WO2015141394A1 - Conditioning agent for fish paste product, and method for manufacturing fish paste product - Google Patents
Conditioning agent for fish paste product, and method for manufacturing fish paste product Download PDFInfo
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- WO2015141394A1 WO2015141394A1 PCT/JP2015/054959 JP2015054959W WO2015141394A1 WO 2015141394 A1 WO2015141394 A1 WO 2015141394A1 JP 2015054959 W JP2015054959 W JP 2015054959W WO 2015141394 A1 WO2015141394 A1 WO 2015141394A1
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- calcium carbonate
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- quality improver
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- fish paste
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L17/00—Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
- A23L17/70—Comminuted, e.g. emulsified, fish products; Processed products therefrom such as pastes, reformed or compressed products
Definitions
- the present invention relates to a quality improver for a fishery product and a method for producing a fishery product using the same.
- transglutaminase is expensive and it is an enzyme, it must be handled with care. Therefore, there is a demand for a quality improving agent that can impart elasticity without using transglutaminase.
- An object of the present invention is to provide a quality improver for an aquatic product that can provide sufficient elasticity without using transglutaminase, and a method for producing an aquatic product using the same.
- the quality improver for aquatic product of the present invention is characterized in that 2 to 20 parts by mass of an alkali metal salt is mixed with 100 parts by mass of calcium carbonate.
- alkali metal salts include alkali metal phosphates.
- alkali metal phosphates include trisodium phosphate and disodium phosphate.
- the BET specific surface area of calcium carbonate is preferably in the range of 10 to 40 m 2 / g.
- 0.1 to 3 parts by mass of an emulsifier may be mixed with 100 parts by mass of calcium carbonate.
- the method for producing a marine product of the present invention comprises the step of adding the quality improver of the present invention to surimi, adjusting the pH to 7.5 to 8.0, molding the surimi to which the quality improver has been added, And a step of heating.
- high jelly strength and high whiteness can be imparted to fishery products.
- BET specific surface area of the calcium carbonate in the present invention is preferably in the range of 10 ⁇ 40m 2 / g, preferably more in the range of 15 ⁇ 30m 2 / g, more 20 ⁇ 30 m 2 / It is preferable to be within the range of g. If the BET specific surface area is too small, dispersion into surimi is insufficient, and the action of calcium ions may not be sufficiently obtained. If the BET specific surface area is too large, the calcium carbonate aggregates, the dispersion into the surimi becomes worse, and a sufficient effect may not be obtained.
- calcium carbonate examples include synthetic calcium carbonate and natural calcium carbonate (heavy calcium carbonate).
- the calcium carbonate is preferably synthetic calcium carbonate.
- Synthetic calcium carbonate is not particularly limited.
- Examples of the synthetic calcium carbonate include precipitated (collaged) calcium carbonate and light calcium carbonate.
- Synthetic calcium carbonate can be produced, for example, by reacting calcium hydroxide with carbon dioxide.
- Calcium hydroxide can be produced, for example, by reacting calcium oxide with water.
- Calcium oxide can be produced, for example, by co-firing raw limestone with coke. In this case, since carbon dioxide gas is generated during firing, calcium carbonate can be produced by reacting this carbon dioxide gas with calcium hydroxide.
- Natural calcium carbonate is obtained by pulverizing naturally produced calcium carbonate ore by a known method.
- Examples of the method for pulverizing the raw calcium carbonate include a roller mill, a high-speed rotation mill (impact shear mill), a container drive medium mill (ball mill), a medium stirring mill, a planetary ball mill, and a jet mill.
- alkali metal salt examples include alkali metal phosphate, potassium carbonate, sodium carbonate and the like.
- alkali metal phosphate include trisodium phosphate, disodium phosphate, tetrasodium pyrophosphate, sodium tripolyphosphate, sodium polyphosphate, dipotassium phosphate, tripotassium phosphate, and tetrapotassium pyrophosphate.
- the alkali metal salt of the present invention is mixed by adding 2 to 20 parts by weight, preferably 2 to 10 parts by weight, more preferably 5 to 10 parts by weight, with respect to 100 parts by weight of calcium carbonate. If the content of the alkali metal salt is too small, the action of calcium ions may not be sufficiently obtained. When there is too much content of an alkali metal salt, the pH of surimi will become high too much and intensity
- the emulsifier is added in an amount of 0.1 to 3 parts by weight, preferably 1 to 2.5 parts by weight, and more preferably 2 to 2.5 parts by weight with respect to 100 parts by weight of calcium carbonate. May be mixed.
- effects such as improved dispersion of calcium carbonate, improved water retention of the kneaded product, and anti-aging effect of starch in the kneaded product can be obtained.
- emulsifier examples include glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, and propylene glycol fatty acid ester.
- the quality improving agent of the present invention can be prepared by adding and mixing an alkali metal salt with calcium carbonate.
- an alkali metal salt As a specific method, calcium carbonate powder and alkali metal salt powder are uniformly mixed with a mixer or the like. At this time, an emulsifier may be added as a powder or liquid and mixed.
- a quality improver is added to surimi and the pH is adjusted to 7.5 to 8.0, and then the surimi added with the quality improver is molded and heated. If the pH value is too low, the action of calcium ions may not be sufficiently obtained. If the pH value is too high, the strength of surimi may decrease.
- fish paste in addition to fish paste as a raw material, known products such as starch, salt, saccharides, seasonings, fats and oils, and coloring agents can be added to the fish paste products.
- fish paste products include salmon, fried fish, chikuwa, hanpen, and fish sausage.
- the fishery paste product of the present invention is not limited to these.
- surimi added with a quality improver is molded according to the shape of the fishery product, and then heated.
- the heating temperature is not particularly limited, and is appropriately determined according to the raw material and the fishery kneaded product that is the final product.
- an alkali metal salt is added and mixed with a large amount of calcium carbonate. For this reason, generation
- Example 2 A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 5 parts by mass.
- Example 3 A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 10 parts by mass.
- Example 4 A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 20 parts by mass.
- the quality improvers obtained in Examples 1 to 4 and Comparative Examples 1 and 2 obtained above were blended with surimi to produce a fish paste product. Specifically, 40 parts by mass of water, 1 part by mass of a quality improver, 3 parts by mass of salt, and 5 parts by mass of starch were added to 100 parts by mass of surimi.
- the blending method involves roughening frozen surimi with a food processor, adding salt, and salting. When the surimi melted sufficiently, a quality improver, starch, and water were added, and the scouring was performed. After the end of sliding, it was filled in a vinylidene chloride casing having a folding diameter of 48 mm, sat in 60 ° C. warm water for 60 minutes, and then boiled at 90 ° C. for 30 minutes. After rapid cooling, after storing overnight at 10 ° C. in a refrigerator, it was cut into 25 mm round slices.
- Comparative Example 3 in which only 0.9 parts by mass of calcium carbonate was added and Comparative Example 4 in which only 0.1 parts by mass of trisodium phosphate were added were prepared. Moreover, after adding 0.9 mass part of calcium carbonate as a quality improvement agent, the comparative example 5 which added 0.1 mass part of trisodium phosphate was produced.
- the breaking load (g) and the concave value (cm) were measured by pressing a blanker having a diameter of 5 mm ⁇ .
- the value obtained by integrating the breaking load and the concave value was taken as the jelly strength (g ⁇ cm).
- Table 1 shows the measurement results.
- Example 5 A quality improver was prepared in the same manner as in Example 2 except that synthetic calcium carbonate having a BET specific surface area of 10 m 2 / g was used.
- Example 6 A quality improver was prepared in the same manner as in Example 2 except that synthetic calcium carbonate having a BET specific surface area of 20 m 2 / g was used.
- Example 7 A quality improver was prepared in the same manner as in Example 2 except that synthetic calcium carbonate having a BET specific surface area of 40 m 2 / g was used.
- Table 2 shows the measurement results. Table 2 also shows the results of Example 2.
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- Life Sciences & Earth Sciences (AREA)
- Marine Sciences & Fisheries (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Fish Paste Products (AREA)
Abstract
Provided are a conditioning agent for a fish paste product, with which ample resilience can be imparted without the use of transglutaminase, and a method for a manufacturing fish paste product employing the same. This conditioning agent for a fish paste product is characterized in that an alkali metal salt is mixed in at a level of 2-20 mass parts per 100 mass parts of calcium carbonate.
Description
本発明は、水産練り製品の品質改良剤及びそれを用いた水産練り製品の製造方法に関する。
[Technical Field] The present invention relates to a quality improver for a fishery product and a method for producing a fishery product using the same.
水産練り製品としては、蒲鉾、さつま揚げ、ちくわ、はんぺん、魚肉ソーセージ等の魚肉すり身を主成分とするものが知られている。これらの水産練り製品には、一般的に、品質として弾力が求められている。弾力を付与する方法として、魚肉すり身中にネットワークを形成させる方法が知られている。ネットワークを形成させて弾力を付与する品種改良剤として、トランスグルタミナーゼを用いる方法が提案されている（特許文献１など）。
As fishery products, products based on fish paste such as salmon, fried fish, chikuwa, hampen, and fish sausage are known. These marine products are generally required to be elastic as quality. As a method of imparting elasticity, a method of forming a network in ground fish meat is known. A method using transglutaminase has been proposed as a breeding agent for forming a network and imparting elasticity (Patent Document 1, etc.).
しかしながら、トランスグルタミナーゼは高価であり、また酵素であるので取り扱いに注意を要する。このため、トランスグルタミナーゼを用いずに弾力を付与することができる品質改良剤が求められている。
However, since transglutaminase is expensive and it is an enzyme, it must be handled with care. Therefore, there is a demand for a quality improving agent that can impart elasticity without using transglutaminase.
本発明の目的は、トランスグルタミナーゼを用いずとも、十分な弾力を付与することができる水産練り製品の品質改良剤及びそれを用いた水産練り製品の製造方法を提供することにある。
An object of the present invention is to provide a quality improver for an aquatic product that can provide sufficient elasticity without using transglutaminase, and a method for producing an aquatic product using the same.
本発明の水産練り製品の品質改良剤は、炭酸カルシウム１００質量部に対して、２～２０質量部のアルカリ金属塩を混合したことを特徴としている。
The quality improver for aquatic product of the present invention is characterized in that 2 to 20 parts by mass of an alkali metal salt is mixed with 100 parts by mass of calcium carbonate.
アルカリ金属塩として、具体的には、リン酸アルカリ金属塩が挙げられる。また、リン酸アルカリ金属塩としては、リン酸三ナトリウム及びリン酸二ナトリウムが挙げられる。
Specific examples of alkali metal salts include alkali metal phosphates. Examples of the alkali metal phosphate include trisodium phosphate and disodium phosphate.
炭酸カルシウムのＢＥＴ比表面積は、１０～４０ｍ２／ｇの範囲であることが好ましい。
The BET specific surface area of calcium carbonate is preferably in the range of 10 to 40 m 2 / g.
炭酸カルシウム１００質量部に対して、さらに乳化剤が０．１～３質量部混合されていてもよい。
Further, 0.1 to 3 parts by mass of an emulsifier may be mixed with 100 parts by mass of calcium carbonate.
本発明の水産練り製品の製造方法は、上記本発明の品質改良剤を、すり身に添加し、ｐＨを７．５～８．０に調整する工程と、品質改良剤を添加したすり身を成型し、加熱する工程とを備えることを特徴としている。
The method for producing a marine product of the present invention comprises the step of adding the quality improver of the present invention to surimi, adjusting the pH to 7.5 to 8.0, molding the surimi to which the quality improver has been added, And a step of heating.
本発明の製造方法においては、すり身１００質量部に対して、品質改良剤を０．１～５．０質量部添加することが好ましい。
In the production method of the present invention, it is preferable to add 0.1 to 5.0 parts by mass of a quality improver to 100 parts by mass of surimi.
本発明によれば、高いゼリー強度と高い白色度を水産練り製品に付与することができる。
According to the present invention, high jelly strength and high whiteness can be imparted to fishery products.
以下、本発明についてさらに詳細に説明する。
Hereinafter, the present invention will be described in more detail.
（炭酸カルシウム）
本発明における炭酸カルシウムのＢＥＴ比表面積は、１０～４０ｍ２／ｇの範囲内であることが好ましく、さらには１５～３０ｍ２／ｇの範囲内であることが好ましく、さらには２０～３０ｍ２／ｇの範囲内であることが好ましい。ＢＥＴ比表面積が小さすぎると、すり身への分散が不十分で、カルシウムイオンの作用が十分に得られない場合がある。ＢＥＴ比表面積が大きすぎると、炭酸カルシウムが凝集してしまい、すり身への分散が悪くなり、十分な効果が得られない場合がある。 (Calcium carbonate)
BET specific surface area of the calcium carbonate in the present invention is preferably in the range of 10 ~ 40m 2 / g, preferably more in the range of 15 ~ 30m 2 / g, more 20 ~ 30 m 2 / It is preferable to be within the range of g. If the BET specific surface area is too small, dispersion into surimi is insufficient, and the action of calcium ions may not be sufficiently obtained. If the BET specific surface area is too large, the calcium carbonate aggregates, the dispersion into the surimi becomes worse, and a sufficient effect may not be obtained.
本発明における炭酸カルシウムのＢＥＴ比表面積は、１０～４０ｍ２／ｇの範囲内であることが好ましく、さらには１５～３０ｍ２／ｇの範囲内であることが好ましく、さらには２０～３０ｍ２／ｇの範囲内であることが好ましい。ＢＥＴ比表面積が小さすぎると、すり身への分散が不十分で、カルシウムイオンの作用が十分に得られない場合がある。ＢＥＴ比表面積が大きすぎると、炭酸カルシウムが凝集してしまい、すり身への分散が悪くなり、十分な効果が得られない場合がある。 (Calcium carbonate)
BET specific surface area of the calcium carbonate in the present invention is preferably in the range of 10 ~ 40m 2 / g, preferably more in the range of 15 ~ 30m 2 / g, more 20 ~ 30 m 2 / It is preferable to be within the range of g. If the BET specific surface area is too small, dispersion into surimi is insufficient, and the action of calcium ions may not be sufficiently obtained. If the BET specific surface area is too large, the calcium carbonate aggregates, the dispersion into the surimi becomes worse, and a sufficient effect may not be obtained.
炭酸カルシウムの具体例としては、合成炭酸カルシウム、天然炭酸カルシウム（重質炭酸カルシウム）などが挙げられる。炭酸カルシウムは、合成炭酸カルシウムであることが好ましい。
Specific examples of calcium carbonate include synthetic calcium carbonate and natural calcium carbonate (heavy calcium carbonate). The calcium carbonate is preferably synthetic calcium carbonate.
合成炭酸カルシウムは、特に限定されない。合成炭酸カルシウムとしては、例えば沈降性（膠質）炭酸カルシウム、軽質炭酸カルシウムなどが挙げられる。合成炭酸カルシウムは、例えば水酸化カルシウムを炭酸ガスと反応させることによって製造することができる。水酸化カルシウムは、例えば酸化カルシウムを水と反応させることによって製造することができる。酸化カルシウムは、例えば石灰石原石をコークスなどで混焼することによって製造することができる。この場合、焼成時に炭酸ガスが発生するので、この炭酸ガスを水酸化カルシウムと反応させることによって炭酸カルシウムを製造することができる。
Synthetic calcium carbonate is not particularly limited. Examples of the synthetic calcium carbonate include precipitated (collaged) calcium carbonate and light calcium carbonate. Synthetic calcium carbonate can be produced, for example, by reacting calcium hydroxide with carbon dioxide. Calcium hydroxide can be produced, for example, by reacting calcium oxide with water. Calcium oxide can be produced, for example, by co-firing raw limestone with coke. In this case, since carbon dioxide gas is generated during firing, calcium carbonate can be produced by reacting this carbon dioxide gas with calcium hydroxide.
天然炭酸カルシウムは、天然に産出する炭酸カルシウム原石を公知の方法で粉砕することにより得られるものである。炭酸カルシウム原石を粉砕する方法としては、ローラーミル、高速回転ミル（衝撃剪断ミル）、容器駆動媒体ミル（ボールミル）、媒体撹拌ミル、遊星ボールミル、ジェットミルなどで粉砕する方法が挙げられる。
Natural calcium carbonate is obtained by pulverizing naturally produced calcium carbonate ore by a known method. Examples of the method for pulverizing the raw calcium carbonate include a roller mill, a high-speed rotation mill (impact shear mill), a container drive medium mill (ball mill), a medium stirring mill, a planetary ball mill, and a jet mill.
（アルカリ金属塩）
本発明におけるアルカリ金属塩としては、リン酸アルカリ金属塩、炭酸カリウム塩、炭酸ナトリウム塩などが挙げられる。リン酸アルカリ金属塩としては、リン酸三ナトリウム、リン酸二ナトリウム、ピロリン酸四ナトリウム、トリポリリン酸ナトリウム、ポリリン酸ナトリウム、リン酸二カリウム、リン酸三カリウム、ピロリン酸四カリウムなどが挙げられる。 (Alkali metal salt)
Examples of the alkali metal salt in the present invention include alkali metal phosphate, potassium carbonate, sodium carbonate and the like. Examples of the alkali metal phosphate include trisodium phosphate, disodium phosphate, tetrasodium pyrophosphate, sodium tripolyphosphate, sodium polyphosphate, dipotassium phosphate, tripotassium phosphate, and tetrapotassium pyrophosphate.
本発明におけるアルカリ金属塩としては、リン酸アルカリ金属塩、炭酸カリウム塩、炭酸ナトリウム塩などが挙げられる。リン酸アルカリ金属塩としては、リン酸三ナトリウム、リン酸二ナトリウム、ピロリン酸四ナトリウム、トリポリリン酸ナトリウム、ポリリン酸ナトリウム、リン酸二カリウム、リン酸三カリウム、ピロリン酸四カリウムなどが挙げられる。 (Alkali metal salt)
Examples of the alkali metal salt in the present invention include alkali metal phosphate, potassium carbonate, sodium carbonate and the like. Examples of the alkali metal phosphate include trisodium phosphate, disodium phosphate, tetrasodium pyrophosphate, sodium tripolyphosphate, sodium polyphosphate, dipotassium phosphate, tripotassium phosphate, and tetrapotassium pyrophosphate.
本発明のアルカリ金属塩は、炭酸カルシウム１００質量部に対して、２～２０質量部、好ましくは２～１０質量部、さらに好ましくは５～１０質量部添加して混合される。アルカリ金属塩の含有量が少なすぎると、カルシウムイオンの作用を十分に得ることができない場合がある。アルカリ金属塩の含有量が多すぎると、すり身のｐＨが高くなり過ぎて、強度が低下する場合がある。
The alkali metal salt of the present invention is mixed by adding 2 to 20 parts by weight, preferably 2 to 10 parts by weight, more preferably 5 to 10 parts by weight, with respect to 100 parts by weight of calcium carbonate. If the content of the alkali metal salt is too small, the action of calcium ions may not be sufficiently obtained. When there is too much content of an alkali metal salt, the pH of surimi will become high too much and intensity | strength may fall.
（乳化剤）
本発明の品質改良剤においては、乳化剤が炭酸カルシウム１００質量部に対して、０．１～３質量部、好ましくは１～２．５質量部、さらに好ましくは２～２．５質量部添加して混合されていてもよい。乳化剤を添加混合することにより、炭酸カルシウムの分散向上や練り製品の保水性向上、練り製品中の澱粉の老化防止効果などの効果が得られる。 (emulsifier)
In the quality improver of the present invention, the emulsifier is added in an amount of 0.1 to 3 parts by weight, preferably 1 to 2.5 parts by weight, and more preferably 2 to 2.5 parts by weight with respect to 100 parts by weight of calcium carbonate. May be mixed. By adding and mixing an emulsifier, effects such as improved dispersion of calcium carbonate, improved water retention of the kneaded product, and anti-aging effect of starch in the kneaded product can be obtained.
本発明の品質改良剤においては、乳化剤が炭酸カルシウム１００質量部に対して、０．１～３質量部、好ましくは１～２．５質量部、さらに好ましくは２～２．５質量部添加して混合されていてもよい。乳化剤を添加混合することにより、炭酸カルシウムの分散向上や練り製品の保水性向上、練り製品中の澱粉の老化防止効果などの効果が得られる。 (emulsifier)
In the quality improver of the present invention, the emulsifier is added in an amount of 0.1 to 3 parts by weight, preferably 1 to 2.5 parts by weight, and more preferably 2 to 2.5 parts by weight with respect to 100 parts by weight of calcium carbonate. May be mixed. By adding and mixing an emulsifier, effects such as improved dispersion of calcium carbonate, improved water retention of the kneaded product, and anti-aging effect of starch in the kneaded product can be obtained.
乳化剤としては、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステルなどが挙げられる。
Examples of the emulsifier include glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, and propylene glycol fatty acid ester.
（品質改良剤の調製方法）
本発明の品質改良剤は、炭酸カルシウムにアルカリ金属塩を添加混合することにより調製することができる。具体的な方法としては、炭酸カルシウム粉体とアルカリ金属塩粉体をミキサー等で均一に混合する。このとき、乳化剤を粉体、または液体で添加して混合しても良い。 (Method for preparing quality improver)
The quality improving agent of the present invention can be prepared by adding and mixing an alkali metal salt with calcium carbonate. As a specific method, calcium carbonate powder and alkali metal salt powder are uniformly mixed with a mixer or the like. At this time, an emulsifier may be added as a powder or liquid and mixed.
本発明の品質改良剤は、炭酸カルシウムにアルカリ金属塩を添加混合することにより調製することができる。具体的な方法としては、炭酸カルシウム粉体とアルカリ金属塩粉体をミキサー等で均一に混合する。このとき、乳化剤を粉体、または液体で添加して混合しても良い。 (Method for preparing quality improver)
The quality improving agent of the present invention can be prepared by adding and mixing an alkali metal salt with calcium carbonate. As a specific method, calcium carbonate powder and alkali metal salt powder are uniformly mixed with a mixer or the like. At this time, an emulsifier may be added as a powder or liquid and mixed.
（水産練り製品の製造方法）
本発明の製造方法では、品質改良剤をすり身に添加し、ｐＨを７．５～８．０に調整した後、品質改良剤を添加したすり身を成型し、加熱する。ｐＨの値が低すぎると、カルシウムイオンの作用を十分に得ることができない場合がある。ｐＨの値が高すぎると、すり身の強度が低下する場合がある。 (Manufacturing method for marine products)
In the production method of the present invention, a quality improver is added to surimi and the pH is adjusted to 7.5 to 8.0, and then the surimi added with the quality improver is molded and heated. If the pH value is too low, the action of calcium ions may not be sufficiently obtained. If the pH value is too high, the strength of surimi may decrease.
本発明の製造方法では、品質改良剤をすり身に添加し、ｐＨを７．５～８．０に調整した後、品質改良剤を添加したすり身を成型し、加熱する。ｐＨの値が低すぎると、カルシウムイオンの作用を十分に得ることができない場合がある。ｐＨの値が高すぎると、すり身の強度が低下する場合がある。 (Manufacturing method for marine products)
In the production method of the present invention, a quality improver is added to surimi and the pH is adjusted to 7.5 to 8.0, and then the surimi added with the quality improver is molded and heated. If the pH value is too low, the action of calcium ions may not be sufficiently obtained. If the pH value is too high, the strength of surimi may decrease.
水産練り製品には、原料となる魚肉すり身の他、澱粉、食塩、糖類、調味料、油脂、着色料など公知のものを添加することができる。水産練り製品としては、例えば、蒲鉾、さつま揚げ、ちくわ、はんぺん、魚肉ソーセージ等が挙げられる。但し、本発明の水産練り製品は、これらに限定されるものではない。
In addition to fish paste as a raw material, known products such as starch, salt, saccharides, seasonings, fats and oils, and coloring agents can be added to the fish paste products. Examples of fish paste products include salmon, fried fish, chikuwa, hanpen, and fish sausage. However, the fishery paste product of the present invention is not limited to these.
本発明の製造方法では、水産練り製品の形状に合わせて、品質改良剤を添加したすり身を成型し、その後加熱する。加熱温度は、特に限定されるものではなく、原料及び最終製品である水産練り製品に応じて、適宜決定される。
In the production method of the present invention, surimi added with a quality improver is molded according to the shape of the fishery product, and then heated. The heating temperature is not particularly limited, and is appropriately determined according to the raw material and the fishery kneaded product that is the final product.
本発明の品質改良剤は、アルカリ金属塩が多量の炭酸カルシウムに添加混合されている。このため、すり身にアルカリ金属塩を単独で添加した場合に生じるすり身のやけの発生を防止することができる。また、炭酸カルシウムに含まれるカルシウムイオンの作用により、すり身に十分な弾力を付与することができる。
In the quality improver of the present invention, an alkali metal salt is added and mixed with a large amount of calcium carbonate. For this reason, generation | occurrence | production of the burn of the surimi which arises when an alkali metal salt is added independently to a surimi can be prevented. Moreover, sufficient elasticity can be provided to surimi by the action of calcium ions contained in calcium carbonate.
＜品質改良剤の調製＞
（実施例１）
炭酸カルシウム（ＢＥＴ比表面積３０ｍ２／ｇの合成炭酸カルシウム)１００質量部に対して、２質量部のリン酸三ナトリウムを添加し、十分に混合して、品質改良剤を調製した。 <Preparation of quality improver>
Example 1
To 100 parts by mass of calcium carbonate (synthetic calcium carbonate having a BET specific surface area of 30 m 2 / g), 2 parts by mass of trisodium phosphate was added and mixed well to prepare a quality improver.
（実施例１）
炭酸カルシウム（ＢＥＴ比表面積３０ｍ２／ｇの合成炭酸カルシウム)１００質量部に対して、２質量部のリン酸三ナトリウムを添加し、十分に混合して、品質改良剤を調製した。 <Preparation of quality improver>
Example 1
To 100 parts by mass of calcium carbonate (synthetic calcium carbonate having a BET specific surface area of 30 m 2 / g), 2 parts by mass of trisodium phosphate was added and mixed well to prepare a quality improver.
（実施例２）
リン酸三ナトリウムの添加量を、５質量部とする以外は、実施例１と同様にして品質改良剤を調製した。 (Example 2)
A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 5 parts by mass.
リン酸三ナトリウムの添加量を、５質量部とする以外は、実施例１と同様にして品質改良剤を調製した。 (Example 2)
A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 5 parts by mass.
（実施例３）
リン酸三ナトリウムの添加量を、１０質量部とする以外は、実施例１と同様にして品質改良剤を調製した。 Example 3
A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 10 parts by mass.
リン酸三ナトリウムの添加量を、１０質量部とする以外は、実施例１と同様にして品質改良剤を調製した。 Example 3
A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 10 parts by mass.
（実施例４）
リン酸三ナトリウムの添加量を、２０質量部とする以外は、実施例１と同様にして品質改良剤を調製した。 Example 4
A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 20 parts by mass.
リン酸三ナトリウムの添加量を、２０質量部とする以外は、実施例１と同様にして品質改良剤を調製した。 Example 4
A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 20 parts by mass.
（比較例１）
リン酸三ナトリウムの添加量を、１質量部とする以外は、実施例１と同様にして品質改良剤を調製した。 (Comparative Example 1)
A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 1 part by mass.
リン酸三ナトリウムの添加量を、１質量部とする以外は、実施例１と同様にして品質改良剤を調製した。 (Comparative Example 1)
A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 1 part by mass.
（比較例２）
リン酸三ナトリウムの添加量を、２５質量部とする以外は、実施例１と同様にして品質改良剤を調製した。 (Comparative Example 2)
A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 25 parts by mass.
リン酸三ナトリウムの添加量を、２５質量部とする以外は、実施例１と同様にして品質改良剤を調製した。 (Comparative Example 2)
A quality improver was prepared in the same manner as in Example 1 except that the amount of trisodium phosphate added was 25 parts by mass.
＜水産練り製品の製造＞
上記で得られた実施例１～４及び比較例１～２の品質改良剤を、すり身に配合して水産練り製品を製造した。具体的には、すり身１００質量部に対し、水４０質量部、品質改良剤１質量部、食塩３質量部、及び澱粉５質量部を添加した。配合方法は、冷凍のすり身をフードプロセッサーで荒摺りした後、食塩を添加し、塩摺りを行う。すり身が十分に溶けたら、品質改良剤、澱粉、水を添加し、本摺りを行った。摺り終わり後に折径４８ｍｍの塩化ビニリデンケーシングに充填、３０℃の温水中で６０分の坐りを行った後、９０℃で３０分のボイル加熱を行った。急冷後、一晩１０℃で冷蔵庫に保存した後、２５ｍｍの輪切りにした。 <Manufacture of marine products>
The quality improvers obtained in Examples 1 to 4 and Comparative Examples 1 and 2 obtained above were blended with surimi to produce a fish paste product. Specifically, 40 parts by mass of water, 1 part by mass of a quality improver, 3 parts by mass of salt, and 5 parts by mass of starch were added to 100 parts by mass of surimi. The blending method involves roughening frozen surimi with a food processor, adding salt, and salting. When the surimi melted sufficiently, a quality improver, starch, and water were added, and the scouring was performed. After the end of sliding, it was filled in a vinylidene chloride casing having a folding diameter of 48 mm, sat in 60 ° C. warm water for 60 minutes, and then boiled at 90 ° C. for 30 minutes. After rapid cooling, after storing overnight at 10 ° C. in a refrigerator, it was cut into 25 mm round slices.
上記で得られた実施例１～４及び比較例１～２の品質改良剤を、すり身に配合して水産練り製品を製造した。具体的には、すり身１００質量部に対し、水４０質量部、品質改良剤１質量部、食塩３質量部、及び澱粉５質量部を添加した。配合方法は、冷凍のすり身をフードプロセッサーで荒摺りした後、食塩を添加し、塩摺りを行う。すり身が十分に溶けたら、品質改良剤、澱粉、水を添加し、本摺りを行った。摺り終わり後に折径４８ｍｍの塩化ビニリデンケーシングに充填、３０℃の温水中で６０分の坐りを行った後、９０℃で３０分のボイル加熱を行った。急冷後、一晩１０℃で冷蔵庫に保存した後、２５ｍｍの輪切りにした。 <Manufacture of marine products>
The quality improvers obtained in Examples 1 to 4 and Comparative Examples 1 and 2 obtained above were blended with surimi to produce a fish paste product. Specifically, 40 parts by mass of water, 1 part by mass of a quality improver, 3 parts by mass of salt, and 5 parts by mass of starch were added to 100 parts by mass of surimi. The blending method involves roughening frozen surimi with a food processor, adding salt, and salting. When the surimi melted sufficiently, a quality improver, starch, and water were added, and the scouring was performed. After the end of sliding, it was filled in a vinylidene chloride casing having a folding diameter of 48 mm, sat in 60 ° C. warm water for 60 minutes, and then boiled at 90 ° C. for 30 minutes. After rapid cooling, after storing overnight at 10 ° C. in a refrigerator, it was cut into 25 mm round slices.
品質改良剤として、炭酸カルシウムのみを０．９質量部添加した比較例３、リン酸三ナトリウムのみを０．１質量部添加した比較例４を作製した。また、品質改良剤として、炭酸カルシウムを０．９質量部添加した後、リン酸三ナトリウムを０．１質量部添加した比較例５を作製した。
As a quality improver, Comparative Example 3 in which only 0.9 parts by mass of calcium carbonate was added and Comparative Example 4 in which only 0.1 parts by mass of trisodium phosphate were added were prepared. Moreover, after adding 0.9 mass part of calcium carbonate as a quality improvement agent, the comparative example 5 which added 0.1 mass part of trisodium phosphate was produced.
＜水産練り製品の評価＞
得られた水産練り製品について、以下のようにして、ゼリー強度及び白色度を測定した。 <Evaluation of marine products>
About the obtained marine product, jelly strength and whiteness were measured as follows.
得られた水産練り製品について、以下のようにして、ゼリー強度及び白色度を測定した。 <Evaluation of marine products>
About the obtained marine product, jelly strength and whiteness were measured as follows.
（ゼリー強度）
直径５ｍｍφのブランジャの押し込みで、破断荷重（ｇ）、凹値（ｃｍ）を測定した。破断荷重と凹値を積算した値をゼリー強度（ｇ・ｃｍ）とした。 (Jelly strength)
The breaking load (g) and the concave value (cm) were measured by pressing a blanker having a diameter of 5 mmφ. The value obtained by integrating the breaking load and the concave value was taken as the jelly strength (g · cm).
直径５ｍｍφのブランジャの押し込みで、破断荷重（ｇ）、凹値（ｃｍ）を測定した。破断荷重と凹値を積算した値をゼリー強度（ｇ・ｃｍ）とした。 (Jelly strength)
The breaking load (g) and the concave value (cm) were measured by pressing a blanker having a diameter of 5 mmφ. The value obtained by integrating the breaking load and the concave value was taken as the jelly strength (g · cm).
（白色度）
試料の切断面を色差計でＬ値、a値、ｂ値をそれぞれ測定して、白色度を算出した。 (Whiteness)
The cut surface of the sample was measured for L value, a value, and b value with a color difference meter, and whiteness was calculated.
試料の切断面を色差計でＬ値、a値、ｂ値をそれぞれ測定して、白色度を算出した。 (Whiteness)
The cut surface of the sample was measured for L value, a value, and b value with a color difference meter, and whiteness was calculated.
（白色度）＝１００－ｓｑｒ［（１００－Ｌ）２＋ａ２＋ｂ２］
ｓｑｒ：平方根 (Whiteness) = 100−sqr [(100−L) 2 + a 2 + b 2 ]
sqr: square root
ｓｑｒ：平方根 (Whiteness) = 100−sqr [(100−L) 2 + a 2 + b 2 ]
sqr: square root
測定結果を表１に示す。
Table 1 shows the measurement results.
表１に示すように、本発明に従う実施例１～４では、比較例１～５に比べ、高いゼリー強度及び高い白色度が得られていることがわかる。比較例５に示すように、炭酸カルシウムとリン酸三ナトリウムを別々に添加したのでは、本発明の効果が得られないことがわかる。
As shown in Table 1, it can be seen that in Examples 1 to 4 according to the present invention, higher jelly strength and higher whiteness were obtained than in Comparative Examples 1 to 5. As shown in Comparative Example 5, it can be seen that the effects of the present invention cannot be obtained when calcium carbonate and trisodium phosphate are added separately.
＜ＢＥＴ比表面積の検討＞
（実施例５）
ＢＥＴ比表面積が１０ｍ２／ｇである合成炭酸カルシウムを用いる以外は、実施例２と同様にして品質改良剤を調製した。 <Examination of BET specific surface area>
(Example 5)
A quality improver was prepared in the same manner as in Example 2 except that synthetic calcium carbonate having a BET specific surface area of 10 m 2 / g was used.
（実施例５）
ＢＥＴ比表面積が１０ｍ２／ｇである合成炭酸カルシウムを用いる以外は、実施例２と同様にして品質改良剤を調製した。 <Examination of BET specific surface area>
(Example 5)
A quality improver was prepared in the same manner as in Example 2 except that synthetic calcium carbonate having a BET specific surface area of 10 m 2 / g was used.
（実施例６）
ＢＥＴ比表面積が２０ｍ２／ｇである合成炭酸カルシウムを用いる以外は、実施例２と同様にして品質改良剤を調製した。 (Example 6)
A quality improver was prepared in the same manner as in Example 2 except that synthetic calcium carbonate having a BET specific surface area of 20 m 2 / g was used.
ＢＥＴ比表面積が２０ｍ２／ｇである合成炭酸カルシウムを用いる以外は、実施例２と同様にして品質改良剤を調製した。 (Example 6)
A quality improver was prepared in the same manner as in Example 2 except that synthetic calcium carbonate having a BET specific surface area of 20 m 2 / g was used.
（実施例７）
ＢＥＴ比表面積が４０ｍ２／ｇである合成炭酸カルシウムを用いる以外は、実施例２と同様にして品質改良剤を調製した。 (Example 7)
A quality improver was prepared in the same manner as in Example 2 except that synthetic calcium carbonate having a BET specific surface area of 40 m 2 / g was used.
ＢＥＴ比表面積が４０ｍ２／ｇである合成炭酸カルシウムを用いる以外は、実施例２と同様にして品質改良剤を調製した。 (Example 7)
A quality improver was prepared in the same manner as in Example 2 except that synthetic calcium carbonate having a BET specific surface area of 40 m 2 / g was used.
＜水産練り製品の製造＞
上記で得られた実施例５～７の品質改良剤を用いて、上記と同様にして水産練り製品を製造した。 <Manufacture of marine products>
Using the quality improvers of Examples 5 to 7 obtained above, fishery paste products were produced in the same manner as described above.
上記で得られた実施例５～７の品質改良剤を用いて、上記と同様にして水産練り製品を製造した。 <Manufacture of marine products>
Using the quality improvers of Examples 5 to 7 obtained above, fishery paste products were produced in the same manner as described above.
＜水産練り製品の評価＞
得られた水産練り製品について、上記と同様にしてゼリー強度及び白色度を測定した。 <Evaluation of marine products>
About the obtained marine product, the jelly strength and whiteness were measured in the same manner as described above.
得られた水産練り製品について、上記と同様にしてゼリー強度及び白色度を測定した。 <Evaluation of marine products>
About the obtained marine product, the jelly strength and whiteness were measured in the same manner as described above.
測定結果を表２に示す。なお、表２には、実施例２の結果も併せて示す。
Table 2 shows the measurement results. Table 2 also shows the results of Example 2.
表２に示すように、炭酸カルシウムのＢＥＴ比表面積が１０～４０ｍ２／ｇである範囲で、高いゼリー強度及び高い白色度が得られていることがわかる。
As shown in Table 2, it can be seen that high jelly strength and high whiteness are obtained in the range where the BET specific surface area of calcium carbonate is 10 to 40 m 2 / g.
Claims (7)
- 炭酸カルシウム１００質量部に対して、２～２０質量部のアルカリ金属塩を混合したことを特徴とする水産練り製品の品質改良剤。 A quality improver for aquatic products obtained by mixing 2 to 20 parts by mass of an alkali metal salt with 100 parts by mass of calcium carbonate.
- 前記アルカリ金属塩が、リン酸アルカリ金属塩であることを特徴とする請求項１に記載の水産練り製品の品質改良剤。 The quality improver for aquatic products according to claim 1, wherein the alkali metal salt is an alkali metal phosphate.
- 前記リン酸アルカリ金属塩が、リン酸三ナトリウムまたはリン酸二ナトリウムであることを特徴とする請求項２に記載の水産練り製品の品質改良剤。 The quality improver for aquatic product according to claim 2, wherein the alkali metal phosphate is trisodium phosphate or disodium phosphate.
- 前記炭酸カルシウムのＢＥＴ比表面積が、１０～４０ｍ２／ｇの範囲である請求項１～３のいずれか一項に記載の水産練り製品の品質改良剤。 The quality improver for aquatic product according to any one of claims 1 to 3, wherein the calcium carbonate has a BET specific surface area of 10 to 40 m 2 / g.
- 前記炭酸カルシウム１００質量部に対して、さらに乳化剤が０．１～３質量部混合されていることを特徴とする請求項１～４のいずれか一項に記載の水産練り製品の品質改良剤。 The quality improver for aquatic product according to any one of claims 1 to 4, wherein 0.1 to 3 parts by mass of an emulsifier is further mixed with 100 parts by mass of the calcium carbonate.
- 請求項１～５のいずれか一項に記載の品質改良剤を、すり身に添加し、ｐＨを７．５～８．０に調整する工程と、
前記品質改良剤を添加したすり身を成型し、加熱する工程とを備えることを特徴とする水産練り製品の製造方法。 Adding the quality improver according to any one of claims 1 to 5 to surimi and adjusting the pH to 7.5 to 8.0;
Forming a surimi to which the quality improver is added, and heating the surimi. - 前記すり身１００質量部に対して、前記品質改良剤を０．１～５．０質量部添加することを特徴とする請求項６に記載の水産練り製品の製造方法。 The method for producing an aquatic product according to claim 6, wherein 0.1 to 5.0 parts by mass of the quality improver is added to 100 parts by mass of the surimi.
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| JP2014053311A JP6370572B2 (en) | 2014-03-17 | 2014-03-17 | Quality improver for marine products and method for producing marine products |
| JP2014-053311 | 2014-03-17 |
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| PCT/JP2015/054959 WO2015141394A1 (en) | 2014-03-17 | 2015-02-23 | Conditioning agent for fish paste product, and method for manufacturing fish paste product |
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| EP3659969A4 (en) * | 2017-07-27 | 2021-05-26 | Shiraishi Kogyo Kaisha, Ltd. | Calcium carbonate, calcium carbonate preparation for food addition use, and food |
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| EP3659969A4 (en) * | 2017-07-27 | 2021-05-26 | Shiraishi Kogyo Kaisha, Ltd. | Calcium carbonate, calcium carbonate preparation for food addition use, and food |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6370572B2 (en) | 2018-08-08 |
| JP2015173646A (en) | 2015-10-05 |
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