WO2014203464A1 - 方向性電磁鋼板およびそれを用いた変圧器鉄心 - Google Patents
方向性電磁鋼板およびそれを用いた変圧器鉄心 Download PDFInfo
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- WO2014203464A1 WO2014203464A1 PCT/JP2014/002804 JP2014002804W WO2014203464A1 WO 2014203464 A1 WO2014203464 A1 WO 2014203464A1 JP 2014002804 W JP2014002804 W JP 2014002804W WO 2014203464 A1 WO2014203464 A1 WO 2014203464A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F3/00—Cores, Yokes, or armatures
- H01F3/02—Cores, Yokes, or armatures made from sheets
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/125—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest with application of tension
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1277—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular surface treatment
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1277—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular surface treatment
- C21D8/1288—Application of a tension-inducing coating
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/24—Magnetic cores
- H01F27/245—Magnetic cores made from sheets, e.g. grain-oriented
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/16—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets
Definitions
- the present invention relates to a grain-oriented electrical steel sheet having a low iron loss, which is suitable for use in iron core materials such as a transformer, and more particularly to a grain-oriented electrical steel sheet subjected to magnetic domain subdivision.
- Oriented electrical steel sheets are mainly used as iron core materials for transformers and the like, and are required to have excellent magnetization characteristics, particularly low iron loss.
- secondary recrystallized grains in the steel sheet should be accumulated in the (110) [001] orientation (so-called Goth orientation), and impurities and precipitates present in the final product steel should be reduced as much as possible. is important.
- the control of crystal orientation and the reduction of impurities and precipitates are limited due to the balance of manufacturing costs.
- a technique for reducing the iron loss by subdividing the width of the magnetic domain by introducing non-uniformity to the surface of the steel sheet by a physical method, that is, a magnetic domain subdivision technique has been developed.
- Patent Document 1 and Patent Document 2 irradiate the surface of the final product plate with a laser beam or an electron beam at intervals of several millimeters at a substantially right angle to the rolling direction, and form a linear high dislocation density region on the steel sheet surface layer.
- a technique for reducing iron loss by narrowing the magnetic domain width by introducing (distortion) is disclosed.
- Patent Document 3 discloses a steel sheet per 280 mm in length of the strain-introducing surface after the strain-introducing treatment, which satisfies a predetermined relationship with the tension applied to the steel plate surface of the tension-applying insulating coating before the strain-introducing treatment.
- a grain-oriented electrical steel sheet is disclosed in which the iron loss is reduced by restricting the amount of warpage to 1 mm to 10 mm, particularly 3 mm to 8 mm.
- the warpage of this steel sheet depends on the irradiation conditions such as laser beam or electron beam when introducing strain.
- Conditions that have a particularly large influence include beam output, beam scanning speed, beam spot shape, irradiation line interval, and the like.
- an object of the present invention is to provide a grain-oriented electrical steel sheet that can further reduce the iron loss of a transformer and consequently contribute to higher efficiency of the transformer.
- the grain-oriented electrical steel sheet is further pressed by a structural steel sheet or the like after being laminated in the shape of the iron core. Therefore, even if the grain-oriented electrical steel sheet is warped at the stage of the iron core material, the grain-oriented electrical steel sheet is straightened in the fabricated core. Conventionally, the smaller the deformation at the time of correction, the smaller the stress applied at the time of correction, so the range of warping has been restricted under the technical idea that the magnetic properties are not deteriorated. However, in reality, since the warpage of the steel sheet is concentrated at the portion where the distortion is introduced, the stress generated by the correction of the warpage is not uniformly applied to the steel sheet.
- a grain-oriented electrical steel sheet in which the introduction of strain linearly in a direction intersecting with the rolling direction of the steel sheet is repeated at intervals in the rolling direction and magnetic domain subdivision is performed.
- the repetition distance in the direction is d (mm)
- d (mm) when the steel sheet is placed on a flat surface, the height from the flat surface at the center of the line portion where the distortion of the steel sheet surface is introduced, and the mutual distance between the line portions
- the ratio h / d to d is 0.0025 or more and 0.015 or less, where h (mm) is the average value of the difference from the flat surface at the equally divided point. Electrical steel sheet.
- iron loss in a transformer can be reliably reduced by giving an appropriate shape when placed on a flat surface to a grain-oriented electrical steel sheet subjected to magnetic domain refinement by introducing strain.
- the present invention is characterized in that the shape of the grain-oriented electrical steel sheet, which has been subdivided by introduction of strain, is appropriately regulated in a state where the steel sheet is placed on a flat surface.
- strain line which is a line portion into which strain is introduced
- the shape of the steel plate at this time is affected by the repetition interval of the strain in the rolling direction and the size of the strain introduced in the vicinity of the strain line, so that the warpage of the steel plate before placing on the flat surface is the same.
- the shape of the steel plate after being placed on a flat surface is not necessarily the same.
- this steel plate is pressed down with a structural steel plate or tightened with a glass tape or the like, and is corrected to be flat, but even in this case, the wavy shape remains, The steel plates do not become completely flat, and a slight gap is generated between the steel plates. This gap lowers the space factor of the iron core and increases the substantial magnetic flux density of the transformer being excited, causing the iron loss to deteriorate in the transformer.
- the warped steel plate when the warped steel plate is straightened, for example, when an iron core is produced, a tensile stress is generated inside the warp, so that the magnetic domain refinement effect is enhanced.
- the outer surface of the warp causes a compressive stress, but there is no portion where the stress is concentrated. Therefore, if the warpage is not excessive, the influence of the stress on the magnetic deterioration is small. That is, the warpage of the steel sheet caused by the distortion works well on the iron loss depending on the stress generated when the steel sheet is straightened.
- the steel plate 1 when the linear strain introduced into the surface of the steel plate 1 is d (mm) in the rolling direction and the steel plate 1 is placed on a flat surface.
- the difference between the height from the flat surface at the center of the line portion where the surface distortion is introduced and the height from the flat surface at the equidistant point between the line portions (hereinafter simply referred to as “height difference”). Let the average value be h (mm).
- the ratio h / d of the average value h (mm) of the height difference with respect to the repetition interval d (mm) in the rolling direction of this strain is 0.0025 or more and 0.015 or less. It was found that the iron loss of a transformer produced using this steel plate can be further reduced. When the ratio h / d is less than 0.0025, the tension generated between the strain lines is small, so the magnetic domain refinement effect is reduced and the iron loss is increased.
- parameters such as repetition interval in the rolling direction of the strain, beam intensity, beam spot shape and beam scanning speed are set. Even if it is changed, the iron loss value of the steel sheet can be made comparable by adjusting other parameters.
- the wave shape when placed on a flat surface is different if the strain wire is introduced differently. For example, when the beam intensity is high, the beam spot is small, or the beam scanning speed is high, the plastic strain introduced into the steel sheet is introduced at a high density on the surface layer. The stress when straightening the steel plate is likely to concentrate in the vicinity of the strain line, and the average value h of the height difference is also increased.
- the beam intensity (laser beam output, electron beam current, acceleration voltage), beam spot shape (focus diameter, defocus amount), beam scanning speed
- the output is 10 to 1000 W
- the beam spot diameter is 0.01 to 0.5 mm
- the scanning speed is 1 to 100 m / s
- the acceleration voltage is 10 to
- the ratio h / d is 0.0025 or more and 0.015 or less. can do.
- the above irradiation conditions are not intended to limit the present invention.
- the size of the average value h of the allowable height difference is limited by the repetition interval d in the rolling direction of strain, but d is 3 mm or more, 6 mm The following is preferable.
- the iron loss of the steel plate iron loss of the transformer
- strain can be introduced by either laser beam irradiation or electron beam irradiation, but it is preferable to introduce strain by electron beam irradiation. This is because, when laser beam irradiation and electron beam irradiation are compared, the electron beam passes through the insulating coating on the steel sheet surface and penetrates the steel sheet surface several ⁇ m to several tens of ⁇ m to generate heat, resulting in damage to the insulating coating. Is small. Furthermore, in the case of electron beam irradiation, strain introduced into the steel sheet is also distributed to the inside of the steel sheet without concentrating on the surface of the steel sheet, and stress concentration when the steel sheet is straightened is alleviated.
- linear includes not only a straight line but also a straight line, and also includes a solid line, a dotted line, a broken line, and the like.
- the “direction intersecting the rolling direction” means an angle range within ⁇ 30 ° with respect to the direction perpendicular to the rolling direction.
- the component composition of the grain-oriented electrical steel sheet according to the present invention and the production conditions thereof will be specifically described.
- the component composition of the slab for grain-oriented electrical steel sheets will not be specifically limited if it is a component composition in which secondary recrystallization with good orientation occurs.
- an inhibitor used to cause secondary recrystallization, for example, Al and N are used when an AlN inhibitor is used, and Mn and Se are used when an MnS / MnSe inhibitor is used. And / or an appropriate amount of S may be contained. Of course, both inhibitors may be used in combination.
- the preferred contents of Al, N, S and Se are Al: 0.01 to 0.065 mass%, N: 0.005 to 0.012 mass%, S: 0.005 to 0.03 mass%, and Se: 0.005 to 0.03 mass%, respectively. .
- the present invention can also be applied to grain-oriented electrical steel sheets in which the contents of Al, N, S and Se are limited and no inhibitor is used.
- the amounts of Al, N, S, and Se are preferably suppressed to Al: 100 mass ppm or less, N: 50 mass ppm or less, S: 50 mass ppm or less, and Se: 50 mass ppm or less, respectively.
- C 0.08 mass% or less C is added to improve the hot-rolled sheet structure. However, if it exceeds 0.08 mass%, C may be reduced to 50 massppm or less during the manufacturing process to prevent magnetic aging. Since it becomes difficult, it is preferable to set it as 0.08 mass% or less. In addition, regarding the lower limit, since a secondary recrystallization is possible even for a material not containing C, it is not particularly necessary to provide it.
- Si 2.0-8.0% by mass
- Si is an element effective in increasing the electrical resistance of steel and improving iron loss.
- the content is less than 2.0% by mass, a sufficient iron loss reduction effect cannot be achieved, while 8.0% by mass. If it exceeds 1, the workability is remarkably lowered and the magnetic flux density is also lowered. Therefore, the Si content is preferably in the range of 2.0 to 8.0% by mass.
- Mn 0.005 to 1.0 mass%
- Mn is an element necessary for improving the hot workability, but if the content is less than 0.005% by mass, the effect of addition is poor. On the other hand, if it exceeds 1.0% by mass, the magnetic flux density of the product plate decreases, so the Mn content is preferably in the range of 0.005 to 1.0% by mass.
- the following elements can be appropriately contained as magnetic property improving components.
- Ni 0.03-1.50% by mass
- Sn 0.01-1.50% by mass
- Sb 0.005-1.50% by mass
- Cu 0.03-3.0% by mass
- P 0.03-0.50% by mass
- Cr 0.03-1.50% by mass
- Mo At least one Ni selected from 0.005 to 0.10% by mass is an element useful for improving the hot rolled sheet structure and improving the magnetic properties.
- the content is less than 0.03% by mass, the effect of improving the magnetic properties is small.
- the amount of Ni is preferably in the range of 0.03 to 1.50% by mass.
- Sn, Sb, Cu, P, Cr and Mo are each an element useful for improving the magnetic properties, but if any of them does not meet the lower limit of each component described above, the effect of improving the magnetic properties is small, If the upper limit amount of each component described above is exceeded, the development of secondary recrystallized grains is hindered.
- the balance other than the above components is inevitable impurities and Fe mixed in the manufacturing process.
- the steel slab having the above component composition is heated and subjected to hot rolling according to a conventional method, but may be immediately hot rolled without being heated after casting.
- hot rolling may be performed, or the hot rolling may be omitted and the process may proceed as it is.
- the hot rolled sheet annealing temperature is preferably in the range of 800 to 1100 ° C.
- the hot-rolled sheet annealing temperature is less than 800 ° C, the band structure in hot rolling remains, making it difficult to achieve a sized primary recrystallization structure and inhibiting the development of secondary recrystallization.
- the hot-rolled sheet annealing temperature exceeds 1100 ° C., the grain size after the hot-rolled sheet annealing is excessively coarsened, so that it is very difficult to realize a sized primary recrystallized structure.
- the steel sheet After the hot-rolled sheet annealing, the steel sheet is subjected to cold rolling twice or more with one or more intermediate annealings, followed by primary recrystallization annealing and applying an annealing separator. After applying the annealing separator, a final finish annealing is performed for the purpose of secondary recrystallization and forsterite film formation.
- This tension coating is generally a phosphate-colloidal silica-based glass coating, but other oxides having a low thermal expansion coefficient such as alumina borate, carbides that are films that generate higher tension, and nitriding Goods are also effective.
- tension coating it is important to adjust the coating amount and baking conditions to generate sufficient tension.
- the grain-oriented electrical steel sheet of the present invention is obtained by further subjecting the grain-oriented electrical steel sheet obtained through the above process to magnetic domain subdivision by introducing strain, and placing the grain-oriented electrical steel sheet on a flat surface.
- the steel plate shape is set to an appropriate shape as described above.
- the transformer core using the above-described grain-oriented electrical steel sheet according to the present invention can further reduce the iron loss, and as a result, can contribute to higher efficiency of the transformer.
- an annealing separator containing MgO as a main component was applied, and final finish annealing including a secondary recrystallization process and a purification process was performed to obtain a grain-oriented electrical steel sheet having a forsterite film.
- an insulating coat composed of 60% colloidal silica and aluminum phosphate was dried and coated at a weight of 5 g / m 2 on one side and baked at 800 ° C.
- the iron loss per kg of steel sheet when magnetized up to 1.7 T with an alternating magnetic field with an excitation frequency of 50 Hz is W 17/50
- the magnetic flux density at a magnetic field strength of 800 A / m is B 8 To do.
- the iron loss W 17/50 and the magnetic flux density B 8 of the obtained steel plate using a single plate magnetometer they were 0.83 W / kg and 1.94 T, respectively.
- the iron core is 500mm x 500mm in outline, 100mm x 300mm in window, 100mm in thickness, and the weight of the iron core is about 145kg.
- a structural steel plate with a thickness of 2 mm was applied and pressed flat, and a jig was applied to the yoke and tightened with bolts.
- the test transformer was excited with an alternating current with a magnetic flux density of 1.7 T and a frequency of 50 Hz, and the no-load loss was measured as the iron loss of the test transformer.
- the steel plate shape was measured using a laser shape meter for each electron beam irradiation condition.
- a laser shape meter for each electron beam irradiation condition.
- cut a 100 mm wide steel strip to a length of 100 mm place the surface irradiated with the electron beam on the flat stage as the measurement surface, and tape the both ends of the steel plate in the rolling direction so that they are in close contact with the stage.
- Fixed Using a laser shape meter, measure the surface profile in the rolling direction 50mm with the center position of the steel sheet as the reference point, and check the maximum and minimum heights from the stage for each electron beam irradiation interval d (mm).
- the difference between the maximum value and the minimum value of the height was obtained, and the average value h (mm) of the height difference over the entire length of 50 mm was obtained.
- the iron loss of the steel plate for iron core materials was measured using the single plate magnetometer.
- Table 1 further shows the ratio h / d of h to the average value h and d of the iron loss, irradiation interval d, and height difference of the prototype transformer. Moreover, the iron loss of a steel plate is also shown.
- Table 1 shows that the iron loss of the prototype transformer can be reduced if the ratio h / d of h to d is 0.0025 or more and 0.015 or less, even though the iron loss of the steel sheet that is the core material is similar. .
- iron loss in a transformer can be reliably reduced by giving an appropriate shape when placed on a flat surface to a grain-oriented electrical steel sheet subjected to magnetic domain refinement by introducing strain.
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Abstract
Description
本発明は、このような知見に基づきなされたものであり、本発明の要旨構成は以下のとおりである。
歪みを導入した線部分である線状の歪み(以下、単に「歪み線」と言う。)を、鋼板の圧延方向と交差する方向へ、圧延方向に繰り返し導入することにより、方向性電磁鋼板は磁区細分化が施され、歪み導入側の面が内側になるような反りが生じるのは既述のとおりである。ここで、歪み線の導入により反った方向性電磁鋼板を、平坦面上に歪み導入面を該平坦面側として置くと、鋼板の自重により鋼板は平坦面に反りが解消された状態となるが、歪み線の導入域近傍において、歪み線を山とする波形状は鋼板に残存する(図1)。
また、二次再結晶を生じさせるために、インヒビターを利用する場合、例えばAlN系インヒビターを利用する場合であればAlおよびNを、またMnS・MnSe系インヒビターを利用する場合であればMnとSeおよび/またはSを適量含有させればよい。勿論、両インヒビターを併用してもよい。この場合におけるAl、N、SおよびSeの好適含有量はそれぞれ、Al:0.01~0.065質量%、N:0.005~0.012質量%、S:0.005~0.03質量%、Se:0.005~0.03質量%である。
Cは、熱延板組織の改善のために添加をするが、0.08質量%を超えると、Cを磁気時効の起こらない50質量ppm以下まで製造工程中に低減することが困難になるため、0.08質量%以下とすることが好ましい。なお、下限に関しては、Cを含まない素材でも二次再結晶が可能であるので特に設ける必要はない。
Siは、鋼の電気抵抗を高め、鉄損を改善するのに有効な元素であるが、含有量が2.0質量%に満たないと十分な鉄損低減効果が達成できず、一方、8.0質量%を超えると加工性が著しく低下し、また磁束密度も低下するため、Si量は2.0~8.0質量%の範囲とすることが好ましい。
Mnは、熱間加工性を良好にする上で必要な元素であるが、含有量が0.005質量%未満ではその添加効果に乏しい。一方、1.0質量%を超えると、製品板の磁束密度が低下するため、Mn量は0.005~1.0質量%の範囲とすることが好ましい。
上記の基本成分以外に、磁気特性改善成分として、次に述べる元素を適宜含有させることができる。
Niは、熱延板組織を改善して磁気特性を向上させるために有用な元素である。しかしながら、含有量が0.03質量%未満では磁気特性の向上効果が小さく、一方1.50質量%を超えると、二次再結晶が不安定になり磁気特性が劣化する。そのため、Ni量は0.03~1.50質量%の範囲とするのが好ましい。
なお、上記成分以外の残部は、製造工程において混入する不可避的不純物およびFeである。
d 歪みの繰り返し間隔
h 高さの差の平均値
Claims (4)
- 鋼板の圧延方向と交差する方向へ線状に歪みを導入することを、前記圧延方向に間隔を置いて繰り返して磁区細分化を施した方向性電磁鋼板であって、
前記歪みの圧延方向への繰り返し間隔をd(mm)とし、前記鋼板を平坦面上に置いたときの、該鋼板表面の歪みを導入した線部分中心における前記平坦面からの高さと、該線部分の相互間隔の等分点における前記平坦面からの高さとの差の平均値をh(mm)としたとき、前記dに対する前記hの比h/dが、0.0025以上0.015以下であることを特徴とする方向性電磁鋼板。 - 前記dが3mm以上6mm以下である、請求項1に記載の方向性電磁鋼板。
- 前記歪みは、電子ビーム照射により形成される、請求項1または2に記載の方向性電磁鋼板。
- 請求項1~3のいずれか1項に記載の方向性電磁鋼板を用いた変圧器鉄心。
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US14/894,697 US10559410B2 (en) | 2013-06-19 | 2014-05-27 | Grain-oriented electrical steel sheet and transformer iron core using same |
RU2016101317A RU2620833C1 (ru) | 2013-06-19 | 2014-05-27 | Лист текстурированной электротехнической стали и стальной сердечник трансформатора, в котором он используется |
CN201480034559.4A CN105339510A (zh) | 2013-06-19 | 2014-05-27 | 取向性电磁钢板及使用该取向性电磁钢板的变压器铁芯 |
EP14814563.4A EP3012332B1 (en) | 2013-06-19 | 2014-05-27 | Grain-oriented electrical steel sheet and transformer iron core using same |
KR1020167000437A KR101607909B1 (ko) | 2013-06-19 | 2014-05-27 | 방향성 전자 강판 및 그것을 이용한 변압기 철심 |
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RU2741585C1 (ru) * | 2018-01-31 | 2021-01-27 | ДжФЕ СТИЛ КОРПОРЕЙШН | Текстурированный лист из электротехнической стали, наборный сердечник трансформатора из текстурированного листа из электротехнической стали и способ изготовления наборного сердечника |
CN111868272B (zh) * | 2018-03-20 | 2022-11-15 | 日本制铁株式会社 | 方向性电磁钢板的制造方法以及方向性电磁钢板 |
RU2744690C1 (ru) * | 2018-03-30 | 2021-03-15 | ДжФЕ СТИЛ КОРПОРЕЙШН | Железный сердечник трансформатора |
US11961647B2 (en) | 2018-03-30 | 2024-04-16 | Jfe Steel Corporation | Iron core for transformer |
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CN114762911B (zh) * | 2021-01-11 | 2023-05-09 | 宝山钢铁股份有限公司 | 一种低磁致伸缩取向硅钢及其制造方法 |
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