WO2015021757A1 - Antibacterial antistatic plastic casing for financial pos device, and preparation method thereof - Google Patents

Antibacterial antistatic plastic casing for financial pos device, and preparation method thereof Download PDF

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Publication number
WO2015021757A1
WO2015021757A1 PCT/CN2014/071686 CN2014071686W WO2015021757A1 WO 2015021757 A1 WO2015021757 A1 WO 2015021757A1 CN 2014071686 W CN2014071686 W CN 2014071686W WO 2015021757 A1 WO2015021757 A1 WO 2015021757A1
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Prior art keywords
antibacterial
antistatic
agent
plastic
pos machine
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PCT/CN2014/071686
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French (fr)
Chinese (zh)
Inventor
陈演光
林财
庄江平
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福建联迪商用设备有限公司
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Publication of WO2015021757A1 publication Critical patent/WO2015021757A1/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/015Biocides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/017Antistatic agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
    • B29K2105/0011Biocides

Definitions

  • the present invention relates to an antibacterial antistatic anti-static financial POS machine plastic casing and a preparation method thereof.
  • the financial POS machine used in medical institutions has a high frequency of contact with the user by the user, and most of the users are patients, which causes the bacteria of the outer casing to breed seriously, becomes a source of bacteria, and ultimately affects the user. Health.
  • static electricity is far more harmful to a specific population than ordinary people.
  • persistent static electricity can cause the pH of human blood to rise, calcium in the urine to increase, and blood calcium to decrease, which is the most harmful to maternal health.
  • Static electricity can cause progesterone levels in pregnant women to decline, making them susceptible to fatigue, irritability and headaches; older people are more susceptible to static electricity, elderly people with cardiovascular disease will aggravate their condition or induce ventricular premature beats and other arrhythmias .
  • the POS machine used by the medical institution puts special requirements on the antibacterial and antistatic performance of the POS casing.
  • the object of the present invention is to provide an antibacterial and antistatic anti-static financial POS machine plastic casing and a preparation method thereof.
  • the plastic casing of the POS machine has not only antibacterial and antistatic properties, but also has a simple structure and is easy to manufacture and produce.
  • an antibacterial antistatic anti-static financial POS machine plastic casing the composition of which comprises: 95.8% ⁇ 96.8% synthetic resin, 0.5% ⁇ 1.0% glass carrier silver It is an inorganic antibacterial agent, 2 ° / ⁇ 2.5% polymer permanent antistatic agent, 0.2% antioxidant, 0.5% coupling agent.
  • the composition of the plastic housing of the POS machine comprises: 95.9% synthetic resin PC + ABS raw material, 0.9% glass carrier silver inorganic antibacterial agent, 2.5% polymer permanent type Antistatic agent, 0.2% antioxidant, 0.5% coupling agent.
  • the composition of the plastic housing of the POS machine comprises: 96.5% synthetic resin ABS raw material, 0.8% glass carrier silver inorganic antibacterial agent, 2% polymer permanent antistatic Agent, 0.2% antioxidant, 0.5% coupling agent.
  • the present invention also provides a method for preparing the above-mentioned antibacterial antistatic financial POS machine plastic outer casing, comprising the following steps: (1) sufficiently drying the polymer permanent antistatic agent;
  • composition of the plastic shell of the POS machine is prepared according to the following proportions: 95.8% ⁇ 96.8% synthetic resin, 0.5% ⁇ 1.0% glass carrier silver inorganic antibacterial agent, 2% ⁇ 2.5% polymer Permanent antistatic agent, 0.2% antioxidant, 0.5% coupling agent;
  • Injection molding The prepared plastic masterbatch is set to various molding parameters according to the substrate, and is molded by injection molding using a mold to obtain an antibacterial and antistatic POS plastic case.
  • the raw material is added and prepared conveniently, suitable for large-scale production in large scale, the plastic casing has sterilization and antistatic property, and is not damaged by light or heat, and does not change color, and has the same antibacterial and antistatic properties from the surface to the inside, and the effective period It is consistent with the product design life.
  • FIG. 1 is a schematic view showing the composition of a plastic casing of a POS machine according to an embodiment of the present invention.
  • the invention has a plastic POS plastic shell with antibacterial and antistatic function, and the composition thereof comprises: 95.8% ⁇ 96.8% synthetic resin (ABS or PC+ABS raw material), 0.5% ⁇ 1.0% glass carrier silver inorganic Antibacterial agent, 2% ⁇ 2.5% polymer permanent antistatic agent, 0.2% antioxidant, 0.5% coupling agent.
  • the above-mentioned constituent raw materials are obtained by the following specific steps to obtain a finished plastic shell of a POS machine, and the finished plastic shell of the POS machine utilizes a sustained release of the antibacterial agent in the outer shell to provide an antibacterial effect, and the surface affinity aqueous ASA coating is effective. Suppresses the accumulation of static electricity.
  • the antibacterial and antistatic anti-static financial POS machine plastic casing of the present invention is prepared as follows:
  • the polymer permanent antistatic agent is sufficiently dried and dried in a dryer set at a temperature of 70 to 80 ° C for 4 hours. This step can prevent the antistatic property of the product from deteriorating due to the absorption of moisture by the antistatic agent during the granulation process.
  • composition of the plastic shell of the POS machine is prepared according to the following proportions: 95.8% ⁇ 96.8% synthetic resin (ABS or PC+ABS raw material), 0.5% ⁇ 1.0% glass carrier silver inorganic Antibacterial agent, 2% ⁇ 2.5% polymer permanent antistatic agent, 0.2% antioxidant, 0.5% coupling agent.
  • proportions 95.8% ⁇ 96.8% synthetic resin (ABS or PC+ABS raw material), 0.5% ⁇ 1.0% glass carrier silver inorganic Antibacterial agent, 2% ⁇ 2.5% polymer permanent antistatic agent, 0.2% antioxidant, 0.5% coupling agent.
  • Stirring The above-mentioned proportioned constituent raw materials are uniformly stirred by a high-mixer in a temperature range of 190 ° C to 230 ° C.
  • Injection molding The prepared plastic masterbatch is subjected to various molding parameters such as mold temperature, pressure and time according to the substrate, and is injection molded by an injection molding machine to obtain an antibacterial and antistatic POS machine. plastic shell.
  • the antibacterial properties of the present invention are achieved by a glass carrier silver-based inorganic antimicrobial agent:
  • the antibacterial ability of silver ions is well known.
  • the chemical structure of silver determines the high catalytic ability of silver, and the high oxidation state of silver is extremely high enough to generate atomic oxygen in its surrounding space.
  • Atomic oxygen has strong oxidizing properties and can be sterilized.
  • Ag+ can strongly attract the sulfhydryl group (-SH) on the protease in the bacterial body, and bind it quickly to inactivate the protease, leading to bacterial death.
  • -SH sulfhydryl group
  • the glass is a material having excellent chemical stability, the glass can serve as a carrier to support metal ions, and the silver having an antibacterial function is attached to the glass structure in the form of silver ions, and the silver ions are dissolved as the glass dissolves, thereby The material is rendered antimicrobial.
  • the antistatic property of the present invention is achieved by an antistatic agent:
  • the polymer permanent antistatic agent is a hydrophilic polymer. When it is blended with the polymer matrix, on the one hand, due to its strong molecular chain movement ability, the protons are easy to move between molecules, and the generated electrostatic charge is transmitted and released by ion conduction; on the other hand, the antistatic ability is through Special dispersion form is reflected.
  • the polymer permanent antistatic agent is mainly distributed in the layered or ribbed layer on the surface of the product to form a conductive surface layer, and is distributed almost spherically in the central portion to form a so-called "core shell structure". Leaking static charge. Because the polymer permanent antistatic agent achieves an antistatic effect by reducing the volume resistivity of the material, it does not completely depend on the surface water absorption, so it is less affected by the humidity of the environment.
  • Baking material The antistatic agent is fully dried before being added, and dried in a dryer with a set temperature of 70 to 80 ° C for 4 hours.
  • Injection molding The prepared plastic masterbatch is subjected to various molding parameters such as mold temperature, pressure and time according to the substrate, and is injection molded by an injection molding machine, thereby obtaining antibacterial and antistatic properties. POS machine plastic case.
  • Baking material The antistatic agent is fully dried before being added, and dried in a dryer with a set temperature of 70 to 80 ° C for 4 hours.
  • injection molding the prepared plastic masterbatch, according to the substrate set mold temperature, pressure, time and other various molding parameters The number of plastic molds of POS machines with antibacterial and antistatic properties is obtained by injection molding using a mold.
  • the known inorganic antibacterial agents for the antibacterial shell plastics of electronic products are all zeolite carriers. Although the antibacterial property of the glass carrier is less than that of the zeolite carrier, the stability and long-term stability of the glass carrier are the best, and the conditions for controlling the addition ratio are controlled. The same strong antibacterial effect can be achieved under the same conditions. Therefore, the glass carrier silver-based inorganic antibacterial agent is preferred in the present invention.
  • the polymer permanent antistatic agent is a hydrophilic polymer which can impart permanent antistatic properties to the hydrophobic polymer, but does not substantially affect other properties, which is not possessed by other modifiers. advantage. It achieves an antistatic effect by reducing the volume resistivity of the material, and does not completely depend on the surface water absorption, so it is less affected by the humidity of the environment. Other types of antistatic agents need to have higher water absorption of the antistatic agent molecules when the external environment humidity is high, and the antistatic performance is more remarkable. Therefore, the present invention is preferably a polymer permanent antistatic agent which is excellent in stability and long-term effectiveness.

Abstract

Provided are an antibacterial antistatic plastic casing for a financial POS device, and preparation method thereof. The composition of the plastic casing for a POS device comprises: 95.8%-96.8% synthetic resin, 0.5%-1.0% glass carrier argentum inorganic antibacterial agent, 2%-2.5% macromolecular permanent antistatic agent, 0.2% antioxidant, and 0.5% coupling agent. The preparation method comprises baking the material, distributing the material by proportion, stirring, pelleting and injection molding, to prepare the antibacterial and antistatic plastic casing for a POS machine. The plastic casing for a POS machine not only has good antibacterial and antistatic properties, but also has a simple structure and is easy to manufacture.

Description

说明书 一种抗菌抗静电的金融 POS机塑料外壳及其制备方法 技术领域  Antibacterial antistatic anti-static financial POS machine plastic casing and preparation method thereof
[0001] 本发明涉及一种抗菌抗静电的金融 POS机塑料外壳及其制备方法。  [0001] The present invention relates to an antibacterial antistatic anti-static financial POS machine plastic casing and a preparation method thereof.
背景技术 Background technique
[0002] 目前, 在医疗机构使用的金融 POS机, 其外壳被使用者接触的频率很高, 而使用者中 多为患者, 导致外壳细菌滋生严重, 成为细菌的传播源, 最终影响到使用者的健康。  [0002] At present, the financial POS machine used in medical institutions has a high frequency of contact with the user by the user, and most of the users are patients, which causes the bacteria of the outer casing to breed seriously, becomes a source of bacteria, and ultimately affects the user. Health.
[0003] 同时, 静电对特定人群的危害更远大于常人, 如持久性的静电可引起人体血液的 pH 值升高, 尿中钙排泄量增加, 血钙减少, 对孕产妇的健康危害最大, 静电可致孕产妇体内孕 激素水平下降, 让她们容易感到疲劳、 烦躁和头痛等; 老年人更容易受到静电的影响, 心血 管疾病的老人会因为静电使病情加重或诱发室性早搏等心律失常。  [0003] At the same time, static electricity is far more harmful to a specific population than ordinary people. For example, persistent static electricity can cause the pH of human blood to rise, calcium in the urine to increase, and blood calcium to decrease, which is the most harmful to maternal health. Static electricity can cause progesterone levels in pregnant women to decline, making them susceptible to fatigue, irritability and headaches; older people are more susceptible to static electricity, elderly people with cardiovascular disease will aggravate their condition or induce ventricular premature beats and other arrhythmias .
[0004] 医院中监护仪器和心电检测仪器对静电的防护要求更高, 静电会影响设备检测结果。  [0004] In hospitals, monitoring instruments and ECG testing instruments have higher requirements for electrostatic protection, and static electricity can affect equipment testing results.
[0005] 综上所述, 医疗机构使用的 POS机对 POS机外壳的抗菌、 抗静电性能提出了特殊的 要求。 [0005] In summary, the POS machine used by the medical institution puts special requirements on the antibacterial and antistatic performance of the POS casing.
发明内容 Summary of the invention
[0006] 本发明的目的在于提供一种抗菌抗静电的金融 POS机塑料外壳及其制备方法,该 POS 机塑料外壳不仅抗菌、 抗静电性能好, 而且结构简单, 易于制造生产。  [0006] The object of the present invention is to provide an antibacterial and antistatic anti-static financial POS machine plastic casing and a preparation method thereof. The plastic casing of the POS machine has not only antibacterial and antistatic properties, but also has a simple structure and is easy to manufacture and produce.
[0007] 为实现上述目的, 本发明的技术方案是: 一种抗菌抗静电的金融 POS机塑料外壳, 其 组成成分包括: 95.8%~96.8%的合成树脂, 0.5%~1.0%的玻璃载体银系无机抗菌剂, 2°/^2.5% 的高分子永久型抗静电剂, 0.2%的抗氧化剂, 0.5%的偶联剂。  [0007] In order to achieve the above object, the technical solution of the present invention is: an antibacterial antistatic anti-static financial POS machine plastic casing, the composition of which comprises: 95.8%~96.8% synthetic resin, 0.5%~1.0% glass carrier silver It is an inorganic antibacterial agent, 2 ° / ^ 2.5% polymer permanent antistatic agent, 0.2% antioxidant, 0.5% coupling agent.
[0008] 在本发明一实施例中, 所述 POS 机塑料外壳的组成成分包括: 95.9%的合成树脂 PC+ABS原料, 0.9%的玻璃载体银系无机抗菌剂, 2.5%的高分子永久型抗静电剂, 0.2%的抗 氧化剂, 0.5%的偶联剂。  [0008] In an embodiment of the invention, the composition of the plastic housing of the POS machine comprises: 95.9% synthetic resin PC + ABS raw material, 0.9% glass carrier silver inorganic antibacterial agent, 2.5% polymer permanent type Antistatic agent, 0.2% antioxidant, 0.5% coupling agent.
[0009] 在本发明一实施例中, 所述 POS机塑料外壳的组成成分包括: 96.5%的合成树脂 ABS 原料, 0.8%的玻璃载体银系无机抗菌剂, 2%的高分子永久型抗静电剂, 0.2%的抗氧化剂, 0.5% 的偶联剂。  [0009] In an embodiment of the invention, the composition of the plastic housing of the POS machine comprises: 96.5% synthetic resin ABS raw material, 0.8% glass carrier silver inorganic antibacterial agent, 2% polymer permanent antistatic Agent, 0.2% antioxidant, 0.5% coupling agent.
[0010] 本发明还提供了上述抗菌抗静电的金融 POS机塑料外壳的制备方法, 包括以下步骤: ( 1 ) 充分烘干高分子永久型抗静电剂;  [0010] The present invention also provides a method for preparing the above-mentioned antibacterial antistatic financial POS machine plastic outer casing, comprising the following steps: (1) sufficiently drying the polymer permanent antistatic agent;
1 1
替换页(细则第 26条) (2) 配料: 按下列比例配制所述 POS 机塑料外壳的组成原料: 95.8%~96.8%的合成树脂, 0.5%~1.0%的玻璃载体银系无机抗菌剂, 2%~2.5%的高分子永久型抗静电剂, 0.2%的抗氧化 剂, 0.5%的偶联剂; Replacement page (Article 26) (2) Ingredients: The composition of the plastic shell of the POS machine is prepared according to the following proportions: 95.8%~96.8% synthetic resin, 0.5%~1.0% glass carrier silver inorganic antibacterial agent, 2%~2.5% polymer Permanent antistatic agent, 0.2% antioxidant, 0.5% coupling agent;
(3)搅拌:将上述按比例配制的组成原料在 190°C~230°C的温度范围内通过高混机搅拌均匀; (3) Stirring: the above-mentioned proportioned raw materials are uniformly stirred by a high-mixer in a temperature range of 190 ° C to 230 ° C;
(4)造粒: 将上述搅拌均匀的组成原料通过造粒机挤出, 经过冷却吹干, 最后切粒, 制得抗 菌抗静电的塑料母料; (4) granulation: the above-mentioned uniformly stirred raw materials are extruded through a granulator, cooled and dried, and finally granulated to obtain an antibacterial and antistatic plastic master batch;
(5)注塑成型: 将制得的塑料母粒, 根据基材设定各种成型参数, 利用模具通过注塑机注塑 成型, 制得抗菌抗静电的 POS机塑料外壳。  (5) Injection molding: The prepared plastic masterbatch is set to various molding parameters according to the substrate, and is molded by injection molding using a mold to obtain an antibacterial and antistatic POS plastic case.
[0011] 相较于现有技术, 本发明的有益效果是:  [0011] Compared with the prior art, the beneficial effects of the present invention are:
1 ) 具有抗菌功能, 对所有的细菌及霉菌都有杀灭、 抑制作用, 抗菌率〉90%, 特别是对金黄 色葡萄球菌和大肠杆菌的抗菌效果在 99%以上, 从而有效的抑制细菌的滋生, 避免 POS机成 为细菌的传播源, 而且对于使用者不会产生任何不良副作用。  1) It has antibacterial function and kills and inhibits all bacteria and molds. The antibacterial rate is >90%, especially the antibacterial effect against Staphylococcus aureus and Escherichia coli is over 99%, thus effectively inhibiting bacteria. Breeding, avoiding the POS machine becoming a source of bacteria, and does not cause any adverse side effects to the user.
[0012] 2) 具有抗静电功能, 表面电阻达到 ΙΟ^ΙΟ11, 有效的抑制静电的蓄积。 [0012] 2) having an antistatic function, a surface resistance reaches ΙΟ ^ ΙΟ 11, effectively suppressing accumulation of static electricity.
[0013] 3) 原料添加制备方便, 适宜规模化大批量生产, 塑料外壳杀菌、 抗静电能力不受光、 热破坏且不变色, 其表层到内部都具备同样的抗菌、 抗静电性能, 持效期和制品设计寿命一 致。  [0013] 3) The raw material is added and prepared conveniently, suitable for large-scale production in large scale, the plastic casing has sterilization and antistatic property, and is not damaged by light or heat, and does not change color, and has the same antibacterial and antistatic properties from the surface to the inside, and the effective period It is consistent with the product design life.
附图说明 DRAWINGS
[0014] 图 1是本发明实施例的 POS机塑料外壳的组成成分示意图。  1 is a schematic view showing the composition of a plastic casing of a POS machine according to an embodiment of the present invention.
具体实 式 Specific form
[0015] 本发明具有抗菌抗静电功能的金融 POS机塑料外壳, 其组成成分包括: 95.8%~96.8% 的合成树脂(ABS或 PC+ABS原料), 0.5%~1.0%的玻璃载体银系无机抗菌剂, 2%~2.5%的高 分子永久型抗静电剂, 0.2%的抗氧化剂, 0.5%的偶联剂。 上述组成原料通过下述具体步骤制 得 POS机塑料外壳成品, 该 POS机塑料外壳成品利用抗菌剂在外壳中持续的微量缓释而起 到抗菌效果, 同时表面亲和水性的 ASA涂层有效的抑制静电的蓄积。  [0015] The invention has a plastic POS plastic shell with antibacterial and antistatic function, and the composition thereof comprises: 95.8%~96.8% synthetic resin (ABS or PC+ABS raw material), 0.5%~1.0% glass carrier silver inorganic Antibacterial agent, 2%~2.5% polymer permanent antistatic agent, 0.2% antioxidant, 0.5% coupling agent. The above-mentioned constituent raw materials are obtained by the following specific steps to obtain a finished plastic shell of a POS machine, and the finished plastic shell of the POS machine utilizes a sustained release of the antibacterial agent in the outer shell to provide an antibacterial effect, and the surface affinity aqueous ASA coating is effective. Suppresses the accumulation of static electricity.
[0016] 本发明抗菌抗静电的金融 POS机塑料外壳, 按如下步骤进行制备: [0016] The antibacterial and antistatic anti-static financial POS machine plastic casing of the present invention is prepared as follows:
( 1 ) 充分烘干高分子永久型抗静电剂, 在设定温度 70〜80°C的干燥机内烘干 4个小时。 此 步骤可以避免造粒过程中因抗静电剂吸收水分而导致制品的抗静电性能下降。  (1) The polymer permanent antistatic agent is sufficiently dried and dried in a dryer set at a temperature of 70 to 80 ° C for 4 hours. This step can prevent the antistatic property of the product from deteriorating due to the absorption of moisture by the antistatic agent during the granulation process.
[0017] (2) 配料: 按下列比例配制所述 POS机塑料外壳的组成原料: 95.8%~96.8%的合成 树脂(ABS或 PC+ABS原料), 0.5%~1.0%的玻璃载体银系无机抗菌剂, 2%~2.5%的高分子永 久型抗静电剂, 0.2%的抗氧化剂, 0.5%的偶联剂。 [0018] (3)搅拌: 将上述按比例配制的组成原料在 190°C~230°C的温度范围内通过高混机搅 拌均匀。 [0017] (2) Ingredients: The composition of the plastic shell of the POS machine is prepared according to the following proportions: 95.8%~96.8% synthetic resin (ABS or PC+ABS raw material), 0.5%~1.0% glass carrier silver inorganic Antibacterial agent, 2%~2.5% polymer permanent antistatic agent, 0.2% antioxidant, 0.5% coupling agent. [0018] (3) Stirring: The above-mentioned proportioned constituent raw materials are uniformly stirred by a high-mixer in a temperature range of 190 ° C to 230 ° C.
[0019] (4) 造粒: 将上述搅拌均匀的组成原料通过双螺杆造粒机挤出, 经过冷却水槽和吹 干机冷却吹干, 最后切粒, 制得抗菌抗静电的塑料母料。  [0019] (4) Granulation: The above-mentioned uniformly stirred raw materials are extruded through a twin-screw granulator, cooled and dried by a cooling water tank and a blow dryer, and finally granulated to obtain an antibacterial antistatic plastic master batch.
[0020] (5 ) 注塑成型: 将制得的塑料母粒, 根据基材设定模温、 压力、 时间等各种成型参 数, 利用模具通过注塑机注塑成型, 制得抗菌抗静电的 POS机塑料外壳。  [0020] (5) Injection molding: The prepared plastic masterbatch is subjected to various molding parameters such as mold temperature, pressure and time according to the substrate, and is injection molded by an injection molding machine to obtain an antibacterial and antistatic POS machine. plastic shell.
[0021] 本发明的抗菌性能通过玻璃载体银系无机抗菌剂实现: [0021] The antibacterial properties of the present invention are achieved by a glass carrier silver-based inorganic antimicrobial agent:
银离子的抗菌能力是公知的, 银的化学结构决定了银具有较高的催化能力, 高氧化态银的还 原势极高, 足以使其周围空间产生原子氧。 原子氧具有强氧化性可以灭菌, Ag+可以强烈地 吸引细菌体中蛋白酶上的巯基 (-SH), 迅速与其结合在一起, 使蛋白酶丧失活性, 导致细菌 死亡。 当细菌被 Ag+杀后, Ag+又由细菌尸体中游离出来, 再与其它菌落接触, 周而复始地 进行上述过程, 这也是银杀菌持久性的原因。 The antibacterial ability of silver ions is well known. The chemical structure of silver determines the high catalytic ability of silver, and the high oxidation state of silver is extremely high enough to generate atomic oxygen in its surrounding space. Atomic oxygen has strong oxidizing properties and can be sterilized. Ag+ can strongly attract the sulfhydryl group (-SH) on the protease in the bacterial body, and bind it quickly to inactivate the protease, leading to bacterial death. When the bacteria are killed by Ag+, Ag+ is released from the corpses of the bacteria and then contacted with other colonies, and the above process is repeated, which is also the reason for the persistence of silver sterilization.
[0022] 而玻璃是化学稳定性极好的材料, 玻璃可作为载体负载金属离子, 将具有抗菌功能的 银以银离子的形态附载于玻璃结构中, 银离子随着玻璃的溶解而溶出, 从而使材料表现出抗 菌性能。  [0022] The glass is a material having excellent chemical stability, the glass can serve as a carrier to support metal ions, and the silver having an antibacterial function is attached to the glass structure in the form of silver ions, and the silver ions are dissolved as the glass dissolves, thereby The material is rendered antimicrobial.
[0023] 以下是 POS机塑料外壳添加不同比例的抗菌剂取得的抗菌性能的测试结果:  [0023] The following are the test results of the antibacterial properties obtained by adding different proportions of antibacterial agents to the plastic casing of the POS machine:
Figure imgf000005_0001
Figure imgf000005_0001
Figure imgf000005_0002
本发明的抗静电性能通过抗静电剂实现: 高分子永久型抗静电剂属亲水性聚合物。 当其和高分子基体共混后, 一方面由于其分子链的 运动能力较强, 分子间便于质子移动, 通过离子导电来传导和释放产生的静电荷; 另一方面, 抗静电能力是通过其特殊的分散形态体现的。 高分子永久型抗静电剂主要是在制品表层呈微 细的层状或筋状分布, 构成导电性表层, 而在中心部分几乎呈球状分布, 形成所谓的 "芯壳 结构", 并以此为通路泄漏静电荷。 因为高分子永久型抗静电剂是以降低材料体积电阻率来达 到抗静电效果, 不完全依赖表面吸水, 所以受环境的湿度影响比较小。
Figure imgf000005_0002
The antistatic property of the present invention is achieved by an antistatic agent: The polymer permanent antistatic agent is a hydrophilic polymer. When it is blended with the polymer matrix, on the one hand, due to its strong molecular chain movement ability, the protons are easy to move between molecules, and the generated electrostatic charge is transmitted and released by ion conduction; on the other hand, the antistatic ability is through Special dispersion form is reflected. The polymer permanent antistatic agent is mainly distributed in the layered or ribbed layer on the surface of the product to form a conductive surface layer, and is distributed almost spherically in the central portion to form a so-called "core shell structure". Leaking static charge. Because the polymer permanent antistatic agent achieves an antistatic effect by reducing the volume resistivity of the material, it does not completely depend on the surface water absorption, so it is less affected by the humidity of the environment.
[0024] 以下是 POS机塑料外壳添加不同比例的抗静电剂取得的抗静电性能的测试结果:  [0024] The following are the test results of the antistatic properties obtained by adding different proportions of antistatic agents to the plastic case of the POS machine:
Figure imgf000006_0001
Figure imgf000006_0001
下面通过具体实施例对本发明作进一步的说明。 The invention is further illustrated by the following specific examples.
[0025] 实施例 1 :  [0025] Example 1 :
( 1 ) 烘料: 抗静电剂在添加前先充分烘干, 在设定温度 70~80°C的干燥机内烘干 4个小时。  (1) Baking material: The antistatic agent is fully dried before being added, and dried in a dryer with a set temperature of 70 to 80 ° C for 4 hours.
[0026] (2)配料: 按下列比例配制: 95.9%的合成树脂 PC+ABS原料, 0.9%的玻璃载体银系 无机抗菌剂, 2.5%的高分子永久型抗静电剂, 0.2%的抗氧化剂, 0.5%的偶联剂。 (2) Ingredients: Prepared in the following proportions: 95.9% synthetic resin PC+ABS raw material, 0.9% glass carrier silver inorganic antibacterial agent, 2.5% polymeric permanent antistatic agent, 0.2% antioxidant , 0.5% coupling agent.
[0027] (3) 搅拌: 按比例混合的配料在 190°C~230°C的温度范围内通过高混机搅拌均匀。 [0027] (3) Stirring: The ingredients mixed in proportion are uniformly stirred by a high mixer in a temperature range of 190 ° C to 230 ° C.
[0028] (4) 造粒: 通过双螺杆造粒机挤出, 经过冷却水槽和吹干机, 最后切粒, 即可制得 具有抗菌抗静电的塑料母料。 [0028] (4) Granulation: Extrusion by a twin-screw granulator, passing through a cooling water tank and a dryer, and finally pelletizing, a plastic masterbatch having antibacterial and antistatic properties can be obtained.
[0029] (5 ) 注塑成型: 将制得的塑料母粒, 根据基材设定模温、 压力、 时间等各种成型参 数, 利用模具通过注塑机注塑成型, 即制得具有抗菌抗静电的 POS机塑料外壳。  [0029] (5) Injection molding: The prepared plastic masterbatch is subjected to various molding parameters such as mold temperature, pressure and time according to the substrate, and is injection molded by an injection molding machine, thereby obtaining antibacterial and antistatic properties. POS machine plastic case.
[0030] 实施例 2: [0030] Example 2:
( 1 ) 烘料: 抗静电剂在添加前先充分烘干, 在设定温度 70~80°C的干燥机内烘干 4个小时。  (1) Baking material: The antistatic agent is fully dried before being added, and dried in a dryer with a set temperature of 70 to 80 ° C for 4 hours.
[0031] (2) 配料: 按下列比例配制: 96.5%的合成树脂 ABS原料, 0.8%的玻璃载体银系无 机抗菌剂, 2%的高分子永久型抗静电剂, 0.2%的抗氧化剂, 0.5%的偶联剂。 [0031] (2) Ingredients: Prepared in the following proportions: 96.5% synthetic resin ABS raw material, 0.8% glass carrier silver inorganic antibacterial agent, 2% polymeric permanent antistatic agent, 0.2% antioxidant, 0.5 % coupling agent.
[0032] (3) 搅拌: 按比例混合的配料在 190°C~230°C的温度范围内通过高混机搅拌均匀。 [0032] (3) Stirring: The ingredients mixed in proportion are uniformly stirred by a high mixer in a temperature range of 190 ° C to 230 ° C.
[0033] (4) 造粒: 通过双螺杆造粒机挤出, 经过冷却水槽和吹干机, 最后切粒, 即可制得 具有抗菌抗静电的塑料母料。 [0033] (4) Granulation: Extrusion by a twin-screw granulator, passing through a cooling water tank and a dryer, and finally pelletizing, a plastic masterbatch having antibacterial and antistatic properties can be obtained.
[0034] (5 ) 注塑成型: 将制得的塑料母粒, 根据基材设定模温、 压力、 时间等各种成型参 数, 利用模具通过注塑机注塑成型, 即制得具有抗菌抗静电的 POS机塑料外壳。 [0034] (5) injection molding: the prepared plastic masterbatch, according to the substrate set mold temperature, pressure, time and other various molding parameters The number of plastic molds of POS machines with antibacterial and antistatic properties is obtained by injection molding using a mold.
[0035] 本发明的主要优点: [0035] The main advantages of the invention:
1、公知的电子产品抗菌外壳塑料选用的无机抗菌剂则都为沸石载体, 玻璃载体的抗菌性虽然 不足沸石载体, 但是玻璃载体的稳定性和长效性最好, 在控制好添加比例的条件下同样可以 达到极强的抗菌效果, 故本发明优选玻璃载体银系无机抗菌剂。  1. The known inorganic antibacterial agents for the antibacterial shell plastics of electronic products are all zeolite carriers. Although the antibacterial property of the glass carrier is less than that of the zeolite carrier, the stability and long-term stability of the glass carrier are the best, and the conditions for controlling the addition ratio are controlled. The same strong antibacterial effect can be achieved under the same conditions. Therefore, the glass carrier silver-based inorganic antibacterial agent is preferred in the present invention.
[0036] 其中抗菌剂的最优化配比为 0.9%, 比外界所用的 0.5~1.5%的比例范围更为精确,有效 的控制抗菌剂原料相对昂贵的价格成本。  [0036] wherein the optimum ratio of the antibacterial agent is 0.9%, which is more precise than the range of 0.5 to 1.5% used by the outside world, and the cost of controlling the antibacterial agent raw material is relatively expensive.
[0037] 2、高分子永久型抗静电剂是亲水性聚合物,可以赋予疏水性聚合物永久性抗静电性能, 但又基本上不影响其它性质, 这是其它改性剂所不具备的优点。 其以降低材料体积电阻率来 达到抗静电效果 , 不完全依赖表面吸水, 所以受环境的湿度影响比较小。 而其它类型抗静电 剂需要在外界环境湿度高的时候, 抗静电剂分子的吸水性就越强 , 抗静电性能才越显著。 故 本发明优选稳定性和长效性最佳的高分子永久型抗静电剂。  [0037] 2. The polymer permanent antistatic agent is a hydrophilic polymer which can impart permanent antistatic properties to the hydrophobic polymer, but does not substantially affect other properties, which is not possessed by other modifiers. advantage. It achieves an antistatic effect by reducing the volume resistivity of the material, and does not completely depend on the surface water absorption, so it is less affected by the humidity of the environment. Other types of antistatic agents need to have higher water absorption of the antistatic agent molecules when the external environment humidity is high, and the antistatic performance is more remarkable. Therefore, the present invention is preferably a polymer permanent antistatic agent which is excellent in stability and long-term effectiveness.
[0038] 3、 同时添加抗菌剂和抗静电剂, 对原基材(ABS或 PC+ABS) 的物性并没有受到太大 的影响, 成品经过振动、 落下、 高低温循环、 抗老化实验测试均保持正常良品状态。  [0038] 3, at the same time adding antibacterial agent and antistatic agent, the physical properties of the original substrate (ABS or PC + ABS) did not have much impact, the finished product after vibration, drop, high and low temperature cycle, anti-aging test Maintain a normal good condition.
[0039] 以上是本发明的较佳实施例, 凡依本发明技术方案所作的改变, 所产生的功能作用未 超出本发明技术方案的范围时, 均属于本发明的保护范围。  The above is a preferred embodiment of the present invention, and any changes made by the technical solutions of the present invention do not depart from the scope of the technical solutions of the present invention.

Claims

权利要求书 Claim
1.一种抗菌抗静电的金融 POS机塑料外壳, 其特征在于, 所述 POS机塑料外壳的组威 成分包插5 95.8»/^96.8%»合戚树脂, 0.5β/ 1.0%»玻璃载体儀系无輒搞菡剂, 2 2.5%»离 分子永久型抗静电細, 0.2%«抗氧化割, 0.5%的偶联剂。 1. An antibacterial antistatic anti-static financial POS machine plastic casing, characterized in that the plastic component of the POS machine has a component package of 5 95.8»/^96.8%» 戚 resin, 0.5 β / 1.0%» glass carrier The instrument is flawless, 2 2.5%»molecular permanent antistatic, 0.2% «antioxidant cut, 0.5% coupling agent.
2.權据权利要求 1 所述的一种抗菌 静电 金融 POS Λ塑料 壳, 其特征在于, * POS机塑料外壳的龜成成 包 95.9%龜合威 脂 PC+ABS原料, 0,9¾釣義璃载律银系无 机抗菌剂, 2.5%的高分子永久型抗静电剂, 0.2%的抗氧化剂, 0.5%的偶联剂。  2. An antibacterial electrostatic financial POS Λ plastic shell according to claim 1, characterized in that: * POS machine plastic shell of the turtle into a package of 95.9% of the tortoise grease PC + ABS raw material, 0, 93⁄4 fishing Glass-based silver-based inorganic antibacterial agent, 2.5% polymer permanent antistatic agent, 0.2% antioxidant, 0.5% coupling agent.
3.棍据校利要求 1 銜述的一种挑菌挑静电》金融 POS机塑料 壳, 其特征在于, 盾述 POS机塑料外壳的组成成分包括: 96.5%的合成树顯 ABS t料, 0.8%»玻璃载悻键系无机擒 菌剂, 2%的高分子永久型钪静电剂, 0.2%的抗氧 ft割, 0.5%»偶联剂 β 3. According to the school's profit requirement 1 a kind of picking bacteria to pick up static electricity" financial POS machine plastic shell, which is characterized by the composition of the plastic shell of the POS machine including: 96.5% synthetic tree ABS material, 0.8 %»Glass-loaded 系 bond is an inorganic bacteriostatic agent, 2% polymer permanent bismuth electrostatic agent, 0.2% anti-oxygen ft cutting, 0.5%»Coupling agent β
4.根据权利要求 1所述的一种抗菌抗静电的金触 POS机塑料外壳的制备方法,其特征在 于, 包 下步骤- The method for preparing a plastic outer shell of an antibacterial antistatic anti-static gold touch POS machine according to claim 1, wherein the step of substituting -
( 1 ) 充分洪千高分子永久靈抗静电剂; (1) Full Hongji Polymer Permanent Antistatic Agent;
(2)配料:按下列比例配制所述 POS机塑料外壳的组成原料: 95,8%~96.8%翁合成树脂 (2) Ingredients: The composition of the plastic shell of the POS machine is prepared according to the following ratio: 95,8%~96.8% Weng synthetic resin
0.5¾r .0%的玻璃载体银系无机 菌割, 2%~2.5%翁高分子永久型擒静电割, 0.2%«抗氧化 剂, 0.5%的偶联割; 0.53⁄4r. 0% of glass carrier silver-based inorganic bacteria cutting, 2%~2.5% Weng polymer permanent type 擒 electrostatic cutting, 0.2% «antioxidant, 0.5% coupling cutting;
(3 )搅拌: 将上述按比例配制的组成原料在 1 0'C~230*C的温度范围内通过高泡机挽拌 均匀:  (3) Stirring: The above-mentioned proportioned raw materials are uniformly mixed in a temperature range of 10'C~230*C through a high foaming machine:
(4)造粒: 将上述搅擰 ¾匀的组虑原料通过造粒机挤出, 经过冷却吹干, 最后切粒, 制 得抗菌抗静电 塑料母料;  (4) granulation: the above-mentioned raw materials which are stirred and twisted are extruded through a granulator, cooled and dried, and finally granulated to obtain an antibacterial antistatic plastic master batch;
( 5 )注塑成型: 将制得的塑料母粒, 根据基材设定各种成型参数, 利用模具通过注塑机 注塑成型, «得抗菌 tt静电 tt POS机塑料外壳 β (5) Injection molding: The prepared plastic masterbatch is set according to various molding parameters of the substrate, and is injection molded by the injection molding machine. «Antibacterial tt electrostatic tt POS machine plastic casing β
替换貢(细则第 20条) Replacement tribute (Article 20)
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CN103435996B (en) * 2013-08-10 2016-03-23 福建联迪商用设备有限公司 Financial POS machine plastic casing of a kind of antibacterial antistatic and preparation method thereof
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CN111087749A (en) * 2019-12-28 2020-05-01 会通新材料股份有限公司 Permanent antibacterial antistatic ABS alloy material and preparation method and application thereof
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101130683A (en) * 2007-08-06 2008-02-27 海信集团有限公司 Antimicrobial dust-proof material for air-conditioning fan and method for producing the same
CN101677575A (en) * 2007-04-18 2010-03-24 巴斯夫欧洲公司 antimicrobial plastics and coatings
CN102464821A (en) * 2010-11-18 2012-05-23 上海杰事杰新材料(集团)股份有限公司 Antibacterial aging-resistant antistatic plastic master batch and preparation method thereof
CN103435996A (en) * 2013-08-10 2013-12-11 福建联迪商用设备有限公司 Antibacterial and anti-static financial POS machine plastic casing and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1225062C (en) * 2002-10-21 2005-10-26 钟诚 Antibacterial plastic switch plug and method for making same
US7504054B2 (en) * 2003-12-11 2009-03-17 Bayer Materialscience Llc Method of treating a plastic article
CN101070424A (en) * 2007-05-24 2007-11-14 深圳市科聚新材料有限公司 Antibacterial engineering plastic and its preparing method
CN102585429B (en) * 2011-01-11 2015-02-25 合肥杰事杰新材料股份有限公司 Resin material, preparation method and applications of resin material
CN102653617B (en) * 2012-05-03 2014-08-27 光大环保科技发展(北京)有限公司 Environment-friendly antibacterial ABS (Acrylonitrile Butadiene StyreneAcrylonitrile Butadiene Styrene) plastic and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101677575A (en) * 2007-04-18 2010-03-24 巴斯夫欧洲公司 antimicrobial plastics and coatings
CN101130683A (en) * 2007-08-06 2008-02-27 海信集团有限公司 Antimicrobial dust-proof material for air-conditioning fan and method for producing the same
CN102464821A (en) * 2010-11-18 2012-05-23 上海杰事杰新材料(集团)股份有限公司 Antibacterial aging-resistant antistatic plastic master batch and preparation method thereof
CN103435996A (en) * 2013-08-10 2013-12-11 福建联迪商用设备有限公司 Antibacterial and anti-static financial POS machine plastic casing and preparation method thereof

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