WO2015026806A1 - System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers - Google Patents

System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers Download PDF

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Publication number
WO2015026806A1
WO2015026806A1 PCT/US2014/051662 US2014051662W WO2015026806A1 WO 2015026806 A1 WO2015026806 A1 WO 2015026806A1 US 2014051662 W US2014051662 W US 2014051662W WO 2015026806 A1 WO2015026806 A1 WO 2015026806A1
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WIPO (PCT)
Prior art keywords
granules
conditioning agent
fertilizer
aqueous conditioning
aqueous
Prior art date
Application number
PCT/US2014/051662
Other languages
French (fr)
Inventor
Timothy Gene HOLT
Bryan Todd BAYLOR
Lauren A. BALABAN
Troy William HOBBS
Kathlene Laurie JACOBSON
Original Assignee
The Mosaic Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP14838566.9A priority Critical patent/EP3036207B1/en
Priority to US14/913,091 priority patent/US10654759B2/en
Priority to JP2016536375A priority patent/JP2016531830A/en
Priority to CA2921846A priority patent/CA2921846C/en
Priority to RU2016109808A priority patent/RU2676734C2/en
Priority to MA38911A priority patent/MA38911B1/en
Priority to EP20199048.8A priority patent/EP3825299A1/en
Application filed by The Mosaic Company filed Critical The Mosaic Company
Priority to ES14838566T priority patent/ES2826200T3/en
Priority to CN202110528917.9A priority patent/CN113200784B/en
Priority to NZ717735A priority patent/NZ717735B2/en
Priority to CN201480057610.3A priority patent/CN105658603B/en
Priority to MX2016002212A priority patent/MX2016002212A/en
Priority to BR112016003586-0A priority patent/BR112016003586B1/en
Priority to AU2014309005A priority patent/AU2014309005A1/en
Publication of WO2015026806A1 publication Critical patent/WO2015026806A1/en
Priority to IL244183A priority patent/IL244183B/en
Priority to PH12016500341A priority patent/PH12016500341A1/en
Priority to AU2019264632A priority patent/AU2019264632B2/en
Priority to US16/878,212 priority patent/US11084762B2/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/20—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for preventing the fertilisers being reduced to powder; Anti-dusting additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B15/00—Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05B—PHOSPHATIC FERTILISERS
    • C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05B—PHOSPHATIC FERTILISERS
    • C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
    • C05B17/02—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal containing manganese
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05B—PHOSPHATIC FERTILISERS
    • C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C1/00—Ammonium nitrate fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C9/00—Fertilisers containing urea or urea compounds
    • C05C9/005—Post-treatment
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00—Fertilisers containing potassium
    • C05D1/005—Fertilisers containing potassium post-treatment
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00—Other inorganic fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00—Other inorganic fertilisers
    • C05D9/02—Other inorganic fertilisers containing trace elements
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00—Other organic fertilisers
    • C05F11/08—Organic fertilisers containing added bacterial cultures, mycelia or the like
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80—Soil conditioners
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00—Fertilisers characterised by their form
    • C05G5/30—Layered or coated, e.g. dust-preventing coatings

Definitions

  • the present invention is directed to a system and related method of reducing dust generated during handling, transporting, and storage of granulated fertilizer. Specifically, the present invention is directed to a system and related method for conditioning the granular fertilizer by a water-based treatment or aqueous conditioning agent for reducing dust generation and/or for the addition of beneficial agricultural, biological, and/or dedusting additives.
  • Agricultural inorganic fertilizers typically include a base comprising at least one of three primary inorganic nutrients - nitrogen (N), phosphate (P), and potassium (K). These fertilizers are identified by their NPK rating in which the N value is the percentage of elemental nitrogen by weight in the fertilizer, and the P and K values represent the amount of oxide in the form of P2O5 and K 2 0 that would be present in the fertilizer if all the elemental phosphorus and potassium were oxidized into these forms.
  • the N-P-K proportions or concentration vary across fertilizer types and user needs.
  • the base fertilizer can comprise a phosphate fertilizer (such as monoammonium phosphate ("MAP"), diammonium phosphate (“DAP”)), a potash fertilizer (such as muriate of potash (“MOP”)) or other potassium-based fertilizer, or a nitrogen-based fertilizer such as a fertilizer containing urea.
  • the fertilizers can also include any combination of secondary nutrients and/or micronutrients.
  • the secondary nutrients can include sulfur compounds, calcium, and/or magnesium, and the micronutrients can include iron, manganese, zinc, copper, boron, molybdenum, and/or chlorine.
  • the micronutrients and/or secondary nutrients can be added to solution in their elemental form, or as compounds, such as a salt.
  • the fertilizer granules are often coated with an anti-dust coating that reduces or entraps the dust created during the granulation or transport.
  • the anti-dust coating can comprise, for example, petroleum, wax, or other oil-based liquids that are sprayed onto the fertilizer granules to adhere any dust particulates formed, during granulation or transport, for example, to the larger fertilizer granules.
  • the coating also encapsulates the dust particulates to prevent or inhibit the dust particulates from becoming airborne.
  • the present invention is directed to a method and related system for conditioning of granular fertilizers post-manufacture to reduce the generation of dust during handling, transport, and storage of the fertilizers, and/or to increase the agricultural benefits of the fertilizer.
  • the method includes introducing a quantity of an aqueous conditioning agent, such as by spraying, to a plurality of fertilizer granules having a surface temperature of about 50°F to about 250°F, and more particularly about 130°F to about 200°F, and a crude moisture content of about 0 to about 6.5 weight percent (wt%), more particularly from about 0.5 wt% to about 3 wt% and more particularly from about 0.5 wt% to about 1.5 wt%, in a conditioning vessel.
  • an aqueous conditioning agent such as by spraying
  • the aqueous conditioning agent can comprise water only or a water-based solution in the form of liquid, steam, and/or superheated steam, and with or without beneficial agricultural and/or dedusting additives.
  • the aqueous conditioning agent is introduced at a temperature of about 32°F to about 800°F depending on the form of the agent, and more particularly from about 70°F to about 170°F when the agent is in the form of water, with or without beneficial agricultural and/or dedusting additives.
  • one or more beneficial agricultural and/or dedusting additives are introduced onto the surface of the granules separate from the aqueous conditioning agent (with or without additives).
  • the one or more additives can be added simultaneously or in series with the aqueous conditioning agent.
  • the aqueous conditioning agent can optionally contain one or more beneficial agricultural and/or dedusting additives, such as, for example, but not limited to, one or more acidifying agents (e.g., but not limited to, citric acid, sulfuric acid, phosphoric acid, sulfamic acid, and combinations thereof), one or more drying agents (e.g., but not limited to, corn starch, and/or wheat starch), and/or one or more chelating agents (e.g., but not limited to, ethylenediaminetetraacetic acid (EDTA), polyethylenimine (PEI)), or combinations thereof, in an amount of about 0.01 wt% to about 99.99 wt% of solution (i.e.
  • one or more acidifying agents e.g., but not limited to, citric acid, sulfuric acid, phosphoric acid, sulfamic acid, and combinations thereof
  • drying agents e.g., but not limited to, corn starch, and/or wheat starch
  • weight of solute/weight of solution and more particularly from about 0.01 wt% to about 20wt% of solution for certain applications, from about 20 wt% to about 50 wt% of solution for other applications, and from about 50 wt% to about 99.99 wt% for yet other applications.
  • the aqueous conditioning agent can contain one or more beneficial agricultural additives selected from one or any combination of secondary nutrients and/or micronutrients in an amount of about 0.01 wt% to about 99.99 wt% of solution, and more particularly from about 20 wt% to about 50 wt% of solution.
  • the secondary nutrients can include sulfur compounds, calcium, and/or magnesium
  • the micronutrients can include iron, manganese, zinc, copper, boron, molybdenum, and/or chlorine.
  • the micronutrients and/or secondary nutrients can be added to solution in their elemental form, or as compounds, such as a salt.
  • the aqueous conditioning agent can contain one or more beneficial agricultural additives selected from one or any combination of herbicides and/or pesticides.
  • aqueous conditioning agent can comprise one or more beneficial agricultural additives selected from one or any combination of biological material.
  • biological materials can comprise, for example, one or more biological chemicals, plant and other extracts, microbial agents, and/or other living organisms.
  • the biological material can comprise microorganisms, including, but not limited to, bacteria such as Bacillus, Rhizobium, Azobacter, and Azospirillum, fungi such as Aspergillus, Mycorhizzae, Beauveria, Metarhizium, and Trichoderma, and/or yeast such as Saccharomyces, Schizosaccharomyces, Sporobolomyces, Candida, Trichosporon, and Rhodosporidium.
  • bacteria such as Bacillus, Rhizobium, Azobacter, and Azospirillum
  • fungi such as Aspergillus, Mycorhizzae, Beauveria, Metarhizium, and Trichoderma
  • yeast such as Saccharomyces, Schizosaccharomyces, Sporobolomyces, Candida, Trichosporon, and Rhodosporidium.
  • the aqueous conditioning agent can comprise biological materials that are small molecule and peptide -based compositions such as, but not limited to, metabolites, peptides, lipopetides, hormones, peptide hormones, siderophores, glycopepetides, humates, surfactants, vitamins, enzymes, amino acids and amino acid derivatives, and nucleic acids and nucleic acid derivatives.
  • biologicals included in embodiments of the aqueous conditioning agent can be applied to fertilizers or fertilizer granules at a final concentration of about 10 3 to about 10 12 CFU (colony forming units)/g, and more particularly about 10 6 to about 10 9 CFU/g. Biologicals applied accordingly have the potential to enhance the growth and development of plants as well as treat plant diseases.
  • the granules with aqueous conditioning agent(s) applied thereto are then optionally subjected to a mechanical energy exposure, such as in the form of tumbling or mixing, in the conditioning vessel to induce desired particle interactions between particles.
  • a mechanical energy exposure such as in the form of tumbling or mixing
  • the granules and the aqueous conditioning agent are introduced into a fluidized bed reactor such that the surface of each individual granule is subjected to surface conditioning described above, without necessarily being subjected to particle to particle interaction or mechanical energy exposure.
  • the granules are exposed to a combination of particle to particle interactions (e.g. tumbling or mixing) and introduced into a fluidized bed reactor in either order, or in any combination.
  • the added moisture from the aqueous conditioning agent is removed from the granules either naturally or with the application of energy. This can be accomplished in the conditioning vessel itself either during the optional tumbling and/or after tumbling of the granules.
  • the drying can be done by drying via a dry airstream (heated or non-heated) such as a fugitive dust air stream for removal of water vapor, dust, and air, a heated dryer such as a blower, until a final moisture content of about 0 wt% to about 6.5 wt% of the granules is achieved, more particularly from about 0.5 wt% to about 3.0 wt, and even more particularly from about 0.5 wt% to about 1.5 wt%, resulting in conditioned fertilizer granules.
  • a dry airstream such as a fugitive dust air stream for removal of water vapor, dust, and air
  • a heated dryer such as a blower
  • the conditioning process can be placed in-line after granulation and/or drying of the fertilizer granules, or at a remote location, i.e. off-line.
  • the conditioning process can be achieved in a warehouse, separate processing facility, at a transportation site, or any of a variety of locations.
  • the conditioning of the granular fertilizers by water treatment allows for the reduction in application of dust control agents, such as the oil-based coatings described above, thereby reducing raw material costs. Also, reduction in dust generated during distribution from the manufacturer to the grower results in improved industrial hygiene for the manufacturers, transporters, customers, and/or customer employees, thereby reducing the costs and equipment otherwise needed to mitigate potential industrial hygiene issues. Finally, when beneficial agricultural additives are incorporated, the conditioned granules can have increased agricultural benefits compared to unconditioned granules.
  • the conditioning methods and systems described above are not limited to the treatment of fertilizer granules.
  • the methods and systems according to embodiments can be used on any granular or particular material that has the propensity to produce unwanted or fugitive dust.
  • Other uses can include, for example, the conditioning of coal, feed products such as feed supplements or pellets, food processing, mining operations including ores and tailings, cured or dried cement, dirt, gravel or sand, waste, asbestos, or any of variety of uses.
  • Figure 1 is a process flow diagram of a conditioning method according to an embodiment of the invention.
  • a non-limiting exemplary embodiment of a system and method for conditioning fertilizer granules for improved dust control and/or agricultural benefits generally includes the supply of a plurality of fertilizer granules at 102.
  • the fertilizer granules can be unconditioned or can be previously condition in which additional conditioning is desired or required.
  • the granules are not limited to fertilizer granules, and can comprise any of a variety of granular or particular materials.
  • the fertilizer granules can be any of a number of fertilizer types including, but not limited to inorgranic including nitrogen-based (e.g. ammonium nitrate or urea), phosphorous-based (e.g. phosphate fertilizers including mono-ammonium and di-ammonium phosphates), potassium-based (e.g. potash or muriate of potash) fertilizers, and any of a variety of N-P-K compound fertilizers, with or without secondary nutrients such as sulfur or sulfur compounds, calcium, and magnesium, and/or micronutrients such as iron, manganese, zinc, copper, boron, molybdenum, and chlorine.
  • nitrogen-based e.g. ammonium nitrate or urea
  • phosphorous-based e.g. phosphate fertilizers including mono-ammonium and di-ammonium phosphates
  • potassium-based (e.g. potash or muriate of potash) fertilizers e.g. potash or muri
  • the fertilizer granules are formed using the granulation methods described in U.S. Patent No. 6,544,313 entitled “Sulfur- Containing Fertilizer Composition and Method for Preparing Same," incorporated herein by reference in its entirety.
  • the fertilizer granules are formed using the granulation methods described in U.S. Patent No. 7,497,891 entitled “Method For Producing A Fertilizer With Micronutrients,” incorporated herein by reference in its entirety.
  • heat and/or air 104 may be necessary or desired.
  • IR heat, gas fired heat, or any of a variety of heat sources can be applied to the plurality of fertilizer granules to dry and/or heat the granules to the target surface temperature and/or moisture content before application of an aqueous conditioning agent at 108.
  • the target surface temperature of the granules is approximately about 50°F to about 250°F, and more particularly about 130°F to about 200°F, and the target moisture content is about 0 to about 6.5 weight percent (wt%), more particularly from about 0.5 wt% to about 3 wt% and more particularly from about 0.5 wt% to about 1.5 wt%
  • the conditioning vessel includes one or more sprayers or nozzles for the spray application of one or more aqueous conditioning agents at 108, with or without beneficial agricultural and/or dedusting additives.
  • the aqueous conditioning agent can comprise water or a water-based solution, in the form of liquid, steam, and/or superheated steam, and with or without beneficial agricultural and/or dedusting additives.
  • the aqueous conditioning agent is introduced at a temperature of about 32°F to about 800°F depending on the form of the agent, and more particularly from about 70°F to about 170°F when the agent is in the form of liquid water or a water-based solution, with or without beneficial agricultural and/or dedusting additives.
  • the aqueous conditioning agent can optionally contain one or more beneficial agricultural and/or dedusting additives, such as, for example, acidifying agents, drying agents, chelating agents, micronutrients, secondary nutrients, biological materials, pesticides and herbicides.
  • Acidifying agents can include, but are not limited to, citric acid, sulfuric acid, phosphoric acid, sulfamic acid, and combinations thereof.
  • Drying agents can include, but are not limited to, corn starch, and/or wheat starch.
  • Chelating agents can include, but are not limited to, ethylenediaminetetraacetic acid (EDTA), polyethylenimine (PEI), or combinations thereof.
  • any of the agents can be added in an amount of about 0.01 wt% to about 99.99 wt% of solution, and more particularly from about 0.01 wt% to about 20 wt% of solution for certain applications, from about 20 wt% to about 50 wt% of solution for other applications, and from about 50 wt% to about 99.99wt% for yet other applications.
  • the aqueous conditioning agent can contain one or more beneficial agricultural additives selected from one or any combination of secondary nutrients and/or micronutrients in an amount of about 0.01 wt% to about 99.99 wt% of solution, and more particularly from about 20 wt% to about 50 wt% of solution.
  • the secondary nutrients can include, for example, sulfur compounds, calcium, and/or magnesium
  • the micronutrients can include, for example, iron, manganese, zinc, copper, boron, molybdenum, and/or chlorine.
  • the aqueous conditioning agent can contain one or more beneficial agricultural additives selected from one or any combination of biological material.
  • biological material or “biologicals,” can comprise microorganisms, including, but not limited to, bacteria such as Bacillus, Rhizobium, Azobacter, and Azospirillum, fungi such as Aspergillus, Mycorhizzae, Beauveria, Metarhizium, and Trichoderma, and/or yeast such as Saccharomyces, Schizosaccharomyces, Sporobolomyces, Candida, Trichosporon, and Rhodosporidium.
  • bacteria such as Bacillus, Rhizobium, Azobacter, and Azospirillum
  • fungi such as Aspergillus, Mycorhizzae, Beauveria, Metarhizium, and Trichoderma
  • yeast such as Saccharomyces, Schizosaccharomyces, Sporobolomyces, Candida, Trichosporon, and Rhodosporidium.
  • the aqueous conditioning agent can comprise biologicals that are not microorganisms, including, but not limited to, small molecule and peptide -based compositions such as metabolites, peptides, lipopetides, hormones, peptide hormones, siderophores, glycopepetides, humates, surfactants, vitamins, enzymes, amino acids and amino acid derivatives, and nucleic acids and nucleic acid derivatives.
  • biologicals that are not microorganisms, including, but not limited to, small molecule and peptide -based compositions such as metabolites, peptides, lipopetides, hormones, peptide hormones, siderophores, glycopepetides, humates, surfactants, vitamins, enzymes, amino acids and amino acid derivatives, and nucleic acids and nucleic acid derivatives.
  • biologicals included in embodiments of the aqueous conditioning agent can be applied to fertilizers or fertilizer granules at a final concentration of about 10 to about 10 12 CFU (colony forming units)/g, and more particularly about 10 6 to about 10 9 CFU/g 10 6 to about 10 9 CFU.
  • 4.1 mis of an aqueous solution comprising biologicals can be added to 1 lb of fertilizer, or about 10 12 to about 10 15 CFU/L can be added to liquid fertilizer to achieve the above target concentration.
  • biologicals included in embodiments of the aqueous conditioning agent can be applied at temperatures ranging from about 70°F to about 210°F, or more particularly, from about 70°F to about 180°F, or more particularly, from about 70°F to about 160°F.
  • Biologicals applied accordingly have the potential to enhance the growth and development of plants as well as treat plant diseases.
  • one or more of the beneficial agricultural and/or dedusting additives described above are optionally introduced at 11 1 onto the surface of the granules separate from the aqueous conditioning agent (with or without additives).
  • the one or more beneficial agricultural and/or dedusting additives can be added simultaneously or in series with (e.g. upstream and/or downstream from) the aqueous conditioning agent, such as by spraying, in conditioning vessel 106.
  • the aqueous conditioning agent is added at 108 in an amount of about 0.1 to about 10 wt% of the total weight of the fertilizer, and more particularly from about 2.0 to about 4.0 wt% of the total weight of the fertilizer.
  • aqueous conditioning agent at a rate of about 0 to about 22 gallons per ton of granular fertilizer, and more particularly about 5-10 gallons per ton of granular fertilizer, depending on the composition or concentration of the aqueous conditioning agent, and the desired amount of aqueous conditioning agent per granule.
  • the granules are optionally subjected to mechanical energy at 110 in the form of agitation, such as shaking and/or tumbling, within the conditioning vessel 106 to promote or induce mechanical interaction between granules.
  • the conditioning vessel can further optionally include mixing equipment such as, a ribbon blender, paddle mixer, baffles, and/or can comprise a rotating drum such that the application of the aqueous conditioning agent is spread evenly over the granules, and to further induce mechanical interaction between the granules.
  • the granules and the aqueous conditioning agent are introduced into a fluidized bed reactor such that surfaces of the granules are subjected to surface conditioning described above, without necessarily being subjected to particle to particle interaction or mechanical energy exposure.
  • one or more beneficial agricultural and/or dedusting additives can be added to the fluidized bed separately from the aqueous conditioning agent (with or without additives).
  • the extra moisture from the application of the aqueous conditioning agent is removed at 112.
  • removal of the moisture at 112 can be accomplished without additional equipment and/or processing. For example, a previously established airflow, such as a ventilation means or duct for removing fugitive dust, water vapor, or other ventilation such as a fluid bed dryer, moves air that is sufficiently dry through vessel 106 to remove the added moisture.
  • one or more gases are supplied to or moved through the vessel at 114 to remove the added moisture from the granules.
  • the one or more gases can be, for example, recycled and/or fresh air, and/or an inert gas such as argon or nitrogen.
  • the gas can be completely dry, or have a low or negligible moisture content.
  • the gas includes one or more beneficial agricultural and/or dedusting additives or agents as described above for application to the granule surface.
  • the latent heat of the fertilizer granules is sufficient to dry the granules by evaporation of the moisture to the surrounding atmosphere of the vessel 106.
  • the air of the vessel 106 is removed and replaced as needed.
  • the granules are subjected to the application of dry air and/or heat in a separate drying vessel (not shown), such as a fluid bed dryer.
  • the added moisture is removed until a final moisture content of about 0 to about 6.5 weight percent (wt%), more particularly from about 0.5 wt% to about 3 wt% and more particularly from about 0.5 wt% to about 1.5 wt% of the granules is achieved, resulting in conditioned fertilizer granules.
  • the conditioned fertilizer granules are removed at 116 are then shipped to storage and/or end-use customers, or are reconditioned or further conditioned or processed as desired.
  • the conditioning of the granular fertilizers by water treatment allows for the reduction in application of dust control agents, such as the oil-based coatings, thereby reducing raw material costs and/or manufacturing costs. Also, reduction in dust generated during distribution from the manufacturer to the grower results in improved industrial hygiene for the manufacturers, transporters, customers, and/or customer employees, thereby reducing the costs and equipment otherwise needed to mitigate industrial hygiene issues.
  • dust control agents such as the oil-based coatings
  • Table 1 lists breakage results comparing conditioned fertilizer granules conditioned with an aqueous conditioning agent in the form of water in weight percent to unconditioned fertilizer granules.
  • the base fertilizer was monoammonium phosphate and the breakage was measured.
  • an accelerated performance measurement procedure used to measure this data consists of the following steps: (1) Initially untreated fertilizer granules are split (with a riffler) to maintain comparable fractions; (2) The baseline granules are not treated with an aqueous conditioning agent while the remaining granules coated with different experimental treatments of different amounts of aqueous conditioning agent; (3) The coated samples are stored under controlled environmental conditions reflecting potential product transportation and storage conditions; and (4) The effectiveness of dust control is measured after several (2, 4, 6, 8) weeks. To measure effectiveness of dust control, samples are removed from the environmental chamber and exposed to a controlled energy input to simulate product handling. Dust sized particles from each sample are then extracted and the dust level is determined by mass difference. The reduction percentage is calculated as a percent change (in this case reduction) from the dust generation of the baseline samples. Table 1: Breaka e results
  • such surface treatments and/or incorporation of additives or agents by the above methods may result in reduced caking tendencies by means of inhibiting chemical and/or physical interactions between granules in storage, during transport, or otherwise.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Biochemistry (AREA)
  • Plant Pathology (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)

Abstract

Methods and related systems for conditioning of granular fertilizers post-manufacture to reduce the generation of dust during handling, transport, and storage of the fertilizers, and/or to increase the agricultural benefits of the fertilizer. The method includes introducing a quantity of an aqueous conditioning agent, such as by spraying, to a plurality of fertilizer granules. The aqueous conditioning agent can include one or more beneficial agricultural and/or dedusting additives including one or more acidifying agents, one or more drying agents, one or more herbicides and/or pesticides, one or more chelating agents, one or more biological agents, and combinations thereof.

Description

SYSTEM AND METHODS FOR ADDITION OF BENEFICIAL AGRICULTURAL, BIOLOGICAL, AND/OR DEDUSTING ADDITIVES TO GRANULAR FERTILIZERS
RELATED APPLICATIONS
The present application claims the benefit of U.S. Provisional Application No. 61/867,334 filed August 19, 2013, and U.S. Provisional Application No. 61/968,328 filed March 20, 2014, each of which is incorporated herein in its entirety by reference.
FIELD OF THE INVENTION
The present invention is directed to a system and related method of reducing dust generated during handling, transporting, and storage of granulated fertilizer. Specifically, the present invention is directed to a system and related method for conditioning the granular fertilizer by a water-based treatment or aqueous conditioning agent for reducing dust generation and/or for the addition of beneficial agricultural, biological, and/or dedusting additives.
BACKGROUND OF THE INVENTION
Agricultural inorganic fertilizers typically include a base comprising at least one of three primary inorganic nutrients - nitrogen (N), phosphate (P), and potassium (K). These fertilizers are identified by their NPK rating in which the N value is the percentage of elemental nitrogen by weight in the fertilizer, and the P and K values represent the amount of oxide in the form of P2O5 and K20 that would be present in the fertilizer if all the elemental phosphorus and potassium were oxidized into these forms. The N-P-K proportions or concentration vary across fertilizer types and user needs.
For example, the base fertilizer can comprise a phosphate fertilizer (such as monoammonium phosphate ("MAP"), diammonium phosphate ("DAP")), a potash fertilizer (such as muriate of potash ("MOP")) or other potassium-based fertilizer, or a nitrogen-based fertilizer such as a fertilizer containing urea. The fertilizers can also include any combination of secondary nutrients and/or micronutrients. The secondary nutrients can include sulfur compounds, calcium, and/or magnesium, and the micronutrients can include iron, manganese, zinc, copper, boron, molybdenum, and/or chlorine. The micronutrients and/or secondary nutrients can be added to solution in their elemental form, or as compounds, such as a salt.
Many of these agricultural fertilizers are granulated, dried, and treated with dust control agents after formulation to provide the fertilizer in a stable and easily handled form. An inherent drawback of the conventional granulation process is that a significant portion of the fertilizer may generate dust particulates either during manufacture, storage, or in distribution, which is significantly more difficult to handle and distribute on the fields to be treated. In addition to wasting otherwise useful fertilizer, the fertilizer may create undesirable fugitive particle emissions. Fugitive particulate emissions can be mitigated, but in certain conditions mitigation costs can become uneconomical.
To reduce the dust generation, the fertilizer granules are often coated with an anti-dust coating that reduces or entraps the dust created during the granulation or transport. The anti-dust coating can comprise, for example, petroleum, wax, or other oil-based liquids that are sprayed onto the fertilizer granules to adhere any dust particulates formed, during granulation or transport, for example, to the larger fertilizer granules. The coating also encapsulates the dust particulates to prevent or inhibit the dust particulates from becoming airborne.
While traditional coatings are effective at controlling the dust particulates, the inherent drawback of these coatings is that the coatings have a limited effective shelf-life and can have diminishing effectiveness as the coating ages. Prolonged storage or transport of the coated fertilizer can present a greater safety risk as the storage or transport time may have exceeded the effective life of the coating resulting in unsafe fertilizer products, and/or undesirable flow characteristics in storage bins, transportation equipment, and field application equipment. Furthermore, these traditional coatings can potentially add significant cost to the end-product due to the cost of the coating composition and/or increased manufacturing costs. Alternative de- dusting agents with extended shelf life are commercially available but these products tend to have substantially higher cost and for this reason have not been broadly adopted by the industry.
As such, there is a need for a means of efficiently and effectively reducing dust generated during the handling of granular fertilizers and/or to increase the agricultural benefits of the fertilizer.
SUMMARY OF THE INVENTION
The present invention is directed to a method and related system for conditioning of granular fertilizers post-manufacture to reduce the generation of dust during handling, transport, and storage of the fertilizers, and/or to increase the agricultural benefits of the fertilizer. The method includes introducing a quantity of an aqueous conditioning agent, such as by spraying, to a plurality of fertilizer granules having a surface temperature of about 50°F to about 250°F, and more particularly about 130°F to about 200°F, and a crude moisture content of about 0 to about 6.5 weight percent (wt%), more particularly from about 0.5 wt% to about 3 wt% and more particularly from about 0.5 wt% to about 1.5 wt%, in a conditioning vessel. The aqueous conditioning agent can comprise water only or a water-based solution in the form of liquid, steam, and/or superheated steam, and with or without beneficial agricultural and/or dedusting additives. The aqueous conditioning agent is introduced at a temperature of about 32°F to about 800°F depending on the form of the agent, and more particularly from about 70°F to about 170°F when the agent is in the form of water, with or without beneficial agricultural and/or dedusting additives.
Alternatively, one or more beneficial agricultural and/or dedusting additives are introduced onto the surface of the granules separate from the aqueous conditioning agent (with or without additives). The one or more additives can be added simultaneously or in series with the aqueous conditioning agent.
As mentioned above, the aqueous conditioning agent can optionally contain one or more beneficial agricultural and/or dedusting additives, such as, for example, but not limited to, one or more acidifying agents (e.g., but not limited to, citric acid, sulfuric acid, phosphoric acid, sulfamic acid, and combinations thereof), one or more drying agents (e.g., but not limited to, corn starch, and/or wheat starch), and/or one or more chelating agents (e.g., but not limited to, ethylenediaminetetraacetic acid (EDTA), polyethylenimine (PEI)), or combinations thereof, in an amount of about 0.01 wt% to about 99.99 wt% of solution (i.e. weight of solute/weight of solution), and more particularly from about 0.01 wt% to about 20wt% of solution for certain applications, from about 20 wt% to about 50 wt% of solution for other applications, and from about 50 wt% to about 99.99 wt% for yet other applications.
In an alternative embodiment of the invention, in addition to or as an alternative to the additives listed above, the aqueous conditioning agent can contain one or more beneficial agricultural additives selected from one or any combination of secondary nutrients and/or micronutrients in an amount of about 0.01 wt% to about 99.99 wt% of solution, and more particularly from about 20 wt% to about 50 wt% of solution. The secondary nutrients can include sulfur compounds, calcium, and/or magnesium, and the micronutrients can include iron, manganese, zinc, copper, boron, molybdenum, and/or chlorine. The micronutrients and/or secondary nutrients can be added to solution in their elemental form, or as compounds, such as a salt.
In yet other embodiments, in addition to or as an alternative to the additives listed above, the aqueous conditioning agent can contain one or more beneficial agricultural additives selected from one or any combination of herbicides and/or pesticides.
In addition to or as an alternative to the additives listed above, other embodiments of the aqueous conditioning agent can comprise one or more beneficial agricultural additives selected from one or any combination of biological material. In some aspects, the biological materials, or "biologicals," can comprise, for example, one or more biological chemicals, plant and other extracts, microbial agents, and/or other living organisms. In some embodiments, the biological material can comprise microorganisms, including, but not limited to, bacteria such as Bacillus, Rhizobium, Azobacter, and Azospirillum, fungi such as Aspergillus, Mycorhizzae, Beauveria, Metarhizium, and Trichoderma, and/or yeast such as Saccharomyces, Schizosaccharomyces, Sporobolomyces, Candida, Trichosporon, and Rhodosporidium. In other cases, the aqueous conditioning agent can comprise biological materials that are small molecule and peptide -based compositions such as, but not limited to, metabolites, peptides, lipopetides, hormones, peptide hormones, siderophores, glycopepetides, humates, surfactants, vitamins, enzymes, amino acids and amino acid derivatives, and nucleic acids and nucleic acid derivatives. In some embodiments, biologicals included in embodiments of the aqueous conditioning agent can be applied to fertilizers or fertilizer granules at a final concentration of about 103 to about 1012 CFU (colony forming units)/g, and more particularly about 106 to about 109 CFU/g. Biologicals applied accordingly have the potential to enhance the growth and development of plants as well as treat plant diseases.
The granules with aqueous conditioning agent(s) applied thereto are then optionally subjected to a mechanical energy exposure, such as in the form of tumbling or mixing, in the conditioning vessel to induce desired particle interactions between particles. In an alternative embodiment, the granules and the aqueous conditioning agent are introduced into a fluidized bed reactor such that the surface of each individual granule is subjected to surface conditioning described above, without necessarily being subjected to particle to particle interaction or mechanical energy exposure. In yet another alternative embodiment, the granules are exposed to a combination of particle to particle interactions (e.g. tumbling or mixing) and introduced into a fluidized bed reactor in either order, or in any combination.
The added moisture from the aqueous conditioning agent is removed from the granules either naturally or with the application of energy. This can be accomplished in the conditioning vessel itself either during the optional tumbling and/or after tumbling of the granules. The drying can be done by drying via a dry airstream (heated or non-heated) such as a fugitive dust air stream for removal of water vapor, dust, and air, a heated dryer such as a blower, until a final moisture content of about 0 wt% to about 6.5 wt% of the granules is achieved, more particularly from about 0.5 wt% to about 3.0 wt, and even more particularly from about 0.5 wt% to about 1.5 wt%, resulting in conditioned fertilizer granules.
The conditioning process can be placed in-line after granulation and/or drying of the fertilizer granules, or at a remote location, i.e. off-line. For example, the conditioning process can be achieved in a warehouse, separate processing facility, at a transportation site, or any of a variety of locations.
The conditioning of the granular fertilizers by water treatment allows for the reduction in application of dust control agents, such as the oil-based coatings described above, thereby reducing raw material costs. Also, reduction in dust generated during distribution from the manufacturer to the grower results in improved industrial hygiene for the manufacturers, transporters, customers, and/or customer employees, thereby reducing the costs and equipment otherwise needed to mitigate potential industrial hygiene issues. Finally, when beneficial agricultural additives are incorporated, the conditioned granules can have increased agricultural benefits compared to unconditioned granules.
The conditioning methods and systems described above are not limited to the treatment of fertilizer granules. The methods and systems according to embodiments can be used on any granular or particular material that has the propensity to produce unwanted or fugitive dust. Other uses can include, for example, the conditioning of coal, feed products such as feed supplements or pellets, food processing, mining operations including ores and tailings, cured or dried cement, dirt, gravel or sand, waste, asbestos, or any of variety of uses.
The above summary of the various representative embodiments of the invention is not intended to describe each illustrated embodiment or every implementation of the invention. Rather, the embodiments are chosen and described so that others skilled in the art can appreciate and understand the principles and practices of the invention. The figures in the detailed description that follow more particularly exemplify these embodiments. BRIEF DESCRIPTION OF THE FIGURES
Figure 1 is a process flow diagram of a conditioning method according to an embodiment of the invention.
DETAILED DESCRIPTION OF THE DRAWINGS Referring to Figure 1, a non-limiting exemplary embodiment of a system and method for conditioning fertilizer granules for improved dust control and/or agricultural benefits generally includes the supply of a plurality of fertilizer granules at 102. The fertilizer granules can be unconditioned or can be previously condition in which additional conditioning is desired or required. The granules are not limited to fertilizer granules, and can comprise any of a variety of granular or particular materials.
In this non-limiting embodiment, the fertilizer granules can be any of a number of fertilizer types including, but not limited to inorgranic including nitrogen-based (e.g. ammonium nitrate or urea), phosphorous-based (e.g. phosphate fertilizers including mono-ammonium and di-ammonium phosphates), potassium-based (e.g. potash or muriate of potash) fertilizers, and any of a variety of N-P-K compound fertilizers, with or without secondary nutrients such as sulfur or sulfur compounds, calcium, and magnesium, and/or micronutrients such as iron, manganese, zinc, copper, boron, molybdenum, and chlorine. In one non-limiting embodiment, the fertilizer granules are formed using the granulation methods described in U.S. Patent No. 6,544,313 entitled "Sulfur- Containing Fertilizer Composition and Method for Preparing Same," incorporated herein by reference in its entirety. In another non-limiting embodiment, the fertilizer granules are formed using the granulation methods described in U.S. Patent No. 7,497,891 entitled "Method For Producing A Fertilizer With Micronutrients," incorporated herein by reference in its entirety.
Depending on the desired temperature and moisture content of the fertilizer granules before application of the aqueous conditioning agent, optional application of heat and/or air 104 may be necessary or desired. For example, IR heat, gas fired heat, or any of a variety of heat sources can be applied to the plurality of fertilizer granules to dry and/or heat the granules to the target surface temperature and/or moisture content before application of an aqueous conditioning agent at 108. In one embodiment, the target surface temperature of the granules is approximately about 50°F to about 250°F, and more particularly about 130°F to about 200°F, and the target moisture content is about 0 to about 6.5 weight percent (wt%), more particularly from about 0.5 wt% to about 3 wt% and more particularly from about 0.5 wt% to about 1.5 wt%
Once the granules are at the target temperature and moisture content, they are placed into a conditioning vessel at 106, such as a tumbling drum or bed, flighted drum or bed, or fluidized bed for application of the one or more aqueous conditioning agents. In one embodiment, the conditioning vessel includes one or more sprayers or nozzles for the spray application of one or more aqueous conditioning agents at 108, with or without beneficial agricultural and/or dedusting additives. As discussed above, the aqueous conditioning agent can comprise water or a water-based solution, in the form of liquid, steam, and/or superheated steam, and with or without beneficial agricultural and/or dedusting additives. The aqueous conditioning agent is introduced at a temperature of about 32°F to about 800°F depending on the form of the agent, and more particularly from about 70°F to about 170°F when the agent is in the form of liquid water or a water-based solution, with or without beneficial agricultural and/or dedusting additives.
As mentioned above, the aqueous conditioning agent can optionally contain one or more beneficial agricultural and/or dedusting additives, such as, for example, acidifying agents, drying agents, chelating agents, micronutrients, secondary nutrients, biological materials, pesticides and herbicides. Acidifying agents can include, but are not limited to, citric acid, sulfuric acid, phosphoric acid, sulfamic acid, and combinations thereof. Drying agents can include, but are not limited to, corn starch, and/or wheat starch. Chelating agents can include, but are not limited to, ethylenediaminetetraacetic acid (EDTA), polyethylenimine (PEI), or combinations thereof. Any of the agents can be added in an amount of about 0.01 wt% to about 99.99 wt% of solution, and more particularly from about 0.01 wt% to about 20 wt% of solution for certain applications, from about 20 wt% to about 50 wt% of solution for other applications, and from about 50 wt% to about 99.99wt% for yet other applications.
In addition to or as an alternative to the additives listed above, the aqueous conditioning agent can contain one or more beneficial agricultural additives selected from one or any combination of secondary nutrients and/or micronutrients in an amount of about 0.01 wt% to about 99.99 wt% of solution, and more particularly from about 20 wt% to about 50 wt% of solution. The secondary nutrients can include, for example, sulfur compounds, calcium, and/or magnesium, and the micronutrients can include, for example, iron, manganese, zinc, copper, boron, molybdenum, and/or chlorine.
In addition to or as an alternative to the additives listed above, the aqueous conditioning agent can contain one or more beneficial agricultural additives selected from one or any combination of biological material. In some cases, biological material, or "biologicals," can comprise microorganisms, including, but not limited to, bacteria such as Bacillus, Rhizobium, Azobacter, and Azospirillum, fungi such as Aspergillus, Mycorhizzae, Beauveria, Metarhizium, and Trichoderma, and/or yeast such as Saccharomyces, Schizosaccharomyces, Sporobolomyces, Candida, Trichosporon, and Rhodosporidium. In other cases, the aqueous conditioning agent can comprise biologicals that are not microorganisms, including, but not limited to, small molecule and peptide -based compositions such as metabolites, peptides, lipopetides, hormones, peptide hormones, siderophores, glycopepetides, humates, surfactants, vitamins, enzymes, amino acids and amino acid derivatives, and nucleic acids and nucleic acid derivatives.
In some embodiments, biologicals included in embodiments of the aqueous conditioning agent can be applied to fertilizers or fertilizer granules at a final concentration of about 10 to about 1012 CFU (colony forming units)/g, and more particularly about 106 to about 109 CFU/g 106 to about 109 CFU. For example, 4.1 mis of an aqueous solution comprising biologicals can be added to 1 lb of fertilizer, or about 1012 to about 1015 CFU/L can be added to liquid fertilizer to achieve the above target concentration. In some cases, biologicals included in embodiments of the aqueous conditioning agent can be applied at temperatures ranging from about 70°F to about 210°F, or more particularly, from about 70°F to about 180°F, or more particularly, from about 70°F to about 160°F. Biologicals applied accordingly have the potential to enhance the growth and development of plants as well as treat plant diseases.
In an alternative embodiment, one or more of the beneficial agricultural and/or dedusting additives described above are optionally introduced at 11 1 onto the surface of the granules separate from the aqueous conditioning agent (with or without additives). The one or more beneficial agricultural and/or dedusting additives can be added simultaneously or in series with (e.g. upstream and/or downstream from) the aqueous conditioning agent, such as by spraying, in conditioning vessel 106. In one non-limiting embodiment, the aqueous conditioning agent is added at 108 in an amount of about 0.1 to about 10 wt% of the total weight of the fertilizer, and more particularly from about 2.0 to about 4.0 wt% of the total weight of the fertilizer. This can be accomplished, for example, by the addition of aqueous conditioning agent at a rate of about 0 to about 22 gallons per ton of granular fertilizer, and more particularly about 5-10 gallons per ton of granular fertilizer, depending on the composition or concentration of the aqueous conditioning agent, and the desired amount of aqueous conditioning agent per granule.
In one embodiment, simultaneously with or after the application of the aqueous conditioning agent at 108, the granules are optionally subjected to mechanical energy at 110 in the form of agitation, such as shaking and/or tumbling, within the conditioning vessel 106 to promote or induce mechanical interaction between granules. The conditioning vessel can further optionally include mixing equipment such as, a ribbon blender, paddle mixer, baffles, and/or can comprise a rotating drum such that the application of the aqueous conditioning agent is spread evenly over the granules, and to further induce mechanical interaction between the granules.
In an alternative embodiment, the granules and the aqueous conditioning agent are introduced into a fluidized bed reactor such that surfaces of the granules are subjected to surface conditioning described above, without necessarily being subjected to particle to particle interaction or mechanical energy exposure. Optionally, one or more beneficial agricultural and/or dedusting additives can be added to the fluidized bed separately from the aqueous conditioning agent (with or without additives). During and/or after the optional application of energy at 1 10, the extra moisture from the application of the aqueous conditioning agent is removed at 112. In one embodiment, removal of the moisture at 112 can be accomplished without additional equipment and/or processing. For example, a previously established airflow, such as a ventilation means or duct for removing fugitive dust, water vapor, or other ventilation such as a fluid bed dryer, moves air that is sufficiently dry through vessel 106 to remove the added moisture.
In another embodiment of the invention, one or more gases are supplied to or moved through the vessel at 114 to remove the added moisture from the granules. The one or more gases can be, for example, recycled and/or fresh air, and/or an inert gas such as argon or nitrogen. The gas can be completely dry, or have a low or negligible moisture content. In a particular embodiment, the gas includes one or more beneficial agricultural and/or dedusting additives or agents as described above for application to the granule surface.
In yet another embodiment, the latent heat of the fertilizer granules is sufficient to dry the granules by evaporation of the moisture to the surrounding atmosphere of the vessel 106. The air of the vessel 106 is removed and replaced as needed. In yet another embodiment, the granules are subjected to the application of dry air and/or heat in a separate drying vessel (not shown), such as a fluid bed dryer. In each of the embodiments, the added moisture is removed until a final moisture content of about 0 to about 6.5 weight percent (wt%), more particularly from about 0.5 wt% to about 3 wt% and more particularly from about 0.5 wt% to about 1.5 wt% of the granules is achieved, resulting in conditioned fertilizer granules. The conditioned fertilizer granules are removed at 116 are then shipped to storage and/or end-use customers, or are reconditioned or further conditioned or processed as desired.
As discussed above, the conditioning of the granular fertilizers by water treatment allows for the reduction in application of dust control agents, such as the oil-based coatings, thereby reducing raw material costs and/or manufacturing costs. Also, reduction in dust generated during distribution from the manufacturer to the grower results in improved industrial hygiene for the manufacturers, transporters, customers, and/or customer employees, thereby reducing the costs and equipment otherwise needed to mitigate industrial hygiene issues.
Table 1 below lists breakage results comparing conditioned fertilizer granules conditioned with an aqueous conditioning agent in the form of water in weight percent to unconditioned fertilizer granules. In this example, the base fertilizer was monoammonium phosphate and the breakage was measured.
In particular, an accelerated performance measurement procedure used to measure this data consists of the following steps: (1) Initially untreated fertilizer granules are split (with a riffler) to maintain comparable fractions; (2) The baseline granules are not treated with an aqueous conditioning agent while the remaining granules coated with different experimental treatments of different amounts of aqueous conditioning agent; (3) The coated samples are stored under controlled environmental conditions reflecting potential product transportation and storage conditions; and (4) The effectiveness of dust control is measured after several (2, 4, 6, 8) weeks. To measure effectiveness of dust control, samples are removed from the environmental chamber and exposed to a controlled energy input to simulate product handling. Dust sized particles from each sample are then extracted and the dust level is determined by mass difference. The reduction percentage is calculated as a percent change (in this case reduction) from the dust generation of the baseline samples. Table 1: Breaka e results
Figure imgf000017_0001
In other embodiments, such surface treatments and/or incorporation of additives or agents by the above methods may result in reduced caking tendencies by means of inhibiting chemical and/or physical interactions between granules in storage, during transport, or otherwise.
While the invention is amenable to various modifications and alternative forms, specifics thereof have been shown by way of example in the drawings and described in detail. It is understood, however, that the intention is not to limit the invention to the particular embodiments described. On the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.

Claims

CLAIMS What is claimed is:
1. A method for conditioning fertilizer granules for improved dust control and/or agricultural benefits, method comprising:
providing a plurality of fertilizer granules having a surface temperature of about 50°F to about 250°F;
introducing a quantity of an aqueous conditioning agent with or without beneficial agricultural and/or dedusting additives;
optionally subjecting the fertilizer granules with an aqueous conditioning agent thereon to a mechanical energy exposure and/or a fluidized bed reactor; and
removing added moisture from the aqueous conditioning agent from the granules until a final moisture content of the granules is about 0 wt% to about 6.5 wt% of the granules.
2. The method of claim 1 , wherein one or more beneficial agricultural and/or dedusting additives is present in an amount of about 20 wt% to about 50 wt% of solution of the aqueous conditioning agent.
3. The method of claim 1, wherein the aqueous conditioning agent comprises a solution or suspension of water and one or more beneficial agricultural and/or dedusting additives selected from the group consisting of one or more acidifying agents, one or more drying agents, one or more herbicides and/or pesticides, one or more chelating agents, one or more biological agents, and combinations thereof.
4. The method of claim 3, wherein the one or more acidifying agents comprises citric acid, sulfamic acid, sulfuric acid, phosphoric acid, or combinations thereof.
5. The method of claim 3, wherein the one or more drying agents comprises corn starch, wheat starch, or combinations thereof.
6. The method of claim 3, wherein the one or more chelating agents comprises ethylenediaminetetraacetic acid (EDTA), polyethylenimine (PEI), or combinations thereof.
7. The method of claim 1, wherein the aqueous conditioning agent comprises a solution or suspension of water and one or more secondary nutrients and/or micronutrients.
8. The method of claim 7, wherein the one or more secondary nutrients are selected from the group consisting of a source of sulfur, a source of calcium, and/or a source of magnesium.
9. The method of claim 7, wherein the one or more micronutrients are selected from the group consisting of a source of iron, a source of manganese, a source of zinc, a source of copper, a source of boron, a source of molybdenum, and/or a source of chlorine.
10. The method of claim 1, wherein subjecting the fertilizer granules with an aqueous conditioning agent thereon to a mechanical energy exposure comprises tumbling or mixing in a conditioning vessel to provide particle to particle interaction.
11. The method of claim 1, wherein subjecting the fertilizer granules with an aqueous conditioning agent thereon into a fluidized bed reactor is such that the surface of each individual granule is subjected to surface conditioning described above, without necessarily being subjected to particle to particle interaction or mechanical energy exposure.
12. The method of claim 1 , wherein introducing a quantity of an aqueous conditioning agent with or without beneficial agricultural and/or dedusting additives comprises spraying the aqueous conditioning agent onto the fertilizer granules in a conditioning vessel, wherein the aqueous conditioning agent is introduced at a temperature of about 32°F to about 800°F.
13. The method of claim 1 , further comprising introducing one or more beneficial agricultural and/or dedusting additives onto a surface of the granules in a separate step from or from a separate source than the aqueous conditioning agent.
14. A method of introducing one or more agriculturally beneficial additives to fertilizer granules in a conditioning vessel, wherein one or more agriculturally beneficial additives comprises one or any combination of biological material.
15. The method of claim 14, wherein the biological material comprises one or more microorganisms.
16. The method of claim 15, wherein the microorganism is bacteria selected from the group consisting of Bacillus, Rhizobium, Azobacter, Azospirillum, and combinations thereof.
17. The method of claim 15, wherein the microorganism is fungi selected from the group consisting of Aspergillus, Mycorhizzae, Beauveria, Metarhizium, and Trichoderma, Saccharomyces, Schizosaccharomyces, Sporobolomyces, Candida, Trichosporon, and Rhodosporidium, and combinations thereof.
18. The method of claim 14, wherein the biological material is selected from the group consisting of metabolites, peptides, lipopetides, hormones, peptide hormones, siderophores, glycopepetides, humates, surfactants, vitamins, enzymes, amino acids, amino acid derivatives, nucleic acids, nucleic acid derivatives, and combinations thereof.
19. The method of any of the preceding claims 14-18, wherein the biological material is applied to fertilizers or fertilizer granules at a final concentration of about 10 3 to about 1012 CFU/g.
20. The method of claim 19, wherein the biological material is applied to fertilizers or fertilizer granules at a final concentration of about 106 to about 109 CFU/g.
21. The method of claim any of the preceding claims 14-20, wherein the biological material is sprayed on the fertilizer or fertilizer granules as an aqueous solution, and then dried leaving the biological material deposited on the fertilizer or fertilizer granule.
22. A system for introducing agriculturally beneficial and/or dedusting additives to fertilizer granules according to the method of any of the preceding claims.
23. The system of claim 22, wherein the system comprises a conditioning vessel with mixing equipment selected from the group consisting of a ribbon blender, paddle mixer, baffles.
24. The system of claim 22, wherein the system comprises a rotating drum such that the application of the aqueous conditioning agent is spread evenly over the granules, and to further induce mechanical interaction between the granules.
25. The system of claim 22, wherein the system comprises a fluidized bed reactor, wherein the granules and the aqueous conditioning agent are introduced into the fluidized bed reactor such that the surface of each individual granule is subjected to surface conditioning described above, without necessarily being subjected to particle to particle interaction or mechanical energy exposure.
26. The system of claim 22, wherein the system comprises any of combination of one or more rotating drums, one or more condition vessels with mixing equipment, and one or more fluidized bed reactors.
PCT/US2014/051662 2013-08-19 2014-08-19 System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers WO2015026806A1 (en)

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BR112016003586-0A BR112016003586B1 (en) 2013-08-19 2014-08-19 METHOD FOR CONDITIONING INORGANIC PHOSPHATE FERTILIZER GRANULES TO IMPROVE DUST CONTROL AND/OR AGRICULTURAL IMPROVEMENT
JP2016536375A JP2016531830A (en) 2013-08-19 2014-08-19 Systems and methods for adding agricultural additives, biological additives and dust control additives to granular fertilizers
CA2921846A CA2921846C (en) 2013-08-19 2014-08-19 System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
RU2016109808A RU2676734C2 (en) 2013-08-19 2014-08-19 System and methods for addition of effective agricultural, biological, and/or dedusting additives to granular fertilizers
MA38911A MA38911B1 (en) 2013-08-19 2014-08-19 System and methods for adding agricultural, biological and / or dust suppressant additives to granular fertilizers
EP20199048.8A EP3825299A1 (en) 2013-08-19 2014-08-19 Methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
NZ717735A NZ717735B2 (en) 2013-08-19 2014-08-19 System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
ES14838566T ES2826200T3 (en) 2013-08-19 2014-08-19 Method for the addition of beneficial agricultural, biological and / or dust removal additives to granular fertilizers
CN202110528917.9A CN113200784B (en) 2013-08-19 2014-08-19 System and method for adding beneficial agricultural, biological and/or dedusting additives to a particulate fertilizer
EP14838566.9A EP3036207B1 (en) 2013-08-19 2014-08-19 Method for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
CN201480057610.3A CN105658603B (en) 2013-08-19 2014-08-19 System and method for adding beneficial agricultural, biological and/or dedusting additives to granular fertilizers
MX2016002212A MX2016002212A (en) 2013-08-19 2014-08-19 System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers.
US14/913,091 US10654759B2 (en) 2013-08-19 2014-08-19 System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
AU2014309005A AU2014309005A1 (en) 2013-08-19 2014-08-19 System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
IL244183A IL244183B (en) 2013-08-19 2016-02-18 System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
PH12016500341A PH12016500341A1 (en) 2013-08-19 2016-02-19 System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
AU2019264632A AU2019264632B2 (en) 2013-08-19 2019-11-14 System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
US16/878,212 US11084762B2 (en) 2013-08-19 2020-05-19 System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers

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US10654759B2 (en) 2013-08-19 2020-05-19 The Mosaic Company System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
US11084762B2 (en) 2013-08-19 2021-08-10 The Mosaic Company System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers
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