WO2015161681A1 - An inert seal explosion suppression device used for hazardous chemical containers and defense method - Google Patents

An inert seal explosion suppression device used for hazardous chemical containers and defense method Download PDF

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Publication number
WO2015161681A1
WO2015161681A1 PCT/CN2015/070242 CN2015070242W WO2015161681A1 WO 2015161681 A1 WO2015161681 A1 WO 2015161681A1 CN 2015070242 W CN2015070242 W CN 2015070242W WO 2015161681 A1 WO2015161681 A1 WO 2015161681A1
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Prior art keywords
fire
liquid
container
gas
medium
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PCT/CN2015/070242
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French (fr)
Chinese (zh)
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孙强丹
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孙强丹
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Publication of WO2015161681A1 publication Critical patent/WO2015161681A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/18Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
    • B65D81/20Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00Component parts, details or accessories for large containers
    • B65D90/22Safety features
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00Component parts, details or accessories for large containers
    • B65D90/22Safety features
    • B65D90/38Means for reducing the vapour space or for reducing the formation of vapour within containers
    • B65D90/44Means for reducing the vapour space or for reducing the formation of vapour within containers by use of inert gas for filling space above liquid or between contents

Definitions

  • the invention relates to the field of safe production, storage and transportation of dangerous chemicals, in particular to an inertial sealing and anti-explosion device for a dangerous chemical container, and a method for arranging the equipment to defend against the Monroe effect.
  • energy-based materials such as crude oil and fuel oil with strategic resource attributes and their production, storage and transportation facilities and equipment are important support for national power and an important component of combat power.
  • materials and containers have typical characteristics such as military-civilian sharing, peacetime generalization, and asset agglomeration, they must become strategic interests and tactical offensive and defensive in military operations such as military confrontation or terrorist attacks.
  • a large number of dangerous chemicals and containers that are capable of forming multiple damages and causing major damages are indiscriminately exposed to densely populated and unpredictable economic and strategic locations.
  • the tactical technical equipment and defense methods of the existing military oil depot only involve the cave library hidden Covered, semi-underground camouflage, floating roof technology and other fire-fighting fields for kinetic energy and combustion-type bomb attacks, but in the context of modern investigative, guidance and multi-level charges, the independent defense force is ineffective.
  • the known anti-explosion material application technology can release the substance which inhibits the formation of free radicals when the material temperature rises rapidly, but the alloy-like grid-like anti-explosion material cannot inhibit the formation of oxygen-containing hydrocarbon gas in the gas phase space of the container, so It is not possible to suppress the oxygenated hydrocarbon gas from being detonated in the event of a detonation in the vessel.
  • the known floating roof technology provides a technique and method for suppressing a large amount of evaporation of materials
  • the redundant space in the outer floating roof container must contain material steam;
  • the traditional rigid inner floating roof technology has many hidden dangers such as easy to loose guide column, easy deformation of the floating plate, easy to seal, and even liquid pan.
  • the gas phase space of the vessel cannot effectively eliminate the oxygenated hydrocarbon gas.
  • the Chinese invention patent "Air Cushion Radial Elastic Sealed Floating Roof and Fire Fighting Method Using the Floating Roof” ZL97119189.1, which is invented by the inventor, provides a gas-type inert medium as a soft inner floating lining gas, which is normalized.
  • the technical solution of covering the surface of the protected material overcomes many defects of the hard inner floating roof, and makes up for the shortcomings of the soft inner floating roof and the unused inertial sealing gas provided by the US Patent No. US3002828, which can be in the container.
  • the effective defense against oxygenated hydrocarbon gas is detonated.
  • this prior art still has the following shortcomings in military applicability: 1.
  • the technical solution can cope with the warfare part to some extent
  • the oxygen-containing hydrocarbon gas mode forms a chemical explosion, but does not consider the energy venting function after the detonation in the container, and there is a possibility of physical explosion of the hazardous chemical container; 2.
  • the technical solution does not carry out follow-up fire
  • the media participates in functions such as saving or enhancing protection.
  • the technical solution also has the following shortcomings in industrial applicability: 1.
  • the inert gas line cannot be recycled; 2.
  • the inert gas line cannot follow the material pipe; 3.
  • the gas can not be separated from the inert gas line and the gas material can be extracted.
  • War prevention prevention strategy focuses on open fire; fire protection is limited to emergency rescue.
  • the first object of the present invention is to provide an inertial sealing and anti-explosion device for a dangerous chemical container, which can adopt the technical measures of filling the gas phase space of the container with a gaseous inert sealing medium under the premise of satisfying the requirements of production, storage and transportation, and controlling the container.
  • the normalization of the oxygen content in the gas phase space is less than the lower limit of the combustion explosion limit of the protected material, thereby permanently inhibiting the combustion and explosion conditions of the hazardous chemical materials in the container.
  • a second object of the present invention is to provide an inertial seal suppression device for a hazardous chemical container, which is capable of using a liquid fire-fighting medium as a self-control type between a gaseous inertial seal medium source and a container gas phase space, a gaseous inert seal medium and the atmosphere.
  • the liquid valve replaces the components and accessories of the large and small breathing valve, safety valve, fire stop valve, rupture disk, etc. for the dangerous chemical container to realize the whole system production, storage and transportation process to isolate the atmosphere.
  • a third object of the present invention is to provide an inertial seal suppression device for a hazardous chemical container, which is capable of separating and extracting gaseous molecules from a gaseous inert seal medium and recycling the gaseous inert seal medium to reduce operating costs.
  • a fourth object of the present invention is to provide an inertial sealing and anti-explosion device for a dangerous chemical container, which can carry the gaseous inert sealing medium into the material pipeline when evacuating the material in the container, thereby further ensuring the safety of personnel and equipment.
  • a fifth object of the present invention is to provide an inert seal anti-explosion device for a hazardous chemical container, which is capable of spraying a liquid fire-fighting medium near the tank at the top of the container, and supporting the container to cool down and clean the container.
  • the sixth object of the present invention is to propose a defense method based on an inertial sealing and anti-explosion device for a dangerous chemical container, which can effectively cope with the Monroe effect elastic type, which is intended to blast the gas phase space in the detonation mode of the warhead container. Strike of oxygen hydrocarbon gas.
  • the seventh object of the present invention is to provide an inertial sealing and anti-explosion device for a dangerous chemical container and a defense method thereof, which can effectively protect the dangerous chemicals in the emergency fighting process.
  • the fire-fighting pipeline of the near-can sprayed liquid fire-fighting medium is protected from heat radiation damage at the top of the vessel, and the near-tank injection liquid fire-fighting medium mode can be switched to the near-tank release gaseous idle-sealing medium mode, and the air-filled air-tight medium mode can be introduced into the container. Switch to inject liquid fire media mode.
  • the present invention provides an inertial anti-explosion device for a hazardous chemical container, comprising an air-sealing device disposed on a hazardous chemical container, the air-sealing device including being installed in a vertical direction a U-shaped sleeve in which a liquid fire-fighting medium having a fire-fighting function relative to a material to be protected in the hazardous chemical container is stored, the U-shaped sleeve including a gas distribution side vertical tube and a container side vertical a tube and a bottom tube, wherein the two ports of the bottom tube are respectively in communication with the lower side ports of the gas distribution side vertical tube and the container side vertical tube, and the upper side of the gas distribution side vertical tube of the U-shaped sleeve
  • the port is in gaseous communication with a source of gaseous inert seal medium capable of providing and recovering a gaseous inert seal medium chemically stable relative to the protected material within the hazardous chemical container, the U-shaped sleeve being on the container
  • the gas inerting medium source comprises a gas distribution pump system, a gas distribution manifold, a gas collection branch pipe and a gas distribution branch pipe
  • the gas distribution pump system comprises a gas inerting medium generator, a high pressure storage tank, a gas distribution pressure tank, a one-way air pump, an oil and gas separation device, and a connecting short pipe and a valve, wherein the gas inerting medium generator, the high pressure storage tank and the gas distribution pressure tank are connected in series to the gas distribution manifold,
  • the one-way air pump and the oil-gas separation device are connected in series to the gas-receiving branch pipe, and the gas-receiving branch pipe is connected in parallel to a part of the pipeline of the gas distribution main pipe, and the gas distribution main pipe and the gas distribution branch pipe are connected in a gas phase connection
  • the gas distribution branch pipe is in gas phase connection with the port of the gas distribution side vertical pipe of the U-shaped sleeve.
  • the invention further includes a liquid fire-fighting medium source, wherein the liquid fire-fighting medium source is in liquid phase communication with the U-shaped sleeve, and the liquid fire-fighting medium capable of being discharged, recycled or recycled is provided inside the U-shaped sleeve.
  • the liquid fire-fighting medium in the U-shaped sleeve separates the gaseous inert seal medium into a gas distribution side as a casing liquid valve a gaseous inert seal medium and a gas-tight seal medium on the container side, the liquid fire-fighting medium source injecting a predetermined amount of liquid fire-fighting medium into the U-shaped sleeve according to a preset liquid level height of the sleeve liquid valve, To adjust the opening and closing pressure of the casing liquid valve.
  • the liquid fire medium source includes a fire pump system, a fire main pipe and a fire branch pipe
  • the fire pump includes a fire medium storage facility, a fire pump and a fire valve control device, the fire medium storage facility and the fire pump
  • the fire mains are connected in series with the fire main pipe in series, and the fire main pipe is connected to the liquid pipe of the U-shaped bushing.
  • a Y-shaped through tube is further disposed in the U-shaped sleeve, and a lower port of the Y-shaped through tube passes through the bottom tube of the U-shaped sleeve and is connected to the fire branch tube Connecting the container side port of the Y-shaped through tube from the upper portion of the container-side standpipe of the U-shaped sleeve close to the top of the hazardous chemical container, or above the dangerous chemical container a spray pipe connection, wherein a gas distribution side port of the Y-shaped pipe is suspended from a predetermined height in a gas distribution side vertical pipe of the U-shaped casing, and the liquid fire protection can be injected into the U-shaped casing medium.
  • a Y-shaped through tube is further disposed outside the U-shaped sleeve, and a lower port of the Y-shaped through tube is in fluid communication with the fire branch pipe, and a container side port of the Y-shaped through tube and a gas distribution side port penetrates from a bottom pipe of the U-shaped sleeve, and a container side port of the Y-shaped pipe passes through an upper portion of the container side vertical pipe of the U-shaped casing to approach the dangerous chemical container
  • the top position is pierced or connected to the spray pipe above the hazardous chemical container, and the gas distribution side port of the Y-shaped pipe is suspended in the gas distribution side vertical pipe of the U-shaped sleeve
  • the height is such that the liquid fire-fighting medium can be injected into the U-shaped sleeve.
  • the Y-shaped through tube is in liquid phase communication with the liquid fire-fighting medium source, and the liquid fire-fighting medium source supplies the liquid fire-fighting to the U-shaped sleeve through a gas distribution side port of the Y-shaped through tube a medium, the liquid fire-fighting medium retained in the Y-shaped pipe is used as a pipe-through liquid valve to isolate the gaseous inert seal medium from the atmosphere
  • the height of the gas distribution side port of the Y-shaped pipe is set to adjust the opening and closing pressure of the pipe-through liquid valve.
  • a valve for controlling communication between the gas distribution side port of the Y-shaped pipe and the fire branch pipe is further disposed on the Y-shaped pipe, and when the valve is closed, the inside of the air-sealing device
  • the pressure relief passage between the gaseous inert seal medium and the atmosphere is shut off by the valve, and the liquid fire-fighting medium input from the liquid fire-fighting medium source can be directly ejected through the container side port of the Y-shaped through tube.
  • a gas distribution pipe network formed by the branch pipe is in gas phase connection with an inerting device on each of the dangerous chemical containers
  • the liquid fire fighting medium source passes through a fire pipe network composed of a fire main pipe and a fire branch pipe and each of the dangerous chemical containers
  • the bottom liquid phase connection of the upper inert seal device is connected.
  • the air-sealing device further includes an air-sealing disk disposed at a top of the hazardous chemical container, the air-latching disk is provided with a pressure relief hole, a disk waist connection hole, a top plate manhole and a cover body a box-type cavity structure, the pressure relief hole of the idler disk is in gas-phase communication with the top pressure relief hole of the hazardous chemical container, and the upper port of the container side standpipe of the U-shaped sleeve
  • the disk waist connecting hole on the idle sealing disk is connected to the gas phase connection, and the top of the disk top hole is closed by the cover body.
  • the gaseous inerting medium is a combination of one or more of nitrogen, a rare earth gas, carbon dioxide gas and water vapor
  • the liquid fire fighting medium is water, antifreeze liquid, parent material liquid, water based fire protection A combination of one or more of the foams.
  • the U-shaped sleeve is wholly or partially installed outside the hazardous chemical container, or is wholly or partially installed inside the hazardous chemical container.
  • U-shaped sleeve and the Y-shaped through tube and its components and accessories are separately fabricated and sequentially connected, or integrally manufactured.
  • the present invention also provides a hazardous chemical based on the foregoing Defense methods for inertial seal suppression equipment for containers, including:
  • the container group According to the technical parameters of the container, the container group, the auxiliary facilities, the operating equipment and the material to be protected, combined with the technical parameters of the enemy missile, the design and assembly engineering of the idle-sealed explosion-proof equipment;
  • the acceptance of the installation project shall be carried out according to the acceptance criteria listed in the listed engineering design results;
  • the negative pressure oxygen drive method or the liquid-filled oxygen-discharging method is adopted to realize the gas-filled medium-driven oxygen-filled gas inertial seal medium source pipeline, the inert seal device and the container gas phase space;
  • the inertial explosion-proof equipment is delivered and packaged, achieving independent non-wartime energy-saving emission reduction of non-wartime chemicals and containers, and independent permanent defensive combat without conversion.
  • the specific steps of the negative pressure oxygen drive method include:
  • the specific steps of the liquid-filled oxygen flooding method include:
  • liquid fire-fighting medium source to vent or recover the liquid fire-fighting medium, and simultaneously introducing relatively pure gaseous inert sealing medium into all the pipelines of the gas distribution manifold, the gas distribution branch pipe, the gas collection branch pipe and the inerting device;
  • steps of the trial run include:
  • the invention follows the known combustion and explosion conditions of the substance and the achievement mechanism of the condition, and utilizes the gaseous inerting medium to systematically liquefy the dynamic gas phase space of the container and the pipeline, and control the oxygen content of the gas phase space to the lower limit of the explosion limit of the protected material.
  • the core function of permanent and normalization to suppress the combustion and explosion conditions of the protected materials is achieved.
  • the present invention utilizes the known liquid substance characteristics, adopts a technical measure of filling a U-shaped casing with a liquid fire-fighting medium, and uses the liquid fire-fighting medium as a self-control liquid between the source of the gaseous inert seal medium and the container.
  • the valve separates the gaseous inert seal medium into two parts of the inertial seal medium on the source side of the inert seal medium and the idle seal medium on the side of the container, thereby eliminating the need to simplify the replacement of the size of the valve and other accessories commonly used in hazardous chemical containers.
  • Protect the volatilization and escape of material vapor achieve energy saving and emission reduction, and improve safety and reliability.
  • the present invention utilizes a well-known gaseous substance separation technology to realize that a gaseous inert seal medium source can provide and recover a gaseous inert seal medium, and can be used in a gaseous inert seal medium mixed with a vaporized molecule of a protected material. Separate and extract the functions of vaporized molecules of the protected material, recycle the gaseous inert seal medium, reduce the operating cost of the system, and meet the operational economic requirements.
  • the present invention can utilize the liquid valve of the inertial explosion suppression device to regulate the functions of the pressure and the amount of the gaseous inert sealing medium, and when the task of evacuating the material is performed, and the material is evacuated due to the misoperation, the gaseous state is obtained.
  • the inert seal medium is inerted with the material entering the pipeline, thus ensuring the safety of the system and the safety of internal cleaning, maintenance and other operations.
  • the present invention can utilize the Y-shaped pipe to guide the liquid fire-fighting medium source to the top of the container to support the cleaning task of the inner wall or the outer wall of the container.
  • the present invention can utilize the U-shaped sleeve to provide protection for the Y-type through-tube, and ensure that it effectively avoids the heat radiation during the participation in the emergency rescue process, and realizes the continuous near-tank top spray.
  • the present invention can utilize the liquid fire-fighting medium in the Y-shaped pipe as the self-control liquid valve for isolating the gaseous inerting medium and the atmosphere, and realizes that the pressure of the gaseous inert seal medium is greater than the design pressure, and the gaseous inert seal medium
  • the safety function of the partial gaseous inert sealing medium is released to the atmosphere.
  • the gas inerting medium pressure is less than the design pressure, and the gas-laden sealing medium source does not execute the gas supply command, the inerting device
  • the safety function of some air can be inhaled from the atmosphere to ensure equipment safety.
  • the present invention can follow the well-known fire chemistry, especially the principle of multi-stage shaped charge detonation, relying on the permanent and normalization to suppress the core function of the combustion and explosion conditions of the protected material, and eliminate the occurrence of chemistry.
  • the possibility of an explosion effectively prevents the oxygenated hydrocarbon gas in the gas phase from being detonated when subjected to a bombardment mode in the container of the warhead.
  • the present invention can follow the well-known Pascal's law, in the manner of providing a high-pressure venting channel and relatively expanding the gas phase space of the container when subjected to a bombardment mode attack in the warhead container. Effectively prevent the container from exploding due to rapid shrinkage of the gas phase space, rapid rise in temperature and pressure, causing the container to collapse or burst.
  • the present invention can automatically follow up or quickly start the gas supply of the gas inerting medium source when the container is subjected to the Monroe effect type or the kinetic energy type attack to form the bullet hole release pressure loss.
  • the system is mandatory to continuously fill the gas phase space of the container into the gaseous inert sealing medium, compensate the bullet hole discharge, and switch to the liquid fire medium mode when necessary; at the same time, quickly start the liquid supply system of the liquid fire medium source through the Y-type
  • the tube sprays the liquid fire-fighting medium to the top of the container to provide a near-tank cooling temperature for the container, and can be switched to a continuous release of the gaseous idle-sealing medium mode through the Y-shaped through-tube to the top of the container when necessary, thereby realizing partial oxygenation at the top of the container, thereby suppressing the container
  • the external material or its steam combustion explosion conditions are achieved.
  • Figure 1 is a schematic view showing the structure of an embodiment of an inertial seal suppression device for a hazardous chemical container according to the present invention.
  • FIG. 2 is a schematic view showing the structure of another embodiment of the inertial seal suppression device for a hazardous chemical container according to the present invention.
  • Fig. 3 is a structural schematic view showing still another embodiment of the inertial sealing and anti-explosive device for a dangerous chemical container according to the present invention.
  • Fig. 4 is a schematic view showing the structure of another embodiment of the inertial sealing and anti-explosive device for a dangerous chemical container according to the present invention.
  • FIG. 5 is a schematic flow chart of a defense method based on an embodiment of an inertial seal suppression device for a hazardous chemical container according to the present invention.
  • FIG. 1 is a schematic view showing the structure of an embodiment of an inertial seal suppression device for a hazardous chemical container according to the present invention.
  • the inert seal explosion-proof equipment for the hazardous chemical container includes an air-sealing device disposed on the hazardous chemical container 1, and the air-sealing device includes a U-shaped sleeve 3 installed in a vertical direction, a U-shaped sleeve
  • the tube 3 stores a liquid fire-fighting medium having a fire-fighting function with respect to the protected material in the dangerous chemical container
  • the U-shaped sleeve 3 includes a gas distribution side vertical pipe, a container side vertical pipe and a bottom joint pipe, and a bottom pipe
  • the two ends of the U-shaped sleeve 3 are respectively connected to the lower port of the gas distribution side vertical pipe and the container side vertical pipe, and the upper port of the gas distribution side vertical pipe of the U-shaped casing 3 is capable of being supplied and recovered with respect to the hazardous chemical container 1
  • the gas distribution side vertical pipe, the container side vertical pipe and the bottom coal pipe in the U-shaped casing 3 can be respectively It can be made and connected in turn, or it can be manufactured in one piece.
  • the U-shaped sleeve 3 may be installed wholly or partially outside the hazardous chemical container 1, or may be wholly or partially installed inside the hazardous chemical container 1, and the entire U-shaped sleeve 3 in Fig. 1 is installed in a hazardous chemical.
  • a plurality of U-shaped sleeves 3 may be provided, distributed outside the hazardous chemical container 1, or may be disposed in the hazardous chemical container 1, for example
  • An internal pipe passage is provided in the side wall of the hazardous chemical container 1, and a part of the U-shaped sleeve 3 may be disposed outside the hazardous chemical container 1 and the other portion may be disposed in the hazardous chemical container 1.
  • the gaseous inert seal medium always fills the gas phase space of the container and can be output and increased as the gas phase space in the container is reduced, the pressure in the gas phase space can be designed and regulated according to the saturated vapor pressure of the material to be protected.
  • the equipment can effectively prevent the combustion of explosive conditions from being achieved when the material to be protected is always isolated from the air.
  • the liquid fire-fighting medium is used as a self-controlling casing liquid valve between the source of the gaseous inerting medium and the dangerous chemical container by adopting a technical measure of filling the U-shaped casing with a liquid fire-fighting medium.
  • the inert seal medium is divided into two parts: the gaseous inerting medium on the gas distribution side and the gas inerting medium on the container side, which effectively supports the size and breathing of the hazardous chemical container, and prevents the material vapor and the gaseous inert seal medium from escaping into the air.
  • the simplification replaces the large and small breathing valves, fire-blocking valves, safety relief valves, rupture discs and other accessories commonly used in hazardous chemical containers to achieve energy saving and emission reduction, and improve safety and reliability.
  • lazy seal as used in this specification is not limited to the well-known concept of "nitrogen seal”. It should be understood that a suitable gaseous inert seal medium is selected according to the requirements of the material to be protected and the container, for example, selected from nitrogen, zero rare gas. a combination of one or more of carbon dioxide gas and water vapor.
  • “Small breathing” as used in this specification refers to the volume of the gas phase space of the container due to the environment. (ie, the external environment of the container), the container (ie, the dangerous chemical container in the foregoing), the temperature of the gas in the gas phase space in the material and the container, and the output or input of part of the gas is required to ensure the balance between the gas phase space of the container and the atmospheric pressure outside the container.
  • the small breathing of the container based on the above technical solution is realized: when the temperature of the gas in the gas phase space in the environment, the container, the material and the container is increased, the material expands, the liquid level of the material rises, the volume of the gas phase space of the container decreases, and the pressure of the gaseous inert seal medium Raising, the liquid level of the liquid fire-fighting medium in the pipeline driving the side of the U-shaped sleeve near the container is lowered, and the liquid level of the liquid fire-fighting medium in the pipeline near the source side of the gaseous inerting medium is raised; When the temperature of the gas in the gas phase space in the environment, the container, the material and the container is lowered, the material shrinks and the liquid level decreases, causing the gas phase space volume of the container to increase, and the pressure of the gas inerting medium is lowered, and the U-shaped sleeve is close to the container.
  • liquid level of the liquid fire-fighting medium in the standpipe on one side rises, and the level of the liquid fire-fighting medium in the line near the source side of the gas-laden seal medium decreases.
  • the liquid fire-fighting medium in the U-shaped sleeve can be used as a casing liquid valve to adjust and control the pressure of the gaseous inert medium in the container by using the automatic adjustment of the liquid level.
  • the liquid fire fighting medium herein may be selected from the group consisting of water, antifreeze, parent material liquid, water based fire fighting foam.
  • the large breathing of the container based on the above technical solution is realized: during the receiving operation, the liquid level of the material gradually rises, the gas phase space in the container gradually decreases, and the pressure of the gaseous inert sealing medium on the inner side of the container and the U-shaped sleeve gradually increases.
  • Raising which lowers the liquid level of the liquid fire-fighting medium in the vertical tube near the container side of the U-shaped sleeve, and the liquid level of the liquid fire-fighting medium in the vertical tube on the source side of the gaseous inerting medium rises when When the pressure reaches the design value, the gas collection system of the gaseous inert seal medium source is started, the pressure on the side is lowered, and the liquid fire-fighting medium in the side vertical pipe is returned to the container side vertical pipe under the action of gravity.
  • the flush release gaseous inert seal medium flows to the source of the gaseous inert seal medium, and the gaseous inert seal medium is filtered, washed, and depressurized by the liquid fire medium to be returned to the gaseous inert seal medium source for recovery until the system pressure is equalized;
  • the liquid level of the material gradually decreases, the gas phase space of the container gradually increases, and the pressure of the gaseous inert sealing medium in the container and the side vertical tube of the U-shaped sleeve container gradually decreases, so that the liquid fire-fighting medium liquid in the side vertical tube
  • the surface gradually rises, and the liquid level of the liquid fire medium in the riser near the source side of the gaseous inert seal medium decreases.
  • the gas supply system of the gaseous inert seal medium source starts, and the container side riser
  • the liquid fire-fighting medium is recirculated to the gas medium source side by gravity under the action of gravity, and the gaseous inert seal medium is pulsed into the container, and the gaseous inert seal medium is filtered and vented by the liquid fire-fighting medium, and then enters into the container until The delivery operation is completed or the system pressure is balanced.
  • the liquid fire-fighting medium filled in the U-shaped sleeve can divide the gaseous inert sealing medium into a gaseous inert sealing medium close to the gas distribution end of the gas inerting medium source side and a gas inertial sealing medium at the container end.
  • the elastic pressure adjustment of the gaseous inert seal medium can be realized, and the gaseous inert seal medium passing through can also be filtered and cleaned during large breathing.
  • gaseous inert seal medium source can recover the gaseous inert seal medium in the container during the container receiving operation, the material vapor molecules mixed in the gaseous inert seal medium can be separated and extracted, and then, when the container is being fed A relatively pure gaseous inert seal medium is provided within the vessel to effect recycling of the gaseous inert seal medium.
  • the traditional operation mode can only suck air into the pipeline, which poses a major safety hazard.
  • the gaseous inert seal medium can be carried into the material pipeline, and the inert seal can be implemented, thereby eliminating the safety hazard due to the inability to seal the material pipeline.
  • the embodiment further includes a liquid
  • the fire medium source 7 and the liquid fire medium source 7 are in liquid phase communication with the U-shaped sleeve 3, and provide, discharge, recycle or recycle the liquid fire-fighting medium to the inside of the U-shaped sleeve 3.
  • the liquid fire-fighting medium in the U-shaped casing separates the gaseous inerting medium into two parts, a gaseous inerting medium on the gas distribution side and a gaseous inert gas sealing medium on the container side.
  • the liquid fire medium source 7 can add or supplement the liquid fire-fighting medium to the U-shaped casing 3 at any time, and inject a preset amount of liquid fire-fighting medium into the U-shaped casing according to the preset liquid level height of the casing liquid valve to adjust the casing liquid.
  • the liquid fire medium source 7 combined with the Y-type pipe can also provide emergency fire protection and outer wall cleaning functions of the hazardous chemical container 1 itself.
  • the Y-shaped tube is described in detail later, and will not be described in detail here.
  • the air-sealing device may further comprise an air-sealing disk 10 disposed at the top of the hazardous chemical container 1, the air-tight disk 10 having a pressure relief hole 14, a disk waist connection hole 13, and a disk
  • the air-sealing disk 10 disposed at the top of the hazardous chemical container 1, the air-tight disk 10 having a pressure relief hole 14, a disk waist connection hole 13, and a disk
  • the top manhole 12 and the box cavity structure of the cover body 11 the pressure relief hole 14 of the idler disk 10 communicates with the top of the hazardous chemical container 1, and the container side port of the U-shaped sleeve 3 and the idler disk 10
  • the waist connection holes 13 are connected, and the top of the top hole 12 is closed by the cover 11.
  • the design of the idler disc is mainly to deal with the Monroe effect.
  • the bomb is designed to blast the oxygen-containing hydrocarbons in the gas-phase space in the detonation mode of the warhead.
  • the detonation here refers to the warhead. Detonation of self-contained oxidant in liquid type materials in hazardous chemical containers.
  • an idler disk with a box cavity structure is designed to effectively prevent chemical explosion, and also provide a channel and space for venting high pressure for the rapidly reducing gas phase space, thereby avoiding the top of the dangerous chemical container due to physics.
  • the explosion was slammed.
  • the pressure relief hole can be modified by the original manhole of the container, and the plurality of waist connection holes can be arranged to connect a plurality of U-shaped sleeves.
  • the gaseous inerting medium source 5 of the present embodiment includes a gas distribution pump system, a gas distribution manifold 56, a gas collection branch pipe 57, and a gas distribution branch pipe 58.
  • the gas distribution pump system includes a gas inerting medium generator 51 and a high pressure.
  • the storage tank 52, the gas distribution pressure regulating tank 53, the one-way air pump 55, the oil and gas separation device 54, and the connecting short pipe and the valve, the gas inerting medium generator 51, the high pressure storage tank 52 and the gas distribution pressure regulating tank 53 are connected in series Restricted to the gas distribution pipe 56, the one-way air pump 55, the oil and gas separation device 54 is connected in series to the gas collection branch pipe 57, and the gas collection branch pipe 57 is connected in parallel with the partial pipe of the gas distribution pipe 56 (ie, from the gas distribution pressure regulating tank 53) a pipeline between the gas distribution manifold 56 and the interface position of the gas distribution branch 58), the gas distribution manifold 56 and the gas distribution branch 58 are connected by a gas phase connection, and the gas distribution branch 58 and the gas distribution side vertical pipe of the U-shaped sleeve 3 The upper port is connected to the gas phase.
  • the gas distribution pump can supply the gaseous inerting medium to the hazardous chemical container 1 connected to the U-shaped sleeve 3 through the gas distribution tank 53, and can also recover the gaseous state from the U-shaped casing 3 through the one-way air pump 55 in the gas collection line.
  • the inert seal medium is introduced into the gas distribution tank 53.
  • the recovered gaseous inert seal medium may be mixed with components such as oil in the container (for example, oil vapor), the oil and gas separation device 54 connected in series in the gas collection branch 57 can reduce the loss of the protected material and eliminate the cause. Safety hazards and environmental pollution caused by evaporation of material vapor.
  • the liquid fire medium source 7 includes a fire pump system, a fire main pipe 74, and a fire branch pipe 75.
  • the fire pump system includes a fire medium storage facility 71, a fire pump 72, and a fire valve control device 73.
  • the fire medium storage facility 71 and the fire pump 72 are connected in series. Refused to the fire main 74, the fire main 74 and the fire branch 75 liquid connection, fire branch 75 It is in fluid communication with the bottom tube of the U-shaped sleeve 3.
  • a Y-shaped through tube 8 (refer to FIG. 2) may be disposed in the U-shaped sleeve 3, and the container-side port of the Y-shaped through tube 8 is from the container of the U-shaped sleeve 3.
  • the upper part of the side standpipe is close to the top of the hazardous chemical container 1 or is connected to the spray pipe 9 above the hazardous chemical container 1, and the gas distribution side port of the Y-type pipe 8 is suspended from the U-shaped bushing.
  • the preset height in the gas distribution side vertical pipe of 3 can inject liquid fire-fighting medium into the U-shaped casing 3, and the lower port of the Y-shaped pipe 8 is pierced from the bottom pipe of the U-shaped casing 3, and is connected with the fire branch pipe 75 liquid phase connection.
  • the liquid fire-fighting medium in the fire-fighting medium storage facility 71 can be sent to the Y-shaped pipe 8 through the fire-fighting pipe 74, and then sprayed through the spray pipe 9, thereby realizing the outer wall of the dangerous chemical container 1.
  • Cleaning, cooling and fire protection Due to the explosion of a dangerous chemical container 1 or a fire, the radiated heat energy will hinder the external spraying of the fire-fighting liquid, and the liquid fire-fighting medium sprayed directly from the spray port above the container can directly realize the fire fighting of the container.
  • the temperature of the outer wall of the container is lowered, so that timely fire protection work is performed on the container, and the cleaning is also more convenient.
  • the spray pipe 9 connected to the Y-shaped pipe 8 can also provide a water source for cleaning the inner wall of the hazardous chemical container 1.
  • the U-shaped sleeve 3 can function to protect the Y-shaped through tube 8.
  • the Y-type pipe is connected to the liquid source of the liquid fire-fighting medium, and the liquid fire-fighting medium source supplies the liquid fire-fighting medium to the U-shaped casing through the gas distribution side port of the Y-type pipe, and the liquid fire-fighting medium retained in the Y-type pipe is also It can be further used as a self-controlled through-pipe liquid valve for isolating the gaseous inertial sealing medium and the atmosphere, and adjusting the opening and closing pressure of the liquid-passing valve through setting the height of the gas distribution side port of the Y-shaped through-tube to realize the pressure of the gaseous inert sealing medium When the gas pressure is greater than the design pressure, and the gas inerting medium does not perform the gas-receiving command, the safety function of the partial gas-tight sealing medium is released to the atmosphere.
  • the air-sealing device can inhale some of the air's insurance function from the atmosphere, thus ensuring the safety of the container and equipment.
  • the U-shaped sleeve and the Y-shaped through-tube and the components and accessories thereof may be separately fabricated and sequentially connected, or integrally manufactured.
  • the gas phase space at the top of the hazardous chemical container is sharply reduced, and the high-pressure gaseous inerting medium can be released into the atmosphere through the Y-shaped pipe, which is a rapidly decreasing gas phase.
  • the space provides a venting high pressure passage to prevent the top of the hazardous chemical container from being blasted due to a physical explosion.
  • the gas supply system of the gas inerting sealing medium source is quickly started, and the gas phase space is continuously filled into the gas inerting medium to compensate the bullet hole venting, and when necessary Switch to the liquid fire medium mode; at the same time, quickly start the liquid supply system of the liquid fire medium, spray the liquid fire medium to the top of the container through the Y-type pipe, provide the tank with near tank cooling, and switch to pass if necessary
  • the Y-shaped through-tube continuously releases the gaseous idle-sealing medium mode to the top of the container to achieve partial oxygenation at the top of the container, thereby suppressing the achievement of the material outside the container or its steam combustion explosion condition.
  • Fig. 3 shows another Y-shaped through tube
  • the container side port and the gas distribution side port of the Y type through tube 15 are both penetrated from the bottom connecting tube of the U-shaped sleeve 3, and the container side of the Y-shaped through tube 15
  • the port passes through the upper portion of the container-side vertical tube of the U-shaped sleeve 3 near the top of the hazardous chemical container 1, or is connected to the spray pipe 9 above the hazardous chemical container 1, and the Y-shaped tube 15 is matched.
  • the gas side port is suspended at a preset height in the gas distribution side vertical pipe of the U-shaped sleeve 3, and the liquid fire-fighting medium can be injected into the U-shaped sleeve 3, and the lower port of the Y-shaped pipe 15 is connected to the fire-fighting branch pipe 75. Connected.
  • a valve 16 for controlling communication between the gas distribution side port of the Y-shaped pipe 15 and the fire branch pipe 15 may be disposed on the Y-shaped pipe 15, and when the valve 16 is closed, the air-sealing device is closed.
  • the pressure relief passage between the gaseous inerting medium and the atmosphere is cut off by the valve 16, and the liquid fire-fighting medium input from the hydraulic fire-fighting medium source can be directly ejected through the container-side port of the Y-shaped pipe through the container side port.
  • the top of the hazardous chemical container 1 is sprayed near the tank.
  • the gaseous inerting medium source 5 is passed through the gas distribution pipe 56, the gas collecting branch 57 and
  • the gas distribution pipe network 15 formed by the gas distribution branch pipe 58 is in gas-phase connection with the air-sealing device on each of the hazardous chemical containers 1, and the liquid fire-fighting medium source 7 passes through the fire-fighting pipe network composed of the fire main pipe 74 and the fire-fighting branch pipe 75 and various dangerous chemicals.
  • the bottom liquid phase of the inerting device on the product container 1 is connected to the liquid phase.
  • the gas distribution pipe network 15 itself has a certain gas pressure adjustment capability, and is capable of transferring the gaseous inert seal medium between the containers.
  • inert seal explosion-proof equipment for hazardous chemical containers, it can be applied to various large or small hazardous chemical containers, such as small oil tanks on tanks or tank trucks, according to hazardous chemicals.
  • the size of the container, the structural characteristics, the environment, the degree of threat, and the type of material to be contained, etc. can select a suitable source of gaseous inerting medium, and choose whether to connect the liquid fire medium source to the small oil tank body on the tank truck. It is also possible not to provide a special source of liquid fire-fighting medium, but also to select the use of the idle-sealing disc, the number and size of the relief holes.
  • the corresponding defense method is as shown in FIG. 5, and may include the following steps:
  • Step 101 According to the technical parameters of the container, the container group, the auxiliary facilities, the operating equipment and the material to be protected, combined with the technical parameters of the enemy missile, the design and assembly engineering of the idle seal anti-explosion equipment;
  • Step 102 Manufacture or select, according to the design result of the idle seal explosion-proof equipment, accessories of the inert seal explosion-proof equipment for the dangerous chemical container, and connect and install according to the listed engineering design result;
  • Step 103 Perform acceptance inspection of the assembly project according to the acceptance criteria listed in the listed engineering design result;
  • Step 104 selecting a negative pressure oxygen drive method or a liquid-filling oxygen-discharging method to realize a gas-state inertial sealing medium to drive oxygen to fill the gaseous inertial sealing medium source pipeline, the inerting device and the container gas phase space;
  • Step 105 operating a gaseous inert seal medium source and a liquid fire protection medium source to make it in a working state;
  • Step 106 operating a pump control system of the hazardous chemical container, performing a trial operation of the receiving and discharging operation, and checking the size and breathing function of the dangerous chemical container and the inertial anti-explosion device;
  • Step 107 After all the functional inspections are passed, the idle-sealed explosion-proof equipment is delivered and assembled, so as to realize the independent permanent defensive power of the tank group during the non-war time energy-saving emission reduction and the battle participation without conversion.
  • the negative pressure flooding method specifically includes:
  • step 104 the liquid-filling oxygen removal method specifically includes:
  • liquid fire-fighting medium source to vent or recover the liquid fire-fighting medium, and simultaneously introducing relatively pure gaseous inert sealing medium into all the pipelines of the gas distribution manifold, the gas distribution branch pipe, the gas collection branch pipe and the inerting device;
  • the steps of the trial run in step 106 include:

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)

Abstract

An inert seal explosion suppression device used for hazardous chemical container, and a defense method responding to multistage shaped charge that aims at conducting sympathetic detonation on oxygen-contained hydrocarbon gas in gas-phase space of the container in a mode of detonation inside the follow-through warhead container. The device comprises an inert seal device arranged on the hazardous chemical containers. The device comprises an U-shaped sleeve (3), a Y-shaped penetrating pipe is arranged inside the U-shaped sleeve, one upper port of the U-shaped sleeve is communicated with the gas-phase of a gas inert seal medium source, the other upper port of the U-shaped sleeve (3) is communicated with the container in gas-phase state through an inert seal disc on the top of the corresponding container, a port on the gas distribution side of the Y-shaped penetrating pipe is hung in a vertical pipe on the gas distribution side of the U-shaped sleeve, a side port of the container is connected with a spraying pipe on the top of the container, a bottom port communicated with a liquid-state fire protection medium source through a bottom connection pipe of the U-shaped sleeve, that can use a liquid valve of the sleeve as a large and small breath valve, and can use a liquid valve of the penetrating pipe as a safety relief valve, that can isolate systematically the atmosphere and restrain permanently the combustion explosion condition of the gas-phase space in the container and the pipelines.

Description

危险化学品容器用惰封抑爆装备及防御方法Idle-sealed anti-explosion equipment for dangerous chemical containers and defense method 技术领域Technical field
本发明涉及危险化学品安全生产与储运领域,尤其涉及一种危险化学品容器用惰封抑爆装备,以及列装该装备防御门罗效应弹种攻击的方法。The invention relates to the field of safe production, storage and transportation of dangerous chemicals, in particular to an inertial sealing and anti-explosion device for a dangerous chemical container, and a method for arranging the equipment to defend against the Monroe effect.
背景技术Background technique
随着兵工技术的进步,基于门罗效应研制的各类高效、远程、巡飞、精准、灵巧、便携等聚能装药破甲弹种不断创新、普遍列装、常践实战。尤其是串联有攻坚战斗部、破壁战斗部和随进战斗部的多级聚能装药,以危险化学品及容器为打击目标,实施前级攻坚钻地、中级侵彻破壁、末级随进容器爆轰,进而殉爆容器气相空间含氧烃类气体,造成整体化学爆炸的打击模式,毁伤力强、效费比高,是捣毁军用油库、重化园区等重要军事、经济目标的最优战术和必选弹种。With the advancement of ordnance technology, various types of high-efficiency, long-range, patrol, precision, dexterous, portable and other energy-generating armor-piercing ammunition developed based on the Monroe effect are constantly innovating, universally installed, and practiced. In particular, there are multi-stage shaped charge in the series, including the attacking warhead, the broken wall warhead and the accompanying warhead. The dangerous chemicals and containers are targeted, and the pre-level drills are drilled, the intermediate level penetrates the wall, and the final stage With the detonation of the container, the oxygenated hydrocarbon gas in the gas phase of the vessel is blasted, resulting in a blow mode of the overall chemical explosion, strong damage and high cost-effectiveness. It is an important military and economic target for destroying military oil depots and heavy chemical parks. Optimal tactics and mandatory bombs.
众所周知,诸如原油、燃料油等具有战略资源属性的能源类物料及其生产、储运设施、装备,既是国力的重要支撑,也是战力的重要组成。由于这类物料及容器具有典型的军民共用、平战通用和资产集聚等特性,在军事对抗或恐怖袭击等战事行动中必然成为战略利益焦点和战术攻防要冲。尤其是在能源日渐匮乏、需求大幅激增的推动下,大批足以形成多重毁伤、造成重大损害的危险化学品及容器,别无选择地裸露于人口稠密且疏于防范的经济、战略要地。As we all know, energy-based materials such as crude oil and fuel oil with strategic resource attributes and their production, storage and transportation facilities and equipment are important support for national power and an important component of combat power. Because such materials and containers have typical characteristics such as military-civilian sharing, peacetime generalization, and asset agglomeration, they must become strategic interests and tactical offensive and defensive in military operations such as military confrontation or terrorist attacks. In particular, driven by the growing shortage of energy and the sharp increase in demand, a large number of dangerous chemicals and containers that are capable of forming multiple damages and causing major damages are indiscriminately exposed to densely populated and unpredictable economic and strategic locations.
显而易见,危险化学品及容器应对门罗效应弹种攻击的技术装备与防御方法不可或缺。Obviously, hazardous chemicals and containers are indispensable for technical equipment and defense methods that attack the Monroe effect.
现有军用油库的战术性技术装备及防御方法仅涉及洞库隐 蔽、半地下伪装、浮顶技术等针对动能类、燃烧类弹种攻击的消防领域,但在现代侦查、制导和多级装药等攻击战力背景下,其独立性防御战力形同虚设。The tactical technical equipment and defense methods of the existing military oil depot only involve the cave library hidden Covered, semi-underground camouflage, floating roof technology and other fire-fighting fields for kinetic energy and combustion-type bomb attacks, but in the context of modern investigative, guidance and multi-level charges, the independent defense force is ineffective.
公知的抑爆材料应用技术,虽能在物料温度骤升时释放出抑制物料自由基生成的物质,但由于合金类网格状抑爆材料无法抑制容器气相空间含氧烃类气体的形成,故其无法在容器内爆轰情形下抑制含氧烃类气体被殉爆。The known anti-explosion material application technology can release the substance which inhibits the formation of free radicals when the material temperature rises rapidly, but the alloy-like grid-like anti-explosion material cannot inhibit the formation of oxygen-containing hydrocarbon gas in the gas phase space of the container, so It is not possible to suppress the oxygenated hydrocarbon gas from being detonated in the event of a detonation in the vessel.
公知的浮顶技术虽然提供了抑制物料大量蒸发的技术与方法,但在军事适用性和工业适用性方面均存在诸多不足。如外浮顶容器内的冗余空间必然存有物料蒸汽;传统硬质内浮顶技术则存在导向柱易松落、浮盘易变形、密封易失效,甚至液泛沉盘等诸多隐患,导致容器气相空间无法有效消除含氧烃类气体。Although the known floating roof technology provides a technique and method for suppressing a large amount of evaporation of materials, there are many disadvantages in terms of military applicability and industrial applicability. For example, the redundant space in the outer floating roof container must contain material steam; the traditional rigid inner floating roof technology has many hidden dangers such as easy to loose guide column, easy deformation of the floating plate, easy to seal, and even liquid pan. The gas phase space of the vessel cannot effectively eliminate the oxygenated hydrocarbon gas.
由本发明人发明的中国发明专利《气垫型径向弹性密封式浮顶及使用该浮顶的消防方法》ZL97119189.1,虽然提供了将气体型惰性介质作为软质内浮顶衬气,常态化敷满被保护物料表面的技术方案,克服了硬质内浮顶的诸多缺陷,弥补了US3002828号美国发明专利所提供的软质内浮顶未使用惰封衬气等诸多不足,能够在容器内爆轰情形下有效防御含氧烃类气体被殉爆,但该项现有技术在军事适用性方面仍存在以下不足:1、该技术方案虽能在一定程度上应对随进战斗部以殉爆含氧烃类气体模式形成化学爆炸的打击,但未考虑容器内爆轰后的能量泄放功能,存在受弹危险化学品容器形成物理爆炸的可能;2、该技术方案不带有跟进消防介质参与扑救或增强防护能力等功能。此外,该技术方案在工业适用性方面也存在以下不足:1、惰性衬气无法循环使用;2、惰性衬气无法跟进物料管道;3、无法从惰性衬气中分离、汲取气态物料。The Chinese invention patent "Air Cushion Radial Elastic Sealed Floating Roof and Fire Fighting Method Using the Floating Roof" ZL97119189.1, which is invented by the inventor, provides a gas-type inert medium as a soft inner floating lining gas, which is normalized. The technical solution of covering the surface of the protected material overcomes many defects of the hard inner floating roof, and makes up for the shortcomings of the soft inner floating roof and the unused inertial sealing gas provided by the US Patent No. US3002828, which can be in the container. In the case of detonation, the effective defense against oxygenated hydrocarbon gas is detonated. However, this prior art still has the following shortcomings in military applicability: 1. Although the technical solution can cope with the warfare part to some extent The oxygen-containing hydrocarbon gas mode forms a chemical explosion, but does not consider the energy venting function after the detonation in the container, and there is a possibility of physical explosion of the hazardous chemical container; 2. The technical solution does not carry out follow-up fire The media participates in functions such as saving or enhancing protection. In addition, the technical solution also has the following shortcomings in industrial applicability: 1. The inert gas line cannot be recycled; 2. The inert gas line cannot follow the material pipe; 3. The gas can not be separated from the inert gas line and the gas material can be extracted.
总之,现有技术涉及危险化学品及容器的防御观念拘泥于非 战防范;防范策略注重于明火消防;消防功能局限于应急救援。In short, the prior art is concerned with the defensive concepts of hazardous chemicals and containers. War prevention; prevention strategy focuses on open fire; fire protection is limited to emergency rescue.
发明内容Summary of the invention
本发明的第一目的是提出一种危险化学品容器用惰封抑爆装备,能够在满足生产、储运运行要求的前提下,采用以气态惰封介质充斥容器气相空间的技术措施,控制容器气相空间含氧浓度常态化小于被保护物料燃烧爆炸极限下线,从而永久性抑制容器内危险化学品类物料燃烧爆炸条件成就。The first object of the present invention is to provide an inertial sealing and anti-explosion device for a dangerous chemical container, which can adopt the technical measures of filling the gas phase space of the container with a gaseous inert sealing medium under the premise of satisfying the requirements of production, storage and transportation, and controlling the container. The normalization of the oxygen content in the gas phase space is less than the lower limit of the combustion explosion limit of the protected material, thereby permanently inhibiting the combustion and explosion conditions of the hazardous chemical materials in the container.
本发明的第二目的是提出一种危险化学品容器用惰封抑爆装备,能够以液态消防介质作为气态惰封介质源和容器气相空间之间、气态惰封介质和大气之间的自控型液体阀门,取代危险化学品容器用大小呼吸阀、安全阀、阻火阀、防爆片等组件、配件,实现全系统生产、储运作业过程隔绝大气。A second object of the present invention is to provide an inertial seal suppression device for a hazardous chemical container, which is capable of using a liquid fire-fighting medium as a self-control type between a gaseous inertial seal medium source and a container gas phase space, a gaseous inert seal medium and the atmosphere. The liquid valve replaces the components and accessories of the large and small breathing valve, safety valve, fire stop valve, rupture disk, etc. for the dangerous chemical container to realize the whole system production, storage and transportation process to isolate the atmosphere.
本发明的第三目的是提出一种危险化学品容器用惰封抑爆装备,能够从气态惰封介质中分离、汲取气态化物料分子,并循环使用气态惰封介质,降低运行成本。A third object of the present invention is to provide an inertial seal suppression device for a hazardous chemical container, which is capable of separating and extracting gaseous molecules from a gaseous inert seal medium and recycling the gaseous inert seal medium to reduce operating costs.
本发明的第四目的是提出一种危险化学品容器用惰封抑爆装备,能够在抽空容器内物料时将气态惰封介质随入物料管路,进一步保障人员与装备安全。A fourth object of the present invention is to provide an inertial sealing and anti-explosion device for a dangerous chemical container, which can carry the gaseous inert sealing medium into the material pipeline when evacuating the material in the container, thereby further ensuring the safety of personnel and equipment.
本发明的第五目的是提出一种危险化学品容器用惰封抑爆装备,能够在容器顶部实施近罐喷淋液态消防介质,支持容器降温和清洁容器等作业。A fifth object of the present invention is to provide an inert seal anti-explosion device for a hazardous chemical container, which is capable of spraying a liquid fire-fighting medium near the tank at the top of the container, and supporting the container to cool down and clean the container.
本发明的第六目的是提出一种基于危险化学品容器用惰封抑爆装备的防御方法,能够有效应对门罗效应弹种旨在以随进战斗部容器内爆轰模式殉爆气相空间含氧烃类气体的打击。The sixth object of the present invention is to propose a defense method based on an inertial sealing and anti-explosion device for a dangerous chemical container, which can effectively cope with the Monroe effect elastic type, which is intended to blast the gas phase space in the detonation mode of the warhead container. Strike of oxygen hydrocarbon gas.
本发明的第七目的是提出一种危险化学品容器用惰封抑爆装备及防御方法,能够在应急扑救过程中有效保护向危险化学品 容器顶部实施近罐喷射液态消防介质的消防管路免遭热辐射损毁,能够将近罐喷射液态消防介质模式切换为近罐释放气态惰封介质模式,能够将向容器内跟进气态惰封介质模式切换为注入液态消防介质模式。The seventh object of the present invention is to provide an inertial sealing and anti-explosion device for a dangerous chemical container and a defense method thereof, which can effectively protect the dangerous chemicals in the emergency fighting process. The fire-fighting pipeline of the near-can sprayed liquid fire-fighting medium is protected from heat radiation damage at the top of the vessel, and the near-tank injection liquid fire-fighting medium mode can be switched to the near-tank release gaseous idle-sealing medium mode, and the air-filled air-tight medium mode can be introduced into the container. Switch to inject liquid fire media mode.
为实现上述目的,本发明提供了一种危险化学品容器用惰封抑爆装备,其中,包括设置在危险化学品容器上的惰封装置,所述惰封装置包括在竖直方向上安装的U型套管,所述U型套管内储有相对于所述危险化学品容器内的被保护物料具有消防功能的液态消防介质,所述U型套管包括配气侧竖管、容器侧竖管和底联管,所述底联管的两个端口分别与所述配气侧竖管和容器侧竖管的下端口接驳连通,所述U型套管的配气侧竖管的上端口与能够提供和回收相对于所述危险化学品容器内的被保护物料具有化学稳定性的气态惰封介质的气态惰封介质源气相连通,所述U型套管的容器侧竖管的上端口与所述危险化学品容器的顶部气相连通。In order to achieve the above object, the present invention provides an inertial anti-explosion device for a hazardous chemical container, comprising an air-sealing device disposed on a hazardous chemical container, the air-sealing device including being installed in a vertical direction a U-shaped sleeve in which a liquid fire-fighting medium having a fire-fighting function relative to a material to be protected in the hazardous chemical container is stored, the U-shaped sleeve including a gas distribution side vertical tube and a container side vertical a tube and a bottom tube, wherein the two ports of the bottom tube are respectively in communication with the lower side ports of the gas distribution side vertical tube and the container side vertical tube, and the upper side of the gas distribution side vertical tube of the U-shaped sleeve The port is in gaseous communication with a source of gaseous inert seal medium capable of providing and recovering a gaseous inert seal medium chemically stable relative to the protected material within the hazardous chemical container, the U-shaped sleeve being on the container side riser The port is in gas phase communication with the top of the hazardous chemical container.
进一步的,所述气态惰封介质源包括配气泵系、配气总管、收气支管和配气支管,所述配气泵系包括气态惰封介质发生器、高压储罐、配气调压罐、单向气泵、油气分离装置及接驳短管和阀门,所述气态惰封介质发生器、所述高压储罐和所述配气调压罐依次串联接驳于所述配气总管,所述单向气泵、油气分离装置串联接驳于所述收气支管,所述收气支管并联于所述配气总管的部分管路,所述配气总管与所述配气支管气相接驳联通,所述配气支管与所述U型套管的配气侧竖管的端口气相接驳连通。Further, the gas inerting medium source comprises a gas distribution pump system, a gas distribution manifold, a gas collection branch pipe and a gas distribution branch pipe, and the gas distribution pump system comprises a gas inerting medium generator, a high pressure storage tank, a gas distribution pressure tank, a one-way air pump, an oil and gas separation device, and a connecting short pipe and a valve, wherein the gas inerting medium generator, the high pressure storage tank and the gas distribution pressure tank are connected in series to the gas distribution manifold, The one-way air pump and the oil-gas separation device are connected in series to the gas-receiving branch pipe, and the gas-receiving branch pipe is connected in parallel to a part of the pipeline of the gas distribution main pipe, and the gas distribution main pipe and the gas distribution branch pipe are connected in a gas phase connection, The gas distribution branch pipe is in gas phase connection with the port of the gas distribution side vertical pipe of the U-shaped sleeve.
进一步的,还包括液态消防介质源,所述液态消防介质源与所述U型套管液相连通,向所述U型套管内部提供能够泄放、回收或循环使用的所述液态消防介质,所述U型套管中的所述液态消防介质作为套管液体阀门将所述气态惰封介质分隔成配气侧的 气态惰封介质和容器侧的气态惰封介质两部分,所述液态消防介质源根据所述套管液体阀门的预设液位高度向所述U型套管注入预设量的液态消防介质,以调节所述套管液体阀门的开闭压力。Further, the invention further includes a liquid fire-fighting medium source, wherein the liquid fire-fighting medium source is in liquid phase communication with the U-shaped sleeve, and the liquid fire-fighting medium capable of being discharged, recycled or recycled is provided inside the U-shaped sleeve. The liquid fire-fighting medium in the U-shaped sleeve separates the gaseous inert seal medium into a gas distribution side as a casing liquid valve a gaseous inert seal medium and a gas-tight seal medium on the container side, the liquid fire-fighting medium source injecting a predetermined amount of liquid fire-fighting medium into the U-shaped sleeve according to a preset liquid level height of the sleeve liquid valve, To adjust the opening and closing pressure of the casing liquid valve.
进一步的,所述液态消防介质源包括消防泵系、消防总管和消防支管,所述消防泵系包括消防介质存储设施、消防泵和消防阀控设备,所述消防介质存储设施和所述消防泵依次串联接驳于所述消防总管,所述消防总管与所述消防支管液相接驳连通,所述消防支管与所述U型套管的底联管液相接驳连通。Further, the liquid fire medium source includes a fire pump system, a fire main pipe and a fire branch pipe, and the fire pump includes a fire medium storage facility, a fire pump and a fire valve control device, the fire medium storage facility and the fire pump The fire mains are connected in series with the fire main pipe in series, and the fire main pipe is connected to the liquid pipe of the U-shaped bushing.
进一步的,在所述U型套管内还设有一Y型穿管,所述Y型穿管的下端口从所述U型套管的底联管穿出,并与所述消防支管液相接驳连通,所述Y型穿管的容器侧端口从所述U型套管的容器侧竖管上部接近所述危险化学品容器的顶部的位置穿出,或与所述危险化学品容器的上方的喷淋管接驳,所述Y型穿管的配气侧端口悬于所述U型套管的配气侧竖管内的预设高度,能够向所述U型套管内注入所述液态消防介质。Further, a Y-shaped through tube is further disposed in the U-shaped sleeve, and a lower port of the Y-shaped through tube passes through the bottom tube of the U-shaped sleeve and is connected to the fire branch tube Connecting the container side port of the Y-shaped through tube from the upper portion of the container-side standpipe of the U-shaped sleeve close to the top of the hazardous chemical container, or above the dangerous chemical container a spray pipe connection, wherein a gas distribution side port of the Y-shaped pipe is suspended from a predetermined height in a gas distribution side vertical pipe of the U-shaped casing, and the liquid fire protection can be injected into the U-shaped casing medium.
进一步的,在所述U型套管外还设有一Y型穿管,所述Y型穿管的下端口与所述消防支管液相接驳连通,所述Y型穿管的容器侧端口和配气侧端口均从所述U型套管的底联管穿入,所述Y型穿管的容器侧端口通过所述U型套管的容器侧竖管上部接近所述危险化学品容器的顶部的位置穿出,或与所述危险化学品容器的上方的喷淋管接驳,所述Y型穿管的配气侧端口悬于所述U型套管的配气侧竖管内的预设高度,能够向所述U型套管内注入所述液态消防介质。Further, a Y-shaped through tube is further disposed outside the U-shaped sleeve, and a lower port of the Y-shaped through tube is in fluid communication with the fire branch pipe, and a container side port of the Y-shaped through tube and a gas distribution side port penetrates from a bottom pipe of the U-shaped sleeve, and a container side port of the Y-shaped pipe passes through an upper portion of the container side vertical pipe of the U-shaped casing to approach the dangerous chemical container The top position is pierced or connected to the spray pipe above the hazardous chemical container, and the gas distribution side port of the Y-shaped pipe is suspended in the gas distribution side vertical pipe of the U-shaped sleeve The height is such that the liquid fire-fighting medium can be injected into the U-shaped sleeve.
进一步的,所述Y型穿管与所述液态消防介质源液相连通,所述液态消防介质源通过所述Y型穿管的配气侧端口向所述U型套管内提供所述液态消防介质,所述Y型穿管中滞留的液态消防介质作为穿管液体阀门,将所述气态惰封介质与大气隔离,通过 设定所述Y型穿管的配气侧端口的高度来调节所述穿管液体阀门的开闭压力。Further, the Y-shaped through tube is in liquid phase communication with the liquid fire-fighting medium source, and the liquid fire-fighting medium source supplies the liquid fire-fighting to the U-shaped sleeve through a gas distribution side port of the Y-shaped through tube a medium, the liquid fire-fighting medium retained in the Y-shaped pipe is used as a pipe-through liquid valve to isolate the gaseous inert seal medium from the atmosphere The height of the gas distribution side port of the Y-shaped pipe is set to adjust the opening and closing pressure of the pipe-through liquid valve.
进一步的,在所述Y型穿管上还设有控制所述Y型穿管的配气侧端口与所述消防支管之间连通的阀门,当该阀门关闭时,所述惰封装置内的气态惰封介质与大气之间的泄压通道被该阀门切断,所述液态消防介质源输入的液态消防介质能够直接经所述Y型穿管的容器侧端口喷出。Further, a valve for controlling communication between the gas distribution side port of the Y-shaped pipe and the fire branch pipe is further disposed on the Y-shaped pipe, and when the valve is closed, the inside of the air-sealing device The pressure relief passage between the gaseous inert seal medium and the atmosphere is shut off by the valve, and the liquid fire-fighting medium input from the liquid fire-fighting medium source can be directly ejected through the container side port of the Y-shaped through tube.
进一步的,所述危险化学品容器有两个以上,每个所述危险化学品容器配装至少一套惰封装置,所述气态惰封介质源通过由配气总管、收气支管和配气支管构成的配气管网与各个所述危险化学品容器上的惰封装置气相接驳连通,所述液态消防介质源通过由消防总管和消防支管构成的消防管网与各个所述危险化学品容器上的惰封装置的底部液相接驳连通。Further, there are more than two hazardous chemical containers, each of which is equipped with at least one set of inerting devices, and the source of the gaseous inerting medium passes through a gas distribution manifold, a gas collection branch pipe and a gas distribution valve. a gas distribution pipe network formed by the branch pipe is in gas phase connection with an inerting device on each of the dangerous chemical containers, and the liquid fire fighting medium source passes through a fire pipe network composed of a fire main pipe and a fire branch pipe and each of the dangerous chemical containers The bottom liquid phase connection of the upper inert seal device is connected.
进一步的,所述惰封装置还包括设置在所述危险化学品容器的顶部的惰封盘,所述惰封盘为带有泄压孔、盘腰接驳孔、盘顶人孔和盖体的箱式空腔结构体,所述惰封盘的泄压孔与所述危险化学品容器的顶部泄压孔气相接驳连通,所述U型套管的容器侧竖管的上端口与所述惰封盘上的盘腰接驳孔气相接驳连通,所述盘顶人孔上方通过所述盖体进行封闭。Further, the air-sealing device further includes an air-sealing disk disposed at a top of the hazardous chemical container, the air-latching disk is provided with a pressure relief hole, a disk waist connection hole, a top plate manhole and a cover body a box-type cavity structure, the pressure relief hole of the idler disk is in gas-phase communication with the top pressure relief hole of the hazardous chemical container, and the upper port of the container side standpipe of the U-shaped sleeve The disk waist connecting hole on the idle sealing disk is connected to the gas phase connection, and the top of the disk top hole is closed by the cover body.
进一步的,所述气态惰封介质为氮气、零族稀有气体、二氧化碳气体和水蒸汽中的一种或多种的组合,所述液态消防介质为水、防冻液、亲物料液体、水基消防泡沫中的一种或多种的组合。Further, the gaseous inerting medium is a combination of one or more of nitrogen, a rare earth gas, carbon dioxide gas and water vapor, and the liquid fire fighting medium is water, antifreeze liquid, parent material liquid, water based fire protection A combination of one or more of the foams.
进一步的,所述U型套管全部或部分安装在所述危险化学品容器的外部,或者全部或部分安装在所述危险化学品容器内部。Further, the U-shaped sleeve is wholly or partially installed outside the hazardous chemical container, or is wholly or partially installed inside the hazardous chemical container.
进一步的,所述U型套管和所述Y型穿管及其各组件、配件为分别制作并依次接驳,或一体制造。Further, the U-shaped sleeve and the Y-shaped through tube and its components and accessories are separately fabricated and sequentially connected, or integrally manufactured.
为实现上述目的,本发明还提供了一种基于前述危险化学品 容器用惰封抑爆装备的防御方法,包括:To achieve the above object, the present invention also provides a hazardous chemical based on the foregoing Defence methods for inertial seal suppression equipment for containers, including:
根据容器、容器群、辅助设施、操作设备及被保护物料的技术参数,结合敌弹技术参数进行惰封抑爆装备设计和列装工程设计;According to the technical parameters of the container, the container group, the auxiliary facilities, the operating equipment and the material to be protected, combined with the technical parameters of the enemy missile, the design and assembly engineering of the idle-sealed explosion-proof equipment;
根据所述惰封抑爆装备的设计成果制造或选配所述危险化学品容器用惰封抑爆装备的组件、配件,并按列装工程设计成果接驳和安装;Manufacture or select components and accessories for the inertial seal explosion-proof equipment for the dangerous chemical container according to the design result of the inert seal suppression equipment, and connect and install according to the listed engineering design result;
根据列装工程设计成果所列验收标准进行列装工程验收;The acceptance of the installation project shall be carried out according to the acceptance criteria listed in the listed engineering design results;
选用负压驱氧法或充液驱氧法实现气态惰封介质驱氧充斥气态惰封介质源管路、惰封装置及容器气相空间;The negative pressure oxygen drive method or the liquid-filled oxygen-discharging method is adopted to realize the gas-filled medium-driven oxygen-filled gas inertial seal medium source pipeline, the inert seal device and the container gas phase space;
操作气态惰封介质源和液态消防介质源,使之处于工作状态;Operating a gaseous inert seal medium source and a liquid fire medium source to operate in a working state;
操作所述危险化学品容器的泵控系统,进行收料付料作业试运行,检验所述危险化学品容器和所述惰封抑爆装备的大小呼吸功能;Operating a pump control system of the hazardous chemical container, performing a trial operation of the receiving and discharging operation, and inspecting the size and breathing function of the hazardous chemical container and the inertial anti-explosion device;
在全部功能检验合格后,惰封抑爆装备交付列装,实现危险化学品及容器非战时节能减排和临战参战无需转换的独立性永久性防御战力。After all the functional inspections are passed, the inertial explosion-proof equipment is delivered and packaged, achieving independent non-wartime energy-saving emission reduction of non-wartime chemicals and containers, and independent permanent defensive combat without conversion.
进一步的,所述负压驱氧法的具体步骤包括:Further, the specific steps of the negative pressure oxygen drive method include:
操作所述液态消防介质源,将液态消防介质注满Y型穿管,形成穿管液体阀门;Operating the liquid fire-fighting medium source, filling the liquid fire-fighting medium with a Y-shaped through pipe to form a pipe-through liquid valve;
操作所述气态惰封介质源,向所述容器方向供气,同时,从所述危险化学品容器或其管路中的较低处抽出气体排入大气,直至所述危险化学品容器及其连通的管路中的含氧量达标。Operating the source of gaseous inerting medium to supply gas to the vessel while simultaneously withdrawing gas from the lower portion of the hazardous chemical vessel or its piping into the atmosphere until the hazardous chemical vessel and its The oxygen content in the connected pipeline is up to standard.
进一步的,所述充液驱氧法的具体步骤包括:Further, the specific steps of the liquid-filled oxygen flooding method include:
操作所述危险化学品容器收料作业至最高物料液位,此过程中的容器内的大部分气体经套管液态阀门进入配气侧气相空间, 再经穿管液体阀门排至大气,实现容器驱氧;Operating the hazardous chemical container receiving operation to the highest material level, in the process, most of the gas in the container enters the gas distribution side gas phase space through the casing liquid valve. Then, the liquid valve is discharged to the atmosphere through the pipe, and the container is driven to drive oxygen;
操作所述液态消防介质源,将液态消防介质注满所述惰封抑爆装备的全部管路,实现惰封抑爆装备的全部或大部分管路驱氧;Operating the liquid fire-fighting medium source, filling the liquid fire-fighting medium with all the pipelines of the idle-sealed explosion-proof equipment, and realizing all or most of the pipelines of the inert-sealed explosion-proof equipment to drive oxygen;
操作所述气态惰封介质源制备气态惰性介质,开启供气阀门;Operating the gaseous inerting medium source to prepare a gaseous inert medium, and opening a gas supply valve;
操作所述液态消防介质源泄放或回收液态消防介质,同时将相对纯净的气态惰封介质引入配气总管、配气支管、收气支管和惰封装置的全部管路;Operating the liquid fire-fighting medium source to vent or recover the liquid fire-fighting medium, and simultaneously introducing relatively pure gaseous inert sealing medium into all the pipelines of the gas distribution manifold, the gas distribution branch pipe, the gas collection branch pipe and the inerting device;
调整U型套管内的液位高度,形成套管液体阀门,至工作液位;Adjusting the liquid level in the U-shaped sleeve to form a casing liquid valve to the working liquid level;
调整Y型穿管内的液位高度,形成穿管液体阀门,至安全液位;Adjust the liquid level in the Y-shaped pipe to form a liquid pipe through the pipe to a safe liquid level;
操作所述危险化学品容器付料作业,将气态惰封介质吸入所述危险化学品容器的气相空间;Operating the hazardous chemical container receiving operation to draw a gaseous inerting medium into the gas phase space of the hazardous chemical container;
查验所述危险化学品容器的气相空间含氧量是否低于被保护物料爆炸极限下限或设计含量。Check whether the oxygen content of the gas phase space of the hazardous chemical container is lower than the lower limit of the explosion limit of the protected material or the designed content.
进一步的,所述试运行的步骤包括:Further, the steps of the trial run include:
分别查验所述危险化学品容器和所述惰封抑爆装备的压力和氧含量测定装置,记录初始数据;Detecting the pressure and oxygen content measuring device of the hazardous chemical container and the inertial anti-explosion device separately, and recording initial data;
进行收料作业试运行,分别查验所述危险化学品容器和所述惰封抑爆装备的压力和氧含量测定装置,记录压力和氧含量数据;Performing a trial run of the receiving operation, respectively checking the pressure and oxygen content measuring device of the dangerous chemical container and the inert seal suppressing device, and recording pressure and oxygen content data;
进行付料作业试运行,分别查验所述危险化学品容器和所述惰封抑爆装备的压力和氧含量测定装置,记录压力和氧含量数据;Carrying out the trial operation of the paying operation, respectively checking the pressure and oxygen content measuring device of the dangerous chemical container and the inert seal suppressing device, and recording the pressure and oxygen content data;
检测所述气态惰封介质源和液态消防介质源的诸组件及部件功能;Detecting components of the gaseous inert seal medium source and the liquid fire fighting medium source and component functions;
设计并实施破坏性实验,查验安全泄压功能。Design and implement destructive experiments to check the safety relief function.
本发明的积极效果结合以下公知的科学原理给出: The positive effects of the present invention are presented in conjunction with the following well-known scientific principles:
本发明遵循公知的物质燃烧爆炸条件和该条件的成就机理,利用气态惰封介质系统化充斥容器和管路的动态化气相空间,将该气相空间的含氧量控制在被保护物料爆炸极限下限以下,在满足生产、储运作业要求的前提下,实现永久性、常态化抑制被保护物料燃烧爆炸条件成就的核心功能。The invention follows the known combustion and explosion conditions of the substance and the achievement mechanism of the condition, and utilizes the gaseous inerting medium to systematically liquefy the dynamic gas phase space of the container and the pipeline, and control the oxygen content of the gas phase space to the lower limit of the explosion limit of the protected material. In the following, under the premise of meeting the requirements of production, storage and transportation, the core function of permanent and normalization to suppress the combustion and explosion conditions of the protected materials is achieved.
进一步的,基于上述技术方案,本发明利用公知的液态物质特性,采用向U型套管内充入液态消防介质的技术措施,将液态消防介质做为气态惰封介质源与容器之间的自控液体阀门,将气态惰封介质分隔成惰封介质源侧惰封介质和容器侧惰封介质二个部分,从而在简约化取代危险化学品容器常用的大小呼吸阀等配件的基础上,消除了被保护物料蒸汽的挥发、逸散,实现节能减排,提高安全性、可靠性。Further, based on the above technical solution, the present invention utilizes the known liquid substance characteristics, adopts a technical measure of filling a U-shaped casing with a liquid fire-fighting medium, and uses the liquid fire-fighting medium as a self-control liquid between the source of the gaseous inert seal medium and the container. The valve separates the gaseous inert seal medium into two parts of the inertial seal medium on the source side of the inert seal medium and the idle seal medium on the side of the container, thereby eliminating the need to simplify the replacement of the size of the valve and other accessories commonly used in hazardous chemical containers. Protect the volatilization and escape of material vapor, achieve energy saving and emission reduction, and improve safety and reliability.
进一步的,基于上述技术方案,本发明利用公知的气态物质分离技术,实现了气态惰封介质源可以提供和回收气态惰封介质,并可从混有被保护物料汽化分子的气态惰封介质中分离、汲取被保护物料汽化分子等功能,循环使用气态惰封介质,降低系统运行成本,满足运行经济性要求。Further, based on the above technical solution, the present invention utilizes a well-known gaseous substance separation technology to realize that a gaseous inert seal medium source can provide and recover a gaseous inert seal medium, and can be used in a gaseous inert seal medium mixed with a vaporized molecule of a protected material. Separate and extract the functions of vaporized molecules of the protected material, recycle the gaseous inert seal medium, reduce the operating cost of the system, and meet the operational economic requirements.
进一步的,基于上述技术方案,本发明能够利用惰封抑爆装备的液体阀门调控气态惰封介质压力和用量等功能,在执行抽空物料任务时,以及因误操作而抽空物料情形下,令气态惰封介质随物料进入管路实施惰封,从而保障系统安全和内部清洗、检修维护等作业使得的人员安全。Further, based on the above technical solution, the present invention can utilize the liquid valve of the inertial explosion suppression device to regulate the functions of the pressure and the amount of the gaseous inert sealing medium, and when the task of evacuating the material is performed, and the material is evacuated due to the misoperation, the gaseous state is obtained. The inert seal medium is inerted with the material entering the pipeline, thus ensuring the safety of the system and the safety of internal cleaning, maintenance and other operations.
进一步的,基于上述技术方案,本发明能够利用Y型穿管将液态消防介质源引至容器顶部,支持容器内壁或外壁清洁任务。Further, based on the above technical solution, the present invention can utilize the Y-shaped pipe to guide the liquid fire-fighting medium source to the top of the container to support the cleaning task of the inner wall or the outer wall of the container.
进一步的,基于上述技术方案,本发明能够利用U型套管对Y型穿管提供保护,保障其在参与应急扑救过程中有效避开热辐射,实现连续近罐顶部喷淋。 Further, based on the above technical solution, the present invention can utilize the U-shaped sleeve to provide protection for the Y-type through-tube, and ensure that it effectively avoids the heat radiation during the participation in the emergency rescue process, and realizes the continuous near-tank top spray.
进一步的,基于上述技术方案,本发明能够利用Y型穿管内的液态消防介质作为隔离气态惰封介质与大气的自控液体阀门,实现当气态惰封介质的压力大于设计压力,且气态惰封介质源未执行收气指令时,向大气泄放部分气态惰封介质的保险功能,同理,当气态惰封介质压力小于设计压力,且气态惰封介质源未执行供气指令时,惰封装置可从大气中吸入部分空气的保险功能,从而保障装备安全。Further, based on the above technical solution, the present invention can utilize the liquid fire-fighting medium in the Y-shaped pipe as the self-control liquid valve for isolating the gaseous inerting medium and the atmosphere, and realizes that the pressure of the gaseous inert seal medium is greater than the design pressure, and the gaseous inert seal medium When the source does not execute the gas-receiving instruction, the safety function of the partial gaseous inert sealing medium is released to the atmosphere. Similarly, when the gas inerting medium pressure is less than the design pressure, and the gas-laden sealing medium source does not execute the gas supply command, the inerting device The safety function of some air can be inhaled from the atmosphere to ensure equipment safety.
进一步的,基于上述技术方案,本发明能够遵循公知的火灾化学、尤其是多级聚能装药爆轰原理,依托永久性、常态化抑制被保护物料燃烧爆炸条件成就的核心功能,消除发生化学爆炸的可能性,进而在遭受门罗效应弹种随进战斗部容器内爆轰模式攻击时,有效防止气相空间含氧烃类气体被殉爆。Further, based on the above technical solutions, the present invention can follow the well-known fire chemistry, especially the principle of multi-stage shaped charge detonation, relying on the permanent and normalization to suppress the core function of the combustion and explosion conditions of the protected material, and eliminate the occurrence of chemistry. The possibility of an explosion, in turn, effectively prevents the oxygenated hydrocarbon gas in the gas phase from being detonated when subjected to a bombardment mode in the container of the warhead.
进一步的,基于上述技术方案,本发明能够遵循公知的帕斯卡定律,在遭受门罗效应弹种随进战斗部容器内爆轰模式攻击时,以提供高压泄放通道、相对扩大容器气相空间的方式有效防止容器因气相空间急速缩小、温度、压力急速升高而发生物理爆炸,造成容器轰顶或爆裂。Further, based on the above technical solution, the present invention can follow the well-known Pascal's law, in the manner of providing a high-pressure venting channel and relatively expanding the gas phase space of the container when subjected to a bombardment mode attack in the warhead container. Effectively prevent the container from exploding due to rapid shrinkage of the gas phase space, rapid rise in temperature and pressure, causing the container to collapse or burst.
进一步的,基于上述技术方案,本发明能够在所述容器遭受门罗效应弹种或动能弹种攻击,形成弹孔泄放失压时,自动跟进或快速启动气态惰封介质源的供气系统,强制性向容器气相空间连续充入气态惰封介质,补偿弹孔泄放,并在必要时切换为注入液态消防介质模式;同时,快速启动液态消防介质源的供液系统,通过Y型穿管向容器顶部喷淋液态消防介质,为容器提供近罐降温,并能够在必要时切换为通过Y型穿管向容器顶部连续释放气态惰封介质模式,实现容器顶部局部驱氧,从而抑制容器外部的物料或其蒸汽燃烧爆炸条件成就。 Further, based on the above technical solution, the present invention can automatically follow up or quickly start the gas supply of the gas inerting medium source when the container is subjected to the Monroe effect type or the kinetic energy type attack to form the bullet hole release pressure loss. The system is mandatory to continuously fill the gas phase space of the container into the gaseous inert sealing medium, compensate the bullet hole discharge, and switch to the liquid fire medium mode when necessary; at the same time, quickly start the liquid supply system of the liquid fire medium source through the Y-type The tube sprays the liquid fire-fighting medium to the top of the container to provide a near-tank cooling temperature for the container, and can be switched to a continuous release of the gaseous idle-sealing medium mode through the Y-shaped through-tube to the top of the container when necessary, thereby realizing partial oxygenation at the top of the container, thereby suppressing the container The external material or its steam combustion explosion conditions are achieved.
附图说明DRAWINGS
图1为本发明危险化学品容器用惰封抑爆装备的一实施例的结构示意图。BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic view showing the structure of an embodiment of an inertial seal suppression device for a hazardous chemical container according to the present invention.
图2为本发明危险化学品容器用惰封抑爆装备的另一实施例的结构示意图。2 is a schematic view showing the structure of another embodiment of the inertial seal suppression device for a hazardous chemical container according to the present invention.
图3为本发明危险化学品容器用惰封抑爆装备的再一实施例的结构示意图。Fig. 3 is a structural schematic view showing still another embodiment of the inertial sealing and anti-explosive device for a dangerous chemical container according to the present invention.
图4为本发明危险化学品容器用惰封抑爆装备的又一实施例的结构示意图。Fig. 4 is a schematic view showing the structure of another embodiment of the inertial sealing and anti-explosive device for a dangerous chemical container according to the present invention.
图5为基于本发明危险化学品容器用惰封抑爆装备实施例的防御方法的流程示意图。5 is a schematic flow chart of a defense method based on an embodiment of an inertial seal suppression device for a hazardous chemical container according to the present invention.
具体实施方式detailed description
下面通过附图和实施例,对本发明的技术方案做进一步的详细描述。The technical solution of the present invention will be further described in detail below through the accompanying drawings and embodiments.
如图1所示,为本发明危险化学品容器用惰封抑爆装备的一实施例的结构示意图。在本实施例中,危险化学品容器用惰封抑爆装备包括设置在危险化学品容器1上的惰封装置,惰封装置包括在竖直方向上安装的U型套管3,U型套管3内储有相对于所述危险化学品容器内的被保护物料具有消防功能的液态消防介质,U型套管3包括配气侧竖管、容器侧竖管和底联管,底联管的两端分别与配气侧竖管和容器侧竖管的下端口接驳连通,U型套管3的配气侧竖管的上端口与能够提供和回收相对于危险化学品容器1内的被保护物料2具有化学稳定性的气态惰封介质6的气态惰封介质源5连通,U型套管的容器侧竖管的上端口与危险化学品容器1的顶部连通。FIG. 1 is a schematic view showing the structure of an embodiment of an inertial seal suppression device for a hazardous chemical container according to the present invention. In the present embodiment, the inert seal explosion-proof equipment for the hazardous chemical container includes an air-sealing device disposed on the hazardous chemical container 1, and the air-sealing device includes a U-shaped sleeve 3 installed in a vertical direction, a U-shaped sleeve The tube 3 stores a liquid fire-fighting medium having a fire-fighting function with respect to the protected material in the dangerous chemical container, and the U-shaped sleeve 3 includes a gas distribution side vertical pipe, a container side vertical pipe and a bottom joint pipe, and a bottom pipe The two ends of the U-shaped sleeve 3 are respectively connected to the lower port of the gas distribution side vertical pipe and the container side vertical pipe, and the upper port of the gas distribution side vertical pipe of the U-shaped casing 3 is capable of being supplied and recovered with respect to the hazardous chemical container 1 The gaseous inerting medium source 5 of the chemically stable gaseous inerting medium 6 of the protected material 2 is in communication, and the upper port of the container-side vertical tube of the U-shaped casing is in communication with the top of the hazardous chemical container 1.
U型套管3中的配气侧竖管、容器侧竖管和底联管可以分别 制作并依次接驳,也可以一体制造而成。U型套管3可以全部或部分安装在危险化学品容器1的外部,或者全部或部分安装在危险化学品容器1的内部,图1中的U型套管3的整体全部安装在危险化学品容器1的外侧方,而且对于一个危险化学品容器1来说,可以设置多个U型套管3,分布在危险化学品容器1的外侧方,也可以设置在危险化学品容器1内,例如在危险化学品容器1的侧壁内设置内部管路通道,也可以将一部分U型套管3设置在危险化学品容器1的外侧方,另一部分设置在危险化学品容器1内。The gas distribution side vertical pipe, the container side vertical pipe and the bottom coal pipe in the U-shaped casing 3 can be respectively It can be made and connected in turn, or it can be manufactured in one piece. The U-shaped sleeve 3 may be installed wholly or partially outside the hazardous chemical container 1, or may be wholly or partially installed inside the hazardous chemical container 1, and the entire U-shaped sleeve 3 in Fig. 1 is installed in a hazardous chemical. The outer side of the container 1, and for a hazardous chemical container 1, a plurality of U-shaped sleeves 3 may be provided, distributed outside the hazardous chemical container 1, or may be disposed in the hazardous chemical container 1, for example An internal pipe passage is provided in the side wall of the hazardous chemical container 1, and a part of the U-shaped sleeve 3 may be disposed outside the hazardous chemical container 1 and the other portion may be disposed in the hazardous chemical container 1.
由于气态惰封介质始终充斥容器气相空间,并可以随容器内的气相空间的缩小而输出、增大而输入,保障了气相空间的压力可以根据被保护物料的饱和蒸汽压进行设计、调控,所以,该装备可以在被保护物料始终处于与空气隔绝的状态下有效阻止其燃烧爆炸条件的成就。Since the gaseous inert seal medium always fills the gas phase space of the container and can be output and increased as the gas phase space in the container is reduced, the pressure in the gas phase space can be designed and regulated according to the saturated vapor pressure of the material to be protected. The equipment can effectively prevent the combustion of explosive conditions from being achieved when the material to be protected is always isolated from the air.
本发明的一个重要方面在于:采用向U型套管内充入液态消防介质的技术措施,将液态消防介质作为气态惰封介质源与危险化学品容器之间的自控套管液体阀门,在将气态惰封介质分隔成配气侧的气态惰封介质和容器侧的气态惰封介质两部分的同时,有效支持危险化学品容器的大小呼吸,并在阻止物料蒸汽和气态惰封介质向空气中逸散的前提下,简约化取代危险化学品容器常用的大小呼吸阀、阻火阀、安全卸压阀、防爆片等配件,实现节能减排,提高安全性、可靠性。An important aspect of the invention is that the liquid fire-fighting medium is used as a self-controlling casing liquid valve between the source of the gaseous inerting medium and the dangerous chemical container by adopting a technical measure of filling the U-shaped casing with a liquid fire-fighting medium. The inert seal medium is divided into two parts: the gaseous inerting medium on the gas distribution side and the gas inerting medium on the container side, which effectively supports the size and breathing of the hazardous chemical container, and prevents the material vapor and the gaseous inert seal medium from escaping into the air. Under the premise of dispersing, the simplification replaces the large and small breathing valves, fire-blocking valves, safety relief valves, rupture discs and other accessories commonly used in hazardous chemical containers to achieve energy saving and emission reduction, and improve safety and reliability.
本说明书所述“惰封”的概念并不限于公知的“氮封”概念,应理解为根据被保护物料及容器的要求而选择合适的气态惰封介质,例如选自氮气、零族稀有气体、二氧化碳气体和水蒸汽中的一种或多种的组合。The concept of "lazy seal" as used in this specification is not limited to the well-known concept of "nitrogen seal". It should be understood that a suitable gaseous inert seal medium is selected according to the requirements of the material to be protected and the container, for example, selected from nitrogen, zero rare gas. a combination of one or more of carbon dioxide gas and water vapor.
本说明书所述“小呼吸”,是指容器气相空间的容积因环境 (即容器外部环境)、容器(即前文的危险化学品容器)、物料和容器内气相空间气体温度变化而需要输出或输入部分气体,从而保障容器气相空间与容器外部大气压力均衡的现象。“Small breathing” as used in this specification refers to the volume of the gas phase space of the container due to the environment. (ie, the external environment of the container), the container (ie, the dangerous chemical container in the foregoing), the temperature of the gas in the gas phase space in the material and the container, and the output or input of part of the gas is required to ensure the balance between the gas phase space of the container and the atmospheric pressure outside the container.
基于上述技术方案的容器小呼吸是这样实现的:当环境、容器、物料和容器内气相空间气体温度升高时,物料膨胀,物料液面升高,容器气相空间容积缩小,气态惰封介质压力升高,驱动U型套管中的靠近容器一侧的管路中的液态消防介质的液面降低,而靠近气态惰封介质源一侧的管路中的液态消防介质的液位升高;当环境、容器、物料和容器内气相空间气体温度降低时,物料收缩,液面降低,导致容器的气相空间容积增大,使气态惰封介质压力降低,此时U型套管中的靠近容器一侧的竖管中的液态消防介质的液面升高,靠近气态惰封介质源一侧的管路中的液态消防介质的液位降低。可见,U型套管内的液态消防介质作为套管液体阀门可以利用液位的自动调整来实现对容器内的气态惰性介质的压力进行调节、控制。The small breathing of the container based on the above technical solution is realized: when the temperature of the gas in the gas phase space in the environment, the container, the material and the container is increased, the material expands, the liquid level of the material rises, the volume of the gas phase space of the container decreases, and the pressure of the gaseous inert seal medium Raising, the liquid level of the liquid fire-fighting medium in the pipeline driving the side of the U-shaped sleeve near the container is lowered, and the liquid level of the liquid fire-fighting medium in the pipeline near the source side of the gaseous inerting medium is raised; When the temperature of the gas in the gas phase space in the environment, the container, the material and the container is lowered, the material shrinks and the liquid level decreases, causing the gas phase space volume of the container to increase, and the pressure of the gas inerting medium is lowered, and the U-shaped sleeve is close to the container. The liquid level of the liquid fire-fighting medium in the standpipe on one side rises, and the level of the liquid fire-fighting medium in the line near the source side of the gas-laden seal medium decreases. It can be seen that the liquid fire-fighting medium in the U-shaped sleeve can be used as a casing liquid valve to adjust and control the pressure of the gaseous inert medium in the container by using the automatic adjustment of the liquid level.
这里的液态消防介质可选自为水、防冻液、亲物料液体、水基消防泡沫中的一种或多种的组合。The liquid fire fighting medium herein may be selected from the group consisting of water, antifreeze, parent material liquid, water based fire fighting foam.
本说明书中的所谓“大呼吸”是指容器收料或付料作业时,容器气相空间随物料液面变化而需要输出或输入大量气体的作业保障。The term "big breath" in this specification refers to the operation guarantee that the gas phase space of the container needs to be output or input a large amount of gas when the container is received or fed.
基于上述技术方案的容器大呼吸是这样实现的:在收料作业时,物料液面逐渐升高,容器内气相空间逐渐减小,容器和U型套管内容器侧的气态惰封介质的压力逐渐升高,这就使得U型套管中的靠近容器侧的竖管中的液态消防介质的液面降低,而气态惰封介质源侧的竖管中的液态消防介质的液位升高,当压力到达设计值时,气态惰封介质源的收气系统启动,该侧压力降低,该侧竖管中的液态消防介质在重力的作用下向容器侧竖管回流,脉 冲式的释放气态惰封介质流向气态惰封介质源,这些气态惰封介质经过液态消防介质的过滤、清洗、泻压后返回到气态惰封介质源进行回收,直到系统压力均衡;同理,付料作业时,物料液面逐渐降低,容器的气相空间逐渐增大,容器和U型套管容器侧竖管内的气态惰封介质的压力逐渐降低,使得该侧竖管中的液态消防介质液面逐渐升高,靠近气态惰封介质源一侧的竖管中的液态消防介质的液位降低,当压力到达设计值时,气态惰封介质源的输气系统启动,容器侧竖管中的液态消防介质在重力的作用下向气体介质源侧竖管回流,脉冲式的向容器内补充气态惰封介质,这些气态惰封介质经过液态消防介质的过滤、泻压后进入到容器内,直到付料作业完成或系统压力均衡。The large breathing of the container based on the above technical solution is realized: during the receiving operation, the liquid level of the material gradually rises, the gas phase space in the container gradually decreases, and the pressure of the gaseous inert sealing medium on the inner side of the container and the U-shaped sleeve gradually increases. Raising, which lowers the liquid level of the liquid fire-fighting medium in the vertical tube near the container side of the U-shaped sleeve, and the liquid level of the liquid fire-fighting medium in the vertical tube on the source side of the gaseous inerting medium rises when When the pressure reaches the design value, the gas collection system of the gaseous inert seal medium source is started, the pressure on the side is lowered, and the liquid fire-fighting medium in the side vertical pipe is returned to the container side vertical pipe under the action of gravity. The flush release gaseous inert seal medium flows to the source of the gaseous inert seal medium, and the gaseous inert seal medium is filtered, washed, and depressurized by the liquid fire medium to be returned to the gaseous inert seal medium source for recovery until the system pressure is equalized; During the material feeding operation, the liquid level of the material gradually decreases, the gas phase space of the container gradually increases, and the pressure of the gaseous inert sealing medium in the container and the side vertical tube of the U-shaped sleeve container gradually decreases, so that the liquid fire-fighting medium liquid in the side vertical tube The surface gradually rises, and the liquid level of the liquid fire medium in the riser near the source side of the gaseous inert seal medium decreases. When the pressure reaches the design value, the gas supply system of the gaseous inert seal medium source starts, and the container side riser The liquid fire-fighting medium is recirculated to the gas medium source side by gravity under the action of gravity, and the gaseous inert seal medium is pulsed into the container, and the gaseous inert seal medium is filtered and vented by the liquid fire-fighting medium, and then enters into the container until The delivery operation is completed or the system pressure is balanced.
从上面的说明可以看出,U型套管内填充的液态消防介质可以将气态惰封介质分成靠近气态惰封介质源一侧的配气端的气态惰封介质和容器端的气态惰封介质两个部分,可以实现气态惰封介质的弹性化压力调整,同时也可以在大呼吸时对通过的气态惰封介质进行过滤、清洗。此外,由于气态惰封介质源可以在容器收料作业时回收容器内的气态惰封介质,并可以将混入气态惰封介质中的物料蒸汽分子分离、汲取,然后再在容器付料作业时向容器内提供相对纯净的气态惰封介质,从而实现气态惰封介质的循环利用。As can be seen from the above description, the liquid fire-fighting medium filled in the U-shaped sleeve can divide the gaseous inert sealing medium into a gaseous inert sealing medium close to the gas distribution end of the gas inerting medium source side and a gas inertial sealing medium at the container end. The elastic pressure adjustment of the gaseous inert seal medium can be realized, and the gaseous inert seal medium passing through can also be filtered and cleaned during large breathing. In addition, since the gaseous inert seal medium source can recover the gaseous inert seal medium in the container during the container receiving operation, the material vapor molecules mixed in the gaseous inert seal medium can be separated and extracted, and then, when the container is being fed A relatively pure gaseous inert seal medium is provided within the vessel to effect recycling of the gaseous inert seal medium.
在执行将容器内物料全部输出任务时,如倒罐、维修、清洗容器等作业,传统作业方式只能将空气吸入管路,这就形成重大安全隐患。而基于本发明所提供的惰封抑爆装备,可以将气态惰封介质随入物料管路,实施惰封,消除了因物料管路内无法惰封而存在的安全隐患。When performing the task of outputting all the materials in the container, such as pouring cans, repairing, cleaning the container, etc., the traditional operation mode can only suck air into the pipeline, which poses a major safety hazard. According to the idle seal explosion-proof equipment provided by the invention, the gaseous inert seal medium can be carried into the material pipeline, and the inert seal can be implemented, thereby eliminating the safety hazard due to the inability to seal the material pipeline.
如图2所示,为本发明危险化学品容器用惰封抑爆装备的另一实施例的结构示意图。与上一实施例相比,本实施例还包括液 态消防介质源7,液态消防介质源7与U型套管3液相连通,向U型套管3内部提供、泄放、回收或循环使用液态消防介质。U型套管中的液态消防介质将气态惰封介质分隔成配气侧的气态惰封介质和容器侧的气态惰封介质两部分。液态消防介质源7可以随时向U型套管3添加或补充液态消防介质,根据套管液体阀门的预设液位高度向U型套管注入预设量的液态消防介质,以调节套管液体阀门的开闭压力。液态消防介质源7再结合Y型穿管还能够提供危险化学品容器1本身的应急消防和外壁清洗功能。Y型穿管在后文中有详细说明,此处暂不详述。2 is a schematic structural view of another embodiment of the inertial seal suppression device for a hazardous chemical container according to the present invention. Compared with the previous embodiment, the embodiment further includes a liquid The fire medium source 7 and the liquid fire medium source 7 are in liquid phase communication with the U-shaped sleeve 3, and provide, discharge, recycle or recycle the liquid fire-fighting medium to the inside of the U-shaped sleeve 3. The liquid fire-fighting medium in the U-shaped casing separates the gaseous inerting medium into two parts, a gaseous inerting medium on the gas distribution side and a gaseous inert gas sealing medium on the container side. The liquid fire medium source 7 can add or supplement the liquid fire-fighting medium to the U-shaped casing 3 at any time, and inject a preset amount of liquid fire-fighting medium into the U-shaped casing according to the preset liquid level height of the casing liquid valve to adjust the casing liquid. The opening and closing pressure of the valve. The liquid fire medium source 7 combined with the Y-type pipe can also provide emergency fire protection and outer wall cleaning functions of the hazardous chemical container 1 itself. The Y-shaped tube is described in detail later, and will not be described in detail here.
在图2的实施例来说,惰封装置可以进一步包括设置在危险化学品容器1的顶部的惰封盘10,惰封盘10为带有泄压孔14、盘腰接驳孔13、盘顶人孔12和盖体11的箱式空腔结构体,惰封盘10的泄压孔14与危险化学品容器1的顶部相通,U型套管3的容器侧端口与惰封盘10上的盘腰接驳孔13连接,盘顶人孔12上方通过盖体11进行封闭。惰封盘的设计主要是为应对门罗效应弹种旨在以随进战斗部容器内爆轰模式殉爆气相空间含氧烃类物的保障结构,这里的爆轰是指随进战斗部在危险化学品容器内的液体型物料中的自带氧化剂的爆轰。In the embodiment of Fig. 2, the air-sealing device may further comprise an air-sealing disk 10 disposed at the top of the hazardous chemical container 1, the air-tight disk 10 having a pressure relief hole 14, a disk waist connection hole 13, and a disk The top manhole 12 and the box cavity structure of the cover body 11, the pressure relief hole 14 of the idler disk 10 communicates with the top of the hazardous chemical container 1, and the container side port of the U-shaped sleeve 3 and the idler disk 10 The waist connection holes 13 are connected, and the top of the top hole 12 is closed by the cover 11. The design of the idler disc is mainly to deal with the Monroe effect. The bomb is designed to blast the oxygen-containing hydrocarbons in the gas-phase space in the detonation mode of the warhead. The detonation here refers to the warhead. Detonation of self-contained oxidant in liquid type materials in hazardous chemical containers.
在军事适用性方面,当储有危险化学品的容器遭受门罗效应弹种破壁攻击时,随进战斗部在液相物料中起爆后球形释放爆轰激波,迫使物料液面急速上升,容器内气相空间骤然缩小,气体压力与温度陡然升高,此时,容器气相空间的气体若为诸如含氧烃类物等易燃易爆气体,则该气体或以物理爆炸方式造成轰顶式毁伤,或以化学爆炸方式被殉爆,进而形成物料及容器整体爆炸。因此,有效控制容器气相空间含氧量,并创建泄放爆轰压力的通道,既是抑制容器气相空间气体燃烧爆炸条件的成就,防御化学爆炸的技术关键,也是防御物理爆炸的技术关键。 In terms of military applicability, when a container containing dangerous chemicals is attacked by the Monroe effect, the ball releases a detonation wave after the detonation of the warhead in the liquid material, forcing the material level to rise rapidly. The gas phase space in the vessel suddenly shrinks, and the gas pressure and temperature rise sharply. At this time, if the gas in the gas phase space of the container is a flammable or explosive gas such as an oxygenated hydrocarbon, the gas may be caused by a physical explosion. Damage, or explosion by chemical explosion, resulting in the explosion of materials and containers. Therefore, effectively controlling the oxygen content of the gas phase space of the container and creating a channel for releasing the detonation pressure is not only an achievement of suppressing the gas combustion and explosion conditions of the gas phase space of the container, but also a technical key for defending against chemical explosion, and also a technical key for defending against physical explosion.
进一步的,设计出具有箱式空腔结构体的惰封盘,既可以有效防止化学爆炸,也可以为急速缩小的气相空间提供泄放高压的通道和空间,避免危险化学品容器的顶部因物理爆炸而被轰顶。而卸压孔可由容器原来的人孔进行改造,盘腰接驳孔可以设置多个,以便连接多个U型套管。Further, an idler disk with a box cavity structure is designed to effectively prevent chemical explosion, and also provide a channel and space for venting high pressure for the rapidly reducing gas phase space, thereby avoiding the top of the dangerous chemical container due to physics. The explosion was slammed. The pressure relief hole can be modified by the original manhole of the container, and the plurality of waist connection holes can be arranged to connect a plurality of U-shaped sleeves.
如图4所示,为本发明危险化学品容器用惰封抑爆装备的又一实施例的结构示意图。与前面实施例相比,本实施例的气态惰封介质源5包括配气泵系、配气总管56、收气支管57和配气支管58,配气泵系包括气态惰封介质发生器51、高压储罐52、配气调压罐53、单向气泵55、油气分离装置54及接驳短管和阀门,气态惰封介质发生器51、高压储罐52和配气调压罐53依次串联接驳于配气总管56,单向气泵55、油气分离装置54串联接驳于收气支管57,收气支管57并联于与配气总管56的部分管路(即从配气调压罐53到配气总管56与配气支管58的接口位置之间的管路),配气总管56与配气支管58气相接驳联通,配气支管58与U型套管3的配气侧竖管的上端口气相接驳连通。配气泵系可以通过配气储罐53向U型套管3所连接的危险化学品容器1提供气态惰封介质,还可以通过收气管路中的单向气泵55从U型套管3回收气态惰封介质到配气储罐53内。考虑到回收的气态惰封介质中可能混有容器内被保护物料(例如油料蒸汽)等成分,因此可以通过收气支路57中串联的油气分离装置54减少被保护物料的损耗,并消除因物料蒸汽的蒸发逸散而造成的安全隐患和环境污染。As shown in FIG. 4, it is a schematic structural view of still another embodiment of the inertial sealing and anti-explosion equipment for the hazardous chemical container of the present invention. Compared with the previous embodiment, the gaseous inerting medium source 5 of the present embodiment includes a gas distribution pump system, a gas distribution manifold 56, a gas collection branch pipe 57, and a gas distribution branch pipe 58. The gas distribution pump system includes a gas inerting medium generator 51 and a high pressure. The storage tank 52, the gas distribution pressure regulating tank 53, the one-way air pump 55, the oil and gas separation device 54, and the connecting short pipe and the valve, the gas inerting medium generator 51, the high pressure storage tank 52 and the gas distribution pressure regulating tank 53 are connected in series Restricted to the gas distribution pipe 56, the one-way air pump 55, the oil and gas separation device 54 is connected in series to the gas collection branch pipe 57, and the gas collection branch pipe 57 is connected in parallel with the partial pipe of the gas distribution pipe 56 (ie, from the gas distribution pressure regulating tank 53) a pipeline between the gas distribution manifold 56 and the interface position of the gas distribution branch 58), the gas distribution manifold 56 and the gas distribution branch 58 are connected by a gas phase connection, and the gas distribution branch 58 and the gas distribution side vertical pipe of the U-shaped sleeve 3 The upper port is connected to the gas phase. The gas distribution pump can supply the gaseous inerting medium to the hazardous chemical container 1 connected to the U-shaped sleeve 3 through the gas distribution tank 53, and can also recover the gaseous state from the U-shaped casing 3 through the one-way air pump 55 in the gas collection line. The inert seal medium is introduced into the gas distribution tank 53. Considering that the recovered gaseous inert seal medium may be mixed with components such as oil in the container (for example, oil vapor), the oil and gas separation device 54 connected in series in the gas collection branch 57 can reduce the loss of the protected material and eliminate the cause. Safety hazards and environmental pollution caused by evaporation of material vapor.
液态消防介质源7包括消防泵系、消防总管74和消防支管75,消防泵系包括消防介质存储设施71、消防泵72和消防阀控设备73,消防介质存储设施71、消防泵72依次串联接驳于消防总管74,消防总管74与消防支管75液相接驳连通,消防支管75 与U型套管3的底联管液相接驳连通。The liquid fire medium source 7 includes a fire pump system, a fire main pipe 74, and a fire branch pipe 75. The fire pump system includes a fire medium storage facility 71, a fire pump 72, and a fire valve control device 73. The fire medium storage facility 71 and the fire pump 72 are connected in series. Refused to the fire main 74, the fire main 74 and the fire branch 75 liquid connection, fire branch 75 It is in fluid communication with the bottom tube of the U-shaped sleeve 3.
为了方便对危险化学品容器1进行消防和清洗,可以在U型套管3内设置Y型穿管8(参考图2),Y型穿管8的容器侧端口从U型套管3的容器侧竖管上部接近危险化学品容器1的顶部的位置穿出,或与危险化学品容器1的上方的喷淋管9接驳,Y型穿管8的配气侧端口悬于U型套管3的配气侧竖管内的预设高度,能够向U型套管3内注入液态消防介质,Y型穿管8的下端口从U型套管3的底联管穿出,并与消防支管75液相接驳连通。In order to facilitate the fire protection and cleaning of the hazardous chemical container 1, a Y-shaped through tube 8 (refer to FIG. 2) may be disposed in the U-shaped sleeve 3, and the container-side port of the Y-shaped through tube 8 is from the container of the U-shaped sleeve 3. The upper part of the side standpipe is close to the top of the hazardous chemical container 1 or is connected to the spray pipe 9 above the hazardous chemical container 1, and the gas distribution side port of the Y-type pipe 8 is suspended from the U-shaped bushing. The preset height in the gas distribution side vertical pipe of 3 can inject liquid fire-fighting medium into the U-shaped casing 3, and the lower port of the Y-shaped pipe 8 is pierced from the bottom pipe of the U-shaped casing 3, and is connected with the fire branch pipe 75 liquid phase connection.
通过消防泵72的作用,可使消防介质存储设施71内的液态消防介质通过消防管路74送入Y型穿管8,再通过喷淋管9喷出,从而实现危险化学品容器1的外壁清洗、降温和消防功能。由于危险化学品容器1在发生爆炸或发生火灾时,辐射出的热能会阻碍外部喷洒消防液体,而直接设置在容器上方的喷淋口所喷出的液态消防介质则可以直接实现容器的消防和容器外壁的降温,从而对容器实现及时的消防工作,在清洗方面也更为方便。与Y型穿管8连接的喷淋管9还能够为危险化学品容器1的内壁清洗提供水源。U型套管3可以起到保护Y型穿管8的作用。Through the action of the fire pump 72, the liquid fire-fighting medium in the fire-fighting medium storage facility 71 can be sent to the Y-shaped pipe 8 through the fire-fighting pipe 74, and then sprayed through the spray pipe 9, thereby realizing the outer wall of the dangerous chemical container 1. Cleaning, cooling and fire protection. Due to the explosion of a dangerous chemical container 1 or a fire, the radiated heat energy will hinder the external spraying of the fire-fighting liquid, and the liquid fire-fighting medium sprayed directly from the spray port above the container can directly realize the fire fighting of the container. The temperature of the outer wall of the container is lowered, so that timely fire protection work is performed on the container, and the cleaning is also more convenient. The spray pipe 9 connected to the Y-shaped pipe 8 can also provide a water source for cleaning the inner wall of the hazardous chemical container 1. The U-shaped sleeve 3 can function to protect the Y-shaped through tube 8.
Y型穿管与液态消防介质源液相连通,液态消防介质源通过Y型穿管的配气侧端口向U型套管内提供所述液态消防介质,Y型穿管中滞留的液态消防介质还可以进一步作为隔离气态惰封介质与大气的自控穿管液体阀门,通过设定Y型穿管的配气侧端口的高度来调节穿管液体阀门的开闭压力,实现当气态惰封介质的压力大于设计压力,且气态惰封介质源未执行收气指令时,向大气泄放部分气态惰封介质的保险功能,同理,当气态惰封介质压力小于设计压力,且气态惰封介质源未执行供气指令时,惰封装置可从大气中吸入部分空气的保险功能,从而保障容器和装备的安全。 The Y-type pipe is connected to the liquid source of the liquid fire-fighting medium, and the liquid fire-fighting medium source supplies the liquid fire-fighting medium to the U-shaped casing through the gas distribution side port of the Y-type pipe, and the liquid fire-fighting medium retained in the Y-type pipe is also It can be further used as a self-controlled through-pipe liquid valve for isolating the gaseous inertial sealing medium and the atmosphere, and adjusting the opening and closing pressure of the liquid-passing valve through setting the height of the gas distribution side port of the Y-shaped through-tube to realize the pressure of the gaseous inert sealing medium When the gas pressure is greater than the design pressure, and the gas inerting medium does not perform the gas-receiving command, the safety function of the partial gas-tight sealing medium is released to the atmosphere. Similarly, when the pressure of the gaseous inerting medium is less than the design pressure, and the source of the gaseous inert seal medium is not When the air supply command is executed, the air-sealing device can inhale some of the air's insurance function from the atmosphere, thus ensuring the safety of the container and equipment.
在上述方案中,U型套管和Y型穿管及其各组件、配件可以为分别制作并依次接驳,或一体制造。In the above solution, the U-shaped sleeve and the Y-shaped through-tube and the components and accessories thereof may be separately fabricated and sequentially connected, or integrally manufactured.
在危险化学品容器遭受门罗效应弹种或动能弹种攻击时,危险化学品容器顶部气相空间急剧缩小,高压的气态惰封介质可以通过Y型穿管释放到大气中,为急速缩小的气相空间提供泄放高压的通道,避免危险化学品容器的顶部因物理爆炸而被轰顶。When the hazardous chemical container is attacked by the Monroe effect or the kinetic energy, the gas phase space at the top of the hazardous chemical container is sharply reduced, and the high-pressure gaseous inerting medium can be released into the atmosphere through the Y-shaped pipe, which is a rapidly decreasing gas phase. The space provides a venting high pressure passage to prevent the top of the hazardous chemical container from being blasted due to a physical explosion.
而当危险化学品容器形成弹孔泄放失压时,快速启动气态惰封介质源的供气系统,强制性向容器气相空间连续充入气态惰封介质,补偿弹孔泄放,并在必要时切换为注入液态消防介质模式;同时,快速启动液态消防介质源的供液系统,通过Y型穿管向容器顶部喷淋液态消防介质,为容器提供近罐降温,并能够在必要时切换为通过Y型穿管向容器顶部连续释放气态惰封介质模式,实现容器顶部局部驱氧,从而抑制容器外部的物料或其蒸汽燃烧爆炸条件成就。When the hazardous chemical container forms a bullet hole venting pressure loss, the gas supply system of the gas inerting sealing medium source is quickly started, and the gas phase space is continuously filled into the gas inerting medium to compensate the bullet hole venting, and when necessary Switch to the liquid fire medium mode; at the same time, quickly start the liquid supply system of the liquid fire medium, spray the liquid fire medium to the top of the container through the Y-type pipe, provide the tank with near tank cooling, and switch to pass if necessary The Y-shaped through-tube continuously releases the gaseous idle-sealing medium mode to the top of the container to achieve partial oxygenation at the top of the container, thereby suppressing the achievement of the material outside the container or its steam combustion explosion condition.
图3示出了另一种Y型穿管,该Y型穿管15的容器侧端口和配气侧端口均从U型套管3的底联管穿入,Y型穿管15的容器侧端口通过U型套管3的容器侧竖管上部接近危险化学品容器1的顶部的位置穿出,或与危险化学品容器1的上方的喷淋管9接驳,Y型穿管15的配气侧端口悬于U型套管3的配气侧竖管内的预设高度,能够向U型套管3内注入液态消防介质,Y型穿管15的下端口与消防支管75液相接驳连通。Fig. 3 shows another Y-shaped through tube, the container side port and the gas distribution side port of the Y type through tube 15 are both penetrated from the bottom connecting tube of the U-shaped sleeve 3, and the container side of the Y-shaped through tube 15 The port passes through the upper portion of the container-side vertical tube of the U-shaped sleeve 3 near the top of the hazardous chemical container 1, or is connected to the spray pipe 9 above the hazardous chemical container 1, and the Y-shaped tube 15 is matched. The gas side port is suspended at a preset height in the gas distribution side vertical pipe of the U-shaped sleeve 3, and the liquid fire-fighting medium can be injected into the U-shaped sleeve 3, and the lower port of the Y-shaped pipe 15 is connected to the fire-fighting branch pipe 75. Connected.
在另一个实施例中,还可以在Y型穿管15上设置控制Y型穿管15的配气侧端口与消防支管15之间连通的阀门16,当该阀门16关闭时,惰封装置内的气态惰封介质与大气之间的泄压通道被该阀门16切断,此时液压消防介质源输入的液态消防介质能够直接经Y型穿管的容器侧端口喷出,经由该容器侧端口向危险化学品容器1的顶部实施近罐喷淋。 In another embodiment, a valve 16 for controlling communication between the gas distribution side port of the Y-shaped pipe 15 and the fire branch pipe 15 may be disposed on the Y-shaped pipe 15, and when the valve 16 is closed, the air-sealing device is closed. The pressure relief passage between the gaseous inerting medium and the atmosphere is cut off by the valve 16, and the liquid fire-fighting medium input from the hydraulic fire-fighting medium source can be directly ejected through the container-side port of the Y-shaped pipe through the container side port. The top of the hazardous chemical container 1 is sprayed near the tank.
在实际设置中,危险化学品容器1可以有两个以上,每个危险化学品容器1配装至少一套惰封装置,气态惰封介质源5通过由配气总管56、收气支管57和配气支管58构成的配气管网15与各个危险化学品容器1上的惰封装置气相接驳连通,液态消防介质源7通过由消防总管74和消防支管75构成的消防管网与各个危险化学品容器1上的惰封装置的底部液相接驳连通。配气管网15本身就具备一定的气压调节能力,能够在容器间进行气态惰封介质的传递。In the actual setting, there may be more than two dangerous chemical containers 1, each of which is equipped with at least one set of inerting device, and the gaseous inerting medium source 5 is passed through the gas distribution pipe 56, the gas collecting branch 57 and The gas distribution pipe network 15 formed by the gas distribution branch pipe 58 is in gas-phase connection with the air-sealing device on each of the hazardous chemical containers 1, and the liquid fire-fighting medium source 7 passes through the fire-fighting pipe network composed of the fire main pipe 74 and the fire-fighting branch pipe 75 and various dangerous chemicals. The bottom liquid phase of the inerting device on the product container 1 is connected to the liquid phase. The gas distribution pipe network 15 itself has a certain gas pressure adjustment capability, and is capable of transferring the gaseous inert seal medium between the containers.
在上述说明的危险化学品容器用惰封抑爆装备中,可适用于各类大型或小型的危险化学品容器,例如大型油罐或油罐车上的小型油罐体等,根据危险化学品容器的大小、结构特点、所处环境、受威胁程度以及所盛装的物料种类等可以选择适合的气态惰封介质源,以及选择是否连接液态消防介质源,对于油罐车上的小型油罐体也可以不设置专门的液态消防介质源,还包括惰封盘的使用与否,卸压孔设置的数量和尺寸等的选择。In the above-mentioned inert seal explosion-proof equipment for hazardous chemical containers, it can be applied to various large or small hazardous chemical containers, such as small oil tanks on tanks or tank trucks, according to hazardous chemicals. The size of the container, the structural characteristics, the environment, the degree of threat, and the type of material to be contained, etc., can select a suitable source of gaseous inerting medium, and choose whether to connect the liquid fire medium source to the small oil tank body on the tank truck. It is also possible not to provide a special source of liquid fire-fighting medium, but also to select the use of the idle-sealing disc, the number and size of the relief holes.
基于前述的各个危险化学品容器用惰封抑爆装备,对应的防御方法如图5所示,可以包括以下步骤:Based on the aforementioned inert seal explosion-proof equipment for each hazardous chemical container, the corresponding defense method is as shown in FIG. 5, and may include the following steps:
步骤101、根据容器、容器群、辅助设施、操作设备及被保护物料的技术参数,结合敌弹技术参数进行惰封抑爆装备设计和列装工程设计;Step 101: According to the technical parameters of the container, the container group, the auxiliary facilities, the operating equipment and the material to be protected, combined with the technical parameters of the enemy missile, the design and assembly engineering of the idle seal anti-explosion equipment;
步骤102、根据所述惰封抑爆装备的设计成果制造或选配所述危险化学品容器用惰封抑爆装备的配件,并按列装工程设计成果接驳和安装;Step 102: Manufacture or select, according to the design result of the idle seal explosion-proof equipment, accessories of the inert seal explosion-proof equipment for the dangerous chemical container, and connect and install according to the listed engineering design result;
步骤103、根据列装工程设计成果所列验收标准进行列装工程验收;Step 103: Perform acceptance inspection of the assembly project according to the acceptance criteria listed in the listed engineering design result;
步骤104、选用负压驱氧法或充液驱氧法实现气态惰封介质驱氧充斥气态惰封介质源管路、惰封装置及容器气相空间; Step 104, selecting a negative pressure oxygen drive method or a liquid-filling oxygen-discharging method to realize a gas-state inertial sealing medium to drive oxygen to fill the gaseous inertial sealing medium source pipeline, the inerting device and the container gas phase space;
步骤105、操作气态惰封介质源和液态消防介质源,使之处于工作状态;Step 105: operating a gaseous inert seal medium source and a liquid fire protection medium source to make it in a working state;
步骤106、操作所述危险化学品容器的泵控系统,进行收料付料作业试运行,检验所述危险化学品容器和所述惰封抑爆装备的大小呼吸功能;Step 106: operating a pump control system of the hazardous chemical container, performing a trial operation of the receiving and discharging operation, and checking the size and breathing function of the dangerous chemical container and the inertial anti-explosion device;
步骤107、在全部功能检验合格后,惰封抑爆装备交付列装,实现罐群非战时节能减排和临战参战无需转换的独立性永久性防御战力。Step 107: After all the functional inspections are passed, the idle-sealed explosion-proof equipment is delivered and assembled, so as to realize the independent permanent defensive power of the tank group during the non-war time energy-saving emission reduction and the battle participation without conversion.
在步骤104中,负压驱氧法具体包括:In step 104, the negative pressure flooding method specifically includes:
操作所述液态消防介质源,将液态消防介质注满Y型穿管,形成穿管液体阀门;Operating the liquid fire-fighting medium source, filling the liquid fire-fighting medium with a Y-shaped through pipe to form a pipe-through liquid valve;
操作所述气态惰封介质源,向所述容器方向供气,同时,从所述危险化学品容器或其管路中的较低处抽出气体排入大气,直至所述危险化学品容器及其连通的管路中的含氧量达标。Operating the source of gaseous inerting medium to supply gas to the vessel while simultaneously withdrawing gas from the lower portion of the hazardous chemical vessel or its piping into the atmosphere until the hazardous chemical vessel and its The oxygen content in the connected pipeline is up to standard.
在步骤104中,充液驱氧法具体包括:In step 104, the liquid-filling oxygen removal method specifically includes:
操作所述危险化学品容器收料作业至最高物料液位,此过程中的容器内的大部分气体经套管液态阀门进入配气侧气相空间,再经穿管液体阀门排至大气,实现容器驱氧;Operating the hazardous chemical container receiving operation to the highest material level, in the process, most of the gas in the container enters the gas phase of the gas distribution side through the casing liquid valve, and is discharged to the atmosphere through the liquid pipe through the pipe to realize the container Exhaust oxygen
操作所述液态消防介质源,将液态消防介质注满所述惰封抑爆装备的全部管路,实现惰封抑爆装备的全部或大部管路驱氧;Operating the liquid fire-fighting medium source, filling the liquid fire-fighting medium with all the pipelines of the idle-sealed explosion-proof equipment, and realizing all or most of the pipelines of the inert-sealed explosion-proof equipment to drive oxygen;
操作所述气态惰封介质源制备气态惰性介质,开启供气阀门;Operating the gaseous inerting medium source to prepare a gaseous inert medium, and opening a gas supply valve;
操作所述液态消防介质源泄放或回收液态消防介质,同时将相对纯净的气态惰封介质引入配气总管、配气支管、收气支管和惰封装置的全部管路;Operating the liquid fire-fighting medium source to vent or recover the liquid fire-fighting medium, and simultaneously introducing relatively pure gaseous inert sealing medium into all the pipelines of the gas distribution manifold, the gas distribution branch pipe, the gas collection branch pipe and the inerting device;
调整U型套管内的液位高度,形成套管液体阀门,至工作液位; Adjusting the liquid level in the U-shaped sleeve to form a casing liquid valve to the working liquid level;
调整Y型穿管内的液位高度,形成穿管液体阀门,至安全液位;Adjust the liquid level in the Y-shaped pipe to form a liquid pipe through the pipe to a safe liquid level;
操作所述危险化学品容器付料作业,将气态惰封介质吸入所述危险化学品容器的气相空间;Operating the hazardous chemical container receiving operation to draw a gaseous inerting medium into the gas phase space of the hazardous chemical container;
查验所述危险化学品容器的气相空间含氧量是否低于被保护物料爆炸极限下限或设计含量。Check whether the oxygen content of the gas phase space of the hazardous chemical container is lower than the lower limit of the explosion limit of the protected material or the designed content.
在步骤106中的试运行的步骤包括:The steps of the trial run in step 106 include:
分别查验所述危险化学品容器和所述惰封抑爆装备的压力和氧含量测定装置,记录初始数据;Detecting the pressure and oxygen content measuring device of the hazardous chemical container and the inertial anti-explosion device separately, and recording initial data;
进行收料作业试运行,分别查验所述危险化学品容器和所述惰封抑爆装备的压力和氧含量测定装置,记录压力和氧含量数据;Performing a trial run of the receiving operation, respectively checking the pressure and oxygen content measuring device of the dangerous chemical container and the inert seal suppressing device, and recording pressure and oxygen content data;
进行付料作业试运行,分别查验所述危险化学品容器和所述惰封抑爆装备的压力和氧含量测定装置,记录压力和氧含量数据;Carrying out the trial operation of the paying operation, respectively checking the pressure and oxygen content measuring device of the dangerous chemical container and the inert seal suppressing device, and recording the pressure and oxygen content data;
检测所述气态惰封介质源和液态消防介质源的诸组件及部件功能;Detecting components of the gaseous inert seal medium source and the liquid fire fighting medium source and component functions;
设计并实施破坏性实验,查验安全泄压功能。Design and implement destructive experiments to check the safety relief function.
最后应当说明的是:以上实施例仅用以说明本发明的技术方案而非对其限制;尽管参照较佳实施例对本发明进行了详细的说明,所属领域的普通技术人员应当理解:依然可以对本发明的具体实施方式进行修改或者对部分技术特征进行等同替换;显然,不脱离本发明技术方案精神的修改或替换,均应被涵盖于本发明请求保护的技术方案范围当中。 It should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and are not intended to be limiting; although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that The invention is not limited to the modifications and substitutions of the technical features of the present invention.

Claims (17)

  1. 一种危险化学品容器用惰封抑爆装备,其特征在于,包括设置在危险化学品容器上的惰封装置,所述惰封装置包括在竖直方向上安装的U型套管,所述U型套管内储有相对于所述危险化学品容器内的被保护物料具有消防功能的液态消防介质,所述U型套管包括配气侧竖管、容器侧竖管和底联管,所述底联管的两端分别与所述配气侧竖管和容器侧竖管的下端口接驳连通,所述U型套管的配气侧竖管的上端口与能够提供和回收相对于所述危险化学品容器内的被保护物料具有化学稳定性的气态惰封介质的气态惰封介质源气相连通,所述U型套管的容器侧竖管的上端口与所述危险化学品容器的顶部气相连通。An inert seal explosion-proof device for a hazardous chemical container, comprising: an air-sealing device disposed on a hazardous chemical container, the air-sealing device comprising a U-shaped sleeve mounted in a vertical direction, The U-shaped sleeve stores a liquid fire-fighting medium having a fire-fighting function with respect to the protected material in the dangerous chemical container, and the U-shaped sleeve includes a gas distribution side vertical pipe, a container side vertical pipe and a bottom joint pipe. The two ends of the bottom joint pipe are respectively connected to the lower port of the gas distribution side vertical pipe and the container side vertical pipe, and the upper port of the gas distribution side vertical pipe of the U-shaped sleeve is capable of providing and recovering a gaseous inerting medium source of a chemically stable gaseous inerting medium in the hazardous chemical container is in gaseous communication, the upper port of the container side riser of the U-shaped casing and the hazardous chemical container The top is connected to the gas phase.
  2. 根据权利要求1所述的危险化学品容器用惰封抑爆装备,其特征在于,所述气态惰封介质源包括配气泵系、配气总管、收气支管和配气支管,所述配气泵系包括气态惰封介质发生器、高压储罐、配气调压罐、单向气泵、油气分离装置及接驳短管和阀门,所述气态惰封介质发生器、所述高压储罐和所述配气调压罐依次串联接驳于所述配气总管,所述单向气泵、油气分离装置串联接驳于所述收气支管,所述收气支管并联于所述配气总管的部分管路,所述配气总管与所述配气支管气相接驳联通,所述配气支管与所述U型套管的配气侧竖管的端口气相接驳连通。The inertial seal suppression device for a hazardous chemical container according to claim 1, wherein the gaseous inerting medium source comprises a gas distribution pump system, a gas distribution manifold, a gas collection branch pipe and a gas distribution branch pipe, and the gas distribution pump The invention comprises a gas inerting medium generator, a high pressure storage tank, a gas distribution pressure tank, a one-way air pump, an oil and gas separation device, and a connecting short pipe and a valve, the gas inerting medium generator, the high pressure storage tank and the The gas distribution pressure tank is connected in series to the gas distribution manifold, and the one-way air pump and the oil and gas separation device are connected in series to the gas collection branch pipe, and the gas collection branch pipe is connected in parallel to the gas distribution manifold. a pipeline, the gas distribution manifold is in communication with the gas distribution branch pipe, and the gas distribution branch pipe is in gas phase connection with a port of the gas distribution side vertical pipe of the U-shaped sleeve.
  3. 根据权利要求1所述的危险化学品容器用惰封抑爆装备,其特征在于,还包括液态消防介质源,所述液态消防介质源与所述U型套管液相连通,向所述U型套管内部提供能够泄放、回收或循环使用的所述液态消防介质,所述U型套管中的所述液态消防介质作为套管液体阀门将所述气态惰封介质分隔成配气侧的气态惰封介质和容器侧的气态惰封介质两部分,所述液态消防介质 源根据所述套管液体阀门的预设液位高度向所述U型套管注入预设量的液态消防介质,以调节所述套管液体阀门的开闭压力。The inert seal explosion-proofing device for a hazardous chemical container according to claim 1, further comprising a liquid fire-fighting medium source, said liquid fire-fighting medium source being in fluid communication with said U-shaped sleeve, said U The liquid casing is internally provided with the liquid fire-fighting medium capable of being vented, recycled or recycled, and the liquid fire-fighting medium in the U-shaped casing separates the gaseous inerting medium into a gas distribution side as a casing liquid valve Two parts of the gaseous inert seal medium and the gaseous idle seal medium on the container side, the liquid fire fighting medium The source injects a predetermined amount of liquid fire-fighting medium into the U-shaped sleeve according to a preset liquid level height of the casing liquid valve to adjust an opening and closing pressure of the casing liquid valve.
  4. 根据权利要求3所述的危险化学品容器用惰封抑爆装备,其特征在于,所述液态消防介质源包括消防泵系、消防总管和消防支管,所述消防泵系包括消防介质存储设施、消防泵和消防阀控设备,所述消防介质存储设施和所述消防泵依次串联接驳于所述消防总管,所述消防总管与所述消防支管液相接驳连通,所述消防支管与所述U型套管的底联管液相接驳连通。The inert gas compression and suppression device for a hazardous chemical container according to claim 3, wherein the liquid fire medium source comprises a fire pump system, a fire main pipe and a fire branch pipe, and the fire pump system comprises a fire medium storage facility. a fire pump and a fire control device, wherein the fire medium storage device and the fire pump are connected in series to the fire main pipe in series, and the fire main pipe is connected to the fire branch pipe liquid phase connection, the fire branch pipe and the fire control pipe The bottom tube of the U-shaped sleeve is connected to the liquid phase.
  5. 根据权利要求4所述的危险化学品容器用惰封抑爆装备,其特征在于,在所述U型套管内还设有一Y型穿管,所述Y型穿管的下端口从所述U型套管的底联管穿出,并与所述消防支管液相接驳连通,所述Y型穿管的容器侧端口从所述U型套管的容器侧竖管上部接近所述危险化学品容器的顶部的位置穿出,或与所述危险化学品容器的上方的喷淋管接驳,所述Y型穿管的配气侧端口悬于所述U型套管的配气侧竖管内的预设高度,能够向所述U型套管内注入所述液态消防介质。The inertial seal suppression device for a hazardous chemical container according to claim 4, wherein a Y-shaped through tube is further disposed in the U-shaped sleeve, and a lower port of the Y-shaped through tube is from the U a bottom tube of the sleeve is threaded out and communicates with the fire branch in liquid phase, the container side port of the Y-shaped tube is close to the dangerous chemistry from the upper portion of the container side of the U-shaped sleeve The top of the product container is pierced or connected to the spray pipe above the hazardous chemical container, and the gas distribution side port of the Y-shaped pipe is suspended from the gas distribution side of the U-shaped sleeve The predetermined height within the tube is capable of injecting the liquid fire fighting medium into the U-shaped sleeve.
  6. 根据权利要求4所述的危险化学品容器用惰封抑爆装备,其特征在于,在所述U型套管外还设有一Y型穿管,所述Y型穿管的下端口与所述消防支管液相接驳连通,所述Y型穿管的容器侧端口和配气侧端口均从所述U型套管的底联管穿入,所述Y型穿管的容器侧端口通过所述U型套管的容器侧竖管上部接近所述危险化学品容器的顶部的位置穿出,或与所述危险化学品容器的上方的喷淋管接驳,所述Y型穿管的配气侧端口悬于所述U型套管的配气侧竖管内的预设高度,能够向所述U型套管内注入所述液态消防介质。The inertial seal suppression device for a hazardous chemical container according to claim 4, wherein a Y-shaped through tube is disposed outside the U-shaped sleeve, and a lower port of the Y-shaped through tube is The fire branch pipe is connected to the liquid phase, and the container side port and the gas distribution side port of the Y-shaped pipe pass through the bottom pipe of the U-shaped bushing, and the container side port of the Y-shaped pipe passes through The upper portion of the container-side vertical tube of the U-shaped sleeve is passed out near the top of the dangerous chemical container, or is connected to the spray pipe above the dangerous chemical container, and the Y-shaped tube is matched The gas side port is suspended from a predetermined height in the gas distribution side riser of the U-shaped sleeve, and the liquid fire-fighting medium can be injected into the U-shaped sleeve.
  7. 根据权利要求5或6所述的危险化学品容器用惰封抑爆装备,其特征在于,所述Y型穿管与所述液态消防介质源液相连 通,所述液态消防介质源通过所述Y型穿管的配气侧端口向所述U型套管内提供所述液态消防介质,所述Y型穿管中滞留的液态消防介质作为穿管液体阀门将所述气态惰封介质与大气隔离,通过设定所述Y型穿管的配气侧端口的高度来调节所述穿管液体阀门的开闭压力。The inertial seal suppression device for a hazardous chemical container according to claim 5 or 6, wherein the Y-shaped through tube is connected to the liquid fire-fighting medium source liquid Passing, the liquid fire-fighting medium source supplies the liquid fire-fighting medium to the U-shaped sleeve through a gas distribution side port of the Y-shaped pipe, and the liquid fire-fighting medium retained in the Y-shaped pipe is used as a pipe-through liquid A valve isolates the gaseous inert seal medium from the atmosphere, and adjusts an opening and closing pressure of the through-pipe liquid valve by setting a height of a gas distribution side port of the Y-shaped through tube.
  8. 根据权利要求7所述的危险化学品容器用惰封抑爆装备,其特征在于,在所述Y型穿管上还设有控制所述Y型穿管的配气侧端口与所述消防支管之间连通的阀门,当该阀门关闭时,所述惰封装置内的气态惰封介质与大气之间的泄压通道被该阀门切断,所述液态消防介质源输入的液态消防介质能够直接经所述Y型穿管的容器侧端口喷出。The inertial seal suppression device for a hazardous chemical container according to claim 7, wherein a gas distribution side port for controlling the Y-shaped pipe and a fire branch pipe are further disposed on the Y-shaped pipe a valve communicating between the valve, when the valve is closed, the pressure relief passage between the gaseous inerting medium and the atmosphere in the inerting device is cut off by the valve, and the liquid fire medium input from the liquid fire medium source can directly pass through The container side port of the Y-shaped tube is ejected.
  9. 根据权利要求4所述的危险化学品容器用惰封抑爆装备,其特征在于,所述危险化学品容器有两个以上,每个所述危险化学品容器配装至少一套惰封装置,所述气态惰封介质源通过由配气总管、收气支管和配气支管构成的配气管网与各个所述危险化学品容器上的惰封装置气相接驳连通,所述液态消防介质源通过由消防总管和消防支管构成的消防管网与各个所述危险化学品容器上的惰封装置的底部液相接驳连通。The inert seal suppressing device for a hazardous chemical container according to claim 4, wherein the dangerous chemical container has two or more, and each of the dangerous chemical containers is equipped with at least one set of inert sealing devices. The source of the gaseous inerting medium passes through a gas distribution network composed of a gas distribution manifold, a gas collection branch pipe and a gas distribution branch pipe, and is connected to a gas phase connection device of each of the dangerous chemical containers, and the liquid fireproof medium source passes through A fire pipe network consisting of a fire main and a fire branch is in fluid communication with the bottom liquid phase of the inerting device on each of the hazardous chemical containers.
  10. 根据权利要求1所述的危险化学品容器用惰封抑爆装备,其特征在于,所述惰封装置还包括设置在所述危险化学品容器的顶部的惰封盘,所述惰封盘为带有泄压孔、盘腰接驳孔、盘顶人孔和盖体的箱式空腔结构体,所述惰封盘的泄压孔与所述危险化学品容器的顶部泄压孔气相接驳连通,所述U型套管的容器侧竖管的上端口与所述惰封盘上的盘腰接驳孔气相接驳连通,所述盘顶人孔上方通过所述盖体进行封闭。The idle seal suppression device for a hazardous chemical container according to claim 1, wherein said inerting device further comprises an idler disk disposed at a top of said hazardous chemical container, said idle disk being a box cavity structure having a pressure relief hole, a waist connection hole, a top hole and a cover body, wherein the pressure release hole of the idle seal disk is connected to the top pressure relief hole of the dangerous chemical container The upper port of the container-side standpipe of the U-shaped sleeve is in gas-phase communication with the waist-receiving hole on the idler disk, and the top of the disk-top manhole is closed by the cover.
  11. 根据权利要求1所述的危险化学品容器用惰封抑爆装备,其特征在于,所述气态惰封介质为氮气、零族稀有气体、二 氧化碳气体和水蒸汽中的一种或多种的组合,所述液态消防介质为水、防冻液、亲物料液体、水基消防泡沫中的一种或多种的组合。The inertial seal suppression device for a hazardous chemical container according to claim 1, wherein the gaseous inert seal medium is nitrogen, zero rare gas, and two A combination of one or more of carbon oxide gas and water vapor, the liquid fire fighting medium being a combination of one or more of water, antifreeze, parent material liquid, water based fire fighting foam.
  12. 根据权利要求1所述的危险化学品容器用惰封抑爆装备,其特征在于,所述U型套管全部或部分安装在所述危险化学品容器的外部,或者全部或部分安装在所述危险化学品容器内部。The inert seal embedding device for a hazardous chemical container according to claim 1, wherein the U-shaped sleeve is wholly or partially installed outside the hazardous chemical container, or is wholly or partially installed in the Dangerous chemical container interior.
  13. 根据权利要求5或6所述的危险化学品容器用惰封抑爆装备,其特征在于,所述U型套管和所述Y型穿管及其各组件、配件为分别制作并依次接驳,或一体制造。The inertial seal suppression device for a hazardous chemical container according to claim 5 or 6, wherein the U-shaped sleeve and the Y-shaped through tube and the components and accessories thereof are separately fabricated and sequentially connected , or integrated manufacturing.
  14. 一种基于危险化学品容器用惰封抑爆装备的防御方法,包括:A method of defense based on inertial seal suppression equipment for hazardous chemical containers, comprising:
    根据容器、容器群、辅助设施、操作设备及被保护物料的技术参数,结合敌弹技术参数进行惰封抑爆装备设计和列装工程设计;According to the technical parameters of the container, the container group, the auxiliary facilities, the operating equipment and the material to be protected, combined with the technical parameters of the enemy missile, the design and assembly engineering of the idle-sealed explosion-proof equipment;
    根据所述惰封抑爆装备的设计成果制造或选配所述危险化学品容器用惰封抑爆装备的配件,并按列装工程设计成果接驳和安装;Manufacture or select the accessories of the inert seal explosion-proof equipment for the dangerous chemical container according to the design result of the inert seal explosion-proof equipment, and connect and install according to the listed engineering design result;
    根据列装工程设计成果所列验收标准进行列装工程验收;The acceptance of the installation project shall be carried out according to the acceptance criteria listed in the listed engineering design results;
    选用负压驱氧法或充液驱氧法实现气态惰封介质驱氧充斥气态惰封介质源管路、惰封装置及容器气相空间;The negative pressure oxygen drive method or the liquid-filled oxygen-discharging method is adopted to realize the gas-filled medium-driven oxygen-filled gas inertial seal medium source pipeline, the inert seal device and the container gas phase space;
    操作气态惰封介质源和液态消防介质源,使之处于工作状态;Operating a gaseous inert seal medium source and a liquid fire medium source to operate in a working state;
    操作所述危险化学品容器的泵控系统,进行收料付料作业试运行,检验所述危险化学品容器和所述惰封抑爆装备的大小呼吸功能;Operating a pump control system of the hazardous chemical container, performing a trial operation of the receiving and discharging operation, and inspecting the size and breathing function of the hazardous chemical container and the inertial anti-explosion device;
    在全部功能检验合格后,惰封抑爆装备交付列装,实现罐群非战时节能减排和临战参战无需转换的独立性永久性防御战力。 After all the functional inspections are passed, the idle-sealed anti-explosive equipment is delivered and assembled, so that the non-wartime energy-saving emission reduction of the tank group and the independent permanent defensive power of the battle can be achieved without conversion.
  15. 根据权利要求14所述的防御方法,其特征在于,所述负压驱氧法的具体步骤包括:The defense method according to claim 14, wherein the specific steps of the negative pressure oxygenation method comprise:
    操作所述液态消防介质源,将液态消防介质注满Y型穿管,形成穿管液体阀门;Operating the liquid fire-fighting medium source, filling the liquid fire-fighting medium with a Y-shaped through pipe to form a pipe-through liquid valve;
    操作所述气态惰封介质源,向所述容器方向供气,同时,从所述危险化学品容器或其管路中的较低处抽出气体排入大气,直至所述危险化学品容器及其连通的管路中的含氧量达标。Operating the source of gaseous inerting medium to supply gas to the vessel while simultaneously withdrawing gas from the lower portion of the hazardous chemical vessel or its piping into the atmosphere until the hazardous chemical vessel and its The oxygen content in the connected pipeline is up to standard.
  16. 根据权利要求14所述的防御方法,其特征在于,所述充液驱氧法的具体步骤包括:The defense method according to claim 14, wherein the specific steps of the liquid-filling oxygen-discharging method comprise:
    操作所述危险化学品容器收料作业至最高物料液位,此过程中的容器内的大部分气体经套管液态阀门进入配气侧气相空间,再经穿管液体阀门排至大气,实现容器驱氧;Operating the hazardous chemical container receiving operation to the highest material level, in the process, most of the gas in the container enters the gas phase of the gas distribution side through the casing liquid valve, and is discharged to the atmosphere through the liquid pipe through the pipe to realize the container Exhaust oxygen
    操作所述液态消防介质源,将液态消防介质注满所述惰封抑爆装备的全部管路,实现惰封抑爆装备的全部或大部分管路驱氧;Operating the liquid fire-fighting medium source, filling the liquid fire-fighting medium with all the pipelines of the idle-sealed explosion-proof equipment, and realizing all or most of the pipelines of the inert-sealed explosion-proof equipment to drive oxygen;
    操作所述气态惰封介质源制备气态惰性介质,开启供气阀门;Operating the gaseous inerting medium source to prepare a gaseous inert medium, and opening a gas supply valve;
    操作所述液态消防介质源泄放或回收液态消防介质,同时将相对纯净的气态惰封介质引入配气总管、配气支管、收气支管和惰封装置的全部管路;Operating the liquid fire-fighting medium source to vent or recover the liquid fire-fighting medium, and simultaneously introducing relatively pure gaseous inert sealing medium into all the pipelines of the gas distribution manifold, the gas distribution branch pipe, the gas collection branch pipe and the inerting device;
    调整U型套管内的液位高度,形成套管液体阀门,至工作液位;Adjusting the liquid level in the U-shaped sleeve to form a casing liquid valve to the working liquid level;
    调整Y型穿管内的液位高度,形成穿管液体阀门,至安全液位;Adjust the liquid level in the Y-shaped pipe to form a liquid pipe through the pipe to a safe liquid level;
    操作所述危险化学品容器付料作业,将气态惰封介质吸入所述危险化学品容器的气相空间;Operating the hazardous chemical container receiving operation to draw a gaseous inerting medium into the gas phase space of the hazardous chemical container;
    查验所述危险化学品容器的气相空间含氧量是否低于被保护物料爆炸极限下限或设计含量。 Check whether the oxygen content of the gas phase space of the hazardous chemical container is lower than the lower limit of the explosion limit of the protected material or the designed content.
  17. 根据权利要求14所述的防御方法,其特征在于,所述试运行的步骤包括:The defense method according to claim 14, wherein the step of trial running comprises:
    分别查验所述危险化学品容器和所述惰封抑爆装备的压力和氧含量测定装置,记录初始数据;Detecting the pressure and oxygen content measuring device of the hazardous chemical container and the inertial anti-explosion device separately, and recording initial data;
    进行收料作业试运行,分别查验所述危险化学品容器和所述惰封抑爆装备的压力和氧含量测定装置,记录压力和氧含量数据;Performing a trial run of the receiving operation, respectively checking the pressure and oxygen content measuring device of the dangerous chemical container and the inert seal suppressing device, and recording pressure and oxygen content data;
    进行付料作业试运行,分别查验所述危险化学品容器和所述惰封抑爆装备的压力和氧含量测定装置,记录压力和氧含量数据;Carrying out the trial operation of the paying operation, respectively checking the pressure and oxygen content measuring device of the dangerous chemical container and the inert seal suppressing device, and recording the pressure and oxygen content data;
    检测所述气态惰封介质源和液态消防介质源的诸组件及部件功能;Detecting components of the gaseous inert seal medium source and the liquid fire fighting medium source and component functions;
    设计并实施破坏性实验,查验安全泄压功能。 Design and implement destructive experiments to check the safety relief function.
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EP3391944A3 (en) * 2017-03-27 2019-01-23 Sun, Qiangdan Dome-based cyclic inerting system for external floating roof tank and qhse storage and transport method thereof

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