WO2015070512A1 - Réacteur de traitement d'eaux usées d-a2/o ayant deux séries d'opérations alternées anaérobie/anoxique - Google Patents

Réacteur de traitement d'eaux usées d-a2/o ayant deux séries d'opérations alternées anaérobie/anoxique Download PDF

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Publication number
WO2015070512A1
WO2015070512A1 PCT/CN2014/000764 CN2014000764W WO2015070512A1 WO 2015070512 A1 WO2015070512 A1 WO 2015070512A1 CN 2014000764 W CN2014000764 W CN 2014000764W WO 2015070512 A1 WO2015070512 A1 WO 2015070512A1
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WO
WIPO (PCT)
Prior art keywords
tank
anoxic
anaerobic
aerobic
acidification
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PCT/CN2014/000764
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English (en)
Chinese (zh)
Inventor
叶长兵
韩相奎
周志明
Original Assignee
玉溪师范学院
叶长兵
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Application filed by 玉溪师范学院, 叶长兵 filed Critical 玉溪师范学院
Publication of WO2015070512A1 publication Critical patent/WO2015070512A1/fr

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/286Anaerobic digestion processes including two or more steps
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2806Anaerobic processes using solid supports for microorganisms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • C02F3/305Nitrification and denitrification treatment characterised by the denitrification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/308Biological phosphorus removal

Definitions

  • the invention patent relates to a sewage treatment reactor.
  • ⁇ 2 /0 and SBR are common processes with high denitrification and dephosphorization.
  • SBR has limited the development of this process due to its high automation and intermittent effluent issues.
  • the traditional ⁇ 2 /0 process for nitrogen and phosphorus removal is not complicated.
  • the anaerobic, anoxic and aerobic three-stage process formed by the improvement of traditional activated sludge can not only effectively remove organic matter, but also simultaneously remove nitrogen. phosphorus.
  • the existing ⁇ 2 /0 also has the problem that the efficiency of nitrogen and phosphorus removal is difficult to be further significantly improved. There are two reasons for this: (1) the existence of carbon source competition for denitrification and phosphorus removal; (2) the presence of microbial phosphorus release and The problem of low phosphorus absorption capacity.
  • the specific analysis is as follows:
  • the existing ⁇ 2 /0 process nitrogen and phosphorus removal is closely related to the reflux ratio. Too low reflux ratio is difficult to have the ideal nitrogen and phosphorus removal efficiency, but too high reflux ratio is also due to the high concentration of DO in the oxygen-deficient (defective) oxygen section, which is difficult to have high denitrification effect and phosphorus release capacity. Therefore, the existing A 2 /0 process controls the reflux ratio of the sludge and mud-water mixture to a lower value, and the ability to release rock and absorb phosphorus is small.
  • the DA 2 /0 reactor has the following characteristics:
  • the present invention integrates a hydrolysis acidification tank before A 2 /0.
  • Most of the poorly soluble organic matter and macromolecular organic matter in the wastewater during hydrolysis and acidification can be degraded into soluble organic matter and small molecular organic matter under hydrolysis and acidification, which can effectively avoid the problem of insufficient A 2 /0 carbon source. This is another key factor for efficient nitrogen and phosphorus removal in the DA 2 /0 reactor.
  • the DA 2 /0 reactor integrates the principles of the A 2 /0 process and the SBR process. Overall, the DA 2 /0 reactor has a significant A 2 /0 sludge reflux system and nitrification reflux characteristics; from a local perspective, the DA 2 /0 anaerobic, anoxic tank replacement operation has a similar SBR Process influent period, reaction period, sedimentation period and drainage sludge discharge stage. This is a possible factor for efficient nitrogen and phosphorus removal in the DA 2 /0 reactor, which needs further investigation.
  • test results of more than 12 months show that the DA 2 /0 reactor is stable and has a high sewage treatment effect, and its COD, nitrogen and phosphorus removal efficiency is much higher than the existing A 2 /0 and SBR processes. .
  • the DA 2 /0 reactor of the invention has the technical advantages of high efficiency of nitrogen and phosphorus removal, stable effluent quality and minimal residual sludge yield, which cannot be replaced by other sewage treatment technologies in a short period of time, which will also make The promotion and application of this technology has long-term market guarantee.
  • the DA 2 /0 reactor study has not been reported yet, and it is the first.
  • the purpose of the present invention is to provide a two-stage anaerobic anoxic replacement operation of a DA 20 sewage treatment reactor, which is characterized by comprising a water tank (1), an acidification tank (2), an anaerobic tank (4), and anoxic acid.
  • the domestic sewage in the water tank (1) passes through the acidification tank (2) in turn, which is tired.
  • the oxygen pool (4), the anoxic tank (5), the aerobic tank (7) and the secondary settling tank (9) receive purified water from the water outlet (15), and the sludge is discharged from the sludge of the secondary settling tank (9). Mouth (14) is excluded.
  • the acidification tank (2) has a suspended membrane packing (3), and the anaerobic tank (4) and the anoxic tank (5) each have a stirrer (6), and the aerobic tank (7) has an aeration Head (8).
  • the aerobic tank (7) has a vacuum pump (12).
  • the acidification tank (2), the anaerobic tank (4), the anoxic tank (5) and the aerobic tank (7) each have a sludge discharge port (10).
  • the acidification tank (2), the anaerobic tank (4), and the anoxic tank (5) each have two series.
  • the process principle is as follows: the influent water is passed through a constant flow pump to a hydrolysis acidification tank provided with an elastic three-dimensional filler, and the hydrolysis acidified bacteria degrades the macromolecular organic matter and the poorly soluble organic matter in the sewage into small molecular organic substances and easily degradable organic substances; and then flows to the phase A phase.
  • the nitrification liquid and the sludge refluxed in the aerobic tank and the sedimentation tank are stirred in the mixer to make the activated sludge microorganisms sufficiently contact with the pollutant matrix in the sewage to cause organic matter degradation, denitrification and release.
  • the acidification tank (2), the anaerobic tank (4), the anoxic tank (5) and both have two series, and when one of the phases is in operation, the other phase is in a resting state. The next time you change the operating state, the opposite is true. Throughout the test process, the two series of successively replaced the operation to achieve the purification of sewage.
  • the DA 20 described in this patent represents two series of anaerobic anoxic replacement operating A70.
  • the structure of DA 2 /0 is characterized by the design of two independent series of sludge return systems and nitrifying liquid reflux systems.
  • the two series of alternate operation modes have largely solved the belt from the nitrifying liquid.
  • the DO in the anoxic tank affects the effect of denitrification and denitrification, thereby ensuring efficient denitrification in the system.
  • the reflux ratio R of the larger flow rate is a key factor. The result will inevitably ensure that one of the phases of the system is normally influent and maintains phosphorus and nitrogen removal. At the same time, the phase in the resting phase undergoes excessive phosphorus release and sufficient denitrification due to excessive hypoxia.
  • the present invention integrates a hydrolysis acidification tank before A 2 /0.
  • Most of the poorly soluble organic matter and macromolecular organic matter in the wastewater during hydrolysis and acidification can be degraded into soluble organic matter and small molecular organic matter under hydrolysis and acidification, which can effectively avoid the problem of insufficient A 2 /0 carbon source. This is a key factor for efficient nitrogen and phosphorus removal in the DA 2 /0 reactor.
  • Figure 1 is a schematic view of a reaction apparatus system of the present invention
  • Figure 2 is a process flow diagram of the present invention.
  • a two-stage anaerobic anoxic replacement operation of a DA 20 sewage treatment reactor characterized by comprising a water tank (1), an acidification tank (2), an anaerobic tank (4), an anoxic tank (5), an aerobic
  • the pool (7) and the secondary settling tank (9) the domestic sewage in the water tank (1) is sequentially passed through the acidification tank (2), the anaerobic tank (4), the anoxic tank (5), the aerobic tank ( 7) and the secondary settling tank (9) obtain purified water from the water outlet (15), and the sludge is excluded from the sludge discharge port (14) of the secondary settling tank (9).
  • the acidification tank (2) has a suspended membrane packing (3), an anaerobic tank (4) and an anoxic tank (5) There is a stirrer (6) having an aeration head (8) therein.
  • the aerobic tank (7) has a vacuum pump (12).
  • the acidification tank (2), the anaerobic tank (4), the anoxic tank (5) and the aerobic tank (7) have a drain port (10) on the same side.
  • the acidification tank (2), the anaerobic tank (4), the anoxic tank (5) and the secondary settling tank (A in Fig. 2 is a phase, and B is a phase).
  • the operation of sewage in the reactor is as follows: after the hydrolysis and acidification of the sewage in the hydrolysis acidification tank, the sewage will enter the anaerobic cell compartment with the return sludge from the secondary sedimentation tank, and the outflow sewage will enter the hypoxia with the mixture from the aerobic tank. After the biochemical reaction is fully mixed by anaerobic/anoxic pool agitation, the muddy water mixture flows to the aerobic tank; a part of the mixture in the aerobic tank is returned to the anoxic tank, and the other part is discharged from the overflow to the second sink.
  • the mud water is separated in the pool, the supernatant is discharged from the effluent, and the sludge is partially returned to the anaerobic tank, and the excess sludge is discharged outside the system.
  • the unified phase is operating in the above operating state, the other phase is in a rest state.
  • the two series of replacement operations realized the treatment of pollutants and the purification of sewage.
  • the wastewater treatment capacity of the DA 20 reactor is increased by about 10%
  • the COD removal rate is increased by about 5%
  • the TN removal rate is increased by about 10%
  • the ammonia nitrogen removal rate is improved.
  • the TP removal rate is increased by about 15%. From the experimental analysis results, the dephosphorization and dephosphorization and COD removal efficiency of the DA 2 0 reactor is very significant.
  • an ecological tank culture ornamental goldfish was set up at the outlet end of the reactor, and the survival rate of the goldfish was observed to further verify whether the water quality was stable. The 2-month observations show that the survival rate of ornamental goldfish is over 90%.

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

La présente invention concerne un réacteur de traitement d'eaux usées D-A2/O ayant deux séries d'opérations alternées anaérobie/anoxique. Le réacteur de traitement d'eaux usées D-A2/O est caractérisé par le fait qu'il comprend un réservoir d'eau (1), un réservoir d'acidification (2), un réservoir anaérobie (4), un réservoir anoxique (5), un réservoir aérobie (7) et un réservoir de sédimentation secondaire (9). Le réacteur D-A2/O de la présente invention a les avantages techniques d'un effet puissant d'élimination d'azote et de phosphore, une qualité d'effluent stable, un faible rendement de boue en excès et analogue.
PCT/CN2014/000764 2013-11-15 2014-08-13 Réacteur de traitement d'eaux usées d-a2/o ayant deux séries d'opérations alternées anaérobie/anoxique WO2015070512A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201310566833.X 2013-11-15
CN201310566833.XA CN103601296B (zh) 2013-11-15 2013-11-15 一种两相厌氧缺氧交替运行的d-a2/o污水处理反应器

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WO2015070512A1 true WO2015070512A1 (fr) 2015-05-21

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
CN110759592A (zh) * 2019-11-05 2020-02-07 天津中冀源环保科技有限公司 一种无外加碳源的水解酸化+a2/o2的污水处理方法
CN111217447A (zh) * 2019-11-29 2020-06-02 段林卓 一种高寒地区室外冲水厕所污水处理工艺及装置

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CN103601296B (zh) * 2013-11-15 2015-11-25 玉溪师范学院 一种两相厌氧缺氧交替运行的d-a2/o污水处理反应器
CN103833142B (zh) * 2014-03-11 2015-09-09 玉溪师范学院 一种阿科蔓生态沟渠污水处理装置
CN104761054A (zh) * 2015-03-19 2015-07-08 叶长兵 一种ao污水处理工艺的改造提标方法
CN105254014A (zh) * 2015-11-20 2016-01-20 江苏合一水业有限公司 多功能污水处理池
CN105502824A (zh) * 2015-12-25 2016-04-20 中铁城市规划设计研究院有限公司 集约化一体化小型污水处理站

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CN111217447A (zh) * 2019-11-29 2020-06-02 段林卓 一种高寒地区室外冲水厕所污水处理工艺及装置
CN111217447B (zh) * 2019-11-29 2022-06-03 段林卓 一种高寒地区室外冲水厕所污水处理工艺及装置

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