester long fiber nonwoven fabric: G2260-1S) to oil-repellent processing. Specifically, cyclic silane 1,3,5,7-tetramethylcyclotetrasiloxane (D 4 H ) is subjected to CVD treatment on the spunbonded nonwoven fabric to make the surface water repellent. Next, the surface is hydrophilized by vacuum plasma. Thereafter, heptadecafluoro-1,1,2,2-trimethoxysilane (FAS17) is subjected to CVD treatment to make the surface oil repellent. Hydrophilization may use methods such as ozone microbubbles and ultraviolet irradiation instead of vacuum plasma.
  • Sample 6 is a water- and oil-repellent finish using a fluorine-based water- and oil-repellent agent (manufactured by Nikka Chemical Co., Ltd., NK Guard S-09) for a spunbonded nonwoven fabric (manufactured by Toray, polyester long-fiber nonwoven fabric, G2200-1S). Is given.
  • the spunbonded nonwoven fabric has a basis weight of 200 g / m 2 and a thickness of 0.54 mm.
  • the size and shape of the spunbonded nonwoven fabric are the same as those in the first embodiment.
  • the water / oil repellent treatment was performed in the same manner as in the first embodiment.
  • Sample 7 is the same as the dust collection filter of Embodiment 1 described above, and is a fluorine-based water and oil repellent (Nikka Chemical Co., Ltd.) for a spunbonded nonwoven fabric (manufactured by Toray Industries, polyester long fiber nonwoven fabric, G2260-1S). Manufactured by NK Guard S-09).
  • oil repellency was evaluated according to AATCC Test Method 118 (1997). Specifically, nine hydrocarbon solvents having different surface tensions shown below were dropped on a sample (dust collection filter), and it was visually determined whether or not each solvent permeates (wetability). And among each solvent, it was a solvent which does not osmose
  • the evaluation criteria for oil repellency are as follows.
  • test particles DOP (dioctyl phthalate, Class 4 Class 4 Petroleum) was used.
  • the particle size of the test particles was 0.3 ⁇ m.
  • permeability P (%) was computed using the following formula
  • ⁇ Ventilation resistance> A dust collection filter of each sample (excluding sample 4) was attached to a dust collector having the same configuration as that of Embodiment 1, and dust collection was performed for one week. Next, mechanical dusting was performed on the dust collecting filter to which the fumes adhered. Next, air was passed through the dust collection filter after the dust was removed, and the pressure difference ⁇ P (Pa) between the upstream side and the downstream side of the dust collection filter was measured. And ventilation resistance R (Pa * s / m) was computed using the following formula
  • ⁇ X-ray CT analysis> A dust collection filter for each sample (only sample 1 and sample 7) was attached to a dust collector having the same configuration as that of the first embodiment, and dust collection was performed for one week. Next, the dust collecting filter to which the fumes adhered was analyzed by X-ray CT (manufactured by Shimadzu Corporation, microfocus X-ray CT apparatus: SMX-160LT).
  • Table 1 shows the result of the characteristic evaluation of each sample.
  • Sample 1 Sample 3 and Sample 4 which are comparative examples had an oil repellency of less than grade 6 and a transmittance of less than 70%.
  • the transmittance of Sample 3 was very low compared to other samples.
  • Samples 1 to 5 had a zeta potential of less than ⁇ 10 mV.
  • Sample 6 and Sample 7 which are examples of the present invention, had oil repellency of grade 6 or higher and transmittance of 70% or higher. Samples 6 and 7 had a zeta potential of ⁇ 10 mV or higher.
  • Sample 6 and Sample 7 which are examples of the present invention have lower values of ventilation resistance than Samples 1 to 3 and Sample 5 which are comparative examples.
  • Sample 7 when compared with the ventilation resistance before dust collection (sample 1 and sample 7 are 1.33 kPa ⁇ s / m, sample 6 is 0.91 kPa ⁇ s / m),
  • Sample 7 an increase in the ventilation resistance is suppressed as compared with Sample 1 which is a comparative example.
  • the airflow resistance of the sample 4 is not obtained, but the results are the same as those of the other comparative examples (samples 1 to 3 and sample 5).
  • Sample 1 Sample 2, and Sample 5 are clogged by fume because fume enters inside from the surface of the dust collection filter and is collected.
  • Sample 3 is considered to be clogged with fume in the PTFE membrane laminated on the surface of the dust collection filter.
  • Sample 6 and Sample 7 since the fumes are collected at a position close to the surface of the dust collection filter, the attached fumes can be easily removed from the dust collection filter, and clogging by the fumes is suppressed. Conceivable.
  • FIGS. 5 to 10 are SEM photographs of Sample 1, Sample 2, Sample 3, Sample 5, Sample 6, and Sample 7, respectively. Only the SEM photograph of sample 5 (FIG. 7) has a magnification of 100 times, and the SEM photographs of other samples have a magnification of 40 times.
  • the sample 1, sample 2, and sample 5 which are comparative examples, have fumes remaining in the gaps between the fibers of the dust collection filter after being removed, and clogging due to the fumes has occurred. It was happening. Further, as shown in FIG. 7, in the sample 3 as a comparative example, the fumes remained adhered to the PTFE membrane laminated on the surface of the dust collecting filter, and the fume was clogged in the PTFE membrane.
  • the sample 6 and the sample 7 according to the embodiment of the present invention have almost no fumes remaining in the gaps between the fibers of the dust collection filter after being removed, and are clogged by the fumes. Was suppressed.
  • FIG. 11 it can be seen that the sample 1 as a comparative example has fume F entering the inside (from the bottom of the surface S1 in the figure) of the dust collection filter S1 and being collected. The result is the same as the schematic diagram shown in FIG.
  • the sample 7 which is an embodiment of the present invention has an extremely large amount of fumes F collected inside the dust collection surface S7 from the inside (the lower side of the surface S7 in the figure). Very few. The result is the same as the schematic diagram shown in FIG. Therefore, the attached fume F can be easily removed from the dust collection filter.
  • the dust collecting filter of the present invention has an oil repellency of 6 grade or higher and a transmittance of 70% or higher, so that the attached fume can be easily removed. Further, it was found that the zeta potential is preferably ⁇ 10 mV or more in the dust collection filter of the present invention.
  • the spunbonded nonwoven fabric is used as the material (filter material) constituting the dust collection filter in the above-described embodiment and the like, other known filter materials may be used.
  • the shape of the dust collection filter is a pleated shape, but other shapes (for example, a bug shape) may be used.
  • an impregnation method for impregnating an oil repellent was used as an oil repellent method for the dust collection filter.
  • other known processing methods for example, spray processing method, CVD, etc.
  • a processing method or the like may be used.

Abstract

A dust collection filter for collecting fumes is constituted of a fiber having an oil repelling coating layer formed on the surface thereof. The dust collection filter has oil repellency of grade 6 or greater according to AATCCT Test Method 118, and transmittance of 70% or greater according to JIS B 9927 (particle size of 0.3 µm for test particles).

Description

集塵フィルタ及びそれを用いた集塵装置Dust collection filter and dust collector using the same
 本発明は、集塵フィルタ及びそれを用いた集塵装置に関する。 The present invention relates to a dust collecting filter and a dust collecting device using the dust collecting filter.
 例えば、レーザ加工機等を用いた金属加工(溶接、溶断等)の際には、金属蒸気が凝集して微細な粒子となった、いわゆるヒューム(金属ヒューム)が発生する。従来、ヒュームを捕集するための集塵フィルタを備えた集塵装置が知られている(特許文献1参照)。このような集塵装置では、集塵フィルタに圧力空気を吹き付けたり、集塵フィルタに機械的な力(例えば振動等)を与えたりして、集塵フィルタに付着したヒュームの払落し作業を行う。 For example, during metal processing (welding, fusing, etc.) using a laser processing machine or the like, so-called fume (metal fume) is generated in which metal vapor is aggregated into fine particles. Conventionally, a dust collector provided with a dust collection filter for collecting fume is known (refer to patent documents 1). In such a dust collecting device, the dust attached to the dust collecting filter is removed by blowing pressurized air on the dust collecting filter or applying a mechanical force (for example, vibration) to the dust collecting filter. .
特開2009-106945号公報JP 2009-106945 A
 しかしながら、従来の集塵装置の集塵フィルタでは、次のような問題があった。集塵フィルタに付着したヒュームには、少なからず油成分が含まれている。そのため、集塵フィルタに付着したヒュームを圧力空気や振動等によって集塵フィルタから容易に分離させることができず、ヒュームの払落し作業が非常に煩雑となっていた。 However, the conventional dust collector filter has the following problems. The fume adhering to the dust collection filter contains a little oil component. For this reason, the fumes adhering to the dust collection filter cannot be easily separated from the dust collection filter by pressure air, vibration, or the like, and the fume removal work has become very complicated.
 したがって、付着したヒュームの払落し作業が容易である集塵フィルタ及びそれを用いた集塵装置を提供することが望ましい。 Therefore, it is desirable to provide a dust collection filter and a dust collection apparatus using the dust collection filter that can easily dispose of adhering fume.
 本発明の一の態様は、ヒュームを捕集するための集塵フィルタであって、該集塵フィルタは、表面に撥油性の被覆層が形成された繊維により構成され、AATCC Test Method 118(AATCC:American Association of Textile Chemists and Colorists、アメリカ繊維化学技術・染色技術協会)による撥油性が6級以上であり、かつ、JIS B 9927(JIS:Japan Industrial Standards、日本工業規格)による透過率(試験用粒子の粒径0.3μm)が70%以上であることを特徴とする集塵フィルタである。 One aspect of the present invention is a dust collection filter for collecting fume, and the dust collection filter is made of a fiber having an oil-repellent coating layer formed on a surface thereof, and is formed of AATCC Test Method 118 (AATCC). : American Association of Textile Chemists and Colorists, American Textile Chemical Technology and Dyeing Technology Association) has oil repellency of 6th grade or higher, and JIS B 9927 (JIS: Japan Industrial Standards, rate for Japanese Industrial Standards) The dust collection filter is characterized in that the particle diameter is 0.3% or more.
 前記集塵フィルタは、表面に撥油性の被覆層が形成された繊維により構成されている。集塵フィルタは、前記特定の試験方法による特性(撥油性、透過率)が前記特定の条件を満たしている。そのため、油分を含むヒュームを集塵フィルタで捕集した後、付着したヒュームを集塵フィルタから容易に分離させることができる。これにより、集塵フィルタからヒュームを払い落とす作業が容易となる。 The dust collection filter is composed of fibers having an oil-repellent coating layer formed on the surface. The dust collection filter has characteristics (oil repellency, transmittance) according to the specific test method satisfying the specific conditions. Therefore, after the fume containing oil is collected by the dust collection filter, the adhered fume can be easily separated from the dust collection filter. Thereby, the operation | work which wipes off a fume from a dust collection filter becomes easy.
 本発明の他の態様は、前記集塵フィルタを備えていることを特徴とする集塵装置である。
 前記集塵装置は、前記集塵フィルタを備えている。そのため、油分を含むヒュームを集塵フィルタで捕集した後、付着したヒュームを集塵フィルタから容易に分離させることができる。これにより、集塵フィルタからヒュームを払い落とす作業が容易となる。
Another aspect of the present invention is a dust collecting apparatus including the dust collecting filter.
The dust collecting device includes the dust collecting filter. Therefore, after the fume containing oil is collected by the dust collection filter, the adhered fume can be easily separated from the dust collection filter. Thereby, the operation | work which wipes off a fume from a dust collection filter becomes easy.
 このように、付着したヒュームの払落し作業が容易である集塵フィルタ及びそれを用いた集塵装置を提供することができる。
 また、前記集塵フィルタにおいて、該集塵フィルタは、ゼータ電位が-10mV以上であることが好ましい。この場合には、集塵フィルタの繊維の表面に付着するヒュームの付着力が小さくなり、ヒュームを集塵フィルタからさらに容易に分離させることができる。これにより、集塵フィルタからヒュームを払い落とす作業の効率を上げることができる。
In this way, it is possible to provide a dust collection filter that facilitates the removal of attached fume and a dust collector using the same.
In the dust filter, the dust filter preferably has a zeta potential of −10 mV or more. In this case, the adhesion force of the fumes adhering to the fiber surface of the dust collection filter is reduced, and the fumes can be more easily separated from the dust collection filter. Thereby, the efficiency of the operation | work which removes a fume from a dust collection filter can be raised.
実施形態1における、集塵装置の構造を示す説明図である。It is explanatory drawing which shows the structure of the dust collector in Embodiment 1. FIG. 実施形態1における、集塵フィルタの構造を示す説明図である。It is explanatory drawing which shows the structure of the dust collection filter in Embodiment 1. FIG. 従来の集塵フィルタに捕集されたヒュームを示す模式図である。It is a schematic diagram which shows the fume collected by the conventional dust collection filter. 実施形態1の集塵フィルタに捕集されたヒュームを示す模式図である。It is a schematic diagram which shows the fume collected by the dust collection filter of Embodiment 1. 実験例における、試料1の集塵フィルタのSEM写真である。It is a SEM photograph of the dust collection filter of sample 1 in an experimental example. 実験例における、試料2の集塵フィルタのSEM写真である。It is a SEM photograph of the dust collection filter of sample 2 in an experimental example. 実験例における、試料3の集塵フィルタのSEM写真である。It is a SEM photograph of the dust collection filter of sample 3 in an experimental example. 実験例における、試料5の集塵フィルタのSEM写真である。It is a SEM photograph of the dust collection filter of sample 5 in an experimental example. 実験例における、試料6の集塵フィルタのSEM写真である。It is a SEM photograph of the dust collection filter of sample 6 in an experimental example. 実験例における、試料7の集塵フィルタのSEM写真である。It is a SEM photograph of the dust collection filter of sample 7 in an experimental example. 実験例における、試料1の集塵フィルタのX線CTによるヒュームの解析結果を示す図である。It is a figure which shows the analysis result of the fume by X-ray CT of the dust collection filter of the sample 1 in an experiment example. 実験例における、試料7の集塵フィルタのX線CTによるヒュームの解析結果を示す図である。It is a figure which shows the analysis result of the fume by X-ray CT of the dust collection filter of the sample 7 in an experiment example.
 1…集塵装置
 22…集塵フィルタ
1 ... Dust collector 22 ... Dust collector filter
 以下、本発明の実施形態を図面と共に説明する。
 (実施形態1)
 図1、図2に示すように、集塵装置1は、ヒュームを捕集するための集塵フィルタ22を備えている。集塵フィルタ22は、表面に撥油性の被覆層が形成された繊維により構成されている。集塵フィルタ22は、AATCC Test Method 118による撥油性(以下、適宜、単に撥油性という。)が6級以上であり、かつ、JIS B 9927による透過率(以下、適宜、単に透過率という。)(試験用粒子の粒径0.3μm)が70%以上である。以下、集塵装置1及び集塵フィルタ22を詳細に説明する。
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
(Embodiment 1)
As shown in FIGS. 1 and 2, the dust collector 1 includes a dust collection filter 22 for collecting fumes. The dust collection filter 22 is composed of fibers having an oil-repellent coating layer formed on the surface. The dust collection filter 22 has an oil repellency according to AATCC Test Method 118 (hereinafter simply referred to as “oil repellency” as appropriate) of grade 6 or higher and a transmittance according to JIS B 9927 (hereinafter simply referred to as “transmittance” as appropriate). (The particle diameter of the test particles is 0.3 μm) is 70% or more. Hereinafter, the dust collector 1 and the dust collection filter 22 will be described in detail.
 図1に示すように、集塵装置1は、レーザ加工機を用いた金属加工(溶接、溶断)の際に発生する金属蒸気が凝集した微細な粒子(以下、ヒュームという。)を捕集する装置である。集塵装置1は、筐体10等を備えている。筐体10内は、集塵室11、吸気室13、集塵室11と吸気室13とを繋ぐ中間室12等に区画されている。 As shown in FIG. 1, the dust collector 1 collects fine particles (hereinafter referred to as fume) in which metal vapor generated during metal processing (welding, fusing) using a laser processing machine is aggregated. Device. The dust collector 1 includes a housing 10 and the like. The housing 10 is partitioned into a dust collection chamber 11, an intake chamber 13, an intermediate chamber 12 that connects the dust collection chamber 11 and the intake chamber 13, and the like.
 集塵室11には、筒状のダクト111が配設されている。ダクト111は、集塵室11と筐体10外とを繋いでいる。集塵室11内には、捕集部2が配設されている。捕集部2は、集塵室11内の空気(雰囲気)中のヒュームを捕集し、その空気中のヒュームを除去する。同図の矢印の方向は、ヒュームを含む空気の流れを示している。 In the dust collection chamber 11, a cylindrical duct 111 is disposed. The duct 111 connects the dust collection chamber 11 and the outside of the housing 10. A collection unit 2 is disposed in the dust collection chamber 11. The collection unit 2 collects fumes in the air (atmosphere) in the dust collection chamber 11 and removes the fumes in the air. The direction of the arrow in the figure indicates the flow of air containing fume.
 吸気室13には、吸気ファン131が配設されている。吸気ファン131は、ヒュームを含む空気を筐体10外からダクト111を介して集塵室11内に導く。中間室12は、集塵室11と吸気室13との間に形成されている。 An intake fan 131 is disposed in the intake chamber 13. The intake fan 131 guides air containing fume from the outside of the housing 10 into the dust collection chamber 11 through the duct 111. The intermediate chamber 12 is formed between the dust collection chamber 11 and the intake chamber 13.
 図2に示すように、捕集部2は、円筒状の芯材21、蛇腹状に折り畳まれた集塵フィルタ22等を有する。捕集部2は、略円筒状に構成されている。金属製の芯材21には、複数の貫通孔211が形成されている。集塵フィルタ22は、芯材21の外側を覆うように配設されている。集塵フィルタ22の詳細は後述する。 As shown in FIG. 2, the collection unit 2 includes a cylindrical core member 21, a dust collection filter 22 folded in a bellows shape, and the like. The collection part 2 is comprised by the substantially cylindrical shape. A plurality of through holes 211 are formed in the metal core material 21. The dust collection filter 22 is disposed so as to cover the outside of the core material 21. Details of the dust collection filter 22 will be described later.
 集塵フィルタ22(芯材21)の軸方向一端側は、閉塞体23により閉塞されている。このため、集塵フィルタ22を通過した空気は、集塵フィルタ22(芯材21)内を軸方向一端側から他端側に向けて流通する。 The one end side in the axial direction of the dust collection filter 22 (core material 21) is closed by a closing body 23. For this reason, the air which passed the dust collection filter 22 distribute | circulates the inside of the dust collection filter 22 (core material 21) toward the other end side from the axial direction one end side.
 図1に示すように、ヒュームを含む空気は、吸気ファン131によりダクト111を介して集塵室11内に導かれる。集塵室11内に導かれた空気は、捕集部2の外側から芯材21に向けて流れる。その空気が集塵フィルタ22を通過する際に、ヒュームが集塵フィルタ22に捕集される。 As shown in FIG. 1, air containing fume is guided into the dust collection chamber 11 through a duct 111 by an intake fan 131. The air guided into the dust collection chamber 11 flows from the outside of the collection unit 2 toward the core member 21. When the air passes through the dust collection filter 22, fumes are collected by the dust collection filter 22.
 集塵フィルタ22に捕集されたヒュームは、集塵フィルタ22の外周面側に蓄積される。一方、集塵フィルタ22にて濾過された空気は、芯材21内を流通した後、中間室12及び吸気室13を介して筐体10外に排出される。 The fume collected by the dust collection filter 22 is accumulated on the outer peripheral surface side of the dust collection filter 22. On the other hand, the air filtered by the dust collection filter 22 circulates in the core member 21 and is then discharged out of the housing 10 through the intermediate chamber 12 and the intake chamber 13.
 次に、集塵フィルタ22について説明する。
 集塵フィルタ22は、長繊維不織布により構成されている。本実施形態の集塵フィルタ22は、スパンボンド不織布(東レ社製、ポリエステル長繊維不織布、G2260-1S)により構成されている。
Next, the dust collection filter 22 will be described.
The dust collection filter 22 is made of a long fiber nonwoven fabric. The dust collection filter 22 of the present embodiment is composed of a spunbond nonwoven fabric (manufactured by Toray Industries Inc., polyester long fiber nonwoven fabric, G2260-1S).
 集塵フィルタ22の繊維の表面には、撥油性を有する被覆層が形成されている。本実施形態の集塵フィルタ22は、スパンボンド不織布に対してフッ素系撥水撥油剤(日華化学製、NKガード S-09)による加工処理が施されたものである。すなわち、集塵フィルタ22の繊維の表面には、フッ素系撥水撥油剤による被覆層が形成されている。本実施形態の被覆層は、撥水性、撥油性を有している。 A coating layer having oil repellency is formed on the surface of the fibers of the dust collection filter 22. The dust collection filter 22 of this embodiment is a spunbonded nonwoven fabric that has been processed with a fluorine-based water and oil repellent (manufactured by Nikka Chemical, NK Guard S-09). That is, a coating layer made of a fluorine-based water and oil repellent is formed on the surface of the fibers of the dust collection filter 22. The coating layer of this embodiment has water repellency and oil repellency.
 集塵フィルタ22は、AATCC Test Method 118の撥油性試験による撥油性が6級以上である。詳細な試験方法については後述する。
 集塵フィルタ22は、JIS B 9927の「クリーンルーム用エアフィルター性能試験方法」による透過率(試験用粒子の粒径0.3μm)が70%以上である。詳細な試験方法については後述する。
The dust collection filter 22 has an oil repellency of 6 or higher according to the oil repellency test of AATCC Test Method 118. A detailed test method will be described later.
The dust collection filter 22 has a transmittance (test particle size of 0.3 μm) according to “Clean air filter performance test method” of JIS B 9927 of 70% or more. A detailed test method will be described later.
 集塵フィルタ22は、その表面のゼータ電位(Z-potential)が-10mV以上である。ゼータ電位は、例えば、ゼータ電位測定装置を用いて測定することができる。 The dust filter 22 has a zeta potential (Z-potential) of −10 mV or more on the surface thereof. The zeta potential can be measured using, for example, a zeta potential measuring device.
 次に、集塵フィルタ22の作製方法について説明する。
 まず、スパンボンド不織布(東レ社製、ポリエステル長繊維不織布:G2260-1S)を準備する。スパンボンド不織布は、サイズが506mm×2800mmである。スパンボンド不織布は、プリーツ形状であり、山高が35mm、山数が40である。スパンボンド不織布は、目付が260g/m2、厚みが0.62mmである。
Next, a method for producing the dust collection filter 22 will be described.
First, a spunbond nonwoven fabric (manufactured by Toray Industries, Inc., polyester long fiber nonwoven fabric: G2260-1S) is prepared. The spunbonded nonwoven fabric has a size of 506 mm × 2800 mm. The spunbonded nonwoven fabric has a pleated shape, a height of 35 mm, and a number of peaks of 40. The spunbonded nonwoven fabric has a basis weight of 260 g / m 2 and a thickness of 0.62 mm.
 次いで、スパンボンド不織布をフッ素系撥水撥油剤(日華化学社製、NKガード S-09)に含浸させる。具体的には、フッ素系撥水撥油剤をパッド処理で8%に希釈した加工液(純水:フッ素系撥水撥油剤=100:8)を作製する。その加工液に不織布を浸漬する(浸漬時間:20分)。 Next, the spunbonded nonwoven fabric is impregnated with a fluorine-based water and oil repellent (manufactured by Nikka Chemical Co., Ltd., NK Guard S-09). Specifically, a processing liquid (pure water: fluorine water / oil repellent = 100: 8) is prepared by diluting a fluorine water / oil repellent to 8% by pad treatment. The nonwoven fabric is immersed in the processing liquid (immersion time: 20 minutes).
 次いで、スパンボンド不織布をマングルにて3回絞る(圧力:34.2kg/cm2、速度:5m/分)。その後、スパンボンド不織布を130℃、1分の条件で乾燥させ、170℃、1分の条件で熱処理する。これにより、集塵フィルタ22(図2参照)を作製する。 Next, the spunbonded nonwoven fabric is squeezed three times with a mangle (pressure: 34.2 kg / cm 2 , speed: 5 m / min). Thereafter, the spunbonded nonwoven fabric is dried at 130 ° C. for 1 minute and heat treated at 170 ° C. for 1 minute. Thereby, the dust collection filter 22 (refer FIG. 2) is produced.
 次に、本実施形態の作用効果について説明する。
 本実施形態の集塵フィルタ22は、表面に撥油性の被覆層が形成された繊維により構成されている。集塵フィルタ22は、AATCC Test Method 118による撥油性が6級以上であり、かつ、JIS B 9927による透過率(試験用粒子の粒径0.3μm)が70%以上である。
Next, the effect of this embodiment is demonstrated.
The dust collection filter 22 of the present embodiment is composed of fibers having an oil-repellent coating layer formed on the surface. The dust collection filter 22 has an oil repellency according to AATCC Test Method 118 of 6 or higher and a transmittance according to JIS B 9927 (particle diameter of test particles 0.3 μm) is 70% or higher.
 そのため、油分を含むヒュームを集塵フィルタ22で捕集した後、付着したヒュームを集塵フィルタ22から容易に分離させることができる。これにより、集塵フィルタ22からヒュームを払い落とす作業が容易となる。また、集塵フィルタ22を備えた集塵装置1も同様の効果が得られる。 Therefore, after the fume containing oil is collected by the dust collection filter 22, the attached fume can be easily separated from the dust collection filter 22. Thereby, the operation | work which removes a fume from the dust collection filter 22 becomes easy. Moreover, the same effect is acquired also in the dust collector 1 provided with the dust filter 22.
 前述の作用効果が得られる理由は、次のように推測される。図3は、従来の集塵フィルタ922に捕集されたヒューム8を示す模式図である。図4は、本実施形態の集塵フィルタ22に捕集されたヒューム8を示す模式図である。図3、図4の矢印の方向は、ヒュームを含む空気の流れを示している。 The reason why the above-mentioned action and effect can be obtained is estimated as follows. FIG. 3 is a schematic diagram showing the fume 8 collected by the conventional dust collection filter 922. FIG. 4 is a schematic diagram showing the fume 8 collected by the dust collection filter 22 of the present embodiment. 3 and 4 indicate the flow of air containing fume.
 図3に示すように、従来の集塵フィルタ922では、初期の段階において、比較的粒径の小さいヒュームが繊維221の隙間を通過し、粒子が凝集した比較的粒径の大きいヒューム8(81、82)が繊維221の隙間に捕集される。このとき、ヒューム8(81、82)が集塵フィルタ922の表面220から内側に入り込んだ位置まで捕集される。その後、繊維221の隙間に捕集されたヒューム8(81、82)に遮られたヒューム8(83)が集塵フィルタ922の表面220上に堆積する。 As shown in FIG. 3, in the conventional dust collection filter 922, in the initial stage, fumes having a relatively large particle diameter in which fumes having a relatively small particle diameter pass through the gaps of the fibers 221 and the particles are aggregated (81 82) is collected in the gaps of the fibers 221. At this time, the fume 8 (81, 82) is collected to the position where it enters the inside from the surface 220 of the dust collection filter 922. Thereafter, the fume 8 (83) blocked by the fume 8 (81, 82) collected in the gap between the fibers 221 is deposited on the surface 220 of the dust collection filter 922.
 このように、従来の集塵フィルタ922では、ヒューム8が集塵フィルタ922の表面220から内側に入り込んで捕集される。そのため、ヒューム8によって集塵フィルタ922に目詰まりが生じ、ヒューム8を集塵フィルタ22から容易に分離させることができない。これにより、集塵フィルタ22からヒューム8を払い落とす作業が困難となる。 Thus, in the conventional dust collection filter 922, the fume 8 enters the inside from the surface 220 of the dust collection filter 922 and is collected. Therefore, the dust collection filter 922 is clogged by the fume 8, and the fume 8 cannot be easily separated from the dust collection filter 22. This makes it difficult to remove the fume 8 from the dust collection filter 22.
 一方、図4に示すように、本実施形態の集塵フィルタ22では、初期の段階において、比較的粒径の小さいヒュームが繊維221の隙間を通過し、粒子がより凝集して形成されたヒュームであって比較的粒径の大きいヒューム8(81、82)が繊維221の隙間に捕集される。ここで、本実施形態の集塵フィルタ22は、繊維221の表面に撥油性の被覆層が形成され、その撥油機能が高く(撥油性が6級以上)、さらに透過率も高い(透過率が70%以上)。そのため、集塵フィルタ22内部に入り込んだヒューム8(81、82)が繊維221の表面に付着しにくく、繊維221の隙間を通過しやすい。その結果、ヒューム8(81、82)が集塵フィルタ922の表面220付近で捕集される。その後、繊維221の隙間に捕集されたヒューム8(81、82)に遮られたヒューム8(83)が集塵フィルタ922の表面220上に堆積する。 On the other hand, as shown in FIG. 4, in the dust collection filter 22 of the present embodiment, in the initial stage, fumes having a relatively small particle diameter pass through the gaps of the fibers 221 and the particles are more aggregated. In addition, the fumes 8 (81, 82) having a relatively large particle diameter are collected in the gaps between the fibers 221. Here, in the dust collection filter 22 of the present embodiment, an oil-repellent coating layer is formed on the surface of the fiber 221, the oil-repellent function is high (oil repellency is 6th or higher), and the transmittance is also high (transmittance). 70% or more). Therefore, the fume 8 (81, 82) that has entered the dust collection filter 22 is less likely to adhere to the surface of the fiber 221 and easily passes through the gap between the fibers 221. As a result, the fume 8 (81, 82) is collected near the surface 220 of the dust collection filter 922. Thereafter, the fume 8 (83) blocked by the fume 8 (81, 82) collected in the gap between the fibers 221 is deposited on the surface 220 of the dust collection filter 922.
 このように、本実施形態の集塵フィルタ22では、ヒューム8が集塵フィルタ22の表面220に近い位置で捕集される。また、集塵フィルタ22の繊維221の表面に撥油性を有する被覆層を形成している。そのため、集塵フィルタ22に付着したヒューム8を集塵フィルタ22から容易に分離させることができる。これにより、集塵フィルタ22からヒューム8を払い落とす作業が容易となる。 Thus, in the dust collection filter 22 of the present embodiment, the fume 8 is collected at a position close to the surface 220 of the dust collection filter 22. In addition, an oil-repellent coating layer is formed on the surface of the fiber 221 of the dust collection filter 22. Therefore, the fume 8 attached to the dust collection filter 22 can be easily separated from the dust collection filter 22. Thereby, the operation | work which wipes off the fume 8 from the dust collection filter 22 becomes easy.
 また、前述のとおり、本実施形態の集塵フィルタ22は、透過率が70%以上と高いが、ヒューム8が集塵フィルタ22の表面220上に堆積して捕集される過程は、従来の集塵フィルタ922と同じであるため(図3、図4参照)、ヒューム8の捕集機能が特段低下することはない。つまり、本実施形態の集塵フィルタ22は、ヒューム8の捕集機能を十分に有していながら、ヒューム8の払落し作業が容易である。 Further, as described above, the dust collection filter 22 of the present embodiment has a high transmittance of 70% or more. However, the process in which the fume 8 is deposited and collected on the surface 220 of the dust collection filter 22 is a conventional process. Since it is the same as dust collection filter 922 (refer to Drawing 3 and Drawing 4), the collection function of fume 8 does not fall especially. That is, the dust collection filter 22 according to the present embodiment has a function of collecting the fume 8 and can easily remove the fume 8.
 また、本実施形態において、集塵フィルタ22は、ゼータ電位が-10mV以上である。そのため、集塵フィルタ22の繊維の表面に付着するヒュームの付着力が小さくなり、ヒュームを集塵フィルタ22からさらに容易に分離させることができる。これにより、集塵フィルタ22からヒュームを払い落とす作業の効率を上げることができる。 In this embodiment, the dust collection filter 22 has a zeta potential of −10 mV or more. Therefore, the adhesion force of the fume adhering to the fiber surface of the dust collection filter 22 is reduced, and the fume can be more easily separated from the dust collection filter 22. Thereby, the efficiency of the operation | work which removes a fume from the dust collection filter 22 can be raised.
 このように、本実施形態によれば、ヒュームを捕集した後、付着したヒュームの払落し作業が容易である集塵フィルタ22及びそれを用いた集塵装置1を提供することができる。 As described above, according to this embodiment, it is possible to provide the dust collection filter 22 and the dust collector 1 using the dust collection filter 22 that can easily remove the attached fume after collecting the fumes.
 (実験例)
 本実験例は、本発明の集塵フィルタの特性を評価した例である。
 本実験例では、種類の異なる複数の集塵フィルタ(試料1~試料7)を準備又は作製した。具体的には、本発明の実施例である集塵フィルタ(試料6、試料7)と比較例である集塵フィルタ(試料1~試料5)とを準備又は作製した。そして、各試料について各種評価した。以下に、各試料の種類及び評価方法を説明する。
(Experimental example)
This experimental example is an example in which the characteristics of the dust collection filter of the present invention were evaluated.
In this experimental example, a plurality of different types of dust collection filters (Sample 1 to Sample 7) were prepared or produced. Specifically, a dust collection filter (sample 6, sample 7) as an example of the present invention and a dust collection filter (sample 1 to sample 5) as comparative examples were prepared or produced. And various evaluation was performed about each sample. Below, the kind and evaluation method of each sample are demonstrated.
 <各試料の種類>
 試料1は、スパンボンド不織布(東レ社製、ポリエステル長繊維不織布:G2260-1S)である。
<Type of each sample>
Sample 1 is a spunbond nonwoven fabric (manufactured by Toray Industries, Inc., polyester long fiber nonwoven fabric: G2260-1S).
 試料2は、撥水加工したスパンボンド不織布(東レ社製、ポリエステル長繊維不織布:G2260-TR)である。
 試料3は、PTFE(polytetrafluoroethylene)メンブレンをラミネートしたスパンボンド不織布(東レ社製、ポリエステル長繊維不織布:G2260-TF)である。
Sample 2 is a water-repellent spunbond nonwoven fabric (manufactured by Toray Industries, Inc., polyester long fiber nonwoven fabric: G2260-TR).
Sample 3 is a spunbond nonwoven fabric (polyester long fiber nonwoven fabric: G2260-TF manufactured by Toray Industries, Inc.) laminated with a PTFE (polytetrafluoroethylene) membrane.
 試料4は、試料1のスパンボンド不織布(東レ社製、ポリエステル長繊維不織布:G2260-1S)に対して環状シラン1,3,5,7-テトラメチルシクロテトラシロキサン(D4 H)をCVD処理し、撥水加工を施したものである。 Sample 4 is a CVD treatment of cyclic silane 1,3,5,7-tetramethylcyclotetrasiloxane (D 4 H ) on the spunbond nonwoven fabric of sample 1 (polyester long fiber nonwoven fabric: G2260-1S manufactured by Toray Industries, Inc.) And water repellent finish.
 試料5は、試料1のスパンボンド不織布(東レ社製、ポリエステル長繊維不織布:G2260-1S)に対して、撥油加工を施したものである。具体的には、スパンボンド不織布に対して環状シラン1,3,5,7-テトラメチルシクロテトラシロキサン(D4 H)をCVD処理し、表面を撥水化する。次いで、真空プラズマによって表面を親水化する。その後、ヘプタデカフルオロ-1,1,2,2-トリメトキシシラン(FAS17)をCVD処理し、表面を撥油化する。親水化は、真空プラズマに代えてオゾンマイクロバブル、紫外線照射等の方法を用いてもよい。 Sample 5 is obtained by subjecting the spunbond nonwoven fabric of Sample 1 (manufactured by Toray Industries, Inc., polyester long fiber nonwoven fabric: G2260-1S) to oil-repellent processing. Specifically, cyclic silane 1,3,5,7-tetramethylcyclotetrasiloxane (D 4 H ) is subjected to CVD treatment on the spunbonded nonwoven fabric to make the surface water repellent. Next, the surface is hydrophilized by vacuum plasma. Thereafter, heptadecafluoro-1,1,2,2-trimethoxysilane (FAS17) is subjected to CVD treatment to make the surface oil repellent. Hydrophilization may use methods such as ozone microbubbles and ultraviolet irradiation instead of vacuum plasma.
 試料6は、スパンボンド不織布(東レ社製、ポリエステル長繊維不織布、G2200-1S)に対して、フッ素系撥水撥油剤(日華化学社製、NKガード S-09)による撥水撥油加工を施したものである。スパンボンド不織布は、目付が200g/m2、厚みが0.54mmである。その他、スパンボンド不織布のサイズ及び形状は、前述の実施形態1と同様である。撥水撥油加工は、前述の実施形態1と同様に行った。 Sample 6 is a water- and oil-repellent finish using a fluorine-based water- and oil-repellent agent (manufactured by Nikka Chemical Co., Ltd., NK Guard S-09) for a spunbonded nonwoven fabric (manufactured by Toray, polyester long-fiber nonwoven fabric, G2200-1S). Is given. The spunbonded nonwoven fabric has a basis weight of 200 g / m 2 and a thickness of 0.54 mm. In addition, the size and shape of the spunbonded nonwoven fabric are the same as those in the first embodiment. The water / oil repellent treatment was performed in the same manner as in the first embodiment.
 試料7は、前述の実施形態1の集塵フィルタと同様であり、スパンボンド不織布(東レ社製、ポリエステル長繊維不織布、G2260-1S)に対して、フッ素系撥水撥油剤(日華化学社製、NKガード S-09)による撥水撥油加工を施したものである。 Sample 7 is the same as the dust collection filter of Embodiment 1 described above, and is a fluorine-based water and oil repellent (Nikka Chemical Co., Ltd.) for a spunbonded nonwoven fabric (manufactured by Toray Industries, polyester long fiber nonwoven fabric, G2260-1S). Manufactured by NK Guard S-09).
 <撥油性>
 撥油性は、AATCC Test Method 118(1997年)に準拠して評価した。具体的には、試料(集塵フィルタ)に対して、下記に示す表面張力の異なる9つの炭化水素系溶媒を滴下し、各溶媒が浸透するかどうか(濡れ性)を目視にて判断した。そして、各溶媒のうち、試料(集塵フィルタ)に浸透しない溶媒であって最も大きい数字を撥油性の評価結果とした。すなわち、数字が大きいほど撥油性が高いことを示す。撥油性の評価基準は、以下のとおりである。
<Oil repellency>
The oil repellency was evaluated according to AATCC Test Method 118 (1997). Specifically, nine hydrocarbon solvents having different surface tensions shown below were dropped on a sample (dust collection filter), and it was visually determined whether or not each solvent permeates (wetability). And among each solvent, it was a solvent which does not osmose | permeate a sample (dust collection filter), and the largest number was made into the evaluation result of oil repellency. That is, the larger the number, the higher the oil repellency. The evaluation criteria for oil repellency are as follows.
 0:None(Fails Kaydol)
 1:Kaydol
 2:65:35 Kaydol:hexadecane(volume ratio)
 3:n-hexadecane
 4:n-tetradecane
 5:n-dodecane
 6:n-decane
 7:n-octane
 8:n-heptane
 <透過率>
 透過率は、JIS B 9927(1999年)に準拠して求めた。具体的には、各試料の集塵フィルタを装着した粒子捕集率測定装置を準備した。次いで、試験用粒子を含む空気を集塵フィルタに通過させ、集塵フィルタの上流側及び下流側を通過した試験用粒子の数を計測した。試験用粒子は、DOP(dioctyl phthalate、第4類第4石油類)を使用した。試験用粒子の粒径は0.3μmとした。そして、透過率P(%)を以下の式(1)を用いて算出した。
0: None (Failes Kaydol)
1: Kaydol
2:65:35 Kaydol: hexadecane (volume ratio)
3: n-hexadecane
4: n-tetradecane
5: n-dodecane
6: n-decane
7: n-octane
8: n-heptane
<Transmissivity>
The transmittance was determined according to JIS B 9927 (1999). Specifically, a particle collection rate measuring device equipped with a dust collection filter for each sample was prepared. Next, air containing test particles was passed through the dust collection filter, and the number of test particles that passed through the upstream side and the downstream side of the dust collection filter was measured. As test particles, DOP (dioctyl phthalate, Class 4 Class 4 Petroleum) was used. The particle size of the test particles was 0.3 μm. And the transmittance | permeability P (%) was computed using the following formula | equation (1).
 P=(C2/C1)×100・・・(1)
  P:透過率(%)
  C1:集塵フィルタの上流側における試験用粒子の計測値(個/L)
  C2:集塵フィルタの下流側における試験用粒子の計測値(個/L)
 <ゼータ電位>
 ゼータ電位測定装置(大塚電子社製、ゼータ電位・粒径測定システム:ELSZ)を用い、各試料の集塵フィルタの表面のゼータ電位を測定した。
P = (C 2 / C 1 ) × 100 (1)
P: Transmittance (%)
C 1 : Measurement value of particles for test on the upstream side of the dust collection filter (pieces / L)
C 2 : Measurement value of test particles on the downstream side of the dust collection filter (pieces / L)
<Zeta potential>
Using a zeta potential measuring device (manufactured by Otsuka Electronics Co., Ltd., zeta potential / particle size measuring system: ELSZ), the zeta potential on the surface of the dust collecting filter of each sample was measured.
 <通気抵抗度>
 実施形態1と同様の構成の集塵装置に各試料(試料4を除く)の集塵フィルタを取り付け、1週間集塵した。次いで、ヒュームが付着した集塵フィルタに対して機械的払落しを行った。次いで、払落し後の集塵フィルタに空気を通過させ、集塵フィルタの上流側と下流側との間の圧力差ΔP(Pa)を測定した。そして、通気抵抗度R(Pa・s/m)を以下の式(2)を用いて算出した。
<Ventilation resistance>
A dust collection filter of each sample (excluding sample 4) was attached to a dust collector having the same configuration as that of Embodiment 1, and dust collection was performed for one week. Next, mechanical dusting was performed on the dust collecting filter to which the fumes adhered. Next, air was passed through the dust collection filter after the dust was removed, and the pressure difference ΔP (Pa) between the upstream side and the downstream side of the dust collection filter was measured. And ventilation resistance R (Pa * s / m) was computed using the following formula | equation (2).
 R=ΔP/(Q/A)・・・(2)
  R:通気抵抗度(Pa・s/m)
  ΔP:圧力差(Pa)
  Q:空気流量(m3/s)
  A:試料面積(空気通過面の面積)(m2
 <SEM観察>
 実施形態1と同様の構成の集塵装置に各試料(試料4を除く)の集塵フィルタを取り付け、1週間集塵した。次いで、ヒュームが付着した集塵フィルタに対して機械的払落しを行った。そして、払落し後の集塵フィルタの表面を走査型電子顕微鏡(SEM、日本電子社製、電子プローブマイクロアナライザ:JXA-8600)で観察した。
R = ΔP / (Q / A) (2)
R: Ventilation resistance (Pa · s / m)
ΔP: Pressure difference (Pa)
Q: Air flow rate (m 3 / s)
A: Sample area (area of air passage surface) (m 2 )
<SEM observation>
A dust collection filter of each sample (excluding sample 4) was attached to a dust collector having the same configuration as that of Embodiment 1, and dust collection was performed for one week. Next, mechanical dusting was performed on the dust collecting filter to which the fumes adhered. Then, the surface of the dust collection filter after the removal was observed with a scanning electron microscope (SEM, manufactured by JEOL Ltd., electronic probe microanalyzer: JXA-8600).
 <X線CT解析>
 実施形態1と同様の構成の集塵装置に各試料(試料1及び試料7のみ)の集塵フィルタを取り付け、1週間集塵した。次いで、ヒュームが付着した集塵フィルタをX線CT(島津製作所社製、マイクロフォーカスX線CT装置:SMX-160LT)で解析した。
<X-ray CT analysis>
A dust collection filter for each sample (only sample 1 and sample 7) was attached to a dust collector having the same configuration as that of the first embodiment, and dust collection was performed for one week. Next, the dust collecting filter to which the fumes adhered was analyzed by X-ray CT (manufactured by Shimadzu Corporation, microfocus X-ray CT apparatus: SMX-160LT).
Figure JPOXMLDOC01-appb-T000001
 各試料の特性評価の結果を表1に示す。
Figure JPOXMLDOC01-appb-T000001
Table 1 shows the result of the characteristic evaluation of each sample.
 同表に示すように、比較例である試料1、試料3及び試料4は、撥油性が6級未満であり、透過率が70%未満であった。特に、試料3は、集塵フィルタの表面に非常に網目の細かいPTFEメンブレンがラミネートされているため、透過率が他の試料に比べて非常に低い値となった。比較例である試料2及び試料5は、撥油性が6級以上であったが、透過率が70%未満であった。また、試料1~試料5は、ゼータ電位が-10mV未満であった。 As shown in the table, Sample 1, Sample 3 and Sample 4 which are comparative examples had an oil repellency of less than grade 6 and a transmittance of less than 70%. In particular, since the PTFE membrane with a very fine mesh was laminated on the surface of the dust collecting filter, the transmittance of Sample 3 was very low compared to other samples. Samples 2 and 5, which are comparative examples, had an oil repellency of grade 6 or higher, but had a transmittance of less than 70%. Samples 1 to 5 had a zeta potential of less than −10 mV.
 一方、本発明の実施例である試料6及び試料7は、撥油性が6級以上であり、透過率が70%以上であった。また、試料6及び試料7は、ゼータ電位が-10mV以上であった。 On the other hand, Sample 6 and Sample 7, which are examples of the present invention, had oil repellency of grade 6 or higher and transmittance of 70% or higher. Samples 6 and 7 had a zeta potential of −10 mV or higher.
 また、同表に示すように、本発明の実施例である試料6及び試料7は、比較例である試料1~試料3及び試料5に比べて通気抵抗度の値が低くなった。また、集塵前の通気抵抗度(試料1及び試料7が1.33kPa・s/m、試料6が0.91kPa・s/m)と比較した場合、本発明の実施例である試料6及び試料7は、比較例である試料1に比べて通気抵抗度の増加が抑えられている。本実験例では、試料4の通気抵抗度を求めていないが、他の比較例(試料1~試料3及び試料5)と同様の結果となる。 In addition, as shown in the table, Sample 6 and Sample 7 which are examples of the present invention have lower values of ventilation resistance than Samples 1 to 3 and Sample 5 which are comparative examples. In addition, when compared with the ventilation resistance before dust collection (sample 1 and sample 7 are 1.33 kPa · s / m, sample 6 is 0.91 kPa · s / m), In Sample 7, an increase in the ventilation resistance is suppressed as compared with Sample 1 which is a comparative example. In this experimental example, the airflow resistance of the sample 4 is not obtained, but the results are the same as those of the other comparative examples (samples 1 to 3 and sample 5).
 この理由として、試料1、試料2及び試料5は、ヒュームが集塵フィルタの表面から内側に入り込んで捕集されるため、ヒュームによる目詰まりが生じていると考えられる。試料3は、集塵フィルタの表面にラミネートされたPTFEメンブレンにおいてヒュームの目詰まりが生じていると考えられる。一方、試料6及び試料7は、ヒュームが集塵フィルタの表面に近い位置で捕集されるため、付着したヒュームを集塵フィルタから容易に払い落とすことができ、ヒュームによる目詰まりが抑制されたと考えられる。 For this reason, it is considered that Sample 1, Sample 2, and Sample 5 are clogged by fume because fume enters inside from the surface of the dust collection filter and is collected. Sample 3 is considered to be clogged with fume in the PTFE membrane laminated on the surface of the dust collection filter. On the other hand, in Sample 6 and Sample 7, since the fumes are collected at a position close to the surface of the dust collection filter, the attached fumes can be easily removed from the dust collection filter, and clogging by the fumes is suppressed. Conceivable.
 次に、各試料のSEM写真を図5~図10に示す。
 図5~図10は、それぞれ試料1、試料2、試料3、試料5、試料6、試料7のSEM写真である。試料5のSEM写真(図7)のみ倍率が100倍であり、その他の試料のSEM写真は倍率が40倍である。
Next, SEM photographs of each sample are shown in FIGS.
5 to 10 are SEM photographs of Sample 1, Sample 2, Sample 3, Sample 5, Sample 6, and Sample 7, respectively. Only the SEM photograph of sample 5 (FIG. 7) has a magnification of 100 times, and the SEM photographs of other samples have a magnification of 40 times.
 図5、図6及び図8に示すように、比較例である試料1、試料2及び試料5は、払落し後の集塵フィルタの繊維の隙間にヒュームが残っており、ヒュームによる目詰まりが生じていた。また、図7に示すように、比較例である試料3は、集塵フィルタの表面にラミネートされたPTFEメンブレンにヒュームが付着したままであり、PTFEメンブレンにおいてヒュームの目詰まりが生じていた。 As shown in FIGS. 5, 6, and 8, the sample 1, sample 2, and sample 5, which are comparative examples, have fumes remaining in the gaps between the fibers of the dust collection filter after being removed, and clogging due to the fumes has occurred. It was happening. Further, as shown in FIG. 7, in the sample 3 as a comparative example, the fumes remained adhered to the PTFE membrane laminated on the surface of the dust collecting filter, and the fume was clogged in the PTFE membrane.
 一方、図9及び図10に示すように、本発明の実施例である試料6及び試料7は、払落し後の集塵フィルタの繊維の隙間にヒュームがほとんど残っておらず、ヒュームによる目詰まりが抑制されていた。 On the other hand, as shown in FIGS. 9 and 10, the sample 6 and the sample 7 according to the embodiment of the present invention have almost no fumes remaining in the gaps between the fibers of the dust collection filter after being removed, and are clogged by the fumes. Was suppressed.
 次に、試料1及び試料7のX線CT解析結果を図11及び図12に示す。ヒュームを含む空気は、同図の上側から下側に流れる。
 図11に示すように、比較例である試料1は、ヒュームFが集塵フィルタの表面S1から内側(同図では表面S1の下側)に入り込んで捕集されていることがわかる。前述の図3に示した模式図と同様の結果となっている。
Next, X-ray CT analysis results of Sample 1 and Sample 7 are shown in FIGS. Air containing fume flows from the upper side to the lower side in the figure.
As shown in FIG. 11, it can be seen that the sample 1 as a comparative example has fume F entering the inside (from the bottom of the surface S1 in the figure) of the dust collection filter S1 and being collected. The result is the same as the schematic diagram shown in FIG.
 一方、図12に示すように、本発明の実施例である試料7は、集塵フィルタの表面S7から内側(同図では表面S7の下側)に入り込んで捕集されているヒュームFが非常に少ない。前述の図4に示した模式図と同様の結果となっている。したがって、付着したヒュームFを集塵フィルタから容易に払い落とすことができる。 On the other hand, as shown in FIG. 12, the sample 7 which is an embodiment of the present invention has an extremely large amount of fumes F collected inside the dust collection surface S7 from the inside (the lower side of the surface S7 in the figure). Very few. The result is the same as the schematic diagram shown in FIG. Therefore, the attached fume F can be easily removed from the dust collection filter.
 以上の結果から、本発明の集塵フィルタは、撥油性が6級以上であり、かつ、透過率が70%以上であるため、付着したヒュームの払落し作業が容易であることがわかった。また、本発明の集塵フィルタにおいて、ゼータ電位が-10mV以上であることが好ましいことがわかった。 From the above results, it was found that the dust collecting filter of the present invention has an oil repellency of 6 grade or higher and a transmittance of 70% or higher, so that the attached fume can be easily removed. Further, it was found that the zeta potential is preferably −10 mV or more in the dust collection filter of the present invention.
 (その他の実施形態)
 本発明は、前述の実施形態、実験例等に何ら限定されるものではなく、本発明を逸脱しない範囲において種々の態様で実施しうることはいうまでもない。
(Other embodiments)
The present invention is not limited to the above-described embodiments and experimental examples, and it goes without saying that the present invention can be implemented in various modes without departing from the present invention.
 (1)前述の実施形態等では、集塵フィルタを構成する材料(フィルタ材)としてスパンボンド不織布を用いたが、その他の公知のフィルタ材を用いてもよい。
 (2)前述の実施形態等では、集塵フィルタの形状をプリーツ形状としたが、その他の形状(例えば、バグ形状等)であってもよい。
(1) Although the spunbonded nonwoven fabric is used as the material (filter material) constituting the dust collection filter in the above-described embodiment and the like, other known filter materials may be used.
(2) In the above-described embodiment, the shape of the dust collection filter is a pleated shape, but other shapes (for example, a bug shape) may be used.
 (3)前述の実施形態等では、集塵フィルタの撥油加工方法として、撥油剤を含浸させる含浸加工法を用いたが、その他の公知の加工方法(例えば、スプレー(噴霧)加工法、CVD加工法等)を用いてもよい。 (3) In the above-described embodiment and the like, an impregnation method for impregnating an oil repellent was used as an oil repellent method for the dust collection filter. However, other known processing methods (for example, spray processing method, CVD, etc.) A processing method or the like) may be used.

Claims (4)

  1.  ヒュームを捕集するための集塵フィルタであって、
     該集塵フィルタは、表面に撥油性の被覆層が形成された繊維により構成され、AATCC Test Method 118による撥油性が6級以上であり、かつ、JIS B 9927による透過率(試験用粒子の粒径0.3μm)が70%以上であることを特徴とする集塵フィルタ。
    A dust collection filter for collecting fume,
    The dust collection filter is composed of fibers having an oil-repellent coating layer formed on the surface, oil-repellency according to AATCC Test Method 118 is grade 6 or higher, and transmittance according to JIS B 9927 (particle size of test particles). A dust collecting filter having a diameter of 0.3 μm) of 70% or more.
  2.  前記集塵フィルタは、ゼータ電位が-10mV以上であることを特徴とする請求項1に記載の集塵フィルタ。 The dust collection filter according to claim 1, wherein the dust collection filter has a zeta potential of -10 mV or more.
  3.  ヒュームを捕集するための集塵フィルタであって、表面に撥油性の被覆層が形成された繊維により構成され、AATCC Test Method 118による撥油性が6級以上であり、かつ、JIS B 9927による透過率(試験用粒子の粒径0.3μm)が70%以上である集塵フィルタを備えていることを特徴とする集塵装置。 A dust collection filter for collecting fume, which is composed of a fiber having an oil-repellent coating layer formed on its surface, has an oil repellency according to AATCC Test Method 118 of 6 or higher, and is according to JIS B 9927 A dust collecting device comprising a dust collecting filter having a transmittance (particle diameter of test particles 0.3 μm) of 70% or more.
  4.  前記集塵フィルタは、ゼータ電位が-10mV以上であることを特徴とする請求項3に記載の集塵装置。 The dust collection device according to claim 3, wherein the dust collection filter has a zeta potential of -10 mV or more.
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JP6931254B1 (en) * 2020-12-14 2021-09-01 関綜エンジニアリング株式会社 Filter unit and particle collector
JP2022093784A (en) * 2020-12-14 2022-06-24 関綜エンジニアリング株式会社 Filter unit and fine particle collection device

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