WO2015045499A1 - Process for producing nonwoven fabric, and nonwoven fabric - Google Patents
Process for producing nonwoven fabric, and nonwoven fabric Download PDFInfo
- Publication number
- WO2015045499A1 WO2015045499A1 PCT/JP2014/065494 JP2014065494W WO2015045499A1 WO 2015045499 A1 WO2015045499 A1 WO 2015045499A1 JP 2014065494 W JP2014065494 W JP 2014065494W WO 2015045499 A1 WO2015045499 A1 WO 2015045499A1
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- WIPO (PCT)
- Prior art keywords
- nonwoven fabric
- protrusion
- fabric according
- surface side
- fiber
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/60—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in dry state, e.g. thermo-activatable agents in solid or molten state, and heat being applied subsequently
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15577—Apparatus or processes for manufacturing
- A61F13/15707—Mechanical treatment, e.g. notching, twisting, compressing, shaping
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/51104—Topsheet, i.e. the permeable cover or layer facing the skin the top sheet having a three-dimensional cross-section, e.g. corrugations, embossments, recesses or projections
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15577—Apparatus or processes for manufacturing
- A61F13/15707—Mechanical treatment, e.g. notching, twisting, compressing, shaping
- A61F2013/15715—Shaping or making outer layers
Definitions
- the present invention relates to a nonwoven fabric manufacturing method and a nonwoven fabric.
- excretory fluid is permeated in the thickness direction from the top sheet and held by the absorbent body.
- the top sheet is likely to be in close contact with the skin while directly receiving excretory fluid. Since measures against skin troubles such as rough skin are indispensable in such a close contact state, various proposals have been made on the surface sheet from the viewpoint of a good wearing feeling.
- Patent Document 1 describes a product in which a surface sheet has double-sided irregularities and a hydrophobic skin care agent is adhered to both sides of a protruding portion in contact with the skin in order to enhance the skin care effect on the skin.
- Patent Document 2 describes a fiber sheet having an uneven structure. A fiber sheet has a fiber inside a convex part. Moreover, the top part is hydrophobic. Further, the portion other than the top has a lower hydrophobicity than the top.
- the present invention has a concavo-convex shape, conveys a web containing thermoplastic fibers to a heated support, and blows hot air from above the web toward the support to shape the concavo-convex shape on the web.
- a method for producing a nonwoven fabric the step of heating the support to a temperature range of not less than the glass transition point of the fibers constituting the web and not more than the melting point, and the fibers of the web by the first hot air blowing
- the step of temporarily fusing the concavo-convex shape and the second hot air having a temperature higher than that of the first hot air is blown, and the fibers of the web are fused together while the concavo-convex shape is maintained.
- corrugated shape is provided.
- the present invention has a first projecting portion projecting on the first surface side of the nonwoven fabric sheet in plan view and having an inner space, and projecting on the second surface side opposite to the first projecting portion and having an inner space. And a plurality of the first protrusions and the second protrusions that are alternately and continuously arranged through the wall portions in different directions intersecting the planar view of the nonwoven fabric.
- the first protrusions and the adjacent second protrusions are nonwoven fabrics that are continuously connected in an oblique direction in plan view with respect to each of the different directions via a ridge portion, and the nonwoven fabrics.
- the height in the thickness direction of the first protrusion is higher than the height in the thickness direction of the ridge, and the rising angle of the wall of the first protrusion is 0 ° or more.
- a non-woven fabric that is 20 ° or less is provided.
- the present invention has a high cushioning property when a nonwoven fabric is used as a top sheet of an absorbent article, and reduces the amount of liquid return in a large amount of excretion under high load and prevents leakage due to liquid flow on the surface.
- the present invention relates to a method for producing a compatible nonwoven fabric and a nonwoven fabric.
- the nonwoven fabric 10 of the present invention is preferably applied to a top sheet of absorbent articles such as sanitary napkins, disposable diapers, and incontinence pads.
- the nonwoven fabric 10 is preferably used with the first surface side Z1 facing the wearer's skin surface side.
- the nonwoven fabric 10 uses the 2nd surface side Z2 arrange
- the first surface side Z1 of the nonwoven fabric 10 shown in the drawings is used toward the skin surface of the wearer will be described.
- the present invention is not construed as being limited thereby.
- the upper side of the nonwoven fabric 10 is defined as the first surface side Z1 and the lower side of the nonwoven fabric 10 is defined as the second surface side Z2 in the z-axis of the orthogonal coordinate system.
- the nonwoven fabric 10 of the present invention has a continuous uneven curved surface, and forms a seamless sheet surface. That is, it protrudes to the 1st surface side Z1 on the side which planarly viewed the nonwoven fabric of the sheet body, and protrudes to the 2nd surface side Z2 on the opposite side to the 1st surface part Z1 and the 1st surface side Z1.
- a second protrusion 12 having an internal space 12K.
- the first protrusion 11 and the second protrusion 12 are different directions that intersect in plan view over the entire surface of the nonwoven fabric 10 in the first direction X and the second direction Y, respectively, in a plane parallel to the xy plane of the orthogonal coordinate system.
- the first direction X and the second direction Y are orthogonal. Accordingly, the first direction X can be a direction parallel to the x-axis of the orthogonal coordinate system, and the second direction Y can be a direction parallel to the y-axis of the orthogonal coordinate system. Note that the first direction X and the second direction Y do not have to be orthogonal. For example, it is preferable that the first direction X and the second direction Y intersect within a range of about 60 ° to 120 °.
- the convex portion viewed from the first surface side Z ⁇ b> 1 is the first projecting portion 11, and the concave portion is the second projecting portion 12. Further, the convex portion viewed from the second surface side Z ⁇ b> 2 is the second projecting portion 12, and the concave portion is the first projecting portion 11. Therefore, the first protrusion 11 and the second protrusion 12 are partially shared.
- the 1st protrusion part 11 is the part protruded to the 1st surface side Z1 of the nonwoven fabric 10 of the 1st surface side Z1 which covers the internal space 11K and this.
- the part which protruded to the 1st surface side Z1 of the nonwoven fabric 10 is a part which connected from the 1st protrusion part top part 11T to the bottom part of the surrounding internal space 12K through the wall part 13 (14).
- the 2nd protrusion part 12 containing the internal space 12K is a part which protruded to the 2nd surface side Z2 of the nonwoven fabric 10 of the 2nd surface side Z2 which covers the internal space 12K and this.
- the portion recessed in the second surface side Z2 of the nonwoven fabric 10 is a portion connecting the bottom portion of the internal space 12K to the surrounding first protruding portion top portion 11T through the wall portion 13 (14).
- the first protrusion 11 and the second protrusion 12 are shared between the first protrusion 11T and the bottom of the internal space 12K.
- the wall portion 13 (14) partitions the two internal spaces 11K and the internal space 12K.
- the height of the thickness direction of the nonwoven fabric 10 is divided into 3 equal parts, the upper part is the 1st protrusion part 11, and the intermediate part is a wall.
- the part 13 (14) and the lower part are defined as the second projecting part 12.
- the ridge portion 15 is a portion connecting the highest positions in the first surface side Z1 direction in which the adjacent first projecting portions 11 are continuous. Furthermore, when it sees with the 1st protrusion part 11 and the ridge part 15, the lower part which equally divided the 1st protrusion part top part 11T and the lowest position of the ridge part 15 into the 1st surface side Z1 direction is made into the ridge part 15. .
- the adjacent first protrusions 11 are continuously connected in an oblique direction with respect to the first direction X and the second direction Y via the ridge 15.
- the first projecting portion 11 is connected to the first direction X and the second direction Y in an oblique direction like a mountain range via the ridge portion 15.
- the oblique direction is, for example, a 45 ° oblique direction with respect to each direction.
- the adjacent second projecting portions 12 are continuous in the oblique direction with respect to the first direction X and the second direction Y through the ridge portion 15 as viewed from the second surface side Z2, similarly to the first projecting portion 11. Are connected.
- the height h1 in the thickness direction of the first protruding portion 11 is higher than the height h5 in the thickness direction of the ridge portion 15 (see also FIG. 3).
- Each of the heights h1 and h5 represents a height in a direction perpendicular to the plane S including the apex of the second protrusion top 12.
- the height h1 represents the height of the first surface side Z1 of the first protrusion top 11T.
- the height h ⁇ b> 5 represents the height of the first surface side Z ⁇ b> 1 of the lowest portion of the ridge portion 15 between the first protrusions 11.
- the liquid is poured into the internal space 12K of the second protruding portion 12 that is surrounded on all sides by the first protruding portion 11. Accumulated, the liquid flows over the ridge 15 in the direction of the internal space 12K of the adjacent second protrusion 12. In this case, the liquid also flows below the ridge 15. However, no liquid leaks to the first surface side Z1.
- the 1st surface side Z1 shows a wearer's skin surface side
- the 2nd surface side Z2 shows a non-skin surface side.
- the hydrophilicity of the 1st protrusion part top part 11T is lower than the part except the 1st protrusion part top part 11T in both surfaces of the 1st surface side Z1 and the 2nd surface side Z2.
- the 1st protrusion part top part 11T has hydrophobicity. That is, the hydrophilicity of the first protruding portion top portion 11T is lower than that of the second protruding portion top portion 12T and the wall portion 13. In other words, the first protrusion top 11T is more hydrophobic than the second protrusion top 12T and the wall 13 (14).
- the nonwoven fabric 10 when used as a surface sheet, the remaining amount of the liquid that touches the skin is reduced on the first surface side Z1 that is the skin contact surface side.
- the first surface side Z1 has a smaller hydrophobic area than the second surface side Z2 of the first protrusion top portion 11T. This makes it difficult for the overflowing liquid from the absorber (not shown) to return to the first surface side Z1 under high pressure such that the wearer is sleeping. Therefore, the liquid which returns to the 1st surface side Z1 used as the skin surface side is suppressed and reduces.
- the level of hydrophilicity and the level of hydrophobicity are determined by measuring the contact angle described later. The smaller the contact angle value described later, the higher the hydrophilicity.
- the nonwoven fabric 10 has an effect of this invention fundamentally. That is, the nonwoven fabric 10 can have a high cushioning property, can maintain an uneven shape even under a high load, and further suppress the increase in the contact area with the skin and suppress the adhesion of discharged liquid to the skin. Can do. As described above, it is more preferable that the first projecting portion top portion 11T is hydrophobized because adhesion of the discharged liquid to the skin can be further suppressed.
- the fibers 16 constituting the wall portion 13 have fiber orientation in the direction indicated by the arrow A connecting the first protruding portion top portion 11T and the edge portion of the opening portion 11H of the internal space 11K. In other words, it has fiber orientation in the direction in which the wall portion 13 stands. Therefore, it has the radial fiber orientation which goes to the 1st protrusion part top part 11T.
- the direction which ties the 1st protrusion part top part 11T and the edge part of the opening part 11H of the internal space 11K, and the direction where the wall part 13 stands up substantially correspond with the thickness direction in a nonwoven fabric.
- the fiber 16 which comprises the wall part 14 (13) of the 2nd protrusion part 12 is the arrow A which connects the edge part of the opening part 12H of the 2nd protrusion part top part 12T and its internal space 12K. It has fiber orientation in the direction indicated by.
- the fiber orientation of the wall portion 14 is the same as the fiber orientation of the wall portion 13 in the common portion with the wall portion 13 described above. Note that the direction connecting the second projecting portion top 12T and the edge of the opening 12H of the internal space 12K and the direction in which the wall 13 rises substantially coincide with the thickness direction of the nonwoven fabric.
- the wall 13 of the first protrusion 11 has fiber orientation in the direction connecting the top 11T of the first protrusion 11 and the opening 11H of the internal space 11K of the first protrusion 11. From this, the 1st protrusion part 11 and the 2nd protrusion part 12 are hard to be crushed even under the high pressurization where a wearer is sleeping. In addition, this configuration provides excellent shape retention, high air permeability, and solves the problem of stuffiness. Furthermore, a firm stiffness is born in the wall portion 13 by the above configuration. For this reason, it also has moderate cushioning properties in which the fibers are not crushed in the thickness direction.
- the shape restoring force is large, and the initial cushioning force is easily maintained even if the packing state and wearing are continued. That is, the shape retention of the nonwoven fabric 10 is excellent even with the seating pressure of the wearer.
- the contact area between the nonwoven fabric 10 and the skin is kept small even at high pressure. For this reason, the first and second protrusions are not easily crushed and can be easily recovered even if deformation occurs.
- the fibers oriented in the thickness direction of the wall portion 13 the liquid flows along the fibers smoothly. And a liquid transfers to the absorber (not shown) distribute
- the return of liquid is reduced by the fiber orientation of the wall portion 13, a smooth touch is realized. Moreover, it is useful for prevention of a blurring by being excellent in the air permeability of nonwoven fabric 10 itself by maintenance of the structure mentioned above.
- the height h1 in the thickness direction of the first protrusion 11 is higher than the height h5 of the ridge 15.
- the flow of the liquid on the first surface side Z1 of the nonwoven fabric 10 is oblique to the first direction X parallel to the x direction of the orthogonal coordinate system and the second direction Y parallel to the y direction of the orthogonal coordinate system.
- the liquid begins to flow. That is, when the nonwoven fabric 10 is used as the top sheet of the absorbent article and the first direction X is used as the width direction of the absorbent article, the liquid flows in an oblique direction with respect to the width direction of the absorbent article.
- the ratio (h1 / h5) between the height h1 of the first protrusion 11 in the thickness direction and the height h5 of the ridge 15 when the nonwoven fabric 10 is pressurized at a pressure of 3.5 kPa is a side leakage. From the viewpoint of difficulty, it is preferably 1.01 or more, more preferably 1.05 or more, and further preferably 1.2 or more.
- the nonwoven fabric 10 is measured by pressurizing at a pressure of 3.5 kPa is that it simulates the pressure applied to the nonwoven fabric when the wearer is seated. That is, the seating pressure is assumed to be 3.5 kPa.
- a wearer is a wearer of the baby diaper which is the main focus in this specification, that is, an infant.
- the pressure concerning a nonwoven fabric when a wearer is standing is measured as follows in the meaning which contrasts with the pressure concerning a nonwoven fabric when the wearer is sitting.
- the load applied to the nonwoven fabric is basically assumed to be no load.
- the measurement values vary due to the characteristics of the nonwoven fabric, which is an aggregate of fibers. For this reason, measurement is carried out by imitating measurement with substantially no pressure while suppressing variations in measured values, that is, with a load of about 0.05 kPa as a state close to no pressure.
- the first protrusion 11 has a height h1 (see FIG. 3), and the rising angle of the wall is steeper and the top is round like a part of the hemisphere, rather than a cone having a round top like a hemisphere. It is more preferable that the truncated cone has.
- the rising angle ⁇ of the wall portion 13 of the first projecting portion 11 is not less than 0 ° and not more than 20 °, preferably greater than 0 ° and not more than 20 °, more preferably not less than 0 ° and not more than 15 °. Is more preferable, and it is further more preferable that it is larger than 0 degree and 12 degrees or less.
- the rising angle ⁇ is obtained by a measurement method described later.
- the nonwoven fabric tends to collapse in the thickness direction. For this reason, the cushioning effect of a nonwoven fabric falls and the amount of liquid return increases. Furthermore, since the skin contact area at the time of high pressurization becomes large, it becomes difficult to give a wearer a gentle touch to the skin.
- the first projecting portion 11 and the second projecting portion 12 have a truncated cone shape or a hemisphere with rounded top portions 11T and 12T.
- the protrusion shape of the 1st protrusion part 11 is a shape close
- the projecting shape of the second projecting portion 12 is a cone or truncated cone shape with a rounded top.
- the 1st, 2nd protrusion parts 11 and 12 are not limited to the said shape. Therefore, any protruding form may be used. For example, it is practical to have various cone shapes.
- the term “conical shape” means that a cone, a truncated cone, a pyramid, a truncated pyramid, an oblique cone, and the like are included.
- the 1st protrusion part 11 is holding
- a wall 13 is provided between the top of the first protrusion 11 (hereinafter also referred to as the first protrusion 11) 11T and the opening 11H.
- the wall portion 13 forms an annular structure in the first projecting portion 11.
- it has the wall part 14 between the top part (henceforth the 2nd protrusion part top part) 12T of the 2nd protrusion part 12, and its opening part 12H.
- the wall portion 14 forms an annular structure in the second projecting portion 12.
- the wall portion 14 is shared with the wall portion 13 in part.
- the “annular” here is not particularly limited as long as it has an endless series of shapes in plan view.
- the “annular” may be any shape such as a circle, an ellipse, a rectangle, or a polygon in plan view.
- the “annular” is preferably a circle or an ellipse.
- annular is a three-dimensional shape: cylinder, oblique cylinder, elliptical cylinder, truncated cone (truncated cone), oblique truncated cone (truncated truncated cone), oblique elliptical truncated cone (truncated elliptical cone), four Arbitrary ring structures composed of side surfaces such as a truncated pyramid (truncated quadrangular pyramid) and an oblique quadrangular pyramid (truncated oblique pyramid) can be mentioned.
- a cylinder, an elliptic cylinder, a truncated cone, and an elliptic truncated cone are preferable.
- the nonwoven fabric 10 having the first and second projecting portions 11 and 12 arranged as described above does not have a bent portion. That is, the nonwoven fabric 10 is formed of a curved surface that is continuous throughout.
- the said bending part means the part which a surface bends and has a corner
- the said nonwoven fabric 10 has a structure continuous in the surface direction. This “continuous” means that there are no intermittent portions or small holes. However, fine holes such as gaps between fibers are not included in the small holes.
- the small hole can be defined, for example, as a hole having a diameter equivalent to a circle of 1.0 mm or more.
- the fiber material that can be used for the nonwoven fabric 10 of the present invention is not particularly limited.
- the fiber material include the following fibers.
- a fiber made of a thermoplastic resin such as a polyolefin resin such as polyethylene (PE) or polypropylene (PP), a polyester resin such as polyethylene terephthalate (PET), or a polyamide-forming resin.
- a thermoplastic resin such as a polyolefin resin such as polyethylene (PE) or polypropylene (PP), a polyester resin such as polyethylene terephthalate (PET), or a polyamide-forming resin.
- Specific examples of the fiber material include composite fibers having a structure such as a core-sheath type and a side-by-side type. In the present invention, it is preferable to use a composite fiber as the fiber material.
- the composite fiber examples include a core-sheath fiber having a high melting point component as a core portion and a low melting point component as a sheath portion, and a side-by-side fiber in which a high melting point component and a low melting point component are arranged in parallel.
- Preferable examples thereof include fibers having a core-sheath structure in which the sheath component (low melting point component) is polyethylene or low melting point polypropylene.
- Representative examples of the core-sheath fiber include PET (core) and PE (sheath), PP (core) and PE (sheath), polylactic acid (core) and PE (sheath), PP (core) and low melting point PP.
- the constituent fibers preferably include polyolefin fibers such as polyethylene fibers and polypropylene fibers, polyethylene composite fibers, and polypropylene composite fibers.
- the composite composition of the polyethylene composite fiber is polyethylene terephthalate and polyethylene.
- the composite composition of the polypropylene composite fiber is preferably polyethylene terephthalate and low melting point polypropylene. More specifically, examples of the composite composition of the polypropylene composite fiber include PET (core) and PE (sheath), and PET (core) and low melting point PP (sheath).
- these fibers may be used alone to constitute a nonwoven fabric, or may be used as a mixed fiber in which two or more kinds are combined.
- the dimension specification in the nonwoven fabric 10 of this embodiment is demonstrated below.
- seat let the whole thickness when the nonwoven fabric 10 is seen from a side view be sheet thickness TS.
- the thickness of the local cross section of the sheet curved by the unevenness of the nonwoven fabric 10 is defined as a layer thickness TL.
- the sheet thickness TS may be appropriately adjusted depending on the application. When used as a top sheet for diapers, sanitary products, etc., 1 mm or more and 7 mm or less is preferable, and 1.5 mm or more and 5 mm or less is more preferable.
- the layer thickness TL may be different at each site in the sheet. Further, the layer thickness TL may be adjusted as appropriate depending on the application.
- the layer thickness TL1 of the first protrusion top 11T is preferably 0.1 mm or more and 3 mm or less, and more preferably 0.4 mm or more and 2 mm or less.
- the preferable range of the layer thickness is the same for the layer thickness TL2 of the second protrusion top 12T and the layer thickness TL3 of the wall 13.
- the relationship between the layer thicknesses TL1, TL2, and TL3 is preferably TL1>TL3> TL2.
- the distance Dy when the first protrusion top 11T and the second protrusion top 12T in the second direction Y are projected onto a plane is the same as the distance Dx in the first direction X. .
- the basic weight of the said nonwoven fabric 10 is not specifically limited.
- the average value of the entire sheet is preferably 15 g / m 2 or more and 50 g / m 2 or less, more preferably 20 g / m 2 or more and 40 g / m 2 or less.
- the nonwoven fabric 10 demonstrated by the said embodiment has the following effects.
- the nonwoven fabric 10 is a case where a large amount of liquid is excreted, and when the load is high, the liquid remaining amount and the liquid return amount are reduced. Therefore, the liquid flow on the surface can be suppressed so that the liquid does not leak. Thereby, both prevention of the liquid flow on a skin contact surface and prevention of the liquid return from the non-skin contact surface side can be aimed at.
- the said nonwoven fabric 10 is excellent in the excretion capture
- the nonwoven fabric 10 of this embodiment it has internal space 11K, 12K inside each of the 1st, 2nd protrusion parts 11 and 12 which protrude on both surfaces. Therefore, these can be captured and dealt with in various forms according to the physical properties of the excretory fluid and excrement.
- the 1st surface side Z1 of the nonwoven fabric 10 is demonstrated as a skin surface side. If the excretory liquid has a low viscosity and easily permeates, it passes through the top sheet of the nonwoven fabric 10 and is then captured in the internal space 11K.
- the portion that first hits the skin surface is the first protrusion top 11T, and the captured excretory fluid or excrement is made difficult to contact the skin. As a result, a very good and smooth feeling is maintained in response to excretion of urine, menstrual blood, and fallen goods.
- the support 110 having the configuration shown in FIG.
- the support 110 has a large number of protrusions 111 corresponding to positions where the second protrusions 12 are shaped.
- the hole 112 is arranged corresponding to the position where the 1st protrusion part 11 is shaped. That is, the support body 110 has an uneven shape.
- the protrusions 111 and the holes 112 are alternately arranged in different directions.
- the protrusions 111 and the holes 112 are alternately arranged in the first direction X and the second direction Y, respectively.
- the support body 110 is heated. As a method for heating the support 110, heat is transferred to the support 110 itself to heat it.
- this is a method of directly heating the support 110 with a heat source (not shown).
- a heat source for example, a heater provided with a heating wire may be provided on the back side of the support 110 on which the protrusions 111 are not provided.
- the support 110 may be warmed by blowing hot air before the web 50 is conveyed onto the support 110.
- any heating means may be used as long as the temperature of the support 110 is within an appropriate temperature range.
- the temperature which heats the support body 110 shall be temperature more than the glass transition point of the fiber which comprises a web, and below melting
- the shape along the support 110 is likely to be obtained. That is, it becomes easy to shape the web 50 along the shape of the support 110.
- the heating of the support 110 is too low, the difference between the height of the first protrusion 11 and the height of the ridge 15 is reduced. In this case, the rising angle of the wall portion does not become steep. If the first projecting portion top portion 11T is hydrophobized in this state, a large amount of liquid is excreted on the nonwoven fabric surface when a high load is applied to the nonwoven fabric 10 (a weight of about the seating pressure). And it becomes easy to raise
- the temperature of the supporting body 110 is preferably set to the above temperature range when the first hot air W1 described in the next step is blown.
- a web 50 (also referred to as a fiber web) obtained by hydrophilizing hydrophobic thermoplastic fibers with a hydrophilizing oil is used.
- a known method can be used for the hydrophilic treatment.
- the web 50 is disposed on the support 110, and the first hot air W1 is blown toward the web 50.
- the first protrusion 11 is shaped corresponding to the hole 112 of the support 110, and the second protrusion 12 is shaped corresponding to the position of the protrusion 111.
- the 1st protrusion part 11 protrudes in the 1st surface side Z1 of the side seen by plane, and has the internal space 11K.
- the 2nd protrusion part 12 protrudes in the 2nd surface side Z2, and has internal space 12K.
- the first protrusions 11 and the second protrusions 12 are alternately and continuously arranged in different first directions X and second directions Y that intersect in plan view. In this way, the web 50 is shaped.
- the first protrusion 11 has a steeper rising angle of the wall than a cone whose top is round like a hemisphere, The top is a truncated cone having a rounded shape like a part of a hemisphere.
- the rising angle ⁇ of the wall portion 13 of the first projecting portion 11 is preferably set as described above.
- the arrows in the drawing schematically show the flow of the first hot air W1.
- the web 50 before being fused is supplied from a card machine (not shown) to a device for shaping the web so as to have a predetermined thickness.
- a card machine not shown
- the shaping apparatus first, the web 50 is conveyed and fixed on the support 110 heated to the above temperature.
- the heating temperature of the support 110 is a temperature not lower than the glass transition point of the fiber to be shaped and not higher than the melting point, preferably higher than the glass transition point of the fiber and not higher than 10 ° C. below the melting point.
- the temperature is 20 ° C. higher than the glass transition point of the fiber and 20 ° C. lower than the melting point.
- the glass transition point of the high glass transition point component is not lower than the glass transition point of the high glass transition point component and not more than 10 ° C. lower than the melting point of the low melting point component.
- the temperature is 20 ° C. or higher and 20 ° C. or lower than the melting point of the low melting point component.
- fiber having a core / sheath structure of PET (core) having a glass transition point of 67 ° C. and a melting point of 258 ° C./PE (sheath) having a glass transition point of ⁇ 20 ° C. and a melting point of 135 ° C. is used as the fiber.
- the first hot air W1 is blown onto the web 50 on the support 110 (the state shown in FIG. 8A). Then, the web 50 is shaped so as to follow the shape of the support 110 (the state shown in FIG. 8B).
- the temperature of the first hot air W1 at this time is preferably 0 ° C. to 70 ° C. lower than the melting point of the thermoplastic fiber constituting the web 50 in consideration of a general fiber material used for this type of product. More preferably, the temperature is 5 to 50 ° C lower.
- the wind speed of the first hot air W1 is set to 20 m / s or more and 150 m / s or less, preferably 30 m / s or more and 100 m / s depending on the height of the protrusions 111 of the support 110, from the viewpoint of shaping and texture. It is as follows. When the wind speed is slower than this lower limit, the nonwoven fabric is not sufficiently shaped. For this reason, the cushioning property of a nonwoven fabric, the stock property of excrement, and the effect of air permeability are not fully exhibited. When the wind speed exceeds this upper limit value, an opening is generated in the top portion 22T of the second protrusion 22.
- the nonwoven fabric tends to be crushed, and the cushioning property, excrement stock property, and air permeability effect are not sufficiently exhibited. Furthermore, it becomes easy for excrement to go back through the opening. In this way, the web 50 is shaped into a concavo-convex sheet.
- the height of the protrusion 111 of the support 110 is appropriately determined depending on the thickness of the entire sheet to be shaped and the layer thickness of the sheet. For example, it is set to 1 mm or more and 10 mm or less, preferably 1.5 mm or more and 9 mm or less, more preferably 2 mm or more and 8 mm or less.
- the second hot air W2 at a temperature at which each fiber of the web 50 can be appropriately fused is blown to fuse and fix the fibers together.
- the temperature of the second hot air W2 at this time is preferably 0 ° C. to 70 ° C. higher than the melting point of the thermoplastic fiber constituting the web 50 in consideration of a general fiber material used for this type of product. More preferably, the temperature is 5 to 50 ° C higher.
- the wind speed of the second hot air W2 is set to 1 m / s or more and 10 m / s or less, preferably 3 m / s or more and 8 m / s or less.
- thermoplastic fiber the fiber described above is used.
- the temperature of the second hot air W2 sprayed on the web 50 is equal to or higher than the melting point of the low melting point component and lower than the melting point of the high melting point component. It is preferable. More preferably, the temperature is at least 10 ° C lower than the melting point of the high melting point component, more preferably at least 5 ° C higher than the melting point of the low melting point component, and more preferably at least 20 ° C lower than the melting point of the high melting point component. .
- the web 50 preferably contains 30% by mass or more and 100% by mass or less of thermoplastic fiber, more preferably 40% by mass or more and 100% by mass or less.
- the web 50 may include fibers that do not inherently have heat-fusibility. Examples of fibers that do not have heat-fusibility include natural fibers such as cotton and pulp, rayon, and acetate.
- the nonwoven fabric 10 basically exhibits the effects of the present invention even if the first protrusion top 11T is not hydrophobized. That is, it becomes easy to shape the web, the nonwoven fabric can have high cushioning properties, and the uneven shape can be maintained even under high load. Furthermore, since the contact area of a nonwoven fabric and skin is not increased and adhesion of the discharged liquid to skin can be suppressed, it is more preferable.
- the hydrophobizing method is not particularly limited.
- the hydrophobizing method includes gravure coating and screen coating. Or it is also possible to employ
- a plate having a non-deformable flat coating surface to which a hydrophobic agent has been applied in advance is prepared.
- the nonwoven fabric 10 is disposed so that the application surface of the hydrophobic agent is in contact with the first protrusions 11 of the nonwoven fabric 10 evenly.
- a weight is placed on the plate so that a pressure of 0.5 kPa to 3.5 kPa is applied.
- a constant pressure is applied to the first protrusion 11 of the nonwoven fabric 10.
- the hydrophobic agent applied to the application surface soaks into the first protruding portion top portion 11T that is in contact with the application surface with this pressure.
- the hydrophobic part 11D is formed in the 1st protrusion part top part 11T (refer FIG. 1).
- a weight By using a weight, it is possible to apply a load evenly to each first protrusion top 11T.
- the hydrophobic agent can be evenly transferred to each first protrusion top 11T. That is, the hydrophobic portion 11D can be formed with high accuracy.
- the hydrophobic agent soaked into the first protrusion top portion 11T is diffused in all directions in the first protrusion top portion 11T.
- the pressure due to the weight can be appropriately adjusted so as to obtain a desired effect of suppressing the adhesion of the discharged liquid to the skin.
- a hydrophobization treatment is performed by applying a pressure of 0.5 kPa or more and 3.5 kPa or less to the plate so that the hydrophobic agent is soaked into the first protrusion top portion 11T.
- a pressure of 0.5 kPa or more and 3.5 kPa or less to the plate so that the hydrophobic agent is soaked into the first protrusion top portion 11T.
- the injection depth of the nozzle there is a method of increasing the injection depth of the nozzle and injecting from the vicinity of the second surface side Z2 side.
- the hydrophobic agent for example, a hydrophobic oil agent is used.
- the area ratio between the area St1 on the first surface side Z1 of the hydrophobic portion 11D and the area St2 on the second surface side Z2 of the hydrophobic portion 11D can be changed.
- the fineness of the second surface side Z2 of the thermoplastic fiber used for the web 50 is made smaller than the fineness of the first surface side Z1. In this way, the fiber density on the second surface side Z2 is made higher than the fiber density on the first surface side Z1. This also makes it possible to achieve the change in the area ratio.
- the hydrophobic agent soaked into the first protrusion top 11T diffuses more on the second surface side Z2 than on the first surface side Z1. Furthermore, the hydrophobic area of the hydrophobic portion 11D is preferably adjusted so that the amount of liquid return is effectively reduced in the usage state.
- hydrophilic agents can be used for the hydrophilic treatment without particular limitation.
- a hydrophilic oil agent is used.
- an anionic, cationic, amphoteric or nonionic surfactant is generally used. In particular, it is not limited to these. These can be used as an aqueous solution or an emulsion having a predetermined concentration.
- Preferred hydrophilizing agents include aliphatic monocarboxylate, polyoxyethylene alkyl sulfate, polyoxyethylene alkyl phosphate, glycerin fatty acid ester, sorbitan fatty acid ester, sucrose fatty acid ester, polyoxyethylene alkyl ether, fatty acid polyethylene Examples include glycols, alkylamine salts, and alkylbetaines.
- the hydrophobic agent include silicone oligomers and fluorine oligomers.
- the silicone oligomer is typically a chain polydimethylsilicone. Further, there are modified silicones in which a part of the methyl group is replaced with a polyether, phenyl group or trifluoropropyl group.
- an acrylic acid ester or a phosphoric acid ester of alcohol containing a perfluoroalkyl group as a water and oil repellent agent is used.
- the feature of the silicone water repellent is that it has excellent water repellency and flexibility and is suitable for the treatment of a surface agent that directly contacts the skin.
- a fluorine-based water repellent exhibits the most excellent water repellency. In particular, there is an advantage that water repellency can be maintained even when a surfactant for hydrophilicity is in contact.
- the nonwoven fabric 10 is produced as described above.
- the manufacturing method considers continuous production.
- the manufacturing apparatus (not shown) includes a conveyor type or a drum type capable of transporting the support 110.
- a mode in which the conveyed sheet with the uneven shape fixed thereon is wound up by a roll (not shown).
- the thickness of each sheet is appropriately determined according to the wind speed of the first hot air W1. For example, when the wind speed is increased, the thickness of the sheet increases. If it is delayed, the thickness of the sheet becomes thinner. Further, when the wind speed is increased, the fiber density difference between the first protrusion and the second protrusion is increased. When the wind speed is decreased, the fiber density difference between the first protrusion and the second protrusion is reduced.
- the nonwoven fabric 10 of the present invention can be used for various applications.
- it can be suitably used as a surface sheet for absorbent articles such as disposable diapers, sanitary napkins, panty liners, urine absorption pads and the like.
- the non-woven fabric 10 is excellent in air permeability, liquid diffusibility, deformation characteristics at the time of pressing force, etc. due to the uneven structure on both sides. From this, it can also be used as a sub-layer interposed between a surface sheet such as a diaper or sanitary product and an absorbent body.
- the form utilized as a gather of an absorbent article, an exterior sheet, and a wing is also mentioned.
- seat, and a filter is also mentioned.
- the disposable diaper shown in the figure is a tape-type disposable diaper for infants.
- the drawing shows a state in which the diaper in a flat state is bent slightly and viewed from the inside (skin contact surface side).
- the disposable diaper 100 includes a liquid permeable top sheet 1 disposed on the skin contact surface side, a liquid poorly permeable back sheet 2 disposed on the non-skin contact surface side, and the above-mentioned A liquid-retaining absorbent 3 is disposed between both sheets.
- the nonwoven fabric 10 of the above embodiment is applied to the top sheet 1.
- the 1st protrusion part 11 side of the nonwoven fabric 10 is made into the skin contact surface.
- the back sheet 2 has a shape in which both side edges are bound inward in the longitudinal center C in the unfolded state.
- back sheet 2 may consist of one sheet, or may consist of a plurality of sheets.
- the back sheet 2 is not particularly limited as long as it has waterproofness and moisture permeability.
- a porous film is mentioned.
- the porous film is formed by melting and kneading a hydrophobic thermoplastic resin, a fine inorganic filler made of calcium carbonate or the like, an incompatible organic polymer, or the like.
- the film is obtained by uniaxial or biaxial stretching.
- the thermoplastic resin include polyolefin.
- the polyolefin include high density to low density polyethylene, linear low density polyethylene, polypropylene, polybutene and the like. And these thermoplastic resins can be used individually or in mixture.
- the absorbent body 3 various forms used for this type of article can be widely adopted as long as they have liquid retention.
- the pulp fiber include wood pulp such as softwood kraft pulp and hardwood kraft pulp.
- wood pulp such as softwood kraft pulp and hardwood kraft pulp.
- natural cellulose fibers such as non-wood pulp, such as cotton pulp and a straw pulp, are mentioned.
- synthetic resin fibers such as polyolefin resin, such as polyethylene and a polypropylene, polyester resins, such as a polyethylene terephthalate, and polyvinyl alcohol resin
- synthetic resin fibers include single fibers or composite fibers containing two or more of these resins.
- semi-synthetic fibers such as acetate and rayon may be included in a part of the absorber.
- superabsorbent polymer various polymer materials usually used for this type of article can be used.
- the water-absorbing polymer is preferably a superabsorbent polymer compound having a performance capable of absorbing and retaining water or saline more than 20 times its own weight.
- the covering sheet is a hydrophilic member.
- thin paper such as hydrophilic tissue paper, crepe paper, non-woven fabric made of hydrophilic fibers such as cotton and rayon, non-woven fabric formed by subjecting synthetic resin fibers to hydrophilic treatment, Etc.
- nonwoven fabric for example, an air-through nonwoven fabric, a point bond nonwoven fabric, a spunlace nonwoven fabric, a spunbond nonwoven fabric, a spunbond-meltblown-spunbond (SMS) nonwoven fabric, or the like can be used.
- SMS spunbond-meltblown-spunbond
- the side sheet 5 is preferably a water-repellent nonwoven fabric.
- a non-woven fabric a spunbonded non-woven fabric, a melt blown non-woven fabric, a spunlace non-woven fabric, a heat roll non-woven fabric, a needle punched non-woven fabric manufactured by the card method can be used.
- Particularly preferred are spunbond nonwoven fabric, spunbond-meltblown (SM) nonwoven fabric, spunbond-meltblown-spunbond (SMS) nonwoven fabric, and the like.
- a side leakage preventing gather 7 is provided on the side seat 5.
- the diaper of the present embodiment may be further provided with a functional structure, a sheet material, and the like.
- FIG. 9 the arrangement
- the above diaper is shown as a tape type.
- a fastening tape 6 is provided on the flap portion on the back side R.
- Fastening tape 6 can be affixed to a tape affixing part (not shown) provided in the flap part of ventral side F, and a diaper can be mounted and fixed.
- the center part C of the diaper is gently bent inward so that the absorbent body 3 is worn along the baby's buttocks and lower abdomen.
- excreta is absorbed and held in the absorber 3 accurately.
- Diapers are used in such a wearing form.
- the nonwoven fabric 10 is applied as the top sheet 1.
- the absorbent article of the present invention is not limited to the disposable diaper of the above embodiment.
- it can be applied to sanitary napkins, panty liners, incontinence pads, urine collection pads, and the like.
- members may be appropriately incorporated as constituent members of the absorbent article according to applications and functions.
- This invention discloses the manufacturing method of the following nonwoven fabrics, the surface sheet for absorbent articles, an absorbent article, and a nonwoven fabric further regarding embodiment mentioned above.
- ⁇ 1> a first protrusion that protrudes toward the first surface of the sheet body in a plan view and has an internal space;
- a second projecting portion projecting on the second surface side opposite to the first projecting portion and having an internal space;
- a plurality of the first protrusions and the second protrusions are alternately and continuously arranged through wall portions in different directions intersecting in plan view of the nonwoven fabric,
- the adjacent first protrusions and the adjacent second protrusions are nonwoven fabrics that are continuously connected in an oblique direction in plan view with respect to each of the different directions via the ridges, respectively.
- the height in the thickness direction of the first protrusion is higher than the height in the thickness direction of the ridge,
- the nonwoven fabric whose rise angle of the wall part of the said 1st protrusion part is 0 degree or more and 20 degrees or less.
- the rising angle of the wall portion of the first protrusion is preferably greater than 0 ° and 20 ° or less, more preferably greater than 0 ° and 15 ° or less, and greater than 0 °.
- the nonwoven fabric according to ⁇ 1> more preferably 12 ° or less.
- the fibers constituting the wall have fiber orientation in a direction connecting the top of the first protrusion and the edge of the opening of the internal space of the first protrusion ⁇ 1>. Or the nonwoven fabric as described in ⁇ 2>.
- the fiber which comprises the ⁇ 5> said wall part is a nonwoven fabric any one of ⁇ 1> to ⁇ 4> which has radial fiber orientation which goes to the said 1st protrusion part top part.
- the fibers constituting the wall of the second protrusion have fiber orientation in the direction connecting the top of the second protrusion and the edge of the opening of the internal space.
- ⁇ 1> to ⁇ 5> The nonwoven fabric of any one.
- ⁇ 7> The nonwoven fabric according to any one of ⁇ 1> to ⁇ 6>, wherein the orientation angle of the wall portion is 50 ° to 130 °, and the orientation strength is 1.05 or more.
- ⁇ 8> The nonwoven fabric according to any one of ⁇ 1> to ⁇ 6>, wherein the wall has an orientation angle of 60 ° to 120 ° and an orientation strength of 1.10 or more.
- ⁇ 9> The nonwoven fabric according to any one of ⁇ 1> to ⁇ 6>, wherein the wall has an orientation angle of 85 ° to 95 ° and an orientation strength of 1.30 or more.
- ⁇ 10> Any one of ⁇ 1> to ⁇ 9>, wherein when the nonwoven fabric is pressurized at a pressure of 3.5 kPa, the height in the thickness direction of the first protrusion is higher than the height in the thickness direction of the ridge.
- the nonwoven fabric described in 1. ⁇ 11> The ratio (h1 / h5) between the height h1 in the thickness direction of the first protrusion and the height h5 of the ridge when the nonwoven fabric is pressurized at a pressure of 3.5 kPa is as follows.
- the first projecting portion has a height h1 in the thickness direction, and its top portion has a steeper rising angle than a cone having a round shape like a hemisphere, and the top portion is a part of a hemisphere.
- ⁇ 13> The nonwoven fabric according to any one of ⁇ 1> to ⁇ 12>, wherein the hydrophilicity of the top of the first protrusion is lower than that of the second protrusion and the wall.
- ⁇ 14> The nonwoven fabric according to any one of ⁇ 1> to ⁇ 13>, wherein the hydrophilicity of the top of the first protrusion is lower than the hydrophilicity of the ridge.
- ⁇ 15> The top of the first protrusion has a contact angle of ion exchange water at 22 ° C.
- the preferred contact angle between the top of the second protrusion and the wall is such that the contact angle of the ion exchange water is 30 ° or more and less than 80 °, preferably 60 ° or more and 70 ° or less ⁇ 1> to ⁇ 14. > Any one of>. Any one of ⁇ 1> to ⁇ 14>, wherein the ⁇ 16> ridge has a contact angle of ion-exchanged water at 22 ° C. of 30 ° or more and less than 80 °, preferably 60 ° or more and 70 ° or less.
- the hydrophilicity of the top portion of the first protruding portion is lower than the portion excluding the top portion of the first protruding portion, or has hydrophobicity.
- ⁇ 18> The nonwoven fabric according to any one of ⁇ 1> to ⁇ 17>, wherein the two different directions are orthogonal to each other.
- ⁇ 19> The nonwoven fabric according to any one of ⁇ 1> to ⁇ 18>, wherein the wall portion forms an annular structure in the first projecting portion and the second projecting portion.
- the layer thickness TL1 of the top of the first protrusion, the layer thickness TL2 of the top of the second protrusion, and the layer thickness TL3 of the wall are TL1>TL3> TL2, and any one of ⁇ 1> to ⁇ 19> Or the nonwoven fabric according to 1.
- ⁇ 21> A topsheet for an absorbent article using the nonwoven fabric according to any one of ⁇ 1> to ⁇ 20>.
- a surface sheet for absorbent articles wherein the nonwoven fabric according to any one of ⁇ 1> to ⁇ 20> is used with the first surface side facing the skin contact surface side.
- a concavo-convex shape is formed, a web containing thermoplastic fibers is conveyed to a heated support, and hot air is blown from the top of the web toward the support to shape the concavo-convex shape on the web.
- a method for producing a nonwoven fabric comprising: Heating the support to a temperature range from the glass transition point to the melting point of the fibers constituting the web; and Temporarily fusing the fibers of the web to a state in which the uneven shape is maintained by blowing a first hot air; and A step of blowing a second hot air having a temperature higher than that of the first hot air, and fixing the uneven shape by fusing the fibers of the web while maintaining the uneven shape.
- the temperature range for heating the support is preferably a temperature higher than the glass transition point of the fiber and 10 ° C. or lower than the melting point, more preferably a temperature 20 ° C. higher than the glass transition point of the fiber.
- ⁇ 27> The method for producing a nonwoven fabric according to ⁇ 25> or ⁇ 26>, wherein the temperature of the support is within the temperature range when the first hot air is blown.
- the manufacturing method of the nonwoven fabric any one of ⁇ 25> to ⁇ 27> including the process of hydrophobizing the top part of the 1st protrusion part used as the said uneven
- ⁇ 29> A nonwoven fabric produced using the nonwoven fabric production method according to any one of ⁇ 25> to ⁇ 28>.
- ⁇ 30> A surface sheet for absorbent articles using the nonwoven fabric according to ⁇ 29>.
- Example 1-9 In Example 1, the core is made of polyethylene terephthalate (melting point 258 ° C., glass transition point 67 ° C.) and the sheath is made of polyethylene (melting point 135 ° C., glass transition point ⁇ 20 ° C.). Then, a 2.4 dtex ⁇ 51 mm core-sheath type composite fiber having a hydrophilic surface was applied to a card machine so as to be a web 50 having a basis weight of 30 g / m 2 , and the web 50 was supplied to a shaping apparatus. In the shaping apparatus, the web 50 was fixed on the support 110 having a large number of protrusions and air permeability. The support 110 is heated to 70 ° C.
- the MD pitch in the plan view of the protrusion 111 of the support 110 was 8 mm
- the CD pitch was 5 mm
- the height of the protrusion 111 was 7.5 mm.
- the hole diameter of the hole 112 in the support body 110 was 2.8 mm.
- the web 50 on the support 110 is blown with the first hot air W1 having a temperature of 130 ° C. and a wind speed of 50 m / s, and the web 50 is shaped along the protrusions 111 on the support 110.
- the shape of each core-sheath structure was fixed by fusing together.
- Example 2 was produced in the same manner as in Example 1 except that the heating temperature of the support 110 in Example 1 was changed to 90 ° C.
- Example 3 was produced in the same manner as in Example 1 except that the heating temperature of the support 110 was 110 ° C. in Example 1 above.
- the nonwoven fabric 10 of Example 1 was produced, and the hydrophobic treatment was further performed.
- the hydrophobic agent KM-903 (manufactured by Shin-Etsu Chemical Co., Ltd.) was used. The hydrophobic agent was dissolved in ethanol, adjusted to a 1.0% by weight solution, and applied to an acrylic plate at 4.3 mg / cm 2 .
- Hydrophobic part 11D was produced by bringing the pressure of 2.0 kPa into contact with the first protrusion top part 11T over 10 seconds.
- Example 5 was produced in the same manner as in Example 4 except that the heating temperature of the support 110 was changed to 90 ° C. in Example 4.
- Example 6 was produced in the same manner as in Example 4 except that the heating temperature of the support 110 was changed to 110 ° C. in Example 4.
- Example 7 was prepared in the same manner as in Example 5 except that KF-6011 (manufactured by Shin-Etsu Chemical Co., Ltd.) was used as the hydrophobic agent in Example 5.
- Example 8 was prepared in the same manner as in Example 5 except that the web 50 was a two-layer product of core-sheath type composite fiber 2.4 dtex ⁇ 51 mm and 1.8 dtex ⁇ 51 mm.
- Example 9 was produced in the same manner as in Example 8, except that the pressure applied to the plate in Example 8 was 1.5 kPa.
- Comparative Example 1 was produced in the same manner as in Example 1 except that the heating temperature of the support 110 was 40 ° C. in Example 1.
- Comparative Example 2 was produced in the same manner as in Example 4 except that the heating temperature of the support 110 was 40 ° C. in Example 4.
- the nonwoven fabric 10 of Comparative Example 2 was prepared, and further a KM-903 (manufactured by Shin-Etsu Chemical Co., Ltd.) 1.0 wt% ethanol solution was applied to the walls and ridges with a brush. This was prepared in the same manner as in Example 2 except that.
- ND500 manufactured by CHINO Co., Ltd. was used for the measuring instrument body, and C510-05K manufactured by CHINO Co., Ltd. was used for the measurement terminal. The temperature was measured three times, and the average value was defined as the support temperature.
- the binarized image is subjected to Fourier transform using Fiber Orientation Analysis 8.13 Single software (trade name), which is a fiber orientation analysis program, to obtain a power spectrum, and from an elliptical distribution map, orientation is obtained. Corners and orientation strength were obtained.
- the orientation angle indicates the angle at which the fibers are most oriented.
- the orientation strength indicates the strength at the orientation angle. In the measurement of the middle portion of the wall portion, it is shown that the fiber is oriented in the central direction of the top portion 11T as the orientation angle is closer to 90 °. And if an orientation angle is 60 degrees or more and 120 degrees or less, it will judge that the fiber has orientated in the center direction of the top part 11T.
- orientation strength is 1.05 or more is assumed to be oriented. Measurement was performed at three locations, and the average was taken as the orientation angle and orientation strength of the sample.
- the fiber orientation described above is a concept consisting of the orientation angle and orientation strength of the fiber.
- the fiber orientation angle is a concept indicating in which direction a plurality of fibers having various directions are oriented as a whole.
- the shape of the fiber aggregate is digitized.
- the fiber orientation strength is a concept indicating the amount of fiber exhibiting an orientation angle. When the orientation strength is less than 1.05, there is almost no orientation. It can be said that it has an orientation at 1.05 or more.
- the fiber orientation changes depending on the part. That is, it changes from a part with a certain orientation angle to a part with a different orientation angle. That is, the fiber changes from a state in which the orientation strength is strong in a certain direction to a portion that shows strong strength in a different orientation.
- the orientation angle of the fiber is changed between a portion showing a strong orientation angle and a portion showing a strong orientation angle in another direction even if the orientation strength of the fiber is weak. And it is more preferable that orientation strength is high.
- An example of the orientation angle and orientation strength is shown in this embodiment.
- the orientation angle is preferably 50 ° or more and 130 ° or less, more preferably 60 ° or more and 120 with respect to the curved surface structure of the wall portion 13 of the first protrusion 11. ° or less.
- the orientation strength is preferably 1.05 or more, more preferably 1.10 or more.
- the wall portion 14 of the second protrusion 12 is the same as the wall portion 13.
- the nonwoven fabric 10 has sufficient compression resistance even under high pressure due to the fiber orientation of each wall portion 13.
- the 1st protrusion part 11 of the nonwoven fabric 10 and the 2nd protrusion part 12 are prevented from collapsing.
- the nonwoven fabric 10 can secure a sufficient capture space and has an effect of reducing the contact area with the skin.
- the nonwoven fabric 10 has high air permeability.
- the nonwoven fabric 10 sufficiently captures a large amount of liquid, solid content, high-viscosity liquid, etc., and sufficiently exhibits the effect of suppressing leakage.
- ⁇ Measurement of thickness at 0.05 kPa pressure The cut surface of the nonwoven fabric 10 is enlarged to a size (10 times to 100 times) that can be measured by a digital microscope VHX-1000 manufactured by Keyence sufficiently to enter the visual field. Next, a weight is placed on the nonwoven fabric 10 so that a pressure of 0.05 kPa is applied. And the height h1 of the thickness direction of the 1st protrusion part 11 and the height h5 of the thickness direction of the ridge part 15 are measured. The measurement was performed 10 times, and the average value was defined as the height h1 of the first protrusion top portion 11T of the nonwoven fabric 10 and the height h5 of the ridge portion 15.
- a contact angle meter is used to measure the contact angle.
- a contact angle meter MCA-J manufactured by Kyowa Interface Science Co., Ltd. is used.
- the contact angle is measured immediately using the contact angle meter.
- the measurement is performed at five or more locations on the nonwoven fabric 10 and the average value thereof is taken as the contact angle.
- the measurement temperature is 22 ° C., and the relative humidity of the measurement atmosphere is 65%.
- the 1st protrusion part top part 11T is hydrophobic, and it is preferable that the contact angle of ion-exchange water is 80 degrees or more. More preferably, it is 100 ° or more.
- the contact angle of ion-exchanged water is 30 ° or more and less than 80 °. Preferably they are 60 degrees or more and 70 degrees or less. Therefore, the contact angle of the ridge portion 15 is preferably set to the above angle. Specifically, it is preferably 30 ° or more and less than 80 °, more preferably 60 ° or more and 70 ° or less. The lower the contact angle value measured here, the higher the hydrophilicity.
- ⁇ Measurement method of rising angle> The cut surface of the nonwoven fabric 10 is enlarged to a size (10 times to 100 times) that can be measured by a digital microscope VHX-1000 manufactured by Keyence sufficiently to enter the visual field. Then, the rising angle ⁇ of the first protrusion 11T is measured. As shown in FIG. 4B, the rising angle ⁇ is obtained as follows. A straight line Lv perpendicular to the straight line Lh connecting the tops 12T of the second protrusions 12 is drawn. The angle ⁇ formed by the straight line Lv and the tangent Lt of the nonwoven fabric (web 50) on the second surface side Z2 drawn from the second protrusion top 12T to the wall 14 is measured. The measurement was performed 10 times, and the average value of 10 times was defined as the rising angle ⁇ of the wall portion 13 (14) of the first protruding portion 11T of the nonwoven fabric 10.
- the area in the range where the contact angle is 80 ° or more is measured by counting the number of squares of 0.2 mm square.
- the measurement results were defined as an area St1 on the first surface side and an area St2 on the second surface side of the hydrophobic portion 11D, respectively.
- a KES compression tester (KES FB-3 manufactured by Kato Tech Co., Ltd.) was used. The compression characteristics up to 5.0 kPa were evaluated in the normal mode, and the RC value was read. As measurement values, three points were measured and the average value was defined as compression recovery.
- This KES compression tester is a plate having a circular plane with an area of 2 cm 2 at the compression site, the compression speed is 0.02 mm / s, the compression maximum pressure is 5.0 kPa, and the compression direction is reached when the compression maximum pressure is reached. Is reversed and the process proceeds to the recovery process.
- the RC value is a percentage of the recovered energy with respect to the energy during compression.
- the RC value in the compression characteristic evaluation is the time integral value of the pressure from the time T 0 when the initial pressure applied to the nonwoven fabric specimen is 0.05 kPa to the time T m when the maximum pressure is 5.0 kPa, up to the maximum pressure of 5.0 kPa. Divided by the amount of work and expressed in%.
- the liquid return amount was measured using an infant diaper for evaluation.
- the surface sheet was removed from an infant diaper, and a test specimen of the nonwoven fabric 10 (hereinafter referred to as a nonwoven test article) was used instead, and the periphery thereof was fixed.
- a test specimen of the nonwoven fabric 10 hereinafter referred to as a nonwoven test article
- Marys Sarasara Air-Through (registered trademark) M size manufactured by Kao Corporation, used in 2012 was used.
- a pressure of 3.5 kPa was applied uniformly on the non-woven fabric test piece, a cylinder having a cross-sectional area of 1000 mm 2 placed at the approximate center of the test piece was applied, and artificial urine was injected therefrom.
- Liquid return amount (g) Mass of filter paper after pressurization (M2)-Mass of filter paper before pressurization (M1)
- ⁇ Measurement method of liquid flow length> For the liquid flow of the artificial urine, an infant diaper for evaluation was used. Artificial urine was supplied to it, and the distance from the supply position was measured. The baby diaper for evaluation was obtained by removing the top sheet from the baby diaper and using a test body of the nonwoven fabric 10 instead, and fixing the periphery of the test body.
- a diaper for infants a product made in 2012 by Marys Sarasara Air-Through (registered trademark) M size manufactured by Kao Corporation was used. In the measurement, a flat acrylic plate is tilted so that an inclined surface of 30 ° is obtained, and the evaluation diaper for infant is attached to the inclined surface and pressurized at 3.5 kPa.
- Table 1 shows the results of the physical properties (support temperature, orientation angle, orientation strength, thickness, contact angle, hydrophobic part area) and performance (compression recovery (RC value), liquid return amount, liquid flow) of the nonwoven fabric 10. Shown in
- the thickness of the first protrusion 11 at a pressure of 3.5 kPa was 2.6 mm or more, and the liquid return amount was 1.3 g or less. This is because the heating temperature of the support 110 is in a suitable range, so that shaping can be performed along the shape of the support 110, and the rising angle is 20 ° or less. Thereby, the nonwoven fabric 10 became difficult to be crushed in the thickness direction. This shows that the RC value (%) is higher than that of the comparative example, and the cushioning property is improved. In Examples 4 to 9, the liquid return amount was 0.8 g or less, and the liquid return amount decreased.
- the first protruding portion top portion 11T is hydrophobic on the first surface side Z1 that is the skin contact surface side, the remaining amount of the liquid that touches the skin This is because of the decrease. And it is because the liquid overflowing from the absorber is difficult to return to the first surface side Z1.
- the liquid flow length was 65 mm or less, and the liquid flow was small. This is because the heating temperature of the support 110 is in a suitable range, so that shaping along the shape of the support 110 can be performed, and the difference in height between the first protrusion 11 and the ridge 15 is increased. by.
- the liquid flow on the first surface side Z ⁇ b> 1 of the nonwoven fabric 10 is caused to flow in an oblique direction with respect to the first direction X and the second direction Y.
- Comparative Example 1 since the heating temperature of the support 110 was as low as 40 ° C., shaping along the shape of the support 110 could not be performed. For this reason, the rising angle became 30 °, and the nonwoven fabric 10 was easily crushed in the thickness direction. And since there was no hydrophobic part in the 1st protrusion part top part 11T, the liquid return amount increased with 1.5g.
- the amount of liquid flows is 58 mm. It became small.
- the liquid return amount was a little as 1.0 g and 0.9 g, and the liquid flow length was very long as 100 mm or more. This is because the heating temperature of the support 110 is as low as 40 ° C., and thus shaping along the shape of the support 110 cannot be performed.
Abstract
Description
本発明は、シート体の不織布を平面視した側の第1面側に突出し内部空間を有する第1突出部と、前記第1突出部とは反対側の第2面側に突出し内部空間を有する第2突出部とを有し、前記第1突出部および前記第2突出部とは該不織布の平面視交差する異なる方向のそれぞれに壁部を介して交互に連続して複数配され、隣接する前記第1突出部同士、および隣接する前記第2突出部同士は、それぞれ尾根部を介して前記の異なる方向のそれぞれに対して平面視斜め方向に連続して連なった不織布であり、前記不織布を0.05kPaの圧力で加圧した時に、前記第1突出部の厚み方向の高さが前記尾根部の厚み方向の高さより高く、前記第1突出部の壁部の立ち上がり角度が、0°以上20°以下である不織布を提供する。 The present invention has a concavo-convex shape, conveys a web containing thermoplastic fibers to a heated support, and blows hot air from above the web toward the support to shape the concavo-convex shape on the web. A method for producing a nonwoven fabric, the step of heating the support to a temperature range of not less than the glass transition point of the fibers constituting the web and not more than the melting point, and the fibers of the web by the first hot air blowing The step of temporarily fusing the concavo-convex shape and the second hot air having a temperature higher than that of the first hot air is blown, and the fibers of the web are fused together while the concavo-convex shape is maintained. The manufacturing method of a nonwoven fabric provided with the process of fixing the said uneven | corrugated shape is provided.
The present invention has a first projecting portion projecting on the first surface side of the nonwoven fabric sheet in plan view and having an inner space, and projecting on the second surface side opposite to the first projecting portion and having an inner space. And a plurality of the first protrusions and the second protrusions that are alternately and continuously arranged through the wall portions in different directions intersecting the planar view of the nonwoven fabric. The first protrusions and the adjacent second protrusions are nonwoven fabrics that are continuously connected in an oblique direction in plan view with respect to each of the different directions via a ridge portion, and the nonwoven fabrics. When pressurized with a pressure of 0.05 kPa, the height in the thickness direction of the first protrusion is higher than the height in the thickness direction of the ridge, and the rising angle of the wall of the first protrusion is 0 ° or more. A non-woven fabric that is 20 ° or less is provided.
本発明の不織布10は、例えば生理用ナプキン、使い捨ておむつ、失禁パッドなどの吸収性物品の表面シートに適用することが好ましい。その際、不織布10は第1面側Z1を着用者の肌面側に向けて用いることが好ましい。かつ不織布10は第2面側Z2を物品内部の吸収体(図示せず)側に配置して用いることが好ましい。以下、図面に示した不織布10の第1面側Z1を着用者の肌面に向けて用いる実施態様を考慮して説明する。本発明はこれにより限定して解釈されるものではない。なお、図2の平面配設図では、直交座標系のz軸において、不織布10より上方側を第1面側Z1、不織布10より下方側を第2面側Z2とする。 A preferred embodiment of the nonwoven fabric according to the present invention will be described below with reference to FIGS. 1 and 2.
The
上記第1面側Z1からみた凸部が第1突出部11であり、凹部が第2突出部12となる。また、第2面側Z2からみた凸部が第2突出部12であり、凹部が第1突出部11となる。したがって、第1突出部11と第2突出部12とは一部が共有されている。 As shown in FIG. 1 and FIG. 2, the
The convex portion viewed from the first surface side Z <b> 1 is the
さらに第1突出部11、第2突出部12、壁部13を明確にするために、不織布10の厚み方向の高さを3等分して、上部を第1突出部11、中間部を壁部13(14)、下部を第2突出部12と定義する。また、隣接する第1突出部11同士を連続させる第1面側Z1方向で最も高い位置を繋ぐ部分が尾根部15である。さらに第1突出部11と尾根部15とでみた場合に、第1突出部頂部11Tと尾根部15の最も低い位置とを第1面側Z1方向で2等分した下部を尾根部15とする。 There is no clear boundary between the
Furthermore, in order to clarify the
上記親水性の高低、疎水性の高低は、後述する接触角の測定によって判断される。後述する接触角の値が小さいほど親水性が高いことになる。また接触角の値が大きいほど疎水性が高いことになる。本願においては、疎水性であると思われる領域であっても、後述する接触角の値の大小で親水性の高低を比較判断する。
なお、第1突出部頂部11Tが疎水化されていなくても、不織布10は、基本的に、本発明の効果を奏する。すなわち、不織布10は高いクッション性を有することができ、また高荷重下であっても凹凸形状を維持でき、さらに肌への接触面積の増大を抑えて肌への排出液の付着を抑制することができる。上述したように第1突出部頂部11Tが疎水化されていると、肌への排出液の付着をさらに抑制することができることから、より好ましい。 Moreover, the hydrophilicity of the 1st protrusion part
The level of hydrophilicity and the level of hydrophobicity are determined by measuring the contact angle described later. The smaller the contact angle value described later, the higher the hydrophilicity. The larger the contact angle value, the higher the hydrophobicity. In the present application, even in a region that is considered to be hydrophobic, the level of hydrophilicity is compared and judged by the magnitude of the contact angle value described later.
In addition, even if the 1st protrusion part
また、図5に示すように、第2突出部12の壁部14(13)を構成する繊維16は、第2突出部頂部12Tとその内部空間12Kの開口部12Hの縁部を結ぶ矢印Aで示した方向に繊維配向性を有する。この壁部14の繊維配向性は、上述の壁部13と共通部分では、壁部13の繊維配向性と同じになっている。なお、第2突出部頂部12Tと内部空間12Kの開口部12Hの縁部を結ぶ方向、及び壁部13の起立する方向とは、不織布における厚み方向に概ね一致している。 As shown in FIG. 4, the
Moreover, as shown in FIG. 5, the
壁部13の厚み方向に配向した繊維によって、液がスムースに繊維を伝い流れる。そして、液が不織布10の下面に配された吸収体(図示せず)に移行する。且つ、壁部13の繊維配向性により液戻りが少なくなることからも、サラッとした肌触りが実現される。また、上述した構造の維持による不織布10自体の通気性に優れることにより、カブレの防止に役立つ。 Thus, the
By the fibers oriented in the thickness direction of the
前記不織布10を3.5kPaの圧力で加圧した時の、第1突出部11の厚み方向の高さh1と尾根部15の高さh5との比(h1/h5)は、横漏れのし難さの観点から、1.01以上であることが好ましく、1.05以上であることがより好ましく、1.2以上であることがさらに好ましい。また上限としては、2.5以下であることが好ましく、2.0以下であることがより好ましく、1.8以下であることがさらに好ましい。
不織布10を3.5kPaの圧力で加圧して測定するのは、着用者が着座しているときの不織布にかかる圧力を模しているためである。すなわち、着座圧を3.5kPaと想定している。着用者とは、本明細書で主眼においているベビーおむつの着用者であり、つまり幼児である。
また、着用者が着座しているときに不織布にかかる圧力と対比する意味で、着用者が立位のときの不織布にかかる圧力は以下のように測定する。着用者が立位の場合、基本的には不織布にかかる荷重は無荷重が想定される。しかし、荷重をかけないで不織布を測定した場合、繊維の集合体である不織布の特性上、測定値にばらつきが生じる。そのため、測定値のばらつきを抑えて実質的に無加圧で測定することを模して、すなわち無加圧に近い状態として、0.05kPa程度の荷重をかけて測定する。 When the
The ratio (h1 / h5) between the height h1 of the
The reason why the
Moreover, the pressure concerning a nonwoven fabric when a wearer is standing is measured as follows in the meaning which contrasts with the pressure concerning a nonwoven fabric when the wearer is sitting. When the wearer is standing, the load applied to the nonwoven fabric is basically assumed to be no load. However, when the nonwoven fabric is measured without applying a load, the measurement values vary due to the characteristics of the nonwoven fabric, which is an aggregate of fibers. For this reason, measurement is carried out by imitating measurement with substantially no pressure while suppressing variations in measured values, that is, with a load of about 0.05 kPa as a state close to no pressure.
このように上記不織布10は、面方向に連続した構造を有していることが好ましい。この「連続」とは、断続した部分や小孔がないことを意味する。ただし、繊維間の隙間のような微細孔は上記小孔に含めない。上記小孔とは、例えば、その孔径が円相当の直径で1.0mm以上のものと定義することができる。 The
Thus, it is preferable that the said
図6に示すように、シートの厚さについては、不織布10を側面視としてみたときの全体の厚さをシート厚みTSとする。不織布10の凹凸により湾曲したシートの局部的な断面の厚さを層厚みTLとする。シート厚みTSは、用途によって適宜調節すればよい。おむつや生理用品等の表面シートとして用い場合、1mm以上7mm以下が好ましく、1.5mm以上5mm以下がより好ましい。その範囲とすることにより、使用時の体液吸収速度が速く、吸収体からの液戻りを抑え、さらには、適度なクッション性を実現することができる。層厚みTLは、シート内の各部位において異なっていてよい。また層厚みTLは、用途によって適宜調節すればよい。おむつや生理用品等の表面シートとして用いる場合、第1突出部頂部11Tの層厚みTL1は0.1mm以上3mm以下であることが好ましく、0.4mm以上2mm以下がより好ましい。好ましい層厚みの範囲としては第2突出部頂部12Tの層厚みTL2および壁部13の層厚みTL3も同様である。各層厚みTL1、TL2、TL3の関係は、TL1>TL3>TL2であることが好ましい。これにより、第1突出部11において、特に肌面側では、繊維密度が低くなる。また、第1突出部11において、特に肌面側では、良好な肌当たりを実現することができる。一方、第2突出部12は繊維密度が高くなり、潰れにくく、型崩れしない。このため、良好なクッション性と液体の吸収速度に優れた不織布になる。
図7に示すように、第1方向Xの第1突出部頂部11Tと第2突出部頂部12Tを平面に投影したときの間隔Dxは、用途によって適宜調節すればよい。おむつや生理用品等の表面シートとして用いる場合、1mm以上15mm以下が好ましく、3mm以上10mm以下がより好ましい。また図面括弧内に符号を示すように、第2方向Yの第1突出部頂部11Tと第2突出部頂部12Tを平面に投影したときの間隔Dyも第1方向Xの間隔Dxと同様になる。また上記不織布10の坪量は特に限定されない。シート全体の平均値で15g/m2以上50g/m2以下が好ましく、20g/m2以上40g/m2以下がより好ましい。 Next, the dimension specification in the
As shown in FIG. 6, about the thickness of a sheet | seat, let the whole thickness when the
As shown in FIG. 7, the distance Dx when the
不織布10は、多量な液の排泄があった場合で、また高荷重下の場合、液残り量および液戻り量が減少する。そのため、表面での液流れを抑制して、液を漏らさないようにできる。これにより、肌当接面上での液流れの防止と非肌当接面側からの液戻りの防止の両立を図ることができる。 The
The
本実施形態の不織布10においては、その両面に突出する第1、第2突出部11、12のそれぞれの内部に内部空間11K、12Kを有する。このことから、排泄液や排泄物の物性に応じて多様な形態でこれらを捕捉し対応することができる。例えば、不織布10の第1面側Z1を肌面側として説明する。粘度が低く透過しやすい排泄液であれば、不織布10の表面シートを透過したのち、内部空間11Kにこれが捕捉される。肌面にまず当たる部分が第1突出部頂部11Tであり、上記捕捉された排泄液ないし排泄物は肌に接触しにくくされている。これにより、尿、経血、下り物等の排泄にも対応して極めて良好なサラッとした感じが持続される。 The said
In the
上述の不織布10の製造方法は、以下の製造方法を適宜採用すればよい。 Next, a preferred embodiment of the method for producing the
The following manufacturing method should just be employ | adopted for the manufacturing method of the above-mentioned
また、支持体110は、加温されている。
支持体110の加温方法は、支持体110自体に熱を伝えて加熱する。すなわち、図示していない熱源で支持体110を直接温める方法である。例えば、電熱線を備えたヒータを突起111が配されていない支持体110の裏面側に配してもよい。または、支持体110上にウエブ50を搬送する前に、熱風を吹き付けて支持体110を温めてもよい。最終的に第1の熱風W1を吹き付ける際に、支持体110の温度が適正温度範囲になっていればどのような加温手段を用いても良い。
支持体110を加温する温度は、ウエブを構成する繊維のガラス転移点以上融点以下の温度とする。支持体110を繊維のガラス転移点以上の温度にすることによって、ウエブ50が塑性変形しやすくなる。そのため、支持体110に沿った形状になりやすくなると考えられる。つまり、ウエブ50を支持体110の形状に沿って賦形しやすくなる。一方、支持体110の加温が低すぎると第1突出部11の高さと尾根部15の高さの差が小さくなる。この場合、壁部の立ち上がり角度が急峻にならない。このままの状態で第1突出部頂部11Tを疎水化すると、不織布10に高加重(着座圧程度の加重)が付加された場合に、不織布表面に多量に液が排泄されることになる。そして、その液が不織布表面を伝い、漏れを起こしやすくなる。また加温が低すぎると、上記疎水化とは関係なく、凹凸形状が潰れやすくなる。そのため、好ましくない。これに対し支持体110の加温が高すぎると繊維同士が融着してしまい、賦形することができなくなる。
上記支時体110の温度は、次工程で説明する第1の熱風W1を吹き付ける際に上記の温度範囲とすることが好ましい。 As an example of the support, the
Moreover, the
As a method for heating the
The temperature which heats the
The temperature of the supporting
その際、第1突出部11の厚み方向の高さh1(図3参照)として、第1突出部11は、頂部が半球のような丸みを有する円錐よりも壁部の立ち上がり角度が急峻な、頂部が半球の一部のような丸みを有する円錐台となる。この第1突出部11の壁部13の立ち上がり角度αは、前述したような角度とすることが好ましい。
なお、図面矢印は第1の熱風W1の流れを模式的に示している。 A web 50 (also referred to as a fiber web) obtained by hydrophilizing hydrophobic thermoplastic fibers with a hydrophilizing oil is used. A known method can be used for the hydrophilic treatment. The
At that time, as the height h1 in the thickness direction of the first protrusion 11 (see FIG. 3), the
The arrows in the drawing schematically show the flow of the first hot air W1.
融着する前のウエブ50を、所定の厚みとなるようカード機(図示せず)からウエブを賦形する装置に供給する。図8(a)に示すように、賦形装置では、まず上記の温度に加温されている支持体110上に上記のウエブ50を搬送して定着させる。
上記支持体110の加温温度は、賦形する繊維のガラス転移点以上融点以下の温度であり、好ましくは繊維のガラス転移点より高い温度以上、融点よりも10℃低い温度以下であり、より好ましくは繊維のガラス転移点より20℃高い温度以上、融点よりも20℃低い温度以下である。例えば熱可塑性繊維として複合繊維を用いる場合、高ガラス転移点成分のガラス転移点以上、低融点成分の融点よりも10℃低い温度以下であり、より好ましくは、高ガラス転移点成分のガラス転移点より20℃高い温度以上、低融点成分の融点よりも20℃低い温度以下である。例えば、繊維に芯/鞘構造の繊維として、ガラス転移点67℃、融点258℃のPET(芯)/ガラス転移点-20℃、融点135℃のPE(鞘)を用いた場合には、67℃以上、125℃以下に加温することが好ましい。また、同じ繊維の例において、87℃以上、115℃以下に加温することがより好ましい。この加温温度が低すぎると支持体110の形状に沿った賦形ができなくなる。この結果、第1突出部11と尾根部15(図1、2参照)の高さの差が大きくならない。このため、高荷重下における不織布10の表面を流れる液が多量になると、漏れやすくなる。一方、支持体110の加温温度が高すぎると、繊維間での融着が生じ、または支持体110への融着が生じ、所望の形状に賦形ができなくなる。 Specific examples of this production method include the following embodiments.
The
The heating temperature of the
このようにして、ウエブ50を凹凸形状のシートに賦形する。 Next, the first hot air W1 is blown onto the
In this way, the
不織布10は、第1突出部頂部11Tが疎水化されていなくても、基本的に、本発明の効果を奏する。すなわち、ウエブを賦形しやすくなり、不織布が高いクッション性を有することができ、高荷重下であっても凹凸形状を維持できる。さらに不織布と肌との接触面積を増大させることがなく、肌への排出液の付着を抑制することができるため、より好ましい。
疎水化方法は、特に限定されない。例えば疎水化方法は、グラビア塗工やスクリーン塗工等が挙げられる。
または、以下のような方法を採用することも可能である。
予め疎水剤を塗布しておいた非変形性の平坦な塗布面を有するプレートを用意する。その疎水剤の塗布面が不織布10の各第1突出部11に均等に接するように不織布10を配置する。そして、幼児の使用状態を想定して、プレート上に0.5kPa以上3.5kPa以下の圧力がかかるようにおもりを載せる。これによって、不織布10の第1突出部11に対し一定圧力を付与する。この圧力で塗布面に接触された第1突出部頂部11Tに対し、塗布面に塗布された疎水剤がしみ込む。そして、第1突出部頂部11Tに疎水部11Dが形成される(図1参照。)。おもりを用いることで、各第1突出部頂部11Tに均等に荷重をかけることができる。これによって、疎水剤を各第1突出部頂部11Tに均等に転写できる。すなわち精度よく疎水部11Dを形成することができる。そして、第1突出部頂部11Tにしみ込んだ疎水剤は第1突出部頂部11T内を四方に拡散される。おもりによる圧力は、排出液の肌への付着を抑制するという所望の効果が得られるよう、適宜調整できる。
上記のように、プレートに0.5kPa以上3.5kPa以下の圧力をかけて疎水剤を第1突出部頂部11Tにしみ込ませる疎水化処理を行う。これにより、後述する実施例4から9に示すように、液戻り量低減効果を得ることができる。
第1突出部頂部11Tにおいて、疎水部11Dの第1面側Z1の面積St1(図示せず)よりも疎水部11Dの第2面側Z2の面積St2(図示せず)を広くする。それには、疎水剤を図示していないノズルから第1突出部頂部11Tに注入する方式がある。具体的には、ノズルの注入深さを深くし、第2面側Z2側付近から注入する方法などが挙げられる。疎水剤には、例えば疎水油剤を用いる。ノズルの注入深さを変えることによって、疎水部11Dの第1面側Z1の面積St1と疎水部11Dの第2面側Z2の面積St2の面積比率を変更できる。また、ウエブ50に使用する熱可塑性繊維の第2面側Z2の繊度を第1面側Z1の繊度よりも小さくする。このようにして、第2面側Z2の繊維密度を第1面側Z1の繊維密度より高くする。これよっても上記の面積比率の変更を達成できる。これは、第1突出部頂部11Tにしみ込んだ疎水剤が、第1面側Z1よりも第2面側Z2でより大きく拡散するためである。さらに疎水部11Dの疎水面積は、使用状態において、液戻り量が効果的に低減されるように調整されることが好ましい。 Next, the hydrophobization of the
The
The hydrophobizing method is not particularly limited. For example, the hydrophobizing method includes gravure coating and screen coating.
Or it is also possible to employ | adopt the following methods.
A plate having a non-deformable flat coating surface to which a hydrophobic agent has been applied in advance is prepared. The
As described above, a hydrophobization treatment is performed by applying a pressure of 0.5 kPa or more and 3.5 kPa or less to the plate so that the hydrophobic agent is soaked into the first
In the first projecting
上記製造方法は、連続生産を考慮する。その製造装置(図示せず)は、上記支持体110を搬送可能なコンベア式またはドラム式のものがある。その一例として、搬送されてくる凹凸形状を固定されたシートを、ロール(図示せず)で巻き取っていく態様が挙げられる。 The
The manufacturing method considers continuous production. The manufacturing apparatus (not shown) includes a conveyor type or a drum type capable of transporting the
表面シート1には上記実施形態の不織布10が適用される。不織布10の第1突出部11側が肌当接面とされている。 As shown in FIG. 9, the
The
裏面シート2としては、防水性があり透湿性を有していれば特に限定されない。例えば、多孔性フィルムが挙げられる。多孔性フィルムは、疎水性の熱可塑性樹脂と、炭酸カルシウム等からなる微小な無機フィラー又は相溶性のない有機高分子等とを、溶融混練してフィルムを形成する。そしてそのフィルムを一軸又は二軸延伸して得られる。前記熱可塑性樹脂には、ポリオレフィンが挙げられる。ポリオレフィンには、高密度ないし低密度ポリエチレン、線状低密度ポリエチレン、ポリプロピレン、ポリブテン等が挙げられる。そして、これらの熱可塑性樹脂は単独で又は混合して用いることができる。 The
The
また被覆シートは、親水性の部材である。例えば、被覆シートとしては、親水性のティッシュペーパー等の薄手の紙(薄葉紙)、クレープ紙、コットンやレーヨンなどの親水性繊維からなる不織布、合成樹脂の繊維に親水化処理を施してなる不織布、等からなる。不織布には、例えばエアスルー不織布、ポイントボンド不織布、スパンレース不織布、スパンボンド不織布、スパンボンド-メルトブローン-スパンボンド(SMS)不織布等を用いることができる。 As the
The covering sheet is a hydrophilic member. For example, as a covering sheet, thin paper (thin paper) such as hydrophilic tissue paper, crepe paper, non-woven fabric made of hydrophilic fibers such as cotton and rayon, non-woven fabric formed by subjecting synthetic resin fibers to hydrophilic treatment, Etc. As the nonwoven fabric, for example, an air-through nonwoven fabric, a point bond nonwoven fabric, a spunlace nonwoven fabric, a spunbond nonwoven fabric, a spunbond-meltblown-spunbond (SMS) nonwoven fabric, or the like can be used.
<1>シート体の不織布を平面視した側の第1面側に突出し内部空間を有する第1突出部と、
前記第1突出部とは反対側の第2面側に突出し内部空間を有する第2突出部とを有し、
前記第1突出部および前記第2突出部とは該不織布の平面視交差する異なる方向のそれぞれに壁部を介して交互に連続して複数配され、
隣接する前記第1突出部同士、および隣接する前記第2突出部同士は、それぞれ尾根部を介して前記の異なる方向のそれぞれに対して平面視斜め方向に連続して連なった不織布であり、
前記不織布を0.05kPaの圧力で加圧した時に、
前記第1突出部の厚み方向の高さが前記尾根部の厚み方向の高さより高く、
前記第1突出部の壁部の立ち上がり角度が、0°以上20°以下である不織布。
<2>前記第1突出部の壁部の立ち上がり角度は、0°よりも大きく20°以下であることが好ましく、0°よりも大きく15°以下であることがより好ましく、0°よりも大きく12°以下であることがさらに好ましい<1>記載の不織布。
<3>前記壁部を構成する繊維が、前記第1突出部の頂部と前記第1突出部の内部空間の開口部の縁部とを結ぶ方向に繊維配向性を有している<1>または<2>に記載の不織布。
<4>前記壁部を構成する繊維は、前記壁部の起立する方向に繊維配向性を有する<1>から<3>のいずれか1に記載の不織布。
<5>前記壁部を構成する繊維は、前記第1突出部頂部に向かうような放射状の繊維配向性を有している<1>から<4>のいずれか1に記載の不織布。
<6>前記第2突出部の壁部を構成する繊維は、前記第2突出部頂部とその内部空間の開口部の縁部を結ぶ方向に繊維配向性を有する<1>から<5>のいずれか1に記載の不織布。
<7>前記壁部の配向角が50°以上130°以下、配向強度が1.05以上である<1>から<6>のいずれか1に記載の不織布。
<8>前記壁部の配向角が60°以上120°以下、配向強度が1.10以上である<1>から<6>のいずれか1に記載の不織布。
<9>前記壁部の配向角が85°以上95°以下、配向強度が1.30以上である<1>から<6>のいずれか1に記載の不織布。
<10>前記不織布を3.5kPaの圧力で加圧した時に、前記第1突出部の厚み方向の高さが前記尾根部の厚み方向の高さより高い<1>から<9>のいずれか1に記載の不織布。
<11>前記不織布を3.5kPaの圧力で加圧した時の、前記第1突出部の厚み方向の高さh1と前記尾根部の高さh5との比(h1/h5)は、1.01以上であることが好ましく、1.05以上であることがより好ましく、1.2以上であることがさらに好ましく、また上限は、2.5以下であることが好ましく、2.0以下であることがより好ましく、1.8以下であることがさらに好ましい<1>から<10>のいずれか1に記載の不織布。
<12>前記第1突出部は、その厚み方向の高さh1として、その頂部が半球のような丸みを有する円錐よりも壁部の立ち上がり角度が急峻な、前記頂部が半球の一部のような丸みを有する円錐台である<1>から<11>のいずれか1に記載の不織布。
<13>前記第1突出部頂部の親水性が、前記第2突出部頂部および前記壁部よりも低い<1>から<12>のいずれか1に記載の不織布。
<14>前記第1突出部の頂部の親水性が、前記尾根部の親水性よりも低い<1>から<13>のいずれか1に記載の不織布。
<15>前記第1突出部頂部は、22℃におけるイオン交換水の接触角が、80°以上であり、好ましくは100°以上であり、
前記第2突出部頂部及び前記壁部の好ましい接触角は、イオン交換水の接触角が、30°以上80°未満度であり、好ましくは60°以上70°以下である<1>から<14>のいずれか1に記載の不織布。
<16>前記尾根部は、22℃におけるイオン交換水の接触角が、30°以上80°未満度であり、好ましくは60°以上70°以下である<1>から<14>のいずれか1に記載の不織布。
<17>前記第1面側および前記第2面側の両面において、前記第1突出部頂部の親水性が、前記第1突出部頂部を除く部分より低いか、または疎水性を有しており、前記第1突出部頂部における前記第2面側よりも前記第1面側の方が疎水化している面積が小さい<1>から<16>のいずれか1に記載の不織布。
<18>前記異なる2つの方向は直交している<1>から<17>のいずれか1に記載の不織布。
<19>前記壁部は、前記第1突出部及び前記第2突出部において環状構造を成している<1>から<18>のいずれか1に記載の不織布。
<20>前記第1突出部頂部の層厚みTL1、前記第2突出部頂部の層厚みTL2および前記壁部の層厚みTL3は、TL1>TL3>TL2である<1>から<19>のいずれか1に記載の不織布。
<21><1>から<20>のいずれか1に記載の不織布を用いた吸収性物品用の表面シート。
<22><1>から<20>のいずれか1に記載の不織布を、前記第1面側を肌当接面側に向けて用いた吸収性物品用の表面シート。
<23><1>から<20>のいずれか1に記載の不織布を表面シートとして用いた吸収性物品。
<24><1>から<20>のいずれか1に記載の不織布を、前記第1面側を肌当接面側に向けて、表面シートとして用いた吸収性物品。
<25>凹凸形状を有し、加温した支持体に熱可塑性繊維を含有するウエブを搬送し、該ウエブの上から前記支持体に向けて熱風を吹き付けて該ウエブに凹凸形状を賦形する不織布の製造方法であって、
前記ウエブを構成する繊維のガラス転移点以上融点以下の温度範囲に前記支持体を加温する工程と、
第1の熱風の吹き付けにより前記ウエブの繊維同士を前記凹凸形状が保持される状態に仮融着させる工程と、
前記の第1の熱風よりも高温度の第2の熱風を吹き付け、前記凹凸形状を保持した状態で前記ウエブの繊維同士を融着させて前記凹凸形状を固定する工程とを備えた、不織布の製造方法。
<26>前記支持体を加温する温度範囲は、好ましくは繊維のガラス転移点より高い温度以上、融点よりも10℃低い温度以下であり、より好ましくは繊維のガラス転移点より20℃高い温度以上、融点よりも20℃低い温度以下である<25>に記載の不織布の製造方法。
<27>前記支持体の温度は前記第1の熱風を吹き付ける際に前記温度範囲とする<25>または<26>記載の不織布の製造方法。
<28>さらに、前記凹凸形状の凸部となる第1突出部の頂部を疎水化する工程を含む、<25>から<27>のいずれか1に記載の不織布の製造方法。
<29><25>から<28>のいずれか1に記載の不織布の製造方法を用いて製造された不織布。
<30><29>に記載の不織布を用いた吸収性物品用の表面シート。
<31><29>に記載の不織布を表面シートとして用いた吸収性物品。 This invention discloses the manufacturing method of the following nonwoven fabrics, the surface sheet for absorbent articles, an absorbent article, and a nonwoven fabric further regarding embodiment mentioned above.
<1> a first protrusion that protrudes toward the first surface of the sheet body in a plan view and has an internal space;
A second projecting portion projecting on the second surface side opposite to the first projecting portion and having an internal space;
A plurality of the first protrusions and the second protrusions are alternately and continuously arranged through wall portions in different directions intersecting in plan view of the nonwoven fabric,
The adjacent first protrusions and the adjacent second protrusions are nonwoven fabrics that are continuously connected in an oblique direction in plan view with respect to each of the different directions via the ridges, respectively.
When pressurizing the nonwoven fabric at a pressure of 0.05 kPa,
The height in the thickness direction of the first protrusion is higher than the height in the thickness direction of the ridge,
The nonwoven fabric whose rise angle of the wall part of the said 1st protrusion part is 0 degree or more and 20 degrees or less.
<2> The rising angle of the wall portion of the first protrusion is preferably greater than 0 ° and 20 ° or less, more preferably greater than 0 ° and 15 ° or less, and greater than 0 °. The nonwoven fabric according to <1>, more preferably 12 ° or less.
<3> The fibers constituting the wall have fiber orientation in a direction connecting the top of the first protrusion and the edge of the opening of the internal space of the first protrusion <1>. Or the nonwoven fabric as described in <2>.
<4> The nonwoven fabric according to any one of <1> to <3>, wherein the fiber constituting the wall portion has fiber orientation in a direction in which the wall portion stands.
The fiber which comprises the <5> said wall part is a nonwoven fabric any one of <1> to <4> which has radial fiber orientation which goes to the said 1st protrusion part top part.
<6> The fibers constituting the wall of the second protrusion have fiber orientation in the direction connecting the top of the second protrusion and the edge of the opening of the internal space. <1> to <5> The nonwoven fabric of any one.
<7> The nonwoven fabric according to any one of <1> to <6>, wherein the orientation angle of the wall portion is 50 ° to 130 °, and the orientation strength is 1.05 or more.
<8> The nonwoven fabric according to any one of <1> to <6>, wherein the wall has an orientation angle of 60 ° to 120 ° and an orientation strength of 1.10 or more.
<9> The nonwoven fabric according to any one of <1> to <6>, wherein the wall has an orientation angle of 85 ° to 95 ° and an orientation strength of 1.30 or more.
<10> Any one of <1> to <9>, wherein when the nonwoven fabric is pressurized at a pressure of 3.5 kPa, the height in the thickness direction of the first protrusion is higher than the height in the thickness direction of the ridge. The nonwoven fabric described in 1.
<11> The ratio (h1 / h5) between the height h1 in the thickness direction of the first protrusion and the height h5 of the ridge when the nonwoven fabric is pressurized at a pressure of 3.5 kPa is as follows. It is preferably 01 or more, more preferably 1.05 or more, further preferably 1.2 or more, and the upper limit is preferably 2.5 or less, and is 2.0 or less. The nonwoven fabric according to any one of <1> to <10>, more preferably 1.8 or less.
<12> The first projecting portion has a height h1 in the thickness direction, and its top portion has a steeper rising angle than a cone having a round shape like a hemisphere, and the top portion is a part of a hemisphere. The nonwoven fabric according to any one of <1> to <11>, which is a circular truncated cone.
<13> The nonwoven fabric according to any one of <1> to <12>, wherein the hydrophilicity of the top of the first protrusion is lower than that of the second protrusion and the wall.
<14> The nonwoven fabric according to any one of <1> to <13>, wherein the hydrophilicity of the top of the first protrusion is lower than the hydrophilicity of the ridge.
<15> The top of the first protrusion has a contact angle of ion exchange water at 22 ° C. of 80 ° or more, preferably 100 ° or more,
The preferred contact angle between the top of the second protrusion and the wall is such that the contact angle of the ion exchange water is 30 ° or more and less than 80 °, preferably 60 ° or more and 70 ° or less <1> to <14. > Any one of>.
Any one of <1> to <14>, wherein the <16> ridge has a contact angle of ion-exchanged water at 22 ° C. of 30 ° or more and less than 80 °, preferably 60 ° or more and 70 ° or less. The nonwoven fabric described in 1.
<17> On both the first surface side and the second surface side, the hydrophilicity of the top portion of the first protruding portion is lower than the portion excluding the top portion of the first protruding portion, or has hydrophobicity. The non-woven fabric according to any one of <1> to <16>, wherein the area of the first surface side at the top of the first protruding portion is less hydrophobic than the second surface side.
<18> The nonwoven fabric according to any one of <1> to <17>, wherein the two different directions are orthogonal to each other.
<19> The nonwoven fabric according to any one of <1> to <18>, wherein the wall portion forms an annular structure in the first projecting portion and the second projecting portion.
<20> The layer thickness TL1 of the top of the first protrusion, the layer thickness TL2 of the top of the second protrusion, and the layer thickness TL3 of the wall are TL1>TL3> TL2, and any one of <1> to <19> Or the nonwoven fabric according to 1.
<21> A topsheet for an absorbent article using the nonwoven fabric according to any one of <1> to <20>.
<22> A surface sheet for absorbent articles, wherein the nonwoven fabric according to any one of <1> to <20> is used with the first surface side facing the skin contact surface side.
<23> An absorbent article using the nonwoven fabric according to any one of <1> to <20> as a surface sheet.
<24> An absorbent article using the nonwoven fabric according to any one of <1> to <20> as a surface sheet with the first surface side facing the skin contact surface side.
<25> A concavo-convex shape is formed, a web containing thermoplastic fibers is conveyed to a heated support, and hot air is blown from the top of the web toward the support to shape the concavo-convex shape on the web. A method for producing a nonwoven fabric, comprising:
Heating the support to a temperature range from the glass transition point to the melting point of the fibers constituting the web; and
Temporarily fusing the fibers of the web to a state in which the uneven shape is maintained by blowing a first hot air; and
A step of blowing a second hot air having a temperature higher than that of the first hot air, and fixing the uneven shape by fusing the fibers of the web while maintaining the uneven shape. Production method.
<26> The temperature range for heating the support is preferably a temperature higher than the glass transition point of the fiber and 10 ° C. or lower than the melting point, more preferably a temperature 20 ° C. higher than the glass transition point of the fiber. As mentioned above, the manufacturing method of the nonwoven fabric as described in <25> below 20 degrees C lower than melting | fusing point.
<27> The method for producing a nonwoven fabric according to <25> or <26>, wherein the temperature of the support is within the temperature range when the first hot air is blown.
<28> Furthermore, the manufacturing method of the nonwoven fabric any one of <25> to <27> including the process of hydrophobizing the top part of the 1st protrusion part used as the said uneven | corrugated shaped convex part.
<29> A nonwoven fabric produced using the nonwoven fabric production method according to any one of <25> to <28>.
<30> A surface sheet for absorbent articles using the nonwoven fabric according to <29>.
<31> An absorbent article using the nonwoven fabric according to <29> as a surface sheet.
実施例1は、芯がポリエチレンテレフタレート(融点258℃、ガラス転移点67℃)で鞘がポリエチレン(融点135℃、ガラス転移点-20℃)からなる。そして表面が親水化処理されている2.4dtex×51mmの芯鞘型複合繊維を、坪量30g/m2のウエブ50となるようカード機にかけ、このウエブ50を賦形装置に供給した。賦形装置では、多数の突起を有し通気性を有する支持体110の上に上記ウエブ50を定着させた。支持体110は、70℃に加温されている。この支持体110の突起111の平面視におけるMDピッチを8mm、CDピッチを5mmとし、突起111の高さを7.5mmとした。また支持体110における孔112の孔径を2.8mmとした。
次いで、その支持体110上のウエブ50に温度130℃、風速50m/sの第1の熱風W1を吹きつけて、支持体110上の突起111にそってウエブ50を賦形する。次に、温度145℃、風速5m/sの第2の熱風W2に切り替えて吹き付けた。そして各芯鞘構造の繊維同士を融着させて賦形形状を固定した。支持体110は第1の熱風W1を吹き付ける際に70℃に加温されている。このようにして不織布10を作製した。
実施例2は、上記実施例1において支持体110の加温温度を90℃にした以外、実施例1と同様に作製した。
実施例3は、上記実施例1において支持体110の加温温度を110℃にした以外、実施例1と同様に作製した。
実施例4は、実施例1の不織布10を作製し、さらに、上記疎水処理を行った。疎水剤にはKM-903(信越化学工業株式会社製)を用い、その疎水剤をエタノールに溶かし、1.0重量%溶液に調整し、アクリルプレートに4.3mg/cm2で塗工した。プレートに2.0kPaの圧力を10秒かけて、第1突出部頂部11Tに接触させることで、疎水部11Dを作製した。
実施例5は、上記実施例4において支持体110の加温温度を90℃にした以外、実施例4と同様に作製した。
実施例6は、上記実施例4において支持体110の加温温度を110℃にした以外、実施例4と同様に作製した。
実施例7は、上記実施例5において、疎水剤にKF-6011(信越化学工業株式会社製)を用いた以外、実施例5と同様に作製した。
実施例8は、上記実施例5において、ウエブ50を芯鞘型複合繊維2.4dtex×51mmと1.8dtex×51mmの二層品にした以外、実施例5と同様に作製した。
実施例9は、上記実施例8において、プレートにかける圧力を1.5kPaにした以外、実施例8と同様に作製した。 [Example 1-9]
In Example 1, the core is made of polyethylene terephthalate (melting point 258 ° C., glass transition point 67 ° C.) and the sheath is made of polyethylene (melting point 135 ° C., glass transition point −20 ° C.). Then, a 2.4 dtex × 51 mm core-sheath type composite fiber having a hydrophilic surface was applied to a card machine so as to be a
Next, the
Example 2 was produced in the same manner as in Example 1 except that the heating temperature of the
Example 3 was produced in the same manner as in Example 1 except that the heating temperature of the
In Example 4, the
Example 5 was produced in the same manner as in Example 4 except that the heating temperature of the
Example 6 was produced in the same manner as in Example 4 except that the heating temperature of the
Example 7 was prepared in the same manner as in Example 5 except that KF-6011 (manufactured by Shin-Etsu Chemical Co., Ltd.) was used as the hydrophobic agent in Example 5.
Example 8 was prepared in the same manner as in Example 5 except that the
Example 9 was produced in the same manner as in Example 8, except that the pressure applied to the plate in Example 8 was 1.5 kPa.
比較例1は、上記実施例1において支持体110の加温温度を40℃にした以外、実施例1と同様に作製した。
比較例2は、上記実施例4において支持体110の加温温度を40℃にした以外、実施例4と同様に作製した。
比較例3は、上記比較例2の不織布10を作製し、さらに、KM-903(信越化学工業株式会社製)1.0重量%エタノール溶液を壁部、尾根部に刷毛で塗工し、疎水化する以外、実施例2と同様に作製した。 [Comparative Example 1-3]
Comparative Example 1 was produced in the same manner as in Example 1 except that the heating temperature of the
Comparative Example 2 was produced in the same manner as in Example 4 except that the heating temperature of the
In Comparative Example 3, the
<支持体温度測定方法>
賦形装置を停止してから5秒後に接触式温度計を用いて、第1の熱風W1の吹き付け位置の支持体温度を測定した。接触式温度計には、計測器本体にCHINO社製ND500、測定端子にCHINO社製C510-05Kを用いた。3回の温度測定を行い、その平均値を支持体温度とした。 Next, a measurement method and an evaluation method will be described. The following measurement tests were performed using the above-mentioned nonwoven fabric test specimens.
<Support temperature measurement method>
Five seconds after stopping the shaping device, the temperature of the support at the position where the first hot air W1 was sprayed was measured using a contact thermometer. For the contact thermometer, ND500 manufactured by CHINO Co., Ltd. was used for the measuring instrument body, and C510-05K manufactured by CHINO Co., Ltd. was used for the measurement terminal. The temperature was measured three times, and the average value was defined as the support temperature.
日本電子(株)社製の走査電子顕微鏡JCM-5100(商品名)を使用した図1におけるz軸方向が上下となるようにサンプルを静置した。そのサンプルの測定する面に対して垂直の方向から撮影した画像(測定する繊維が10本以上計測できる倍率に調整;100ないし300倍)を印刷した。印刷された繊維画像を、透明PET製シート上からなぞり、この透明PET製シートに繊維画像を写し取った。その透明PET製シートの画像をパソコン内に取り込み、株式会社ネクサス社製のnexusNewQube[商品名](スタンドアロン版)画像処理ソフトウエアを使用し、画像を二値化した。次いで、二値化した画像を、繊維配向解析プログラムである、Fiber Orientation Analysis 8.13 Singleソフト(商品名)を用いて、フーリエ変換し、パワースペクトルを得て、楕円近似した分布図から、配向角と配向強度を得た。
配向角は繊維が最も配向している角度を示している。また、配向強度はその配向角における強度を示している。壁部中間部分の測定においては、配向角が90°に近い値ほど、頂部11Tの中心方向に繊維が配向していることを示している。そして、配向角が60°以上120°以下であれば、頂部11Tの中心方向に繊維が配向していると判断する。
また、配向強度の値が大きいほど繊維の向きがそろっていることを表す。配向強度が1.05以上の場合を配向しているとする。
測定は3ヶ所行い、平均してそのサンプルの配向角と配向強度とした。 <Measurement of fiber orientation (orientation angle, orientation strength)>
Using a scanning electron microscope JCM-5100 (trade name) manufactured by JEOL Ltd., the sample was allowed to stand so that the z-axis direction in FIG. An image taken from a direction perpendicular to the surface to be measured of the sample (adjusted to a magnification capable of measuring 10 or more fibers to be measured; 100 to 300 times) was printed. The printed fiber image was traced from the transparent PET sheet, and the fiber image was copied onto the transparent PET sheet. The image of the transparent PET sheet was taken into a personal computer, and the image was binarized using NexusNewQube [trade name] (stand-alone version) image processing software manufactured by Nexus Corporation. Then, the binarized image is subjected to Fourier transform using Fiber Orientation Analysis 8.13 Single software (trade name), which is a fiber orientation analysis program, to obtain a power spectrum, and from an elliptical distribution map, orientation is obtained. Corners and orientation strength were obtained.
The orientation angle indicates the angle at which the fibers are most oriented. The orientation strength indicates the strength at the orientation angle. In the measurement of the middle portion of the wall portion, it is shown that the fiber is oriented in the central direction of the
Moreover, it represents that the direction of a fiber has gathered, so that the value of orientation strength is large. The case where the orientation strength is 1.05 or more is assumed to be oriented.
Measurement was performed at three locations, and the average was taken as the orientation angle and orientation strength of the sample.
繊維の配向角は、色々な方向性を有する複数の繊維が全体としてどの方向に配向しているかを示す概念である。そして、繊維の集合体の形状を数値化している。繊維の配向強度は、配向角を示す繊維の量を示す概念である。配向強度は、1.05未満では、ほとんど配向していない。1.05以上で配向を有しているといえる。しかしながら、本実施形態においては、繊維配向がその部位によって変化している。すなわち、ある配向角の状態の部位から異なる配向角の部位へと変化する。すなわち、繊維がある方向に配向強度が強い状態から異なる配向に強い強度を示す部位へ変化する。その間に、配向強度が弱い状態に至ることや、再配向することで高い状態へ至る等の様々な状態を有する。そのため、ある強い配向角を示す部位と別の方向に強い配向角を示す部位との間においては、繊維の配向強度が弱くとも繊維の配向角が変わっていることが好ましい。そして配向強度が高いことがより好ましい。配向角、配向強度について本実施形態において一例を示すと、第1突出部11の壁部13の曲面構造に対して配向角は、50°以上130°以下が好ましく、より好ましくは60°以上120°以下である。配向強度は1.05以上が好ましく、より好ましくは1.10以上である。第2突出部12の壁部14は上記壁部13と同様になる。
不織布10を吸収性物品の表面シートとして用いた場合、各々の壁部13の繊維配向性により高加圧下においても不織布10は十分な耐圧縮性を有する。これにより、不織布10の第1突出部11、第2突出部12の潰れを防ぐ。この結果、不織布10は十分な捕捉空間を確保でき、肌との接触面積を小さくする効果がある。また、不織布10は高い通気性を有する。さらに、不織布10は多量の液、固形分、高粘性液体等を十分に捕捉し、漏れを抑制する効果を十分に発揮する。 The fiber orientation described above is a concept consisting of the orientation angle and orientation strength of the fiber.
The fiber orientation angle is a concept indicating in which direction a plurality of fibers having various directions are oriented as a whole. The shape of the fiber aggregate is digitized. The fiber orientation strength is a concept indicating the amount of fiber exhibiting an orientation angle. When the orientation strength is less than 1.05, there is almost no orientation. It can be said that it has an orientation at 1.05 or more. However, in this embodiment, the fiber orientation changes depending on the part. That is, it changes from a part with a certain orientation angle to a part with a different orientation angle. That is, the fiber changes from a state in which the orientation strength is strong in a certain direction to a portion that shows strong strength in a different orientation. In the meantime, it has various states such as a state in which the orientation strength is weak and a state in which the orientation strength is high by reorientation. Therefore, it is preferable that the orientation angle of the fiber is changed between a portion showing a strong orientation angle and a portion showing a strong orientation angle in another direction even if the orientation strength of the fiber is weak. And it is more preferable that orientation strength is high. An example of the orientation angle and orientation strength is shown in this embodiment. The orientation angle is preferably 50 ° or more and 130 ° or less, more preferably 60 ° or more and 120 with respect to the curved surface structure of the
When the
不織布10の切断面を、キーエンス製デジタルマイクロスコープVHX-1000で測定する部位が十分に視野に入り測定できる大きさ(10倍ないし100倍)に拡大する。次いで、0.05kPaの圧力がかかるように重りを不織布10の上に置く。そして、第1突出部11の厚み方向の高さh1と尾根部15の厚み方向の高さh5を測定する。測定は、10回行い、平均値を不織布10の第1突出部頂部11Tの高さh1、尾根部15の高さh5とした。
<3.5kPa圧力時の厚みの測定>
3.5kPa加圧下での第1突出部11Tの高さh1、尾根部15の高さh5の測定方法は、0.05kPa圧力時の厚みの測定方法のおもりを3.5kPaの圧力がかかるように調整する以外は同様に行った。 <Measurement of thickness at 0.05 kPa pressure>
The cut surface of the
<Measurement of thickness at 3.5 kPa pressure>
The measuring method of the height h1 of the first projecting
接触角の具体的な測定方法は以下のように行った。接触角の測定には接触角計を用いる。例えば協和界面科学株式会社製の接触角計MCA-Jを用いる。具体的には、疎水剤が施された不織布10上に、イオン交換水を滴下(約20ピコリットル)した後、直ちに前記接触角計を用いて接触角の測定を行う。測定は、不織布10の5箇所以上の箇所で行い、それらの平均値を接触角とする。測定温度は22℃、測定雰囲気の相対湿度は65%とする。
第1突出部頂部11Tは疎水性であることが好ましく、イオン交換水の接触角は、80°以上であることが好ましい。より好ましくは100°以上である。
第1突出部頂部11Tを除く部分(第2突出部頂部12T、壁部13(14))の好ましい接触角としてイオン交換水の接触角は、30°以上80°未満である。好ましくは60°以上70°以下である。したがって、尾根部15の接触角も上記のような角度とすることが好ましい。具体的には、好ましくは30°以上80°未満であり、より好ましくは60°以上70°以下である。ここで測定する接触角の値が低いほど親水性が高いことになる。 <Measuring method of contact angle CA (°)>
The specific method for measuring the contact angle was as follows. A contact angle meter is used to measure the contact angle. For example, a contact angle meter MCA-J manufactured by Kyowa Interface Science Co., Ltd. is used. Specifically, after ion-exchanged water is dropped (about 20 picoliters) on the
It is preferable that the 1st protrusion part
As a preferred contact angle of the portion excluding the
不織布10の切断面を、キーエンス製デジタルマイクロスコープVHX-1000で測定する部位が十分に視野に入り測定できる大きさ(10倍ないし100倍)に拡大する。そして第1突出部11Tの立ち上がり角度αを測定する。前記図4(b)に示すように、立ち上がり角度αは、以下のように求める。第2突出部12の頂部12Tを結んだ直線Lhに対して垂直な直線Lvを引く。直線Lvと、第2突出部頂部12Tから壁部14にかけて引いた第2面側Z2における不織布(ウエブ50)の接線Ltとのなす角度αを測定する。測定は、10回行い、10回の平均値を不織布10の第1突出部11Tの壁部13(14)の立ち上がり角度αとした。 <Measurement method of rising angle>
The cut surface of the
疎水部11Dの第1面側、第2面側のそれぞれにおいて、0.2mm毎に接触角を測定する。接触角が80°以上になる範囲の面積を0.2mm四方の正方形の数を数えることで測定する。測定結果を、それぞれ疎水部11Dの第1面側の面積St1と第2面側の面積St2とした。 <Measuring method of area of first surface side and area of second surface side of
The contact angle is measured every 0.2 mm on each of the first surface side and the second surface side of the
圧縮回復性は、KES圧縮試験機(カトーテック(株)製KES FB-3)を用いた。通常モードで5.0kPaまでの圧縮特性評価を行い、RC値を読み取った。測定値としては、3点を測定しその平均値を圧縮回復性とした。このKES圧縮試験機は、圧縮部位が面積2cm2の円形平面を持つ板であり、圧縮速度は0.02mm/s、圧縮最大圧力は5.0kPaで、圧縮最大圧力に到達した時点で圧縮方向を反転させ回復過程に移行するものである。上記RC値は、圧縮時のエネルギーに対する回復されるエネルギーの割合を%表示したものである。RC値が大きいほど、圧縮に対する回復性が良く、弾力性があり、クッション性が良いとされる。上記圧縮特性評価におけるRC値は、不織布の試験体に掛かる初期圧力0.05kPaがかかる時間T0から最大圧力5.0kPaがかかる時間Tmまでの圧力の時間積分値を最大圧力5.0kPaまでの仕事量で除し、%で表示したものである。 <Evaluation of compression recovery>
For compression recovery, a KES compression tester (KES FB-3 manufactured by Kato Tech Co., Ltd.) was used. The compression characteristics up to 5.0 kPa were evaluated in the normal mode, and the RC value was read. As measurement values, three points were measured and the average value was defined as compression recovery. This KES compression tester is a plate having a circular plane with an area of 2 cm 2 at the compression site, the compression speed is 0.02 mm / s, the compression maximum pressure is 5.0 kPa, and the compression direction is reached when the compression maximum pressure is reached. Is reversed and the process proceeds to the recovery process. The RC value is a percentage of the recovered energy with respect to the energy during compression. The greater the RC value, the better the recovery from compression, the elasticity, and the better the cushioning. The RC value in the compression characteristic evaluation is the time integral value of the pressure from the time T 0 when the initial pressure applied to the nonwoven fabric specimen is 0.05 kPa to the time T m when the maximum pressure is 5.0 kPa, up to the maximum pressure of 5.0 kPa. Divided by the amount of work and expressed in%.
液戻り量の測定は、評価用の乳幼児用おむつを用いた。それは、吸収性物品100の一例として乳幼児用おむつから表面シートを取り除き、その代わりに不織布10の試験体(以下、不織布試験体という)を用い、その周囲を固定して得た。上記乳幼児用おむつには、花王株式会社製のメリーズさらさらエアスルー(登録商標)Mサイズ、2012年製を用いた。
上記不織布試験体上に3.5kPaの圧力を均等にかけ、試験体のほぼ中央に設置した断面積1000mm2の筒を当て、そこから人口尿を注入した。人工尿としては、生理食塩水を用い、10分ごとに40gずつ4回にわたり、計160gの人工尿を注入した。
注入完了から10分静置した後に、上述の円筒および圧力を取り除いた。そして、アドバンテック社製のろ紙No.5C(100mm×100mm)を20枚重ねた吸収シート(質量=M1)に3.5kPaの圧力がかかるように調整した重りを載せ、それらを、注入点を中心として不織布試験体上に置いた。
5分静置した後に重りを取り除き、ろ紙の質量(M2)を測定した。そして、次式のようにして、液戻り量を算出した。 <Measurement method of liquid return amount>
The liquid return amount was measured using an infant diaper for evaluation. As an example of the
A pressure of 3.5 kPa was applied uniformly on the non-woven fabric test piece, a cylinder having a cross-sectional area of 1000 mm 2 placed at the approximate center of the test piece was applied, and artificial urine was injected therefrom. As the artificial urine, physiological saline was used, and a total of 160 g of artificial urine was infused 4 times by 40 g every 10 minutes.
After standing for 10 minutes from the completion of the injection, the above cylinder and pressure were removed. And filter paper No. made by Advantech Co., Ltd. A weight adjusted so as to apply a pressure of 3.5 kPa was placed on an absorbent sheet (mass = M1) in which 20 sheets of 5C (100 mm × 100 mm) were stacked, and these were placed on a nonwoven fabric specimen around the injection point.
After standing for 5 minutes, the weight was removed, and the mass (M2) of the filter paper was measured. And the liquid return amount was computed like following Formula.
人工尿の液流れは、評価用の乳幼児用おむつを用いた。それに人工尿を供給し、供給した位置から流れ落ちた距離を測定した。
評価用の乳幼児用おむつは、乳幼児用おむつから表面シートを取り除き、その代わりに不織布10の試験体を用い、試験体の周囲を固定して得た。乳幼児用おむつには、花王株式会社製のメリーズさらさらエアスルー(登録商標)Mサイズ、2012年製を用いた。
測定は、平坦なアクリル板を30°の傾斜面が得られるように傾け、その傾斜表面に上記評価用の乳幼児用おむつを貼り付けて3.5kPaで加圧する。その状態で乳幼児用おむつの表面側に配した注入口から人工尿として生理食塩水を乳幼児用おむつに40g注入し、注入口から全ての液が吸収し終わるまでの液流れ量として、注入口から液の下端までの距離を吸収性物品の縦方向(長手方向)で測定した。なお、注入された液が、吸収性物品の縦方向から斜め方向に吸収された場合は、注入口と斜め方向に吸収された液の下端とを吸収性物品の縦方向にそって結んだ最短距離を液流れ長さとした。 <Measurement method of liquid flow length>
For the liquid flow of the artificial urine, an infant diaper for evaluation was used. Artificial urine was supplied to it, and the distance from the supply position was measured.
The baby diaper for evaluation was obtained by removing the top sheet from the baby diaper and using a test body of the
In the measurement, a flat acrylic plate is tilted so that an inclined surface of 30 ° is obtained, and the evaluation diaper for infant is attached to the inclined surface and pressurized at 3.5 kPa. In that state, 40 g of physiological saline as artificial urine is injected into the infant diaper from the inlet arranged on the surface side of the infant diaper, and the amount of liquid flow from the inlet to the end of absorption of all the liquid from the inlet. The distance to the lower end of the liquid was measured in the longitudinal direction (longitudinal direction) of the absorbent article. In addition, when the injected liquid is absorbed obliquely from the longitudinal direction of the absorbent article, the shortest connecting the injection port and the lower end of the liquid absorbed obliquely along the longitudinal direction of the absorbent article The distance was the liquid flow length.
実施例4から9は、液戻り量が0.8g以下であり、液戻り量が少なくなった。これは、上記実施例1から3の効果に加えて、肌当接面側となる第1面側Z1において、第1突出部頂部11Tが疎水性であるために、肌に触れる液の残り量が減少されたためである。かつ吸収体からの溢れた液が第1面側Z1に戻りにくくなったためである。また液流れ長さは、65mm以下であり、少ない液流れになった。これは、支持体110の加温温度が適した範囲であるため、支持体110の形状に沿った賦形ができ、第1突出部11と尾根部15の高さの差が大きくなったことによる。この結果、不織布10の第1面側Z1の液の流れが、第1方向X、第2方向Yに対して斜め方向に液が流れるようになったためである。
一方、比較例1は、支持体110の加温温度が40℃と低いため、支持体110の形状に沿った賦形ができなくなった。このため、立ち上がり角度が30°となり、不織布10が厚み方向に潰れ易くなった。かつ第1突出部頂部11Tに疎水部がないため、液戻り量が1.5gと多くなった。また、第1突出部頂部11Tに疎水部がないため、高荷重下における、第1突出部11の高さh1と尾根部15の高さh5の差によらないため、液流れ量は、58mmと小さくなった。
また、比較例2、比較例3では、液戻り量が1.0g、0.9gとやや少なく、液流れ長さが100mm以上と非常に長くなった。これは、支持体110の加温温度が40℃と低いため、支持体110の形状に沿った賦形ができなくなったためである。また、第1突出部11と尾根部15の高さの差が大きくならなかったためである。この結果、実施例と同様の効果が十分に発揮されなかった結果を示した。
上記したように実施例1から9は液戻り量および表面液流れ長さの両方を低い数値に抑えられていた。したがって、実施例1から9は、比較例1ないし3では達成できない液戻り防止および表面液流れ防止の両立を実現できたことが分かった。 As shown in Table 1 above, in Examples 1 to 9, the thickness of the
In Examples 4 to 9, the liquid return amount was 0.8 g or less, and the liquid return amount decreased. This is because, in addition to the effects of the first to third embodiments, since the first protruding
On the other hand, in Comparative Example 1, since the heating temperature of the
Moreover, in Comparative Example 2 and Comparative Example 3, the liquid return amount was a little as 1.0 g and 0.9 g, and the liquid flow length was very long as 100 mm or more. This is because the heating temperature of the
As described above, in Examples 1 to 9, both the liquid return amount and the surface liquid flow length were suppressed to low values. Therefore, it was found that Examples 1 to 9 were able to achieve both liquid return prevention and surface liquid flow prevention that could not be achieved in Comparative Examples 1 to 3.
2 裏面シート
3 吸収体
4 本体
5 サイドシート
6 ファスニングテープ
7 横漏れ防止ギャザー
10 不織布
11 第1突出部
11D 疎水部
11H 開口部
11K 内部空間
11T 第1突出部頂部
12 第2突出部
12H 開口部
12K 内部空間
12T 第2突出部頂部
13,14 壁部
15 尾根部
16 繊維
50 ウエブ
100 使い捨ておむつ
110 支持体
111 突起
112 孔
W1 第1の熱風
W2 第2の熱風 DESCRIPTION OF
Claims (35)
- 凹凸形状を有し、加温した支持体に熱可塑性繊維を含有するウエブを搬送し、該ウエブの上から前記支持体に向けて熱風を吹き付けて該ウエブに凹凸形状を賦形する不織布の製造方法であって、
前記ウエブを構成する繊維のガラス転移点以上融点以下の温度範囲に前記支持体を加温する工程と、
第1の熱風の吹き付けにより前記ウエブの繊維同士を前記凹凸形状が保持される状態に仮融着させる工程と、
前記第1の熱風よりも高温度の第2の熱風を吹き付け、前記凹凸形状を保持した状態で前記ウエブの繊維同士を融着させて前記凹凸形状を固定する工程とを備えた不織布の製造方法。 Production of a nonwoven fabric having a concavo-convex shape, transporting a web containing thermoplastic fibers to a heated support, and blowing hot air from above the web toward the support to shape the concavo-convex shape on the web A method,
Heating the support to a temperature range from the glass transition point to the melting point of the fibers constituting the web; and
Temporarily fusing the fibers of the web to a state in which the uneven shape is maintained by blowing a first hot air; and
A method for producing a nonwoven fabric, comprising: blowing a second hot air having a temperature higher than that of the first hot air, and fixing the uneven shape by fusing the fibers of the web while maintaining the uneven shape. . - 前記支持体を加温する温度範囲は、繊維のガラス転移点より高い温度以上、融点よりも10℃低い温度以下である請求項1に記載の不織布の製造方法。 The method for producing a nonwoven fabric according to claim 1, wherein the temperature range for heating the support is not less than a temperature higher than the glass transition point of the fiber and not more than 10 ° C lower than the melting point.
- 前記支持体を加温する温度範囲は、繊維のガラス転移点より20℃高い温度以上、融点よりも20℃低い温度以下である請求項1または2に記載の不織布の製造方法。 The method for producing a nonwoven fabric according to claim 1 or 2, wherein the temperature range for heating the support is at least 20 ° C higher than the glass transition point of the fiber and not higher than 20 ° C lower than the melting point.
- 前記支持体の温度は前記第1の熱風を吹き付ける際に前記温度範囲とする請求項1から3のいずれか1項に記載の不織布の製造方法。 The method for producing a nonwoven fabric according to any one of claims 1 to 3, wherein the temperature of the support is within the temperature range when the first hot air is blown.
- 前記凹凸形状の凸部となる第1突出部の頂部を疎水化する工程を含む請求項1から4のいずれか1項に記載の不織布の製造方法。 The manufacturing method of the nonwoven fabric of any one of Claim 1 to 4 including the process of hydrophobizing the top part of the 1st protrusion part used as the said uneven | corrugated shaped convex part.
- 請求項1から5のいずれか1項に記載の不織布の製造方法を用いて製造された不織布。 The nonwoven fabric manufactured using the manufacturing method of the nonwoven fabric of any one of Claim 1 to 5.
- 請求項6に記載の不織布を用いた吸収性物品用の表面シート。 A surface sheet for absorbent articles using the nonwoven fabric according to claim 6.
- 請求項6に記載の不織布を表面シートとして用いた吸収性物品。 An absorbent article using the nonwoven fabric according to claim 6 as a surface sheet.
- シート体の不織布を平面視した側の第1面側に突出し内部空間を有する第1突出部と、
前記第1突出部とは反対側の第2面側に突出し内部空間を有する第2突出部とを有し、
前記第1突出部および前記第2突出部とは該不織布の平面視交差する異なる方向のそれぞれに壁部を介して交互に連続して複数配され、
隣接する前記第1突出部同士、および隣接する前記第2突出部同士は、それぞれ尾根部を介して前記の異なる方向のそれぞれに対して平面視斜め方向に連続して連なった不織布であり、
前記不織布を0.05kPaの圧力で加圧した時に、
前記第1突出部の厚み方向の高さが前記尾根部の厚み方向の高さより高く、
前記第1突出部の壁部の立ち上がり角度が、0°以上20°以下である不織布。 A first projecting portion projecting to the first surface side of the sheet body in a plan view and having an internal space;
A second projecting portion projecting on the second surface side opposite to the first projecting portion and having an internal space;
A plurality of the first protrusions and the second protrusions are alternately and continuously arranged through wall portions in different directions intersecting in plan view of the nonwoven fabric,
The adjacent first protrusions and the adjacent second protrusions are nonwoven fabrics that are continuously connected in an oblique direction in plan view with respect to each of the different directions via the ridges, respectively.
When pressurizing the nonwoven fabric at a pressure of 0.05 kPa,
The height in the thickness direction of the first protrusion is higher than the height in the thickness direction of the ridge,
The nonwoven fabric whose rise angle of the wall part of the said 1st protrusion part is 0 degree or more and 20 degrees or less. - 前記第1突出部の壁部の立ち上がり角度は、0°以上15°以下である請求項9記載の不織布。 The nonwoven fabric according to claim 9, wherein a rising angle of the wall portion of the first protrusion is not less than 0 ° and not more than 15 °.
- 前記第1突出部の壁部の立ち上がり角度は、0°以上12°以下である請求項9記載の不織布。 The nonwoven fabric according to claim 9, wherein the rising angle of the wall portion of the first protrusion is not less than 0 ° and not more than 12 °.
- 前記第1突出部の壁部を構成する繊維が、前記第1突出部の頂部と前記第1突出部の内部空間の開口部の縁部とを結ぶ方向に繊維配向性を有している請求項9から11のいずれか1項に記載の不織布。
The fiber which comprises the wall part of the said 1st protrusion part has fiber orientation in the direction which ties the top part of the said 1st protrusion part, and the edge part of the opening part of the internal space of the said 1st protrusion part. Item 12. The nonwoven fabric according to any one of Items 9 to 11.
- 前記第1突出部の壁部を構成する繊維は、前記壁部の起立する方向に繊維配向性を有する請求項9から12のいずれか1項に記載の不織布。 The non-woven fabric according to any one of claims 9 to 12, wherein the fibers constituting the wall portion of the first protruding portion have fiber orientation in a direction in which the wall portion stands.
- 前記第1突出部の壁部を構成する繊維は、前記第1突出部頂部に向かう放射状の繊維配向性を有する請求項9から13のいずれか1項に記載の不織布。 The nonwoven fabric according to any one of claims 9 to 13, wherein the fibers constituting the wall of the first protrusion have a radial fiber orientation toward the top of the first protrusion.
- 前記第2突出部の壁部を構成する繊維は、前記第2突出部頂部とその内部空間の開口部の縁部を結ぶ方向に繊維配向性を有する請求項9から14のいずれか1項に記載の不織布。 The fiber which comprises the wall part of a said 2nd protrusion part has a fiber orientation in the direction which connects the edge part of the opening part of the said 2nd protrusion part and its internal space in any one of Claim 9 to 14 The nonwoven fabric described.
- 前記第1突出部及び前記第2突出部のそれぞれの壁部の配向角が50°以上130°以下、配向強度が1.05以上である請求項9から15のいずれか1項に記載の不織布。 The nonwoven fabric according to any one of claims 9 to 15, wherein an orientation angle of each wall portion of the first projecting portion and the second projecting portion is 50 ° to 130 °, and an orientation strength is 1.05 or more. .
- 前記第1突出部及び前記第2突出部のそれぞれの壁部の配向角が60°以上120°以下、配向強度が1.10以上である請求項9から15のいずれか1項に記載の不織布。 The nonwoven fabric according to any one of claims 9 to 15, wherein an orientation angle of each wall portion of the first projecting portion and the second projecting portion is 60 ° to 120 °, and an orientation strength is 1.10 or more. .
- 前記第1突出部及び前記第2突出部のそれぞれの壁部の配向角が85°以上95°以下、配向強度が1.30以上である請求項9から15のいずれか1項に記載の不織布。 The nonwoven fabric according to any one of claims 9 to 15, wherein an orientation angle of each wall portion of the first projecting portion and the second projecting portion is 85 ° to 95 ° and an orientation strength is 1.30 or more. .
- 前記不織布を3.5kPaの圧力で加圧した時の、前記第1突出部の厚み方向の高さが前記尾根部の厚み方向の高さより高い請求項9から18のいずれか1項に記載の不織布。
The height of the thickness direction of the said 1st protrusion part when the said nonwoven fabric is pressurized by the pressure of 3.5 kPa is higher than the height of the thickness direction of the said ridge part. Non-woven fabric.
- 前記不織布を3.5kPaの圧力で加圧した時の、前記第1突出部の厚み方向の高さh1と前記尾根部の高さh5との比h1/h5は、1.01以上2.5以下である請求項9から19のいずれか1項に記載の不織布。 The ratio h1 / h5 of the height h1 in the thickness direction of the first protrusion and the height h5 of the ridge when the nonwoven fabric is pressurized at a pressure of 3.5 kPa is 1.01 or more and 2.5. The nonwoven fabric according to any one of claims 9 to 19, which is:
- 前記不織布を3.5kPaの圧力で加圧した時の、前記第1突出部の厚み方向の高さh1と前記尾根部の高さh5との比h1/h5は、1.05以上である2.0以下である請求項9から19のいずれか1項に記載の不織布。 A ratio h1 / h5 of the height h1 in the thickness direction of the first protrusion and the height h5 of the ridge when the nonwoven fabric is pressurized at a pressure of 3.5 kPa is 1.05 or more. The nonwoven fabric according to any one of claims 9 to 19, which is 0.0 or less.
- 前記不織布を3.5kPaの圧力で加圧した時の、前記第1突出部の厚み方向の高さh1と前記尾根部の高さh5との比h1/h5は、1.2以上である1.8以下である請求項9から19のいずれか1項に記載の不織布。 A ratio h1 / h5 between the height h1 in the thickness direction of the first protrusion and the height h5 of the ridge when the nonwoven fabric is pressurized at a pressure of 3.5 kPa is 1.2 or more. 20. The nonwoven fabric according to any one of claims 9 to 19, which is 8 or less.
- 前記第1突出部は、その厚み方向の高さh1として、頂部が半球の丸みを有する円錐よりも壁部の立ち上がり角度が急峻な、前記頂部が半球の一部の丸みを有する円錐台である請求項9から22のいずれか1項に記載の不織布。
The first protrusion is a truncated cone having a height h1 in the thickness direction with a steeper rising angle of the wall than a cone having a hemispherical round at the top, and a portion having a rounded hemisphere at the top. The nonwoven fabric according to any one of claims 9 to 22.
- 前記第1突出部の頂部の親水性が、前記第2突出部の頂部および前記壁部よりも低い請求項9から23のいずれか1項に記載の不織布。 The nonwoven fabric according to any one of claims 9 to 23, wherein the hydrophilicity of the top of the first protrusion is lower than the top of the second protrusion and the wall.
- 前記第1突出部の頂部の親水性が、前記尾根部の親水性よりも低い請求項9から24のいずれか1項に記載の不織布。
The nonwoven fabric according to any one of claims 9 to 24, wherein the hydrophilicity of the top of the first protrusion is lower than the hydrophilicity of the ridge.
- 前記第1突出部頂部は、22℃におけるイオン交換水の接触角が、80°以上であり、前記第2突出部頂部及び前記壁部は、22℃におけるイオン交換水の接触角が、30°以上80°未満である請求項9から25のいずれか1項に記載の不織布。 The contact angle of ion exchange water at 22 ° C. is 80 ° or more at the top of the first protrusion, and the contact angle of ion exchange water at 22 ° C. is 30 ° at the top of the second protrusion and the wall. The nonwoven fabric according to any one of claims 9 to 25, wherein the nonwoven fabric is less than 80 °.
- 前記第1突出部頂部は、22℃におけるイオン交換水の接触角が、100°以上であり、前記第2突出部頂部及び前記壁部は、22℃におけるイオン交換水の接触角が、60°以上70°以下である請求項9から25のいずれか1項に記載の不織布。 The contact angle of ion exchange water at 22 ° C. is 100 ° or more at the top of the first protrusion, and the contact angle of ion exchange water at 22 ° C. is 60 ° at the top of the second protrusion and the wall. The nonwoven fabric according to any one of claims 9 to 25, wherein the nonwoven fabric is 70 ° or more and 70 ° or less.
- 前記尾根部は、22℃におけるイオン交換水の接触角が、30°以上80°未満である請求項9から27のいずれか1項に記載の不織布。 The nonwoven fabric according to any one of claims 9 to 27, wherein the ridge portion has a contact angle of ion exchange water at 22 ° C of 30 ° or more and less than 80 °.
- 前記尾根部は、22℃におけるイオン交換水の接触角が、60°以上70°以下である
請求項9から27のいずれか1項に記載の不織布。 The nonwoven fabric according to any one of claims 9 to 27, wherein a contact angle of the ion exchange water at 22 ° C is 60 ° or more and 70 ° or less. - 前記第1面側および前記第2面側の両面において、前記第1突出部の頂部が、前記第1突出部の頂部を除く部分より親水性が低い、または疎水性を有しており、前記第1突出部の頂部における前記第2面側よりも前記第1面側の方が疎水化している面積が小さい請求項9から29のいずれか1項に記載の不織布。 On both the first surface side and the second surface side, the top of the first protrusion is lower in hydrophilicity or hydrophobic than the portion excluding the top of the first protrusion, 30. The nonwoven fabric according to any one of claims 9 to 29, wherein an area where the first surface side is hydrophobized is smaller than the second surface side at the top portion of the first protrusion.
- 前記異なる2つの方向は直交している請求項9から30のいずれか1項に記載の不織布。 The nonwoven fabric according to any one of claims 9 to 30, wherein the two different directions are orthogonal to each other.
- 前記壁部は、前記第1突出部及び前記第2突出部において環状構造を成している請求項9から31のいずれか1項に記載の不織布。 The non-woven fabric according to any one of claims 9 to 31, wherein the wall portion forms an annular structure in the first projecting portion and the second projecting portion.
- 前記第1突出部頂部の層厚みTL1、前記第2突出部頂部の層厚みTL2および前記壁部の層厚みTL3は、TL1>TL3>TL2である請求項9から32のいずれか1項に記載の不織布。 The layer thickness TL1 of the top of the first protrusion, the layer thickness TL2 of the top of the second protrusion, and the layer thickness TL3 of the wall are TL1> TL3> TL2. Non-woven fabric.
- 請求項9から33のいずれか1項に記載の不織布を、前記第1面側を肌当接面側に向けて用いた吸収性物品用の表面シート。 A top sheet for absorbent articles, wherein the nonwoven fabric according to any one of claims 9 to 33 is used with the first surface side facing the skin contact surface side.
- 請求項9から33のいずれか1項に記載の不織布を、前記第1面側を肌当接面側に向けて、表面シートとして用いた吸収性物品。 An absorbent article using the nonwoven fabric according to any one of claims 9 to 33 as a surface sheet with the first surface side facing the skin contact surface side.
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JP2013132523A (en) * | 2011-12-27 | 2013-07-08 | Kao Corp | Absorptive article |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3636090A4 (en) * | 2017-06-09 | 2021-03-31 | Kao Corporation | Water repellency-imparting fiber article |
Also Published As
Publication number | Publication date |
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TW201527075A (en) | 2015-07-16 |
CN105517523B (en) | 2019-07-09 |
CN105517523A (en) | 2016-04-20 |
JP2015086501A (en) | 2015-05-07 |
JP5925835B2 (en) | 2016-05-25 |
BR112016006662A2 (en) | 2017-08-01 |
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