WO2015181458A1 - Composition de liant pour laine minerale - Google Patents
Composition de liant pour laine minerale Download PDFInfo
- Publication number
- WO2015181458A1 WO2015181458A1 PCT/FR2015/051135 FR2015051135W WO2015181458A1 WO 2015181458 A1 WO2015181458 A1 WO 2015181458A1 FR 2015051135 W FR2015051135 W FR 2015051135W WO 2015181458 A1 WO2015181458 A1 WO 2015181458A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acid
- composition according
- weight
- sugars
- hydrogenated
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 69
- 239000011490 mineral wool Substances 0.000 title claims abstract description 18
- 239000011230 binding agent Substances 0.000 title description 16
- 235000000346 sugar Nutrition 0.000 claims abstract description 54
- 150000008163 sugars Chemical class 0.000 claims abstract description 40
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000002253 acid Substances 0.000 claims abstract description 23
- 150000001720 carbohydrates Chemical class 0.000 claims abstract description 20
- 235000014633 carbohydrates Nutrition 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000005192 partition Methods 0.000 claims abstract description 12
- 150000008064 anhydrides Chemical class 0.000 claims abstract description 6
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 5
- 125000003118 aryl group Chemical group 0.000 claims abstract description 4
- 150000003839 salts Chemical class 0.000 claims abstract description 4
- 238000004513 sizing Methods 0.000 claims description 39
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 229920002472 Starch Polymers 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 11
- 239000008107 starch Substances 0.000 claims description 11
- 235000019698 starch Nutrition 0.000 claims description 11
- 238000005984 hydrogenation reaction Methods 0.000 claims description 10
- 150000004676 glycans Chemical class 0.000 claims description 7
- 229920001282 polysaccharide Polymers 0.000 claims description 7
- 239000005017 polysaccharide Substances 0.000 claims description 7
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 150000002772 monosaccharides Chemical class 0.000 claims description 6
- 150000002016 disaccharides Chemical class 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 229920001542 oligosaccharide Polymers 0.000 claims description 4
- 150000002482 oligosaccharides Chemical class 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 description 27
- -1 cellobitol Chemical compound 0.000 description 14
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 9
- 229920001296 polysiloxane Polymers 0.000 description 8
- 238000011084 recovery Methods 0.000 description 8
- 239000000523 sample Substances 0.000 description 8
- 230000032683 aging Effects 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 230000002209 hydrophobic effect Effects 0.000 description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 150000001323 aldoses Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000011435 rock Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 239000008121 dextrose Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000005011 phenolic resin Substances 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical group FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000011491 glass wool Substances 0.000 description 3
- 239000000845 maltitol Substances 0.000 description 3
- 235000010449 maltitol Nutrition 0.000 description 3
- 239000002557 mineral fiber Substances 0.000 description 3
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
- QQOMQLYQAXGHSU-UHFFFAOYSA-N 2,3,6-Trimethylphenol Chemical compound CC1=CC=C(C)C(O)=C1C QQOMQLYQAXGHSU-UHFFFAOYSA-N 0.000 description 2
- NKTOLZVEWDHZMU-UHFFFAOYSA-N 2,5-xylenol Chemical compound CC1=CC=C(C)C(O)=C1 NKTOLZVEWDHZMU-UHFFFAOYSA-N 0.000 description 2
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N 2-Ethylphenol Chemical compound CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- CETWDUZRCINIHU-UHFFFAOYSA-N 2-heptanol Chemical compound CCCCCC(C)O CETWDUZRCINIHU-UHFFFAOYSA-N 0.000 description 2
- CRBJBYGJVIBWIY-UHFFFAOYSA-N 2-isopropylphenol Chemical compound CC(C)C1=CC=CC=C1O CRBJBYGJVIBWIY-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- YCOXTKKNXUZSKD-UHFFFAOYSA-N 3,4-xylenol Chemical compound CC1=CC=C(O)C=C1C YCOXTKKNXUZSKD-UHFFFAOYSA-N 0.000 description 2
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 description 2
- HMNKTRSOROOSPP-UHFFFAOYSA-N 3-Ethylphenol Chemical compound CCC1=CC=CC(O)=C1 HMNKTRSOROOSPP-UHFFFAOYSA-N 0.000 description 2
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 2
- MXLMTQWGSQIYOW-UHFFFAOYSA-N 3-methyl-2-butanol Chemical compound CC(C)C(C)O MXLMTQWGSQIYOW-UHFFFAOYSA-N 0.000 description 2
- YVBCULSIZWMTFY-UHFFFAOYSA-N 4-Heptanol Natural products CCCC(O)CCC YVBCULSIZWMTFY-UHFFFAOYSA-N 0.000 description 2
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 2
- MQWCXKGKQLNYQG-UHFFFAOYSA-N 4-methylcyclohexan-1-ol Chemical compound CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- RZKSECIXORKHQS-UHFFFAOYSA-N Heptan-3-ol Chemical compound CCCCC(O)CC RZKSECIXORKHQS-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 2
- MUPFEKGTMRGPLJ-UHFFFAOYSA-N UNPD196149 Natural products OC1C(O)C(CO)OC1(CO)OC1C(O)C(O)C(O)C(COC2C(C(O)C(O)C(CO)O2)O)O1 MUPFEKGTMRGPLJ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 2
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- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007071 enzymatic hydrolysis Effects 0.000 description 2
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
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- ZOCHHNOQQHDWHG-UHFFFAOYSA-N hexan-3-ol Chemical compound CCCC(O)CC ZOCHHNOQQHDWHG-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- ROBFUDYVXSDBQM-UHFFFAOYSA-N hydroxymalonic acid Chemical compound OC(=O)C(O)C(O)=O ROBFUDYVXSDBQM-UHFFFAOYSA-N 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 125000000468 ketone group Chemical group 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 2
- 229940035436 maltitol Drugs 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 2
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- 239000011591 potassium Substances 0.000 description 2
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- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 239000013074 reference sample Substances 0.000 description 2
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- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
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- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- 239000000832 lactitol Substances 0.000 description 1
- VQHSOMBJVWLPSR-JVCRWLNRSA-N lactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-JVCRWLNRSA-N 0.000 description 1
- 235000010448 lactitol Nutrition 0.000 description 1
- 229960003451 lactitol Drugs 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QWIZNVHXZXRPDR-WSCXOGSTSA-N melezitose Chemical compound O([C@@]1(O[C@@H]([C@H]([C@@H]1O[C@@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O)CO)CO)[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O QWIZNVHXZXRPDR-WSCXOGSTSA-N 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N n-butyl methyl ketone Natural products CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-methyl phenol Natural products CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 1
- HGASFNYMVGEKTF-UHFFFAOYSA-N octan-1-ol;hydrate Chemical compound O.CCCCCCCCO HGASFNYMVGEKTF-UHFFFAOYSA-N 0.000 description 1
- WOFPPJOZXUTRAU-UHFFFAOYSA-N octan-4-ol Chemical compound CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- DFOXKPDFWGNLJU-UHFFFAOYSA-N pinacolyl alcohol Chemical compound CC(O)C(C)(C)C DFOXKPDFWGNLJU-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000006239 protecting group Chemical group 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- UQZIYBXSHAGNOE-XNSRJBNMSA-N stachyose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO[C@@H]3[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O3)O)O2)O)O1 UQZIYBXSHAGNOE-XNSRJBNMSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Chemical group OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- MAZWDMBCPDUFDJ-UHFFFAOYSA-N trans-Traumatinsaeure Natural products OC(=O)CCCCCCCCC=CC(O)=O MAZWDMBCPDUFDJ-UHFFFAOYSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- MAZWDMBCPDUFDJ-VQHVLOKHSA-N traumatic acid Chemical compound OC(=O)CCCCCCCC\C=C\C(O)=O MAZWDMBCPDUFDJ-VQHVLOKHSA-N 0.000 description 1
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 1
- FLUADVWHMHPUCG-SWPIJASHSA-N verbascose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO[C@@H]3[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO[C@@H]4[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O4)O)O3)O)O2)O)O1 FLUADVWHMHPUCG-SWPIJASHSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
- C03C13/06—Mineral fibres, e.g. slag wool, mineral wool, rock wool
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/1095—Coating to obtain coated fabrics
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/321—Starch; Starch derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/092—Polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09D103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4209—Inorganic fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4209—Inorganic fibres
- D04H1/4218—Glass fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
Definitions
- the present invention relates to a composition, in particular a sizing composition for insulating products based on mineral wool, in particular glass wool or rock, containing a carbohydrate component, at least one polycarboxylic acid or anhydride and a hydrophobic monoalcohol. .
- the manufacture of insulating products based on mineral wool generally comprises a step of manufacturing the glass or rock fibers by a centrifugation process. On their path between the centrifuge device and the fiber collection belt, an aqueous sizing composition, also called a binder, is vaporized on the still hot fibers, which is then subjected to a thermosetting reaction at temperatures of about 200 ° C. .
- the sizing compositions based on reducing sugars have the disadvantage of giving rise to coloring reactions (caramelization, Maillard reaction) which make it difficult or impossible to obtain light-colored products.
- binders not based on reducing sugars, but based on hydrogenated sugars, also called sugar alcohols. These reagents have a considerably higher thermal stability than the reducing sugars and do not give rise to Maillard reactions and / or caramelization. Insulation products based on mineral wool and this new generation of "green" binders, however, are relatively hygroscopic and retain less mechanical properties over time than more colorful products made with reducing sugars. To compensate for the loss of mechanical properties after a certain period of aging of these insulating products, it is generally necessary to increase the proportion of binder by about 10 to 20%, which not only increases the cost of the final product but also alters its reaction to fire.
- the present invention therefore relates to an aqueous composition, especially a sizing composition for insulating products based on mineral wool, comprising
- (c) from 1 to 25% by weight, based on the sum of the components (a) and (b), of at least one aliphatic, cycloaliphatic or aromatic monoalcohol containing no acid or basic functions (Bronsted) and having a octanol / water partition (Log Kow) between 1 and 3.
- carbohydrate has a broader meaning than in the past, since it encompasses not only strict carbohydrates, ie reducing sugars or carbohydrates of formula C n (H 2 0) p having at least one aldehyde or ketone group (group reducer), but also the hydrogenation products of these carbohydrates where the aldehyde or ketone group has been reduced to alcohol.
- This term also encompasses non-reducing sugars consisting of several carbohydrate units whose carbons bearing the hemi-acetalic hydroxyl are involved in the saccharic bonds connecting the units to each other.
- the carbohydrate component (a) of the sizing composition according to the invention may consist solely of hydrogenated sugars and be free of reducing or non-reducing sugars. This embodiment is interesting because it leads to insulating products particularly poorly colored.
- Insulating products based on mineral wool obtained with a sizing composition having a certain content of reducing sugars are relatively more colored, but may be of real economic interest related to the low cost of reducing sugars or incompletely hydrogenated sugar mixtures.
- hydrophilic sugar is meant in the present invention all products resulting from the reduction of a saccharide selected from monosaccharides, disaccharides, oligosaccharides and polysaccharides and mixtures of these products.
- the hydrogenated sugar is preferably a hydrogenation product of a starch hydrolyzate.
- Starch hydrolysates are products obtained by enzymatic hydrolysis and / or starch acid.
- the degree of hydrolysis is generally characterized by the equivalent dextrose (DE), defined by the following relationship: number of glycosidic bonds broken number of glycosidic bonds in the initial starch
- the preferred starch hydrolysates have, before the hydrogenation step, an DE of between 5 and 99, and advantageously between 10 and 80.
- the hydrogenation of the saccharide can be carried out by known methods operating under conditions of high hydrogen pressure and high temperature, in the presence of a catalyst chosen from the elements groups IB, MB, IVB, VI, VII and VIII of the periodic table of the elements, preferably in the group comprising nickel, platinum, palladium, cobalt, molybdenum and mixtures thereof.
- a catalyst chosen from the elements groups IB, MB, IVB, VI, VII and VIII of the periodic table of the elements, preferably in the group comprising nickel, platinum, palladium, cobalt, molybdenum and mixtures thereof.
- the preferred catalyst is Raney nickel. Hydrogenation converts sugar or the mixture of sugars (starch hydrolyzate) into polyols or sugar alcohols.
- hydrogenated sugars mention may be made of erythritol, arabitol, xylitol, sorbitol, mannitol, iditol, maltitol, isomaltitol, lactitol, cellobitol, palatinitol, maltotritol and hydrogenation products of starch hydrolysates.
- the products of hydrogenation of starch hydrolysates will preferably be used.
- the hydrogenated sugar or the mixture of hydrogenated sugars consists mainly, that is to say more than 50% by weight, of maltitol (hydrogenation product of maltose, glucose dimer resulting from enzymatic hydrolysis starch).
- the carbohydrate component (a) may consist solely of reducing sugars. However, for the reasons stated in the introduction, it preferably contains a significant fraction of hydrogenated sugars.
- the proportion of hydrogenated sugars in the carbohydrate is advantageously between 25 and 100% by weight, and the component (a) then contains up to 75% by weight of one or more reducing sugars, in addition to the hydrogenated sugar or sugars.
- the hydrogenated sugar content of the carbohydrate (component (a)) is preferably at least 30% by weight, in particular at least 50% by weight, and ideally at least 70% by weight.
- Reducing sugars include monosaccharides (monosaccharides) and osides (disaccharides, oligosaccharides and polysaccharides).
- monosaccharides mention may be made of those comprising from 3 to 8 carbon atoms, preferably the aldoses and advantageously the aldoses containing 5 to 7 carbon atoms.
- the particularly preferred aldoses are natural aldoses (belonging to the D series), in particular hexoses such as glucose, mannose and galactose. Lactose or maltose are examples of disaccharides which can be used as reducing sugar.
- the polysaccharides which can be used for the present invention preferably have a weight average molecular weight of less than 100,000, preferably less than 50,000, advantageously less than 10,000.
- the polysaccharide contains at least one unit chosen from the abovementioned aldoses, advantageously glucose.
- reducing polysaccharides which consist predominantly (more than 50% by weight) of glucose units,
- the reducing sugar may especially be a mixture of monosaccharides, oligosaccharides and polysaccharides, in particular a dextrin.
- Dextrins are compounds corresponding to the general formula (C 6 H 0 O 5 ) n- They are obtained by partial hydrolysis of starch. Their DE is advantageously between 5 and 99, preferably between 10 and 80.
- the non-reducing sugar is preferably a non-reducing oligoholoside containing at most ten carbohydrate units.
- non-reducing sugars examples include diholosides such as trehalose, isotrehaloses, sucrose and isosucrose ("isosucrosis" in English), triholosides such as melezitose, gentianose, raffinose, erlose and umbelliferosis, tetraolosides such as stachyose, and pentaholosides such as verbascose.
- diholosides such as trehalose, isotrehaloses, sucrose and isosucrose ("isosucrosis" in English
- triholosides such as melezitose, gentianose, raffinose, erlose and umbelliferosis
- tetraolosides such as stachyose
- pentaholosides such as verbascose.
- sucrose and trehalose are preferred.
- the polycarboxylic acid may be a polymeric acid or a monomeric acid.
- this polycarboxylic acid advantageously has an average molecular weight in a number less than or equal to 50000, preferably less than or equal to 10000 and advantageously less than or equal to 5000.
- polymeric polycarboxylic acids examples include homopolymers and copolymers obtained from monomers bearing at least one carboxylic acid group such as (meth) acrylic acid, crotonic acid, isocrotonic acid, maleic acid, cinnamic acid, 2-methylmaleic acid, fumaric acid, itaconic acid, 2-methylitaconic acid, ⁇ , ⁇ -methyleneglutaric acid and unsaturated dicarboxylic acid monoesters such as maleates and C1-C10 alkyl fumarates.
- carboxylic acid group such as (meth) acrylic acid, crotonic acid, isocrotonic acid, maleic acid, cinnamic acid, 2-methylmaleic acid, fumaric acid, itaconic acid, 2-methylitaconic acid, ⁇ , ⁇ -methyleneglutaric acid and unsaturated dicarboxylic acid monoesters such as maleates and C1-C10 alkyl fumarates.
- the copolymers may also contain one or more vinyl or acrylic monomers such as vinyl acetate, styrene, which may or may not be substituted by alkyl, hydroxyl or sulphonyl groups, or by a halogen atom, (meth) acrylonitrile, (meth) acrylamide, C 1 -C 10 alkyl (meth) acrylates, especially methyl (meth) acrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate and (meth) acrylate. isobutyl.
- vinyl or acrylic monomers such as vinyl acetate, styrene, which may or may not be substituted by alkyl, hydroxyl or sulphonyl groups, or by a halogen atom, (meth) acrylonitrile, (meth) acrylamide, C 1 -C 10 alkyl (meth) acrylates, especially methyl (meth) acrylate,
- Component (b) is preferably a polycarboxylic acid monomer. It can be a dicarboxylic, tricarboxylic or tetracarboxylic acid.
- the dicarboxylic acids include, for example, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, malic acid, tartaric acid, tartronic acid, aspartic acid, glutamic acid, fumaric acid, itaconic acid, maleic acid, traumatic acid, camphoric acid, phthalic acid and its derivatives, in particular containing at least one boron or chlorine atom, tetrahydrophthalic acid and its derivatives, especially containing at least one chlorine atom such as chlorendic acid, isophthalic acid , terephthalic acid, mesaconic acid and citraconic acid.
- oxalic acid malonic acid
- succinic acid glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, malic acid, tartaric acid, tartronic acid, as
- Tricarboxylic acids include, for example, citric acid, tricarballylic acid, 1,2,4-butanetricarboxylic acid, aconitic acid, hemimellitic acid, trimellitic acid and trimesic acid; Tetracarboxylic acid, for example 1,2,3,4-butanetetracarboxylic acid and pyromellitic acid, may be mentioned.
- Citric acid is preferably used.
- Component (b) is preferably from 30 to 70% by weight, preferably from 40 to 60% by weight solids of the sizing composition of the present invention.
- the weight ratio of component (a) to component (b) is preferably from 70/30 to 30/70, in particular from 60/40 to 40/60.
- the component (c) of the sizing composition is a relatively hydrophobic monovalent alcohol, that is to say a compound having a single C-OH function and having an octanol / water partition coefficient (logP) greater than 1.
- the partition coefficient octanol / water of a pure substance X also called log P or Log Kow (EU English Log K oc tanoi / wat e r), is the logarithm of the ratio P defined by the following formula:
- [X] octanoi is the concentration of X in octanol saturated with water and
- [X] aq Ue u Se is the concentration of X in octanol saturated water
- this partition coefficient has a positive value, the solubility in octanol of substance X is greater than that in water.
- the higher the value of the partition coefficient the more hydrophobic a compound is considered. For example, see the article by James Sangster entitled “Octanol-Water Partition Coefficients of Simple Organic Compounds" in J. Phys. Chem. Ref. Data, Vol. 18, No. 1989, which contains tables showing the logP value of more than 600 pure organic compounds.
- the monoalcohols of the present invention are devoid of acidic or basic functions, that is, they are non-ionizable molecules in water.
- the value of their partition coefficient thus does not depend on the pH of the aqueous phase of the biphasic octanol / water system.
- the component (c) functions as a hydrophobic agent reacting with the components (a) and / or (b) and thus reducing the hydrophilic and / or hygroscopic character of the final insulation product obtained after crosslinking the binder.
- this component must both have a high partition coefficient and be sufficiently soluble in the aqueous sizing composition to react with the carboxyl and / or hydroxyl functions of components (a) and (b).
- the octanol / water partition coefficient (logP) of component (c) is preferably between 1.05 and 2.0, in particular between 1.1 and 1.5.
- logP value of each of these pure substances must be within the ranges indicated above.
- monoalcohol having a partition coefficient of less than 3, or even less than 2 is further advantageous for sanitary and environmental reasons, the substances having an excessively hydrophobic character tending to accumulate in the adipose tissues.
- the concentration of the component (c) in the sizing composition of the present invention is preferably between 1, 5 and 10% by weight, in particular between 2 and 8% by weight, based on the sum of the components (a) and B).
- Aromatic alcohols are indeed less reactive than (cyclo) aliphatic alcohols, but could be used in particular in combination with a component (b) containing activated carboxylic functions, such as anhydride functions.
- Examples of monoalcohols suitable for the present invention are 1-pentanol, 3-methyl-1-butanol, 2,2-dimethyl-1-propanol, 2-pentanol, 3-pentanol, 3-methyl 2-butanol, 2-methyl-2-butanol, 2-ethyl-2-propanol, phenol, cyclohexanol, 1-hexanol, 2-hexanol, 3-hexanol, 3,3-dimethyl-2-butanol, benzyl alcohol, 2 methylphenol, 3-methylphenol, 4-methylphenol, cis-2-methylcyclohexanol, trans-2-methylcyclohexanol, 4-methylcyclohexanol, 1-heptanol, 2-heptanol, 3-heptanol, 4-heptanol, alcohol 3- methylbenzyl alcohol, 4-methylbenzyl alcohol, 2-ethylphenol, 3-ethylphenol, 4-ethylphenol, 1-phenyl
- the sizing composition furthermore preferably comprises an esterification catalyst which may be chosen from Lewis bases and acids, such as clays, colloidal or non-colloidal silica, organic amines, quaternary ammoniums and metal oxides. , metal sulphates, metal chlorides, urea sulphates, urea chlorides and silicate catalysts.
- an esterification catalyst which may be chosen from Lewis bases and acids, such as clays, colloidal or non-colloidal silica, organic amines, quaternary ammoniums and metal oxides. , metal sulphates, metal chlorides, urea sulphates, urea chlorides and silicate catalysts.
- the catalyst may also be a phosphorus-containing compound, for example an alkali metal hypophosphite, an alkali metal phosphite, an alkali metal polyphosphate, an alkali metal hydrogen phosphate, a phosphoric acid or an alkyl phosphonic acid.
- the alkali metal is sodium or potassium.
- the catalyst may also be a compound containing fluorine and boron, for example tetrafluoroboric acid or a salt of this acid, especially an alkali metal tetrafluoroborate such as sodium or potassium, an alkaline earth metal tetrafluoroborate such as calcium or magnesium, zinc tetrafluoroborate and ammonium tetrafluoroborate.
- tetrafluoroboric acid or a salt of this acid especially an alkali metal tetrafluoroborate such as sodium or potassium, an alkaline earth metal tetrafluoroborate such as calcium or magnesium, zinc tetrafluoroborate and ammonium tetrafluoroborate.
- the catalyst is sodium hypophosphite, sodium phosphite or a mixture of these compounds.
- the amount of catalyst introduced into the sizing composition generally represents at most 20% by weight, advantageously from 1 to 10% by weight, relative to the total weight of components (a) and (b).
- the sizing composition according to the invention may furthermore comprise the conventional additives hereafter in the following proportions calculated on the basis of 100 parts by weight of component (a) + (b):
- silane in particular an aminosilane
- an extender filler selected from lignin derivatives such as ammonium lignosulfonate (LSA) or sodium lignosulfonate, and animal or vegetable proteins.
- LSA ammonium lignosulfonate
- animal or vegetable proteins animal or vegetable proteins.
- Silane is a coupling agent capable of reacting with both the fiber surface and the binder components.
- Oils are anti-dust agents and hydrophobic agents; the urea acts as a plasticizer and also makes it possible to adjust the gel time of the sizing composition in order to avoid the problems of pre-gelling; the extension charge is a soluble or dispersible organic filler in the sizing composition which makes it possible in particular to reduce the cost thereof.
- the reactive silicone is preferably a polydiorganosiloxane bearing at least one hydroxyl (silanol), carboxyl, anhydride, amine, epoxy or vinyl function capable of reacting with at least one of the constituents of the sizing composition and / or with the groups silanol of the glass surface.
- the reactive silicone is preferably liquid at room temperature. Its average molar mass is generally less than or equal to 50,000, preferably less than or equal to 10,000.
- the reactive silicone comprises a reactive function, advantageously a silanol function, at each of its chain ends.
- the reactive function of the reactive silicone can be blocked by a protective group which releases said reactive function under the effect of the heat.
- the proportion of reactive silicone in the sizing composition generally varies from 0.1 to 5 parts, preferably from 0.3 to 3 parts, advantageously from 0.5 to 2.5 parts and better still from 0.7 to 1 part. , 8 parts by weight, per 100 parts by weight of the sum of components (a) and (b).
- the preparation of the sizing composition is carried out by simply mixing the aforementioned constituents with water.
- the sizing composition is intended to be applied to mineral fibers, in particular glass or rock fibers.
- the present invention also relates to a process for producing an insulating product based on mineral wool, comprising
- the sizing composition is sprayed onto the mineral fibers at the outlet of the centrifugal device and before they are collected on the receiving member in the form of a sheet of fibers which is then treated at a temperature allowing crosslinking of the sizing and the formation of an infusible binder.
- the crosslinking of the sizing according to the invention is carried out at a temperature comparable to that of a formalin-phenolic resin, at a temperature greater than or equal to 1 10 ° C, preferably greater than or equal to 130 °, and advantageously greater than or equal to 140 ° C.
- the sizing composition advantageously has a pH of between 2 and 4, in particular between 2.5 and 3.5, ideally close to 3.
- the acoustic and / or thermal insulating products obtained by the process according to the invention from these glued fibers also constitute an object of the present invention.
- These products are generally in the form of a mattress or felt of mineral wool, glass or rock, or a veil of mineral fibers, also glass or rock, intended in particular to form a coating surface of said mattress or felt.
- the component (a) contains a very small proportion of reducing sugars, the products have a particularly advantageous white color.
- the insulating products have a high resistance to the development of microorganisms, especially molds, which is due to the non-fermentable nature of hydrogenated sugars.
- Sizing compositions comprising the constituents appearing in Table 1, expressed in weight parts, are prepared.
- the sizing compositions are prepared by introducing into a container water (about 80% of the final composition), hydrogenated sugar (maltitol syrup), citric acid, sodium hypophosphite (catalyst). , the emulsion of anti-dust oil, the silicone emulsion, and 1-phenoxy-2-ethanol with vigorous stirring.
- Glass wool is produced by the internal centrifugation technique in which the molten glass composition is converted into fibers by means of a tool called "centrifugation plate" comprising a basket forming a chamber for receiving the melted composition and a peripheral band pierced with a multitude of orifices: the plate is rotated about its axis of symmetry arranged vertically, the composition is ejected through the orifices under the effect of the centrifugal force and the escaping material orifices are drawn into fibers with the assistance of a stream of drawing gas.
- centrifugation plate comprising a basket forming a chamber for receiving the melted composition and a peripheral band pierced with a multitude of orifices: the plate is rotated about its axis of symmetry arranged vertically, the composition is ejected through the orifices under the effect of the centrifugal force and the escaping material orifices are drawn into fibers with the assistance of a stream of drawing gas.
- a sizing spray crown is disposed below the fiberizing plate so as to evenly distribute the sizing composition on the glass wool just formed.
- the mineral wool thus glued is collected on a belt conveyor equipped with internal suction boxes which hold the mineral wool in the form of a felt or a sheet on the surface of the conveyor.
- the conveyor then circulates in an oven maintained at 270 ° C where the components of the sizing polymerize to form a binder.
- the insulating product obtained has a width of 2.4 m, a nominal density equal to 17.5 kg / m 3 , a nominal thickness of about 82 mm and a loss on ignition of the order of 5%.
- the tensile strength is measured according to ASTM C 686-71 T on a punched sample in the insulating product.
- the sample has the shape of a ring 122 mm long, 46 mm wide, a radius of curvature of the outside edge cut equal to 38 mm and a radius of curvature of the cut of the inner edge equal to 12, 5 mm.
- the sample is placed between two cylindrical chucks of a test machine, one of which is movable and moves at a constant speed.
- the tensile strength F of the sample is measured and the tensile strength RT, defined by the ratio of the breaking force F (in Newton) to the mass of the sample (in grams), is calculated.
- the "thickness recovery” indicates the compressive elasticity of the final product. In order to measure it, a compression pressure is applied for a given time, in this case 90 days, such that the thickness is reduced to 1 / 4.8 of its initial value. After releasing this compression pressure, the thickness is again measured. Thickness recovery is the ratio, expressed in%, of the thickness measured after releasing the compression pressure at the initial thickness.
- RT tensile strength
- Emulsion of anti-dust oil Emulsion of anti-dust oil
- the recovery in thickness of the sample 2 shows a recovery in thickness after 90 days that is greater than that of the reference sample, whereas the recovery in thickness of the comparative sample 1 is about 2 to 3% less than that of the reference sample.
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Abstract
Description
Claims
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2016149892A RU2677510C2 (ru) | 2014-05-28 | 2015-04-27 | Композиция связующего для минеральной ваты |
KR1020167032690A KR20170012249A (ko) | 2014-05-28 | 2015-04-27 | 광물 울을 위한 결합제 조성물 |
SG11201609918QA SG11201609918QA (en) | 2014-05-28 | 2015-04-27 | Binder composition for mineral wool |
UAA201613400A UA120055C2 (uk) | 2014-05-28 | 2015-04-27 | Композиція зв'язуючого для мінеральної вати |
CN201580027520.4A CN106459700B (zh) | 2014-05-28 | 2015-04-27 | 矿物棉的粘结剂组合物 |
EP15725809.6A EP3148951B1 (fr) | 2014-05-28 | 2015-04-27 | Composition de liant pour laine minerale |
AU2015265804A AU2015265804B2 (en) | 2014-05-28 | 2015-04-27 | Binder composition for mineral wool |
CA2947385A CA2947385A1 (fr) | 2014-05-28 | 2015-04-27 | Composition de liant pour laine minerale |
ES15725809T ES2751768T3 (es) | 2014-05-28 | 2015-04-27 | Composición de aglutinante para lana mineral |
US15/313,342 US10119211B2 (en) | 2014-05-28 | 2015-04-27 | Binder composition for mineral wool |
PL15725809T PL3148951T3 (pl) | 2014-05-28 | 2015-04-27 | Kompozycja lepiszcza dla wełny mineralnej |
SI201530989T SI3148951T1 (sl) | 2014-05-28 | 2015-04-27 | Vezivni sestavek za mineralno volno |
MX2016014966A MX2016014966A (es) | 2014-05-28 | 2015-04-27 | Composicion de ligante para lana mineral. |
JP2016569052A JP6530427B2 (ja) | 2014-05-28 | 2015-04-27 | ミネラルウールのためのバインダ組成物 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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FR1454885A FR3021651A1 (fr) | 2014-05-28 | 2014-05-28 | Composition de liant pour laine minerale |
FR1454885 | 2014-05-28 |
Publications (1)
Publication Number | Publication Date |
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WO2015181458A1 true WO2015181458A1 (fr) | 2015-12-03 |
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PCT/FR2015/051135 WO2015181458A1 (fr) | 2014-05-28 | 2015-04-27 | Composition de liant pour laine minerale |
Country Status (18)
Country | Link |
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US (1) | US10119211B2 (fr) |
EP (1) | EP3148951B1 (fr) |
JP (1) | JP6530427B2 (fr) |
KR (1) | KR20170012249A (fr) |
CN (1) | CN106459700B (fr) |
AR (1) | AR102114A1 (fr) |
AU (1) | AU2015265804B2 (fr) |
CA (1) | CA2947385A1 (fr) |
CL (1) | CL2016003033A1 (fr) |
ES (1) | ES2751768T3 (fr) |
FR (1) | FR3021651A1 (fr) |
MX (1) | MX2016014966A (fr) |
PL (1) | PL3148951T3 (fr) |
RU (1) | RU2677510C2 (fr) |
SG (1) | SG11201609918QA (fr) |
SI (1) | SI3148951T1 (fr) |
UA (1) | UA120055C2 (fr) |
WO (1) | WO2015181458A1 (fr) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018042085A1 (fr) * | 2016-09-02 | 2018-03-08 | Saint-Gobain Isover | Procede de fabrication de laine minerale |
FR3069536A1 (fr) * | 2017-07-31 | 2019-02-01 | Saint-Gobain Isover | Procede de fabrication de laine minerale |
WO2019025707A1 (fr) | 2017-07-31 | 2019-02-07 | Saint-Gobain Isover | Installation de fabrication de laine minérale et dispositif de projection d'une composition d'encollage équipant une telle installation |
WO2020144436A1 (fr) | 2019-01-11 | 2020-07-16 | Saint-Gobain Isover | Procédé de fabrication d'un produit d'isolation à base de laine minérale |
EP3831791A1 (fr) | 2019-12-04 | 2021-06-09 | Saint-Gobain Isover | Procédé pour améliorer les performances acoustiques d'un produit isolant á base de fibres minérales et produit |
US11959210B2 (en) | 2018-05-18 | 2024-04-16 | Owens Corning Intellectual Capital, Llc | Nonwoven with two-part binder system |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3019815B1 (fr) * | 2014-04-15 | 2016-05-06 | Saint Gobain Isover | Composition d'encollage a base de saccharide non reducteur et de saccharide hydrogene, et produits isolants obtenus. |
EP3694918B1 (fr) * | 2017-10-09 | 2023-12-06 | Owens Corning Intellectual Capital, LLC | Compositions liantes aqueuses |
US11813833B2 (en) | 2019-12-09 | 2023-11-14 | Owens Corning Intellectual Capital, Llc | Fiberglass insulation product |
EP3896045A1 (fr) | 2020-04-16 | 2021-10-20 | URSA Insulation, S.A. | Liants et résines durcissables pour laine minérale |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999056720A1 (fr) * | 1998-05-07 | 1999-11-11 | The Procter & Gamble Company | Composition contenant un compose d'acide ascorbique |
WO2001096254A1 (fr) | 2000-06-13 | 2001-12-20 | Saint-Gobain Isover | Produit d'isolation notamment thermique contenant un liant a base de resine formo-phenolique et sa fabrication |
WO2002020622A1 (fr) * | 2000-09-11 | 2002-03-14 | Indústria e Comércio de Cosméticos Natura Ltda. | Melange d'oligosaccharides a base de fucose non-sulfate, cosmetique ou composition pharmaceutique comportant ledit melange et son utilisation dans l'industrie cosmetique ou pharmaceutique |
US20050215153A1 (en) * | 2004-03-23 | 2005-09-29 | Cossement Marc R | Dextrin binder composition for heat resistant non-wovens |
WO2010029266A1 (fr) | 2008-09-11 | 2010-03-18 | Saint-Gobain Isover | Composition d'encollage pour laine minerale a base de sucre hydrogene et produits isolants obtenus |
WO2010106181A1 (fr) * | 2009-03-19 | 2010-09-23 | Rockwool International A/S | Composition aqueuse liante pour fibres minérales |
US20110223364A1 (en) | 2009-10-09 | 2011-09-15 | Hawkins Christopher M | Insulative products having bio-based binders |
WO2013014399A1 (fr) | 2011-07-27 | 2013-01-31 | Saint-Gobain Isover | Composition d'encollage pour laine minerale a base de maltitol et produits isolants obtenus |
WO2014038078A1 (fr) * | 2012-09-04 | 2014-03-13 | L'oreal | Composition cosmétique ou dermatologique pour hydrater la peau |
JP2014062077A (ja) * | 2012-09-24 | 2014-04-10 | Kyoei Kagaku Kogyo Kk | 化粧料用組成物 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63227864A (ja) * | 1987-03-12 | 1988-09-22 | 日本板硝子株式会社 | ガラス繊維用バインダ− |
US20030212181A1 (en) * | 1999-12-17 | 2003-11-13 | Takumi Honda | Autodepositing coating composition and process and coated metal articles therefrom |
US20100233146A1 (en) * | 2002-09-09 | 2010-09-16 | Reactive Surfaces, Ltd. | Coatings and Surface Treatments Having Active Enzymes and Peptides |
US8604122B2 (en) * | 2006-12-20 | 2013-12-10 | Rohm And Haas Company | Curable aqueous compositions |
EP2450493A3 (fr) * | 2007-01-25 | 2015-07-29 | Knauf Insulation SPRL | Panneau de fibres minérales |
FR2924719B1 (fr) * | 2007-12-05 | 2010-09-10 | Saint Gobain Isover | Composition d'encollage pour laine minerale comprenant un monosaccharide et/ou un polysaccharide et un acide organique polycarboxylique, et produits isolants obtenus. |
EP2223940B1 (fr) * | 2009-02-27 | 2019-06-05 | Rohm and Haas Company | Composition de liaison durcissable en glucide modifié à polymère |
CA2954722C (fr) * | 2009-10-09 | 2020-03-10 | Owens Corning Intellectual Capital, Llc | Liants biologiques pour l'isolation et mats non tisses |
FR2951189B1 (fr) * | 2009-10-13 | 2011-12-09 | Saint Gobain Isover | Composition d'encollage pour laine minerale comprenant un sucre reducteur et un sel metallique d'acide inorganique, et produits isolants obtenus |
FR2978768B1 (fr) * | 2011-08-05 | 2014-11-28 | Saint Gobain Isover | Composition d'encollage pour laine minerale a base de saccharide reducteur et de saccharide hydrogene, et produits isolants obtenus |
-
2014
- 2014-05-28 FR FR1454885A patent/FR3021651A1/fr active Pending
-
2015
- 2015-04-27 JP JP2016569052A patent/JP6530427B2/ja not_active Expired - Fee Related
- 2015-04-27 CN CN201580027520.4A patent/CN106459700B/zh not_active Expired - Fee Related
- 2015-04-27 UA UAA201613400A patent/UA120055C2/uk unknown
- 2015-04-27 SG SG11201609918QA patent/SG11201609918QA/en unknown
- 2015-04-27 PL PL15725809T patent/PL3148951T3/pl unknown
- 2015-04-27 CA CA2947385A patent/CA2947385A1/fr not_active Abandoned
- 2015-04-27 US US15/313,342 patent/US10119211B2/en not_active Expired - Fee Related
- 2015-04-27 KR KR1020167032690A patent/KR20170012249A/ko active IP Right Grant
- 2015-04-27 MX MX2016014966A patent/MX2016014966A/es unknown
- 2015-04-27 WO PCT/FR2015/051135 patent/WO2015181458A1/fr active Application Filing
- 2015-04-27 SI SI201530989T patent/SI3148951T1/sl unknown
- 2015-04-27 EP EP15725809.6A patent/EP3148951B1/fr active Active
- 2015-04-27 RU RU2016149892A patent/RU2677510C2/ru active
- 2015-04-27 AU AU2015265804A patent/AU2015265804B2/en not_active Ceased
- 2015-04-27 ES ES15725809T patent/ES2751768T3/es active Active
- 2015-05-13 AR ARP150101473A patent/AR102114A1/es unknown
-
2016
- 2016-11-25 CL CL2016003033A patent/CL2016003033A1/es unknown
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999056720A1 (fr) * | 1998-05-07 | 1999-11-11 | The Procter & Gamble Company | Composition contenant un compose d'acide ascorbique |
WO2001096254A1 (fr) | 2000-06-13 | 2001-12-20 | Saint-Gobain Isover | Produit d'isolation notamment thermique contenant un liant a base de resine formo-phenolique et sa fabrication |
WO2002020622A1 (fr) * | 2000-09-11 | 2002-03-14 | Indústria e Comércio de Cosméticos Natura Ltda. | Melange d'oligosaccharides a base de fucose non-sulfate, cosmetique ou composition pharmaceutique comportant ledit melange et son utilisation dans l'industrie cosmetique ou pharmaceutique |
US20050215153A1 (en) * | 2004-03-23 | 2005-09-29 | Cossement Marc R | Dextrin binder composition for heat resistant non-wovens |
WO2010029266A1 (fr) | 2008-09-11 | 2010-03-18 | Saint-Gobain Isover | Composition d'encollage pour laine minerale a base de sucre hydrogene et produits isolants obtenus |
WO2010106181A1 (fr) * | 2009-03-19 | 2010-09-23 | Rockwool International A/S | Composition aqueuse liante pour fibres minérales |
US20110223364A1 (en) | 2009-10-09 | 2011-09-15 | Hawkins Christopher M | Insulative products having bio-based binders |
WO2012118939A1 (fr) * | 2011-03-01 | 2012-09-07 | Owens Corning Intellectual Capital, Llc | Produits isolants à liants d'origine biologique |
WO2013014399A1 (fr) | 2011-07-27 | 2013-01-31 | Saint-Gobain Isover | Composition d'encollage pour laine minerale a base de maltitol et produits isolants obtenus |
WO2014038078A1 (fr) * | 2012-09-04 | 2014-03-13 | L'oreal | Composition cosmétique ou dermatologique pour hydrater la peau |
JP2014062077A (ja) * | 2012-09-24 | 2014-04-10 | Kyoei Kagaku Kogyo Kk | 化粧料用組成物 |
Non-Patent Citations (1)
Title |
---|
"Octanol-Water Partition Coefficients of Simple Organic Compounds", J. PHYS. CHEM. REF. DATA, vol. 18, 1989 |
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Also Published As
Publication number | Publication date |
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FR3021651A1 (fr) | 2015-12-04 |
ES2751768T3 (es) | 2020-04-01 |
JP6530427B2 (ja) | 2019-06-12 |
RU2016149892A (ru) | 2018-06-28 |
CN106459700B (zh) | 2019-09-27 |
CL2016003033A1 (es) | 2017-05-12 |
AU2015265804A1 (en) | 2016-12-15 |
JP2017517644A (ja) | 2017-06-29 |
CN106459700A (zh) | 2017-02-22 |
US10119211B2 (en) | 2018-11-06 |
CA2947385A1 (fr) | 2015-12-03 |
EP3148951A1 (fr) | 2017-04-05 |
KR20170012249A (ko) | 2017-02-02 |
UA120055C2 (uk) | 2019-09-25 |
US20170198425A1 (en) | 2017-07-13 |
SI3148951T1 (sl) | 2019-12-31 |
AU2015265804B2 (en) | 2019-01-31 |
RU2016149892A3 (fr) | 2018-11-07 |
RU2677510C2 (ru) | 2019-01-17 |
PL3148951T3 (pl) | 2020-01-31 |
EP3148951B1 (fr) | 2019-08-14 |
MX2016014966A (es) | 2017-04-11 |
SG11201609918QA (en) | 2016-12-29 |
AR102114A1 (es) | 2017-02-08 |
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