WO2015090662A1

WO2015090662A1 - Heatable elastomeric hollow article, in particular a heatable hose

Info

Publication number: WO2015090662A1
Application number: PCT/EP2014/071482
Authority: WO
Inventors: Metin Tasseki; Rainer Lange
Original assignee: Contitech Schlauch Gmbh
Priority date: 2013-12-19
Filing date: 2014-10-08
Publication date: 2015-06-25
Also published as: DE102013226629A1

Abstract

The present invention relates to a heatable elastomeric hollow article (1), in particular a heatable hose (1), for conducting and/or accommodating liquid, gaseous and/or pasty media and having an electrically conductive heat conductor (3). The heatable elastomeric hollow article (1) is characterized in that the electrically conductive heat conductor (3) has at least one metallic stranded wire element (5a) and at least one non-metallic stranded wire element (5b).

Description

description

Heatable elastomeric hollow body, in particular heatable hose

The invention relates to a heatable elastomeric hollow body, in particular a heatable hose, according to the preamble of claim 1.

Elastomeric hollow bodies are used in a wide variety of applications to store and / or transport media. The term media refers to both liquid and gaseous or pasty media. For example, in automobiles, liquids such as e.g. Fuels, hydraulic fluids,

Refrigeration cycle agents, oils or additives in elastomeric hollow bodies, such as e.g. stored in a tank and / or transported in a hose. Due to the elastomeric material, rigid materials such as e.g. Metal or plastic a certain flexibility and elasticity can be achieved in order to facilitate the assembly or in use to achieve a desired bending and vibration behavior.

Such elastomeric hollow body are used in automobiles as heatable elastomeric hollow body, if the medium is to be heated if necessary. This is the case, for example, with the SCR technology (Selective Catalytic Reduction), because the urea used for the additive freezes below about -11 ° C. and is then no longer available for nitrogen reduction in the exhaust gas. In order to avoid this freezing, both the tank and the hoses, including connecting pieces of the SCR systems, are designed to be heatable. The usual heating is here about the electrical heat losses generated by the electrical resistance of metallic conductors. For this purpose, electrical heating conductors are generally used in the form of cylindrical wires or strands, which are electrically conductive and have an insulating sheath. The heating conductors are embedded in the elastomeric housing of the hollow body, such as a tank or hose, and their strands are supplied with electrical current from the outside, so that the strands can release their current heat losses into the elastomeric material of the housing, which then heats the stored or transported medium. see. For example, EP 1 329 660 B1. In SCR hoses, the heating conductors are often arranged helically around the inner layers of the hose and then covered from the outside with a further layer of hose. The finished tube body can then be cut to the desired length for further processing. The heating power can be adjusted to each other via the lateral spacing of the individual turns of the heating conductors, from which then the slope of the turns results to the longitudinal direction of the hose. The denser the windings, the larger and more evenly distributed the heating power. However, due to the higher density of the windings, the amount of heat conductors used and thus these costs, which are very significant for the total product costs of an SCR hose, also increase at the same time.

As metallic strands of the heating conductors are generally strands of one or more metallic components, i. Alloys, used. This metals are used, which have an electrical resistance, which is a good

Heat generation with sufficient electrical conductivity along the entire length of the planned hose product allows.

Such metals such as copper or alloys with copper content, however, have comparatively low tensile strengths, so that they deform plastically at higher tensile forces, ie dilute sections, which can lead to a change in the electrical resistance, since in these the cross-sectional area of considered body as a parameter. This also changes the heating behavior of the strands and thus the heating conductor in the SCR hose.

The exercise of such high tensile forces of e.g. up to 200 N can in

Manufacturing process of SCR tubes with heating conductors occur in that the heating conductors are applied helically to the inner layers of the hose and coated with at least one other layer to the outside. In order to provide the hose blank with a reinforcement at its ends and to be able to connect the strands to an electrical system, the heating conductors are usually freed at the ends from the outer tube layers or passed through them, cf. e.g. EP 1 329 660 B1. In both cases, the spiraling of the heating conductors in this area is canceled again in order to make room for the reinforcement and handle the strand ends, expose them from their insulation, provide them with connections and connect them. In this unwinding or pulling out of the heat conductor tensile forces can occur up to 200 N, which in some of the commonly used materials can lead to plastic deformation in the form of elongation of the strands, which at the same time a cross-sectional reduction or diameter reduction and thus an increase of the electrical Resistance causes. However, since the electrical

Resistance values for SCR hoses are very narrowly specified, even a slight change in the electrical resistance of the strand can lead to a violation of the specification.

To avoid this elongation metals can be used as stranded material, which the o.g. Withstand tensile forces. For this purpose, strands of steel, stainless steel or steel alloys as well as hybrid strands with steel core and copper cladding can be used, whereby the steel core provides the required tensile strength.

The disadvantage here, however, that steel has a comparatively high bending stiffness. This means in this case that comparatively high tensile stresses are required to the rigid heat conductor in small bending radii to the underlying Wind hose body. In this case, the high tensile stresses can press the heating conductor on the generally underlying underlying reinforcing layer, that in the electrical insulation of the heating element such as a plastic sheath to

Defects such as e.g. Notches or holes can come, which can lead up to the strand through which the insulation material. If these damages are recognized in time in the production, thereby increases the committee of

non-salable products. In use, these damage to the heating conductors can lead to failure of the hose. Furthermore, the high bending stiffness of the steel in the attachment of terminals, which is generally done by crimping hinders, because the spiral heating conductor largely retains its helical rotation due to the flexural rigidity of its strands even after exposing or pulling out of the hose material. As a result, the curved end of the heat conductor must be crimped by hand in general, because of the irregular configuration of the different degrees

wound heating conductor end eliminates an automatic crimping. To make this possible, a prior manual straightening would be required, which also means extra effort. A disadvantage of the use of strands of steel or steel content also that the low ductility of the steel leads to the fact that in a crimping of the strands with a connection within the crimped terminal cavities between the strand and the terminal interior or between the each

Litzenelementen can form themselves. This is undesirable because spark overruns can occur here. This disadvantage is usually avoided by connecting the steel strands to the terminal, e.g. a crimp sleeve to be welded. However, this causes an additional effort in the production of SCR hoses.

However, if the steel content of an alloy or a hybrid strand is reduced in favor of a more flexible material such as copper to increase the flexibility of the heating element as a whole, this results in a thicker strand in total because Steel has a higher electrical resistivity, ie resistivity, than copper, ie can produce a higher electrical loss heat, and so that the reduced mass fraction of the steel must be compensated by more copper material again. An object of the invention is therefore to provide a heatable elastomeric hollow body, in particular a heatable hose, of the type described above, the defined electrical resistance of the heating conductor remains secured in the production, the heating conductor a lower bending stiffness than steel strands at the same time at least comparable electrical Has resistance and / or its

Heating element easier and faster than steel strands can be provided with a connection.

The object is achieved according to fiction by a heatable elastomeric hollow body, in particular a heatable hose, with the features of claim 1. Advantageous developments are described in the subclaims.

Thus, the present invention relates to a heatable elastomeric hollow body and in particular to a heatable hose with an electrical heating conductor, the strand of which comprises both at least one metallic strand element and at least one non-metallic strand element. In this way, the functions of the strand of the heating element, in this case tensile strength and electrical heatability, not as previously known by the whole strand taken over but can be divided between the two strand elements, so that each strand element designed and used optimized for its function can be. Thus, the electrical conductivity to produce sufficient for the application of electrical heat losses through the metallic strand element

accepted. In this case, this property is optimized, so that metals with a relatively low tensile strength can be used. In particular, more flexible, i. Less rigid, metals than especially steel or

Steel alloys are used to provide sufficient electrical power at the same time

Heating power to allow easier production of the turns of the heating element and thereby simplifying the production of a heatable hose. This also simplifies the connection of the stranded wire to connection elements by means of a crimp connection, because the more flexible strand can be developed more easily and has less permanent curvature, so that straightening of the stranded end for crimping can be dispensed with. Furthermore, the strand can then also be handled automatically during crimping, which simplifies this process.

Also, damage to the insulation of the heat conductor can be avoided, since less pressure is exerted by the heating element on the underlying reinforcing layer due to the lower assembly forces when winding the fiction, modern heat conductor.

Furthermore, the lower tensile strength also causes the metallic material of the strand to undergo plastic deformation during crimping and can be compressed such that the voids between metallic and non-metallic

Fill strand element or inner surface of the connection element, so that a

Sparkover over cavities can be avoided. Also can be omitted so usual in steel strands welding process. This improved crimping process also results in improved thermal energy transfer, i. of the

electrical loss heat, the crimped metallic strand elements, which would otherwise be hindered by possible air pockets.

The use of this advantageous for the present application properties of the metallic Litzenelementes is possible because fiction, according to the transmission of tensile forces by the non-metallic Litzenelement. This can be optimized for this purpose. At the same time, the non-metallic strand element is at the same time very flexible, so that it supports the flexibility of the metallic strand element or at least does not hinder it or at least impedes it as little as possible. Preferably, the non-metallic Litzenelement has a plastic deformability, which supports the crimping process as well as the metallic strand element or this at least not at all or at least as little hindered. So can preferably textile high-strength threads are used as tension members, which may have all the aforementioned material properties.

Due to this combination of two strand elements not only a better plastic deformation in the crimping is achieved and the winding or developing the

Heat conductor easier, but also complied with the specification of the electrical resistance of the heating element in the production safely, because the tensile forces can be kept away from the metallic strand element and thus an extension of the metallic strand element can be avoided by tensile forces in the production.

Also, the number of materials that can be used as a resistive element is increased because they can now be used regardless of their tensile strength. This can become one

Reduction of the diameter of the heating lead, because by optimizing the heating properties of the metallic Litzenelementes and the tensile strength of the non-metallic Litzenelementes overall a reduction in cross section of the heating can be achieved, which can simultaneously lead to a reduction of the wall thickness of the outer layer of the elastomeric hollow body. These

Reduction in the cross section of the heat conductor can simultaneously reduce the manufacturing costs by reducing set-up times because larger run lengths can be provided on a supply coil.

According to one aspect of the invention, the electrically conductive heating conductor has a

Plurality of metallic strand elements. This can be metallic

Stranded elements with different materials and alloys as well as cross-sectional geometries and cross-sectional areas can be combined with one another or several identical metallic stranded elements can be used. It is advantageous here that the design scope is increased to provide a heating element according to the invention. According to a further aspect of the invention, the metallic strand elements surround the non-metallic strand element. The advantage here is that in this arrangement the non-metallic strand element can be arranged centrally as a tension member, so that it can transmit the tensile forces uniformly. Also, the metallic strand elements are arranged in this way closer to the electrical insulation of the heating element, so that they can deliver their current heat losses directly to the surrounding material of the elastomeric hollow body.

According to a further aspect of the invention, the metallic strand elements surround the non-metallic strand element as wire or rope. In this case, a wire is to be understood as meaning a single metallic strand element. A rope consists of several wires. In both cases, this ensures the arrangement of the metallic strand element around the central non-metallic strand element, because they are not arranged loosely but defined around the tension member.

According to a further aspect of the invention, a metallic strand element comprises a metallic alloy, preferably a copper alloy, a copper-nickel alloy and / or a nickel-chromium alloy. These materials or alloys have a good electrical conductivity at the same time sufficient electrical resistance to generate sufficient electrical heat losses that can be used to heat the environment. At the same time they are flexible, i. less rigid, so that they can be well winding and developing and straightening, which simplifies the production of an SCR hose and its connections. Furthermore, they can be plastically deformed, which also benefits the crimping. These materials or alloys are priced favorable. According to a further aspect of the invention, the electrically conductive heating conductor has a plurality of non-metallic strand elements. This will be the

Design freedom of the tension member increased, because here also different non-metallic strand element can be combined with each other, resulting in the material as well

Cross section geometries and cross sectional areas can differ. However, it is also possible to use a plurality of identical non-metallic strand elements. According to another aspect of the invention, the non-metallic strand elements are twisted together or intertwined. In this case, a twine is understood to mean a plurality of twisted-together strands, which thereby have a higher tensile strength than non-twisted single strands together. Under a network becomes one

Strand assembly which is made by braiding, i. by regular interlacing of several strands of flexible material. In this case, a braid is more complicated to produce than a thread, but also more durable and robust.

According to a further aspect of the invention, a non-metallic strand element is a yarn, preferably a monofilament. A yarn is understood to mean a linear textile structure. This can consist of one or more fibers. To use a textile yarn as a non-metallic Litzenelement is advantageous because this high tensile strength and flexibility with low weight and low cost can be realized.

Preferably, the yarn is a monofilament or monofilament. Monofilament yarns can be spun from single-hole dies by extrusion melt spinning and undergo parallel alignment of the molecular chains through downstream, usually multi-stage drawing. The stretching process produces longitudinal mechanical properties (such as strength and modulus) that are well above the values of the undrawn base polymers. Monofilaments can be produced from almost all thermoplastics, in particular from polyester (PES), polyethylene (PE), polypropylene (PP), polyamide (PA), polyvinyl chloride (PVC),

Polyvinylidene chloride (PVDC), polyphenylene sulfide (PPS), polyether ether ketone (PEEK), polyvinylidene fluoride (PVDF), polyoxymethylene (POM), resorbable polydiaxanone, polycapronlactone lactide, polyoxadiazole (POD), aramid (AR), polyimide (PI), polyethylene 2,6- naphthalate (PEN), polyphenylene (PPP), polyphenylene oxide (PPO), polyphenylene ether (PPE), polybenzoxazole (PBO), carbon fibers (CF) and / or metal fibers (MF). According to a further aspect of the invention, a non-metallic strand element is a textile high-strength fiber, preferably an LCP (liquid crystal polymer; Liquid crystal polymer). Due to its high strength, such a fiber is particularly suitable for tensile strength for the present application.

According to another aspect of the invention, the textile high-strength fiber comprises an aromatic polyamide or an aromatic polyester. These materials have the high strengths required for the loads of the present application.

It is advantageous for aromatic polyamides (aramids) that these fibers are characterized by very high strength, high impact strength, high elongation at break, good vibration damping and resistance to acids and alkalis. They are also very heat and fire resistant. As aromatic polyamides, preferably para-aramides, which are available, for example, under the trade names Twaron® or Kevlar®, as well as para-aramid copolymer, which are known under the trade name Technora®, can be used. However, it is also conceivable that meta-aramides, such as, for example, the fibers available under the trade name Nomex®, are used. Likewise, hybrid fibers of m-aramid and p-aramid are possible.

As aromatic polyesters may preferably polyester polyarylates, which

for example, under the trade names Vectran®, or POD

(Polyoxadiazole) can be used.

In particular, polyester polyarylate is better suited for this application than the aromatic polyamides, since due to the very low water content of the fiber (about 0.5%) predrying of the fiber during the extrusion process of the plastic coating can be dispensed with. At higher water contents without predrying, this can due to the evaporation of water in the extrusion process to defects or voids in the

Plastic coating of the heat conductor lead. Exemplary embodiments and further advantages of the invention are described below

Explained in connection with the following figures. It shows:

Fig. 1 is a perspective schematic view of a heatable elastomeric

Hollow body in the form of a heatable tube according to the present invention

Invention;

Fig. 2a is a schematic sectional view of a heat conductor according to a first

Embodiment of the present invention;

2b is a schematic sectional view of a heat conductor according to a second

Embodiment of the present invention;

Fig. 3 is a perspective schematic view of the heat conductor according to the second

Embodiment of the present invention; and

Fig. 4 is a sectional view through a crimping of a heat conductor according to the

present invention.

1 shows a perspective schematic representation of a heatable elastomeric hollow body 1 in the form of a heatable hose 1 according to the present invention. The tube 1 has an inner layer 7, within which the medium can be transported. On the inner layer 7, a reinforcing layer 2 is provided, which reinforces the hose 1 as a whole and can transmit tensile forces. To the

Reinforcing layer 2, a heating conductor 3 is wound, which can be electrically heated. The heating conductor 3 is surrounded by an elastomeric outer layer 4.

The heating conductor 3 has a strand 5, which of an electrically insulating

Sheath 6 is surrounded. The strand 5 has a plurality of metallic strand elements 5a in the form of copper strands 5a or copper wires 5a and in a first

Embodiment, a non-metallic braid member 5b in the form of a high-strength textile Monofilamentgams 5b, see. Fig. 2a. In a second embodiment, the non-metallic strand element 5b is a twist on three high-strength textile yarns 5b, cf. Fig. 2b and 3. In both cases, the non-metallic Litzenelement 5b serves the

Transmission of the tensile forces of the heat conductor 3 and the copper strands 5a of the delivery of their electrical current heat losses to the surrounding layers 7, 2, 4 of the tube 1 and to its medium to be transported.

Fig. 4 shows a sectional view through a crimping of a heat conductor 3 according to the present invention. Here it can be seen that by crimping a

Connection element 8 with the exposed strand elements 5a, 5b of the heating element 3 a filled with material and seamless connection between the inside of the

Connecting element 8, the copper strands 5a and the monofilament yarn 5b or the twisted high-strength textile yarns 5b is formed. This is achieved by the plastic deformability of both the copper strands 5a and the yarns 5b.

LIST OF REFERENCE NUMBERS

(Part of the description)

1 Heated elastomeric hollow body, heatable hose 2 reinforcing layer, strengthening layer of the hollow body. 1

3 electrically conductive heating conductor

4 elastomeric outer layer of the hollow body. 1

5 strand of the heating conductor 3

5a metallic strand element, copper strand, copper wire

5b non-metallic strand element, textile high-strength fiber

6 sheathing of the heating conductor 3

7 inner layer of the hollow body. 1

8 connection element, crimp connection of the heating conductor 3

Claims

claims

1. Heated elastomeric hollow body (1), in particular heatable hose (1), for conducting and / or receiving liquid, gaseous and / or pasty media, with an electrically conductive heating conductor (3),

characterized in that

the electrically conductive heating conductor (3) has at least one metallic strand element (5a) and at least one non-metallic strand element (5b).

2. Heated elastomeric hollow body (1) according to claim 1,

wherein the electrically conductive heating conductor (3) comprises a plurality of metallic ones

Litz elements (5a).

3. Heatable elastomeric hollow body (1) according to claim 2,

wherein the metallic strand elements (5a) surround the non-metallic strand element (5b).

4. Heatable elastomeric hollow body (1) according to claim 3,

wherein the metallic strand elements (5a) surround the non-metallic strand element (5b) as wire or rope.

5. Heated elastomeric hollow body (1) according to one of the preceding claims, wherein a metallic strand element (5a) comprises a metallic alloy, preferably a copper alloy, a copper-nickel alloy and / or a nickel-chromium alloy.

6. Heatable elastomeric hollow body (1) according to one of the preceding claims, wherein the electrically conductive heating conductor (3) comprises a plurality of non-metallic Litzenelementen (5b).

7. Heated elastomeric hollow body (1) according to claim 6, wherein the non-metallic strand elements (5b) are twisted or intertwined with each other.

8. Heatable elastomeric hollow body (1) according to one of the preceding claims, wherein a non-metallic strand element (5b) is a yarn, preferably a monofilament.

9. A heatable elastomeric hollow body (1) according to one of the preceding claims, wherein a non-metallic strand element (5b) is a textile high-strength fiber (5b), preferably an LCP fiber (5b).

10. Heated elastomeric hollow body (1) according to claim 9,

wherein the high strength textile fiber (5b) comprises an aromatic polyamide or an aromatic polyester.