WO2014178371A1

WO2014178371A1 - Skin cleanser composition

Info

Publication number: WO2014178371A1
Application number: PCT/JP2014/061856
Authority: WO
Inventors: 晃平山田; 敦史友國; 田中　幸司; 大輔澤; 川合　隆
Original assignee: 花王株式会社
Priority date: 2013-04-30
Filing date: 2014-04-28
Publication date: 2014-11-06

Abstract

Provided is a skin cleanser composition that comprises the following components (A), (B), (C), (D), and (E): 0.1-25 mass% of an ether oil (A) that is a liquid at 25 °C; 0.003-1 mass% of a water-soluble polymer (B) that includes acrylic acid or methacrylic acid as a constituent unit thereof; 1-30 mass% of a hydrocarbon oil (C) that has a viscosity of 15 mPa·s or less at 30 °C; 60-95 mass% of water (D); and 0.49 mass% or less of a non-ionic surfactant (E) having an HLB that is greater than 9. The mass ratio (B)/(A) of the components (A) and (B) is 0.0001-0.1 and the mass ratio (A)/((A)+(C)) of the components (A) and (C) is 0.05-0.9.

Description

Skin cleanser composition

The present invention relates to a skin cleanser composition and a skin cleansing sheet.

A variety of cleansing agents that remove makeup stains have been developed due to diversification of makeup products and consumer preference. In recent years, the number of waterproof mascaras that are difficult to remove has increased, and cleansing agents that firmly remove difficult-to-drop waterproof mascaras have been studied. Patent Documents 1 to 3).

Further, conventionally, a cleaning sheet in which a base material sheet such as a nonwoven fabric is impregnated with a cleaning agent is known. For example, a cleaning sheet (Patent Document 4, Patent Document 5) that specifies the basis weight of the nonwoven fabric to be the base sheet, the type of fiber, and the composition of the cleaning agent, and a wet wipe product that enhances the skin barrier (Patent Document 6) Furthermore, a cleansing material (Patent Document 7) in which the viscosity of the cleaning agent is specified has been studied.

(Patent Document 1) JP 2000-191438 (Patent Document 2) JP 2004-339212 (Patent Document 3) JP 2009-242340 (Patent Document 4) JP 2003-164407 (Patent Document 3) Document 5) JP 2002-209823 (Patent Document 6) JP 2002-542274 (Patent Document 7) JP 2001-302450

The present invention includes the following components (A), (B), (C), (D) and (E):
(A) 0.1 to 25% by mass of ether oil which is liquid at 25 ° C.
(B) a water-soluble polymer containing acrylic acid or methacrylic acid as a structural unit 0.003 to 1% by mass,
(C) 1-30% by mass of a hydrocarbon oil having a viscosity at 30 ° C. of 15 mPa · s or less,
(D) 60-95% by weight of water,
(E) A nonionic surfactant having an HLB greater than 9 is contained in an amount of 0.49% by mass or less, and the mass ratio (B) / (A) of the component (A) to the component (B) is 0.0001-0. And a skin cleansing composition having a mass ratio (A) / ((A) + (C)) of components (A) and (C) of 0.05 to 0.9.

The present invention also provides a non-woven fabric having a layer structure including a first layer and two second layers arranged on the surface side of the first layer, and an O / W having a viscosity at 30 ° C. of 200 to 15000 mPa · s. The ratio of the density of the first layer of the nonwoven fabric to the density of the second layer (density of the first layer / density of the second layer) is 1.05 or more. And the thickness of one side of the second layer (the thickness of the first layer / the thickness of the one side of the second layer) is related to the skin cleansing sheet of 0.6 to 1.5.

It is a figure which shows an example of the cross section at the time of folding the skin washing sheet of this invention.

Detailed Description of the Invention

Patent Document 1 describes a cleansing cosmetic containing a dialkyl ether and a nonionic surfactant. However, since the content of the nonionic surfactant is large, it takes time until oil is released from the product. The familiarity with the mascara stain was slow, and the skin after washing remained oily. Patent Document 2 describes a cleansing composition containing a specific polyol and an oil, but it was not satisfactory in terms of the oily feeling of the skin after use. Patent Document 3 describes a cleansing cosmetic containing a volatile oil, a non-volatile oil, a hydrophilic nonionic surfactant and a thickening agent, but the skin feeling after use can be satisfied. It was not a thing.

Thus, the conventional cleansing agents have problems in terms of feel, such as insufficient detergency and further leaving an oily feeling on the skin after use.
The present invention relates to a skin cleanser composition capable of sufficiently removing difficult makeup such as waterproof mascara and having good skin feel after use.

Further, the conventional cleaning sheet has insufficient cleaning power, and there is a problem in terms of stability. In particular, when a skin cleaning sheet is used, it is impossible to remove makeup that is difficult to remove, and there are problems with the feel and stability when the skin is wiped off.
The present invention relates to a skin cleansing sheet that can sufficiently remove difficult makeup such as a waterproof mascara and has excellent feel and stability when the skin is wiped off.

The inventors of the present invention can sufficiently remove difficult makeup such as a waterproof mascara by using a liquid ether oil, a specific water-soluble polymer, and a hydrocarbon oil in combination at a specific ratio. It has been found that a skin cleansing composition can be obtained in which the skin feels like sticking and the feeling is sustained. The feeling that the skin sticks is that it feels like it sticks to the hand when the skin after use is touched with a hand, and does not slide up.

The inventors have also found that a skin cleansing sheet that solves the above problems can be obtained by impregnating a non-woven fabric having a layer structure with different densities with an O / W emulsion having a specific viscosity.

The skin cleanser composition of the present invention provides high cleaning power even for makeup that is difficult to fall off, such as waterproof mascara, and it feels refreshing without feeling oily, so that the skin after use sticks to it. A feeling of moistness is obtained, and the feeling lasts.

In addition, the skin cleaning sheet of the present invention provides a refreshing feeling with high detergency even for makeup that is difficult to remove, such as waterproof mascara, and is excellent in sheet thickness, softness, and smoothness. The stability of the skin cleaning sheet is also good.

The ether oil of component (A) used in the skin cleansing composition of the present invention is liquid at 25 ° C. The liquid state is a state having fluidity at 25 ° C., and the viscosity at 25 ° C. is 10000 mPa · s or less, preferably 50 mPa · s or less, more preferably 15 mPa · s or less.
The liquid ether oil of component (A) is preferably a dialkyl ether having 2 alkyl groups having 16 or less carbon atoms, and more preferably a dialkyl ether having 2 alkyl groups having 8 or less carbon atoms. In the dialkyl ether, the two alkyl groups may be the same or different.
More specifically, for example, dioctyl ether, cetyl-1,3-dimethylbutyl ether, dihexyl ether, dilauryl ether and the like can be mentioned. Of these, cetyl-1,3-dimethylbutyl ether and dioctyl ether are preferred, and dioctyl ether is more preferred from the viewpoint that high detergency and oily feeling are not felt.

Component (A) can be used singly or in combination of two or more, and in terms of detergency, refreshing feeling, moist feeling, the content is 0.1% by mass or more in the total composition, 0.5 mass% or more is preferable, 1 mass% or more is more preferable, it is 25 mass% or less, 10 mass% or less is preferable, and 6 mass% or less is more preferable. The content of component (A) is from 0.1 to 25% by mass, preferably from 0.5 to 10% by mass, more preferably from 1 to 6% by mass in the total composition.

The water-soluble polymer of the component (B) contains acrylic acid or methacrylic acid as a constituent component, and is a water-soluble polymer containing constituent units derived from acrylic acid or methacrylic acid.
The water-soluble polymer containing a structural unit of acrylic acid or methacrylic acid is synthesized using acrylic acid or methacrylic acid as a monomer, and examples thereof include a carboxyvinyl polymer and an acrylic acid / alkyl methacrylate copolymer. Of these, from the viewpoint of stability after storage, an acrylic acid / alkyl methacrylate copolymer is preferable, and a copolymer of acrylic acid and an alkyl methacrylate having 10 to 30 carbon atoms ((acrylic acid / alkyl acrylate)). (C10-30)) copolymers) are more preferred. Examples of commercially available products include PEMULEN TR-1, PEMULEN TR-2, Carbopol ETD2020 (manufactured by Lubrizol Advanced Materials) and the like.

The water-soluble polymer containing the component (B) acrylic acid or methacrylic acid as a structural unit is preferably used by neutralizing all or part of the acrylic acid or methacrylic acid unit with an alkali agent. The alkali agent to be neutralized is not particularly limited as long as it is an alkali agent that can be usually added to cosmetics. For example, potassium hydroxide, sodium hydroxide, and the like can be used. The alkaline agent can be used alone or in combination of two or more, and is preferably contained in the skin cleanser composition of the present invention in an amount of 0.0012% by mass to 0.4% by mass. The pH of the cleaning composition is preferably 5 to 9, and more preferably adjusted to pH 5.5 to 8.

Component (B) can be used singly or in combination of two or more. From the viewpoint of detergency, refreshing feeling, moist feeling, and stability, the content is 0.003% by mass or more in the total composition. 0.01 mass% or more is preferable, 0.05 mass% or more is more preferable, 1 mass% or less is preferable, 0.5 mass% or less is preferable, and 0.1 mass% or less is more preferable. The content of component (B) is 0.003 to 1% by mass, preferably 0.01 to 0.5% by mass, and more preferably 0.05 to 0.1% by mass in the total composition.

In the present invention, the mass ratio (B) / (A) of the component (A) and the component (B) is from the viewpoint of detergency, refreshing feeling, feeling that the skin after use is sucked, moist feeling, and stability. 0.0001 or more, 0.001 or more is more preferable, 0.01 or more is more preferable, 0.1 or less is preferable, 0.085 or less is more preferable, and 0.07 or less is more preferable. Further, the mass ratio (B) / (A) of the component (A) to the component (B) is preferably 0.0001 to 0.1, more preferably 0.001 to 0.085, and 0.01 to 0.00. 07 is more preferable.

The hydrocarbon oil of component (C) used in the present invention has a viscosity at 30 ° C. of 15 mPa · s or less, preferably 1 to 10 mPa · s from the viewpoint of refreshing feeling.
Here, the viscosity is measured with a BM viscometer (manufactured by Tokimec, measurement conditions: rotor No. 1, 60 rpm, 1 minute).
Examples of the hydrocarbon oil of component (C) include isododecane, isohexadecane, hydrogenated polyisobutene, and the like, and isododecane is preferred because it has excellent detergency and feel without oiliness.

Component (C) can be used singly or in combination of two or more. From the standpoint of detergency and refreshing feeling, the content is 1% by mass or more, and 5% by mass or more in the total composition. Preferably, 8 mass% or more is more preferable, it is 30 mass% or less, 25 mass% or less is preferable, and 15 mass% or less is more preferable. Further, the content of the component (C) is 1 to 30% by mass in the total composition, preferably 5 to 25% by mass, and more preferably 8 to 15% by mass.

In the present invention, the mass ratio (A) / ((A) + (C)) of the component (A) and the component (C) has a high detergency and feels like the skin after use is sucked. From the point which suppresses the skin's sliminess, it is 0.05 or more, 0.08 or more is preferable, 0.1 or more is more preferable, it is 0.9 or less, 0.8 or less is preferable, and 0.4 or less is More preferred. The mass ratio (A) / ((A) + (C)) of the component (A) and the component (C) is 0.05 to 0.9, preferably 0.08 to 0.8, 1 to 0.4 is more preferable.

The water of component (D) forms the balance of each component, and the content is 60% by mass or more, preferably 65% by mass or more, more preferably 70% by mass or more in the total composition from the point of refreshing feeling. , 95% by mass or less, preferably 90% by mass or less, and more preferably 85% by mass or less. The content of component (D) is 60 to 95% by mass in the total composition, preferably 65 to 90% by mass, and more preferably 70 to 85% by mass.

In the present invention, the mass ratio (A) / (D) of the component (A) and the component (D) is preferably 0.001 or more from the viewpoint that the skin after use is not oily and refreshes, The above is more preferable, 0.02 or more is more preferable, 0.45 or less is preferable, 0.25 or less is more preferable, and 0.15 or less is more preferable. Further, the mass ratio (A) / (D) of the component (A) to the component (D) is preferably 0.001 to 0.45, more preferably 0.01 to 0.25, and 0.02 to 0.00. 15 is more preferable.

In the present invention, the mass ratio (B) / (D) of the component (B) and the component (D) makes the component (B) easily spread in water, and maintains the stability when an O / W emulsion is obtained, 0.000035 or more is preferable, 0.0001 or more is more preferable, 0.0005 or more is further preferable, 0.015 or less is preferable, and 0.015 or less is preferable, in that the feeling that the skin after wiping becomes stronger becomes stronger. The following is more preferable, and 0.005 or less is more preferable. The mass ratio (B) / (D) of the component (B) to the component (D) is preferably 0.000035 to 0.015, more preferably 0.0001 to 0.01, and 0.0005 to 0.00. 005 is more preferable.

The skin cleansing composition of the present invention can further contain (E) a nonionic surfactant having an HLB greater than 9, and when used, accelerates the release of oil in the emulsion and quickly exhibits the cleaning performance. And more excellent stability can be obtained.
The nonionic surfactant is preferably HLB 9 to 20, more preferably HLB 10 to 17.
HLB is an index indicating a hydrophilic-lipophilic balance, and in the present invention, a value calculated using the following equation by Oda and Teramura et al. Is used.

Examples of the nonionic surfactant include polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, propylene glycol fatty acid ester, polyoxyethylene polyoxypropylene glycol, sorbitan fatty acid ester, and polyoxyethylene sorbitan fatty acid. Ester, polyoxyethylene sorbit fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester, polyoxypropylene polyglyceryl ether, polyalkyl glyceryl ether, polyoxyethylene alkyl ether, polyoxy Ethylene alkyl ether fatty acid ester, sucrose fatty acid ester, alkyl polyglucoside, Poly) alkyl glyceryl ether, and the like.

Nonionic surfactants include polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, alkylpolyglucoside, and (poly) alkylglyceryl ether from the viewpoint of detergency. preferable.

Nonionic surfactants can be used alone or in combination of two or more. From the viewpoints of detergency, low stickiness, and stability, the content is 0.0001% by mass in the total composition. The above is preferable, 0.005 mass% or more is more preferable, 0.01 mass% or more is more preferable, 3 mass% or less is preferable, 0.49 mass% or less is more preferable, and 0.049 mass% or less is more preferable. . The content of the nonionic surfactant is preferably 0.0001 to 3% by mass, more preferably 0.005 to 0.49% by mass, and 0.01 to 0.049% by mass in the total composition. Further preferred.
In the present invention, the mass ratio ((E) / total oil agent) of the component (E) and the total oil agent is preferably 0.01 or less, more preferably 0.008 or less, and more preferably 0.005 or less from the viewpoint of stability. Further preferred.

In the present invention, the mass ratio (A) / (E) of the component (A) and the component (E) is 0.1 or more from the viewpoint of reducing detergency, stability, and the feeling of slimness of the skin after use. Preferably, 1 or more is more preferable, 40 or more is more preferable, 200000 or less is preferable, 600 or less is more preferable, and 200 or less is further preferable. Further, the mass ratio (A) / (E) between the component (A) and the component (E) is preferably 0.1 to 200000, more preferably 1 to 600, and further preferably 40 to 200.

The cleaning composition of the present invention can further contain (F) a water-soluble solvent and can provide a moist feeling.
Specific examples of the component (F) include polyhydric alcohol, polyglycerin, polyethylene glycol, polypropylene glycol, glyceryl ether in which an alkylene group is added to glycerin, sugar and the like.

More specifically, examples of the polyhydric alcohol include ethylene glycol, propylene glycol, isoprene glycol, 1,3-butylene glycol, hexylene glycol, trimethylolpropane, and glycerin. Of these, propylene glycol, isoprene glycol, 1,3-butylene glycol, hexylene glycol and glycerin are preferable, and 1,3-butylene glycol, propylene glycol, isoprene glycol and glycerin moisturize the skin after rinsing and wiping. More preferable in terms of feeling.

Also, examples of polyglycerin, polyethylene glycol, and polypropylene glycol include polyglycerin having a molecular weight of 2000 or less, polyethylene glycol having a molecular weight of 10,000 or less, and polypropylene glycol having a molecular weight of 1000 or less. Of these, diglycerin, polyethylene glycol 200, polyethylene glycol 400, polyethylene glycol 1000, polyethylene glycol 1540, dipropylene glycol, polypropylene glycol (3), and polypropylene glycol (7) are moisturizing feelings after rinsing and wiping. From the point of view, it is preferable.

Examples of the glyceryl ether in which an alkylene group is added to glycerin include polyoxypropylene diglyceryl ether, polyoxypropylene glyceryl ether, polyoxybutylene polyoxyethylene polyoxypropylene glyceryl ether, and the like. Among these, polyoxypropylene (9) diglyceryl ether, polyoxypropylene (14) diglyceryl ether, polyoxybutylene polyoxyethylene polyoxypropylene glyceryl ether (3B.O.) (8E.O.) (5P. O.) is preferable from the viewpoint of less stickiness.

Examples of the saccharide include sorbitol, erythritol, pentaerythritol, methyl glucoside, ethyl glucoside, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside, and alkyl glucosides having 2 or less carbon atoms in the alkyl chain are preferable. Of these, methyl glucoside, ethyl glucoside, polyoxyethylene methyl glucoside, and polyoxypropylene methyl glucoside are preferable, and polyoxyethylene methyl glucoside and polyoxypropylene methyl glucoside are preferred from the viewpoint of moisturizing skin after rinsing and wiping. More preferred.

Component (F) can be used singly or in combination of two or more, and a moist feeling is obtained, and the content is preferably 1% by mass or more, preferably 3% by mass in the total composition. % Or more is more preferable, 5 mass% or more is more preferable, 35 mass% or less is preferable, 25 mass% or less is more preferable, and 15 mass% or less is further more preferable. The content of component (F) is preferably 1 to 35% by mass, more preferably 3 to 25% by mass, and still more preferably 5 to 15% by mass in the total composition.

In the present invention, the mass ratio (A) / (F) of the component (A) and the component (F) is preferably 0.003 or more, more preferably 0.01 or more, from the point that moist feeling is obtained and there is little stickiness. Preferably, 0.1 or more is more preferable, 25 or less is preferable, 10 or less is more preferable, and 1 or less is more preferable. Further, the mass ratio (A) / (F) of the component (A) and the component (F) is preferably 0.003 to 25, more preferably 0.01 to 10, and further preferably 0.1 to 1.

In the present invention, the mass ratio (B) / (F) of the component (B) and the component (F) is preferably 0.0001 or more, more preferably 0.001 or more from the viewpoint that moist feeling is obtained and there is little stickiness. Preferably, 0.005 or more is more preferable, 1 or less is preferable, 0.1 or less is more preferable, and 0.02 or less is more preferable. Further, the mass ratio (B) / (F) of the component (B) to the component (F) is preferably 0.0001 to 1, more preferably 0.001 to 0.1, and 0.005 to 0.02. Further preferred.

The skin cleansing composition of the present invention can further contain (G) a nonionic water-soluble polymer containing cellulose as a structural unit, and can further reduce oiliness.
Examples of such nonionic water-soluble polymers include alkyl celluloses such as methyl cellulose and ethyl cellulose; hydroxyalkyl celluloses such as hydroxyethyl cellulose, hydroxypropyl cellulose, and hydroxypropyl methylcellulose.
Of these, hydroxyalkylcellulose is preferred and hydroxyethylcellulose is more preferred because of its high detergency and no oily feeling.

Further, the nonionic water-soluble polymer of component (G) is preferably one having a molecular weight of 50,000 to 3,000,000, more preferably 100,000 to 1300000, from the viewpoint of lack of detergency and oiliness.

Component (G) can be used singly or in combination of two or more, and in terms of detergency, lack of oiliness, moist feeling, the content is 0.01% by mass or more in the total composition Yes, 0.05 mass% or more is preferable, 0.075 mass% or more is more preferable, 5 mass% or less is preferable, 2 mass% or less is preferable, and 0.5 mass% or less is more preferable. The content of component (G) is 0.01 to 5% by mass, preferably 0.05 to 2% by mass, more preferably 0.075 to 0.5% by mass in the total composition.

In addition, the skin cleanser composition of the present invention preferably contains less than 5% by mass of the anionic surfactant in terms of detergency and low stickiness, and less than 5% by mass in the total composition. Is more preferable, 1 mass% or less is further more preferable, 0.1 mass% or less is further more preferable, and it is still more preferable not to contain.

The skin cleanser composition of the present invention can contain, in addition to the above-described components, components used in a normal cleanser composition as long as the effects of the present invention are not impaired. For example, oils other than the components (A) and (C), polymers other than the components (B) and (G), cationic surfactants, amphoteric surfactants, bactericides, anti-inflammatory agents, antiseptics, chelating agents , Salts, pearlizing agents, fragrances, cooling agents, pigments, ultraviolet absorbers, antioxidants, plant extracts, and the like.

Examples of the oil agent other than the components (A) and (C) include hydrocarbon oils such as liquid paraffin having a viscosity at 30 ° C. exceeding 30 mPa · s. Oil agents other than the components (A) and (C) can be used alone or in combination of two or more, and the content is preferably 0.01% by mass or more and 20% by mass or less in the total composition. Preferably, 10 mass% or less is more preferable, 5 mass% or less is more preferable, and 1 mass% or less is still more preferable.
Examples of the polymer other than the components (B) and (G) include sodium hyaluronate.
The cationic surfactant and the amphoteric surfactant are preferably not contained unless they are irreversibly mixed within a range that does not impair the effects of the present invention.

The skin cleansing composition of the present invention can be produced by mixing compounding ingredients and by a usual method. In the case of containing a raw material that is solid at room temperature, it can be produced by uniformly mixing all the components after heating and melting or dissolving in other components.
The skin cleansing composition of the present invention preferably has a viscosity at 25 ° C. of 200 to 10000 mPa · s, more preferably 500 to 4000 mPa · s, from the viewpoints of detergency, freshness and stability.
In addition, when the skin cleanser composition of the present invention is an O / W emulsion, the average particle size of the emulsified particles is preferably 1 to 30 μm from the viewpoint of detergency, stability and moist feeling, and 2 to 20 μm. Is more preferable, and 3 to 15 μm is even more preferable.

The skin cleansing composition of the present invention is suitable as, for example, a facial cleanser, a cleansing agent, etc., and a cleansing agent is more preferable. Further, it is preferably used for cleansing makeup cosmetics applied to the face.
The skin cleanser composition of the present invention is, for example, a method of shaking the composition as it is or by shaking and separating it, and then immersing it in cotton etc. It can be used by a wiping method, a method of rinsing after washing with a hand, a method of rinsing after soaking in cotton or the like, a method of rinsing after wiping with cotton or the like, a method of rinsing after wiping with the above method. Furthermore, it can also be used as the form impregnated into the sheet, and the form impregnated into the sheet is most preferable.

The skin cleansing composition of the present invention can be impregnated into a sheet to obtain a skin cleaning sheet. The sheet is preferably a non-woven fabric, and is composed of fibers having a cellulose content of 30% by mass or more and a density of 0.05 to 0 from the viewpoint of detergency, stability, smoothness, and a moist feeling after washing. It is preferable that it is ³ g / cm ³ .
Specific examples of the cellulose fiber include cotton, rayon and the like, and cotton is preferable from the viewpoint of smooth touch. The nonwoven fabric is preferably obtained by hydroentanglement from the viewpoint of skin feel.
In addition, hydrophobic fibers may be mixed to modify the sheet. Examples of the hydrophobic fibers include polyester fibers such as polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polypropylene (PP), and polyethylene (PE).

The nonwoven fabric preferably has a relatively high density in order to retain the impregnated skin cleansing composition and suppress movement in the sheet material. The density of the non-woven fabric is preferably 0.05 g / cm ³ or more because the liquid does not easily move to the lower sheet due to gravity. On the other hand, the impregnating liquid tends to penetrate into the sheet and softens the feel of use of the sheet. 0.3 g / cm ³ or less is preferable. The density of the nonwoven fabric is more preferably 0.075 to 0.25 g / cm ³ from the balance of liquid movement suppression and feeling of use.

In addition, the average basis weight (mass per unit area) of the nonwoven fabric is preferably 40 g / m ² or more from the viewpoint that it is easy to use without depending on wiping and the dirt does not reverse, and does not increase in bulk when laminated, and is supple. 100 g / m ² or less is preferable from the viewpoint of obtaining a good feel. The average basis weight of the nonwoven fabric is more preferably 50 to 80 g / m ² because it is easy to handle at the time of use and has an appropriate bulkiness at the time of lamination.

The non-woven fabric may be a sheet material in which two or more non-woven fabrics are overlapped or bonded. A three-layer structure is more preferable.
The shape of the non-woven fabric is preferably a shape, size and thickness that can be easily used by a human hand. Examples thereof include a square, a rectangle, a circle and an ellipse having a side or a diameter of about 5 to 20 cm. The thickness is preferably about 0.2 to 0.6 mm.

The impregnation ratio of the skin cleanser composition to the nonwoven fabric is preferably 50 to 1500%, more preferably 300 to 700% from the viewpoints of detergency, refreshing feeling, smoothness, stability and usability.

In order to impregnate the sheet with the skin cleanser composition, for example, it is produced by applying or spraying the skin cleanser composition from a nozzle onto a non-woven fabric, and then leaving it to fully impregnate the sheet material. can do.

The skin cleansing sheet can be used for use usually by sealing one by one or by stacking a plurality of sheets. When using, open the bag, take out the sheet-like cleansing material one by one, press it against the site where you want to remove the makeup cosmetic, regardless of whether it is oily makeup cosmetic or aqueous makeup cosmetic, make-up makeup Use as if wiping off the material. Thereby, it is possible to exert a high detergency even for makeup that is difficult to remove, such as waterproof mascara.

The skin cleanser sheet of the present invention can maintain the quality stably even when stored for a long time in the form of a laminated sheet, since the vertical movement of the impregnating liquid is suppressed and the composition does not change.

The nonwoven fabric used in the skin cleaning sheet of the present invention has a layer structure, and includes two second layers (surface layers) arranged on the surface side of the first layer (intermediate layer). In addition, the ratio of the density of the first layer and the density of the second layer of the nonwoven fabric (density of the first layer / density of the second layer) is 1.05 or more, and one side of the first layer and the second layer of the nonwoven fabric. An O / W type emulsion having a thickness ratio (the thickness of the first layer / the thickness of one side of the second layer) of 0.6 to 1.5 and a viscosity at 30 ° C. of 200 to 15000 mPa · s. It is included as an impregnation liquid.
Usually, in the case of a skin cleansing sheet using a high density non-woven fabric, the non-woven fabric is densely packed and hard to hold and the amount of impregnating liquid retained tends to be small. . However, it may not be preferred for those who want to wipe the skin gently because the contact with the skin becomes stronger due to the hardness of the nonwoven fabric and the lack of cleaning liquid.
Therefore, a skin cleaning sheet using a non-woven fabric having a low density is conceivable. Since the non-woven fabric having a low density has sparse fibers, the non-woven fabric itself is softly deformed and can be wiped off smoothly. However, since the fibers are sparse and easily deformed, when they are stored in a laminated state, the impregnation liquid tends to ooze out and it is often difficult to keep the quality over time stable. In addition, the impregnating liquid overflows (and flows out) when it is picked up by hand or when the sheet is applied to the skin, and the cleaning liquid may not be sufficiently provided between the skin and the sheet during the wiping operation.
Therefore, like the skin cleaning sheet of the present invention, by combining two non-woven fabrics (fiber webs) with different densities, the impregnating liquid does not bleed out and overflow, and the stability of the quality during lamination can be maintained. By using a non-woven fabric having a low density as a surface layer, a high detergency and a refreshing feeling can be obtained, and a sheet thickness feeling, softness and smoothness can be obtained. Here, the “feel of sheet thickness” means that the sheet is deformed at the time of wiping and the skin feel becomes soft.

The reason why the skin cleaning sheet of the present invention can stably maintain the quality at the time of lamination is considered to be that a low density nonwoven fabric is used as a surface layer and a high density nonwoven fabric is combined as an intermediate layer. After laminating the skin cleaning sheet and confirming the stability over time, when only the low density nonwoven fabric is impregnated with the impregnating liquid, the impregnating liquid oozes out from the upper layer side to the lower layer side and is retained on the sheet The amount of will decrease. However, in the case of the skin cleaning sheet of the present invention, the first layer of the high-density nonwoven fabric is combined between the second layer (surface layer) which is a low-density nonwoven fabric, and the high-density nonwoven fabric has dense fibers. The impregnating liquid which is likely to ooze from the low density nonwoven fabric is difficult to pass through, and furthermore, the structure in which the density gradient is reversed makes it difficult to move the impregnating liquid downward, and as a result, the quality can be kept stable.

The ratio of the density of the first layer and the density of the second layer of the nonwoven fabric (density of the first layer / density of the second layer) is 1.05 or more, preferably 1.1 or more, more preferably 1.15 or more. Preferably, it is 2.3 or less, preferably 2.0 or less, and more preferably 1.7 or less. The ratio of the density of the first layer and the density of the second layer of the nonwoven fabric (density of the first layer / density of the second layer) is 1.05 to 2.3, and 1.1 to 2.0 is Preferably, it is 1.15 to 1.7. The density is calculated from the basis weight and thickness (basis weight / thickness). Moreover, the density of the 1st layer and 2nd layer here shows the density of each independently before combining a 1st layer and a 2nd layer into a nonwoven fabric.
The porosity of each layer is determined by measuring the area S1 occupied by the fiber in an arbitrary area (rectangular portion) S0 of each layer by image analysis from an enlarged photograph of the cross section of the sheet using an electron microscope, and determining the density of the fiber itself. Calculate from ρ. (Porosity calculation formula of each layer: ρ × S1 / S0)
The porosity of the pulp is preferably from 0.01 to 0.2, more preferably from 0.02 to 0.1, and the porosity of the cotton is preferably from 0.001 to 0.04, preferably from 0.002 to 0.02. Is more preferable.

In nonwovens, the density of the first layer (intermediate layer) is preferably from 0.08 g / cm ³ or more, 0.1 g / cm ³ or more, and further preferably 0.12 g / cm ³ or more, 0.3 g / cm ³ or less is preferable, 0.2 g / cm ³ or less is more preferable, and 0.18 g / cm ³ or less is more preferable. The density of the first layer (intermediate layer) is preferably 0.08 ~ 0.3g / cm ^3, more preferably ^{0.1 ~ 0.2g / cm 3, 0.12} ~ 0.18g / cm 3 Is more preferable.
In nonwovens, the density of the second layer (surface layer) is preferably from 0.04 g / cm ³ or more, 0.06 g / cm ³ or more, and further preferably 0.08 g / cm ³ or more, 0.27 g / cm ³ or less is preferable, 0.18 g / cm ³ or less is more preferable, and 0.16 g / cm ³ or less is more preferable. The density of the second layer (surface layer) is preferably 0.04 ~ 0.27g / cm ^3, more preferably ^{0.06 ~ 0.18g / cm 3, 0.08} ~ 0.16g / cm 3 Is more preferable.

In the nonwoven fabric, the first layer is not affected when the skin is wiped off, has a waist when wiping off, and from the viewpoint of retention stability of the impregnating liquid, the hydrophilicity of cellulose such as pulp, cotton, rayon, cupra, lyocell, etc. It is preferable that it is comprised with the fiber chosen from a property fiber, and a pulp is more preferable at the point which is easy to obtain the density which does not raise | generate passage of an impregnating liquid easily.
In addition, the thickness of the first layer fiber is preferably 5 to 100 μm, more preferably 10 to 40 μm from the viewpoint that it does not change when the skin is wiped off.
The basis weight of the first layer of the non-woven fabric is not dependent on wiping the skin, and is preferably 10 to 80 g / m ² from the viewpoint of retention stability of the impregnating liquid, from the point of giving an appropriate waist during wiping. 15 to 30 g / m ² is more preferable.
The thickness of the first layer of the non-woven fabric is preferably 50 to 700 μm, more preferably 100 to 300 μm, from the viewpoints of good formation so that the liquid does not easily pass through and the retention stability of the impregnating liquid.
In the present invention, the thickness of the whole sheet is obtained by collecting two points of 200 mm × 200 mm non-woven fabric, measuring three points with a dial gauge with a pressure of 1.96 kPa (20 g / cm ² ), and indicating the average value (mm ). Moreover, the thickness of each layer for calculating the density is shown as an average value of the measurement results at three locations using an enlarged photograph.

On the other hand, the second layer has less friction when wiping the skin (by suppressing the softness of the nonwoven fabric and the impregnating liquid before it is wiped off), and in terms of smooth feel and cleaning power, cotton, rayon, It is preferably composed of fibers selected from lyocell, PET, and nylon. In addition, from the point of suppressing the overflow of the impregnating liquid, it is preferable to contain a lot of hydrophilic fibers, from the point of softness to the skin due to the structure of a nonwoven fabric that is easily deformed and easily returned by twisted fibers, A fiber containing at least cotton is preferable, and cotton is more preferable.
The thickness of the fibers of the second layer is preferably 1 to 80 μm, more preferably 10 to 30 μm, from the viewpoint of soft and smooth feel and cleaning power without friction when wiping the skin.
The basis weight of the second layer of the nonwoven fabric is preferably 10 to 80 g / m ² from the viewpoint of the texture and the impregnating property of the cleaning liquid, because the total weight of the two two layers is not easily affected when the skin is wiped off. m ² is more preferable.

The thickness of one side of the second layer of the nonwoven fabric is preferably 50 to 500 μm, more preferably 100 to 300 μm, from the viewpoints of softness, stability, and impregnating property of the cleaning liquid. The thickness of the second layer can be determined by subtracting the thickness of the first layer from the thickness of the entire sheet ((total thickness of the sheet) − (thickness of the first layer)). The thickness of one side of the second layer can be estimated as half of the calculated thickness of the second layer when the thicknesses of the two second layers are equal.
The two second layers may be the same or different.
The ratio of the thickness of one side of the first layer and the second layer of the nonwoven fabric (thickness of the first layer / thickness of the one side of the second layer) feels soft and is 0.2 to 5. 0 is preferred, 0.4 to 2.5 is more preferred, 0.5 to 2.0 is more preferred, and 0.6 to 1.5 is even more preferred.

The non-woven fabric has a second layer (surface layer) disposed on both surfaces of the first layer (intermediate layer), and preferably has a three-layer structure. Such a nonwoven fabric is manufactured by combining each layer by hydroentanglement and heat embossing.
In the nonwoven fabric, it is preferable that the fibers of the first layer and the second layer are entangled at the boundary between the first layer and the second layer from the viewpoint of difficulty.
The average fiber diameter of the fibers constituting the non-woven fabric is preferably 1 to 50 μm, more preferably 5 to 30 μm from the viewpoint of detergency because it has a soft and smooth feel with little friction when the skin is wiped off.

When a mixed layer of fibers of the first layer and the second layer is formed at the boundary between the first layer and the second layer that are formed more by the composite by the hydroentanglement method, the impregnation liquid oozes out and overflows. Is more difficult to get up. The mixed layer of the fibers has a thickness of the mixed layer on one side of 5 between the first layer and the second layer (one side) with respect to the thickness of the sheet of the first layer and the entire two second layers. It is preferably formed at a rate of ˜40%, and the soft and smooth feel to the skin when wiping the skin and the impregnating liquid are easily disposed between the skin and the sheet at the time of wiping, reducing friction and cleaning properties. From the viewpoint, the ratio is more preferably 10 to 35%.
In addition, the mixed layer has a fiber gradation structure in which the first layer has many fibers in the first layer and the second layer has many fibers on the second layer side. This is preferable because it is provided between the skin and the sheet and the cleaning property is enhanced.
In addition, the thickness of the 1st layer and 2nd layer mentioned above is the thickness of the single layer before manufacture. Further, the thickness of the mixed layer is included in the total thickness of the first layer and the second layer.

In addition, the ratio of the mixed layer of the fiber is measured from the enlarged photograph of the cross section of the sheet by measuring the thickness of the portion where the fibers of the first layer and the second layer are mixed as the mixed layer thickness. It is calculated from the half value of the sheet thickness (whole) in the layer thickness measurement part. (Mixed layer thickness / half value of sheet thickness x 100 (%))

The formation of the mixed layer is considered to be possible to form a wide spread layer by rebounding and dispersing the water flow in the first layer by entanglement of the water flow without penetrating the high-density first layer, but the composite of the sheet becomes weak Since a tendency is observed, it is preferable to apply a water flow to one surface under strong water flow conditions after the water flow entanglement of the first surface / second surface. Even if it is a water flow on strong conditions, since the density of the whole sheet | seat is in the state raised, it has the advantage that a water flow does not penetrate a 1st layer easily.
Further, it is also preferable to suppress the peeling of the sheet due to partial improvement in composite and uneven structure by the dispersed embossing treatment.
In the sheet of the present invention, it is preferable that a concavo-convex structure is provided on the surfaces on both sides of the sheet.

In the combination of sheets, if a minute surface uneven structure by hydroentanglement or a relatively large uneven structure by embossing is given, contact between the inner surfaces of the sheet is reduced by the size and shape of the uneven structure, and between the inner surfaces The movement of the liquid can be further reduced. The uneven shape of the sheet is preferably a shape in which a linearly asymmetric shape such as an ellipse, a rectangle, or a streak that hardly overlaps between the inner surfaces is formed.
In addition, when the cross section of the sheet is a partial convex portion, the amount of the impregnating liquid is partially increased, and the inner surface sheets are in contact with each other at the increased portion, so the liquid movement from other parts of the sheet is minute. As a result, the other portions are relatively lower than the convex portions. When the sheet is folded, on the folded inner surface side, even if a small amount of liquid oozes out at the upper inner surface and lower inner surface, the liquid volume is maintained at the upper inner surface and lower inner surface near the folding portion. As a result of the difference in the amount, the liquid is sucked up by the capillary effect by the high-density portion of the second layer on the inner surface of the folding portion, and the effect of alleviating the relative liquid amount difference is further enhanced.

The total basis weight of the nonwoven fabric, skin can often impregnated with a wiping accordance difficulty and impregnation liquid when the a, in terms of stability, preferably 20 ~ 150g / ^{m 2,} more preferably 35 ~ 80g / ^{m 2.}
In the nonwoven fabric, the ratio of the basis weight on one side of the first layer and the second layer (basis weight of the first layer / basis weight on the one side of the second layer) is the ratio of the wiping liquid when the skin is wiped off. From the viewpoint of easy oozing and detergency, 0.2 to 5.0 is preferable, and 0.4 to 2.0 is more preferable.
The nonwoven fabric preferably has a thickness of 0.1 to 1.5 mm, more preferably 0.3 to 0.7 mm, from the viewpoints of softness, stability, and impregnation with a cleaning solution.

The saturated water ratio of the nonwoven fabric is preferably 500 to 1500%, more preferably 750 to 1000%, from the viewpoints of stability, detergency, and impregnating property of the cleaning liquid. The saturated water ratio is determined by a method based on the JIS L 1913 general nonwoven fabric test method (6.9.2 water retention ratio). That is, after immersing a non-woven fabric having a size of 10 cm × 10 cm in a container containing ion-exchanged water for 5 minutes, the non-woven fabric is taken out from the container and held at both ends with tweezers for 30 seconds, and then impregnated with ion-exchanged water. The weight of the nonwoven fabric is measured and the saturated water ratio is calculated.
Furthermore, the ratio (basis weight / viscosity of the second layer) of the basis weight (g / m ² ) of the second layer of the nonwoven fabric and the viscosity (mPa · s) at 30 ° C. of the O / W type emulsion described later is From the viewpoint of stability, detergency, and impregnating property of the cleaning liquid, 0.007 to 0.7 is preferable, and 0.01 to 0.15 is more preferable.

As the nonwoven fabric used in the present invention, pulp is used as the first layer from the viewpoint of smooth and natural skin feel when wiping the skin, cleaning power, softness, stability, and impregnating properties of the cleaning liquid, and the second layer. It is preferable to use cotton. In this case, the weight ratio of cotton in all fibers, that is, cotton / (cotton + pulp) has a low strength when wet when wiping the skin, and can be wiped softly and has excellent extensibility. From the viewpoint of stability, it is preferably 0.3 to 0.95, more preferably 0.5 to 0.6.

In the present invention, the O / W type emulsion impregnated in the nonwoven fabric as described above has a viscosity at 30 ° C. of 200 to 15000 mPa · s, and preferably 500 to 3000 mPa · s. If it is this viscosity, when it laminates | stores and preserve | saves, an impregnation liquid will be hard to transfer to the lower part side from the upper side, and it is excellent also in the smoothness at the time of wiping off.
Here, the viscosity is measured with a BM viscometer (manufactured by Tokimec, measurement conditions: rotor No. 2, 6 rpm, 1 minute).

The O / W emulsion may contain (H) ether oil that is liquid at 25 ° C. The liquid state is a state having fluidity at 25 ° C., and the viscosity at 25 ° C. is 10000 mPa · s or less, preferably 50 mPa · s or less, more preferably 15 mPa · s or less.
The liquid ether oil of component (H) is preferably a dialkyl ether having 2 alkyl groups having 16 or less carbon atoms, and more preferably a dialkyl ether having 2 alkyl groups having 8 or less carbon atoms. In the dialkyl ether, the two alkyl groups may be the same or different.
More specifically, for example, dioctyl ether, cetyl-1,3-dimethylbutyl ether, dihexyl ether, dilauryl ether and the like can be mentioned. Of these, cetyl-1,3-dimethylbutyl ether and dioctyl ether are preferred, and dioctyl ether is more preferred from the viewpoint of high detergency against oily mascara and no oily feeling.

Component (H) can be used singly or in combination of two or more. From the viewpoint of detergency, refreshing feeling, and moist feeling, the content is preferably 0.1% by mass or more in the total composition, 0 More preferably, 5 mass% or more is more preferable, 1 mass% or more is more preferable, 25 mass% or less is preferable, 10 mass% or less is more preferable, and 6 mass% or less is further more preferable. The content of component (H) is preferably from 0.1 to 25% by mass, more preferably from 0.5 to 10% by mass, and even more preferably from 1 to 6% by mass in the total composition.

The O / W emulsion may further contain (I) a hydrocarbon oil having a viscosity at 30 ° C. of 30 mPa · s or less, preferably 1 to 10 mPa · s. Here, the viscosity is measured by a BM viscometer (manufactured by Tokimec, measurement conditions: rotor No. 1, 60 rpm, 1 minute).
Examples of the hydrocarbon oil include isododecane, isohexadecane, hydrogenated polyisobutene, and the like, and isododecane is preferable from the viewpoint of excellent detergency and feel without oiliness.

Component (I) can be used singly or in combination of two or more. From the standpoint of detergency, refreshing feeling, and stability, the content is preferably 1% by mass or more in the total composition, and 5% by mass. % Or more is more preferable, 10 mass% or more is more preferable, 50 mass% or less is preferable, 35 mass% or less is more preferable, and 20 mass% or less is further more preferable. The content of the component (I) hydrocarbon oil is preferably 1 to 50% by mass, more preferably 5 to 35% by mass, and still more preferably 10 to 20% by mass in the total composition.

Further, the O / W emulsion can contain (J) a water-soluble polymer, and can obtain higher detergency.
As the water-soluble polymer, from the viewpoint of detergency and stability, a nonionic water-soluble polymer containing cellulose as a structural unit, a water-soluble polymer containing acrylic acid or methacrylic acid as a structural unit (a structure derived from acrylic acid or methacrylic acid) Water-soluble polymers containing units) are preferred.
Examples of the nonionic water-soluble polymer containing cellulose as a structural unit include alkyl celluloses such as methyl cellulose and ethyl cellulose; hydroxyalkyl celluloses such as hydroxyethyl cellulose, hydroxypropyl cellulose, and hydroxypropyl methylcellulose.
Of these, hydroxyalkylcellulose is preferred and hydroxyethylcellulose is more preferred because of its high detergency and no oily feeling.

Further, the water-soluble polymer containing acrylic acid or methacrylic acid as a structural unit is synthesized using acrylic acid or methacrylic acid as a monomer, and examples thereof include carboxyvinyl polymer and acrylic acid / alkyl methacrylate copolymer. Of these, from the viewpoint of stability after storage, an acrylic acid / alkyl methacrylate copolymer is preferable, and a copolymer of acrylic acid and an alkyl methacrylate having 10 to 30 carbon atoms ((acrylic acid / alkyl acrylate)). (C10-30)) copolymers) are more preferred. Examples of commercially available products include PEMULEN® TR-1, PEMULEN® TR-2, Carbopol ETD2020 (manufactured by Lubrizol® Advanced® Materials).

The water-soluble polymer containing acrylic acid or methacrylic acid as a constituent unit is preferably used by neutralizing all or part of the acrylic acid or methacrylic acid unit with an alkali agent. The alkali agent to be neutralized is not particularly limited as long as it is an alkali agent that can be usually added to cosmetics. For example, potassium hydroxide, sodium hydroxide, and the like can be used. The alkaline agent can be used alone or in combination of two or more, and is preferably contained in the O / W emulsion in an amount of 0.001% by mass to 0.4% by mass, and the pH of the composition is 5 To 9, and more preferably to pH 5.5-8.

The water-soluble polymer of component (J) is preferably one having a molecular weight of 50,000 to 5,000,000, and more preferably 100,000 to 4,000,000 from the viewpoints of detergency, stability and refreshing feeling.
The water-soluble polymer can be used alone or in combination of two or more. From the viewpoint of detergency, stability, impregnation, and refreshing feeling, the content is 0.01% by mass or more in the total composition. Preferably, 0.025 mass% or more is more preferable, 0.05 mass% or more is more preferable, 1 mass% or less is preferable, 0.7 mass% or less is more preferable, and 0.3 mass% or less is more preferable. The content of the water-soluble polymer is preferably 0.01 to 1% by mass, more preferably 0.025 to 0.7% by mass, and more preferably 0.05 to 0.3% by mass in the total composition.

In the O / W type emulsion, the mass ratio (J) / (H) of the component (H) and the component (J) is 0.001 or more from the viewpoint that the smooth feel remains on the skin and the smooth feel continues. Is preferable, 0.004 or more is more preferable, 0.01 or more is further preferable, 5 or less is preferable, 2.5 or less is more preferable, and 1 or less is more preferable. The mass ratio (J) / (H) of the component (H) to the component (J) is preferably 0.001 to 5, more preferably 0.004 to 2.5, and still more preferably 0.01 to 1. .

Further, the O / W emulsion can contain (K) a water-soluble solvent and can provide a moist feeling.
Specific examples of the component (K) include polyhydric alcohol, polyglycerin, polyethylene glycol, polypropylene glycol, glyceryl ether in which an alkylene group is added to glycerin, sugar and the like.

Examples of glyceryl ethers in which an alkylene group is added to glycerin include polyoxypropylene diglyceryl ether, polyoxypropylene glyceryl ether, polyoxybutylene polyoxyethylene polyoxypropylene glyceryl ether, and the like. Among these, polyoxypropylene (9) diglyceryl ether, polyoxypropylene (14) diglyceryl ether, polyoxybutylene polyoxyethylene polyoxypropylene glyceryl ether (3B.O.) (8E.O.) (5P. O.) is preferable from the viewpoint of less stickiness.

The water-soluble solvent of component (K) can be used singly or in combination of two or more, can provide a moist feeling, and has little stickiness, so that the content is 1% by mass or more in the total composition. Preferably, 3 mass% or more is more preferable, 5 mass% or more is more preferable, 35 mass% or less is preferable, 20 mass% or less is more preferable, and 15 mass% or less is further preferable. The content of the water-soluble solvent of IOB 0.5 to 6 is preferably 1 to 35% by mass, more preferably 3 to 20% by mass, and further preferably 5 to 15% by mass in the total composition.

The O / W emulsion can further contain (L) a nonionic surfactant of HLB8 or higher.
HLB is an index indicating a balance between hydrophilicity and lipophilicity, and in the present invention, a value calculated using the following equation by Oda and Teramura et al. Is used.

The nonionic surfactant having a component (L) of HLB 8 or higher is preferably HLB 8 to 15, for example, polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene polyoxypropylene. Glycol, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl ether fatty acid Examples include esters, sucrose fatty acid esters, alkyl polyglucosides, (poly) alkyl glyceryl ethers, and the like.
Among these, in terms of detergency, polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene hydrogenated castor oil fatty acid ester, alkylpolyglucoside, (poly) Alkyl glyceryl ether is preferable, and from the viewpoint of stability, a polyethylene glycol fatty acid ester is preferable, and polyethylene phosphate polyethylene glycol (12) is more preferable.

Component (L) HLB8 or higher nonionic surfactant can be used alone or in combination of two or more, and from the viewpoint of detergency and low stickiness, the content is 0.001% by mass or more is preferable, 0.01% by mass or more is more preferable, 0.03% by mass or more is more preferable, 5% by mass or less is preferable, 1% by mass or less is more preferable, and 0.5% by mass or less. Is more preferable. In addition, the content of the nonionic surfactant of HLB8 or higher as component (L) is preferably 0.001 to 5% by mass, more preferably 0.01 to 1% by mass, and more preferably 0.03 to 0.5 mass% is further more preferable.

O / W type emulsion can contain (M) water and makes the remainder of each component. The content of water is preferably 30% by mass or more, more preferably 40% by mass or more, further preferably 50% by mass or more, preferably 95% by mass or less, more preferably 90% by mass or less, and 80% by mass in the total composition. % Or less is more preferable.

Furthermore, in addition to the above, the O / W emulsion is a component used in a normal cleaning composition, for example, an oil agent other than the components (H) and (I), a polymer other than the component (J), an anion. Surfactant, cationic surfactant, amphoteric surfactant, bactericidal agent, anti-inflammatory agent, preservative, chelating agent, salt, pearlizing agent, fragrance, cooling agent, pigment, UV absorber, antioxidant, plant Extracts and the like can be contained.

Examples of the oil other than the components (H) and (I) include hydrocarbon oils such as liquid paraffin having a viscosity at 30 ° C. exceeding 30 mPa · s. Oil agents other than the components (H) and (I) can be used alone or in combination of two or more, and the content is preferably 0.01% by mass or more and 50% by mass or less in the total composition. Preferably, 40 mass% or less is more preferable, 30 mass% or less is more preferable, and 20 mass% or less is still more preferable.
Examples of the polymer other than the component (J) include sodium hyaluronate.

The O / W type emulsion can be produced by mixing the blending components and by an ordinary method. In the case of containing a raw material that is solid at room temperature, it can be produced by uniformly mixing all the components after heating and melting or dissolving in other components.
The skin cleaning sheet of the present invention is obtained by impregnating the above-described nonwoven fabric with an O / W emulsion. Examples of the method of impregnating the nonwoven fabric with the O / W type emulsion include a method in which the nonwoven fabric is applied by dropping or flowing down from a nozzle, or impregnation by spraying.
The impregnation ratio of the O / W emulsion to the nonwoven fabric is preferably 50 to 1500%, more preferably 300 to 700% from the viewpoints of detergency, wiping comfort, refreshing feeling and usability. The impregnation rate is calculated from the following formula.

Impregnation rate (%)
= ((Weight of nonwoven fabric impregnated with impregnation liquid) / (Weight of dried nonwoven fabric) -1) × 100

The thickness of the sheet after impregnating the O / W emulsion is preferably 100 to 2000 μm, more preferably 250 to 800 μm.
The skin cleaning sheet of the present invention is suitable, for example, as a facial cleanser, a cleansing agent, etc., and a cleansing agent is more preferable. Further, it is preferably used for cleansing makeup cosmetics applied to the face.

Further, the amount of the liquid per unit volume of the second layer feels that the amount of liquid contained in the sheet is large at the time of wiping, so that the skin can be gently wiped, and from the point of improving stability, 1 × 10 ⁶ to 3 × 10 ⁶ g / m ³ is preferable, 1.02 × 10 ⁶ to 2.8 × 10 ⁶ g / m ³ is more preferable, and 1.04 × 10 ⁶ to 2.6 × 10 ⁶ g / m ³ is preferable. ³ is even more preferable.
The amount of liquid per unit volume of the second layer is calculated from the following equation.

The skin cleansing sheet of the present invention can keep the quality at the time of lamination after impregnating the O / W emulsion, but keeps the quality stable even when the sheet is folded and stored. Can do.
In the skin cleansing sheet of the present invention, as described above, the first layer having a high density is arranged in the middle of the thickness direction of the sheet, and the second layer having a low density is arranged on both sides thereof, and the sheets face each other. (FIG. 1).
Since the sheet is folded, the liquid impregnation liquid oozes out (moves) on the inner surface side and the outer surface side that are folded, and thus the behavior is different. On the outer surface of the sheet, as described above, the liquid seepage (movement) is suppressed by the effect of the first layer, and the quality is kept stable. On the other hand, when the folded sheets come into contact with each other on the inner surface and the second layer is deformed by its own weight (smashing in the thickness direction), the impregnating liquid oozes out (moves) easily. Since the non-woven fabric has an appropriate waist due to the high-density first layer, deformation due to the contact of the second layer on the inner surface is suppressed by the deformation being bent from the sheet folded portion.

Therefore, since the first layer suppresses the seepage of the liquid from the outer surface side to the inner surface side and between the inner surface sides, the movement of the impregnating liquid is mainly performed in the plane direction of the sheet. A folding part is formed, and the movement of the liquid in the planar direction is suppressed at the folding part. Specifically, the second layer, which has a lower density than the first layer, is easily deformed in the thickness direction, and the density inside the folded portion when folded is increased, and the surfaces of the second layer facing each other The density is larger than that of the first layer and smaller than the density of the first layer, but close to the first layer. Therefore, on the inner surface side, the movement of the liquid can be suppressed similarly to the effect by the first layer. Density inside the folded portion of the second layer is preferably 0.05 ~ 0.28g / cm ^3, more preferably 0.07 ~ 0.19g / cm ^3, is 0.09 ~ 0.17g / cm ³ Further preferred.

On the other hand, on the outer surface, the folded portion is not deformed at an acute angle due to the influence of the dense first layer, but is deformed in a shape bent outward, so that the second layer is more deformed than the acute deformation. The second layer is pulled to partially reduce the fibers, making the sparse structure more sparse and reducing the thickness. Thereby, planar movement of the impregnating liquid on the outer surface is suppressed. The density outside the folded portion of the second layer is preferably 0.005 to 0.26 g / cm ³ , more preferably 0.01 to 0.17 g / cm ³ , and 0.02 to 0.15 g / cm ^3. Further preferred.

As described above, the density of the second layer is increased on the inner surface of the folding portion, and the movement of the second layer in the planar direction is caused by the seepage from the second layer to the first layer in terms of the laminated structure of the fibers. If the relative amount of the impregnating liquid retained between the upper part of the folding inner surface and the lower part of the folding inner surface is likely to occur, the liquid tends to move from the lower part of the inner surface to the upper part of the inner surface due to the capillary effect of the structure. Therefore, the ratio between the density inside the folded portion when folded and the density of the facing surface of the second layer (the density inside the folded portion / the density of the facing surface) is greater than 1, 1.01 The above is preferable, 1.03 or more is more preferable, 1.05 or more is further preferable, 3.5 or less is preferable, 2.0 or less is more preferable, 1.8 or less is further preferable, and 1.5 or less is further more preferable. preferable.
This invention discloses the following compositions further regarding embodiment mentioned above.

<1> The following components (A), (B), (C), (D) and (E):
(A) 0.1 to 25% by mass of ether oil which is liquid at 25 ° C.
(B) a water-soluble polymer containing acrylic acid or methacrylic acid as a structural unit 0.003 to 1% by mass,
(C) 1-30% by mass of a hydrocarbon oil having a viscosity at 30 ° C. of 15 mPa · s or less,
(D) 60-95% by weight of water,
(E) A nonionic surfactant having an HLB greater than 9 is contained in an amount of 0.49% by mass or less, and the mass ratio (B) / (A) of the component (A) to the component (B) is 0.0001-0. 1. A skin cleanser composition having a mass ratio (A) / ((A) + (C)) of components (A) and (C) of 0.05 to 0.9.

<2> The above <1> description, wherein the component (A) is preferably a dialkyl ether having two alkyl groups having 16 or less carbon atoms, and more preferably a dialkyl ether having two alkyl groups having 8 or less carbon atoms. Skin cleansing composition.
<3> Component (A) is preferably octyl ether, cetyl-1,3-dimethylbutyl ether, dicaprylyl ether, dihexyl ether, dilauryl ether, and cetyl-1,3-dimethylbutyl ether, dioctyl ether The skin cleansing composition according to <1> or <2>, more preferably dioctyl ether.
The content of <4> component (A) is preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably 10% by mass or less, and preferably 6% by mass or less in the total composition. More preferably, the content of the component (A) is preferably 0.5 to 10% by mass in the total composition, and more preferably 1 to 6% by mass. 2. A skin cleanser composition according to claim 1.

<5> The component (B) is preferably a carboxyvinyl polymer or an acrylic acid / alkyl methacrylate copolymer, more preferably an acrylic acid / alkyl methacrylate copolymer, any one of the above items <1> to <4> Skin cleansing composition.
The content of <6> component (B) is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, and preferably 0.5% by mass or less in the total composition. More preferably, the content of the component (B) is preferably 0.01 to 0.5% by mass and 0.05 to 0.1% by mass in the total composition. The skin cleansing composition according to any one of <1> to <5>, more preferably.
<7> The mass ratio (B) / (A) of the component (A) and the component (B) is preferably 0.0001 or more, more preferably 0.001 or more, and further preferably 0.01 or more. 0.1 or less is preferable, 0.085 or less is more preferable, 0.07 or less is more preferable, and the mass ratio (B) / (A) of the component (A) and the component (B) is preferably The skin cleanser composition according to any one of <1> to <6>, which is 0.0001 to 0.1, more preferably 0.001 to 0.085, and still more preferably 0.01 to 0.07. object.

<8> The hydrocarbon oil of component (C) is preferably any one of the above items <1> to <7>, preferably having a viscosity at 30 ° C. of 15 mPa · s or less and more preferably 1 to 10 mPa · s. Skin cleansing composition.
The content of <9> component (C) is preferably 5% by mass or more, more preferably 8% by mass or more, preferably 25% by mass or less, more preferably 15% by mass or less in the total composition. In addition, the content of the component (C) is preferably 5 to 25% by mass in the total composition, and more preferably 8 to 15% by mass, according to any one of the above <1> to <8> Skin cleansing composition.
<10> The mass ratio (A) / ((A) + (C)) of the component (A) and the component (C) is preferably 0.08 or more, more preferably 0.1 or more, and 0 0.8 or less, more preferably 0.4 or less, and the mass ratio (A) / ((A) + (C)) of the component (A) to the component (C) is preferably 0.08 to The skin cleanser composition according to any one of <1> to <9>, wherein 0.8 and more preferably 0.1 to 0.4.

The content of <11> component (D) is preferably 65% by mass or more, more preferably 70% by mass or more, preferably 90% by mass or less, and more preferably 85% by mass or less in the total composition. In addition, the content of the component (D) is preferably 65 to 90% by mass in the total composition, and more preferably 70 to 85% by mass, according to any one of the above <1> to <10> Skin cleansing composition.
<12> The mass ratio (A) / (D) of the component (A) and the component (D) is preferably 0.001 or more, more preferably 0.01 or more, and further preferably 0.02 or more. 0.45 or less, more preferably 0.25 or less, still more preferably 0.15 or less, and the mass ratio (A) / (D) of the component (A) to the component (D) is preferably The skin cleanser composition according to any one of <1> to <11>, wherein the composition is 0.001 to 0.45, more preferably 0.01 to 0.25, and further preferably 0.02 to 0.15. object.

<13> The content of the nonionic surfactant is preferably 0.0001% by mass or more, more preferably 0.005% by mass or more, and further preferably 0.01% by mass or more in the total composition. 0.049% by mass or less, and the content of the nonionic surfactant is preferably 0.0001 to 0.49% by mass in the total composition, and 0.005 to 0.49. The skin cleanser composition according to any one of <1> to <12>, wherein the composition is more preferably by mass%, and further preferably from 0.01 to 0.049 mass%.
<14> Component (E) is preferably polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, propylene glycol fatty acid ester, polyoxyethylene polyoxypropylene glycol, sorbitan fatty acid ester, polyoxyethylene sorbitan Fatty acid ester, polyoxyethylene sorbite fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester, polyoxypropylene polyglyceryl ether, polyalkyl glyceryl ether, polyoxyethylene alkyl ether, poly Oxyethylene alkyl ether fatty acid ester, sucrose fatty acid ester, alkyl polyglucoside, (poly <1>-<Alkyl glyceryl ether, more preferably polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, alkyl polyglucoside, and (poly) alkyl glyceryl ether. The skin cleansing composition according to any one of 13>.

The content of <15> component (E) is preferably 0.0001% by mass or more, more preferably 0.005% by mass or more, further preferably 0.01% by mass or more, in the total composition. 3 mass% or less is preferable, 0.49 mass% or less is more preferable, 0.049 mass% or less is further preferable, and the content of the nonionic surfactant is preferably 0.0001 in the total composition. The skin cleanser according to any one of the above <1> to <14>, which is preferably 3 to 3% by mass, more preferably 0.005 to 0.49% by mass, and still more preferably 0.01 to 0.049% by mass. Composition.
<16> The mass ratio (A) / (E) of the component (A) and the component (E) is preferably 0.1 or more, more preferably 1 or more, further preferably 40 or more, and 200000 or less. It is preferably 600 or less, more preferably 200 or less, and the mass ratio (A) / (E) of the component (A) to the component (E) is preferably 0.1 to 200000, The skin cleansing composition according to any one of the above <1> to <15>, more preferably -600, and still more preferably 40-200.
<17> The skin cleanser composition according to any one of <1> to <16>, further comprising (F) a water-soluble solvent.

<18> Component (F) is preferably 1,3-butylene glycol, propylene glycol, isoprene glycol, glycerin, diglycerin, polyethylene glycol 200, polyethylene glycol 400, polyethylene glycol 1000, polyethylene glycol 1540, diproprene glycol, Polypropylene glycol (3), polypropylene glycol (7), polyoxypropylene (9) diglyceryl ether polyoxypropylene (14) diglyceryl ether, polyoxybutylene polyoxyethylene polyoxypropylene glyceryl ether (3B.O.) (8E) O.) (5P.O.), polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside, <17> said skin cleanser group Thing.
The content of <19> component (F) is preferably 1% by mass or more, more preferably 3% by mass or more, further preferably 5% by mass or more, and preferably 35% by mass or less in the total composition. 25% by mass or less, more preferably 15% by mass or less, and the content of the component (F) is preferably 1 to 35% by mass in the total composition, and 3 to 25% by mass. The skin cleanser composition according to <17> or <18>, more preferably 5 to 15% by mass.

<20> The skin cleanser composition according to any one of <1> to <19>, which is preferably impregnated into a sheet.
<21> A skin cleansing sheet that is preferably used in a form in which the skin cleansing composition according to any one of <1> to <20> is impregnated in the sheet.
The <22> sheet is preferably a nonwoven fabric, more preferably composed of fibers having a cellulose content of 30% by mass or more, and a density of 0.05 to 0.3 g / cm ³ is preferable. The skin cleaning sheet according to <21>, wherein 075 to 0.25 g / cm ³ is more preferable.
<23> The average basis weight (mass per unit area) of the nonwoven fabric of the sheet is preferably 40 g / m ² or more, preferably 100 g / m ² or less, and more preferably 50 to 80 g / m ² <22> skin cleaning sheet.
<24> The non-woven fabric of the sheet is preferably a sheet material in which two or more kinds of non-woven fabrics are overlapped or bonded, and more preferably a three-layer structure, the skin cleaning sheet according to <22> or <23> .
<25> The skin cleansing sheet according to any one of the above <22> to <24>, wherein the impregnation ratio of the skin cleansing composition to the nonwoven fabric is preferably 50 to 1500%, more preferably 300 to 700% .

<26> The content of the oil agent other than components (A) and (C) is preferably 0.01% by mass or more, preferably 20% by mass or less, and more preferably 10% by mass or less in the total composition. The skin cleanser composition according to any one of <1> to <25>, further preferably 5% by mass or less, and further preferably 1% by mass or less.
<27> The skin cleanser composition according to any one of <1> to <26>, wherein a cationic surfactant and an amphoteric surfactant are preferably not contained.

<28> It is preferably used for a facial cleanser and a cleansing agent, more preferably a cleansing agent, and preferably used for cleansing a makeup cosmetic applied to the face. > The skin cleanser composition of any one of>.
<29> The composition was left as it was or after being shaken and homogenized, then the sheet was impregnated and wiped off. The method of wiping it with the hand and then wiping it with the sheet. Any one of the above <1> to <27>, which is preferably used by a method of washing after washing, a method of washing off after impregnating the sheet, a method of washing off after wiping by the above method, etc. The skin cleansing composition as described.
<30> The skin cleanser composition according to any one of <1> to <27>, wherein the sheet is preferably in the form of impregnation.

<31> The skin cleanser composition according to <30>, wherein the sheet preferably contains cotton.
<32> Use of the skin cleanser composition according to any one of the above <1> to <27> for producing a cleansing agent for cleansing a makeup cosmetic applied to a face.
<33> The skin cleanser composition according to any one of the above <1> to <27> for producing a cleansing agent for cleansing a makeup cosmetic applied to the face and immersing it in a sheet. use.
<34> Skin cleansing according to any one of the above <1> to <27> for producing a cleansing agent for use as a form impregnated in a sheet for cleansing a makeup cosmetic applied to the face Use of the agent composition.

<35> The following components (A), (B), (C), (D) and (E):
(A) 0.1 to 25% by mass of ether oil which is liquid at 25 ° C.
(B) a water-soluble polymer containing acrylic acid or methacrylic acid as a structural unit 0.003 to 1% by mass,
(C) 1-30% by mass of a hydrocarbon oil having a viscosity at 30 ° C. of 15 mPa · s or less,
(D) 60-95% by mass of water
(E) Nonionic surfactant having an HLB greater than 9 is contained in an amount of 0.49% by mass or less, and the mass ratio (A) / ((A) + (C)) of components (A) and (C) is 0. .05-0.9,
A skin cleanser composition having a mass ratio (A) / (E) of component (A) to component (E) of 40 to 200.

<36> Non-woven fabric having a layer structure comprising a first layer and two second layers disposed on the surface side of the first layer, and an O / W emulsion having a viscosity at 30 ° C. of 200 to 15000 mPa · s The ratio of the density of the first layer and the density of the second layer of the nonwoven fabric (density of the first layer / density of the second layer) is 1.05 or more, and the first layer and the second layer of the nonwoven fabric A skin cleansing sheet in which the ratio of the thickness of one side of the layer (thickness of the first layer / thickness of the one side of the second layer) is 0.6 to 1.5.
<37> The ratio of the density of the first layer and the density of the second layer of the nonwoven fabric (the density of the first layer / the density of the second layer) is preferably 1.1 or more, more preferably 1.15 or more. 2.3 or less is preferable, 2.0 or less is more preferable, and 1.7 or less is still more preferable, The skin cleaning sheet as described in said <36>.
The porosity of <38> pulp is preferably 0.01 to 0.2, more preferably 0.02 to 0.1, and the porosity of cotton is preferably 0.001 to 0.04. The skin cleaning sheet according to <36> or <37>, wherein 0.002 to 0.02 is more preferable.

<39> In the nonwoven fabric, the density of the first layer (intermediate layer) is preferably an at 0.08 g / cm ³ or more, 0.1 g / cm ³ or more, more preferably, 0.12 g / cm ³ or more and more The skin cleansing sheet according to any one of <36> to <38>, preferably 0.3 g / cm ³ or less, more preferably 0.2 g / cm ³ or less, and still more preferably 0.18 g / cm ³ or less. .
<40> In the nonwoven fabric, the density of the second layer (surface layer) is preferably an at 0.04 g / cm ³ or more, 0.06 g / cm ³ or more, more preferably, 0.08 g / cm ³ or more and more preferably, preferably 0.27 g / cm ³ or less, more preferably 0.18 g / cm ^3, skin cleansing as claimed in any one of 0.16 g / cm ³ or less is more preferable that the <36> - <39> sheet .
<41> The skin cleaning sheet according to any one of the above <36> to <40>, wherein the first layer is preferably selected from cellulose hydrophilic fibers such as pulp, cotton, rayon, cupra, lyocell, etc. .
<42> The skin cleansing sheet according to any one of the above <36> to <41>, wherein the thickness of the first layer fiber is preferably 5 to 100 μm, and more preferably 10 to 40 μm.

<43> The skin wash according to any one of <36> to <42>, wherein the basis weight of the first layer of the nonwoven fabric is preferably 10 to 80 g / m ² , and more preferably 15 to 30 g / m ^2. Sheet.
<44> The skin cleaning sheet according to any one of the above <36> to <43>, wherein the thickness of the first layer of the nonwoven fabric is preferably 50 to 700 μm, and more preferably 100 to 300 μm.
<45> The skin cleansing sheet according to any one of <36> to <44>, wherein the second layer is preferably selected from cotton, rayon, lyocell, PET, and nylon.
<46> The skin cleaning sheet according to any one of the above <36> to <45>, wherein in the non-woven fabric, the thickness of the fiber of the second layer is preferably 1 to 80 μm, and more preferably 10 to 30 μm.
<47> The basis weight of the second layer of the nonwoven fabric, the total of the two two layers is preferably 10 to 80 g / m2, and more preferably 10 to 40 g / m2 Any of the above <36> to <46> 2. The skin cleaning sheet according to claim 1.

<48> The skin cleaning sheet according to any one of the above <36> to <47>, wherein the thickness of one side of the second layer of the nonwoven fabric is preferably 50 to 500 μm and more preferably 100 to 300 μm.
<49> The ratio of the thickness of one side of the first layer and the second layer of the nonwoven fabric (the thickness of the first layer / the thickness of one side of the second layer) is preferably 0.2 to 5.0, The skin cleansing sheet according to any one of <36> to <47>, wherein 0.4 to 2.5 is more preferable, 0.5 to 2.0 is more preferable, and 0.6 to 1.5 is still more preferable. .
<50> The skin cleaning sheet according to any one of the above <36> to <49>, wherein an average fiber diameter of fibers constituting the nonwoven fabric is preferably 1 to 50 μm, and more preferably 5 to 30 μm.
In the <51> non-woven fabric, preferably, a mixed layer of fibers of the first layer and the second layer is formed at the boundary between the first layer and the second layer formed more by the composite by the hydroentanglement method, The mixed layer of the fibers has a thickness of the mixed layer on one side of 5 between the first layer and the second layer (one side) with respect to the thickness of the sheet of the first layer and the entire two second layers. The skin cleaning sheet according to any one of the above <36> to <50>, which is more preferably formed at a ratio of ˜40%, and more preferably at a ratio of 10 to 35%.

<52> Preferably, the skin cleaning sheet according to any one of the above items <36> to <51>, wherein a concavo-convex structure is provided on both surfaces of the sheet.
<53> The skin cleansing sheet according to any one of <36> to <52>, wherein the total basis weight of the nonwoven fabric is preferably 20 to 150 g / m ² and more preferably 35 to 80 g / m ² .
In the <54> nonwoven fabric, the ratio of the basis weight on one side of the first layer and the second layer (basis weight of the first layer / basis weight on one side of the second layer) is preferably 0.2 to 5 The skin cleansing sheet according to any one of <36> to <53>, which is 0.0 and more preferably 0.4 to 2.0.
<55> The skin cleaning sheet according to any one of <36> to <54>, wherein the nonwoven fabric preferably has a thickness of 0.1 to 1.5 mm, and more preferably 0.3 to 0.7 mm.
<56> The skin cleansing sheet according to any one of the above <36> to <55>, wherein the non-woven fabric has a saturated water ratio of preferably 500 to 1500%, more preferably 750 to 1000%.
<57> The skin cleaning sheet according to any one of the above <36> to <56>, wherein it is preferable to use pulp as the first layer and cotton as the second layer.

<58> The weight ratio of cotton in the total fiber, cotton / (cotton + pulp) is preferably 0.3 to 0.95, more preferably 0.5 to 0.6. <36> to <57>. The skin cleaning sheet according to any one of 57>.
<59> The skin cleaning sheet according to any one of <36> to <58>, wherein the O / W emulsion to be impregnated into the nonwoven fabric preferably has a viscosity at 30 ° C. of 500 to 3000 mPa · s.

The <60> O / W emulsion may contain (H) an ether oil that is liquid at 25 ° C., and the ether oil that is liquid at component (H) 25 ° C. is preferably 50 mPa · s or less. The skin cleaning sheet according to any one of the above <36> to <59>, wherein 15 mPa · s or less is more preferable.
<61> The component (H) is preferably a dialkyl ether having two alkyl groups having 16 or less carbon atoms, more preferably a dialkyl ether having two alkyl groups having 8 or less carbon atoms. Skin cleaning sheet.
<62> Component (H) is preferably cetyl-1,3-dimethylbutyl ether or dioctyl ether, and more preferably dioctyl ether, the skin cleaning sheet according to the above <60> or <61>.
The content of <63> component (H) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, further preferably 1% by mass or more, and 25% by mass or less in the total composition. The skin cleaning sheet according to any one of <60> to <62>, preferably 10% by mass or less, and more preferably 6% by mass or less.

<64> The O / W emulsion may contain (I) a hydrocarbon oil having a viscosity at 30 ° C. of 30 mPa · s or less, preferably 1 to 10 mPa · s. The skin cleaning sheet according to any one of the above.
<65> The skin cleansing sheet according to <64>, wherein the component (I) is preferably isododecane.
The content of <66> component (I) is preferably 1% by mass or more, more preferably 5% by mass or more, further preferably 10% by mass or more, and preferably 50% by mass or less in the total composition. The skin cleaning sheet according to <64> or <65>, wherein 35% by mass or less is more preferable, and 20% by mass or less is more preferable.

<67> The O / W emulsion is the skin cleansing sheet according to any one of the above <36> to <66>, which may contain a water-soluble polymer (J).
<68> Component (J) is preferably a nonionic water-soluble polymer containing cellulose as a constituent unit, hydroxyalkyl cellulose is more preferable, and hydroxyethyl cellulose is more preferable.
<69> Component (J) is preferably a water-soluble polymer containing acrylic acid or methacrylic acid as a structural unit, more preferably an acrylic acid / alkyl methacrylate copolymer, and acrylic acid and a carbon number of 10 to 30 The skin cleansing sheet according to the above <67>, wherein a copolymer with an alkyl methacrylate ((acrylic acid / alkyl acrylate (C10-30)) copolymer) is more preferable.
The content of the <70> component (J) is preferably 0.01% by mass or more, more preferably 0.025% by mass or more, further preferably 0.05% by mass or more, in the total composition. The skin cleansing sheet according to any one of the above <67> to <69>, preferably at most mass%, more preferably at most 0.7 mass%, further preferably at most 0.3 mass%.

In the <71> O / W emulsion, the mass ratio (J) / (H) of the component (H) and the component (J) is preferably 0.001 or more, more preferably 0.004 or more, The skin cleansing sheet according to any one of <60> to <70>, more preferably 0.01 or more, preferably 5 or less, more preferably 2.5 or less, and further preferably 1 or less.
<72> The O / W type emulsion is the skin cleansing sheet according to any one of the above <36> to <71>, which may contain (K) a water-soluble solvent.
<73> Component (K) is preferably propylene glycol, isoprene glycol, 1,3-butylene glycol, hexylene glycol or glycerin, more preferably 1,3-butylene glycol, propylene glycol, isoprene glycol or glycerin. The skin cleaning sheet according to <72>.
<74> Component (K) is preferably polyoxypropylene (9) diglyceryl ether, polyoxypropylene (14) diglyceryl ether, polyoxybutylene polyoxyethylene polyoxypropylene glyceryl ether (3B.O.) ( The skin cleansing sheet according to <72>, which is 8E.O.) (5P.O.).
The content of the <75> component (K) is preferably 1% by mass or more, more preferably 3% by mass or more, further preferably 5% by mass or more, and preferably 35% by mass or less in the total composition. The skin cleansing sheet according to any one of <72> to <74>, more preferably 20% by mass or less, and further preferably 15% by mass or less.

<76> The skin cleansing sheet according to any one of <36> to <75>, wherein the O / W emulsion may contain (L) a nonionic surfactant of HLB8 or higher.
<77> The skin cleansing sheet according to <76>, wherein the component (L) is preferably a polyethylene glycol fatty acid ester, and more preferably mono-polyethylene glycol (12).
The content of <78> component (L) is preferably 0.001% by mass or more, more preferably 0.01% by mass or more, still more preferably 0.03% by mass or more, in the total composition. The skin cleaning sheet according to the above <76> or <77>, preferably at most mass%, more preferably at most 1 mass%, further preferably at most 0.5 mass%.
The <79> O / W emulsion can contain (M) water, and the content of water is preferably 30% by mass or more and more preferably 40% by mass or more in the total composition. 50% by mass or more, preferably 95% by mass or less, more preferably 90% by mass or less, and still more preferably 80% by mass or less, in any one of the above items <36> to <78>.

<80> The skin cleansing sheet according to any one of the above <36> to <79>, wherein the impregnation ratio of the O / W emulsion to the nonwoven fabric is preferably 50 to 1500%, more preferably 300 to 700%. .
The liquid amount per unit volume of the surface area of the <81> second layer is preferably 1 × 10 ⁶ to 3 × 10 ⁶ g / m ³ , and 1.02 × 10 ⁶ to 2.8 × 10 ⁶ g. The skin cleansing sheet according to any one of <36> to <80>, wherein / m ³ is more preferable, and 1.04 × 10 ⁶ to 2.6 × 10 ⁶ g / m ³ is more preferable.
<82> Use of the skin cleansing sheet according to any one of the above <36> to <81> for the manufacture of a skin cleansing sheet for cleansing makeup cosmetics applied to a face.

Examples 1-7, Comparative Examples 1-5
A skin cleanser composition having the composition shown in Table 1 is manufactured, and the shape of the film, the uniformity of the film, the persistence of the moist feeling of the skin after wiping, the persistence of the feeling of sticking to the skin after wiping, and the oily mascara Detergency was evaluated. The results are also shown in Table 1.

(Production method)
Put the water of component (D) weighed into a container, add component (B) while stirring with a disper (1200 rpm, 10 minutes) to prepare a solution, and then add component (A), component (C) and other components. In addition, the mixture was stirred with a homomixer to produce a skin cleanser composition. The pH was adjusted to 5 to 7 and the viscosity was adjusted to be in the range of 1000 to 2500 mPa · s. In Example 7, the skin cleansing composition of Example 1 was dropped onto the non-woven fabric at a predetermined impregnation rate, and then allowed to stand for one day to allow the non-woven fabric to be sufficiently used to produce a skin cleansing sheet.

(Evaluation methods)
(1) Shape of the film:
Five expert panelists dropped 0.1 g of each liquid skin cleanser composition (Examples 1 to 6, Comparative Examples 1 to 5) on a glass plate and wiped with cotton, or with a skin cleansing sheet (Example 7). After wiping the glass plate, the film formed when allowed to stand for 12 hours was touched by hand, evaluated in the following five stages, and judged by the total score of five persons.
5: I feel moist.
4: I feel a little moist.
3: I can't say either.
2: Does not feel moist.
1: Does not feel moist.

(2) Film uniformity:
Five expert panelists dropped 0.1 g of each liquid skin cleanser composition (Examples 1 to 6, Comparative Examples 1 to 5) on a glass plate and wiped with cotton, or with a skin cleansing sheet (Example 7). After wiping the glass plate, the shape of the film produced when the glass plate was allowed to stand for 12 hours was visually evaluated in the following 5 stages, and judged by the total score of 5 persons.
5: A very uniform appearance is exhibited.
4: An almost uniform appearance is exhibited.
3: I can't say either.
2: Presents a slightly non-uniform appearance.
1: Presents a non-uniform appearance.

(3) Persistence of moist feeling after wiping:
Five professional panelists use 1 g of each liquid detergent composition (Examples 1 to 6 and Comparative Examples 1 to 5) to prepare a foundation (Sofina Primavis Tart Liquid Foundation Ocher 05. Use the same foundation for the following evaluations) About the moist feeling of the skin after having massaged the applied face and wiping with cotton or wiping the face with a skin cleansing sheet (Example 7) and resting in a room at 20 ° C and 40% RH for 3 hours Evaluation was made based on the following 5 grades, and the total score of 5 people was judged.
5: Moist.
4: Slightly moist.
3: I can't say either.
2: Not very moist.
1: Not moist.

(4) Sustainability of the skin feeling after wiping off:
5 professional panelists use 1 g of each liquid detergent composition (Examples 1 to 6, Comparative Examples 1 to 5) to massage the face with the foundation applied and wipe it off with cotton or use a skin cleansing sheet (Example) After wiping the face in 7), after having spent 3 hours resting in a room at 20 ° C and 40% RH, the skin feels when the face is touched with the hand. Judged by the total score.
5: It feels like sucking.
4: I feel a little sticky.
3: I can't say either.
2: Doesn't feel so sticky.
1: Does not feel sticky.

(5) Detergency for oily mascara:
As an oily mascara (waterproof mascara), Kose Sports Beauty Facio Powerstay Mascara (Karl Long) BK001 (trade name) 0.005 g is uniformly applied on a slide glass in a circular shape with a diameter of 1.2 cm and left for 2 hours. And dried. Each liquid detergent composition (Examples 1 to 6 and Comparative Examples 1 to 5) is gently wiped with cotton for 10 seconds, and then wiped with cotton or skin cleansed. The oily mascara was gently wiped with a sheet (Example 7) with a finger for 10 seconds and wiped off. The fall of the mascara was evaluated in the following five stages and judged by the total score of the five persons.
5: About 5% or less of the amount applied by mascara remained.
4: More than about 5% of the amount applied by mascara and 20% or less remained.
3: More than about 20% and 50% or less of the amount applied by mascara remained.
2: More than about 50% of the amount applied by mascara and 80% or less remained.
1: More than about 80% of the applied amount of mascara remained.

Examples 8 to 15 and Comparative Examples 6 to 14
Skin cleansing compositions having the compositions shown in Tables 2 and 3 were produced, and the viscosity and average particle diameter were measured. In the same manner as in Examples 1 to 7, the moist feeling of the skin after wiping was maintained. In addition to evaluating the persistence of the skin's stickiness and detergency against oily mascara, it was also evaluated for its freshness and moistness immediately after wiping, the feeling of use after storage, the feeling of thickness, the ease of handling, and the smoothness of wiping. The results are shown in Tables 2 and 3.

(Production method)
Put the water of component (D) weighed into a container, add component (B) while stirring with a disper (1200 rpm, 10 minutes) to prepare a solution, and then add component (A), component (C) and other components. In addition, the mixture was stirred with a homomixer to produce a skin cleanser composition. The pH was adjusted to 5 to 7 and the viscosity was adjusted to be in the range of 1000 to 2500 mPa · s. In Examples 9 to 15 and Comparative Examples 6 to 14, skin cleansing sheets were produced by dripping the skin cleansing composition onto the nonwoven fabric at a predetermined impregnation rate, and then letting it stand for 1 day to allow it to fully fit into the sheets.

(Evaluation methods)
(1) Viscosity:
The viscosity of the skin cleanser composition before impregnating the sheet was measured at 25 ° C. using a B-type viscometer, and the rotor No. The measurement was performed at 2, 6 rpm and 1 minute.

(2) Average particle size:
About the skin cleansing composition before impregnating the sheet, the particle size of the emulsified particles is determined by using a laser diffraction / scattering type particle size distribution measuring device (LA-910, manufactured by HORIBA) at a concentration of 70 to 95% transmittance. It diluted with water so that it might become, and measured, and the average particle diameter was computed.

(3) Fresh feeling immediately after wiping:
Five professional panelists massaged the face with the foundation applied with 1 g of the liquid detergent composition (Example 8) and wiped it off with cotton, or each skin cleaning sheet (Examples 9 to 15 and Comparative Examples 6 to 14). ), And after wiping off the face, the refreshing feeling was evaluated in the following five stages and judged by the total score of five persons.
5: Refresh.
4: Slightly refreshing.
3: I can't say either.
2: Not very refreshing.
1: Not refreshing.

(4) Moist feeling immediately after wiping:
Five professional panelists massaged the face with the foundation applied with 1 g of the liquid detergent composition (Example 8) and wiped it off with cotton, or each skin cleaning sheet (Examples 9 to 15 and Comparative Examples 6 to 14). ), And after wiping the face, the moist feeling was evaluated according to the following 5 levels and judged by the total score of 5 people.
5: Moist.
4: Slightly moist.
3: I can't say either.
2: Not very moist.
1: Not moist.

(5) Usability after storage:
A liquid detergent composition (Example 8) filled in a 100 mL glass bottle (diameter: about 5 cm, height: about 8 cm, manufacturer: Tokyo Glass Co., Ltd.) was stored at 50 ° C. for 4 weeks, and then the upper part ( About 1 g of the composition at the bottom (between 5 mm below the liquid level) and the bottom (between 5 mm above the bottom) is gently sucked with a dropper (material: polyethylene, volume 2 mL). About the difference in the usability | use_condition of a liquid cleaning composition, the face which apply | coated the foundation was massaged and wiped off with cotton, and the following five steps evaluated. Further, 40 skin cleaning sheets (Examples 9 to 15 and Comparative Examples 6 to 14) were laminated, sealed in an aluminum pillow, and stored at 50 ° C. for 4 weeks. After that, when using the uppermost sheet and the lowermost sheet of the preserved product on the face, 5 expert panelists evaluated the difference in feeling of use in the following 5 stages, and the total score of 5 people Judged by.
5: There is no difference.
4: There is not much difference.
3: I can't say either.
2: There is a slight difference.
1: There is a difference.

(6) Thickness:
Five professional panelists use 1 g of the liquid detergent composition (Example 8) to massage the face to which the foundation is applied and wipe it off with cotton, or each skin cleaning sheet (Examples 9 to 15 and Comparative Examples 6 to 6). When the face was wiped off in 14), the sense of thickness was evaluated in the following five stages, and judged by the total score of five people.
The sense of thickness indicates how the sheet is deformed during wiping, and the thicker the skin, the easier it is to wipe off.
5: There is a feeling of thickness.
4: Slightly thick.
3: I can't say either.
2: Not very thick.
1: There is no sense of thickness.

(7) Ease of handling (no liquid dripping):
Five professional panelists use 1 g of the liquid detergent composition (Example 8) to massage the face to which the foundation is applied and wipe it off with cotton, or each skin cleaning sheet (Examples 9 to 15 and Comparative Examples 6 to 6). When the face was wiped off in 14), the ease of handling was evaluated according to the following 5 levels, and the total score of 5 people was determined.
5: Easy to handle.
4: Slightly easy to handle.
3: I can't say either.
2: Slightly difficult to handle.
1: It is difficult to handle.

(8) Smooth feeling:
Five professional panelists use 1 g of the liquid detergent composition (Example 8) to massage the face to which the foundation is applied and wipe it off with cotton, or each skin cleaning sheet (Examples 9 to 15 and Comparative Examples 6 to 6). In 14), when the face was wiped off, whether or not the face was wiped smoothly was evaluated according to the following five levels, and the total score of five persons was determined.
5: Smooth.
4: Slightly smooth.
3: I can't say either.
2: Not very smooth.
1: Not smooth.

Examples 15-17
In the same manner as in Examples 8 to 15, skin cleanser compositions having the compositions shown in Table 4 were produced, the viscosity and average particle size were measured, and the moist feeling of the skin after wiping was observed. Evaluates the persistence of the sticking feeling, the refreshing and moist feeling immediately after wiping, the feeling of use after storage, the feeling of thickness, the ease of handling, the smooth wiping feeling, and the detergency against oily mascara, and the stickiness immediately after wiping Evaluation was made. The results are also shown in Table 4.

(Evaluation methods)
(1) No stickiness immediately after wiping:
Five professional panelists use 1g of each liquid detergent composition to massage the face with foundation applied, wipe it off with cotton, and evaluate the non-stickiness immediately after wiping in the following five stages. Judged by point.
5: There is no stickiness.
4: Almost no stickiness.
3: I can't say either.
2: There is a little stickiness.
1: There is stickiness.

Examples 18 to 24, Comparative Examples 15 to 20
A skin cleaning sheet is manufactured using the nonwoven fabric and the O / W emulsion shown in Table 5, and the cleaning power, stability, sheet thickness, sheet softness, sheet smoothness, refreshing feeling and wiping The feeling of the amount of liquid contained in was evaluated. The results are also shown in Table 5.
The viscosity of the O / W emulsion was measured with a BM viscometer (manufactured by Tokimec, measurement conditions: rotor No. 2, 6 rpm, 1 minute). Moreover, the impregnation rate in each of the first layer and the second layer in the nonwoven fabric was evaluated by the following method.

(Evaluation method of impregnation rate (%) in each of first layer and second layer in nonwoven fabric)
One set of the second layer on the upper and lower surfaces of the first layer was taken as one set, and 20 sets were left at 50 ° C. for 1 month. Thereafter, the impregnation rates of the 10th and 11th sets of the first layer (2 sheets in total) and the second layer (4 sheets in total) from the top were measured, and the average value was taken as the impregnation rate.

(Production method)
At room temperature, water of component (M) was put into a container, and component (J) was added while stirring with a disper. Further, a base was added and stirred as necessary. Furthermore, component (H), (I), (K) was added, and it stirred with the homomixer, and obtained the O / W type | mold emulsion. The obtained O / W emulsion is applied by dropping or flowing down from a nozzle, or by spraying to impregnate the nonwoven fabric, and then leaving it to fully fit the sheet to obtain a skin cleaning sheet. It was.

(Evaluation methods)
(1) Detergency:
As an oily mascara (waterproof mascara), Kose Sports Beauty Facio Powerstay Mascara (Carl Long) BK001 (trade name) 0.005 g is uniformly formed into a circular shape with a diameter of 1.2 cm on a polypropylene plate (Engineering Test Service). It was applied and left to dry for 2 hours. Each skin cleansing sheet was applied to an oily mascara and lightly pressed for 10 seconds, then wiped off at a constant pressure (7.8 kPa), and the number of times of wiping required to remove the mascara was measured.
5: Less than 5 times.
4: 6-9 times.
3: 10-15 times.
2: 16-20 times.
1: 21 times or more.

(2) Stability (laminated sheet):
Each non-woven fabric 10 cm × 10 cm was uniformly impregnated with each O / W type emulsion so as to have a predetermined impregnation rate in the table with respect to the dry mass of the non-woven fabric to prepare a skin cleaning sheet. After stacking 40 skin cleansing sheets and letting them stand at 50 ° C. for 1 month, when comparing the uppermost sheet and the lowermost sheet in the laminated sheet, five expert panelists and the uppermost sheet For the difference in the feeling of use of the lower sheet, wipe the face with the foundation (Sofina Primavis Talkid Foundation Ocher 05. Use the same foundation for the following evaluations) and evaluate it according to the following 5 levels. did.
5: There is no difference.
4: There is not much difference.
3: I can't say either.
2: There is a slight difference.
1: There is a difference.

(3) Sheet thickness feeling:
Each non-woven fabric 10 cm × 10 cm was uniformly impregnated with each O / W type emulsion so as to obtain a predetermined impregnation ratio in the table with respect to the dry mass of the non-woven fabric to prepare a skin cleaning sheet. When five professional panelists wiped the face on which the foundation was applied with each skin cleansing sheet, the thickness of the sheet was evaluated in the following five stages and judged by the total score of the five persons.
5: There is a feeling of thickness.
4: Slightly thick.
3: I can't say either.
2: Not very thick.
1: There is no sense of thickness.

(4) Softness of the sheet:
Each non-woven fabric 10 cm × 10 cm was uniformly impregnated with each O / W type emulsion so as to obtain a predetermined impregnation ratio in the table with respect to the dry mass of the non-woven fabric to prepare a skin cleaning sheet. When five professional panelists wiped the face with the foundation applied on each skin cleaning sheet, the softness of the skin cleaning sheet was evaluated in the following five stages, and judged by the total score of the five persons.
5: Soft.
4: Slightly soft.
3: I can't say either.
2: Not very soft.
1: Not soft.

(5) Sheet smoothness:
Each non-woven fabric 10 cm × 10 cm was uniformly impregnated with each O / W type emulsion so as to obtain a predetermined impregnation ratio in the table with respect to the dry mass of the non-woven fabric to prepare a skin cleaning sheet. When five expert panelists wiped the face on which the foundation was applied with each skin cleaning sheet, whether or not it could be wiped smoothly was evaluated according to the following five levels, and judged by the total score of the five persons.
5: Smooth.
4: Slightly smooth.
3: I can't say either.
2: Not very smooth.
1: Not smooth.

(6) Refreshing feeling:
Each non-woven fabric 10 cm × 10 cm was uniformly impregnated with each O / W type emulsion so as to obtain a predetermined impregnation ratio in the table with respect to the dry mass of the non-woven fabric to prepare a skin cleaning sheet. When five professional panelists wiped the face on which the foundation was applied with each skin cleaning sheet, the refreshing feeling was evaluated in the following five stages and judged by the total score of the five persons.
5: Refresh.
4: Slightly refreshing.
3: I can't say either.
2: Not very refreshing.
1: Not refreshing.

(7) Feeling the amount of liquid contained in the sheet when wiping off:
Each non-woven fabric 10 cm × 10 cm was uniformly impregnated with each O / W type emulsion so as to obtain a predetermined impregnation ratio in the table with respect to the dry mass of the non-woven fabric to prepare a skin cleaning sheet. When five professional panelists wiped the face with the foundation applied on each skin cleaning sheet, the amount of liquid felt on the skin was evaluated in the following five stages, and judged by the total score of the five persons. The more liquid you feel, the more gently you feel.
5: I feel that the amount of liquid is large.
4: I feel that the amount of liquid is a little larger 3: I can't say either.
2: I feel that the amount of liquid is a little small.
1: Feels that the amount of liquid is small.

Examples 25 to 28, Comparative Examples 21 to 22
In the same manner as in Examples 18 to 24, a skin cleaning sheet shown in Table 6 was produced, and the feeling of the amount of liquid contained in the sheet was evaluated at the time of cleaning and wiping. The feeling of use was evaluated. The results are also shown in Table 6.

(Evaluation methods)
(1) Usability after storage:
After storing 40 sets of each skin cleansing sheet at 50 ° C for 2 weeks, compare the feeling of use of the group located at the top and the group located at the bottom by wiping the face to which the foundation was applied. Five panelists evaluated the difference in usability in the following five stages, and judged by the total score of the five persons.
5: No.
4: Not much.
3: I can't say either.
2: Somewhat.
1: Yes.

(2) Usability immediately after impregnation:
Each non-woven fabric 10 cm × 10 cm was uniformly impregnated with each O / W type emulsion so as to obtain a predetermined impregnation ratio in the table with respect to the dry mass of the non-woven fabric to prepare a skin cleaning sheet. When five professional panelists wiped the face with the foundation applied on each skin cleaning sheet, the sliminess was evaluated in the following five levels and judged by the total score.
5: Smooth without stickiness.
4: Slightly non-smooth and smooth.
3: I can't say either.
2: Slightly sticky and not smooth.
1: There is stickiness and it is not smooth.

Claims

The following components (A), (B), (C), (D) and (E):
(A) 0.1 to 25% by mass of ether oil which is liquid at 25 ° C.
(B) a water-soluble polymer containing acrylic acid or methacrylic acid as a structural unit 0.003 to 1% by mass,
(C) 1-30% by mass of a hydrocarbon oil having a viscosity at 30 ° C. of 15 mPa · s or less,
(D) 60-95% by weight of water,
(E) A nonionic surfactant having an HLB greater than 9 is contained in an amount of 0.49% by mass or less, and the mass ratio (B) / (A) of the component (A) to the component (B) is 0.0001-0. 1. A skin cleanser composition having a mass ratio (A) / ((A) + (C)) of components (A) and (C) of 0.05 to 0.9.
The skin cleansing composition according to claim 1, wherein the mass ratio (A) / (D) of the components (A) and (D) is 0.45 or less.
The skin cleansing composition according to claim 1 or 2, wherein the component (A) is a dialkyl ether having two alkyl groups having 16 or less carbon atoms.
The skin cleanser composition according to any one of claims 1 to 3, wherein the component (A) is a dialkyl ether having two alkyl groups having 8 or less carbon atoms.
The skin cleanser composition according to any one of claims 1 to 4, wherein the component (B) is an acrylic acid / alkyl methacrylate copolymer.
The skin cleansing composition according to any one of claims 1 to 5, wherein the component (B) is a copolymer of acrylic acid and an alkyl methacrylate having 10 to 30 carbon atoms.
The skin cleanser composition according to any one of claims 1 to 6, wherein the mass ratio (A) / (E) of the components (A) and (E) is 0.1 to 200000.
The skin cleanser composition according to any one of claims 1 to 7, further comprising (F) a water-soluble solvent.
The skin cleanser composition according to any one of claims 1 to 8, which is impregnated into a sheet.
A skin cleansing sheet comprising a sheet impregnated with the skin cleansing composition according to any one of claims 1 to 8.
A non-woven fabric having a layer structure comprising a first layer and two second layers arranged on the surface side of the first layer;
An O / W type emulsion having a viscosity at 30 ° C. of 200 to 15000 mPa · s as an impregnating liquid,
The ratio of the density of the first layer and the density of the second layer of the nonwoven fabric (density of the first layer / density of the second layer) is 1.05 or more,
A skin cleansing sheet in which the ratio of the thickness of one side of the first layer and the second layer of the nonwoven fabric (thickness of the first layer / thickness of the one side of the second layer) is 0.6 to 1.5.