WO2014199090A2 - Procede et ensemble de production d'une piece mecanique par frittage d'un materiau metallique pulverulent - Google Patents
Procede et ensemble de production d'une piece mecanique par frittage d'un materiau metallique pulverulent Download PDFInfo
- Publication number
- WO2014199090A2 WO2014199090A2 PCT/FR2014/051433 FR2014051433W WO2014199090A2 WO 2014199090 A2 WO2014199090 A2 WO 2014199090A2 FR 2014051433 W FR2014051433 W FR 2014051433W WO 2014199090 A2 WO2014199090 A2 WO 2014199090A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cavity
- solid body
- metal material
- metallic material
- punch
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
- B22F3/03—Press-moulding apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/003—Apparatus, e.g. furnaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/14—Both compacting and sintering simultaneously
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/16—Both compacting and sintering in successive or repeated steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/006—Pressing and sintering powders, granules or fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/52—Heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B15/00—Details of, or accessories for, presses; Auxiliary measures in connection with pressing
- B30B15/34—Heating or cooling presses or parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
- B22F3/03—Press-moulding apparatus therefor
- B22F2003/031—Press-moulding apparatus therefor with punches moving in different directions in different planes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
- B29C43/16—Forging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/26—Component parts, details or accessories; Auxiliary operations
- B29C51/42—Heating or cooling
- B29C51/428—Heating or cooling of moulds or mould parts
Definitions
- the present invention relates to a method for producing a mechanical part by sintering a pulverulent metallic material and a production assembly making it possible to implement such a method.
- a field of application envisaged is that of mechanics in general for producing, for example, gears, pads or even rings.
- Another targeted field of application is that of biomedical applications, for example to produce prosthetic elements.
- Sintering here means the treatment by which grains of a compressed powder in a metal mold are heated to a temperature below their melting point so as to weld them together to form a single solid mass while retaining the shape given by the mold.
- the matrix is oriented so that the longitudinal orifice extends vertically.
- the cavity can then be filled with a powder, which is retained by the lower punch.
- the upper punch through the longitudinal hole to be able to close the cavity and apply a force.
- the powder is then agglomerated and compressed by force between the two punches.
- a particular compaction process involves impacting the upper punch with a given energy to produce the effort required to form a tablet.
- a second distinct sintering step consists of a temperature treatment of the part to give it its mechanical properties.
- the piece thus produced deforms substantially after being ejected from the matrix and it can also appear flaw type defects that can render the part unusable. Also, for precision mechanical parts, it is necessary to come and machine the piece thus obtained to be able to bring it to the good odds.
- a problem that arises and that aims to solve the present invention is to provide a method that allows the mechanical parts obtained by sintering a powder material to retain their dimensions after ejection of the matrix.
- the present invention provides a method for producing a mechanical part by sintering a powdery material, said method being of the type comprising the following steps: a powdery metallic material having grains is provided said powdered metallic material having a determined melting temperature; a given quantity of said powdered metallic material is then agglomerated under pressure inside a cavity; then heat energy is supplied to said given amount of powdered metallic material to bring it to a given temperature below said melting temperature; and shocking said given amount of agglomerated powdered metallic material and brought to said given temperature to be able to weld together the grains of said powdered metallic material so as to obtain a single solid body.
- said single solid body is maintained under pressure and has caused dissipation of the thermal energy accumulated in said solid body to obtain said mechanical part.
- a feature of the invention lies in the induced cooling of the solid body while maintaining it under pressure.
- the solid body is maintained in its geometry and its dimensions thanks to the pressure applied to it during the entire cooling step.
- the method according to the invention makes it possible to prevent the appearance of the defects related to cooling, which makes it possible to envisage the manufacture of massive pieces
- the powdered metallic material provided is constituted by grains of a powdery metal material having a low melting point, for example at a temperature below 800 ° C. Copper-based alloys can thus be used by the process according to the invention.
- said given quantity of said powdered metallic material is agglomerated under pressure within a cylindrical symmetry cavity. Thanks to a cylindrical cavity, it is easy to translate a punch inside to compress and agglomerate the powdery metal material.
- said single solid body is carried inside another cavity in order to dissipate said accumulated thermal energy. Thanks to the transfer of the solid body from a relatively hot cavity to a relatively cold cavity, it is possible to reduce the temperature of the solid body more sharply and thus freeze the dimensions thereof. According to another alternative embodiment, the dissipation of thermal energy accumulated in the solid body, is carried out in said one cavity.
- said given quantity of said powdery metal material is agglomerated under pressure within said cavity between two opposite walls. In this way, it is easier to provide a large amount of kinetic energy to the agglomerated metal material powder and thus together with the initial thermal energy, to weld the grains of metallic material together.
- the present invention proposes a mechanical part production assembly by sintering of powdery metallic material having grains, said powdered metal material having a determined melting temperature, said assembly comprising on the one hand a matrix having a suitable cavity. receiving a given quantity of pulverulent metallic material and secondly a punch for pressurizing said given amount of said powdered metallic material, said die having a heating device to be able to supply energy thermally at said given amount of powdered metallic material and bring it to a given temperature below said melting temperature, said assembly further comprising a punching device of said punch to be able to shock said given amount of agglomerated powdered metallic material and brought to said temperature given, so as to be welded together grains of said powdered metal material so as to obtain a single solid body.
- the assembly further comprises a heat exchanger for causing the dissipation of the thermal energy accumulated in said solid body, while said punch maintains said single solid body under pressure so as to obtain said mechanical part.
- the heat exchanger which is located around the solid body, it causes the dissipation of the thermal energy that has accumulated both during the heating phase and during shocks.
- the set of productions according to the invention comprises a further counter-punch adapted to come coaxially facing said punch.
- a further counter-punch adapted to come coaxially facing said punch.
- said one cavity has a cylindrical symmetry.
- the punch and the counter punch can be driven in translation coaxially facing each other.
- the solid body is held in pressure between the punch and the counter-punch, while it rests radially against the wall of the die cavity, thanks to the effect of the pressure.
- the solid body can be driven in translation axially inside the cavity.
- said heat exchanger defines another cavity having the same cylindrical symmetry, and said exchanger is able to be connected to said matrix so that said other cavity comes to fit in the extension of said one. cavity.
- the punch and the counter punch are able to come through said other cavity.
- the coaxial movement in translation of the punch and the counter punch between which the solid body is held allows the latter to be driven into the interior of said other cavity.
- the solid body is driven from the cavity of the matrix, hot, to the cavity of the exchanger thermal, cold. Accordingly, the temperature of the solid body can be lowered sharply while maintaining pressure between the punch and the counter punch within said other cavity.
- said heat exchanger has two half-shells capable of forming said other cavity.
- the two half-shells are fitted facing one another and they are movable transversely between a position spaced from each other and a position close to one another or they then form said other cavity in the extension of said one cavity of the matrix.
- said heat exchanger preferably comprises channels for circulating a heat transfer fluid. These are formed in the two half-shells and in particular in the vicinity of the walls forming said other cavity. The arrangement of the circulation channels through the heat exchanger will be explained in greater detail in the remainder of the description.
- FIGS. 1A-1D are partial schematic views of a production assembly of a mechanical part by sintering in the different phases of the implementation method
- Figure 2A is a schematic top view of an element of the production assembly shown in Figure 1D;
- Figure 2B is a schematic perspective view of an element shown in Figure 2A.
- the production process according to the invention and the production assembly making it possible to implement it are adapted to pulverulent metallic materials.
- they are suitable for pulverulent metallic materials having a melting temperature substantially below 800 ° C.
- low melting point metal alloys can be implemented by such a method. Referring to Figures 1A to 1D to describe in detail schematically the essential elements of a tool and the various steps of the compaction method according to the invention.
- FIG. 1A schematically illustrates a matrix 10 having a circular cylindrical through-hole of circular symmetry 12.
- the matrix 10 is equipped with a heating device, not shown.
- heating cartridges operating by Joule effect are inserted through the matrix 10.
- circulation channels of a hot coolant through the die 10 are warmed up.
- induction heating means are implemented.
- the die 10 is equipped with a counterpunch 14 partially engaged in the lower part of the die 10 through the cylindrical orifice 12 by defining an open cavity 16 inside the die 10.
- the upper end of the counter -poinarme 14 is equipped with a lower sealing disc 18 forming a lower flat wall of the cavity 16.
- the lower sealing disc 18 closes the lower end of the cylindrical orifice 12, and leaving the cavity 16, sealingly.
- Figure 1 A illustrates a punch 19 located opposite the cavity 16 and at a distance from the die 10.
- the punch 19 has a section identical to that of the counter punch 14 and is positioned coaxially.
- the counterpunch 14 and the punch 19 are also heated by heating means not shown. They can be heated by heating collars and / or by a system of movable shells comprising heating cartridges, which movable shells come to grip the active end of the punches.
- the pulverulent metal material 20 for example a copper alloy
- the pulverulent metal material 20 is introduced inside the cavity 16 on the sealing disk 18.
- 60 g of powder of said alloy is poured into the interior of the cavity 16.
- the metal powder is carried, for example in an oven, at a temperature of 700 ° C.
- the die 10 and the parts of the punch 19 and the counter punch 14 in contact with the metallic material are brought to temperature, by means of clean heating and thermal regulation devices.
- the punch 19 is introduced inside the cavity 16 and, in a first sequence, the powder metal material 20 is pre-compacted so as to drive out the air.
- the punch 19 is devoid of sealing disc, and thus the air escapes between the wall of the cavity 16 and the punch 19 itself.
- the force exerted by the punch 19 on the powdery metal material 20 is here 5 tons for a period of time for example between one and five seconds.
- the punch 19 is extracted from the cavity 16 and is equipped with an upper sealing disc 22 to pre-compact the powdered metallic material 20. Also, the cavity 16 enclosing the metallic material powder is waterproof.
- This second sequence is of a duration of 30 seconds for example and the force exerted by the punch 19 is about 10 tons.
- the temperature of the pulverulent metal material is homogenized and brought to near the working temperature set at 18 ° C.
- the impact energy is of the order of 1680 J and 40 impacts are carried.
- the grains of metal powder 20 locally reach the melting point of the material which has the effect of forming a single common phase between the grains.
- the appearance of the melted phase appears preferentially at the grain boundaries during the first impacts then the proportion of this phase then increases as the impacts. And thus, the whole is consolidated during the cooling phase illustrated in Figure 1 D. In this way is obtained a solid body 23 in one piece.
- FIG. 2A illustrates the heat exchanger 24 seen from above with transparency, channels for circulating a coolant 26.
- the heat exchanger 24 has two half-portions 28, 30 symmetrical to each other relative to each other. at an axial plane P.
- the half-portions 28, 30 respectively have end faces 32, 34, in which are formed two recesses 36, 38 of cylindrical symmetry forming two half-shells.
- the two half-shells 36, 38 define a cooling cavity 40 of cylindrical symmetry of revolution.
- FIG. 2B shows a three-quarter rear view of one of the two half-portions 30 of the heat exchanger 24.
- the front face 34 located in a front portion 41, which is opposite a rear portion, thus appears. 43, and the half-shell formed by the recess 38 formed in the front face 34.
- the circulation channels 26 of the coolant This is for example cold water. They are thus divided into two opposite branches 42, 44 which meet at the front portion 41 through a network 46 of ducts forming a refrigerant screen in the thickness of the front portion 41 around the recess 38. symmetrical, the other half-part 28 has the same characteristics.
- the cold fluid is injected into the branch 42 and flows at the front portion 41 through the network 46 of ducts forming the refrigerant screen around the recess 38 which will be in direct contact with the room to be cooled. .
- This network is defined so as to maximize the heat exchange surface closest to the room and thus be able to evacuate the maximum of calories.
- the fluid then emerges from the branch 44 opposite to the branch 42. This fluid can advantageously be reintroduced after cooling the inlet of the circuit by the branch 42 to form a circuit
- FIG. 1 D shows not only the matrix 10 but also the heat exchanger 24 formed from its two half-portions 28, 30.
- the front portions 41 come to bear not only laterally against one another but also axially on the upper edges of the die 10, so that the cooling cavity 40 comes to extend with respect to the cylindrical orifice 42, in the extension of the cavity 16 of the matrix 10.
- the solid body 23 is driven from the cavity 16 of the die 10, into the cooling cavity 40 of the heat exchanger 24 while the pressure exerted by the two punches 14, 19 on the solid body 23 remains. It is for example increased to 15 tons for 120 seconds.
- the production assembly described here with reference to the figures and making it possible to illustrate the process according to the invention may take another form and for example comprise a matrix having a plurality of indentations or cavities respectively associated with a plurality of punches. and counter punches.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016518571A JP6293878B2 (ja) | 2013-06-12 | 2014-06-12 | 粉体状金属性物質を焼結させることによって機械的部品を製造するための方法及びアセンブリー |
CN201480043899.3A CN105492180A (zh) | 2013-06-12 | 2014-06-12 | 通过烧结粉状金属材料制造机械部件的方法和装置 |
US14/898,012 US10226816B2 (en) | 2013-06-12 | 2014-06-12 | Method and assembly for production of a mechanical component by sintering a pulverulent metallic material |
EP14734890.8A EP3007843B1 (fr) | 2013-06-12 | 2014-06-12 | Procede et ensemble de production d'une piece mecanique par frittage d'un materiau metallique pulverulent |
HK16111558.3A HK1223333A1 (zh) | 2013-06-12 | 2016-10-04 | 通過燒結粉狀金屬材料製造機械部件的方法和裝置 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1355447A FR3006936B1 (fr) | 2013-06-12 | 2013-06-12 | Procede et ensemble de production d'une piece mecanique par frittage d'un materiau pulverulent |
FR1355447 | 2013-06-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2014199090A2 true WO2014199090A2 (fr) | 2014-12-18 |
WO2014199090A3 WO2014199090A3 (fr) | 2015-05-07 |
Family
ID=49212842
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2014/051433 WO2014199090A2 (fr) | 2013-06-12 | 2014-06-12 | Procede et ensemble de production d'une piece mecanique par frittage d'un materiau metallique pulverulent |
PCT/FR2014/051435 WO2014199092A2 (fr) | 2013-06-12 | 2014-06-12 | Procédé et ensemble de production d'une pièce mécanique par frittage d'un matériau pulvérulent |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2014/051435 WO2014199092A2 (fr) | 2013-06-12 | 2014-06-12 | Procédé et ensemble de production d'une pièce mécanique par frittage d'un matériau pulvérulent |
Country Status (7)
Country | Link |
---|---|
US (1) | US10226816B2 (fr) |
EP (1) | EP3007843B1 (fr) |
JP (1) | JP6293878B2 (fr) |
CN (2) | CN105492180A (fr) |
FR (1) | FR3006936B1 (fr) |
HK (1) | HK1223333A1 (fr) |
WO (2) | WO2014199090A2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3184211A1 (fr) | 2015-12-21 | 2017-06-28 | ETA SA Manufacture Horlogère Suisse | Matériau obtenu par compaction et densification de poudre(s) métallique(s) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106367629B (zh) * | 2016-08-31 | 2018-06-26 | 上海交通大学 | 改善原位颗粒增强铝基复合材料颗粒分布的设备及应用 |
CN106367698B (zh) * | 2016-08-31 | 2018-06-26 | 上海交通大学 | 制备超细等轴晶粒铝合金的正交叠片挤压设备及应用 |
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DE356716C (de) * | 1919-05-15 | 1922-07-27 | Andre Gueret | Verfahren und Maschine zur Herstellung von Legierungen und Agglomerierungen aus pulverfoermigen Metallen |
CH272006A (fr) * | 1942-03-04 | 1950-11-30 | Inc Charles Hardy | Procédé d'agglomération d'une masse compacte de poudre métallique, notamment de poudre métallique non ferreuse, et appareil pour la mise en oeuvre de ce procédé. |
FR1186924A (fr) * | 1956-04-06 | 1959-09-03 | Plessey Co Ltd | Procédé et appareil de forgeage par impact utilisables notamment dans la métallurgie des poudres |
GB1166779A (en) * | 1968-07-17 | 1969-10-08 | Du Pont | Hot Pressing Process and Apparatus |
CH604984A5 (en) * | 1975-02-17 | 1978-09-29 | Mitsubishi Heavy Ind Ltd | Sintering metal powders such as iron |
DE2611420C3 (de) * | 1976-03-18 | 1979-07-26 | Vereinigung Zur Foerderung Des Instituts Fuer Kunststoffverarbeitung In Industrie Und Handwerk An Der Rhein.- Westf. Technischen Hochschule Aachen E.V., 5100 Aachen | Verfahren zum Herstellen von Formteilen aus Polymeren durch Schlagschmelzen von pulver- oder granulatförmigen Rohstoffen |
US4738610A (en) * | 1986-12-04 | 1988-04-19 | Aerojet-General Corporation | Isostatic press using a shape memory alloy |
JP2551614B2 (ja) * | 1988-02-15 | 1996-11-06 | 株式会社クボタ | 筒状体の製造法 |
DE4241757A1 (de) | 1992-12-11 | 1994-06-16 | Hoechst Ag | Verfahren zur Herstellung von Formkörpern aus ultrahochmolekularem Polyethylen |
US5721334A (en) * | 1996-02-16 | 1998-02-24 | Newyork Society For The Ruptured And Crippled Maintaining The Hospital For Special Surgery | Process for producing ultra-high molecular weight low modulus polyethylene shaped articles via controlled pressure and temperature and compositions and articles produced therefrom |
JP3873357B2 (ja) * | 1997-03-18 | 2007-01-24 | セイコーエプソン株式会社 | 圧縮成形装置および圧縮成形方法 |
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2013
- 2013-06-12 FR FR1355447A patent/FR3006936B1/fr active Active
-
2014
- 2014-06-12 EP EP14734890.8A patent/EP3007843B1/fr active Active
- 2014-06-12 WO PCT/FR2014/051433 patent/WO2014199090A2/fr active Application Filing
- 2014-06-12 CN CN201480043899.3A patent/CN105492180A/zh active Pending
- 2014-06-12 CN CN202110423053.4A patent/CN113118442A/zh not_active Withdrawn
- 2014-06-12 JP JP2016518571A patent/JP6293878B2/ja active Active
- 2014-06-12 US US14/898,012 patent/US10226816B2/en active Active
- 2014-06-12 WO PCT/FR2014/051435 patent/WO2014199092A2/fr active Application Filing
-
2016
- 2016-10-04 HK HK16111558.3A patent/HK1223333A1/zh unknown
Non-Patent Citations (1)
Title |
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None |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3184211A1 (fr) | 2015-12-21 | 2017-06-28 | ETA SA Manufacture Horlogère Suisse | Matériau obtenu par compaction et densification de poudre(s) métallique(s) |
WO2017108293A1 (fr) | 2015-12-21 | 2017-06-29 | Eta Sa Manufacture Horlogère Suisse | Materiau obtenu par compaction et densification de poudre(s) metallique(s) |
Also Published As
Publication number | Publication date |
---|---|
WO2014199092A2 (fr) | 2014-12-18 |
JP6293878B2 (ja) | 2018-03-14 |
CN105492180A (zh) | 2016-04-13 |
EP3007843B1 (fr) | 2019-01-16 |
HK1223333A1 (zh) | 2017-07-28 |
FR3006936B1 (fr) | 2015-07-03 |
WO2014199090A3 (fr) | 2015-05-07 |
EP3007843A2 (fr) | 2016-04-20 |
JP2016527389A (ja) | 2016-09-08 |
FR3006936A1 (fr) | 2014-12-19 |
US20160107230A1 (en) | 2016-04-21 |
US10226816B2 (en) | 2019-03-12 |
WO2014199092A3 (fr) | 2015-05-07 |
CN113118442A (zh) | 2021-07-16 |
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