WO2014158095A1

WO2014158095A1 - Methanation catalyst

Info

Publication number: WO2014158095A1
Application number: PCT/SG2014/000143
Authority: WO
Inventors: Luwei Chen; Zhi Qun Tian; Armando Borgna; Hiroyuki Kamata; Yoshinori Izumi
Original assignee: IHI Corp; Agency for Science Technology and Research Singapore
Current assignee: IHI Corp; Agency for Science Technology and Research Singapore
Priority date: 2013-03-28
Filing date: 2014-03-28
Publication date: 2014-10-02
Anticipated expiration: 2015-09-28
Also published as: CN105377422B; CN105377422A; JP2016515470A; US20160052837A1; JP6203375B2; US9802872B2

Abstract

The invention relates to use of a catalyst comprising particles of nickel dispersed in a porous silica matrix for catalysing a methanation reaction. There is also described a method for methanation of a feedstock at least comprising gases carbon monoxide and hydrogen, said method comprising contacting the feedstock with the catalyst.

Description

METHANATION CATALYST

Incorporation by Cross Reference

[0001] The present application claims priority from Singapore patent application

SG 201302358-5, the entire contents of which are incorporated herein by cross-reference.

Field

[0002] The invention deals with methanation catalysts.

Background

[0003] Substitute natural gas can be produced by a nickel-catalysed methanation reaction using the effluent from a coal biomass gasification process. However, compounds of sulfur can severely poison nickel catalysts and are often unavoidable in the effluent (commonly up to 5000 ppm) since sulfur is a component of most coal supplies. When nickel is immobilised on an aluminium oxide substrate for use as a catalyst, it is necessary to remove substantially all of the sulfur contained in the feed gas before allowing it to enter the methanator. In particular, it is necessary to reduce the sulfur content of the feed gas to a level of less than about 0.1 ppm, since sulfur poisons the nickel catalyst if it is present in any higher concentration. The gas cleaning process to remove sulfur down to 0.1 ppm imposes additional capital and processing costs. Therefore, there is a need for a nickel catalyst possessing a higher sulfur tolerance than Ni/Al₂0₃ so as to minimise the costs of substitute natural gas production.

[0004] It is an object of the invention to at least partially satisfy the above need;

Summary of Invention

[0005] In a first aspect of the invention there is provided a catalyst comprising particles of nickel dispersed in a porous silica matrix, when used for catalysing a methanation reaction.

[0006] The present invention also encompasses the use of a catalyst comprising particles of nickel dispersed in a porous silica matrix for catalysing a methanation reaction. [0007] The following options may be used in conjunction with the first aspect either individually or in any suitable combination.

[0008] The porous silica matrix of the catalyst may have pores of about 1 to about 100 nm diameter. The particles of nickel may comprise particles of nickel oxide. The particles of nickel oxide may have a mean particle diameter of about 2 to about 10 nm before being reduced under an atmosphere comprising hydrogen. The particles of nickel may comprise particles of metallic nickel. The particles of metallic nickel may have a mean particle diameter of about 2 to about 10 nm. The catalyst may be particulate. The catalyst may have a sheet-like structure. The catalyst particles may have an aspect ratio of at least about 10, wherein the aspect ratio refers to a ratio of length to thickness of sheets of the sheet-like structure.

[0009] The catalyst may comprise a plurality of particles of nickel dispersed therein, wherein the nickel particles may be metallic nickel particles.

[00010] The catalyst may have a BET surface area of at least about 200 m²/g. It may have a BET surface area of about 200 to about 1000 m /g. The catalyst may be porous. The pores of the catalyst, and/or of the silica matrix, may extend continuously from an outside surface of the silica matrix to an outside surface of the nickel. This may allow a reactant or other species to penetrate through the silica matrix to the surface of the nickel.

[00011] The catalyst may comprise about 16 wt% to about 63 wt% metallic nickel. The catalyst may comprise about 20 wt% to about 80 wt% nickel oxide. The catalyst may comprise about 20 wt% to about 80 wt% nickel oxide before being reduced under an atmosphere comprising hydrogen. The catalyst may have an active nickel surface area of about 50 to about 160 m²/g.Ni. The term "active nickel surface area" refers to the area of the nickel after the nickel oxide has been reduced and is therefore accessible to hydrogen or reactant gases. The term 'metallic nickel' refers to nickel in its elemental state (i.e., Ni(0)).

[00012] In an embodiment there is provided a catalyst when used for catalysing a methanation reaction, said catalyst comprising a plurality of particles of metallic nickel dispersed in a porous silica matrix, wherein the porous silica matrix has pores that extend continuously from an outside surface of the silica matrix to an outside surface of the nickel. [00013] In another embodiment there is provided a catalyst when used for catalysing a nlethanation reaction, said catalyst comprising a plurality of particles of metallic nickel dispersed in a porous silica matrix, wherein the porous silica matrix, or the catalyst, has a BET surface area of at least about 200 m /g.

[00014] In a further embodiment there is provided a catalyst when used for catalysing a methanation reaction, said catalyst comprising a plurality of particles of metallic nickel dispersed in a porous silica matrix, wherein the catalyst comprises about 13 to 63 wt% nickel and has an active nickel surface area of about 50 to about 160 m²/g.Ni.

[00015] The invention also encompasses the use of a catalyst comprising particles of metallic nickel dispersed in a porous silica matrix, e.g., use of a catalyst according the first aspect, for catalysing a methanation reaction, e.g. of a feedstock comprising carbon monoxide and hydrogen, and optionally also comprising a sulfur-containing gas.

[00016] In a second aspect of the present invention there is provided use of a catalyst comprising particles of nickel dispersed in a porous silica matrix, e.g., use of a catalyst according the first aspect, for reducing the carbon monoxide content of a gas mixture

comprising carbon monoxide and hydrogen.

[00017] In an embodiment of the second aspect, the catalyst comprises particles of metallic nickel dispersed in a porous silica matrix.

[00018] In a third aspect of the present invention there is provided a method for methanation of a feedstock comprising carbon monoxide and hydrogen. This method comprises contacting the feedstock with a catalyst comprising particles of nickel dispersed in a porous silica matrix, e.g., . with a catalyst according the first aspect.

[00019] In an embodiment of the third aspect, the catalyst comprises particles of metallic nickel dispersed in a porous silica matrix.

[00020] The following options may be used in conjunction with the third aspect either individually or in any suitable combination. [00021] The feedstock may additionally comprise carbon dioxide gas. It may comprise coal gasification effluent and/or biomass gasification effluent. It may additionally comprise a sulfur- containing gas. The sulfur-containing gas may be present at a concentration of over 0. lppm, or of about 0.1 to about 5000 ppm. It may comprise hydrogen sulfide, carbonyl sulfide, sulfur dioxide, one or more organic thiols and/or some other sulfur containing gas. The molar ratio of hydrogen to carbon monoxide in the feedstock may be between about 4: 1 and about 1 :1.

[00022] The contacting may comprise passing the feedstock over and/or through and/or past the catalyst, e.g., through a packed bed reactor comprising the catalyst. The pressure of the feedstock during said contacting may be between about 0.5 and about 40 bar. The flow rate of the feedstock may be between about 1000 h^"1 and 100 OOOh^"1.

[00023] The contacting may be conducted at a temperature of at least about 250 °C, e.g., at a temperature of between about 250 and about 800°C. The temperature and feedstock flow rate during the contacting may be sufficient to achieve equilibrium conversion from carbon monoxide to methane.

[00024] The catalyst may be effective without regeneration after use in the method for at least 2000 minutes using a feedstock having at least about 20 ppm of a sulfur containing gas.

[00025] In an embodiment there is provided a method for methanation of a feedstock comprising carbon monoxide and hydrogen, the method comprising contacting the feedstock with a catalyst comprising a plurality of particles of metallic nickel dispersed in a porous silica matrix, wherein the porous silica matrix has pores that extend continuously from an outside surface of the silica matrix to an outside surface of the metallic nickel.

[00026] In another embodiment there is provided a method for methanation of a feedstock comprising carbon monoxide and hydrogen, the method comprising contacting the feedstock with a catalyst comprising a plurality of particles of nickel dispersed in a porous silica matrix, wherein the feedstock additionally comprises a sulfur-containing gas present at a concentration of at least about O.lppm, e.g., at about 0.1 to about 5000 ppm.

[00027] In another embodiment there is provided a method for methanation of a feedstock comprising carbon monoxide and hydrogen, the method comprising passing the feedstock through a packed bed reactor comprising a catalyst comprising a plurality of particles of nickel dispersed in a porous silica matrix at a flow rate of between about 1000 h^{" 1} and about

100 000 h^"1 wherein the pressure and temperature during said passing are between about 0.5 and about 40 bar and between about 250 and about 800 °C respectively.

[00028] In a further embodiment there is provided a method for methanation of a feedstock comprising carbon monoxide, hydrogen, water (steam), methane and carbon dioxide and additionally comprising a sulfur containing gas present at a concentration of at least 0.1 ppm, optionally at least about 20 ppm, wherein the method comprises contacting the feedstock with a catalyst comprising a plurality of particles of nickel dispersed in a porous silica matrix and wherein the catalyst remains effective without regeneration after use in the method for at least 2000 minutes.

[00029] In yet a further embodiment there is provided a method for methanation of a feedstock comprising carbon monoxide and hydrogen and additionally comprising a sulfur containing gas at a concentration of at least about 0.1 ppm, optionally at least about 20 ppm, the method comprising passing the feedstock through a packed bed reactor comprising a catalyst comprising a plurality of particles of nickel dispersed in a porous silica matrix and having pores that extend continuously from an outside surface of the silica matrix to an outside surface of the nickel, at a flow rate of between about 1000 h^"1 and about 100 000 h^"1 wherein the pressure and temperature during said passing are between about 0.5 and about 40 bar and between about 250 and about 800 °C respectively.

[00030] In another aspect there is provided a method for conversion of carbon monoxide and hydrogen to methane in the presence of a sulfur containing gas, said method comprising contacting the carbon monoxide and hydrogen with a catalyst comprising particles of nickel dispersed in a porous silica matrix, e.g., with a catalyst according the first aspect.

[00031] In a further aspect there is provided a method for reducing the carbon monoxide content of a gas mixture comprising carbon monoxide and hydrogen, said method comprising exposing the gas mixture to a catalyst comprising particles of nickel dispersed in a porous silica matrix. The gas mixture may comprise a sulfur containing gas.

[00032] In a further aspect there is provided a method for reducing the carbon monoxide content of a gas, said method comprising adding hydrogen to said gas to form a gas mixture and exposing the gas mixture to a catalyst comprising particles of nickel dispersed in a porous silica matrix. The gas may comprise a sulfur containing gas.

Brief Description of Drawings

[00033] Figure 1 is a graph illustrating the long-term stability test of catalysts. The graph shows alterations of the methane concentrations with time-on-stream. The feed composition used was: 10% H₂0, 10% N₂, 40% H₂, 20% CO, 16% C0₂, 4% CH₄, 20 ppm H₂S; T = 500 °C; GHSV = 20,000 h^"1. All the catalysts were reduced at 500 °C in 50% H₂ N₂ for 2 h.

[00034] Figure 2 shows transmission electron microscope images of raw and post reaction Ni@Si0₂.

[00035] Figure 3 shows transmission electron microscope images of raw and post reaction commercial catalyst.

[00036] Figure 4 shows X-ray diffraction (XRD) patterns of spent catalysts Ni@Si0₂ and commercial catalyst.

[00037] Figure 5 shows the surface areas of Ni on Ni@Si0₂, commercial catalyst and

Ni/SBA- 15 under various reduction treatments.

[00038] Figure 6 is a graph illustrating the long-term stability of Ni@Si0₂. Concentrations of products (dry based, N₂ included) are shown as a function of time-on-stream. The feed composition used was 40% H₂, 10% H₂0, 20% CO, 10% C0₂, 4% CH₄, and 10% N₂; T = 500 °C; P = 1 bar; GHSV = 20 250 h^"1. The catalyst has been reduced in 50% H₂/N₂ at 500 ^PC for 2 h.

[00039] Figure 7 shows the experimental results obtained using Ni@Si0₂ (39% Ni) and commercial catalyst and a coal gasifier outlet gas. Concentration of methane shown as a function of time-on-stream. Reaction conditions: T = 485 °C, GHSV = 50 000 h^"1. Catalysts have been reduced in 50% H₂/N₂ at 600 °C for 2 h.

[00040] Figure 8 shows concentration of CH₄ (dry based, N₂ included) in the product as a function of time-on-stream over commercial (57% Ni) and Ni@Si0₂ (39% Ni) catalysts at 500 °C, 1 bar and GHSV 36 000 h^"1. Catalysts have been reduced in 50%.H₂/N₂ at 600 °C for

[00041] Figure 9 shows the concentration of CH₄ (dry based, N₂ included) in the product as a function of time-pn-stream over commercial (57% Ni) and Ni@Si(¾ (39% Ni) catalysts (10% H₂0, 10% N₂, 40% H₂, 20% CO, 16% C0₂, 4% CH₄, 20 ppm H₂S; T = 600 °C; GHSV = 20 000 b^'1.

[00042] Figure 10 shows the long-term stability test of Ni@Si0₂ (55% Ni) catalyst: Alterations of concentrations of CH₄ (dry based, N₂ included) in the product with time-on-stream. (GHSV = 19,800 h^"1, 300 °C, 1 bar, Gas compositions: 45% H₂, 22.5 %CO, 18% C0₂, 4.5% CH₄, 10% N₂).

[00043] Figure 11 shows the BET surface area of Ni@Si0₂ catalysts with various Ni loadings.

Definitions

[00044] As used in this application, the singular form "a", "an" and "the" include plural references unless the context clearly dictates otherwise. For example, the phrase "a catalyst" also includes a plurality of catalysts.

[00045] As used herein, the term "comprising" means "including." Variations of the word "comprising", such as "comprise" and "comprises," have correspondingly varied meanings. Thus, for example, a gas mixture "comprising" carbon monoxide and hydrogen may consist exclusively of carbon monoxide and hydrogen or may include one or more additional components (e.g., carbon dioxide, water vapour, molecular nitrogen, methane, etc.).

[00046] As used herein the term "plurality" means more than one. In certain specific aspects or embodiments, a plurality may mean 2, 5, 10, 10³, 10⁶, 10⁹, 10¹², 10¹⁵, 10¹⁸, 10²¹, 10²³, 10²⁴, or more, and any integer derivable therein, and any range derivable therein.

[00047] It will be understood that use the term "about" herein in reference to a recited numerical value includes the recited numerical value and numerical values within plus or minus ten percent of the recited value unless otherwise specified. [00048] It will be understood that use of the term "between" herein when referring to a range of numerical values encompasses the numerical values at each endpoint of the range. For example, a molar ratio of molecular hydrogen to carbon monoxide in the feedstock of between about 4:1 and about 3:1 is inclusive of a molar ratio of molecular hydrogen to carbon monoxide of 4:1 and a molar ratio of molecular hydrogen to carbon monoxide of 3 : 1.

[00049] Any description of prior art documents herein, or statements herein derived fjom or based on those documents, is not an admission that the documents or derived statements are part of the common general knowledge of the relevant art.

[00050] For the purposes of description all documents referred to herein are hereby

incorporated by reference in their entirety unless otherwise stated.

Description of Embodiments

[00051] The following description conveys exemplary embodiments of the present invention in sufficient detail to enable those of ordinary skill in the art to practice the present invention. Features or limitations of the various embodiments described do not necessarily limit other embodiments of the present invention or the present invention as a whole. Hence, the following detailed description does not limit the scope of the present invention, which is defined only by the claims.

[00052] The present invention relates to use of a nickel-based methanation catalyst, Ni@Si0_2; which has improved sulfur resistance in methanation reactions. The terminology Ni@Si0₂ indicates metallic nickel encapsulated in silica. The present invention also relates to a method for the methanation of a feedstock comprising contacting the feedstock with the Ni@Si0₂ catalyst.

[00053] The present inventors have identified a nickel-based catalyst (Ni@Si0₂) that is able to catalyse the methanation reaction in the presence of sulfur, a common contaminant in coal gasification effluent streams. Experimental evidence suggests the Ni@Si0₂ of the present invention is able to outperform the commercial catalyst and significantly outperform other catalysts comprising nickel immobilised on a solid support (Ni/Al₂0₃ and Ni/SBA-15) when catalysing a methanation reaction in the presence of sulfur. Further, although the nickel content of the Ni@Si0₂ is about equal to, or less than, the nickel content of Ni/SBA-15 and the commercial catalyst, Ni@Si0₂ maintains. a higher level of catalytic activity for longer during exposure to a feedstock comprising hydrogen sulfide. The superior performance of the

Ni@Si0₂ of the present invention is thought to be due to the improved sintering resistance of the nickel particles protected by the porous Si0₂, the structure of which results from the synthesis method employed.

[00054] The methanation reaction involves the generation of methane from a feedstock comprising carbon monoxide and hydrogen. The associated exothermic chemical

transformation is:

CO + 3H₂ -→ CH₄ + H₂0

[00055] The methanation reaction above is the reverse reaction of steam reforming of methane.

[00056] Additionally, in the presence of carbon dioxide, the methanation reaction may also generate methane via:

C0₂ + 4H₂→ CH₄ + 2H₂0

Catalyst

[00057] The Ni@Si0₂ catalyst of the present invention comprises particles of nickel dispersed in a porous silica matrix. The nickel particles may be metallic nickel particles. The porous silica matrix may have pores of about 1 to about 100 nm in diameter, or about 1 to 50, 1 to 20, 1 to 10, 2 to 10, 5 to 20, 10 to 20, 10 to 50, or 20 to 50 nm in diameter, e.g., about 1, 2, 3, 4, 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, 60, 70, 80, 90 or 100 nm in diameter. Silica pore size and distribution can be determined by those skilled in the art using, for example, nitrogen or hydrogen adsorption/desorption methods. The nickel particles dispersed in the porous silica matrix may have a mean particle diameter of about 2 to about 10 nm, or about 2 to 5, 5 to 10 or 3 to 7 nm, e.g., about 2, 3, 4, 5, 6, 7, 8, 9 or 10 nm. In the event that the nickel particles are not spherical, the diameter of a particle may be taken as the hydrodynamic diameter, or may be take to be the minimum dimension of a particle (e.g., a thickness) or the maximum dimension of a particle (e.g., a length) or the mean dimension of a particle. The particle diameter of the nickel particles may be determined using well-established techniques including transmission electron microscopy and X-ray powder diffraction. The shape of the nickel particles and of the catalyst particles may, independently, be spherical, acicular, flat, flaky, prismoidal, polyhedral, fibrous, irregular, spheroidal, or granular. The pores of the Ni@Si0₂ catalyst may extend continuously from an outside surface of the porous silica matrix to an outside surface of the nickel. This may allow gases such as the carbon monoxide and hydrogen gas reactants to penetrate through the encapsulating silica to the surface of the nickel.

[00058] The nickel particles may be dispersed, optionally evenly or homogeneously dispersed, throughout the porous silica matrix such that each particle of catalyst comprises a plurality of particles of nickel dispersed therein. The catalyst may comprise about 20 to about 80 wt% nickel oxide, or about 20 to 30, 30 to 40, 40 to 50, 50 to 60, 40 to 60, 60 to 70, 50 to 70, or 70 to 80 wt% nickel oxide, e.g., about 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75 or 80 wt% nickel oxide on a weight basis before being reduced under an atmosphere comprising hydrogen. The catalyst may comprise about 16 wt% to about 63 wt% metallic nickel, or about 20 to about 63 wt%, or about 25 to about 63 wt%, or about 30 to about 63 wt%, or about 16 to about 30 wt%, or about 16 to about 55 wt% metallic nickel, or about 16, 20, 25, 30, 35, 40, 45, 50, 55, 60 or 63 wt% metallic nickel. Suitable methods for determining metal content in porous silica are known in the art.

[00059] The active nickel surface area of the catalyst may be about 50 to about 160 m²/g.Ni, about 50 to 70, 60 to 80, 60 to 90, 70 to 110, 80 to 120, 90 to 130, 80 to 140, 90 to 150, 90 to 160, 70 to 90 or 75 to 85 m²/g.Ni, e.g., about 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 100, 105, 110, 120, 130, 140, 150 or 160 m /g.Ni. When measured using a temperature-programmed desorption of hydrogen method, the active nickel surface area of the catalyst measured at about 500 °C after exposure to hydrogen for about 2 h may be about 40 to about 90 m²/g.Ni, about 50 to about 80 m²/g.Ni, about 60 to about 70 m²/g.Ni, or about 40 to 60, 70 to 90, or 50 to 70 m²/g.Ni, e.g., about 65 m²/g.Ni, or about 40, 50, 60, 70, 80 or 90 m²/g.Ni. Further, the active nickel surface area of the catalyst measured at about 620 °C after exposure to hydrogen for about 15 h may be 75 to about 150 m²/g.Ni, about 85 to about 115 m²/g.Ni, 95 to about 105 - m²/g.Ni, e.g., about 100 m /g.Ni, or about 75, 80, 85, 90, 95, 96, 97, 98, 99, 101, 102, 103, 104,

105, 110, 115, 120 or 125 m 2 /g.Ni and the active nickel s■urface area o ' f the catalyst measured at about 750 °C after exposure to hydrogen for about 15 h may be about 55 to about 160 m²/g.Ni, about 65 to about 95 m /g.Ni, about 75 to about 85, or about 55 to 90 or about 90 to 105, or about 90 to 115, or about 90 to 125, or about 100 to 140, or about 110 to 150, or about 120 to 160 m²/g.Ni, e.g., about 80 m²/g.Ni, or about 65, 70, 75, 76, 77, 78, 79, 81, 82, 83, 84, 85, 90, 95, 100, 110, 120, 130, 140, 150 or 160 m²/g.Ni.

[00060] The catalyst, or the porous silica, may have a BET surface area of at least about 200

" 2 2 2

m /g, or at least about 300, 400 or 500 m /g, or from about 200 m /g to about 600 m /g, about 200 to 500, 500 to 1000, 300 to 900, 400 to 700, 500 to 700 or 300 to 600 m²/g, or about 200, 300, 400, 500, 600, 700, 800, 900 or 1000 m²/g. The measurement and modeling of a BET equation are methods well known in the art.

[00061] In the event that the catalyst particles have a sheet-like structure, they may have an aspect ratio of at least about 10, at least about 12, at least about 15, at least about 20, between about 10 and about 20, between about 10 and about 15, between about 10 and about 30, between about 10 and about 40, between about 20 and about 40, between about 15 and about 25, or about 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 30, 40, or 50, wherein the aspect ratio refers to the ratio of length to thickness of the sheets of the sheet-like structure.

Catalysis

[00062] The catalyst described herein may be used for catalysing a methanation reaction. It may also be used for reducing the carbon monoxide content of a gas mixture comprising carbon monoxide and hydrogen. As noted above, the catalyst is capable of catalysing the conversion of carbon monoxide to methane. This may be useful for generating methane (e.g., for use as a fuel) or for scrubbing carbon monoxide from a feed stream (so as to reduce toxicity) or both.

[00063] The catalyst described herein may be used in a method for the methanation of a feedstock comprising gases carbon monoxide and hydrogen, the method comprising contacting the feedstock with the Ni@Si0₂ catalyst of the present invention.

[00064] The feedstock for input into the claimed method may comprise molecular hydrogen and carbon monoxide, but may additionally comprise carbon dioxide, water vapour, molecular nitrogen, methane, or may additionally comprise a mixture of any two or more of these. The molar ratio of molecular hydrogen to carbon monoxide in the feedstock may be about 4:1, about 3:1, about 2:1, or about 1 :1, between about 4:1 and about 3:1, between about 4:1 and about 2:1, between about 4:1 and about 1 :1, between about 3:1 and about 2:1, between about 3:1 and about 1 :1, or about 4:1, 3.5:1, 3:1, 2.5:1, 2:1, _.1.5:1 or 1 :1. The ratio may depend on the source of the feedstock. The concentration of carbon monoxide in the gas mixture may be about 10% to about 40%, or about 10 to 30%, 20 to 40% or 20 to 30%, e.g., about 10%, 15%, 20%, 25%, 30%, 35% or 40%. These percentages may be by volume. The feedstock in the present invention may comprise, or may consist essentially of, coal gasification effluent, which is the effluent produced by heating black or brown coal in the presence of oxygen, steam (water vapour) and heat. The feedstock in the present invention may comprise, or may consist essentially of, effluent produced by heating biomass in the presence of oxygen, steam (water vapour) and heat.

[00065] The feedstock may also comprise a sulfur-containing gas. The sulfur containing gas may be present at a total concentration of at least about O.lppm, or at least about 0.2, 0.3, 0.4, 0.5, 1, 2, 3, 4, 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, 60, 70, 80, 90, 100, 200, 300, 400, 500, 1000, 1500, 2000, 2500, 3000, 3500, 4000, 4500, or 5000 ppm, or at about 0.1 to about 5000 ppm, or about 1 to about 500 ppm, or about 5 to about 100 ppm, or about 0.1 to 500, 0.5 to 500, 10 to about 100 ppm, or about 10 to about 80 ppm, or about 20 to about 80 ppm, or about 20 to about 100 ppm, or about 10 to about 50 ppm, or about 20 to about 200 ppm, or about 50 to about 300 ppm, or about 100 to about 300 ppm, or about 100 to about 500 ppm, or about 200 to about 600 ppm, or about 300 to about 700 ppm, or about 500 to about 1000 ppm, or about 1000 to about 2000 ppm, or about 1000 to about 3000 ppm, or about 1000 to about 4000 ppm, or about 1000 to about 5000 ppm, or about 2000 to about 3000 ppm, or about 2000 to about 4000 ppm, or about 2000 to about 5000 ppm, or at a total concentration of about 0.1, 0.2, 0.3, 0.4, 0.5, 1, 2, 3, 4, 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, 60, 70, 80, 90, 100, 200, 300, 400, 500, 1000, 1500, 2000, 2500, 3000, 3500, 4000, 4500, or 5000 ppm. The sulfur-containing gas may be hydrogen sulfide, may be carbonyl sulfide, or may be organic thiols (e.g. methane thiol, ethane thiol, thiophenol etc.), or may be an oxide of sulfur, e.g., sulfur dioxide, or may be a mixture of any two or more of these. In the present invention, ppm of a sulfur-containing gas is by volume, i.e. is taken to mean microlitres of gas per litre of air ^L/L).

[00066] The contacting method may comprise passing the feedstock through a packed bed reactor comprising the catalyst, or over or past a catalyst disposed in a reactor. The reactor may comprise one or more (e.g., 1, 2, 3, 4 or 5) packed reactor beds arranged in series or in parallel. The packed bed reactor or reactors may operate under isothermal or adiabatic conditions. The catalyst may be packed in beds, or in rods, or in plates, or may be coated on the inside surface of a reactor vessel or on some other surface thereof. The catalyst may be coated on any one or more of honeycomb catalyst structures, porous metal catalyst structures, or ceramic matrix catalyst structures. The contacting method may instead comprise bubbling the feedstock through a slurry comprising the catalyst.

[00067] During contacting of the feedstock with the Ni@Si0₂ catalyst, the feedstock may be at a pressure of about 0.5 to about 40 bar, at least about 0.5 bar, 1 bar, 2 bar, 5 bar, 10 bar, 15 bar, 20 bar, 25 bar, 30 bar, 35 bar or 40 bar or between about 1 and about 2 bar, or between about 1 and 5 bar, 5 and 10 bar, 5 and 20 bar, 10 and 20 bar, 15 and 25 bar, or 15 and 30 bar, or 20 and 40 bar, or 25 and 40 bar, or 30 and 40 bar, or about 0.5, 1, 2, 3, 3.5, 4, 4.5, 5, 6, 7, 8, 9, 10, 15, 20, 25, 30, 35 or 40 bar. The flow rate of the feedstock may be about 20 000 h^"1, or may be at least about 1000 h^"1, 5000 h^"1, or 10 000 h^"1, or 20 000 h^"1, or 30 000 h^"1, or 40 000 h^"1, or 50 000 h^"1, or 60 000 h^"1, or 70 000 h^"1, or 80 000 h^"1, or 90 000 b^"1, or 100 000 If¹, or between about 1000 h^"1 and about 100 000 h^"1, or between about 1000 h^"1 and about 10 000 h^"1, or between about 10 000 h^"1 and about 50 000 h^"1, or between about 20 000 h^"1 and about 60 000 h^"1, or between about 30 000 h^"1 and about 70 000 h^'1, or between about 30 000 h^"1 and about 80 000 h^"1, or between about 40 000 h^"1 and about 90 000 h^"1, or between about 50 000 h^"1 and about 100 000 h^"1, or between about 50 000 h^"1 and about 80 000 h^"1, or may be about 1000, 5000, 10 000, 20 000, 30 000, 40 000, 50 000, 60 000, 70 000, 80 000, 90 000, or 100 000 h^"1. At times, other flow rates may be used. These flow rates may be a space velocity (SV;

volumetric flow rate/catalyst volume) or a gas hourly space velocity (GHSV; reactant gas flow rate/catalyst volume). The contacting may be conducted at a temperature of at least about 250 °C, or at least about 300, 350, 400, 450, 500, 550 or 600°C, or between about 250 and 800 °C, or between about 350 and 600 °C, or between about 400 and 500 °C, or between about 500 and 800 °C, or between about 400 and 600 °C, or between about 400 and 700 °C, or between about 450 and 550 °C, or between about 450 and 650 °C, or about 400, 450, 500, 550, 600, 650, 700, 750 or 800 °C. The temperature and feedstock flow rate during the contacting method may be chosen to achieve conversion of carbon oxides to methane of at least 50%, at least 60%, at least 70%, at least 80%, or at least 90% of the equilibrium conversion.

[00068] The Ni@Si0₂ catalyst disclosed herein may remain effective in use without

regeneration for at least about 1000 minutes, or at least about 1500, 2000, 2500 or 3000 minutes. It may remain effective for these times when catalysing a m emanation reaction using a feedstock comprising at least about 20 ppm of a sulfur containing gas. The term 'effective' here may refer to a reduction in conversion efficiency from its initial value of less than about 20%, or of less than about 15, 10, 5 or 2% over the stated period. [00069] It will be appreciated by persons of ordinary skill in the art that numerous variations and/or modifications can be made to the present invention as disclosed in the specific embodiments without departing from the spirit or scope of the present invention as broadly described. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive. "

Examples

[00070] The present invention will now be described with reference to specific examples, which should not be construed as in any way limiting.

Example 1: Synthesis and Characterisation of Ni@Si0₂ Catalyst

[00071] In a typical synthesis of 50 wt% NiO@Si0₂, 7.8 g of Ni(N0₃)₂-6H₂0 and 10 g of cetyltrimethylammonium bromide (CTAB) were dissolved in 400 mL H₂0 followed by the addition of 80 mL of NaOH water solution with 4.0 g NaOH by pouring at room temperature. The Ni(OH)₂ precipitate capped with CTAB was then collected by centrifugation. The precipitate was dispersed into 320 mL of water to form a suspension. The pH value of the suspension was adjusted to above 12. Subsequently, 7.6 mL of tetraethoxysilane (TEOS) in 80 mL ethanol was slowly dropped into the suspension and maintained at room temperature for 48 h under constant stirring to form a Si0₂ shell coated onto the Ni(OH)₂ precipitate. After centrifugation, the as received Ni(OH)₂ with Si0₂ shell was washed thoroughly with deionized water to remove sodium residue in the composite, and dried at 80°C. Finally, 50 wt% NiO@ Si0₂ was obtained by calcination in air at 500 °C for 2 h. The as-prepared 50 wt% NiO@Si0₂ needs to be reduced in pure or diluted hydrogen gas at a temperature of between 350 and 600 °C for several hours before catalysing the methanation reaction. The Ni content of the resultant Ni@Si0₂ catalyst is 39 wt%.

[00072] The synthesis of nickel-based Ni@Si0₂ catalysts is also described in

PCT/SG2013/000472.

[00073] The particle size and morphology of pre- and post-reaction Ni@Si0₂ were

characterised by transmission electron microscopy (TEM, HR-TEM, JEOL JEM-2010F) as discussed below. The crystallization size and phase transformation were determined by X-ray diffraction using a Bruker D8 Advance X-ray diffractometer equipped with Cu a radiation (λ = 0.154 nm) and in situ X-ray diffraction, respectively, selected results from which are included below. N₂ adsorption-desorption isotherms were collected on Micromeritics ASAP 2420 V2.05 (V2.05 J). H₂ temperature-programmed reduction (H₂-TPR) measurements were carried out with 50 mg of fresh catalysts. Before measurement, the samples were thermally treated under Ar stream at 200 °C for 2 h to remove moisture and other contaminants. The reactor was heated from 30 °C to 850 °C at a rate of 10 °C/min in 50 mL/min of 5% of H₂/Ar. The hydrogen consumption was monitored using a thermal conductivity detector (TCD) and the results for catalysts Ni@Si0₂, commercial catalyst, Ni/SBA-15 are included in the following section.

Example 2: Laboratory tests of Ni@Si0₂ catalyst compared to commercial catalyst, Ni/SBA-15 and Ni/Al₂0₃ in the presence of H₂S at 500 ^°C

[00074] Laboratory testing of the long-term stability of the catalyst of the present invention Ni@Si0₂, including other catalysts Ni/SBA-15, Ni/Al₂0₃ and commercial catalyst, under methanation reaction conditions was undertaken using a feedstock comprising 10% H₂0, 10% N₂, 40% H₂, 20% CO, 16% C0₂, 4% CH₄, and 20 ppm H₂S at a temperature of 500 °C and a feedstock flow rate of 20 000 h^'1.

[00075] The results of laboratory tests of Ni@Si0₂, commercial catalyst, Ni/SBA-15 and Ni/Al₂0₃ in catalysing a methanation reaction of this feedstock comprising H₂S are shown in Figure 1, which compares the catalytic performances of commercial catalyst (55%Ni), Ni/SBA- 15 (44%Ni) and Ni/Al₂0₃ (20%Ni) in terms of the concentration of CH in the product gas mixture as a function of time-on- stream.

[00076] The methane concentrations at the start of the reaction without H₂S feeding are around 18 to 20% for the latter three catalysts (commercial catalyst, Ni/SBA-15 and Ni/Al₂0₃).

Obvious deactivation starts over Ni/Al₂0₃ (20%Ni) when H₂S is introduced at the 90^th minute, and the activity is completely lost at the 500^th minute. The durability of Ni/SBA-15 with 44% Ni content is about the twice of that over 20% Ni/Al₂0₃. Performances of commercial catalyst (58% Ni) and Ni@Si0₂ (39% Ni) are similar and relatively stable at the first 900 minutes of time-on-stream. After 900 minutes, commercial catalysts deactivates with a faster rate than Ni@Si0₂. Complete deactivation occurs at around 1800 and 3600 minutes for commercial catalyst and Ni@Si0₂, respectively. Figure 1 clearly indicates the increased durability of Ni@Si0₂ over commercial catalyst in the presence of 20 ppm H₂S, despite the Ni loading being lower in Ni@Si0₂. [00077] The spent Ni@Si0₂ and commercial catalysts were then analysed by TEM and XRD, and results are shown in Figures 2 and 3 respectively. The TEM image in Figure 2 shows that, for the Ni@Si0₂ catalyst, the Ni particles in the Si0₂ matrix remain small. The TEM image in Figure 3 shows that, for the commercial catalyst, the Ni particle sizes become larger. The Ni (111) peak in the XRD pattern for spent Ni@Si0₂ is visibly broader than the corresponding peak in the XRD pattern for the spent commercial catalyst (Figure 4). Further, the average Ni particle sizes calculated from these XRD patterns according to Scherrer's equation are 3.4 nm for Ni@Si0₂ and 6.7 nm for commercial catalyst. Therefore, TEM and XRD results consistently indicate that Ni@Si0₂ is more resistant to sintering than commercial catalyst.

[00078] The active Ni surface area of Ni@Si0₂ (39%), commercial catalyst (57%) and Ni/SBA- 15 (44% Ni) were measured by temperature-programmed desorption of hydrogen. Three different reduction conditions were applied, namely 500 °C/2 h, 600 °C/15 h and 750 °C/15 h. As shown in Figure 5, the Ni surface areas of Ni@Si0₂, commercial catalyst and Ni/SBA-15 after being reduced at 500 °C for 2 h are 65.4, 78.4 and 27.2 m²/g.Ni respectively. The areas increase to 90 m²/g (Ni) for both Ni@Si0₂ and commercial catalyst when the reduction temperature is increased to 620 °C and the reduction time extended to 15 hours. When the reduction temperature is increased further to 750 °C and 15 hours, the active Ni area of commercial catalyst greatly decreases to 24.7 m²/g.Ni, while the decrease of Ni area in

Ni@Si0₂ (80.2 mVg.Ni) is less severe than in commercial catalyst.

Example 3: Laboratory tests of Ni@Si0₂ catalyst in the absence of H₂S at 500 C

[00079] Figure 6 displays the results of laboratory tests of Ni@Si0₂ in a gas stream under H₂S- free conditions, using a feedstock comprising 40% H₂, 10% H₂0, 20% CO, 16% C0₂, 4% CH₄, and 10% N₂ at 500 °C, 1 bar pressure, and a feedstock flow rate of 20 250 h^"1 showing the concentration of the various catalysis products as a function of time-on-stream. Figure 6 reveals that in the absence of H₂S, the Ni@Si0₂ catalyst exhibits very stable activity and lasts for at least 500 h without visible deactivation.

Example 4: Industrial test of Ni@Si0₂ catalyst compared to commercial catalyst in the presence of H₂S

[00080] Figure 7 shows the experimental results obtained using coal gasification outlet gas from a gasifier facility as feedstock. Two reactors, one containing Ni@Si0₂ and the other containing commercial catalyst, were operated for the same time under identical conditions (T = 485 °C, GHSV = 50 OOOh^"1) for three consecutive days. The reaction was stopped at the end of each day and the catalysts were kept in the reactor under the protection of Ar gas overnight.. The reactors were heated to the desired reaction temperature under the flow of Ar and the reaction was resumed by reintroducing the outlet gas from the gasifier.

[00081] Both catalysts exhibit stable catalytic performance on the first day, producing 9% CH₄ and 8% CH₄ on average over commercial and Ni@Si0₂, respectively. The equilibrium concentration of CH₄ should be 11.5%. On the second day, both catalysts start to deactivate gradually with similar deactivation rate. However, commercial catalyst loses its activity very rapidly on the third day test, while Ni@Si0₂ seems to maintain a stable deactivation rate as before.

[00082] In summary, Ni@Si0₂ has shown better catalytic performance for methanation reaction under the gas stream with and without H₂S than a bench mark commercial catalyst and other catalysts with similar Ni loading prepared using conventional impregnation method. The superior performance of Ni@Si0₂ is due to the improved sintering resistance of Ni protected by porous Si0₂.

Example 5: Laboratory tests of Ni@Si0₂ catalyst compared to commercial catalyst in the presence of H₂S at 500 C

[00083] Laboratory testing of the long-term stability of the catalyst of the present invention Ni@Si0₂ (39%) Ni) and commercial catalyst (57%), under methanation reaction conditions was undertaken using a feedstock comprising 20% N₂, 34.4% H₂, 22.9% CO, 18.2% C0₂, 4.5% CH₄, and 10 ppm H₂S at a temperature of 500 °C and a feedstock flow rate of GHSV =

36 OOO h^"1. The results are shown in Figure 8.

[00084] Figure 8 shows the concentration of CH₄ alteration with time-on-stream over these two catalysts. The present invention Ni@Si0₂ (39% Ni) catalyst lasts for about 70 h while the commercial catalyst (57% Ni) can only last for 42 h before becoming completely deactivated. Example 6: Laboratory tests of Ni@Si0₂ catalyst compared to commercial catalyst in the presence of H₂S at 600 C

[00085] Laboratory testing of the long-term stability of the catalyst of the present invention Ni@Si0₂ (39% Ni) and commercial catalyst (57%), under methanation reaction conditions was undertaken using a feedstock comprising 40% H₂, 10% ¾0, 20% CO, 16% C0₂, 4% CH₄, and 10% N₂ and 20 ppm H₂S at a temperature of 600 °C and a feedstock flow rate of GHSV = 20 000 h^"1. The results are shown in Figure 9.

[00086] Figure 9 shows the concentration of CH alteration with time-on-stream over these two catalysts. The present invention Ni@Si0₂ (39% Ni) catalyst lasts for about 35 h while the commercial catalyst (57% Ni) can only last for 16 h before completely deactivated.

Example 7: Laboratory tests of Ni@Si0₂ catalyst in the absence of H₂S at 300 C

[00087] Figure 10 displays the results of laboratory tests of Ni@Si(½ in a gas stream under H₂S- free conditions, using a feedstock comprising 45% H₂, 22.5% CO, ^'18% C0₂, 4.5%» CH₄, and 10%) N₂ at 300 °C, 1 bar pressure, and a feedstock flow rate of 19 800 h^"1 (GHSV) showing the concentration of the various catalysis products as a function of time-on-stream. Figure 10 reveals that in the absence of H₂S, the Ni@Si0₂ catalyst exhibits very stable activity and lasts for at least 1250 h without visible deactivation.

Example 8: Characterization of catalysts-— BET surface area and specific Ni area

[00088] The BET surface areas of the present invention Ni@Si0₂ catalysts with various NiO contents of 20%, 40%, 60%, 70%, 80% and 90% are compared in Figure 11. The surface areas decrease with the increment of NiO loadings since the main contributor of the surface area is the porous Si0₂. The BET surface area decreases from 475 m²/g from 20% NiO to 375 m²/g of 70%NiO. However, the BET surface area decreases dramatically from 375 m²/g to 175 m²/g when the loading of NiO increases from of 70% to 90%.

[00089] The specific Ni area in terms of square meter per gram of catalyst and per gram of Ni of the present invention Ni@Si0₂ with various NiO loadings of 40, 50, and 60% as well as the commercial catalyst are tabulated in Table 1. The catalysts have been reduced for 15 h at 620 C in the flow of pure H₂ prior to the H₂ adsorption and desorption. The specific Ni area increases with Ni loading and reaches 152.5 m²-g^_1Ni for Ni@Si0₂ with 47% Ni loading. However, the specific Ni area is only 93.5 m 2 -g^" 1 Ni for the commercial catalyst with 57% Ni * loading. This result clearly indicates that the present invention Ni@Si0₂ catalyst has higher Ni utilisation efficiency than the commercial catalyst.

Table 1: The specific surface area of Ni after the catalysts have been reduced at 620 °C for 15 hours.

Ni loading (%) m²/gcat m²/gNi

40% NiO@Si0₂ 31 37.7 120

50% NiO@Si0₂ 39 39.4 100.3

60% NiO@Si0₂ 47 71.9 152.5

Commercial catalyst 57 52.9 93.5

Claims

1. A catalyst comprising particles of nickel dispersed in a porous silica matrix, when used for catalysing a methanation reaction.

2. The catalyst of claim 1 wherein the porous silica matrix of the catalyst has pores of about 1 to about 100 nm diameter.

3. The catalyst of claim 1 or 2 wherein the particles of nickel have a mean particle diameter of about 2 to about 10 nm.

4. The catalyst of any one of claims 1 to 3 wherein said catalyst has a BET surface area of at least about 200 m²/g, or from about 200 to about 1000 m²/g.

5. The catalyst of any one of claims 1 to 4 wherein the pores of said catalyst extend continuously from an outside surface of the silica matrix to an outside surface of the nickel so as to allow a reactant to penetrate to the surface of the nickel.

6. The catalyst of any one of claims 1 to 5 wherein the catalyst comprises about 16 wt% to about 63 wt% metallic nickel.

7. The catalyst of any one of claims 1 to 6 wherein the active nickel surface area in said catalyst is about 50 to about 160 m²/g.Ni.

8. Use of a catalyst comprising particles of nickel dispersed in a porous silica matrix for catalysing a methanation reaction.

9. Use of a catalyst comprising particles of nickel dispersed in a porous silica matrix, said use being for reducing the carbon monoxide content of a gas mixture comprising carbon monoxide and hydrogen.

10. A method for methanation of a feedstock comprising carbon monoxide and hydrogen, said method comprising contacting the feedstock with a catalyst comprising particles of nickel dispersed in a porous silica matrix.

11. The method of claim 10 wherein the feedstock additionally comprises carbon dioxide gas.

12. The method of claim 10 or 11 wherein the feedstock additionally comprises steam.

13. The method of any one of claims 10 to 12 wherein the feedstock comprises coal gasification effluent and/or biomass gasification effluent.

14. The method of any one of claims 10 to 13 wherein the feedstock additionally comprises a sulfur-containing gas.

15. The method of claim 14 wherein the sulfur-containing gas is present at a concentration of about 0.1 to about 5000 ppm.

16. The method of claim 14 or 15 wherein the sulfur-containing gas comprises any one or more of hydrogen sulfide, carbonyl sulfide, sulfur dioxide and an organic thiol.

17. The method of any one of claims 10 to 16 wherein the molar ratio of hydrogen to carbon monoxide in the feedstock is between about 4:1 and about 1 :1.

18. The method of any one of claims 10 to 17 wherein contacting comprises passing the feedstock through a packed bed reactor comprising the catalyst.

19. The method of any one of claims 10 to 18 wherein the pressure of the feedstock during said contacting is between about 0.5 and about 40 bar.

20. The method of any one of claims 10 to 19 wherein said contacting is conducted at a temperature of at least about 250 °C.

21. The method of any one of claims 10 to 20 wherein the temperature and feedstock flow rate during said contacting are sufficient to achieve equilibrium conversion of carbon oxides to methane.

22. The method of any one of claims 10 to 21 wherein the flow rate of the feedstock is between about 1000 h^"1 and 100 000 h^"1.

23. The method of any one of claims 10 to 22 wherein the catalyst is effective without regeneration after use in said method for at least 2000 minutes using a feedstock having at least about 20 ppm of a sulfur containing gas.

24. A method for reducing the carbon monoxide content of a gas mixture comprising carbon monoxide and hydrogen, said method comprising exposing the gas mixture to a catalyst comprising particles of nickel dispersed in a porous silica matrix.

25. The method of claim 24 wherein the gas mixture comprises a sulfur containing gas.

26. A method for reducing the carbon monoxide content of a gas, said method comprising adding hydrogen to said gas to form a gas mixture and exposing the gas mixture to a catalyst comprising particles of nickel dispersed in a porous silica matrix.

27. The method of claim 26 wherein the gas comprises a sulfur containing gas.