WO2014126488A2 - Method for the manufacturing of elements of non-ferrous metal alloys, advantageously aluminium alloys - Google Patents

Method for the manufacturing of elements of non-ferrous metal alloys, advantageously aluminium alloys Download PDF

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Publication number
WO2014126488A2
WO2014126488A2 PCT/PL2014/000009 PL2014000009W WO2014126488A2 WO 2014126488 A2 WO2014126488 A2 WO 2014126488A2 PL 2014000009 W PL2014000009 W PL 2014000009W WO 2014126488 A2 WO2014126488 A2 WO 2014126488A2
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WO
WIPO (PCT)
Prior art keywords
advantageously
temperature
range
plastic working
solid solution
Prior art date
Application number
PCT/PL2014/000009
Other languages
French (fr)
Other versions
WO2014126488A3 (en
Inventor
Andrzej Korbel
Włodzimierz BOCHNIAK
Jacek BOROWSKI
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Instytut Obróbki Plastycznej
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Publication date
Application filed by Instytut Obróbki Plastycznej filed Critical Instytut Obróbki Plastycznej
Priority to EP14707853.9A priority Critical patent/EP2956252A2/en
Priority to US14/385,460 priority patent/US20150376727A1/en
Publication of WO2014126488A2 publication Critical patent/WO2014126488A2/en
Publication of WO2014126488A3 publication Critical patent/WO2014126488A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/02—Hardening articles or materials formed by forging or rolling, with no further heating beyond that required for the formation
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C23/00—Extruding metal; Impact extrusion
    • B21C23/002—Extruding materials of special alloys so far as the composition of the alloy requires or permits special extruding methods of sequences
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
    • C21D1/60—Aqueous agents
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/10—Alloys based on aluminium with zinc as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/002—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working by rapid cooling or quenching; cooling agents used therefor
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/053—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with zinc as the next major constituent

Definitions

  • the subject of the invention is a method for the construction of elements of non-ferrous metal alloys, advantageously aluminium alloys, used for the manufacturing of shaped elements, in particular rods, in thermal treatment of metals.
  • alloys with different solubility when solid, in particular finished products or semi-finished products undergo thermal treatment, which consists of a supersaturation operation and ageing operation, or thermal and thermo-mechanical treatment, composed of, in the following order: supersaturation operation, plastic deformation and ageing operation.
  • the supersaturation operation consists of heating the alloy to temperature from the range of a solid solution, annealing it for a time necessary to dissolve the secondary phase particles and rapid cooling, as a result of which the alloy in the ambient temperature remains in a single-phase stmcture, which will be theiTnodynamically unstable and will transform during the ageing operation.
  • This operation consists of the heating of the supersaturated alloy to the temperature bel ow the solubility limit and annealed for the time required for precipitation from the supersaturated solid solution of phases with a high degree of dispersion.
  • the thermal treatment is conducted on elements with initially or finally shaped geometry, as a result of casting, machining or plastic working. If plastic working is conducted in an appropriately high temperature, which guarantees the alloy will achieve the structure of a solid solution, rapid cooling of the deformed element will result in its supersaturation.
  • the supersaturation may be performed directly at the press delay route, through intensive cooling of the compact, usually with water.
  • Single-phase structure of the alloy which results from the supersaturation operation, increases its plastic properties and enables intense plastic working of the alloy, up to achieving a product with final geometry, and subsequently the used aging process, as well as the assumed mechanical properties.
  • the time of annealing necessary for the full occurrence of the heat activated process of diffusion of alloy components amounts usually from 1 to a few hours.
  • the conditions of alloy annealing are not differentiated depending on whether it was or was not subjected to initial plastic working.
  • a charge with dimensions of 040 x 40 mm, of a 7075 aluminium alloy was pressed on a hydraulic press with a speed of 0.5 mm/s within a temperature of 450°C to which both the charge and the working tools were heated, after which the charge was annealed within this temperature for 2 hours.
  • the obtained rod with a diameter of 12 mm was immediately cooled with water.
  • the rod was aged by annealing at a temperature of 150°C for a time of 3 hours. As a result, the rod obtained a hardness of 160 HV.
  • a charge with dimensions of 040 x 40 mm was pressed on a hydraulic press equipped with a mechanical system resulting in oscillating rotation of the die along its axis with an angle of ⁇ 8° with a frequency of 5 Hz.
  • the process of pressing was conducted at a speed of 0.5 mm/s at a temperature of 20°C, without initial heating of the charge and the tools, obtaining a rod with a diameter of 12 mm, which was immediately cooled in water.
  • the rod was aged by annealing at a temperature of 150°C for a time of 3 hours. As a result, the rod obtained a hardness of 137 HV.
  • the essence of the invention which is a method of manufacturing non- ferrous metal alloy elements, with the use of plastic working and thermal treatment, advantageously aluminium alloys, consists of the metallic charge being subjected to a plastic deformation of at least 60%, advantageously by pressing with the extrusion ratio exceeding the value of 2, at a temperature below the range of occurrence of a solid solution, after which the obtained element undergoes the supersaturation process by heating it up to the temperature of occurrence of a solid solution and keeping it at this temperature for a period of 2-25 minutes, advantageously 5 minutes, and then rapidly cooled, advantageously using water, to the ambient temperature, after which it is subjected to the ageing process.
  • plastic working is conducted by pressing with oscillating rotations of the die along its axis with an angle in the range of ⁇ (4-25)° and a frequency in the range of 1.-15 Hz.
  • plastic working is conducted by rolling, with at least one of the working rollers moving along its axis or an additional working tool, restricting the roll gap, whereas the movement range may not be higher than 10 mm, and the frequency may not be lower than 2 Hz.
  • the use of the solution presented in the invention obtains a technical and utility effect, which is the shortening of the time needed to anneal alloys during a supersaturation operation, while simultaneously increasing its strength properties.
  • the most advantageous effects are obtained when the initial deformation of the alloy is conducted in condition of a variable deformation path, implemented by the change of the load scheme, which is obtained in the pressing process through the additional use of oscillating die rotations along its axis by an angle in the range of ⁇ (4-25)° and a frequency in the range of 1-15 Hz.
  • Shortening the annealing time in the supersaturation operation with the method presented in the invention is possible due to the generation during the initial deformation of the alloy an above-equilibrium concentration of point defects, advantageously in the conditions of change of the path of deformation.
  • these defects along with the atoms of alloying elements in the temperature below the temperature of occurrence of a solid solution create relatively mechanically and thermally stable nano-sized clusters, which hinder the diffusion, and thus the effectiveness of the aging operation.
  • the aging operation will be preceded by a classic supersaturation operation, including short-term annealing at the temperature from the range of a solid solution presence, the clusters dissolve and point defects are released, significantly accelerating the new phase precipitation.
  • the higher the annealing temperature is in the super-saturation operation the shorter the super-saturation time.
  • the method presented in the invention results in the increase of the strength properties of the products and the efficiency of technological processes including the thermal and thermo-mechanical treatment, is energy-saving and environmentally friendly.

Abstract

The subject of the invention is a method for the manufacturing of elements of non-ferrous metal alloys, advantageously aluminium alloys, used for the manufacturing of shaped elements, in particular rods, in thermal treatment of metal s. It is characterized in that the charge will be subjected to plastic working of at least 60% deformation, advantageously by pressing with the degree of processing exceeding the value of 2, at a temperature below the range of occurrence of a solid solution, after which the obtained element undergoes the supersaturation process by heating it up to the temperature of occurrence of a solid solution and keeping it at this temperature for a period of 2-25 minutes, advantageously 5 minutes, and then rapidly cooled, advantageously using water, to the ambient temperature, after which it is subjected to the ageing process.

Description

Method for the manufacturing of elements of non-ferrous metal alloys, advantageously aluminium alloys
The subject of the invention is a method for the construction of elements of non-ferrous metal alloys, advantageously aluminium alloys, used for the manufacturing of shaped elements, in particular rods, in thermal treatment of metals.
In order to achieve high strength properties, alloys with different solubility when solid, in particular finished products or semi-finished products undergo thermal treatment, which consists of a supersaturation operation and ageing operation, or thermal and thermo-mechanical treatment, composed of, in the following order: supersaturation operation, plastic deformation and ageing operation.
The supersaturation operation consists of heating the alloy to temperature from the range of a solid solution, annealing it for a time necessary to dissolve the secondary phase particles and rapid cooling, as a result of which the alloy in the ambient temperature remains in a single-phase stmcture, which will be theiTnodynamically unstable and will transform during the ageing operation. This operation consists of the heating of the supersaturated alloy to the temperature bel ow the solubility limit and annealed for the time required for precipitation from the supersaturated solid solution of phases with a high degree of dispersion.
Usually, the thermal treatment is conducted on elements with initially or finally shaped geometry, as a result of casting, machining or plastic working. If plastic working is conducted in an appropriately high temperature, which guarantees the alloy will achieve the structure of a solid solution, rapid cooling of the deformed element will result in its supersaturation. In particular, in case of high-temperature pressing of the alloy, the supersaturation may be performed directly at the press delay route, through intensive cooling of the compact, usually with water. Single-phase structure of the alloy, which results from the supersaturation operation, increases its plastic properties and enables intense plastic working of the alloy, up to achieving a product with final geometry, and subsequently the used aging process, as well as the assumed mechanical properties.
Since the annealing of the alloy in an appropriately high temperature, which is an element of the supersaturation, is intended to dissolve the phases and obtain a solid solution, the time of annealing necessary for the full occurrence of the heat activated process of diffusion of alloy components amounts usually from 1 to a few hours. The conditions of alloy annealing are not differentiated depending on whether it was or was not subjected to initial plastic working.
In accordance with the method of aluminium alloy element manufacturing, a charge with dimensions of 040 x 40 mm, of a 7075 aluminium alloy, was pressed on a hydraulic press with a speed of 0.5 mm/s within a temperature of 450°C to which both the charge and the working tools were heated, after which the charge was annealed within this temperature for 2 hours. The obtained rod with a diameter of 12 mm was immediately cooled with water. Then, the rod was aged by annealing at a temperature of 150°C for a time of 3 hours. As a result, the rod obtained a hardness of 160 HV.
In accordance with another used so far method of manufacturing of aluminium alloy elements, in particular of 7075 aluminium alloy, a charge with dimensions of 040 x 40 mm was pressed on a hydraulic press equipped with a mechanical system resulting in oscillating rotation of the die along its axis with an angle of ± 8° with a frequency of 5 Hz. The process of pressing was conducted at a speed of 0.5 mm/s at a temperature of 20°C, without initial heating of the charge and the tools, obtaining a rod with a diameter of 12 mm, which was immediately cooled in water. Then, the rod was aged by annealing at a temperature of 150°C for a time of 3 hours. As a result, the rod obtained a hardness of 137 HV.
The essence of the invention, which is a method of manufacturing non- ferrous metal alloy elements, with the use of plastic working and thermal treatment, advantageously aluminium alloys, consists of the metallic charge being subjected to a plastic deformation of at least 60%, advantageously by pressing with the extrusion ratio exceeding the value of 2, at a temperature below the range of occurrence of a solid solution, after which the obtained element undergoes the supersaturation process by heating it up to the temperature of occurrence of a solid solution and keeping it at this temperature for a period of 2-25 minutes, advantageously 5 minutes, and then rapidly cooled, advantageously using water, to the ambient temperature, after which it is subjected to the ageing process. It is advantageous when plastic working is conducted by pressing with oscillating rotations of the die along its axis with an angle in the range of ±(4-25)° and a frequency in the range of 1.-15 Hz.
It is also advantageous when plastic working is conducted by rolling, with at least one of the working rollers moving along its axis or an additional working tool, restricting the roll gap, whereas the movement range may not be higher than 10 mm, and the frequency may not be lower than 2 Hz.
The use of the solution presented in the invention obtains a technical and utility effect, which is the shortening of the time needed to anneal alloys during a supersaturation operation, while simultaneously increasing its strength properties. The higher the deformation obtained before the thennal or thermal and mechanical treatment is, the shorter the annealing time, whereas the minimum deformation value should be 60%. The most advantageous effects are obtained when the initial deformation of the alloy is conducted in condition of a variable deformation path, implemented by the change of the load scheme, which is obtained in the pressing process through the additional use of oscillating die rotations along its axis by an angle in the range of ±(4-25)° and a frequency in the range of 1-15 Hz.
Shortening the annealing time in the supersaturation operation with the method presented in the invention is possible due to the generation during the initial deformation of the alloy an above-equilibrium concentration of point defects, advantageously in the conditions of change of the path of deformation. On one hand, these defects along with the atoms of alloying elements in the temperature below the temperature of occurrence of a solid solution create relatively mechanically and thermally stable nano-sized clusters, which hinder the diffusion, and thus the effectiveness of the aging operation. On the other hand, if the aging operation will be preceded by a classic supersaturation operation, including short-term annealing at the temperature from the range of a solid solution presence, the clusters dissolve and point defects are released, significantly accelerating the new phase precipitation. Thus, the higher the annealing temperature is in the super-saturation operation, the shorter the super-saturation time.
The method presented in the invention results in the increase of the strength properties of the products and the efficiency of technological processes including the thermal and thermo-mechanical treatment, is energy-saving and environmentally friendly.
Example
Charge of the 7075 aluminium alloy with dimensions of 040 x 40 mm was pressed on a hydraulic press equipped with a mechanical system resulting in oscillating rotation of the die along its axis with an angle of ± 8° with a frequency of 5 Hz. The process of pressing was conducted at a speed of 0.5 mm/s at a temperature of 20°C, without the initial heating of the charge and the tools, obtaining a rod with a diameter of 12 mm, which after air cooling was subjected to rod super-saturation operation, which includes 2 min long heating up to a temperature of 470°C, holding this temperature for 5 min, after which rapid cooling with water was conducted. Then, the rod was aged by annealing at a temperature of 150°C for a time of 3 hours. As a result, the rod obtained a hardness of 192 HV.

Claims

014/126488
6
Claims
A method of manufacturing non-ferrous metal alloy elements, with the use of plastic working and thermal treatment, advantageously aluminium alloys, characterized in that the charge will be subjected to plastic working of at least 60% defonnation, advantageously by pressing with the extrusion ratio exceeding the value of 2, at a temperature below the range of occurrence of a solid solution, after which the obtained element undergoes the supersaturation process by heating it up to the temperature of occurrence of a solid solution and keeping it at this temperature for a period of 2-25 minutes, advantageously 5 minutes, and then rapidly cooled, advantageously using water, to the ambient temperature, after which it is subjected to the ageing process.
A method in accordance with claim 1 , characterized in that plastic working is conducted by pressing with oscillating rotations of the die along its axis with an angle in the range of ±(4-25)° and a frequency in the range of 1-15 Hz.
A method in accordance with claim 1, characterized in that plastic working is conducted by rolling, with an over the axis movement of at least one of the working rollers or an additional working tool, restricting the roll gap, whereas the movement range may not be higher than 10 mm, and the frequency may not be lower than 2 Hz.
PCT/PL2014/000009 2013-02-18 2014-01-31 Method for the manufacturing of elements of non-ferrous metal alloys, advantageously aluminium alloys WO2014126488A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP14707853.9A EP2956252A2 (en) 2013-02-18 2014-01-31 Method for the manufacturing of elements of non-ferrous metal alloys, advantageously aluminium alloys
US14/385,460 US20150376727A1 (en) 2013-02-18 2014-01-31 Method for the manufacturing of elements of non-ferrous metal alloys, advantageously aluminium alloys

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PL402817A PL224248B1 (en) 2013-02-18 2013-02-18 Method for producing parts from non-ferrous alloys, preferably aluminum alloys
PLP.402817 2013-02-18

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WO2014126488A2 true WO2014126488A2 (en) 2014-08-21
WO2014126488A3 WO2014126488A3 (en) 2014-10-16

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EP (1) EP2956252A2 (en)
PL (1) PL224248B1 (en)
WO (1) WO2014126488A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105642692A (en) * 2014-11-18 2016-06-08 宁波市鄞州五洲渔具有限公司 Machining technology of novel aluminum alloy section extrusion die

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE195674T1 (en) * 1994-05-30 2000-09-15 Andrzej Korbel METHOD FOR PLASTIC DEFORMATION OF MATERIALS
JP3654466B2 (en) * 1995-09-14 2005-06-02 健司 東 Aluminum alloy extrusion process and high strength and toughness aluminum alloy material obtained thereby
US20080299000A1 (en) * 2002-09-21 2008-12-04 Universal Alloy Corporation Aluminum-zinc-copper-magnesium-silver alloy wrought product
BR112013005659A2 (en) * 2010-09-08 2016-05-03 Alcoa Inc improved lithium aluminum alloys, and method for producing the same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105642692A (en) * 2014-11-18 2016-06-08 宁波市鄞州五洲渔具有限公司 Machining technology of novel aluminum alloy section extrusion die

Also Published As

Publication number Publication date
EP2956252A2 (en) 2015-12-23
US20150376727A1 (en) 2015-12-31
WO2014126488A3 (en) 2014-10-16
PL402817A1 (en) 2014-09-01
PL224248B1 (en) 2016-12-30

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