WO2014184387A1 - Optoelektronisches bauelement - Google Patents
Optoelektronisches bauelement Download PDFInfo
- Publication number
- WO2014184387A1 WO2014184387A1 PCT/EP2014/060243 EP2014060243W WO2014184387A1 WO 2014184387 A1 WO2014184387 A1 WO 2014184387A1 EP 2014060243 W EP2014060243 W EP 2014060243W WO 2014184387 A1 WO2014184387 A1 WO 2014184387A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- optoelectronic component
- cover
- component according
- encapsulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
- H10K50/841—Self-supporting sealing arrangements
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/80—Constructional details
- H10K30/88—Passivation; Containers; Encapsulations
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
- H10K50/844—Encapsulations
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Definitions
- Optoelectronic component The following is an optoelectronic component with a radiation-emitting or radiation-absorbing
- Optoelectronic devices such as organic light emitting diodes (OLEDs) or organic solar cells usually have a thin film encapsulant which encases the electrodes and radiation emitters
- Cover substrate layer applied to the thin-film encapsulation which may for example consist of glass.
- the optoelectronic component is subjected to a mechanical load, delamination of the cover substrate layer may occur, as a result of which the thin-film encapsulation is damaged and the thin-film encapsulant is damaged
- At least one object of certain embodiments is to provide an optoelectronic device with a
- An optoelectronic component comprises in particular a substrate, a first electrode on the substrate, a radiation-emitting or
- Electrode a second electrode on the layer sequence, an encapsulation layer arranged on the second electrode and an arranged on the encapsulation layer
- Cover layer with a first and a second
- Main area being between the first and the second
- Main surface of the cover layer at least one
- a layer or an element is arranged or applied "on” or “above” another layer or another element can mean here and below that the one layer or the one element is directly in direct mechanical and / or electrical contact is arranged on the other layer or the other element.
- the one layer or the one element is arranged indirectly on or above the other layer or the other element.
- the cover layer does not have to be formed homogeneously, but may, for example, be made up of a plurality of
- Main surface of the cover layer are the two largest boundary surfaces of the preferably flat-shaped
- Cover layer meant in a plate-shaped
- cover layer for example, the two side surfaces with the largest surface area. If the
- Cover layer is disposed directly on the encapsulation layer, the first major surface preferably falls with the interface between the cover layer and the
- the two main surfaces are parallel to each other.
- predetermined breaking area is meant a surface on which the material of the cover layer yields mechanically when the optoelectronic component is subjected to mechanical stress. This relates in particular to a mechanical load in an area of the optoelectronic
- Encapsulation layer and the cover layer comprises.
- mechanical stress is meant in particular a state in which deformation forces such as
- the predetermined breaking surface does not necessarily have to be flat and does not necessarily have to run parallel to one of the two main surfaces of the covering layer. Similarly, the predetermined breaking surface does not have to over the entire surface extend the cover layer, but can only in
- Subareas thereof may be arranged.
- Cover layer extends and in particular not on one of the encapsulation layer facing the main surface of the
- Component for example, after a partial delamination of the cover layer is still fully usable, since both the encapsulation layer is still intact and the mechanical protection continues to exist through the cover layer.
- Sollbruch parallel to the first major surface and / or to the second major surface of the cover layer and / or to the interface between the cover layer and the
- Angle between a normal vector of the predetermined breaking surface and a normal vector of the first major surface and / or a normal vector of the second major surface of the cap layer and / or a normal vector of the interface between the cap layer and the encapsulation layer is less than 30 °, in particular less than 15 °.
- Cover layer largely under mechanical stress or remains completely undamaged and there is no demolition of the two layers from each other.
- the first electrode and / or the second electrode may be formed over a large area or particularly preferably over a large area. Large area can mean that the first
- Electrode and / or the second electrode has an area greater than or equal to a few square millimeters, preferably greater than or equal to one square centimeter, and more preferably greater than or equal to a square decimeter
- first electrode and / or the second electrode in first and second, respectively
- first electrode in the form of parallel juxtaposed first electrode strips
- first and second electrode strips can thus be considered as separate
- first and / or the second electrode or electrode subregions are electrically conductively connected to first conductor tracks.
- an electrode or an electrode part region for example, in a first
- the encapsulation layer can cover the entire layer sequence with the electrodes. Furthermore, it may cover at least a part of the surface of the substrate on which the
- the layer sequence comprises one or more functional layers of organic material.
- the layer sequence comprises one or more functional layers of organic material.
- Optoelectronic component may be formed as an organic light-emitting diode (OLED) or as an organic solar cell, depending on whether the layer sequence is formed radiation-emitting or radiation-absorbing.
- OLED organic light-emitting diode
- O solar cell organic solar cell
- the functional layers can, for example, as
- Layers and / or hole transport layers may be formed.
- a second electrode may be applied over the functional layers.
- the functional layers in an active region by electron and hole injection and - Recombination electromagnetic radiation with a
- the functional layers may be organic polymers, organic oligomers, organic monomers, organic small, non-polymeric molecules ("small molecules") or
- the optoelectronic component can also as
- Layer sequence comprise a semiconductor layer sequence.
- Cover layer may be transparent, so that the optoelectronic component is designed as a so-called “top emitter”
- the optoelectronic component can be embodied both as a “top emitter” and as a “bottom emitter”.
- the encapsulation layer is designed to protect the electrodes and the layer sequence from moisture and / or atmospheric oxygen.
- the encapsulation layer is preferably a so-called thin-film encapsulation, which consists of one or more thin ones Layers is formed.
- Thin-film encapsulation layers are known, for example, from the publications WO 2009/095006 Al and WO 2010/108894 Al, their respective
- the individual layers of the thin-film encapsulation may each have a thickness between an atomic layer and about 1 ⁇ m.
- the total thickness of the encapsulation layer is for example less than 10 ⁇ m, less than 1 ⁇ m or even less than 100 nm.
- the thin-film encapsulation preferably contains one or more metal oxide layers.
- the encapsulation layer is advantageously by means of plasma enhanced chemical ⁇ vapor deposition (PE-CVD, plasma-enhanced chemical vapor deposition),
- ALD Atomic layer deposition
- MLD molecular deposition
- thermal evaporation applied.
- the encapsulation layer preferably forms a
- Barrier layer or comprises at least one barrier layer.
- the barrier layer may be impermeable or difficult to penetrate for oxygen and / or moisture.
- the barrier layer may comprise an oxide, a nitride or an oxynitride.
- the oxide, nitride or oxynitride may further comprise aluminum, silicon, tin or zinc.
- the barrier layer may have dielectric or also electrically conductive properties and, for example, silicon oxide, for example S1O 2 , Silicon nitride, such as S1 2 3 , silicon oxynitride (SiO x N y ),
- Alumina such as Al 2 O 3 , aluminum nitride, tin oxide,
- the barrier layer can be Indium tin oxide, zinc oxide or aluminum zinc oxide. Alternatively or additionally, the barrier layer can be any suitable barrier layer.
- Prevent barrier layer Suitable materials for this purpose may be, for example, alkali metals and alkaline earth metals.
- the barrier layer for example, by a
- Application method can be a method of chemical
- PVD Physical vapor deposition
- the encapsulation layer can also be a plurality of
- barrier layers may mean at least two or more layers
- the barrier layers may have the same or different materials as stated above.
- the cover layer is split by cohesive failure when a tensile or shear force acting locally on it cohesively
- the cover layer comprises a plurality of single-layer elements, wherein two adjacent single-layer elements are connected to one another via a cohesive connection, which is designed such that the predetermined breaking surface
- Component occurs an adhesion break at the interface between the two adjacent single-layer elements.
- Cover layer and the encapsulation layer is so large that the cover layer at a mechanical load of the optoelectronic device at the
- cover layer will adhere to the encapsulation layer. Rather, it is sufficient that at least one sub-layer of the cover layer, one main surface of which with the interface between cover layer and encapsulation layer coincides, adheres to the encapsulation layer, so that the interface between cover layer and
- Encapsulation layer is not damaged. According to a further embodiment, it is provided that the cover layer has an adhesive layer and one on the
- Adhesive layer arranged cover substrate layer comprises.
- adhesive layer is to be understood in the context of the present invention as functional and not merely in the narrow sense of an adhesive. Adhesive effect is the adhesive layer only as long as a separation between the by the
- Adhesive layer cohesively bonded layers has not yet occurred.
- the adhesive layer may consist of or contain liquid epoxy resin cured by UV irradiation.
- the material of the adhesive layer is
- liquid adhesives but not limited to liquid adhesives. It can also be, for example, an acrylate adhesive.
- a thickness of the adhesive layer is between 5 ⁇ m and 100 ⁇ m, particularly preferably between 20 ⁇ m and 30 ⁇ m.
- the cover substrate layer may comprise, for example, one or more materials in the form of a layer, a plate, a foil or a laminate, which are selected from glass, quartz, plastic, metal and silicon wafers.
- the cover substrate layer particularly preferably comprises or is made of glass, for example in the form of a glass layer, glass film or glass plate. Furthermore, it is preferred that a thickness of the cover substrate layer is between 0.1 and 4 mm. According to a further embodiment, it is provided that the adhesive layer is arranged directly on the encapsulation layer and an adhesion force between the adhesive layer and the encapsulation layer is so great that the adhesive layer is exposed to a mechanical load of the optoelectronic
- Component sticks to the encapsulation layer.
- Encapsulation layer is not damaged.
- the adhesive layer adheres to a sufficient adhesive force preventing the delamination of the adhesive layer from the encapsulation layer, and on the other hand a layer arranged above the interface between the adhesive layer and the encapsulation layer, for example the adhesive layer itself or an additionally inserted intermediate layer due to cohesive failure two sublayers is split or two adjacent above the interface between the
- Adhesive layer and the encapsulation layer arranged
- the adhesive layer thus has optimized adhesive properties with respect to the encapsulation layer, so that the mechanical stress at least in the local area between
- Adhesive layer and encapsulation layer unfolds little or no effect.
- the entire adhesive layer adheres or adheres to the encapsulation layer.
- the cover substrate layer is arranged directly on the adhesive layer and that, in the case of a mechanical load on the adhesive layer
- Optoelectronic device an adhesion break at an interface between the adhesive layer and the
- Whether an adhesion break between the adhesive layer and the top substrate layer or a cohesive break within the adhesive layer occurs during the separation can be adjusted via the material and / or the surface properties of the adhesive layer and the encapsulation layer.
- At least one intermediate layer is arranged between the adhesive layer and the cover substrate layer and that, in the case of a mechanical load of the optoelectronic
- FIGS. 2 and 3 show the effect of a mechanical load in an optoelectronic component according to the prior art
- FIGS 4 to 9 are schematic representations of optoelectronic components according to further embodiments.
- the same or equivalent components may each have the same
- FIG. 1 shows an optoelectronic component according to a first embodiment of the invention.
- Substrate layer 1 made of glass is a first transparent
- Electrode layer 2 is arranged. On the first Electrode layer 2 is a radiation emitting
- a second electrode layer 6 which contains a metal. So that's it
- OLED organic light emitting diode
- Thin-film encapsulation layer 8 applied, which the two electrode layers 2, 6 and the layer sequence 4 before
- a laminating adhesive layer 10 is arranged, which serves a directly on the laminating adhesive layer 10 and arranged as
- Cover layer 24 which provides mechanical protection for the thin film encapsulation layer 8.
- the interface between the thin film encapsulation layer 8 and the laminating adhesive layer 10 coincides with a first one
- an adhesion break takes place at the predetermined breaking surface 18.
- FIGS. 2 and 3 show how a mechanical load on a prior art optoelectronic component causes damage to the device
- Thin film encapsulation layer 8 can lead, so if no predetermined breaking surface in the interior of the cover layer 24th
- the laminating substrate layer 12 is brought to a desired size by breaking a large-area glass layer along mechanically weakened by boundaries scratches 26. During the breaking of the material, the glass layer is lifted up, whereby it is in an area between the
- Thin film encapsulation layer 8 and the laminating adhesive layer 10 comes to tensile stresses, which upon reaching a critical threshold, the lamination adhesive layer 10 from the thin film encapsulation layer 8 replace. This can lead to unwanted damage to the
- Thin film encapsulation layer 8 come, so that subsequently moisture or oxygen in the interior of the
- FIGS. 4 and 5 show how an adhesion break occurs at the predetermined breaking surface 18 when the predetermined breaking surface 18 coincides with the interface between the laminating adhesive layer 10 and the laminating substrate layer 12, as also shown in FIG.
- the adhesion forces are coordinated with respect to the respective interfaces that occur when
- Laminierubstrat Anlagen 12 peels off the laminating adhesive layer 10, while the laminating adhesive layer 10 completely adheres to the Dünn fürverkapselungs für 8, whereby the interface between the laminating adhesive layer 10 and the Dünn fürverkapselungs für 8 remains undamaged.
- a similar mechanism also works when
- the laminating adhesive layer 10 and the thin film encapsulation layer 8 are larger (for example, greater than or equal to 50 N / cm) than the adhesion force between the laminating adhesive layer 10 and the laminating substrate layer 12 (for example, less than or equal to 30 N / cm). Furthermore, the cohesive force, which respectively in the respective layers
- Laminierubstrat Anlagen 12 of the laminating adhesive layer 10 for example, starting from an edge of the laminating adhesive layer
- Laminating adhesive layer 10 wherein the adhesion fracture gradually towards an opposite edge along a direction perpendicular to the tension plane extending
- Embodiment extends the predetermined breaking surface 18 within the laminating adhesive layer 10. In this case, takes place at
- Lamination adhesive layer 10 As a result, this splits into two separate sublayers, one of which adheres to the thin film encapsulation layer 8, while the other sublayer adheres to the lamination substrate layer 12 and goes with it.
- a cohesive force within the laminating adhesive layer 10 is smaller than that
- a splittable laminating adhesive layer 10 is provided so that the interface between the Laminierklebertik 10 and the thin film encapsulation layer 8 is not affected by a mechanical stress.
- FIG. 7 shows an optoelectronic component according to a further embodiment. In contrast to the embodiments shown in Figure 1 and Figures 4-6 is between the laminating adhesive layer 10 and the
- Laminierubstrat Anlagen 12 an additional intermediate layer 22 is arranged so that the cover layer 24 by the three said layers 10, 12, 22 is formed.
- the predetermined breaking surface 18 can be formed in different levels of the cover layer 24. In the embodiment shown in Figure 8, the predetermined breaking surface 18 extends within the intermediate layer 22. In this case, takes place under mechanical stress
- Thin film encapsulation layer 8 adheres, while the other sub-layer adheres to the laminating substrate layer 12 and goes along.
- the predetermined breaking surface 18 extends at the interface between the
- Interlayer 22 detaches from the laminating adhesive layer 10, while the laminating adhesive layer 10 completely adheres to the thin film encapsulating layer 8, whereby the interface between the laminating adhesive layer 10 and the thin film encapsulating layer 8 remains undamaged.
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- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Electromagnetism (AREA)
- Electroluminescent Light Sources (AREA)
Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201480028678.9A CN105229816B (zh) | 2013-05-17 | 2014-05-19 | 光电子器件 |
| DE112014002467.8T DE112014002467B4 (de) | 2013-05-17 | 2014-05-19 | Optoelektronisches Bauelement |
| US14/888,395 US9748519B2 (en) | 2013-05-17 | 2014-05-19 | Optoelectronic component |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102013105128.6 | 2013-05-17 | ||
| DE102013105128.6A DE102013105128A1 (de) | 2013-05-17 | 2013-05-17 | Optoelektronisches Bauelement |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2014184387A1 true WO2014184387A1 (de) | 2014-11-20 |
Family
ID=50780473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2014/060243 Ceased WO2014184387A1 (de) | 2013-05-17 | 2014-05-19 | Optoelektronisches bauelement |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US9748519B2 (de) |
| CN (1) | CN105229816B (de) |
| DE (2) | DE102013105128A1 (de) |
| WO (1) | WO2014184387A1 (de) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102016103336B4 (de) * | 2016-02-25 | 2026-04-02 | Pictiva Displays International Limited | Elektronisches Bauelement und Verfahren zu seiner Herstellung |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002164164A (ja) * | 2000-11-27 | 2002-06-07 | Denso Corp | 有機el素子 |
| JP2004303529A (ja) * | 2003-03-31 | 2004-10-28 | Toppan Printing Co Ltd | 有機エレクトロルミネッセンス素子用封止部材及び有機エレクトロルミネッセンス素子 |
| US20080220151A1 (en) * | 2007-03-07 | 2008-09-11 | Canon Kabushiki Kaisha | Method for manufacturing organic electroluminescence panel |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006351299A (ja) * | 2005-06-14 | 2006-12-28 | Tohoku Pioneer Corp | 自発光パネル、自発光パネル用の封止部材、および自発光パネルの製造方法 |
| EP2193691B1 (de) * | 2007-08-17 | 2011-10-26 | Philips Intellectual Property & Standards GmbH | Skalierbarer stromverteiler |
| TWI420722B (zh) | 2008-01-30 | 2013-12-21 | 歐斯朗奧托半導體股份有限公司 | 具有封裝單元之裝置 |
| LU91493B1 (en) | 2008-10-31 | 2010-05-03 | Wurth Paul Sa | Method for operating a blast furnace and blast furnace installation |
| DE102009024411A1 (de) | 2009-03-24 | 2010-09-30 | Osram Opto Semiconductors Gmbh | Dünnschichtverkapselung für ein optoelektronisches Bauelement, Verfahren zu dessen Herstellung und optoelektronisches Bauelement |
| DE102009042795A1 (de) * | 2009-09-25 | 2011-04-07 | Schreiner Group Gmbh & Co. Kg | Verfahren zur Herstellung eines Elektrolumineszenzelements, Verwendung eines Drucklacks und Elektrolumineszenzelement |
| JP5290268B2 (ja) | 2009-12-31 | 2013-09-18 | 三星ディスプレイ株式會社 | バリア・フィルム複合体、これを含む表示装置、バリア・フィルム複合体の製造方法、及びこれを含む表示装置の製造方法 |
| DE102011077614B4 (de) | 2011-06-16 | 2023-08-17 | Osram Gmbh | Verfahren zur Herstellung einer Leuchtvorrichtung und Leuchtvorrichtung |
| DE102011084276B4 (de) * | 2011-10-11 | 2019-10-10 | Osram Oled Gmbh | Verkapselung für ein organisches elektronisches bauelement, ein organisches elektronisches bauelement mit der verkapselung und ein verfahren zur herstellung eines organischen elektronischen bauelements mit der verkapselung |
-
2013
- 2013-05-17 DE DE102013105128.6A patent/DE102013105128A1/de not_active Withdrawn
-
2014
- 2014-05-19 WO PCT/EP2014/060243 patent/WO2014184387A1/de not_active Ceased
- 2014-05-19 CN CN201480028678.9A patent/CN105229816B/zh active Active
- 2014-05-19 US US14/888,395 patent/US9748519B2/en active Active
- 2014-05-19 DE DE112014002467.8T patent/DE112014002467B4/de active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002164164A (ja) * | 2000-11-27 | 2002-06-07 | Denso Corp | 有機el素子 |
| JP2004303529A (ja) * | 2003-03-31 | 2004-10-28 | Toppan Printing Co Ltd | 有機エレクトロルミネッセンス素子用封止部材及び有機エレクトロルミネッセンス素子 |
| US20080220151A1 (en) * | 2007-03-07 | 2008-09-11 | Canon Kabushiki Kaisha | Method for manufacturing organic electroluminescence panel |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105229816B (zh) | 2017-08-08 |
| DE112014002467B4 (de) | 2022-05-25 |
| DE112014002467A5 (de) | 2016-02-18 |
| DE102013105128A1 (de) | 2014-11-20 |
| CN105229816A (zh) | 2016-01-06 |
| US20160079563A1 (en) | 2016-03-17 |
| US9748519B2 (en) | 2017-08-29 |
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