WO2014100303A3 - Tampon recyclable pour le traitement hydrocatalytique hydrothermique de biomasse - Google Patents

Tampon recyclable pour le traitement hydrocatalytique hydrothermique de biomasse Download PDF

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Publication number
WO2014100303A3
WO2014100303A3 PCT/US2013/076325 US2013076325W WO2014100303A3 WO 2014100303 A3 WO2014100303 A3 WO 2014100303A3 US 2013076325 W US2013076325 W US 2013076325W WO 2014100303 A3 WO2014100303 A3 WO 2014100303A3
Authority
WO
WIPO (PCT)
Prior art keywords
ammonia
biomass
hydrothermal
hydrothermal hydrocatalytic
hydrocatalytic treatment
Prior art date
Application number
PCT/US2013/076325
Other languages
English (en)
Other versions
WO2014100303A2 (fr
Inventor
Joseph Broun Powell
Glenn Charles Komplin
John Anthony Smegal
Kim Ann JOHNSON
Original Assignee
Shell Oil Company
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Oil Company, Shell Internationale Research Maatschappij B.V. filed Critical Shell Oil Company
Priority to CN201380066742.8A priority Critical patent/CN104903425B/zh
Priority to EP13818620.0A priority patent/EP2935519A2/fr
Publication of WO2014100303A2 publication Critical patent/WO2014100303A2/fr
Publication of WO2014100303A3 publication Critical patent/WO2014100303A3/fr

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/006—Pulping cellulose-containing materials with compounds not otherwise provided for
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
    • C07G1/00—Lignin; Lignin derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
    • C10G1/065—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation in the presence of a solvent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C10G3/55—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds
    • C10G3/56—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds suspended in the oil, e.g. slurries, ebullated beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé de traitement hydrocatalytique hydrothermique de biomasse. Des matières solides de biomasse lignocellulosique sont introduites dans une unité de digestion hydrothermique en présence d'un solvant de digestion, au moins l'un parmi l'ammoniaque ou une source d'ammoniaque, et un catalyseur d'hydrogénolyse supporté contenant (a) du soufre, (b) Mo ou W et (c) Co, Ni ou un mélange de ceux-ci, incorporé dans un support approprié. Les matières solides de biomasse lignocellulosique et le solvant de digestion sont chauffés en présence d'hydrogène, du catalyseur d'hydrogénolyse supporté et dudit un parmi l'ammoniaque ou une source d'ammoniaque formant une solution de produit contenant une pluralité d'hydrocarbures oxygénés et de l'ammoniaque. Au moins une partie de l'ammoniaque est séparée et recyclée vers l'unité de digestion hydrothermique.
PCT/US2013/076325 2012-12-19 2013-12-19 Tampon recyclable pour le traitement hydrocatalytique hydrothermique de biomasse WO2014100303A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201380066742.8A CN104903425B (zh) 2012-12-19 2013-12-19 用于生物质的水热加氢催化处理的可再循环缓冲剂
EP13818620.0A EP2935519A2 (fr) 2012-12-19 2013-12-19 Tampon recyclable pour le traitement hydrocatalytique hydrothermique de biomasse

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261739354P 2012-12-19 2012-12-19
US61/739,354 2012-12-19

Publications (2)

Publication Number Publication Date
WO2014100303A2 WO2014100303A2 (fr) 2014-06-26
WO2014100303A3 true WO2014100303A3 (fr) 2014-08-14

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/076325 WO2014100303A2 (fr) 2012-12-19 2013-12-19 Tampon recyclable pour le traitement hydrocatalytique hydrothermique de biomasse

Country Status (4)

Country Link
US (1) US20140166221A1 (fr)
EP (1) EP2935519A2 (fr)
CN (1) CN104903425B (fr)
WO (1) WO2014100303A2 (fr)

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US9371488B2 (en) 2013-12-18 2016-06-21 Shell Oil Company Biomass pretreatment for hydrothermal hydrocatalytic conversion
CN105829498A (zh) 2013-12-18 2016-08-03 国际壳牌研究有限公司 用于水热加氢催化转化的生物质处理
CN105829499A (zh) 2013-12-18 2016-08-03 国际壳牌研究有限公司 用于水热加氢催化转化的生物质处理
WO2015095454A2 (fr) 2013-12-18 2015-06-25 Shell Oil Company Traitement d'une biomasse pour la conversion hydrocatalytique hydrothermique
WO2015095455A1 (fr) 2013-12-18 2015-06-25 Shell Oil Company Système de lavage continu ou semi-continu d'une biomasse pour la conversion hydrocatalytique hydrothermique
EP3083894A1 (fr) 2013-12-18 2016-10-26 Shell Internationale Research Maatschappij B.V. Traitement de biomasse pour la conversion hydrocatalytique hydrothermique
EP3083892A1 (fr) 2013-12-18 2016-10-26 Shell Internationale Research Maatschappij B.V. Traitement d'une biomasse pour la conversion hydrocatalytique hydrothermique
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US10138428B2 (en) * 2014-05-08 2018-11-27 Reliance Industries Limited Catalyst assisted conversion of biomass to bio-oil
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CA2990437C (fr) 2015-06-30 2023-12-12 Shell Internationale Research Maatschappij B.V. Procede de conversion de biomasse a l'aide d'alumine-silice amorphe pour obtenir un flux monooxygene
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Also Published As

Publication number Publication date
US20140166221A1 (en) 2014-06-19
CN104903425B (zh) 2016-12-14
WO2014100303A2 (fr) 2014-06-26
CN104903425A (zh) 2015-09-09
EP2935519A2 (fr) 2015-10-28

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