WO2014123835A1 - X-ray source with improved target lifetime - Google Patents
X-ray source with improved target lifetime Download PDFInfo
- Publication number
- WO2014123835A1 WO2014123835A1 PCT/US2014/014535 US2014014535W WO2014123835A1 WO 2014123835 A1 WO2014123835 A1 WO 2014123835A1 US 2014014535 W US2014014535 W US 2014014535W WO 2014123835 A1 WO2014123835 A1 WO 2014123835A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- target
- electron beam
- focussing
- ray source
- steering means
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J35/00—X-ray tubes
- H01J35/24—Tubes wherein the point of impact of the cathode ray on the anode or anticathode is movable relative to the surface thereof
- H01J35/30—Tubes wherein the point of impact of the cathode ray on the anode or anticathode is movable relative to the surface thereof by deflection of the cathode ray
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J35/00—X-ray tubes
- H01J35/02—Details
- H01J35/14—Arrangements for concentrating, focusing, or directing the cathode ray
- H01J35/147—Spot size control
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J35/00—X-ray tubes
- H01J35/02—Details
- H01J35/04—Electrodes ; Mutual position thereof; Constructional adaptations therefor
- H01J35/08—Anodes; Anti cathodes
- H01J35/112—Non-rotating anodes
- H01J35/116—Transmissive anodes
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05G—X-RAY TECHNIQUE
- H05G1/00—X-ray apparatus involving X-ray tubes; Circuits therefor
- H05G1/08—Electrical details
- H05G1/70—Circuit arrangements for X-ray tubes with more than one anode; Circuit arrangements for apparatus comprising more than one X ray tube or more than one cathode
Definitions
- the small area of the target that is bombarded by electrons can wear out. If this happens, or before this happens, either the target must be replaced or repositioned, or the entire x-ray tube assembly must be replaced.
- the target In prior x-ray tubes, in order to allow the target to be repositioned so that the electron beam impinges on a new area of the target, the target is typically mounted to the x-ray tube using an elastomer seal. This allows the target to be slid or rotated to a new position, while the tube remains evacuated.
- an elastomer seal has a significant disadvantage.
- the x-ray tube must maintain a good vacuum. Even very small rates of ingress of atmospheric gases will shorten the target life and the life of the filament in the electron gun, and therefore reduce the operational lifetime of the x-ray tube.
- Elastomer seals are unable to maintain a good vacuum for long periods as gases can permeate through the elastomer itself. Also organic elastomers are susceptible to degradation on exposure to x-rays, leading to increased permeation and reduced reliability. It is an object of the present invention to provide an x-ray source with an improved lifetime without compromising the performance of the x-ray source or compromising the spot size of the electron beam on the target material.
- an x-ray source comprising: an enclosure body; a target permanently fixed to or forming part of the enclosure body; an electron beam source within the enclosure body, the electron beam source configured to produce an electron beam along a beam path between the electron beam source and the target, the electron beam incident on the target to generate x-rays; an electron beam focussing assembly positioned around the beam path between the target and the electron beam source, wherein the electron beam focussing assembly comprises a magnetic focussing assembly configured to adjust the spot size of the electron beam on the target, and an aperture within the magnetic focussing assembly, such that in use the electron beam passes through the aperture; a first electron beam steering means positioned around the beam path between the electron beam source and the electron beam focussing element; and a second beam steering means positioned around the beam path between the first electron beam steering means and the focussing assembly, wherein the first and second beam steering means are adjustable to alter a position of incidence of the beam on the target.
- the target being "permanently fixed" to the enclosure body means that the target is fixed in a such a way that either the target, the enclosure body or some bonding material between the two, must be broken to move the target relative to the enclosure body.
- the permanent fixing between the target and the enclosure body can be made using a fixing method or material that is relatively impermeable to gases compared to an elastomer seal and does not degrade on exposure to x-rays.
- Example fixing methods for permanently fixing the target to the enclosure body include brazing, conflat sealing and crushed metal sealing.
- electron beam focussing assembly means any assembly or component that can act to focus or limit an electron beam. This is distinct from “beam steering means” which is an assembly or component that operates to deflect an electron beam without significantly affecting the cross-sectional size or shape of the electron beam. Positioning the second beam steering means between the first electron beam steering means and the electron beam focussing assembly allows the focussing assembly to be positioned as close to the target as possible, providing maximal control over the beam spot size on the target.
- the first or second beam steering means, or both the first and second beam steering means may comprise an electromagnet.
- the first or second beam steering means may then be positioned outside of the enclosure body.
- the first or second beam steering means, or both the first and second beam steering means may comprise a quadrupole magnet and advantageously a "push-pull" type quadrupole magnet.
- the quadrupole magnet may provide magnetic flux in a direction substantially normal to the electron beam path.
- the first or second beam steering means, or both the first and second beam steering means may comprise electrostatic beam steering means.
- the electron beam source may comprise a cathode and an anode.
- the cathode may comprise a filament connected to a high voltage source. Electrons from the cathode at a high electrical potential are accelerated towards the anode to produce an electron beam.
- the x-ray source comprises a controller connected to the second beam steering means, the controller configured to adjust the second beam steering means to alter the position of the beam on the target.
- the controller is configured to alter an angle of incidence of the beam relative to the electron beam focussing assembly.
- the controller is connected to the first beam steering means, the controller configured to adjust the first beam steering means to alter an angle of incidence of the beam relative to the electron beam focussing assembly.
- the first and second beam steering means are configured to provide the electron beam with a dogleg shape.
- the controller may be configured to measure a current flowing from the target to a ground potential. This current, herein referred to as the target current, provides a measure of the number of electrons absorbed by the target.
- the x-ray source may further comprise a backscatter element configured to absorb electrons that are scattered by the target rather than being absorbed.
- the controller may also be configured to measure a current flowing from the backscatter element to a ground potential. This current, herein referred to as the backscatter current, provides a measure of the number of electrons scattered from the target.
- the controller may be configured to calculate a ratio of the target current to the backscatter current.
- the amount of electrons that is absorbed by a target from a given electron beam is dependent on the angle of incidence of the electron beam and the material properties of the target at the point of incidence of the beam. Measuring the target current or the backscatter current can therefore provide information about the condition of the target. This can be used for several purposes. Measuring a ratio of the target current to the backscatter current provides for a measure of the condition of the target that is independent of the number of electrons in the electron beam.
- the controller may be configured to provide a measure of target current, backscatter current or a ratio of target current to backscatter current to a user interface, such as a display connected to or integral with the x-ray source.
- the controller may be configured to provide an alarm or alert to and end user based on a result of a comparison of target current, backscatter current or a ratio of target current to backscatter current, with a threshold value.
- the alert or alarm may be a visual alarm provided on a display connected to or integral with the x-ray source or may be an audible alarm.
- the controller may be configured to automatically alter the position of the beam on the target based on a result of a comparison of target current, backscatter current or a ratio of target current to backscatter current, with a threshold value.
- the target may be provided with a pattern that affects the electron absorption behaviour of the target.
- the pattern can be imaged by scanning the beam over the target and measuring the target current, backscatter current or a ratio of the target current to the backscatter current, to provide a means for optimising the focus of the electron beam on the target.
- the pattern may comprise a pattern of different materials on the target. Alternatively, or in addition, the pattern may comprise a patterned texture on the target surface.
- the pattern may be in the form of a grid or array.
- the focussing assembly may comprise an adjustable magnet or magnets, such as an electromagnet, or an adjustable electrostatic assembly.
- the focussing assembly may be adjusted so as to provide the sharpest image of the pattern. This corresponds to the smallest possible spot size of the electron beam on the target surface.
- Adjustment of the focussing assembly may be carried out automatically by the controller by using image processing software to compare recorded images with an ideal image of the pattern or by comparing recorded images of the pattern with one another.
- the controller may be configured to automatically adjust the focussing assembly to provide the sharpest image of the pattern, or to provide an image that most closely matches the ideal image, in an iterative process. Alternatively, the adjustment of the focussing assembly may be carried out manually.
- a method of measuring the condition of the target in an x-ray source comprising: a) measuring a current flowing from the target to a ground potential when the electron beam is incident at a first position on the target to provide a first target value; b) moving the electron beam to a new position on the target; c) measuring a current flowing from the target to a ground potential when the electron beam is incident at the new position on the target to provide a new target value, wherein each target value is indicative of the condition of the target.
- a method of adjusting the focus of the electron beam on the target in an x-ray source in accordance with the first aspect of the invention, wherein the target comprises a surface pattern of areas with different electron absorption characteristics, comprising: a) measuring a current flowing from the target to a ground potential when the electron beam is incident at a first position on the target to provide a first target value; b) moving the electron beam to a new position on the target; c) measuring a current flowing from the target to a ground potential when the electron beam is incident at the new position on the target to provide a new target value; d) repeating steps b) and c) a plurality of times to provide a set of target values corresponding to an image of at least a portion of the target; e) comparing the set of target values with an ideal set of target values to generate a first measure of beam focussing; f) adjusting a configuration of the electron beam focussing assembly; g) repeating steps a) to
- Figure 2 is a schematic illustration of an x-ray source with an electron beam focussed in a first position
- Figure 3 is a schematic illustration of an x-ray source with an electron beam focussed in a second position
- Figure 4 is a cut-away view of the target assembly in the x-ray tube of Figure 1 .
- FIG. 1 is cross- section of an x-ray tube 10 in accordance with an embodiment of the invention.
- the x-ray tube comprises an enclosure body 12 and a target assembly 14.
- the enclosure body and target assembly together define an evacuable enclosure 15.
- An electron beam is produced within the evacuable enclosure by an electron gun assembly.
- the electron gun assembly comprises a cathode 16 and an anode 18 which are spatially separated.
- a filament 20 is positioned at the cathode.
- the cathode 16 is connected to a high voltage power supply by a high power cable 22.
- the cable is connected to the enclosure by a suitable connector 24.
- the high voltage power supply allows the cathode 16 to be held at a very high negative potential while the anode 18 is held at a ground potential.
- the large potential difference between the anode and the cathode results in electrons being emitted from the cathode and accelerated towards the anode 18.
- the anode is shaped so that the electrons are accelerated towards a gap in the anode, towards the target assembly 14.
- the evacuable enclosure 15 is evacuated by vacuum pumps.
- An ion pump 26 provides a high vacuum and a getter pump 24 is provided to maintain the vacuum within the enclosure over time.
- the beam of electrons emitted from the filament is initially directed to the target assembly 14 by the construction of the anode 18.
- the electron beam can be further manipulated by electromagnets 32, 34 and 36.
- An aperture 30 is provided to remove the outermost electrons from the beam, ensuring that aberrations in the lenses are kept to a minimum, whilst maintaining a reasonable level of electron throughput and therefore tube power.
- the aperture is sized to remove approximately 50% of the beam cross-section so that all aberrant electrons are removed.
- the first set of electromagnets are centering coils 32,
- the centering coils 32 are arranged around the path of the electron beam and comprise four coils forming a quadrupole normal to the electron beam.
- the centering coils centre the electron beam accurately with respect to the aperture 30.
- a set of steering coils 34 are located around the path of the electron beam between the centering coils and the aperture.
- the steering coils allow the electron beam to be moved to impinge on different parts of the target assembly 14 by changing the angle of incidence of the electron beam through the aperture.
- there are four steering coils 34 which are also arranged as a quadrupole normal to the electron beam. Both the centering coils 32 and the steering coils are positioned outside of the enclosure body 12.
- a focussing magnet assembly 36 is provided between the steering coils and the target assembly.
- the focussing magnet assembly 36 operates to control the spot size of the electron beam on the target assembly, counteracting the space-charge effect that tends to expand the electron beam.
- the focussing magnet assembly comprises a single coil arranged coaxially with the path of the electron beam.
- the coil is housed in a soft iron body which directs the magnetic field from the coil into a tight focussing pattern close to the electron beam.
- the soft iron body has an annular air gap that surrounds the aperture. It is at the position of the air gap, where the magnetic field leaks from the soft iron body, that the focussing magnet assembly provides a strong focussing effect, controlling spot size. It is important that the aperture is located at this position as it is here that the beam will always pass through a central point.
- the focussing magnet assembly is provided within the enclosure body 12.
- the focussing magnet assembly 36 and the aperture 30 together form an electron beam focussing assembly.
- the target assembly 14 comprises a target material mounted on a substrate material.
- the target assembly14 is conflat sealed to the enclosure body 12 to provide a gas tight, evacuable enclosure 15.
- the evacuable enclosure has no elastomeric seals which are gas permeable and can degrade and so the enclosure can be maintained with a good vacuum for a long period of time.
- x-rays When the electron beam impinges on the target material x-rays are produced.
- the x-rays pass through the substrate material and exit the x-ray tube.
- the amount of x- rays produced from the target material is monitored by measuring the current flowing from the target to ground. This current correlates directly to the number of electrons incident on the target.
- the centering coils 32 and the steering coils 34 can be electrically controlled.
- the steering coils 34 can be controlled to alter the position at which the electron beam strikes the target.
- Figures 2 and 3 are schematic illustrations of this process.
- Figures 2 and 3 show centering coils 32 and steering coils 34 connected to a controller 40.
- the controller 34 controls the voltage across the centering and steering coils.
- the controller 40 is shown connected to only one of each of the steering and centering coils but in fact the controller is connected to each of the centering and steering coils.
- Figures 2 and 3 also show the electron beam 52, the aperture 30 and the target assembly 14.
- the target assembly 14 comprise a layer of target material 42, which is in this example is tungsten, bonded to a substrate 44.
- the substrate is made from diamond, but may be made from beryllium or aluminium, or any low atomic number element or compound.
- the emitted x-rays 50 are illustrated as dotted lines.
- Figure 2 illustrates a configuration in which the steering coils 34 are not activated, i.e. there is no voltage across any of the steering coils.
- the electron beam 52 passes through the aperture 30 and is focussed on a first spot 46 on the target material. This configuration is maintained for a predetermined length of time, after which degradation of the target material at the first spot 46 becomes likely with continued use.
- the steering coils 34 are then activated and this causes the electron beam 52 to be deflected to a new position on the target as illustrated in Figure 3.
- Figure 3 shows the steering coils 34 and centering coils 32 activated and controlled so that the electron beam 52 has a dogleg shape.
- the electron beam is still directed through the aperture 30 but the angle of incidence through the aperture is altered by the centering and steering coils. As a result the position at which the electron beam impinges on the target is changed to a second position 48. As illustrated in Figure 3 the target has been eroded at the first position 46.
- the steering and centering coils can be electrically controlled to deflect the electron beam to a plurality of further positions on the target. If both the centering coils and the steering coils are arranged in a quadrupole a raster pattern of positions on the target material can be obtained. This deflection to a new position may be carried out automatically and periodically based on usage time of the x-ray tube. Alternatively, the deflection may be carried out based on a user input to the controller.
- the x-ray tube also allows for an automated assessment of the condition of the target to be made. This can be used to determine when and where to move the electron beam on the target.
- Figures 2 and 3 illustrate that the controller 40 may be configured to measure the current flowing to a ground potential from the target. This provides a measure of the number of electrons that are being absorbed by the target. If the target becomes eroded, as shown at position 46 in Figure 3, so that the electron beam is incident on the substrate material, the number of electrons absorbed will be reduced, leading to a lower current measured by the controller 40. Accordingly, if the current measured by the controller suddenly drops, or drops below a threshold value, the controller may control the steering coils 32, 34 to adjust the position of the electron beam on the target. Alternatively, the controller may be configured to alert a user that the beam position needs to be altered by generating a visual or audible indication.
- FIG 4 is a cut-away, perspective view of a target assembly 14.
- the target assembly comprises a target 42 and a backscatter cup 48.
- the backscatter cup 48 comprises a central bore49, through which the electron beam passes before reaching the target 42.
- the backscatter cup absorbs electrons that have rebounded from the target.
- the backscatter cup and target are not electrically connected to one another.
- the controller may be configured to calculate a ratio of the current flowing from the target to ground to the current flowing from the backscatter cup to ground. This provides a ration of the number of electrons absorbed by the target to the number of electrons scattered by the target, and so is independent of the number of electrons in the electron beam.
- the measurement of current from the target and from the backscatter cup, or a ratio of these currents, can also be used to provide an image of the target surface.
- the controller can be configured to move the electron beam across the target to a plurality of discrete positions to perform a scan, such as a raster scan, of the target. At each discrete position, the current or ration of currents can be determined and recorded. In this way an image of the target condition over the entire available target surface can be obtained. This image can be used to decide on suitable positions for the electron beam.
- the beam can then be moved successively to new, suitable positions on a periodic basis or when the target at the current position has become degraded.
- the controller may be connected to the focussing magnet assembly 36 and may be configured to adjust the current supplied to the focussing magnet to adjust the focussing of the electron beam on the target.
- the focussing of the beam on the target may need to be adjusted on setting up the x-ray source and from time to time thereafter to compensate for environmental changes.
- the target may be provided with a pattern 60.
- the pattern may be a pattern formed of different materials or may be surface texturing that affects the number of electrons from the electron beam that are scattered or absorbed by the target.
- the controller is then configured to perform a scan of the target surface, as described above, by moving the electron beam to a plurality of different positions on the target. The resulting image can be compared to an expected image of the pattern.
- the controller then adjusts the focussing of the electron beam on the target by adjusting the supply of current to the focussing magnet assembly and another image recorded.
- the controller may continue to adjust the focus of the electron beam until the recorded image most closely matches the expected image. In other words, the focussing of the electron beam is adjusted until the sharpest possible image of the pattern is obtained.
- An x-ray tube in accordance with the invention has a target permanently fixed to the evacuated enclosure. As the electron beam can be deflected to different positions on the target, there is no need to provide a target that is movable relative to the enclosure body. This eliminates the need for an elastomer seal between the target and the enclosure body. The elimination of elastomer seals has significant benefits in terms of the performance and lifetime of the x-ray tube.
- the arrangement shown in Figures 1 , 2 and 3 provides for deflection of the electron beam prior to the passage of the electron beam through the focussing assembly of the aperture and the focussing magnet. This is advantageous as it allows for point of contact with the target to be altered accurately while allowing for tight control of the beam spot size.
- the focussing of the electron beam is substantially unaffected by the different deflections provided by the centering and steering coils and the electron beam always passes through the centre of the focussing assembly.
- the beam may be deflected either within or after the beam focussing assembly but that arrangement introduces aberrations in the beam and reduces control over the spot size of the beam on the target and so affects the spot size of the x-ray source.
- the arrangement described also provides the advantage of automatic monitoring of target condition and the ability to optimise the focus of the electron beam on the target.
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- X-Ray Techniques (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1512823.4A GB2525111B (en) | 2013-02-05 | 2014-02-04 | X-ray source with improved target lifetime |
DE212014000043.2U DE212014000043U1 (en) | 2013-02-05 | 2014-02-04 | X-ray source with improved target lifetime |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13154072.6A EP2763156A1 (en) | 2013-02-05 | 2013-02-05 | X-ray source with improved target lifetime |
EP13154072.6 | 2013-02-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014123835A1 true WO2014123835A1 (en) | 2014-08-14 |
Family
ID=47709950
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2014/014535 WO2014123835A1 (en) | 2013-02-05 | 2014-02-04 | X-ray source with improved target lifetime |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP2763156A1 (en) |
DE (1) | DE212014000043U1 (en) |
GB (1) | GB2525111B (en) |
WO (1) | WO2014123835A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110999543A (en) * | 2017-08-04 | 2020-04-10 | 昂达博思有限公司 | X-ray generator |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105047509B (en) * | 2015-07-24 | 2017-03-29 | 中国科学院电工研究所 | The focusing arrangement of big beam deflection target practice X-ray source with microbeam |
DE102018100956B4 (en) * | 2018-01-17 | 2021-06-24 | Comet Ag | Transmission target for an open X-ray tube, open X-ray tube, method for recognizing a transmission target and method for setting the parameters of this transmission target |
US11864300B2 (en) | 2021-04-23 | 2024-01-02 | Carl Zeiss X-ray Microscopy, Inc. | X-ray source with liquid cooled source coils |
US11961694B2 (en) | 2021-04-23 | 2024-04-16 | Carl Zeiss X-ray Microscopy, Inc. | Fiber-optic communication for embedded electronics in x-ray generator |
US12035451B2 (en) | 2021-04-23 | 2024-07-09 | Carl Zeiss X-Ray Microscopy Inc. | Method and system for liquid cooling isolated x-ray transmission target |
EP4254464A1 (en) * | 2022-03-29 | 2023-10-04 | Excillum AB | Determination of operational state of x-ray source |
US20240130028A1 (en) * | 2022-10-18 | 2024-04-18 | Carl Zeiss X-ray Microscopy, Inc. | Reflection target X-ray source with steered beam on target |
EP4451308A1 (en) * | 2023-04-18 | 2024-10-23 | Excillum AB | Secondary radiation mitigation |
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EP1557864A1 (en) * | 2004-01-23 | 2005-07-27 | Tohken Co., Ltd. | X-ray microscopic inspection apparatus |
JP2005327497A (en) * | 2004-05-12 | 2005-11-24 | Shimadzu Corp | X-ray generator |
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US20100141151A1 (en) * | 2006-12-28 | 2010-06-10 | Yxlon International Feinfocus Gmbh | X-ray tube and method for examining a target by scanning with an electron beam |
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GB9620160D0 (en) * | 1996-09-27 | 1996-11-13 | Bede Scient Instr Ltd | X-ray generator |
GB9906886D0 (en) * | 1999-03-26 | 1999-05-19 | Bede Scient Instr Ltd | Method and apparatus for prolonging the life of an X-ray target |
DE102010009276A1 (en) * | 2010-02-25 | 2011-08-25 | Dürr Dental AG, 74321 | X-ray tube and system for producing X-ray images for dental or orthodontic diagnostics |
-
2013
- 2013-02-05 EP EP13154072.6A patent/EP2763156A1/en not_active Withdrawn
-
2014
- 2014-02-04 GB GB1512823.4A patent/GB2525111B/en active Active
- 2014-02-04 WO PCT/US2014/014535 patent/WO2014123835A1/en active Application Filing
- 2014-02-04 DE DE212014000043.2U patent/DE212014000043U1/en not_active Expired - Lifetime
Patent Citations (6)
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EP1557864A1 (en) * | 2004-01-23 | 2005-07-27 | Tohken Co., Ltd. | X-ray microscopic inspection apparatus |
JP2005327497A (en) * | 2004-05-12 | 2005-11-24 | Shimadzu Corp | X-ray generator |
JP2006024522A (en) * | 2004-07-09 | 2006-01-26 | Shimadzu Corp | X-ray generation device |
US20070051907A1 (en) * | 2005-09-03 | 2007-03-08 | Alfred Reinhold | Device for generating X-ray or XUV radiation |
US20100141151A1 (en) * | 2006-12-28 | 2010-06-10 | Yxlon International Feinfocus Gmbh | X-ray tube and method for examining a target by scanning with an electron beam |
GB2473137A (en) * | 2009-08-31 | 2011-03-02 | Hamamatsu Photonics Kk | An X-ray generator |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110999543A (en) * | 2017-08-04 | 2020-04-10 | 昂达博思有限公司 | X-ray generator |
CN110999543B (en) * | 2017-08-04 | 2023-08-25 | 昂达博思有限公司 | X-ray generator |
Also Published As
Publication number | Publication date |
---|---|
GB2525111B (en) | 2018-10-31 |
GB201512823D0 (en) | 2015-09-02 |
EP2763156A1 (en) | 2014-08-06 |
GB2525111A (en) | 2015-10-14 |
DE212014000043U1 (en) | 2015-09-24 |
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