WO2014185126A1

WO2014185126A1 - Support roller, method for molding glass plate, method for manufacturing glass plate, and device for manufacturing glass plate

Info

Publication number: WO2014185126A1
Application number: PCT/JP2014/056033
Authority: WO
Inventors: 海郡司; 瑞樹松岡; 裕史前野; 信之伴
Original assignee: 旭硝子株式会社
Priority date: 2013-05-16
Filing date: 2014-03-07
Publication date: 2014-11-20
Also published as: KR102153288B1; CN105143119B; JP6137306B2; JPWO2014185126A1; CN105143119A; KR20160010401A

Abstract

Provided is a support roller that supports a strip-shaped glass ribbon and that comprises: a rotating member that comes into contact with the glass ribbon; a shaft member that has a refrigerant flow path in the interior thereof and that rotates together with the rotating member; and a protruding member that protrudes from the outer periphery of the shaft member and that comprises a branch path that branches from the refrigerant flow path. The rotating member is formed from ceramic. A heat transfer member that has higher thermal conductivity than the rotating member is arranged between the protruding member and the rotating member.

Description

Support roll, glass plate forming method, glass plate manufacturing method, and glass plate manufacturing apparatus

The present invention relates to a support roll, a glass plate forming method, a glass plate manufacturing method, and a glass plate manufacturing apparatus.

The glass plate forming method includes a step of forming molten glass into a strip-like glass ribbon. A glass ribbon having a thickness smaller than the equilibrium thickness tends to shrink in the width direction. Therefore, in order to keep the thickness of the glass ribbon at a desired thickness, a support roll that applies tension to the glass ribbon in the width direction is used (for example, see Patent Document 1). The support rolls are used in pairs and hold the side edges of the glass ribbon. A plurality of pairs of support rolls are disposed at intervals along the moving direction of the glass ribbon. The support roll has a rotating member in contact with the glass ribbon at the tip, and the rotating member rotates to feed the glass ribbon in a predetermined direction. The glass ribbon is gradually cooled and hardened while moving in a predetermined direction.

JP 2011-225386 A

The conventional rotating member is made of a metal material and has low heat resistance. On the other hand, a rotating member formed of ceramics has a problem that it is easily broken by a temperature gradient.

The present invention has been made in view of the above problems, and an object of the present invention is to provide a support roll capable of suppressing cracking of a ceramic rotating member.

In order to solve the above problems, according to one aspect of the present invention,
A support roll for supporting a belt-like glass ribbon,
A rotating member in contact with the glass ribbon;
A shaft member having a refrigerant flow path therein and rotating together with the rotating member;
A branch path branched from the refrigerant flow path, and a projecting member projecting from the outer periphery of the shaft member,
The rotating member is formed of ceramics;
A support roll is provided in which a heat transfer member having a higher thermal conductivity than the rotating member is disposed between the projecting member and the rotating member.

According to one aspect of the present invention, it is possible to provide a support roll that can suppress cracking of a ceramic rotating member.

1 is a partial cross-sectional view showing a glass sheet forming apparatus according to an embodiment of the present invention. It is a top view which shows the lower structure of the shaping | molding apparatus of the glass plate of FIG. It is sectional drawing which shows the support roll by one Embodiment of this invention. 6 is a graph showing the change over time of the wettability of molten glass with respect to sintered bodies according to Examples 1 to 4. It is sectional drawing which shows the rotating member by a modification. FIG. 6 is a first diagram illustrating dimensions of a convex shape of the rotating member of FIG. 5. FIG. 6 is a second diagram illustrating dimensions of a convex shape of the rotating member of FIG. 5. It is sectional drawing which shows the rotating member by another modification.

Hereinafter, embodiments of the present invention will be described with reference to the drawings. In the following drawings, the same or corresponding components are denoted by the same or corresponding reference numerals, and description thereof is omitted.

FIG. 1 is a partial cross-sectional view showing a glass sheet forming apparatus according to an embodiment of the present invention. FIG. 2 is a plan view showing a lower structure of the glass sheet forming apparatus of FIG.

The forming apparatus 10 forms molten glass into a strip-like glass ribbon 14. The forming apparatus 10 includes a bathtub 20 that accommodates molten metal (for example, molten tin) 16, and allows molten glass continuously supplied onto the molten metal 16 to move in a predetermined direction (X direction in FIG. 2). ) To form a strip. The glass ribbon 14 is cooled in the process of flowing in a predetermined direction (X direction in FIG. 2), then pulled up from the molten metal by a lift-out roll, gradually cooled in a slow cooling furnace, and taken out of the slow cooling furnace, and then cut. It is cut into a predetermined size and shape by a machine and becomes a glass plate as a product.

The forming apparatus 10 includes a bathtub 20 that accommodates the molten metal 16, a ceiling 22 that is provided above the bathtub 20, and a side wall 24 that closes a gap between the bathtub 20 and the ceiling 22. A gas supply path 32 is provided in the ceiling 22, and a heater 34 as a heating source is inserted into the gas supply path 32.

The gas supply path 32 supplies a reducing gas to the space above the molten metal 16 to prevent the molten metal 16 from being oxidized. The reducing gas includes, for example, 1 to 15% by volume of hydrogen gas and 85 to 99% by volume of nitrogen gas.

A plurality of heaters 34 are provided above the molten metal 16 and the glass ribbon 14 at intervals in the moving direction and the width direction of the glass ribbon 14. The output of the heater 34 is controlled so that the temperature of the glass ribbon 14 becomes lower from the upstream side toward the downstream side. The output of the heater 34 is controlled so that the thickness of the glass ribbon 14 is uniform in the width direction (Y direction).

The forming apparatus 10 includes a support roll 40 that is used for suppressing shrinkage in the width direction of the strip-shaped glass ribbon 14. The support rolls 40 are used in pairs and hold the side edges of the glass ribbon 14. A plurality of pairs of support rolls 40 are disposed at intervals along the moving direction of the glass ribbon 14. The support roll 40 has a rotating member 42 in contact with the glass ribbon 14 at the distal end, and the rotating member 42 rotates to feed the glass ribbon 14 in a predetermined direction. The glass ribbon 14 is gradually cooled and hardened while moving in a predetermined direction.

FIG. 3 is a cross-sectional view showing a support roll according to an embodiment of the present invention. The support roll 40 includes a rotating member 42, a shaft member 44, a flange 46 as an overhang member, a heat transfer member 48, a pressing member 50, a first elastic body 54, a heat insulating member 60, a centering member 64, and a second elastic body 66. Etc.

Rotating member 42 may have gear-shaped irregularities 43 on the outer periphery thereof that come into contact with glass ribbon 14, for example, as shown in FIG. 1, in order to suppress slip on glass ribbon 14. Although the shape of the convex part of the gear-shaped unevenness | corrugation 43 is not specifically limited, For example, as shown in FIG. 3, you may form in a taper shape (for example, square pyramid shape). As shown in FIG. 1, the gear-shaped irregularities 43 are formed in a line in the thickness direction (Y direction in FIG. 1) of the outer periphery of the rotating member 42, but a plurality of lines may be formed.

Rotating member 42 does not have a refrigerant flow path inside. Since the shaft member 44 inserted through the through hole of the rotating member 42 is a member different from the rotating member 42, the coolant channel 45 formed in the shaft member 44 is a coolant formed outside the rotating member 42. It is a flow path.

The rotating member 42 is formed of ceramics having higher heat resistance than the metal material. The ceramic of the rotating member 42 is not particularly limited. For example, silicon carbide (SiC) ceramics, silicon nitride (Si ₃ N ₄ ) ceramics, or the like is used. Silicon carbide and silicon nitride have high resistance to the splash of the molten metal 16 and the vapor of the molten metal 16 and are excellent in high-temperature strength and creep characteristics.

The ceramic type of the rotating member 42 is selected according to the type of glass. For example, in the case of non-alkali glass, since the glass forming temperature is high, silicon nitride ceramics excellent in thermal shock resistance are suitable. Silicon nitride ceramics are also excellent in that they have low reactivity with alkali-free glass. On the other hand, in the case of soda lime glass, silicon carbide ceramics and alumina ceramics can be used in addition to silicon nitride ceramics.

In the case of alkali-free glass, at least a portion of the rotating member 42 that contacts the glass ribbon 14 may be silicon nitride ceramics, and the entire rotating member 42 may not be silicon nitride ceramics. For example, a layer of silicon nitride ceramics may be formed on a substrate made of ceramics other than silicon nitride ceramics.

The silicon nitride ceramics may be a sintered body obtained by sintering a molded body made of a mixed powder containing silicon nitride powder and sintering aid powder. As the sintering method, there are an atmospheric pressure sintering method, a pressure sintering method (including hot press sintering, gas pressure sintering) and the like. As the sintering aid, for example, at least one selected from alumina (Al ₂ O ₃ ), magnesia (MgO), titania (TiO ₂ ), zirconia (ZrO ₂ ), and yttria (Y ₂ O ₃ ) is used. It is done.

The silicon nitride ceramic has an aluminum (Al) content of 0.1% by mass or less, preferably less than 1% by mass, and a magnesium (Mg) content of 0.7% by mass or less, preferably 0.7% by mass. The content of titanium (Ti) may be 0.9 mass% or less, preferably less than 0.9 mass%. When the Al content, the Mg content, and the Ti content are in the above ranges, the reactivity between the rotating member 42 and the glass ribbon 14 is low, and the rotating member 42 and the glass ribbon 14 are difficult to adhere to each other. Durability is obtained. The Al content, Mg content, and Ti content may each be 0% by mass.

The silicon nitride ceramic has a zirconium (Zr) content of 3.5% by mass or less, preferably less than 3.5% by mass, and a yttrium (Y) content of 0.5% by mass or more, preferably 0.5%. It may be more than 10% by mass, preferably less than 10% by mass, and less than 10% by mass. Zr and Y are components that are less likely to interdiffuse with the glass ribbon 14 as compared with Al, Mg, and Ti, and thus may be contained in the above range. By containing in the above range, sintering of the silicon nitride powder can be promoted. Zr is an optional component, and the Zr content may be 0% by mass.

The silicon nitride ceramic of the present embodiment is a sintered body obtained by a normal pressure sintering method or a pressure sintering method, but may be a sintered body obtained by a reactive sintering method. . The reaction sintering method is a method in which a molded body formed of metal silicon (Si) powder is heated in a nitrogen atmosphere. Since the reaction sintering method does not use a sintering aid, a high-purity sintered body can be obtained, and the durability of the sintered body with respect to the glass ribbon 14 can be improved.

The glass plate as a product is not particularly limited, but may be for a flat panel display (FPD) such as a liquid crystal display (LCD), a plasma display (PDP), or an organic EL display. In recent years, thinning of FPDs has progressed, and thinning of glass plates for FPDs has progressed. In particular, in the case of a glass plate for a display substrate, a glass plate of 0.7 mm or less, more preferably 0.3 mm or less, more preferably 0.2 mm or less, particularly preferably 0.1 mm or less is desired. For this reason, the thickness of the glass ribbon 14 is reduced, the shrinkage force in the width direction of the glass ribbon 14 is increased, and the molding temperature of the glass ribbon 14 is increased. As will be described in detail later, the support roll 40 of the present embodiment includes a heat transfer member 48 having a higher thermal conductivity than that of the rotating member 42 between the rotating member 42 and the flange 46 serving as an overhang member. Therefore, the crack of the rotating member 42 can be suppressed, and it is suitable for forming a glass plate for FPD.

The kind of glass plate which is a product is not particularly limited. The composition of the glass plate is, for example, expressed as mass% on the basis of oxide, SiO ₂ : 50 to 75%, Al ₂ O ₃ : 0.1 to 24%, B ₂ O ₃ : 0 to 12%, MgO: 0 ~ 10%, CaO: 0-14.5%, SrO: 0-24%, BaO: 0-13.5%, Na ₂ O: 0-20%, K ₂ O: 0-20%, ZrO ₂ : 0 to 5%, MgO + CaO + SrO + BaO: 5 to 29.5%, Na ₂ O + K ₂ O: 0 to 20%.

The glass plate may be formed of non-alkali glass, for example. The alkali-free glass is a glass that does not substantially contain an alkali metal oxide (Na ₂ O, K ₂ O, Li ₂ O, etc.). The alkali-free glass may have a total content of alkali metal oxides of 0.1% by mass or less.

The alkali-free glass is, for example, SiO ₂ : 50 to 70% (preferably 50 to 66%), Al ₂ O ₃ : 10.5 to 24%, B ₂ O ₃ : 0 in terms of mass% based on oxide. To 12%, MgO: 0 to 10% (preferably 0 to 8%), CaO: 0 to 14.5%, SrO: 0 to 24%, BaO: 0 to 13.5%, ZrO ₂ : 0 to 5 %, MgO + CaO + SrO + BaO: 8 to 29.5% (preferably 9 to 29.5%).

When the alkali-free glass has both a high strain point and high solubility, it is preferably expressed in terms of mass% on the basis of oxide, SiO ₂ : 58 to 66%, Al ₂ O ₃ : 15 to 22%, B ₂ O ₃ : 5 to 12%, MgO: 0 to 8%, CaO: 0 to 9%, SrO: 3 to 12.5%, BaO: 0 to 2%, MgO + CaO + SrO + BaO: 9 to 18%.

When it is desired to obtain a particularly high strain point, the alkali-free glass is preferably expressed in terms of mass% based on oxide, SiO ₂ : 54 to 73%, Al ₂ O ₃ : 10.5 to 22.5%, B ₂ O ₃ : 0 to 5.5%, MgO: 0 to 10%, CaO: 0 to 9%, SrO: 0 to 16%, BaO: 0 to 2.5%, MgO + CaO + SrO + BaO: 8 to 26%.

As shown in FIG. 1, the shaft member 44 penetrates the side wall 24 and is connected to a driving device 36 disposed outside the side wall 24. The drive device 36 includes a motor, a speed reducer, and the like, and rotates the shaft member 44 around the center line of the shaft member 44. The shaft member 44 is inserted through a through hole formed in the central portion of the rotating member 42 and rotates together with the rotating member 42.

The shaft member 44 may be formed in a cylindrical shape with, for example, a metal material, and has a refrigerant flow path 45 through which a refrigerant such as water passes. The refrigerant may be a fluid, such as air.

The flange 46 may be formed integrally with the shaft member 44. The flange 46 projects from the outer periphery of the shaft member 44 in the radial direction of the rotating member 42 in the middle of the shaft member 44. A branch path 47 that branches from the refrigerant flow path 45 of the shaft member 44 is formed on the inner periphery of the flange 46, and the branch path 47 extends to the vicinity of the outer periphery of the flange 46. The flange 46 is cooled by the refrigerant passing through the branch passage 47.

The heat transfer member 48 is formed in a ring shape, for example. The inner diameter of the heat transfer member 48 is larger than the outer diameter of the shaft member 44, and the heat transfer member 48 does not contact the shaft member 44. The heat transfer member 48 is positioned by a positioning groove 49 formed on the side surface of the flange 46 on the rotating member 42 side.

The heat transfer member 48 is provided between the flange 46 and the rotation member 42, has a higher thermal conductivity than the rotation member 42, and releases the heat of the rotation member 42 transmitted from the glass ribbon 14 to the flange 46. The temperature at which the outer periphery of the rotating member 42 does not stick to the glass ribbon 14 is maintained, and the rotational torque can be reduced.

Here, the thermal conductivity of the heat transfer member 48 and the thermal conductivity of the rotating member 42 are measured at the operating temperature of the support roll 40. At the operating temperature of the support roll 40, the heat conductivity of the heat transfer member 48 is preferably 30 to 200 W / (m · ° C.).

Since the flange 46 cools the heat transfer member 48 and the heat transfer member 48 cools the rotating member 42 from the side surface, the temperature gradient in the radial direction of the rotating member 42 is larger than when the rotating member 42 is cooled from the inner periphery. Is reduced, and the damage of the rotating member 42 due to the thermal stress can be suppressed.

The heat transfer member 48 only needs to have a higher thermal conductivity than the rotating member 42, and is formed of, for example, metal or carbon. Metal and carbon are softer than ceramics, and the heat transfer member 48 and the rotating member 42 are likely to be in close contact. Therefore, the contact thermal resistance is low and the heat transfer efficiency is good. Carbon is particularly preferable from the viewpoint of heat resistance.

When the heat transfer member 48 is formed of the same material as the flange 46, the heat transfer member 48 and the flange 46 may be formed integrally.

The pressing member 50 presses the rotating member 42 against the heat transfer member 48 and reduces the contact thermal resistance between the heat transfer member 48 and the rotating member 42. The pressing member 50 is disposed on the opposite side of the heat transfer member 48 with the rotating member 42 as a reference.

The pressing member 50 includes, for example, a pressing member main body 51 and a contact portion 52. The pressing member main body 51 is made of, for example, metal, and the shaft member 44 is inserted into a through hole formed in the central portion of the pressing member main body 51. The contact portion 52 may be formed in a ring shape like the heat transfer member 48. The outer diameter of the contact portion 52 is larger than the inner diameter of the shaft member 44, and the contact portion 52 presses the opposite side of the contact portion of the heat transfer member 48 in the rotating member 42 without contacting the shaft member 44. The contact portion 52 is made of metal or carbon. Carbon is particularly preferable from the viewpoint of heat resistance. The contact portion 52 is positioned by a positioning groove 53 formed on the side surface of the pressing member main body 51 on the rotating member 42 side. When the contact part 52 is formed of the same material as the pressing member main body 51, the contact part 52 and the pressing member main body 51 may be formed integrally.

The first elastic body 54 urges the pressing member 50 that is displaceable in the axial direction of the shaft member 44 toward the rotating member 42. The first elastic body 54 is configured by, for example, a disc spring, and the shaft member 44 is inserted into a through hole formed in the first elastic body 54. The shaft member 44 has a screw shaft portion 44a, and the first elastic body 54 is disposed between the first nut 58 and the rotating member 42 screwed into the screw shaft portion 44a in a state where the first elastic body 54 is contracted from the natural state. The When a dimensional change occurs due to a temperature change or the like, the rotating member 42 is always pressed against the heat transfer member 48 by the pressing member 50.

In addition, although the 1st elastic body 54 of this embodiment is comprised with a disc spring, it may be comprised with a coil spring and the structure of the 1st elastic body 54 is not specifically limited. The first elastic body 54 may not be provided. In this case, by tightening the first nut 58, the first nut 58 presses the pressing member 50, and the pressing member 50 presses the rotating member 42 against the heat transfer member 48. .

The heat insulating member 60 is formed in a cylindrical shape, for example. The heat insulating member 60 may be divided into a plurality of divided bodies (for example, two halves) in the circumferential direction from the viewpoint of workability and cost.

The heat insulating member 60 is disposed between the inner periphery of the rotating member 42 and the outer periphery of the shaft member 44, has a lower thermal conductivity than the rotating member 42, and heat of the rotating member 42 escapes to the shaft member 44. Suppress. The temperature gradient in the radial direction of the rotating member 42 becomes gentler, and the damage due to the thermal stress of the rotating member 42 can be suppressed.

Here, the thermal conductivity of the heat insulating member 60 and the thermal conductivity of the rotating member 42 are measured at the operating temperature of the support roll 40. At the use temperature of the support roll 40, the heat conductivity of the heat insulating member 60 is preferably 0.01 to 30 W / (m · ° C.).

The material of the heat insulating member 60 is not particularly limited as long as it has a lower thermal conductivity than the material of the rotating member 42. For example, slate is used. The slate may be either a natural slate made of rock such as slate, or an artificial slate in which a fiber material is mixed in cement.

The outer peripheral surface of the heat insulating member 60 is a contact surface that comes into contact with the inner peripheral surface of the rotating member 42, and has a tapered shape whose diameter decreases toward the flange 46 along the center line of the rotating member 42. Similarly, the inner peripheral surface of the rotating member 42 is a contact surface that comes into contact with the outer peripheral surface of the heat insulating member 60, and has a tapered shape whose diameter decreases toward the flange 46 along the center line of the rotating member 42. If at least one of the contact surfaces of the heat insulating member 60 and the rotating member 42 that are in contact with each other is tapered, rattling between the heat insulating member 60 and the rotating member 42 can be reduced. Note that the direction of the taper may be reversed, and each contact surface may have a taper shape in which the diameter increases toward the flange 46 along the center line of the rotating member 42.

The centering member 64 aligns the center line of the heat insulating member 60 and the center line of the shaft member 44, and is formed in a cylindrical shape, for example, and is arranged between the inner periphery of the heat insulating member 60 and the outer periphery of the shaft member 44. Established. The centering member 64 may be made of metal like the shaft member 44. Since the difference in thermal expansion between the centering member 64 and the shaft member 44 is small, the clearance between the centering member 64 and the shaft member 44 can be set narrow, and rattling between the centering member 64 and the shaft member 44 can be reduced.

The core alignment member 64 plays the role of aligning the positions of the plurality of divided bodies when the heat insulating member 60 is divided into the plurality of divided bodies in the circumferential direction.

The outer peripheral surface of the core alignment member 64 is a contact surface that comes into contact with the inner peripheral surface of the heat insulating member 60, and has a tapered shape whose diameter decreases toward the flange 46 along the center line of the rotating member 42. Similarly, the inner peripheral surface of the heat insulating member 60 is a contact surface that comes into contact with the outer peripheral surface of the centering member 64 and has a tapered shape whose diameter decreases toward the flange 46 along the center line of the rotating member 42. . If the contact surface of at least one of the core alignment member 64 and the heat insulating member 60 that are in contact with each other is tapered, rattling between the core alignment member 64 and the heat insulating member 60 can be reduced. Note that the direction of the taper may be reversed, and each contact surface may have a taper shape in which the diameter increases toward the flange 46 along the center line of the rotating member 42.

In this embodiment, the centering member 64 is disposed between the inner periphery of the heat insulating member 60 and the outer periphery of the shaft member 44. However, the centering member 64 may not be provided, and the inner periphery of the heat insulating member 60 may be omitted. There may be a slight clearance between the shaft member 44 and the outer periphery of the shaft member 44.

The second elastic body 66 urges the heat insulating member 60 that is displaceable in the axial direction of the shaft member 44 toward the flange 46 via the centering member 64 that is displaceable in the axial direction of the shaft member 44. The second elastic body 66 is configured by a disc spring, for example, and the shaft member 44 is inserted into a through hole formed in the second elastic body 66. The second elastic body 66 is disposed between the second nut 68 screwed into the screw shaft portion 44a of the shaft member 44 and the core alignment member 64 in a state where the second elastic body 66 is contracted from the natural state. When a dimensional change occurs due to a temperature change or the like, separation between the core alignment member 64 and the heat insulating member 60 can be prevented, and separation between the heat insulating member 60 and the rotating member 42 can be prevented.

In addition, although the 2nd elastic body 66 of this embodiment is comprised with a disc spring, it may be comprised with a coil spring and the structure of the 2nd elastic body 66 is not specifically limited. When the centering member 64 is not present, the second elastic body 66 contacts the heat insulating member 60 and biases the heat insulating member 60 toward the flange 46. Further, the second elastic body 66 may not be provided. In this case, by tightening the second nut 68, the centering member 64 and the heat insulating member 60 are brought into close contact with each other, and the heat insulating member 60 and the rotating member 42 are brought into close contact with each other.

In consideration of the moldability of the glass ribbon 14, the support roll 40 of the present embodiment has a molding area of the molding apparatus 10 (the glass ribbon 14 has a viscosity range of 10 ^4.5 to 10 ^7.5 dPa · s) and It is preferably used in a low temperature range (the glass ribbon 14 has a viscosity range of 10 ^6.7 to 10 ^7.65 dPa · s), and the molding zone (the glass ribbon 14 has a viscosity of 10 ^4.5 to 10 ^7.5 dPa · s). and the second low temperature region (the region where the glass ribbon 14 has a viscosity range of more than 10 ^7.5 to 10 ^7.65 dPa · s). In the case of alkali-free glass, the glass ribbon 14 has a viscosity range of 10 ^4.5 to 10 ^7.5 dPa · s, which corresponds to a temperature range of 946 to 1200 ° C. for the

glass ribbon

14 and 10 ^6.7 for the glass ribbon 14. The viscosity range of ˜10 ^7.65 dPa · s corresponds to the temperature range of 937 to 1000 ° C. for the glass ribbon 14, and the viscosity range of 10 ^7.5 to 10 ^7.65 dPa · s for the glass ribbon 14 is The glass ribbon 14 corresponds to a temperature range of 937 ° C. or more and less than 946 ° C.

In addition, the support roll 40 may be used in combination with a support roll having a general configuration, and may be used in a part of the molding region, the first low temperature region, the second low temperature region, and the like.

In Examples 1 to 4, the relationship between the wettability of the sintered body with respect to the molten glass and the impurities contained in the sintered body was examined.

The test piece and the test plate for evaluation were produced by processing a sintered body of silicon nitride (Si ₃ N ₄ ) -based ceramics that differs for each example.

The content of impurities in the sintered body was measured by analyzing a test piece cut into a square shape from the sintered body by glow discharge mass spectrometry. Impurities to be measured are included as sintering aids, and are aluminum (Al), magnesium (Mg), titanium (Ti), zirconium (Zr), and yttrium (Y).

The wettability of the sintered body with respect to the molten glass was measured with a high temperature wettability tester (manufactured by ULVAC-RIKO, WET1200). Specifically, a square glass piece of alkali-free glass (manufactured by Asahi Glass Co., Ltd., AN100) was placed on a test plate processed to a thickness of 1 mm, heated in a nitrogen atmosphere to 1150 ° C. in 10 minutes, and 1150 ° C. Was maintained for 10 minutes to form a molten glass, and the temperature was lowered from 1150 ° C. to 1050 ° C. in 90 seconds and maintained at 1050 ° C., and the contact angle of the droplet was measured. The measurement was performed when the temperature dropped to 1050 ° C., and after 2 hours, 4 hours, 6 hours, and 8 hours from that point. A larger contact angle means that the molten glass is less likely to get wet with the sintered body, and therefore indicates that the reactivity between the molten glass and the sintered body is low. In addition, the smaller the change in the contact angle with time, the easier the wettability is sustained.

Evaluation results are shown in Table 1 and FIG. In FIG. 4, the vertical axis represents the contact angle (°), and the horizontal axis represents the elapsed time (h: hours). In addition, 10000 mass ppm is 1 mass%.

As apparent from Table 1 and FIG. 4, the Al content is 0.1% by mass or less, preferably less than 0.1% by mass, and the Mg content is 0.7% by mass or less, preferably less than 0.7% by mass. Ti content is 0.9 mass% or less, preferably less than 0.9 mass%, Zr content is 3.5 mass% or less, preferably less than 3.5 mass%, and Y content is 0.5 mass%. More than 10% by mass, preferably more than 0.5% by mass and less than 10% by mass, there is little change in the contact angle over time, and the contact angle after 8 hours is large, so that good durability can be obtained. I understand that.

As mentioned above, although embodiment of the manufacturing method of a support roll, a glass plate, and the manufacturing apparatus of a glass plate was demonstrated, this invention is not limited to the said embodiment. The present invention can be modified and improved within the scope of the gist of the claims.

For example, although the support roll 40 of the above embodiment is used in a float method for forming the glass ribbon 14 on the molten metal 16, it may be used in other forming methods, for example, a fusion method.

The rotating member 42 of the above embodiment has gear-like irregularities on the outer periphery, but may not have gear-like irregularities on the outer periphery. Since the refrigerant does not flow inside the rotating member, the glass ribbon is not strongly cooled in the vicinity of the rotating member and is not easily hardened. Therefore, even if there is no gear-like unevenness, the rotating member can easily hold the glass ribbon, and shrinkage in the width direction of the glass ribbon can be suppressed.

FIG. 5 is a cross-sectional view showing a rotating member according to a modification. FIG. 6 is a first diagram showing the dimensions of the convex shape of the rotating member of FIG. 5. FIG. 7 is a second diagram illustrating dimensions of the convex shape of the rotating member of FIG. 5.

The rotating member 242 shown in FIG. 5 is used in place of the rotating member 42 shown in FIG. The outer peripheral surface of the rotating member 242 is a curved shape whose cross-sectional shape is convex outward in the radial direction over the entire periphery, and the central portion in the axial direction protrudes outward in the radial direction from both ends in the axial direction. The outer peripheral surface of the rotating member 242 has the same cross-sectional shape over the entire periphery. Since there are no gear-like irregularities, it is difficult to break and the molding and processing costs are reduced.

For example, as shown in FIG. 6, the convex curved curvature radius Ra is preferably R1 to R100 mm, more preferably R3 to R50 mm, and even more preferably R5 to R30 mm in consideration of the grip force with the glass ribbon 14. R10 to R20 mm are particularly preferable. In the convex curved shape, for example, as shown in FIG. 7, the curvature radius Rb at the central portion in the axial direction and the curvature radius Rc at both end portions in the axial direction may be a composite R. At this time, the radii of curvature Rb and Rc are preferably R1 to R100 mm, more preferably R3 to R50 mm, still more preferably R5 to R30 mm, and particularly preferably R10 to R20 mm. Further, the convex curved shape may have a flat portion in part, but it is preferable not to have the flat portion because the grip force with the glass ribbon 14 is stabilized.

In consideration of the grip force with the glass ribbon 14, the radial width d of the rotating member 242 in the convex curved shape shown in FIG. 6 is preferably 0.5 mm or more, more preferably 1 mm or more, and further preferably 2 mm or more. . Similarly, the radial width d of the rotating member 242 in the convex curved shape is preferably 5 mm or less, and more preferably 4 mm or less.

The radius r of the rotating member 242 shown in FIG. 6 is preferably 100 mm or more, more preferably 150 mm or more, still more preferably 180 mm or more, considering the contact between the flange 46 and the glass ribbon 14 and the horizontality of the shaft member 44. Considering the positional adjustment between the rotating member 242 and the glass ribbon 14 and the fine adjustment of the rotational speed of the rotating member 242, 350 mm or less is preferable, 300 mm or less is more preferable, and 270 mm or less is more preferable.

The thickness w of the rotating member 242 is preferably 5 mm or more, more preferably 10 mm or more, further preferably 15 mm or more, particularly preferably 30 mm or more, and the flatness improvement of the glass ribbon 14 in consideration of the grip force with the glass ribbon 14. In view of preventing unnecessary increase in grip width, it is preferably 120 mm or less, more preferably 100 mm or less, further preferably 80 mm or less, still more preferably 60 mm or less, and particularly preferably 40 mm or less.

FIG. 8 is a cross-sectional view showing a rotating member according to another modification. A rotating member 342 shown in FIG. 8 is used in place of the rotating member 42 shown in FIG. The cross-sectional shape of the outer peripheral surface of the rotating member 342 is flat, and the rotating member 342 has a rounded boundary portion between the outer peripheral surface and the side surface. The boundary is formed by chamfering or the like.

In the modification shown in FIG. 5 or the modification shown in FIG. 8, a plurality of protrusions having a height of 0.1 to 10 mm may be provided on the outer peripheral surface of the rotating member, or the depth of 0.1 to 10 may be provided on the outer peripheral surface of the rotating member. A plurality of 10 mm grooves may be provided. Moreover, you may provide both a processus | protrusion and a groove | channel on the outer peripheral surface of a rotation member. The height of the protrusion and the depth of the groove are measured using the outer peripheral surface of the rotating member as a reference surface. The height of the protrusion and the depth of the groove are smaller than the radius r shown in FIG. 6, the curvature radius Ra shown in FIG. 6, and the curvature radii Rb and Rc shown in FIG.

This application claims priority based on Japanese Patent Application No. 2013-104378 filed with the Japan Patent Office on May 16, 2013. The entire contents of Japanese Patent Application No. 2013-104378 are incorporated herein by reference. To do.

DESCRIPTION OF SYMBOLS 10 Forming apparatus 40 Support roll 42 Rotating member 43 Concavity and convexity 44 Shaft member 46 Flange (overhang member)
48 heat transfer member 50 pressing member 51 pressing member main body 52 contact portion 54 first elastic body 60 heat insulating member 64 centering member 66 second elastic body

Claims

A support roll for supporting a belt-like glass ribbon,
A rotating member in contact with the glass ribbon;
A shaft member having a refrigerant flow path therein and rotating together with the rotating member;
A branch path branched from the refrigerant flow path, and a projecting member projecting from the outer periphery of the shaft member,
The rotating member is formed of ceramics;
A support roll in which a heat transfer member having a higher thermal conductivity than the rotating member is disposed between the projecting member and the rotating member.
The support roll according to claim 1, further comprising a pressing member that presses the rotating member against the heat transfer member.
The support roll according to claim 2, further comprising a first elastic body that urges the pressing member that is displaceable in the axial direction of the shaft member toward the rotating member.
The shaft member is inserted through a through hole formed in the rotating member,
The support according to any one of claims 1 to 3, wherein a heat insulating member having a thermal conductivity lower than that of the rotating member is disposed between an inner periphery of the rotating member and an outer periphery of the shaft member. roll.
The support roll according to claim 4, wherein a contact surface of the rotating member with the heat insulating member has a tapered shape.
The support roll according to claim 4 or 5, wherein a contact surface of the heat insulating member with the rotating member has a tapered shape.
The support roll according to claim 5 or 6, further comprising a second elastic body that urges the heat insulating member that is displaceable in the axial direction of the shaft member toward the projecting member.
The support roll according to any one of claims 1 to 7, wherein at least a portion of the rotating member that contacts the glass ribbon is formed of silicon nitride ceramics.
The silicon nitride ceramic is a sintered body having an aluminum (Al) content of 0.1% by mass or less, a magnesium (Mg) content of 0.7% by mass or less, and a titanium (Ti) content. The support roll of Claim 8 whose quantity is 0.9 mass% or less.
10. The silicon nitride ceramic according to claim 9, wherein the content of zirconium (Zr) is 3.5 mass% or less and the content of yttrium (Y) is 0.5 mass% or more and 10 mass% or less. Support roll.
The support roll according to any one of claims 1 to 10, wherein an outer peripheral surface of the rotating member is formed in a curved shape whose cross-sectional shape is convex radially outward over the entire circumference.
The support roll according to any one of claims 1 to 10, wherein the rotating member has gear-like irregularities on an outer periphery.
A method for forming a glass plate, comprising a step of supporting a strip-shaped glass ribbon using the support roll according to any one of claims 1 to 12.
A glass having a step of supporting a strip-shaped glass ribbon using the support roll according to any one of claims 1 to 12, and then gradually cooling and cutting the glass ribbon. A manufacturing method of a board.
A glass plate forming apparatus comprising the support roll according to any one of claims 1 to 12.