WO2015007090A1 - 浅埋煤层矿区地表堵漏的无机固化泡沫材料及制备方法 - Google Patents
浅埋煤层矿区地表堵漏的无机固化泡沫材料及制备方法 Download PDFInfo
- Publication number
- WO2015007090A1 WO2015007090A1 PCT/CN2014/072169 CN2014072169W WO2015007090A1 WO 2015007090 A1 WO2015007090 A1 WO 2015007090A1 CN 2014072169 W CN2014072169 W CN 2014072169W WO 2015007090 A1 WO2015007090 A1 WO 2015007090A1
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- WO
- WIPO (PCT)
- Prior art keywords
- parts
- inorganic
- slurry
- powder
- rpm
- Prior art date
Links
- 239000003245 coal Substances 0.000 title claims abstract description 22
- 239000006261 foam material Substances 0.000 title claims abstract description 12
- 238000005065 mining Methods 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000002002 slurry Substances 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000005751 Copper oxide Substances 0.000 claims abstract description 14
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 14
- 239000006260 foam Substances 0.000 claims abstract description 14
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 13
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 13
- 235000011116 calcium hydroxide Nutrition 0.000 claims abstract description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 12
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 10
- 229920000137 polyphosphoric acid Polymers 0.000 claims abstract description 10
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 9
- 239000004568 cement Substances 0.000 claims abstract description 9
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000010959 steel Substances 0.000 claims abstract description 9
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims abstract description 8
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims abstract description 8
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 8
- 239000000853 adhesive Substances 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 21
- 239000010881 fly ash Substances 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 12
- 239000012530 fluid Substances 0.000 claims description 9
- 210000003097 mucus Anatomy 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 2
- 238000005187 foaming Methods 0.000 abstract description 4
- 239000010883 coal ash Substances 0.000 abstract 4
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 description 6
- 239000003292 glue Substances 0.000 description 6
- 230000002269 spontaneous effect Effects 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- 210000002421 cell wall Anatomy 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000011496 polyurethane foam Substances 0.000 description 2
- 239000003566 sealing material Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009933 burial Methods 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
- C04B28/342—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders the phosphate binder being present in the starting composition as a mixture of free acid and one or more reactive oxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00724—Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Definitions
- the invention relates to an inorganic solidified foam material and a preparation method thereof, in particular to an inorganic solidified foam material for surface plugging in a shallow buried coal seam mining area and a preparation method thereof.
- Coal spontaneous combustion is one of the most important disasters faced by coal mine safety production in China, which seriously threatens the safety of underground workers and the normal mining of the working face, resulting in significant economic losses.
- the focus of China's energy strategy has shifted westward, while the coal seams in the shallow buried mining areas in the west are prone to spontaneous combustion and shallow burial (the buried depth is generally 30 ⁇ 250m), and the surface fissures are severely leaked.
- the resulting coal spontaneous combustion is more and more frequent, in order to be efficient.
- crack sealing is carried out, and the contact between oxygen and coal in the goaf becomes one of the most effective means to prevent mine fire.
- the purpose of the invention is to provide a foaming ratio of 7 to 10 times, which can quickly penetrate into small cracks, and the effect of blocking air leakage is obvious. Adjustable time, high compressive strength after curing, high temperature resistance, good heat insulation performance, inorganic solidified foam material for surface plugging of shallow buried coal seam mining area with pure inorganic and non-polluting substrate and preparation method.
- the technical solution of the present invention comprises an inorganic curable foam material and a preparation method thereof;
- the inorganic curable foam material comprises the following components and parts by weight: 40-60 parts of water, 100 parts of fly ash, 5 parts of slaked lime, 20 parts of cement , horn powder 0.15-0.3 parts, aluminum powder 4 parts, copper oxide 1-3.5 parts, polyphosphoric acid 0.4-1.4 parts, aluminum hydroxide 0.04-0.1 parts, hydroxypropyl methyl cellulose 0.8-1.2 parts, steel fiber 3 parts; the copper oxide is 300 mesh.
- the mucus formed by the horn powder can reduce the surface tension of the slurry, so that the solid particles in the slurry are dispersed and the stability of the foam is improved; the aluminum powder and the slaked lime react chemically to generate gas, which together constitute the slurry.
- Step 1 Add 35-55 parts of water, 100 parts of fly ash, 20 parts of cement, 0.8-1.2 parts of hydroxypropyl methylcellulose, 3 parts of steel fiber, 5 parts of slaked lime to the special mixing container A, and stirrer Rotating at 5000 ⁇ 200 rpm, stirring time is 2 min, forming a slurry of fly ash substrate;
- Step 2 Add 5 parts of water and 0.15-0.3 parts of horn powder in the special mixing container B, and rotate the mixer at a speed of 10000 ⁇ 500 rpm, and stir for 3 minutes to form a mucus;
- Step 3 Add the horn powder in the special mixing container B to the fly ash substrate slurry in the special mixing container A.
- the special mixing container A stirrer rotates at 12000 ⁇ 500 rpm, and the stirring time is 3 min.
- Step 4 Add a mixture of 1-3.5 parts of copper oxide, 0.4-1.4 parts of polyphosphoric acid and 0.04-0.1 parts of aluminum hydroxide to the mixture, and the stirrer rotates at 5000 ⁇ 200 rpm, stirring. The time is 5 min, forming a mixed glue solution;
- Step 5 4 parts of aluminum powder is added to the mixed glue liquid, the stirrer is rotated at 12000 ⁇ 500 rpm, and the stirring time is 3 min, and the inorganic solidified foam fluid material for crack sealing of coal mine surface is prepared.
- the utility model has the advantages that the mucus formed by the horn powder and the water of the invention can make the solid phase particles of the fly ash base material be uniformly dispersed, which contributes to the stability of the cells and can improve the foaming efficiency of the hydrogen gas; Copper oxide, polyphosphoric acid, and aluminum hydroxide react as an inorganic adhesive system. By changing the ratio between the three, 15 mit can be achieved at room temperature! The solidification time of the solution is adjustable between ⁇ 2h; finally, the aluminum powder and the hydrated lime (calcium hydroxide) aqueous solution react to form hydrogen as a self-reactive air entraining agent for the slurry.
- Hydroxypropyl methylcellulose can thicken the slurry in the early stage, which helps the foam fluid to seep in the fine cracks. After curing, it can increase the toughness of the solidified foam.
- the steel fibers are dispersed on the cell walls. After solidification, as the skeleton of the cell wall, the foam is connected to improve the compressive performance of the solidified foam; the cement promotes the hydration reaction of the fly ash, and acts as an activator to rapidly solidify the fly ash.
- the inorganic solidified foam fluid material of the invention does not need an external gas source, and only relies on the chemical reaction of aluminum powder and slaked lime in the slurry system to generate gas as a gas source, and the process flow is simple; the foam fluid has good permeation performance, and the solidification time is adjustable, and the plugging is blocked. The wind effect is remarkable; the foaming ratio is high, the compressive strength is high, the high temperature resistance and the heat insulation performance are good, and the price is cheap; and the utility model has wide applicability in the field of surface crack sealing in coal mine and coal field fire area.
- Example 1 First, 35 parts by weight of water, 100 parts by weight of fly ash, 20 parts by weight of cement, 0.8 parts by weight of hydroxypropylmethylcellulose, 3 parts by weight of steel fiber, and 5 parts by weight of slaked lime were added to the dedicated mixing vessel A.
- the stirrer is rotated at 5000 ⁇ 200 rpm, and the stirring time is 2 min to form a slurry of fly ash base material; then, 5 parts of water, 0.15 parts by weight of horn powder, and 10000 ⁇ 500 are added to the special mixing container B.
- the rotation speed of the revolution/minute is rotated for 3 minutes to form a mucus; then, the horn powder in the special mixing container B is added to the slurry of the fly ash substrate in the special mixing container A, and the special mixing container A stirrer is 12000 ⁇ Rotating at 500 rpm, stirring for 3 min, forming a mixed solution; then, adding 1 part by weight of copper oxide, 0.4 parts by weight of polyphosphoric acid, and 0.04 parts by weight of aluminum hydroxide to the mixture.
- the copper oxide is 300 mesh, the stirrer rotates at 5000 ⁇ 200 rpm, and the stirring time is 5 min to form a mixed glue; finally, 4 parts of aluminum powder is added to the mixed glue.
- Example 2 First, 50 parts by weight of water, 100 parts by weight of fly ash, 20 parts by weight of cement, 1.0 part by weight of hydroxypropylmethylcellulose, 3 parts by weight of steel fiber, and 5 parts by weight of slaked lime were added to the dedicated mixing vessel A.
- the stirrer is rotated at 5000 ⁇ 200 rpm, and the stirring time is 2 min to form a slurry of fly ash substrate; then 5 parts of water, 0.25 parts by weight of horn powder, and 10000 ⁇ 500 of agitator are added to the special mixing container B.
- the rotation speed of the revolution/minute is rotated for 3 minutes to form a mucus; then, the horn powder in the special mixing container B is added to the slurry of the fly ash substrate in the special mixing container A, and the special mixing container A stirrer is 12000 ⁇ Rotating at 500 rpm, stirring time is 3 min, forming a mixed solution; then, adding 2 parts by weight of copper oxide, 0.8 parts by weight of polyphosphoric acid, and 0.08 parts by weight of aluminum hydroxide to the mixture, The copper oxide is 300 mesh, the stirrer is rotated at 5000 ⁇ 200 rpm, and the stirring time is 5 min to form a mixed glue; finally, 4 parts of the aluminum powder is added to the mixed glue.
- the 2MPa ground moving grouting pump is used to inject the prepared inorganic solidified foam fluid into the surface crack of the coalfield fire area where the wind leakage is required through the conveying pipeline, thereby reducing and controlling the air leakage, thereby preventing coal spontaneous combustion.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Sealing Material Composition (AREA)
- Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2014253466A AU2014253466B2 (en) | 2013-07-17 | 2014-02-18 | Inorganic cured foam material for surface leaking stoppage in shallow buried coal seam mining area and preparation method of the same |
RU2014143659/03A RU2592912C2 (ru) | 2013-07-17 | 2014-02-18 | Неорганический отвержденный пеноматериал для остановки течей на поверхности в районе добычи угля в пласте неглубокого залегания и способ его получения |
ZA2014/07486A ZA201407486B (en) | 2013-07-17 | 2014-10-15 | Inorganic cured foam material for surface leaking stoppage in shallow buried coal seam mining area and preparation method of the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310301511.2A CN103396154B (zh) | 2013-07-17 | 2013-07-17 | 浅埋煤层矿区地表堵漏的无机固化泡沫材料 |
CN201310301511.2 | 2013-07-17 |
Publications (1)
Publication Number | Publication Date |
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WO2015007090A1 true WO2015007090A1 (zh) | 2015-01-22 |
Family
ID=49559944
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2014/072169 WO2015007090A1 (zh) | 2013-07-17 | 2014-02-18 | 浅埋煤层矿区地表堵漏的无机固化泡沫材料及制备方法 |
Country Status (5)
Country | Link |
---|---|
CN (1) | CN103396154B (zh) |
AU (1) | AU2014253466B2 (zh) |
RU (1) | RU2592912C2 (zh) |
WO (1) | WO2015007090A1 (zh) |
ZA (1) | ZA201407486B (zh) |
Cited By (2)
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---|---|---|---|---|
CN113773827A (zh) * | 2021-08-31 | 2021-12-10 | 广汉市福客科技有限公司 | 一种自发泡延缓型固体泡沫排水剂及其制备方法 |
CN115849839A (zh) * | 2022-11-24 | 2023-03-28 | 湖南科技大学 | 一种用于采空区密闭裂隙封堵的修复型泡沫及其制备方法 |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103396154B (zh) * | 2013-07-17 | 2014-12-31 | 中国矿业大学 | 浅埋煤层矿区地表堵漏的无机固化泡沫材料 |
CN103967512B (zh) * | 2014-03-31 | 2016-08-17 | 中国矿业大学 | 一种矿用防治煤炭自燃的水基泡沫及其制备方法 |
CN103964766B (zh) * | 2014-04-29 | 2016-09-14 | 胡相明 | 防治煤炭自燃的粉煤灰-水泥泡沫材料及其制备方法 |
CN105435411B (zh) * | 2015-12-01 | 2018-09-25 | 太原理工大学 | 一种用于煤自燃灾害防治的金属骨架泡沫及其制备方法 |
CN106679207B (zh) * | 2017-01-09 | 2018-10-30 | 中国矿业大学 | 一种提取煤田火区地下高温区热能的方法 |
CN106593523B (zh) * | 2017-01-23 | 2018-08-17 | 中国矿业大学 | 一种浅埋近距煤层开采过程中采空区漏风控制方法 |
CN112480648B (zh) * | 2020-11-26 | 2022-05-03 | 湖南科技大学 | 浅埋煤层堵漏风与氧化产热吸排的浆泡材料及其制备方法 |
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- 2013-07-17 CN CN201310301511.2A patent/CN103396154B/zh not_active Expired - Fee Related
-
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- 2014-02-18 WO PCT/CN2014/072169 patent/WO2015007090A1/zh active Application Filing
- 2014-02-18 RU RU2014143659/03A patent/RU2592912C2/ru not_active IP Right Cessation
- 2014-02-18 AU AU2014253466A patent/AU2014253466B2/en not_active Ceased
- 2014-10-15 ZA ZA2014/07486A patent/ZA201407486B/en unknown
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113773827A (zh) * | 2021-08-31 | 2021-12-10 | 广汉市福客科技有限公司 | 一种自发泡延缓型固体泡沫排水剂及其制备方法 |
CN115849839A (zh) * | 2022-11-24 | 2023-03-28 | 湖南科技大学 | 一种用于采空区密闭裂隙封堵的修复型泡沫及其制备方法 |
CN115849839B (zh) * | 2022-11-24 | 2023-10-31 | 湖南科技大学 | 一种用于采空区密闭裂隙封堵的修复型泡沫及其制备方法 |
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ZA201407486B (en) | 2016-11-30 |
AU2014253466A1 (en) | 2015-02-05 |
RU2592912C2 (ru) | 2016-07-27 |
CN103396154B (zh) | 2014-12-31 |
RU2014143659A (ru) | 2016-05-27 |
AU2014253466B2 (en) | 2015-03-26 |
CN103396154A (zh) | 2013-11-20 |
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