WO2014166021A1 - 一种含硅与铝的铜基合金管及其制备方法 - Google Patents

一种含硅与铝的铜基合金管及其制备方法 Download PDF

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WO2014166021A1
WO2014166021A1 PCT/CN2013/000795 CN2013000795W WO2014166021A1 WO 2014166021 A1 WO2014166021 A1 WO 2014166021A1 CN 2013000795 W CN2013000795 W CN 2013000795W WO 2014166021 A1 WO2014166021 A1 WO 2014166021A1
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alloy tube
copper
total weight
alloy
annealing
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PCT/CN2013/000795
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English (en)
French (fr)
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孙飞
赵勇
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苏州金仓合金新材料有限公司
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Publication of WO2014166021A1 publication Critical patent/WO2014166021A1/zh

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/04Alloys based on copper with zinc as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/06Alloys containing less than 50% by weight of each constituent containing zinc

Definitions

  • the present invention relates to the field of alloy pipes, and in particular to a copper-based alloy pipe containing silicon and aluminum and a preparation method thereof.
  • Lead-containing copper alloys have good cutting performance and anti-friction and wear resistance, mainly because lead exists in a single item in a copper alloy, and performs good chip breaking during cutting; in a friction and wear environment, Since the shear strength of lead is very low, the lead on the surface of the copper alloy part makes the friction coefficient of the lead-containing copper alloy relatively low, so the lead element is more commonly used in the brass alloy.
  • lead is one of the chemicals that seriously endanger human life and the natural environment.
  • Lead in alloys can easily escape or escape from the matrix during use.
  • Lead in industrial wastes penetrates into groundwater systems, and various forms of lead. Entering the animal or human food chain through various means, endangering human health and affecting the environment.
  • the object of the present invention is to provide a copper-based alloy tube containing silicon and aluminum and a preparation method thereof, and the invention can satisfy the requirements of lead-free environmental protection performance while ensuring the material at the same time without increasing the cost. Requirements for cutting performance and mechanical physical properties in the application.
  • a copper-based alloy tube containing silicon and aluminum consisting of the following components: copper of 50-55% of the total weight of the alloy tube, 1-1.5% of the total weight of the alloy tube, accounting for 0.05-0.5 of the total weight of the alloy tube % aluminum, the balance is zinc.
  • the alloy tube is composed of the following components: copper, which accounts for 50% of the total weight of the alloy tube, and accounts for the total weight of the alloy tube.
  • the amount of silicon is 1%, and the total weight of the alloy tube is 0.05% of aluminum.
  • the balance is zinc.
  • the alloy tube is composed of the following components: copper which accounts for 55% of the total weight of the alloy tube, silicon which accounts for 1.5% of the total weight of the alloy tube, and aluminum which accounts for 0.5% of the total weight of the alloy tube, and the balance is zinc.
  • it is composed of the following components: 52.5% of the total weight of the alloy tube, 1.25% of the total weight of the alloy tube, and 0.275% of the total weight of the alloy tube, and the balance is zinc.
  • the copper is electrolytic copper.
  • the invention provides a method for preparing a novel lead-free copper-based alloy tube, which comprises the following steps:
  • Annealing before extrusion annealing the alloy tube with a box annealing furnace: annealing temperature is 300-350 degrees, annealing time is 1.5-2 hours, the hardness of the alloy tube is reduced to 60-70HB, so as to facilitate extrusion ;
  • the spectrometer described in step 3 uses a Spike direct reading spectrometer.
  • step 3 the number of component inspections in step 3 is 3-6 times.
  • the invention has the beneficial effects that the present invention provides a copper-based alloy tube containing silicon and aluminum and a preparation method thereof, which utilizes silicon and aluminum elements instead of lead elements to form a dispersed phase of a separate phase in a copper alloy. These phases allow the present invention to act as a chip breaking during cutting, thereby improving the cutting performance of the copper alloy and complying with environmentally healthy standards.
  • BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in conjunction with the embodiments, but it is not intended to limit the scope of application of the present invention.
  • a copper-based alloy tube containing silicon and aluminum consisting of the following components: copper, which accounts for 50% of the total weight of the alloy tube, accounts for 1% of the total weight of the alloy tube, and accounts for 0.05% of the total weight of the alloy tube.
  • copper which accounts for 50% of the total weight of the alloy tube, accounts for 1% of the total weight of the alloy tube, and accounts for 0.05% of the total weight of the alloy tube.
  • zinc For zinc.
  • the electrolytic copper, silicon, aluminum and zinc are placed in a power frequency electric furnace, heated to 1150-1200 degrees, completely melted and then kept to 1100 degrees; after fully melting the completely melted alloy liquid with a graphite rod, It is covered with high-purity flaky graphite powder to prevent its oxidation, and its thickness is about 10-15cm. After 1-1.5 hours of heat preservation, the sample taken from the furnace is tested 3-6 times with the imported Spike direct reading spectrometer imported from Germany.
  • the surface-processed alloy tube is extruded with a 2,500-ton single-action extruder: wherein the temperature of the alloy ingot is 180-200 degrees, the extrusion temperature is 400 degrees, and the extrusion speed is 15 mm. /s, after multiple extrusions, the outer diameter of the alloy tube is 185 mm ⁇ l mm.
  • the inner diameter is 165mm ⁇ l mm; after the final annealing treatment, the extruded alloy tube is annealed in a box annealing furnace: annealing temperature is 100-200 degrees, annealing time is 1.5-2 hours; final flaw detection, annealing The completed copper tube is inspected, the flaw detection ratio is 100%, and the product with the flaw detection is cut into a finished product with a length of 300 mm ⁇ l mm for packaging and storage.
  • the copper-based alloy tube containing silicon and aluminum provided by the embodiment has good cutting performance, good workability, good wear resistance, simple preparation process and cost. Low, no pollution to the environment.
  • a copper-based alloy tube containing silicon and aluminum which is composed of the following components: copper which accounts for 55% of the total weight of the alloy tube, silicon which accounts for 1.5% of the total weight of the alloy tube, and aluminum which accounts for 0.5% of the total weight of the alloy tube, balance For zinc.
  • the electrolytic copper, silicon, aluminum and zinc are placed in a power frequency electric furnace, heated to 1150-1200 degrees, completely melted and then kept to 1100 degrees; after fully melting the completely melted alloy liquid with a graphite rod, It is covered with high-purity flaky graphite powder to prevent its oxidation, and its thickness is about 10-15cm. After 1-1.5 hours of heat preservation, the sample taken from the furnace is tested 3-6 times with the imported Spike direct reading spectrometer imported from Germany.
  • the surface-processed alloy tube is extruded with a 2,500-ton single-action extruder: wherein the temperature of the alloy ingot is 180-200 degrees, the extrusion temperature is 400 degrees, and the extrusion speed is 15 mm. /s, after multiple extrusions, the outer diameter of the alloy tube is 185 mm ⁇ l mm, and the inner diameter is 165 mm ⁇ l mm; after that, the finished alloy is annealed, and the extruded alloy tube is annealed by a box annealing furnace.
  • Annealing temperature is 100-200 degrees, annealing time is 1.5-2 hours; final flaw detection, the annealed copper tube is tested, the flaw detection ratio is 100%, and the qualified product is cut into finished products with length 300mm ⁇ l mm Pack into the warehouse.
  • the copper-based alloy tube containing silicon and aluminum provided by the embodiment improves the cutting performance of the brass, and the production process is simple, the cost is low, and It will pollute the environment.
  • the total weight of the alloy tube is 52.5% of copper, accounting for 1.25% of the total weight of the alloy tube, and the total weight of the alloy tube is 0.275% of aluminum.
  • the balance is zinc.
  • the electrolytic copper, silicon, aluminum and zinc are placed in a power frequency electric furnace, heated to 1150-1200 degrees, completely melted and then kept to 1100 degrees; after fully melting the completely melted alloy liquid with a graphite rod, It is covered with high-purity flaky graphite powder to prevent its oxidation, and its thickness is about 10-15cm. After 1-1.5 hours of heat preservation, the sample taken from the furnace is tested 3-6 times with the imported Spike direct reading spectrometer imported from Germany.
  • alloy tube with a length of 500 mm ⁇ l mm; the surface treated alloy tube is extruded with a 2,500 ton single-action extruder: wherein the temperature of the alloy ingot is 180-200 degrees and the extrusion temperature is 400 degrees The extrusion speed is 15mm/s. After multiple extrusions, the outer diameter of the alloy tube is 185mm ⁇ l mm, and the inner diameter is 165mm ⁇ l mm. After that, the finished product is annealed and pressed by a box annealing furnace.
  • Annealing of the alloy tube annealing temperature is 100-200 degrees, annealing time is 1.5-2 hours; final flaw detection, the annealed copper tube is tested, the flaw detection ratio is 100%, and the qualified product is cut into length
  • the finished product of 300mm ⁇ l mm is packaged and stored.
  • the copper-based alloy tube containing silicon and aluminum provided by the embodiment improves the cutting performance of the brass, and the production process is simple, the cost is low, and It will pollute the environment.
  • the invention provides a copper-based alloy tube containing silicon and aluminum and an existing lead-containing alloy tube
  • the mechanical properties are shown in Table 1.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Extrusion Of Metal (AREA)
  • Conductive Materials (AREA)

Abstract

一种含硅与铝的铜基合金管及其制备方法,该合金管由以下组份组成:占合金管总重量50-55%的铜,占合金管总重量1-1.5%的硅,占合金管总重量0.05-0.5%的铝,余量为锌。在所述铜基合金中,硅和铝元素替代了铅元素,形成弥散分布的单独相,这些相在切削时具有断屑作用,从而改善了铜合金的切削加工性能,而且还符合环保健康标准。

Description

一种含硅与铝的铜基合金管及其制备方法 技术领域 本发明涉及合金管材领域, 具体涉及一种含硅与铝的铜基合金管及其 制备方法。 背景技术 含铅铜合金之所以具有好的切削性能和减摩耐磨性能,主要是由于铅 在铜合金中以单项存在, 在切削时起到良好的断屑作用; 在摩擦摩损环境 下, 由于铅的剪切强度非常低, 铜合金零件表面的铅使得含铅铜合金的摩 擦系数比较低, 所以, 铅元素在黄铜合金中较普遍使用。
然而铅是严重危害人类寿命与自然环境的化学物质之一,合金中的铅 在使用过程中极易从基体中侵出或脱出,工业废品中的含铅则渗入地下水 系统, 各种形式的铅通过各种途径进入动物或人的食物链, 危害人类的健 康, 影响环境。
由上可知,开发无铅铜合金成为了当今金属材料行业所面临的重大课 题, 也是响应世界循环经济 (EHS计划) 要求的重要工作。 发明内容
本发明的目的在于提供一种含硅与铝的铜基合金管及其制备方法,利 用本发明在不提高成本的基础上既满足了无铅环保性能的要求的同时, 又 能保证了材料在应用中对切削性能及机械物理性能的要求。
为了实现上述发明目的, 本发明采用的技术方案如下:
一种含硅与铝的铜基合金管, 由以下组份组成: 占合金管总重量 50-55%的铜, 占合金管总重量 1-1.5%的硅, 占合金管总重量 0.05-0.5%的 铝, 余量为锌。
优选地, 由以下组份组成: 占合金管总重量 50%的铜, 占合金管总重 量 1%的硅, 占合金管总重量 0.05%的铝, 余量为锌。
优选地, 由以下组份组成: 占合金管总重量 55%的铜, 占合金管总重 量 1.5%的硅, 占合金管总重量 0.5%的铝, 余量为锌。
优选地, 由以下组份组成: 占合金管总重量 52.5%的铜, 占合金管总 重量 1.25%的硅, 占合金管总重量 0.275%的铝, 余量为锌。
优选地, 铜为电解铜。
本发明提供的一种新型无铅铜基合金管的制备方法, 包括以下歩骤:
1 )按照配比将电解铜、硅、铝、锌置于工频电炉内,加热至 1150-1200 度, 待完全熔化后保温至 1100度;
2 ) 用石墨棒将完全熔化的合金液体充分搅拌后, 在其上面覆盖高纯 度鳞片石墨粉以防止其氧化, 厚度为 10-15cm;
3 ) 保温 1-1.5小时后, 用光谱仪对从炉内取出的样品进行成分检验, 确定其合金成分在规定的范围内;
4) 进一歩保温至 50-60分钟后, 重新升温至 1200度, 开启工频电炉 的振动装置, 采用水平连铸方法造成外径为 200mm, 内径为 150mm, 长 度为 550mm的空心毛坯合金管材;
5 ) 挤压前退火, 用箱式退火炉对合金管进行退火处理: 退火温度为 300-350度, 退火时间为 1.5-2小时, 使合金管的硬度下降至 60-70HB, 以 便于挤压;
6 ) 用铜锭铣床对退火后的毛坯合金管材进行表面加工, 加工为表面 外径为 190mm, 内径为 155mm, 长度为 500mm的合金管;
7 )挤压,采用 2500吨单动挤压机挤压,合金锭的加热温度为 180-200 度, 挤压温度为 400度, 挤压速度为 15mm/s, 多次挤压后合金管的外径 为 185mm, 公差为 +/-lmm, 内径为 165mm, 公差为 +/-lmm;
8 ) 成品退火, 用箱式退火炉对挤压后的合金管进行退火处理; 退火 温度为 100-200度, 退火时间为 1.5-2小时。
9) 探伤, 将退火处理后的合金管进行探伤, 探伤比例为 100%; 10 ) 将探伤合格的产品切割为长度 300mm的成品包装入库。
进一歩地, 歩骤 3 ) 中所述光谱仪采用斯派克直读光谱仪。
进一歩地, 歩骤 3 ) 中的成分检验次数为 3-6次。
本发明的有益效果是:本发明提供了一种含硅与铝的铜基合金管及其 制备方法,其利用硅和铝元素替代了铅元素在铜合金中形成弥散分布的单 独相, 形成的这些相使本发明在切削时起到断屑作用, 从而改善了铜合金 的切削加工性能, 而且还符合环保健康标准。 具体实施方式 以下结合实施例对本发明作进一歩说明,但并非限制本发明的应用范 围。
实施例 1
一种含硅与铝的铜基合金管, 由以下组份组成: 占合金管总重量 50% 的铜, 占合金管总重量 1%的硅, 占合金管总重量 0.05%的铝, 余量为锌。
按照上述配比将电解铜、硅、铝、锌置于工频电炉内,加热至 1150-1200 度, 完全熔化后保温至 1100度; 用石墨棒将完全熔化后的合金液体充分 搅拌后, 在其上面覆盖高纯度鳞片状石墨粉以防止其氧化, 其厚度约为 10-15cm; 保温 1-1.5小时后, 用德国进口斯派克直读光谱仪对从炉内取出 的样品进行 3-6次检验, 来确定其合金成分在规定范围之内; 进一歩保温 50-60分钟后, 重新升温至 1200度, 并开启工频电炉的振动装置, 采用水 平连铸方法铸造成外径为 200mm± l mm, 内径为 150mm± l mm,长度为 550mm± l mm的空心毛坯合金管材; 用箱式退火炉对毛坯合金管材进行 退火处理, 且退火温度为 300-350度, 退火时间为 1.5-2小时, 使其硬度 下降至 60-70HB, 以便于挤压; 用铜锭铣床对上述退火后的合金管材进行 表面力 B工, 加工为表面光洁直径为 190mm± l mm,内径为 155mm± l mm, 长度为 500mm± l mm的合金管; 将表面加工后的合金管用 2500吨的单 动挤压机挤压: 其中, 合金锭的温度为 180-200度, 挤压温度为 400度, 挤压速度为 15mm/s,进行多次挤压后,该合金管的外径为 185mm± l mm, 内径为 165mm± l mm; 之后进行成品退火处理, 用箱式退火炉对挤压后 的合金管进行退火处理: 退火温度为 100-200度, 退火时间为 1.5-2小时; 最后探伤, 将退火完成的铜管进行探伤, 探伤比例为 100%, 并将探伤合 格的产品切割为长度 300mm± l mm的成品进行包装入库。 与现有的含铅合铜基合金管相比,本实施例提供的一种含硅与铝的铜 基合金管切削性能好, 可加工性好, 耐磨性好, 且制备工艺简单, 成本低, 不会对环境造成污染。
实施例 2
一种含硅与铝的铜基合金管, 由以下组份组成: 占合金管总重量 55% 的铜, 占合金管总重量 1.5%的硅, 占合金管总重量 0.5%的铝, 余量为锌。
按照上述配比将电解铜、硅、铝、锌置于工频电炉内,加热至 1150-1200 度, 完全熔化后保温至 1100度; 用石墨棒将完全熔化后的合金液体充分 搅拌后, 在其上面覆盖高纯度鳞片状石墨粉以防止其氧化, 其厚度约为 10-15cm; 保温 1-1.5小时后, 用德国进口斯派克直读光谱仪对从炉内取出 的样品进行 3-6次检验, 来确定其合金成分在规定范围之内; 进一歩保温 50-60分钟后, 重新升温至 1200度, 并开启工频电炉的振动装置, 采用水 平连铸方法铸造成外径为 200mm± l mm, 内径为 150mm± l mm,长度为 550mm± l mm的空心毛坯合金管材; 用箱式退火炉对毛坯合金管材进行 退火处理, 且退火温度为 300-350度, 退火时间为 1.5-2小时, 使其硬度 下降至 60-70HB, 以便于挤压; 用铜锭铣床对上述退火后的合金管材进行 表面力 B工, 加工为表面光洁直径为 190mm± l mm,内径为 155mm± l mm, 长度为 500mm± l mm的合金管; 将表面加工后的合金管用 2500吨的单 动挤压机挤压: 其中, 合金锭的温度为 180-200度, 挤压温度为 400度, 挤压速度为 15mm/s,进行多次挤压后,该合金管的外径为 185mm± l mm, 内径为 165mm± l mm; 之后进行成品退火处理, 用箱式退火炉对挤压后 的合金管进行退火处理: 退火温度为 100-200度, 退火时间为 1.5-2小时; 最后探伤, 将退火完成的铜管进行探伤, 探伤比例为 100%, 并将探伤合 格的产品切割为长度 300mm± l mm的成品进行包装入库。 与现有的含铅合铜基合金管相比,本实施例提供的一种含硅与铝的铜 基合金管改善了黄铜的切削加工性能, 其生产工艺简单、 成本较低、 且不 会对环境造成污染。
实施例 3
占合金管总重量 52.5%的铜, 占合金管总重量 1.25%的硅, 占合金管 总重量 0.275%的铝, 余量为锌。
按照上述配比将电解铜、硅、铝、锌置于工频电炉内,加热至 1150-1200 度, 完全熔化后保温至 1100度; 用石墨棒将完全熔化后的合金液体充分 搅拌后, 在其上面覆盖高纯度鳞片状石墨粉以防止其氧化, 其厚度约为 10-15cm; 保温 1-1.5小时后, 用德国进口斯派克直读光谱仪对从炉内取出 的样品进行 3-6次检验, 来确定其合金成分在规定范围之内; 进一歩保温 50-60分钟后, 重新升温至 1200度, 并开启工频电炉的振动装置, 采用水 平连铸方法铸造成外径为 200mm± l mm, 内径为 150mm± l mm,长度为 550mm± l mm的空心毛坯合金管材; 用箱式退火炉对毛坯合金管材进行 退火处理, 且退火温度为 300-350度, 退火时间为 1.5-2小时, 使其硬度 下降至 60-70HB, 以便于挤压; 用铜锭铣床对上述退火后的合金管材进行 表面力 B工, 加工为表面光洁直径为 190mm± l mm,内径为 155mm± l mm, 长度为 500mm± l mm的合金管; 将表面加工后的合金管用 2500吨的单 动挤压机挤压: 其中, 合金锭的温度为 180-200度, 挤压温度为 400度, 挤压速度为 15mm/s,进行多次挤压后,该合金管的外径为 185mm± l mm, 内径为 165mm± l mm; 之后进行成品退火处理, 用箱式退火炉对挤压后 的合金管进行退火处理: 退火温度为 100-200度, 退火时间为 1.5-2小时; 最后探伤, 将退火完成的铜管进行探伤, 探伤比例为 100%, 并将探伤合 格的产品切割为长度 300mm± l mm的成品进行包装入库。
与现有的含铅合铜基合金管相比,本实施例提供的一种含硅与铝的铜 基合金管改善了黄铜的切削加工性能, 其生产工艺简单、 成本较低、 且不 会对环境造成污染。
本发明提供的一种含硅与铝的铜基合金管以及现有的含铅合金管的 机械性能如表 1所示。
表 1新型无铅铜基合金管性能
Figure imgf000007_0001
以上所述仅为本发明的较佳实施例, 并非用来限定本发明的实施范 围; 如果不脱离本发明的精神和范围, 对本发明进行修改或者等同替换, 均应涵盖在本发明权利要求的保护范围当中。

Claims

权 利 要 求 书
1. 一种含硅与铝的铜基合金管, 其特征在于, 由以下组份组成: 占合 金管总重量 50-55%的铜, 占合金管总重量 1-1.5%的硅, 占合金管总重量 0.05-0.5%的铝, 余量为锌。
2. 根据权利要求 1所述新型无铅铜基合金管,其特征在于, 由以下组 份组成: 占合金管总重量 50%的铜, 占合金管总重量 1%的硅, 占合金管 总重量 0.05%的铝, 余量为锌。
3. 根据权利要求 1所述的新型无铅铜基合金管,其特征在于, 由以下 组份组成: 占合金管总重量 55%的铜, 占合金管总重量 1.5%的硅, 占合 金管总重量 0.5%的铝, 余量为锌。
4. 根据权利要求 1所述的新型无铅铜基合金管, 其特征在于, 由以 下组份组成: 占合金管总重量 52.5%的铜, 占合金管总重量 1.25%的硅, 占合金管总重量 0.275%的铝, 余量为锌。
5. 根据权利要求 1-4任一权利要求所述的新型无铅铜基合金管,其特 征在于, 铜为电解铜。
6. 一种如权利要求 1-5 任一权利要求所述的新型无铅铜基合金管的 制备方法, 其特征在于包括以下歩骤:
1 )按照配比将电解铜、硅、铝、锌置于工频电炉内,加热至 1150-1200 度, 待完全熔化后保温至 1100度;
2 ) 用石墨棒将完全熔化的合金液体充分搅拌后, 在其上面覆盖高纯 度鳞片石墨粉以防止其氧化, 厚度为 10-15cm;
3 ) 保温 1-1.5小时后, 用光谱仪对从炉内取出的样品进行成分检验, 确定其合金成分在规定的范围内;
4) 进一歩保温至 50-60分钟后, 重新升温至 1200度, 开启工频电炉 的振动装置, 采用水平连铸方法造成外径为 200mm, 内径为 150mm, 长 度为 550mm的空心毛坯合金管材; 5 ) 挤压前退火, 用箱式退火炉对合金管进行退火处理: 退火温度为 300-350度, 退火时间为 1.5-2小时, 使合金管的硬度下降至 60-70HB, 以 便于挤压;
6 ) 用铜锭铣床对退火后的毛坯合金管材进行表面加工, 加工为表面 外径为 190mm, 内径为 155mm, 长度为 500mm的合金管;
7)挤压,采用 2500吨单动挤压机挤压,合金锭的加热温度为 180-200 度, 挤压温度为 400度, 挤压速度为 15mm/s, 多次挤压后合金管的外径 为 185mm, 公差为 +/-lmm, 内径为 165mm, 公差为 +/-lmm;
8 ) 成品退火, 用箱式退火炉对挤压后的合金管进行退火处理; 退火 温度为 100-200度, 退火时间为 1.5-2小时;
9) 探伤, 将退火处理后的合金管进行探伤, 探伤比例为 100%;
10 ) 将探伤合格的产品切割为长度 300mm的成品包装入库。
7. 根据权利要求 6要求所述的新型无铅铜基合金管,其特征在于,歩 骤 3 ) 中所述光谱仪采用斯派克直读光谱仪。
8. 根据权利要求 6要求所述的新型无铅铜基合金管,其特征在于,歩 骤 3 ) 中的成分检验次数为 3-6次。
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