WO2015198351A3 - Ni containing anionic clay catalyst useful for selective hydrogenation of furfural to furfuryl alcohol and its preparation thereof - Google Patents

Ni containing anionic clay catalyst useful for selective hydrogenation of furfural to furfuryl alcohol and its preparation thereof Download PDF

Info

Publication number
WO2015198351A3
WO2015198351A3 PCT/IN2015/050050 IN2015050050W WO2015198351A3 WO 2015198351 A3 WO2015198351 A3 WO 2015198351A3 IN 2015050050 W IN2015050050 W IN 2015050050W WO 2015198351 A3 WO2015198351 A3 WO 2015198351A3
Authority
WO
WIPO (PCT)
Prior art keywords
furfural
furfuryl alcohol
selective hydrogenation
preparation
containing anionic
Prior art date
Application number
PCT/IN2015/050050
Other languages
French (fr)
Other versions
WO2015198351A9 (en
WO2015198351A2 (en
Inventor
Raja Thirumalaiswamy
Manikandan MARIMUTHU
Venugopal ASHOK KUMAR
Original Assignee
Council Of Scientific & Industrial Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Council Of Scientific & Industrial Research filed Critical Council Of Scientific & Industrial Research
Publication of WO2015198351A2 publication Critical patent/WO2015198351A2/en
Publication of WO2015198351A3 publication Critical patent/WO2015198351A3/en
Publication of WO2015198351A9 publication Critical patent/WO2015198351A9/en

Links

Classifications

    • B01J35/392—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • B01J27/236—Hydroxy carbonates
    • B01J35/613—
    • B01J35/615—
    • B01J35/647—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms
    • C07D307/44—Furfuryl alcohol

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses Ni containing anionic clay catalyst and its preparation thereof useful for selective hydrogenation of furfural to furfuryl alcohol. Particularly the invention discloses a novel catalyst system comprising Ni over anionic clays for the selective hydrogenation of furfural (FAL) to furfuryl alcohol (FOL). Further, the patent discloses a catalytic process for hydrogenation of FAL to FOL, THFA, 2-methyl furan and other products catalysed by Ni supported on anionic clays with conversion > 89%and selectivity towards FOL > 92%.
PCT/IN2015/050050 2014-06-25 2015-06-25 Ni containing anionic clay catalyst useful for selective hydrogenation of furfural to furfuryl alcohol and its preparation thereof WO2015198351A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN1699DE2014 2014-06-25
IN1699/DEL/2014 2014-06-25

Publications (3)

Publication Number Publication Date
WO2015198351A2 WO2015198351A2 (en) 2015-12-30
WO2015198351A3 true WO2015198351A3 (en) 2016-04-07
WO2015198351A9 WO2015198351A9 (en) 2016-05-12

Family

ID=54197025

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IN2015/050050 WO2015198351A2 (en) 2014-06-25 2015-06-25 Ni containing anionic clay catalyst useful for selective hydrogenation of furfural to furfuryl alcohol and its preparation thereof

Country Status (1)

Country Link
WO (1) WO2015198351A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106944087B (en) * 2016-01-07 2018-12-18 中国石油化工股份有限公司 A kind of preparation method of producing isobutene from oxidative dehydrogenation of isobutane catalyst
CN107170583A (en) * 2017-05-15 2017-09-15 北京化工大学 A kind of method and its application that the aluminium-doped zinc oxide for dye-sensitized solar cell anode is prepared based on hydrotalcite
RU2660439C1 (en) * 2017-12-28 2018-07-06 Федеральное государственное автономное образовательное учреждение высшего образования "Новосибирский национальный исследовательский государственный университет" (Новосибирский государственный университет, НГУ) Furfural hydrogenation catalyst
RU2680799C1 (en) * 2018-11-27 2019-02-27 Федеральное государственное автономное образовательное учреждение высшего образования "Новосибирский национальный исследовательский государственный университет" (Новосибирский государственный университет, НГУ) Method of obtaining furfuryl alcohol by selective hydrogenation of furfuryl
CN110302789A (en) * 2019-06-27 2019-10-08 中国科学院广州能源研究所 A kind of Na-NiAl (O) catalyst and its application in the biological aviation fuel presoma of preparation
CN113117682A (en) * 2021-03-15 2021-07-16 吉林大学 Method for catalytic hydrogenation upgrading of Pickering emulsion system biomass platform compound
CN114558578A (en) * 2022-03-08 2022-05-31 中国石油大学(华东) Novel nickel-carbon catalytic material with radial center and preparation method and application thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5399537A (en) * 1992-12-21 1995-03-21 Amoco Corporation Method for preparing synthesis gas using nickel catalysts

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2094975A (en) 1932-05-18 1937-10-05 Quaker Oats Co Method of hydrogenation of furfural to furfuryl alcohol
US2754304A (en) 1952-05-27 1956-07-10 Quaker Oats Co Catalytic production of furfuryl alcohol and catalyst therefor
US3856710A (en) 1974-02-04 1974-12-24 Us Agriculture Nickel/copper chromite catalysts for hydrogenating edible oils
US5162531A (en) 1990-09-20 1992-11-10 Union Carbide Chemicals & Plastics Technology Corporation Mixed metal oxide catalytic process for the preparation of triethylenediamines
US5243095A (en) 1992-04-24 1993-09-07 Engelhard Corporation Hydrogenation catalyst, process for preparing and process for using said catalyst
WO2008043060A2 (en) 2006-10-05 2008-04-10 Research Triangle Institute Highly dispersed nickel hydrogenation catalysts and methods for making the same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5399537A (en) * 1992-12-21 1995-03-21 Amoco Corporation Method for preparing synthesis gas using nickel catalysts

Also Published As

Publication number Publication date
WO2015198351A9 (en) 2016-05-12
WO2015198351A2 (en) 2015-12-30

Similar Documents

Publication Publication Date Title
WO2015198351A9 (en) Ni containing anionic clay catalyst useful for selective hydrogenation of furfural to furfuryl alcohol and its preparation thereof
WO2014199348A3 (en) Metal doped silicate catalysts for the selective conversion of ethanol to butadiene
EP2864306B8 (en) Purifying crude furan 2,5-dicarboxylic acid by hydrogenation
WO2017123763A8 (en) Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
MY181873A (en) Gold-based catalyst for the oxidative esterification of aldehydes to obtain carboxylic esters
PH12014500727A1 (en) Production of adipic acid and derivatives from carbohydrate-containing materials
WO2014199349A3 (en) Metal impregnated amorphous silicates for the selective conversion of ethanol to butadiene
WO2014199306A3 (en) Process for preparation of 5-hydroxymethylfurfural(hmf)
FR3001728B1 (en) PROCESS FOR PREPARING OLEFIN BY CATALYTIC CONVERSION OF AT LEAST ONE ALCOHOL
WO2016125080A3 (en) Process for the preparation of baricitinib and an intermediate thereof
WO2013108045A3 (en) Process intensification in the catalytic synthesis of supported catalysts with hierarchic pore structure
MX2015012182A (en) Process for the conversion of methoxylated aromatic compounds to simple aromatic compounds.
MX2016011476A (en) Ruthenium-phenol catalysts for transfer hydrogenation reactions.
SG10201809465PA (en) A metal-doped hydroxyapatite catalyst
WO2016020941A3 (en) Preparation of functionalized castor oil derivatives using solid acid and base catalysts
MX2015001492A (en) Supported noble metal-comprising catalyst for oxidative dehydrogenation or epoxidation.
FR3001965B1 (en) PROCESS FOR THE SYNTHESIS OF AMINOACID BY METATHESIS, HYDROLYSIS THEN HYDROGENATION
EP3556463A4 (en) Catalyst system for oxidative dehydrogenation reaction, reactor for butadiene production including same, and method for preparing 1,3-butadiene
FR2995897B1 (en) PROCESS FOR THE SYNTHESIS OF 2,5-DI (HYDROXYMETHYL) FURANE AND 2,5-DI (HYDROXYMETHYL) TETRAHYDROFURAN BY SELECTIVE HYDROGENATION OF FURANE-2,5-DIALDEHYDE
WO2012074841A3 (en) Copper chromite hydrogenation catalysts for production of fatty alcohols
MX2013000778A (en) Method for producing 2,5-diaminotoluene.
TW201611889A (en) Solid catalyst for dehydration of sugar alcohol and method for preparing dianhydrosugar alcohol using said catalyst
WO2016099066A8 (en) Catalyst for glycerin dehydration, preparation method therefor, and acrolein preparation method using catalyst
MX2015014835A (en) Catalytic synthesis of reduced furan derivatives.
WO2016060488A3 (en) Method for producing anhydrous sugar alcohol using non-evaporating catalyst

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 15770659

Country of ref document: EP

Kind code of ref document: A2

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 15770659

Country of ref document: EP

Kind code of ref document: A2