JP2009297535A - Cosmetic base material and skin cleansing sheet using this - Google Patents
Cosmetic base material and skin cleansing sheet using this Download PDFInfo
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- JP2009297535A JP2009297535A JP2009205575A JP2009205575A JP2009297535A JP 2009297535 A JP2009297535 A JP 2009297535A JP 2009205575 A JP2009205575 A JP 2009205575A JP 2009205575 A JP2009205575 A JP 2009205575A JP 2009297535 A JP2009297535 A JP 2009297535A
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Abstract
Description
本発明は化粧液を皮膚に塗布したり、メーク汚れや皮脂汚れを取る際に使用される、い
わゆるパフ等の化粧用基材、及びこれと同様の目的で薬液が含浸された状態で使用される
皮膚洗浄用シートに関する。更に詳しくは、メーク汚れや皮脂汚れの拭き取り性が非常に
良好で、化粧液の拡散性が良好で、皮膚への基材からの汚染が少なく、湿潤状態における
形態安定性に優れ、皮膚への物理刺激性が低い化粧用基材及び皮膚洗浄用シートに関する
。
The present invention is used when a cosmetic liquid is applied to the skin or when make-up dirt or sebum dirt is removed, so-called puffs and other cosmetic base materials, and used in a state impregnated with a chemical for the same purpose. The present invention relates to a skin cleaning sheet. More specifically, the wiping property of make-up stains and sebum stains is very good, the diffusibility of the cosmetic liquid is good, there is little contamination from the base material to the skin, the form stability in a wet state is excellent, and the skin The present invention relates to a cosmetic substrate and a skin cleansing sheet having low physical irritation.
化粧水や乳液を肌に塗布する際には、脱脂綿やコットンスパレース不織布等で製造され
たいわゆるパフにこれらの化粧液を含ませて塗布することが多い。また、口紅、ファンデ
ーション、アイシャドウ、マスカラ等のメークアップ化粧料を落とす際には、クレンジン
グ液等の化粧液をパフ等に含浸したり、メークレンジング液等の化粧液が含浸された脱脂
綿や脱脂綿シート、コットンスパンレース不職布等からなる皮膚洗浄用シートを使用する
ことが多い。
これらの化粧用基材および化粧用基材に薬液が含浸されてなる皮膚洗浄用シートには上
述のように脱脂綿や脱脂綿シート、コットンスパンレース不織布のような短繊維が一般的
に使用されている。これは綿がセルロース繊維で液含浸性が良好であること、天然繊維で
肌への刺激が少ないと考えられていること、短繊維のため膨らみがあり柔らかな触感があ
ることなどを理由とする。しかし、これらの基材は短繊維であるため、多量の油分、固体
油を含有する化粧液を含浸した状態では、短繊維が脱落して皮膚へ付着し再汚染したり、
化粧液を含浸しない状態では繊維径が太いため化粧落とし効果が充分でないなどの問題点
があった。
When applying lotion or milky lotion to the skin, these cosmetics are often applied to so-called puffs made of absorbent cotton or cotton spalace nonwoven fabric. Also, when removing make-up cosmetics such as lipsticks, foundations, eye shadows and mascaras, impregnating cosmetic liquids such as cleansing liquids into puffs, or absorbent cotton or absorbent cotton impregnated with cosmetic liquids such as cleansing liquids In many cases, a skin cleaning sheet made of a sheet, a cotton spunlace unemployed cloth or the like is used.
As described above, short fibers such as absorbent cotton, absorbent cotton sheet, and cotton spunlace nonwoven fabric are generally used in these cosmetic substrates and skin cleaning sheets in which a cosmetic solution is impregnated with a chemical solution. . This is because cotton is a cellulose fiber and has good liquid impregnation properties, natural fibers are considered to be less irritating to the skin, and because of short fibers, there is swelling and a soft touch. . However, since these base materials are short fibers, in a state impregnated with a cosmetic liquid containing a large amount of oil and solid oil, the short fibers fall off and adhere to the skin and re-contamination,
When the cosmetic liquid is not impregnated, there is a problem that the makeup removal effect is not sufficient because the fiber diameter is large.
また、化粧用基材の表面材がポリエステルやナイロンの合成繊維であると保液性が綿等
に比べて低いことや肌への刺激性が懸念される等の問題があった。
これらの問題点を解決するために再生セルロース長繊維不織布からなる化粧綿が特許文
献１に開示されている。再生セルロース長繊維不織布は、例えば銅アンモニア法レーヨン
やビスコース法レーヨンにより製造された不織布で通常繊維径が１０〜１６μｍ程度のも
のである。銅アンモニアレーヨン法による再生セルロース連続長繊維不織布は、繊維自体
の自己接着と高圧水流による繊維交絡により不織布が形成され、融着繊維等を使用するこ
とがないので脱脂綿と同様に皮膚への刺激性が非常に低い素材であり、かつ、長繊維で構
成されているため繊維の脱落による皮膚への再汚染も非常に少ないという特徴がある。し
かし、メークの拭き取り性は脱脂綿等とほとんど変わらず、より簡単にメーク落としを行
いたいという要求を満足できるものではなく、また、化粧液に含浸すると湿潤時の伸度が
大きいため形態安定性に問題があった。
Further, when the surface material of the cosmetic base material is a synthetic fiber such as polyester or nylon, there are problems such as low liquid retention compared to cotton and concerns about irritation to the skin.
In order to solve these problems, Patent Document 1 discloses a cosmetic cotton made of a regenerated cellulose long fiber nonwoven fabric. The regenerated cellulose long fiber nonwoven fabric is a nonwoven fabric produced by, for example, copper ammonia method rayon or viscose method rayon, and usually has a fiber diameter of about 10 to 16 μm. The regenerated cellulose continuous long-fiber nonwoven fabric by the copper ammonia rayon method is formed by self-adhesion of the fiber itself and fiber entanglement by high-pressure water flow. Is a very low material, and because it is composed of long fibers, it is characterized by very little re-contamination on the skin due to fiber dropping. However, the wiping property of make-up is almost the same as that of absorbent cotton, etc., and it does not satisfy the requirement for easier make-up removal. There was a problem.
また、単繊維繊度が０．５ｄｔｅｘ以下の極細繊維が不織布表面積の２０％以上を占め
る不織布からなる化粧用ワイパーが特許文献２に開示されている。しかし、この化粧用ワ
イパーでは、極細繊維としてポリエチレンテレフタレートやポリプロピレン等の合成繊維
が用いられているため、保液性や肌への刺激性について改善されているものの、まだセル
ロース系繊維に比べると劣っていた。
Further, Patent Document 2 discloses a cosmetic wiper made of a nonwoven fabric in which ultrafine fibers having a single fiber fineness of 0.5 dtex or less occupy 20% or more of the surface area of the nonwoven fabric. However, in this cosmetic wiper, synthetic fibers such as polyethylene terephthalate and polypropylene are used as ultrafine fibers, so the liquid retention and irritation to the skin are improved, but still inferior to cellulosic fibers. It was.
本発明は、メーク汚れや皮脂汚れの拭き取り性が非常に良好で、化粧液の拡散性が良好
で、皮膚への基材からの汚染が少なく、保液性及び湿潤状態における形態安定性に優れ、
皮膚への物理刺激性が低いパフ等の化粧用基材及び薬液が含浸された皮膚洗浄用シートを
提供することにある。
The present invention has very good wiping of make-up stains and sebum stains, good diffusibility of the cosmetic liquid, little contamination from the base material to the skin, excellent liquid retention and form stability in wet conditions ,
An object of the present invention is to provide a skin cleaning sheet impregnated with a cosmetic base material such as a puff having low physical irritation to the skin and a chemical solution.
本発明者等は上記問題に鑑み、セルロース長繊維不織布の特徴を活かしながら湿潤時の
形態安定性を向上させる方法を検討し、繊維径の小さいセルロース長繊維からなる不織布
を用いる場合に、湿潤時でも形態安定性が向上すること、また、繊維径を低下させること
により拭き取り性が向上するとともに滑らかな触感が得られることを見出し、本発明を成
すに至った。
すなわち、本発明は以下のとおりである。
（１）表面がセルロース長繊維不織布であって、該不織布の少なくとも表面を構成する繊
維本数の６０％以上が繊維径２．９〜７．１μｍのセルロース長繊維であり、該不織布の
開孔部の平均面積が０．１〜２ｍｍ２であり、開孔部の面積率が３〜２５％であり、湿潤
形態保持率が８０％以上であり、液拡散状態係数が０．６５〜１．３５、液拡散面積が４
．１〜８．６ｃｍ ２ であることを特徴とする化粧用基材。
（２）該不織布が再生セルロース連続長繊維不織布であることを特徴とする（１）に記載
の化粧用基材。
（３）（１）または（２）に記載の化粧用基材に薬液が含浸されてなることを特徴とする
皮膚洗浄用シート。
In view of the above problems, the present inventors examined a method for improving the morphological stability at the time of wetting while taking advantage of the characteristics of the cellulose long fiber nonwoven fabric, and when using a nonwoven fabric composed of cellulose long fibers having a small fiber diameter, However, the present inventors have found that morphological stability is improved and that the wiping property is improved by reducing the fiber diameter and that a smooth tactile sensation is obtained, thereby achieving the present invention.
That is, the present invention is as follows.
(1) The surface is a cellulose long fiber nonwoven fabric, and at least 60% of the number of fibers constituting the surface of the nonwoven fabric is a cellulose long fiber having a fiber diameter of 2.9 to 7.1 μm. the average area is 0.1 to 2 mm 2, the area ratio of the openings is 3-25% state, and are wet form retention of 80% or more, a liquid distribution condition coefficient is 0.65 to 1. 35, liquid diffusion area is 4
. 1~8.6cm 2 der Rukoto cosmetic base material which is characterized in.
(2) The cosmetic substrate according to (1), wherein the nonwoven fabric is a regenerated cellulose continuous long fiber nonwoven fabric.
(3) A skin cleaning sheet, wherein the cosmetic base material according to (1) or (2) is impregnated with a chemical solution.
本発明の化粧用基材は、メーク汚れや皮脂汚れの拭き取り性が極めて良好で、化粧液の
拡散性が良好で、皮膚への基材からの汚染が少なく、保液性及び湿潤状態における形態安
定性に優れ、皮膚への物理刺激性が低いという効果を有する。
The cosmetic base material of the present invention has very good wiping off of makeup stains and sebum stains, good diffusibility of the cosmetic liquid, little contamination from the base material to the skin, liquid retention and form in a wet state Excellent stability and low physical irritation to skin.
本発明について以下具体的に説明する。
本発明でいうセルロース長繊維不織布とは、例えば銅アンモニア法レーヨン原液を流下
緊張紡糸法によりネット上に連続で紡糸し、繊維自体の自己接着と水流交絡にて接着、交
絡させた再生セルロース連続長繊維不織布や、特表２００２−５２１５８５号公報に開示
される方法等で製造されたリヨセル等の精製セルロース長繊維不織布等のことをいう。
セルロース長繊維不織布は、構成する繊維が長繊維であるため繊維の脱落が少なく表面
材として使用した場合、綿等の短繊維不織布に比べて人体への繊維付着による汚染が少な
い。また、従来の合成繊維不織布に比べ、保液性及び物理刺激性に優れるため好ましい。
また、セルロース長繊維不織布が再生セルロース連続長繊維不織布である場合、不織布
形成時に接着用の樹脂等のバインダーを使用しないため、安全性に優れたものであるので
好ましい。また、自己接着により形態安定性が高いので好ましい。
The present invention will be specifically described below.
The cellulose long fiber nonwoven fabric referred to in the present invention is, for example, a regenerated cellulose continuous length in which a copper ammonia rayon stock solution is continuously spun onto a net by a flow-down tension spinning method and bonded and entangled by self-adhesion and hydroentanglement of the fiber itself. This refers to fiber nonwoven fabrics and purified cellulose long fiber nonwoven fabrics such as lyocell produced by the method disclosed in JP-T-2002-521585.
Cellulose long fiber nonwoven fabrics are composed of long fibers, so that the fibers do not drop out, and when used as a surface material, there is less contamination due to fiber adhesion to the human body than short fiber nonwoven fabrics such as cotton. Moreover, since it is excellent in a liquid retention property and physical irritation compared with the conventional synthetic fiber nonwoven fabric, it is preferable.
In addition, when the cellulose long fiber nonwoven fabric is a regenerated cellulose continuous long fiber nonwoven fabric, since a binder such as an adhesive resin is not used when forming the nonwoven fabric, it is preferable because it is excellent in safety. In addition, self-adhesion is preferable because of high form stability.
本発明の化粧用基材は、表面がセルロース長繊維不織布であって、不織布の少なくとも
表面を構成する繊維本数の６０％以上、好ましくは８０％以上、最も好ましくは１００％
が繊維径２．９〜７．１μｍのセルロース長繊維からなることを特徴とする。ここでいう
繊維径とは、不織布表面の電子顕微鏡写真で単繊維が約１ｃｍ程度になる倍率で観察した
時に焦点があった繊維の直径のことをいう。本発明では、不織布表面の任意の２００点で
繊維の直径を測定して、その存在比率が６０％以上である、すなわち１２０点以上が繊維
径２．９〜７．１μｍの繊維で構成されていることをいう。不織布の少なくとも表面を形
成するセルロース長繊維本数の６０％以上が繊維径２．９〜７．１μｍであることにより
、同一目付で繊維径が７．１μｍを超えるものに比べて、不織布を構成する繊維の交絡点
や自己接着点の数が増加するので湿潤時の形態安定性が飛躍的に向上する。また、再生セ
ルロース連続長繊維不織布の場合、繊維径が小さくなることにより単糸の精練性が向上し
、更に乱反射により白色度が増加し、化粧用基材としての清潔感が向上する。これに加え
て表面積が増加し、拭き取り面との接触面積も増加することから拭き取り性能も飛躍的に
増加する。また、繊維径がこの範囲にあることにより毛細管現象で輸水性能も向上する。
The cosmetic base material of the present invention has a cellulose long fiber nonwoven fabric surface, and is 60% or more, preferably 80% or more, most preferably 100% of the number of fibers constituting at least the surface of the nonwoven fabric.
Is made of long cellulose fibers having a fiber diameter of 2.9 to 7.1 μm. The fiber diameter here refers to the diameter of the fiber that is in focus when observed at a magnification at which the single fiber is about 1 cm in the electron micrograph of the nonwoven fabric surface. In the present invention, the fiber diameter is measured at an arbitrary 200 points on the surface of the nonwoven fabric, and the abundance ratio is 60% or more, that is, 120 points or more are composed of fibers having a fiber diameter of 2.9 to 7.1 μm. It means being. When 60% or more of the number of long cellulose fibers forming at least the surface of the nonwoven fabric has a fiber diameter of 2.9 to 7.1 μm, it constitutes a nonwoven fabric as compared with those having the same basis weight and a fiber diameter exceeding 7.1 μm. Since the number of fiber entanglement points and self-adhesion points increases, the morphological stability when wet is drastically improved. Further, in the case of the regenerated cellulose continuous long-fiber nonwoven fabric, the scouring property of the single yarn is improved by reducing the fiber diameter, the whiteness is increased by irregular reflection, and the clean feeling as a cosmetic base material is improved. In addition to this, the surface area increases, and the contact area with the wiping surface also increases, so that the wiping performance also increases dramatically. In addition, when the fiber diameter is within this range, the water infusion performance is improved by capillary action.
繊維径２．９〜７．１μｍのセルロース長繊維不織布を得るには、例えば銅アンモニア
法レーヨン原液を用いて再生セルロース長繊維不織布を得る際に、原液を紡糸する紡口の
直径を従来のものより小さくすると共に、原液の粘度や原液温度を調整したり、凝固速度
をコントロールし、更に延伸倍率を従来よりも高く取ることで好適に得られる。
不織布の少なくとも表面を構成する繊維のうち、繊維径２．９〜７．１μｍの繊維本数
が６０％未満であると湿潤時の形態安定性と白色度が減少するばかりでなく、拭き取り性
も低下することがある。
In order to obtain a cellulose long fiber nonwoven fabric having a fiber diameter of 2.9 to 7.1 μm, for example, when a regenerated cellulose long fiber nonwoven fabric is obtained using a copper ammonia method rayon stock solution, the diameter of the spinning nozzle for spinning the stock solution is conventional. It can be suitably obtained by making it smaller, adjusting the viscosity of the stock solution and the temperature of the stock solution, controlling the coagulation rate, and taking a higher draw ratio than before.
If the number of fibers having a fiber diameter of 2.9 to 7.1 μm is less than 60% among the fibers constituting at least the surface of the nonwoven fabric, not only the shape stability and whiteness when wet are reduced, but also the wiping property is lowered. There are things to do.
本発明の化粧用基材におけるセルロース長繊維不織布は、湿潤形態保持率が８０％以上
であることが好ましく、更に好ましくは９０％以上である。ここでいう湿潤形態保持率と
は以下の方法で測定される。測定装置の模式図を図１に示す。不織布の機械軸方向に縦長
となるように５ｃｍ×１２ｃｍにサンプルを準備し、上下１ｃｍの部分の中央部に印をつ
けて測定部を作成する。サンプル重量Ｗ１の１０倍量の純水をサンプルに均一に付与する
。サンプルの上下１ｃｍをサンプル保持板に挟み固定する。１ｍ２あたりのサンプル重量
Ｗ１の３０重量％の荷重（サンプル保持板はＷ１の１０重量％とし、荷重はこれを加えた
もとする）をかけて３０秒間吊り下げた後除重し（下部のサンプル保持板も外す）、３０
秒後に測定部の長さＬを測定する。初期サンプル長は１０ｃｍ（サンプル保持板間の長さ
）として湿潤形態保持率を次式で計算する。
湿潤形態保持率（％）＝（１０−（Ｌ−１０））／１０×１００
湿潤形態保持率は化粧液を含浸させた湿潤状態におけるメーク拭き取り時の取扱い性と
大きく相関する。湿潤形態保持率が８０％未満では湿潤状態におけるメーク拭き取り時に
表面材がヨレて取扱い性が低下したり、表面材が破れて中綿等が体表面に接触したりして
拭き取り面を再汚染することがある。
The cellulose long fiber nonwoven fabric in the cosmetic base material of the present invention preferably has a wet form retention of 80% or more, more preferably 90% or more. The wet form retention rate here is measured by the following method. A schematic diagram of the measuring apparatus is shown in FIG. A sample is prepared in a size of 5 cm × 12 cm so as to be vertically long in the machine axis direction of the nonwoven fabric, and a measurement part is created by marking the center part of the upper and lower parts of 1 cm. Pure water of 10 times the sample weight W1 is uniformly applied to the sample. 1 cm above and below the sample is sandwiched between sample holding plates and fixed. 30 wt% of the load of the sample weight W1 per 1 m 2 (Sample holding plate is 10% by weight of W1, load to original which was added) was subjected dividing weigh after hanging for 30 sec (at the bottom of the sample holding Remove the plate), 30
The length L of the measurement part is measured after 2 seconds. The initial sample length is 10 cm (length between sample holding plates), and the wet form retention rate is calculated by the following equation.
Wet form retention rate (%) = (10− (L−10)) / 10 × 100
The wet form retention rate greatly correlates with the handleability at the time of makeup wiping in a wet state impregnated with a cosmetic liquid. If the wet form retention rate is less than 80%, the surface material may be distorted when the make-up is wiped in a wet state, and the handleability may be reduced, or the surface material may be broken and the batting etc. may come into contact with the body surface to recontaminate the wiping surface. There is.
本発明の化粧用基材における、表面を構成するセルロース長繊維不織布は、好ましくは
目付が７〜３０ｇ／ｍ２、更に好ましくは１０〜２５ｇ／ｍ２である。目付が７ｇ／ｍ２
未満では湿潤時の強度が低下し拭き取りに手間がかかることがある。目付が３０ｇ／ｍ２
を超えると柔軟性が低下し、拭き取り時に違和感を生じたり、肌との密着性が低下して拭
き取り性が低下することがある。
本発明の化粧用基材における、表面を構成するセルロース長繊維不織布の厚みは、化粧
液等をクッション層や吸収材層へ速やかに移行させる観点から０．１〜０．４ｍｍが好ま
しい。０．１ｍｍ未満であると湿潤時の強度に問題を生じることがある。０．４ｍｍを超
えると化粧液等の吸収速度が遅くなることがあり、化粧液等が表面を流れ手や周辺を汚染
することがある。
The cellulose continuous fiber nonwoven fabric constituting the surface of the cosmetic base material of the present invention preferably has a basis weight of 7 to 30 g / m 2 , more preferably 10 to 25 g / m 2 . The basis weight is 7 g / m 2
If it is less than 1, the strength when wet may be reduced, and it may take time to wipe off. The basis weight is 30 g / m 2
If it exceeds, the flexibility may be lowered, causing uncomfortable feeling during wiping, or the adhesion to the skin may be lowered, resulting in a decrease in wiping property.
The thickness of the cellulose long fiber nonwoven fabric constituting the surface in the cosmetic base material of the present invention is preferably 0.1 to 0.4 mm from the viewpoint of promptly transferring the cosmetic liquid or the like to the cushion layer or the absorbent layer. If the thickness is less than 0.1 mm, there may be a problem in strength when wet. If it exceeds 0.4 mm, the absorption speed of the cosmetic liquid or the like may be slow, and the cosmetic liquid or the like may flow on the surface and contaminate the hands or the periphery.
本発明の化粧用基材は液拡散面積が好ましくは４００ｍｍ２以上で、かつ、液拡散状態
係数が好ましくは０．６５〜１．３５、更に好ましくは０．７５〜１．２５である。
ここでいう液拡散面積とは以下の方法で測定したものをいう。
２０ｃｍ四方の試料を準備し、直径１２ｃｍの円筒に試料表面にしわが入らない状態で
輪ゴムやテープ等で固定する。蒸留水１Ｌにシャチハタスタンプインキ水性染料系Ｓ−１
（赤）を１０ｍｌ入れ、評価液を作成する。評価液を先端口径０．７ｍｍのビューレット
に注入する。ビューレットとカメラを図１に示すようにセットする。カメラは固定式、ビ
ューレットは高さ固定の横移動式で、カメラ位置は試料表面から１０ｃｍ上方に、ビュー
レットは試料表面から５ｃｍ上方にセットする。評価液を１滴（０．０１ｍｌ）サンプル
上に落とし、同時にビューレットを横に移動させ、１０秒後の拡散状態の写真撮影を行う
。この際、試料表面にＪＩＳ規格の金尺を置き、写真に写るようにして実際の拡散面積に
換算できるようにする。写真から画像処理等で拡散面積を求める。
The cosmetic base material of the present invention preferably has a liquid diffusion area of 400 mm 2 or more and a liquid diffusion state coefficient of preferably 0.65 to 1.35, more preferably 0.75 to 1.25.
The liquid diffusion area here means that measured by the following method.
A 20 cm square sample is prepared, and is fixed to a cylinder having a diameter of 12 cm with a rubber band, tape or the like in a state where no wrinkles are formed on the sample surface. 1L of distilled water and killer whale stamp ink aqueous dye system S-1
Add 10 ml of (red) to make an evaluation solution. The evaluation liquid is injected into a burette having a tip diameter of 0.7 mm. The viewlet and camera are set as shown in FIG. The camera is a fixed type, the burette is a lateral movement type with a fixed height, the camera position is set 10 cm above the sample surface, and the burette is set 5 cm above the sample surface. The evaluation solution is dropped on a drop (0.01 ml) of the sample, and at the same time, the burette is moved to the side to take a photograph of the diffusion state after 10 seconds. At this time, a JIS standard metal scale is placed on the surface of the sample so that it can be converted into an actual diffusion area as shown in a photograph. The diffusion area is obtained from the photograph by image processing or the like.
拡散面積は繊維径と繊維間の空隙とに関連する。繊維径が本発明の範囲にあることによ
り、この範囲を超えるものより毛管現象により拡散面積が向上する。拡散面積が４００ｍ
ｍ２以上であれば、少量の化粧液でも表面に大きく広がるため化粧液の効率が向上する。
繊維径がこの範囲を下回ると拡散面積は向上するものの、単繊維の強度が低下し拭き取り
時に繊維が切断し、拭き取り面へ残留する繊維量が増加するので実使用に耐えないものと
なる。
The diffusion area is related to the fiber diameter and the voids between the fibers. When the fiber diameter is within the range of the present invention, the diffusion area is improved by capillarity from those exceeding this range. Diffusion area is 400m
If m 2 or more, the efficiency of a small amount of cosmetic liquid cosmetic liquid for spreading significantly to the surface even improved.
When the fiber diameter is below this range, the diffusion area is improved, but the strength of the single fiber is reduced, the fiber is cut at the time of wiping, and the amount of fiber remaining on the wiping surface increases, so that it cannot be used in actual use.
また、液拡散状態係数は前述の液拡散面積測定時の写真を用いて測定する。通常、液は
楕円形に拡散するのでこの楕円の長径ａと短径ｂを測定する。液拡散状態係数ｃは以下の
方法で算出される。
液拡散状態係数ｃ＝ｂ／ａ
液拡散状態係数は液が滴下された時の拡散状態を示す係数であり、どの方向にも同じ状
態で拡散すると円状になり、この場合液拡散状態係数は１となる。クレンジング用基材の
液拡散状態は、形状によって製造方法や使用方向を変えなくても済む観点から等方性があ
る方が好ましいと考えられるため、液拡散状態係数は０．６５〜１．３５が好ましく、よ
り好ましくは０．７５〜１．２５である。液拡散性は基材を構成する繊維の配向状態を調
整することによってコントロールすることが可能である。長繊維不織布の場合、製法上の
特性から機械軸（ＭＤ）方向に繊維が多く配向する傾向にあるが、例えば繊維をネット上
に振り落とす際に機械軸と垂直（ＣＤ）方向に振動を与えることにより繊維の配向状態を
制御することが可能である。
Further, the liquid diffusion state coefficient is measured using the above-mentioned photograph at the time of liquid diffusion area measurement. Usually, since the liquid diffuses into an ellipse, the major axis a and minor axis b of the ellipse are measured. The liquid diffusion state coefficient c is calculated by the following method.
Liquid diffusion state coefficient c = b / a
The liquid diffusion state coefficient is a coefficient indicating the diffusion state when the liquid is dropped, and becomes circular when diffused in the same state in any direction. In this case, the liquid diffusion state coefficient is 1. Since the liquid diffusion state of the cleansing base material is considered to be isotropic from the viewpoint that it is not necessary to change the production method and the direction of use depending on the shape, the liquid diffusion state coefficient is 0.65 to 1.35. Is more preferable, and 0.75 to 1.25 is more preferable. The liquid diffusibility can be controlled by adjusting the orientation state of the fibers constituting the substrate. In the case of long-fiber non-woven fabrics, many fibers tend to be oriented in the machine axis (MD) direction due to the characteristics of the manufacturing method. For example, when the fibers are shaken off on the net, vibration is given in the direction perpendicular to the machine axis (CD). Thus, it is possible to control the orientation state of the fiber.
本発明の化粧用基材の表面を構成するセルロース長繊維不織布は、メーク落としの効果
を向上させたり、化粧液等をクッション層や吸収材層へ速やかに移行させる観点や意匠の
観点から、開孔部のあるメッシュ調や開孔部による模様や凹凸による模様が形成されてい
てもよい。開孔部の形状は特に限定されないが、強度や柔軟性の観点から開孔部の平均面
積は０．１〜２ｍｍ２が好ましく、更に好ましくは０．２〜１ｍｍ２である。開孔部の平
均面積が０．１ｍｍ２未満では通液速度が低下することがある。開孔部の平均面積が２ｍ
ｍ２を超えると開孔部によるメークの掻き取り効果が減少し、メーク落としの効果が開孔
部があるものに比べて低下することがある。また、表面材全体に占める開孔部の面積率は
３〜２５％が好ましく、更に好ましくは１０〜２０％である。表面材全体に占める開孔部
の面積率が３％未満の場合は通液効果が減少することがある。表面材全体に占める開孔部
の面積率が２５％を超えると湿潤時の強度が低下し、ヨレ等の形態保持性に問題が生じる
ことがある。
The cellulose long-fiber nonwoven fabric constituting the surface of the cosmetic base material of the present invention is improved from the viewpoint of improving the effect of make-up removal, promptly transferring cosmetic liquid, etc. to the cushion layer or absorbent layer, and design. A mesh pattern with holes, a pattern with openings, or a pattern with irregularities may be formed. The shape of the openings is not particularly limited, the average area of the openings in terms of strength and flexibility is preferably 0.1 to 2 mm 2, more preferably from 0.2 to 1 mm 2. If the average area of the apertures is less than 0.1 mm 2 , the liquid passing speed may decrease. The average area of the opening is 2m
It exceeds m 2 when reduced makeup scraping effect by the openings, the effect of dropping the make is reduced as compared to what has openings. Moreover, 3-25% of the area ratio of the opening part which occupies for the whole surface material is preferable, More preferably, it is 10-20%. When the area ratio of the opening portion in the entire surface material is less than 3%, the liquid passing effect may be reduced. If the area ratio of the apertures in the entire surface material exceeds 25%, the strength when wet is lowered, and there may be a problem in form retention such as twisting.
開孔部がある場合にはクッション層や吸収材層の繊維等が表面に出ないようにセルロー
ス長繊維不織布を２枚重ねて表面層としたり、他の不織布がセルロース長繊維不織布とク
ッション層や吸収材層の間に入っていてもよい。
本発明のセルロース長繊維不織布は、前記条件を満足していれば複合されていてもよい
。例えば、保液性を向上させるため、繊維径の異なるセルロース長繊維不織布を水流交絡
等で複合してもよい。この場合、繊維径の異なる繊維が表面に出ることがあるが、前記条
件の範囲内であれば効果に影響はない。
When there is an open part, two cellulose long fiber nonwoven fabrics are stacked to form a surface layer so that the fibers of the cushion layer and absorbent layer do not appear on the surface, and other nonwoven fabrics are cellulose long fiber nonwoven fabrics and cushion layers. It may be interposed between the absorbent layers.
The cellulose long fiber nonwoven fabric of the present invention may be combined as long as the above conditions are satisfied. For example, in order to improve liquid retention, cellulose long fiber nonwoven fabrics having different fiber diameters may be combined by hydroentanglement. In this case, fibers with different fiber diameters may come out on the surface, but the effect is not affected as long as they are within the range of the above conditions.
本発明の化粧用基材は、少なくとも表面を構成する繊維本数の６０％以上が繊維径２．
９〜７．１μｍのセルロース長繊維であるセルロース長繊維不織布のみからなるものであ
っても良く、更なる強度保持、形態保持、熱接着性の付与のため、熱可塑性の不織布や繊
維等が拭き取り面でない面に複合されていてもよい。
The cosmetic base material of the present invention has a fiber diameter of at least 60% of the number of fibers constituting the surface.
It may be composed only of cellulose long-fiber non-woven fabrics, which are 9 to 7.1 μm long cellulose fibers, and wipes away thermoplastic non-woven fabrics and fibers for further strength retention, form retention, and thermal adhesion. It may be combined with a non-surface surface.
本発明の化粧用基材は、単独でパフ等として用いることもでき、例えば表面材として本
発明の化粧用基材を用い、これに挟まれるような構造で短繊維やクリンプ等のついた捲縮
繊維などが中綿として用いられてパフが形成されていてもよい。中綿はバルキー性やソフ
トさ、化粧液等を保液するのに有効である。このようなパフは上記のように基材及び中綿
を配置し、熱接着や圧着することで得ることができる。熱接着する場合には、ヒートシー
ル性のある低融点の微粉末を拭き取り面の裏面に散布固定したり、中綿に熱融着性の繊維
を用いればよい。何れの形態においても拭き取り面が本発明の化粧用基材で構成されてい
れば汚れ落としの効果やメーク落としの効果、湿潤時の形態保持性が従来品よりも格段に
向上する。
The cosmetic base material of the present invention can be used alone as a puff or the like. For example, the cosmetic base material of the present invention is used as a surface material, and the structure is sandwiched between the base material and has a short fiber or a crimp. A puff may be formed by using compressed fibers or the like as batting. Filling is effective for retaining bulkiness, softness, and cosmetic liquid. Such a puff can be obtained by arranging the base material and the batting as described above, and performing thermal bonding or pressure bonding. In the case of heat bonding, a heat-sealable low melting point fine powder may be sprayed and fixed on the back surface of the wiping surface, or a heat-sealable fiber may be used for the batting. In any form, if the wiping surface is composed of the base material for makeup of the present invention, the effect of removing dirt, the effect of removing makeup, and the form retainability when wet are remarkably improved as compared with the conventional product.
また、本発明の化粧用基材は化粧用落とし用の薬液が含浸された状態で供給される、い
わゆるウエットのメーク落とし商品、皮膚洗浄用シートの基材としても最適である。
皮膚洗浄用シートには、薬液を充分に保持する機能と拭取り性と拭き拭取り時の形態保
持性が要求されるが、本発明の化粧用基材は前述の理由で上記の機能性を全て満足する極
めて有効な基材である。
本発明の化粧用基材からなる皮膚洗浄用シートに含浸される薬液は、通常のメーク落と
しのウエット商品に使用される薬液を用いればよい。例えば、薬液には化粧落とし用の活
性剤、例えばＧラウリン酸ＰＥＧ−１２等の親油性乳化剤や、保湿剤、抗菌剤、防腐剤、
香料などが水やアルコール水溶液に含まれていてもよい。
The cosmetic base material of the present invention is also optimal as a base material for so-called wet make-up products and skin cleaning sheets, which are supplied in the state of being impregnated with a chemical solution for cosmetic removal.
The skin cleaning sheet is required to have a function of sufficiently retaining a chemical solution, a wiping property, and a shape retaining property at the time of wiping, but the cosmetic base material of the present invention has the above-described functionality for the reasons described above. It is a very effective substrate that satisfies all.
As the chemical solution impregnated in the skin cleansing sheet comprising the cosmetic base material of the present invention, a chemical solution used for ordinary make-up wet products may be used. For example, the chemical solution includes an active agent for makeup removal, for example, a lipophilic emulsifier such as G lauric acid PEG-12, a moisturizer, an antibacterial agent, an antiseptic,
A fragrance | flavor etc. may be contained in water or alcohol aqueous solution.
また、皮膚洗浄用シートは１００〜４００質量％の薬液が含浸された状態で供給される
ことが好ましい。より好ましくは１５０〜３５０質量％の薬液が含浸された状態である。
含浸される薬液量が１００質量％未満であると保存中に薬液が蒸発し、ウエット状態を保
つことができなかったり、清拭時の拭き取り効果が低下することがある。含浸される薬液
量が４００質量％を越えると、使用時に薬液が垂れて服等を汚したり、薬液のコストが高
くなり経済的な問題を生じることがある。
Further, the skin cleaning sheet is preferably supplied in a state of being impregnated with 100 to 400% by mass of a chemical solution. More preferably, the state is impregnated with 150 to 350% by mass of a chemical solution.
When the amount of the impregnating chemical solution is less than 100% by mass, the chemical solution evaporates during storage, and the wet state may not be maintained, or the wiping effect during wiping may be reduced. If the amount of the impregnating chemical solution exceeds 400% by mass, the chemical solution may drip at the time of use and stain clothes or the like, and the cost of the chemical solution may increase, resulting in an economical problem.
本発明を実施例に基づいて説明する。
尚、実施例中の評価は以下の方法で行った。
（１）拭き取り性
鏡の上に口紅を塗り、更にティッシュ等で塗り広げて出来る限り均一な油膜を作成する
。標準品としてカネボウ合繊株式会社製クリーンルーム用ワイピングクロス「ザヴィーナ
ミニマックス（商品名）」と日本薬局方綿ガーゼを用意する。基材１枚を取り、親指と人
差し指と中指で保持し、人差し指の腹で油膜を１回拭き取る。同程度の力で各基材を用い
て拭き取りを実施し、拭き取り性を官能評価し下記のように級判定を行う。各基材につい
て５回の評価を行い、平均値を結果とした。
１０級：油膜がほぼ完全に拭き取れる（「ザヴィーナミニマックス（商品名）」で拭き取
った状態に相当）。
５級：油膜はそこそこ拭き取れているが筋状の拭き残しがある。
１級：油膜は殆ど拭き取れず、伸ばされた感じである（日本薬局方ガーゼで拭き取った状
態に相当）。
尚、１〜１０級の間は相対的に見て中間の級を補間する。６級以上であれば合格とする
。
The present invention will be described based on examples.
In addition, evaluation in an Example was performed with the following method.
(1) Wipeability Apply lipstick on the mirror and spread it with a tissue to create an oil film that is as uniform as possible. We prepare Kanebo Synthetic Co., Ltd. clean room wiping cloth “Zavina Minimax (trade name)” and Japanese Pharmacopoeia Cotton Gauze as standard products. Take one substrate, hold it with the thumb, index finger and middle finger, and wipe the oil film once with the belly of the index finger. Wiping is performed using each base material with the same level of force, and the wiping performance is sensory evaluated and the grade is determined as follows. Each substrate was evaluated 5 times, and the average value was taken as the result.
Grade 10: The oil film can be wiped off almost completely (equivalent to the state where it was wiped off with “Zavina Minimax (trade name)”).
Grade 5: The oil film has been wiped off properly, but there are streaks.
First grade: The oil film is hardly wiped off and feels stretched (corresponding to the state wiped off with Japanese Pharmacopoeia gauze).
In addition, the intermediate class is interpolated relatively between the first to tenth classes. If it is grade 6 or higher, it will be accepted.
（２）液拡散面積及び液拡散状態係数
前述の方法で測定、算出した。
（３）湿潤時の形態安定性
前述の方法で測定した。
（４）脱落繊維
試料を３００ｍｌの純水に浸し、１５分間超音波を当てた後にワイパーを取り出す。こ
の液を黒色に着色された濾紙を用いて濾過し、濾紙上に残されたファイバー状のワイパー
からの脱落物を測定する。長さが１００μｍ以上のものを数えて、試料１ｍ２当たりに換
算して記録する。
(2) Liquid diffusion area and liquid diffusion state coefficient It measured and calculated by the above-mentioned method.
(3) Morphological stability when wet It was measured by the method described above.
(4) Dropping fiber The sample is immersed in 300 ml of pure water, subjected to ultrasonic waves for 15 minutes, and then the wiper is taken out. This liquid is filtered using a filter paper colored in black, and the fallen matter from the fiber-like wiper remaining on the filter paper is measured. A sample having a length of 100 μm or more is counted and recorded per 1 m 2 of the sample.
［実施例１］
コットンリンターを銅アンモニア溶液で溶解し、直径０．３ｍｍの原液吐出孔が１８０
．９個／ｃｍ２である紡口を用い、流下緊張下で連続してネット上に５層重ねで紡糸して
シートを形成させ、高圧水流により繊維を交絡させながらシートに貫通孔及び凹部を形成
させた後、乾燥させて再生セルロース連続長繊維不織布を得た。得られた再生セルロース
連続長繊維不織布は、目付１８．７ｇ／ｍ２、厚み０．１３ｍｍ、平均単繊維径が３．２
μｍ、貫通孔の平均面積０．２５３ｍｍ２、シート表面に占める貫通孔の面積率が１５．
３％であり、繊維径２．９〜７．１μｍの単繊維が表面に占める割合は１００％であった
。
得られた再生セルロース連続長繊維不織布からなる化粧用基材の性能評価結果を表１に
示す。表からもわかるとおり、得られた再生セルロース連続長繊維不織布は化粧用基材と
して極めて良好なものであった。
[Example 1]
Cotton linter was dissolved with copper ammonia solution, and the stock solution discharge hole with a diameter of 0.3mm was 180
. Using a spout of 9 pieces / cm 2 , a sheet is formed by spinning five layers on the net continuously under flow tension, and through holes and recesses are formed in the sheet while the fibers are entangled by high-pressure water flow. Then, it was dried to obtain a regenerated cellulose continuous long fiber nonwoven fabric. The obtained regenerated cellulose continuous long-fiber nonwoven fabric has a basis weight of 18.7 g / m 2 , a thickness of 0.13 mm, and an average single fiber diameter of 3.2.
μm, the average area of the through holes is 0.253 mm 2 , and the area ratio of the through holes in the sheet surface is 15.
3%, and the ratio of the single fiber having a fiber diameter of 2.9 to 7.1 μm to the surface was 100%.
Table 1 shows the performance evaluation results of the base material for makeup made of the obtained regenerated cellulose continuous long fiber nonwoven fabric. As can be seen from the table, the obtained regenerated cellulose continuous long-fiber nonwoven fabric was extremely good as a cosmetic base material.
［実施例２］
原液の吐出量を増加させた以外は実施例１と同様の方法で再生セルロース連続長繊維不
織布を得た。得られた再生セルロース連続長繊維不織布は、目付２９．３ｇ／ｍ２、厚み
０．２２ｍｍ、平均単繊維径が６．８μｍ、貫通孔の平均面積０．２９５ｍｍ２、シート
表面に占める貫通孔の面積率が１４．９％であり、繊維径２．９〜７．１μｍの単繊維が
表面に占める割合は１００％であった。
得られた再生セルロース連続長繊維不織布からなる化粧用基材の性能評価結果を表１に
示す。表からもわかるとおり、得られた再生セルロース連続長繊維不織布は化粧用基材と
して極めて良好なものであった。
[Example 2]
A regenerated cellulose continuous long-fiber nonwoven fabric was obtained in the same manner as in Example 1 except that the discharge amount of the stock solution was increased. The obtained regenerated cellulose continuous long-fiber nonwoven fabric has a basis weight of 29.3 g / m 2 , a thickness of 0.22 mm, an average single fiber diameter of 6.8 μm, an average area of through holes of 0.295 mm 2 , The area ratio was 14.9%, and the ratio of single fibers having a fiber diameter of 2.9 to 7.1 μm on the surface was 100%.
Table 1 shows the performance evaluation results of the base material for makeup made of the obtained regenerated cellulose continuous long fiber nonwoven fabric. As can be seen from the table, the obtained regenerated cellulose continuous long-fiber nonwoven fabric was extremely good as a cosmetic base material.
［実施例３］
実施例１において、積層するシートの１層目と５層目は直径０．３ｍｍの原液吐出孔が
１８０．９個／ｃｍ２である紡口を用い、２〜４層目は直径０．６ｍｍの原液吐出孔が４
５．３個／ｃｍ２である紡口を用い、紡糸されたシートを積層するネットのスピードを遅
くした以外は実施例１と同様の方法で再生セルロース連続長繊維不織布を得た。得られた
再生セルロース連続長繊維不織布は、目付２８．９ｇ／ｍ２、厚み０．２３ｍｍ、平均単
繊度が３．２μｍと１１．８μｍの２種類であり、貫通孔の平均面積０．２８３ｍｍ２、
シート表面に占める貫通孔の面積率が１９．４％であり、繊維径２．９〜７．１μｍの単
繊維が表面に占める割合は７３％であった。
得られた再生セルロース連続長繊維不織布からなる化粧用基材の性能評価結果を表１に
示す。表からもわかるとおり、得られた再生セルロース連続長繊維不織布は化粧用基材と
して極めて良好なものであった。
[Example 3]
In Example 1, the first and fifth layers of the sheets to be laminated use a spinning nozzle having a stock solution discharge hole with a diameter of 0.3 mm of 180.9 holes / cm 2 , and the second to fourth layers have a diameter of 0.6 mm. 4 stock solution discharge holes
A regenerated cellulose continuous long-fiber non-woven fabric was obtained in the same manner as in Example 1 except that a spout of 5.3 pieces / cm 2 was used and the speed of the net for laminating the spun sheets was reduced. The obtained regenerated cellulose continuous long-fiber nonwoven fabric has two weights of 28.9 g / m 2 in basis weight, thickness of 0.23 mm, average single fineness of 3.2 μm and 11.8 μm, and average through-hole area of 0.283 mm 2. ,
The area ratio of through-holes occupying the sheet surface was 19.4%, and the ratio of single fibers having a fiber diameter of 2.9 to 7.1 μm occupying the surface was 73%.
Table 1 shows the performance evaluation results of the base material for makeup made of the obtained regenerated cellulose continuous long fiber nonwoven fabric. As can be seen from the table, the obtained regenerated cellulose continuous long-fiber nonwoven fabric was extremely good as a cosmetic base material.
［比較例１］
実施例１において直径０．６ｍｍの原液吐出孔が４５．３個／ｃｍ２である紡口を用い
た以外は実施例１と同様の方法で再生セルロース連続長繊維不織布を得た。得られた再生
セルロース連続長繊維不織布は、目付１８．５ｇ／ｍ２、厚み０．１３ｍｍ、平均単繊維
径が１１．８μ、貫通孔の平均面積０．２１５ｍｍ２、シート表面に占める貫通孔の面積
率が１９．０％であり、繊維径２．９〜７．１μｍの単繊維が表面に占める割合は０％で
あった。
得られた再生セルロース連続長繊維不織布からなる化粧用基材の性能評価結果を表１に
示す。表からもわかるとおり、得られた再生セルロース連続長繊維不織布は化粧用基材と
して実施例に比べて湿潤時の形態保持性と拭き取り性が劣るものであった。
[Comparative Example 1]
A regenerated cellulose continuous long-fiber nonwoven fabric was obtained in the same manner as in Example 1 except that a spinning nozzle having a diameter of 0.6 mm of stock solution discharge holes of 45.3 holes / cm 2 was used in Example 1. The obtained regenerated cellulose continuous long-fiber nonwoven fabric has a basis weight of 18.5 g / m 2 , a thickness of 0.13 mm, an average single fiber diameter of 11.8 μm, an average area of through holes of 0.215 mm 2 , The area ratio was 19.0%, and the ratio of monofilaments having a fiber diameter of 2.9 to 7.1 μm on the surface was 0%.
Table 1 shows the performance evaluation results of the base material for makeup made of the obtained regenerated cellulose continuous long fiber nonwoven fabric. As can be seen from the table, the obtained regenerated cellulose continuous long fiber nonwoven fabric was inferior in form retention and wiping property when wet as a cosmetic base material compared to Examples.
［実施例４］
Ｇラウリン酸ＰＥＧ−１２をベースとする、市販のメイク落としに用いられているもの
と同様の薬液を、実施例１で得た再生セルロース連続長繊維不織布に２５０重量％含浸さ
せ皮膚洗浄用シートを得た。
得られた皮膚洗浄用シートを用いて化粧をした２０歳代の女性１０名にメイク落としの
効果を従来のコットン系ウエブ使用の洗浄シートと比較したところ、全員がメイク落とし
の効果が向上すると共に、基材から肌への繊維の脱落が大幅に減少したとの官能評価であ
った。
[Example 4]
A skin cleansing sheet was impregnated with 250% by weight of the regenerated cellulose continuous long-fiber non-woven fabric obtained in Example 1 using a chemical solution similar to that used for a commercial makeup remover based on G lauric acid PEG-12. Obtained.
When the effect of makeup removal was compared with a cleaning sheet using a conventional cotton web for 10 women in their 20s who applied makeup using the obtained skin cleaning sheet, the effect of makeup removal was improved for all. It was a sensory evaluation that the loss of fibers from the base material to the skin was greatly reduced.
本発明の化粧用基材は、メーク汚れや皮脂汚れの拭き取り性が極めて良好で、化粧液の
拡散性が良好で、皮膚への基材からの汚染が少なく、保液性及び湿潤状態における形態安
定性に優れ、皮膚への物理刺激性が低いパフ等の化粧用基材と極めて有効である。また、
薬液が含浸された皮膚洗浄用シートとしても同様の理由で極めて有効である。
The cosmetic base material of the present invention has very good wiping off of makeup stains and sebum stains, good diffusibility of the cosmetic liquid, little contamination from the base material to the skin, liquid retention and form in a wet state It is extremely effective with cosmetic base materials such as puffs that have excellent stability and low physical irritation to the skin. Also,
For the same reason, it is extremely effective as a skin cleaning sheet impregnated with a chemical solution.
Claims (3)
数の６０％以上が繊維径２．９〜７．１μｍのセルロース長繊維であり、該不織布の開孔
部の平均面積が０．１〜２ｍｍ２であり、開孔部の面積率が３〜２５％であり、湿潤形態
保持率が８０％以上であり、液拡散状態係数が０．６５〜１．３５、液拡散面積が４．１
〜８．６ｃｍ ２ であることを特徴とする化粧用基材。 The surface is a cellulose long fiber nonwoven fabric, and at least 60% of the number of fibers constituting the surface of the nonwoven fabric is cellulose long fibers having a fiber diameter of 2.9 to 7.1 μm, and the average area of the pores of the nonwoven fabric There is a 0.1 to 2 mm 2, the area ratio 3 to 25% of the opening state, and are wet form retention of 80% or more, a liquid distribution condition coefficient is 0.65 to 1.35, the liquid The diffusion area is 4.1
~8.6cm 2 der Rukoto cosmetic base material which is characterized in.
化粧用基材。 The cosmetic base material according to claim 1, wherein the nonwoven fabric is a regenerated cellulose continuous long-fiber nonwoven fabric.
浄用シート。 A skin cleaning sheet, wherein the cosmetic base material according to claim 1 or 2 is impregnated with a chemical solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009205575A JP2009297535A (en) | 2009-09-07 | 2009-09-07 | Cosmetic base material and skin cleansing sheet using this |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009205575A JP2009297535A (en) | 2009-09-07 | 2009-09-07 | Cosmetic base material and skin cleansing sheet using this |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004059545A Division JP4873836B2 (en) | 2004-03-03 | 2004-03-03 | Cosmetic base material and skin cleaning sheet using the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2009297535A true JP2009297535A (en) | 2009-12-24 |
Family
ID=41545010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009205575A Pending JP2009297535A (en) | 2009-09-07 | 2009-09-07 | Cosmetic base material and skin cleansing sheet using this |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2009297535A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012214922A (en) * | 2011-03-31 | 2012-11-08 | Kuraray Kuraflex Co Ltd | Laminated sheet and method of manufacturing the same |
| JP2013192700A (en) * | 2012-03-19 | 2013-09-30 | Oji Kinocloth Co Ltd | Cosmetic puff and method for producing the same |
| JP2015159842A (en) * | 2014-02-26 | 2015-09-07 | 一心堂本舗株式会社 | Base material sheet for cosmetic pack, cosmetic pack material prepared using the same, and method of producing cosmetic pack material |
| JP2016104322A (en) * | 2016-03-02 | 2016-06-09 | 一心堂本舗株式会社 | Base material sheet for cosmetic pack, cosmetic pack material prepared therewith, and method for producing cosmetic pack material |
| WO2019240224A1 (en) * | 2018-06-15 | 2019-12-19 | 株式会社タイキ | Carrier for cosmetic product impregnation |
| JP2020515737A (en) * | 2017-04-03 | 2020-05-28 | レンツィング アクツィエンゲゼルシャフト | Non-woven cellulose fiber cloth with liquid wicking capacity according to the situation |
| WO2020226181A1 (en) | 2019-05-09 | 2020-11-12 | 旭化成株式会社 | Recycled cellulosic fiber nonwoven fabric, chemical impregnation sheet, and face mask |
| JP2021023669A (en) * | 2019-08-07 | 2021-02-22 | ダイワボウホールディングス株式会社 | Non-woven fabric for liquid impregnated skin covering sheet, manufacturing method therefor, liquid impregnated skin covering sheet, and face mask |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001314342A (en) * | 2000-05-08 | 2001-11-13 | Lion Corp | Skin cleaning sheet |
-
2009
- 2009-09-07 JP JP2009205575A patent/JP2009297535A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001314342A (en) * | 2000-05-08 | 2001-11-13 | Lion Corp | Skin cleaning sheet |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012214922A (en) * | 2011-03-31 | 2012-11-08 | Kuraray Kuraflex Co Ltd | Laminated sheet and method of manufacturing the same |
| JP2013192700A (en) * | 2012-03-19 | 2013-09-30 | Oji Kinocloth Co Ltd | Cosmetic puff and method for producing the same |
| JP2015159842A (en) * | 2014-02-26 | 2015-09-07 | 一心堂本舗株式会社 | Base material sheet for cosmetic pack, cosmetic pack material prepared using the same, and method of producing cosmetic pack material |
| JP2016104322A (en) * | 2016-03-02 | 2016-06-09 | 一心堂本舗株式会社 | Base material sheet for cosmetic pack, cosmetic pack material prepared therewith, and method for producing cosmetic pack material |
| JP7005740B2 (en) | 2017-04-03 | 2022-01-24 | レンツィング アクツィエンゲゼルシャフト | Non-woven cellulose fiber fabrics, methods, equipment, and products or complexes with improved oil absorption capacity |
| JP2020515737A (en) * | 2017-04-03 | 2020-05-28 | レンツィング アクツィエンゲゼルシャフト | Non-woven cellulose fiber cloth with liquid wicking capacity according to the situation |
| JPWO2019240224A1 (en) * | 2018-06-15 | 2021-07-26 | 株式会社タイキ | Carrier for cosmetic impregnation |
| CN112469308A (en) * | 2018-06-15 | 2021-03-09 | 株式会社黛怡茜 | Cosmetic material impregnation carrier |
| WO2019240224A1 (en) * | 2018-06-15 | 2019-12-19 | 株式会社タイキ | Carrier for cosmetic product impregnation |
| WO2020226181A1 (en) | 2019-05-09 | 2020-11-12 | 旭化成株式会社 | Recycled cellulosic fiber nonwoven fabric, chemical impregnation sheet, and face mask |
| JPWO2020226181A1 (en) * | 2019-05-09 | 2021-11-18 | 旭化成株式会社 | Regenerated cellulose fiber non-woven fabric, chemical impregnated sheet, and face mask |
| JP7101879B2 (en) | 2019-05-09 | 2022-07-15 | 旭化成株式会社 | Regenerated cellulose fiber non-woven fabric, chemical impregnated sheet, and face mask |
| JP2021023669A (en) * | 2019-08-07 | 2021-02-22 | ダイワボウホールディングス株式会社 | Non-woven fabric for liquid impregnated skin covering sheet, manufacturing method therefor, liquid impregnated skin covering sheet, and face mask |
| JP7497964B2 (en) | 2019-08-07 | 2024-06-11 | 大和紡績株式会社 | Nonwoven fabric for liquid-impregnated skin covering sheet and manufacturing method thereof, liquid-impregnated skin covering sheet, and face mask |
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