WO2014096596A1

WO2014096596A1 - Facility for storing and dispensing fuels, in particular for motor vehicles

Info

Publication number: WO2014096596A1
Application number: PCT/FR2013/052882
Authority: WO
Inventors: Frederic Kolenda; Adriano POLONI; Sylvain BACHER; Michel Angonin
Original assignee: IFP Energies Nouvelles; Covaltech
Priority date: 2012-12-18
Filing date: 2013-11-28
Publication date: 2014-06-26
Also published as: CN105026308A; FR2999553B1; EP2935089A1; FR2999553A1

Abstract

The present invention concerns a facility for storing and dispensing fuels, in particular for motor vehicles, comprising at least one device for dispensing fuel (18), at least one light fuel tank (12, 14), and at least one vent pipe (38), the vent pipe connected to the light fuel tank being provided with an over/underpressure valve (44) and carrying a condenser (40) for condensing petrol vapours coming from said tank. According to the invention, the facility further comprises a dehumidifier (42) for the outside air allowed into the light fuel tank.

Description

Fuel storage and distribution facility, particularly for motor vehicles.

The present invention relates to a fuel storage and distribution installation, in particular for motor vehicles.

In a fuel storage and distribution facility for motor vehicles, such as a service station, the tanks are conventionally filled with different types of fuel. These tanks contain so-called light fuels, such as unleaded gasoline 98 octane (E98), 95 unleaded gasoline octane (E95), the mixture of gasoline and diesel. ethanol (biofuel) as those additives with ethanol up to 10% or up to 85% by volume, called E10 and E85, and so-called heavy fuels, such as oil or diesel.

The major difference between these two types of fuels is the content of volatile organic compounds (VOCs), or gasoline vapors, from the liquid fuel, in the gas phase in thermodynamic equilibrium in the tank with the liquid phase.

For light products, the gas phase can contain between 40 and 90% by volume of VOCs, some of which are very harmful to human health. The gaseous complement is air charged with water vapor or moisture. For heavy products, the VOC content is very low.

It is therefore very important to be able to avoid any emission of VOCs into the atmosphere, in particular for the VOCs entirely generated by the "gasoline" products during tank filling and fuel distribution operations.

Each fuel tank, which is generally buried, has a filling means which connects it to the fuel delivery truck, at least one withdrawal means to a distribution device and a conduit. vent which avoids overpressure or depression of this tank. Each vent is generally provided with a valve to balance the pressure of the storage tank according to whether this tank is in depression or in overpressure.

Thus, during a filling of a storage tank, the liquid fuel, which enters, expels the gas phase contained in this tank to a discharge circuit which includes the vent pipe. Depending on the regulations in place in certain countries, there are two main situations: the direct discharge of this gaseous phase into the atmosphere or the return of the gaseous phase to the delivery truck. This truck leaves again with the recovery of a gaseous phase containing a high content of hydrocarbons of explosive nature. This gaseous phase is then treated at the oil depot when reloading the truck.

This recovery is better known under the name "recovery phase I", which has been in place for many years in European countries in particular. In the case of the distribution of fuel in the tank of a motor vehicle to the distribution station, the liquid fuel supply flushes out of this tank, the gaseous phase loaded with hydrocarbons contained in the tank of the vehicle.

This gaseous phase is then emitted into the atmosphere while, in the storage tank, the volume of liquid fuel thus subtracted is compensated by an air intake coming from the outside, generally through the vent pipe.

To avoid this gas phase emission containing hydrocarbons in the surrounding atmosphere, a complementary regulation called "phase II recovery" has been introduced in some countries. For this, it implements, in the fuel dispensing gun, a collection line by suction of the gas phase of the automobile tank with a return to a storage tank of light products, generally E95.

In theory, the volume of the sucked gas phase is identical to the volume of liquid delivered into the tank, which is not necessarily the case in practice.

This results in an overpressure or depression in the tank with a rebalancing through the vent pipe. This generates either a gas phase emission loaded with hydrocarbons to the outside or an external air inlet loaded with moisture into the tank.

These phenomena are further amplified by significant temperature differences between the storage tank and the ambient air, as is often the case during periods of high temperatures associated with a high relative humidity of the air.

Water vapor is thus brought from outside by the vent pipe for pressure compensation or rebalancing in the storage tanks or by return to the tank of the gaseous phase sucked into the tanks of the cars. even in contact with the outside air and therefore loaded with moisture.

This results in the presence of moisture-laden air in the fuel storage tanks.

This moisture has the disadvantage of causing corrosion of the walls of the tank which, in time, can be pierced with the spillage of fuel in the basement resulting in significant pollution.

In addition, this moisture can cause icing of the water during negative temperature with a risk of clogging the vent ducts or fuel distribution ducts.

As is better described in the document FR 2 827 268, for limiting atmospheric pollution by VOC emission during the operations of tank filling and distribution in the tank of vehicles, as described above, and / or to reduce the return of gaseous hydrocarbons to the delivery truck, the recovery of these gaseous hydrocarbons by refrigerating condensation is most often mentioned.

The negative cold supply thus makes it possible to condense the hydrocarbons in a temperature range below 0 ° C. (typically 0 ° C. to -40 ° C.).

This technique has the disadvantage of also condensing in frost water vapor contained in the gas head of the tank, which has the effect of reducing the condensation performance of gaseous hydrocarbons and impose a systematic defrosting step.

The present invention proposes to overcome the drawbacks mentioned above by proposing a fuel storage and distribution facility that allows both the recovery of gaseous hydrocarbons from light fuels by refrigerating condensation at a negative temperature and the dehumidification of the air. outside when storing and distributing fuels.

To this end, the invention relates to a fuel storage and distribution facility, particularly for motor vehicles, comprising at least one fuel dispensing device, at least one light fuel tank, and at least one vent pipe, the vent pipe connected to the light fuel tank being provided with a pressure / vacuum valve and carrying a condenser for condensing gasoline vapors from said tank, characterized in that the installation further comprises a dehumidifier for outdoor air admitted inside the light fuel tank.

The installation may comprise the dehumidifier and the condenser carried by the vent duct being placed in series with respect to one another. The installation may include the dehumidifier carried by a breathing duct and the condenser carried by the vent duct.

The breathing duct may comprise a non-return valve.

The breathing duct may comprise a vacuum valve calibrated more weakly than the vacuum setting value of the vent pipe valve carrying the condenser. The dehumidifier may include a drain for discharging water extracted from the fluid flowing through it.

The installation may comprise a collector between the vent pipe carrying the condenser and at least one vent pipe coming from a light fuel tank.

The installation may include a gas collection return duct, released during the distribution of light fuel at a dispensing gun of a fuel dispensing device, which leads to the dehumidifier.

The invention also relates to a method for storing and dispensing fuels, in particular for motor vehicles, comprising at least one fuel dispensing device, at least one light fuel tank, and at least one vent pipe, the fuel pipe. vent connected to the light fuel tank being provided with a pressure / vacuum valve and carrying a condenser for condensing gasoline vapors from said tank, characterized in that it consists, at the introduction of outside air in the light fuel tank, to dehumidify the outside air prior to this introduction. The method may include dehumidifying the outside air introduced into the light fuel tank during fuel dispensing operations.

The method can consist in condensing the vapors of gasoline escaping from the tank during filling operations of the tank.

The method may include draining the condensates to one of the light fuel tanks. The other features and advantages of the invention will now appear on reading the following description, given solely by way of illustration and not limitation, and to which are appended:

FIG. 1 is a diagram showing the fuel storage and dispensing installation for motor vehicles according to the invention in a fuel distribution configuration in the tank of a vehicle,

FIG. 2 which illustrates the fuel storage and distribution installation of FIG. 1 in a tank filling configuration,

FIG. 3, which schematically shows a variant of the fuel storage and distribution installation of FIG. 1,

FIG. 4, which is a diagram of a variant of the fuel storage and distribution installation of FIG. 2,

FIG. 5, which is an illustration of another variant of the fuel storage and distribution installation of FIG. 2,

FIG. 6, which shows another variant of the fuel storage and distribution installation of FIG. 4,

FIG. 7 which is a diagram of another variant of the fuel storage and distribution installation of FIG. 1, and

FIG. 8 which illustrates another variant of the fuel storage and distribution installation of FIG. 1. In the example of Figure 1 is shown a storage facility and distribution 10 of at least one fuel.

This installation comprises, in the example, three storage tanks 12, 14, 16 each containing a fuel intended to be distributed by at least one dispensing device 18, such as a meter or pump.

The tanks are intended to receive light fuels, such as ΙΈ98, ΙΈ95 or Biofuel, or a heavy fuel, such as diesel. As an illustration, the tank 12 contains E95, the tank 14 of the biofuel E10 and the tank 16 of the diesel fuel.

Each storage tank is connected to a filling pipe 20,

22, 24 which starts from the tank to arrive at a loading station 26, whose role will be explained later in the description.

Each tank also comprises a vent pipe which originates in the upper part of the tank, respectively a vent pipe 28 for the E95 tank, a vent pipe 30 for the E10 tank and a pipe for the tank. vent 32 for the diesel tank.

The vent pipe 32 of the diesel tank arrives in the atmosphere generally freely (without valve). In the example described, the duct is advantageously provided at its free end with a pressure / vacuum valve 34.

Preferably, the vent ducts 28, 30 of the light fuel tanks result in a manifold 36.

This manifold shares a common vent pipe 38 for the two vent ducts 28 and 30. This common duct carries a condenser 40 for the transformation of a fluid in the vapor phase into a liquid and, in series with the condenser, a dehumidifier 42 which removes the water present in the fluid passing through it. The conduit 38 subsequently opens to the open air being provided, at its free end, a pressure / vacuum valve 44 for controlling the pressure of the tanks, which pressure must be generally close to atmospheric pressure. Preferably, the common vent pipe 38 passes through a device 46 which makes it possible to connect the dehumidifier with the vent pipe 38 and / or with the return pipe to the delivery truck, as will be better described in the following description. .

As best seen in Figure 1, the condenser 40 includes a condensate drain conduit 48 which terminates at one of the fuel tank filling lines, here fuel E95. The dehumidifier 42 comprises a drain 50 for evacuating the water withdrawn from the fluid that has passed through it.

Thus, the vent circuit C comprises the vent ducts 28, 30, the manifold 36, the common vent duct 38 provided with its valve 44 and carrying the condenser and the dehumidifier, both of which are mounted in series. one compared to the other.

Of course and without departing from the scope of the invention, it can be provided a vent pipe for a light fuel storage tank, each vent pipe carrying a condenser, a dehumidifier and a pressure / vacuum valve.

Although this is not shown in the drawing, the condenser and dehumidifier are each part of a fluid circulation circuit that allows to perform the functions to which they are attached.

For example, the condenser 40 is supplied with a heat transfer fluid from a cooling unit of this fluid. This unit can comprise one or more compressors able to cool the fluid passing through the condenser to a temperature of up to -60 ° C.

The dehumidifier 42 is supplied with a heat transfer fluid from either the cooling unit of the condenser or a cooling unit separate from that of the condenser. Preferably, the temperature of the fluid passing through the dehumidifier is slightly positive.

To ensure the distribution of fuel, especially to motor vehicles, the pump 18 is connected to the fuel tanks by a pipe of distribution of which only the distribution lines 52, 54 of light fuels are illustrated in Figure 1.

In the configuration of this figure, the tank of the motor vehicle is connected to the pump 18 by a dispensing gun 56 for filling with a light fuel, here ΙΈ95.

Under the effect of this filling, a slight depression is created in the storage tank 12. This has the effect of causing the opening of the valve 44 of the vent circuit and the introduction of the outside air, which is generally moist, in the tank 12.

Prior to the introduction of this air into the tank, the air admitted into the common vent pipe 38 passes through the dehumidifier 42, which is then in operation, to be rid of its moisture by evacuating the water thus formed by the drain 50. After this passage through the dehumidifier, the water thus formed is discharged through the drain 50 and dry air passes through the condenser 40, which is not in operation, to enter the storage tank 12 by the manifold 36 and the vent duct 28.

A new thermodynamic equilibrium is established between the liquid phase 58 of the fuel and the gaseous sky 60 and this without the presence of water vapor.

This operation therefore makes it possible to ensure a gaseous sky that is free of water vapor in the tank and thus to prevent any icing in the condenser during the tank filling operations, and any condensation in the tank which may lead to corrosion of the walls. and / or degradation of the intrinsic quality of the fuel stored therein. In the configuration shown in Figure 2, the tank 12 is being filled from a tank 62 of a delivery truck 64 through a stripping pipe 66 which is connected to the filling line 20 of this tank by the loading station 26.

During this filling operation, the introduction of fuel into the tank via line 20 has the effect of creating an overpressure inside this tank. This overpressure will cause the opening of the valve 44, which will allow to escape, in part or in all, the gaseous sky 60 of the tank to the vent pipe 28.

The volatile organic compounds (VOCs) of this gaseous atmosphere and in particular the condensable hydrocarbon vapors at negative temperature and the incondensables (nitrogen, oxygen,...) Result in the collector 36 for circulating in the common vent pipe 38.

This gaseous sky passes through the condenser 40 which operates with a negative cold and which condenses the fuel particles of the hydrocarbon vapors into a hydrocarbon liquid phase. This liquid phase is returned, in particular by gravity, into the tank 12 of light fuel E95 via the evacuation duct 48, here through the filling line 20.

The residual gases leaving the condenser 40 continue to circulate in the conduit 38 and then pass through the dehumidifier 42, which is inactive. These gases are then released into the atmosphere through the valve 44 without VOCs or with a minimum of VOC, not condensed at the minimum temperature of the cooling system.

Of course, the above description also applies in the configuration where the fuel distribution and refilling occur based on E10 contained in the storage tank 14.

In the example of the variants of Figures 3 and 4, the dehumidifier 42 and the condenser 40 are no longer arranged in series but in parallel. In these figures, the vent circuit C comprises a vent circuit C1 and another vent circuit C2 placed in parallel with respect to each other.

The vent circuit C1 comprises the vent ducts 28 and 30 of the storage tanks 12 and 14, the manifold 36, the common vent pipe 38 provided with its valve 44 and the condenser 40 with its exhaust duct 48. .

The vent circuit C2, placed in parallel with the circuit C1, being independent of this circuit, comprises an independent vent duct 68, called breathing duct, carrying the dehumidifier 42 with its drain 50. This duct starts from light fuel tanks 12, 14 and opens in the open air by its free end which is provided with a vacuum valve 70.

Advantageously, the breathing duct 68 comprises a branch 72 for connecting the E10 tank to this duct.

In addition, a non-return valve 74 (or any equivalent system) is installed between the tank and the dehumidifier to prevent any rise of gaseous phase (air or air loaded with hydrocarbons) to the dehumidifier. In this arrangement, the valve 70 and the non-return valve 74 are shaped to open only when the tank is in a vacuum to let in outside air while the valve 44 opens only for a overpressure in this same tank.

It should be noted that for the examples described above, the condenser and the dehumidifier have different exchange characteristics so as not to penalize one with respect to the other.

Thus, the flow entering the dehumidifier is much lower than that of the condenser, the proportion can be up to about 15 times. With regard to the powers to exchange, this proportion can reach a ratio of 500 times.

In the configuration of Figure 3, the tank of the motor vehicle is connected to the pump 18 by a dispensing gun 56 for filling with a light fuel, here ΙΈ95.

Under the effect of this filling, a slight depression is created in the storage tank 12. This has the effect of causing the opening of the valve 70 of the vent circuit C2 and the intake of outside air, which is usually wet.

The air admitted into the breathing duct 68 passes through the dehumidifier 42, which is then in operation, to be rid of its moisture. After this passage through the dehumidifier, the dry air ends directly in the storage tank. As previously mentioned, this makes it possible to obtain in the tank a gaseous sky that is free of water vapor and to prevent any icing in the condenser during the tank filling operations, and any condensation in the tank which may lead to corrosion of the tanks. walls thereof and / or degradation of the intrinsic quality of the fuel stored therein.

Preferably, the calibration of the valve 70 of the breathing duct 68 will be lower than that of the vacuum set point of the valve 44 of the vent duct 38 so as to allow the admission of outside air only through this line of breathing.

In the configuration shown in FIG. 4, the tank 12 is being filled from a tank 62 of a delivery truck 64 through a delivery pipe 66.

This filling produces an overpressure inside this tank, which will cause the opening of the valve 44, thus leaving the possibility of the gas skies escaping from the tank to the vent pipe 28 only of the circuit vent C1.

Indeed, given the presence of the non-return valve 74, the gaseous sky can circulate only in the circuit C1.

This gaseous sky arrives at the collector 36, passes through the condenser 40 which operates with a negative cold and which condenses the hydrocarbon vapors in a liquid phase. This liquid phase is returned to the tank 12 of light fuel E95 via the exhaust duct 48.

The residual gaseous phase leaving the condenser 40 is discharged through the conduit 38 to the atmosphere through the valve 44 by not conveying any hydrocarbon vapor or at least a minute amount.

In the examples illustrated in FIGS. 5 and 6 which correspond to the examples of FIGS. 2 and 4, the fuel storage and dispensing installation 10 meets the requirements related to the "recovery phase I" regulation for tank filling operations. with the return of the gases in the tank of the truck. For this, the gaseous phase initially contained in the tank and which is devoid of gasoline through the condensation of hydrocarbon vapors by the condenser 40, as described above, is discharged through the recycling conduit 76 to the tank 62 of the truck 64.

In the case of the installation of FIG. 5 where the condenser 40 and the dehumidifier 42 are placed in series in the vent circuit C, the recycling duct 76 originates on the section of the vent duct 38 between the dehumidifier 42 and the valve 44 to reach the tank 62. Preferably, this recycling duct may originate on the device 46.

For the installation of FIG. 6, the condenser 40 and the dehumidifier 42 are placed in parallel with each other. As previously mentioned, the condenser 40 is placed in a vent circuit C1 and the dehumidifier 42 in another parallel circuit C2. In this configuration, the recycling duct 76 originates on the section of the vent duct 38 between the condenser 40 and the valve 44 to reach the tank 62. As mentioned above, the recycling duct may originate on the device 46.

The examples illustrated in FIGS. 7 and 8, which show the configuration of the examples of FIGS. 1 and 3, correspond to a fuel storage and distribution installation 10 which meets the "phase II recovery" regulation for the distribution operations of fuel in the tank of a motor vehicle.

For this, the filling gun 56 is connected to a gas collection duct 78 which leads to the dehumidifier 42.

As mentioned above, this filling generates either an overpressure in the storage tank, or a vacuum in this tank, with the risk of gaseous phase emissions loaded with hydrocarbons to the outside by the vent duct or an external air inlet loaded with moisture into the tank also through the vent duct.

In the configuration of FIG. 7 with the vent circuit C in which the condenser and the dehumidifier are in series, the gaseous phase coming from the tank of the motor vehicle via the return duct and / or the outside air circulating in the duct 38 end at the dehumidifier 42.

The hydrocarbon gas phase sucked into the tank of the motor vehicle and / or the outside air pass through the dehumidifier which operates at a positive temperature close to zero to possibly condense the water present in this gas mixture. This gaseous phase of gasoline vapors and / or water-free air then enters the condenser (the latter does not work), then inside the storage tank where there is thermodynamic rebalancing between the phase gaseous 60 and the liquid phase 58 without the presence of water vapor.

In a subsequent operation of filling the light fuel tank, as mentioned above, the gaseous sky 60 contains only easily condensable hydrocarbon vapors at negative temperature. Similarly, for the configuration of FIG. 8, the gaseous phase coming from the tank of the motor vehicle by the collection duct 78 and / or the outside air circulating in the vent duct 68 leads to the dehumidifier 42 which is placed in parallel with the condenser 40.

The gaseous phase sucked from the tank of the motor vehicle and / or the outside air pass into the dehumidifier of the vent circuit C2 to rid the water vapor of the outside air and / or the hydrocarbon vapors.

This gaseous phase and / or the outside air devoid of moisture penetrates directly into the fuel tank without passing through the condenser.

Thus, as already mentioned, for a subsequent filling operation of the fuel tank, the gaseous sky 60 will contain only readily condensable hydrocarbon vapors. Although this is not shown, the installation 10 may include a control automaton which will control the various circuits (condenser, dehumidifier, meter ...) and which will adapt the installation to the situation.

Thus, for example, the controller will control the installation so that the default configuration is that of the fuel distribution to the tank of a motor vehicle with the actuation of the fluid circulation circuit connected to the dehumidifier and the stopping the coolant circulation circuit connected to the condenser.

Conversely, during filling operations of the fuel tanks, the controller will control the installation for stopping the fluid circulation circuit connected to the dehumidifier and the actuation of the fluid circulation circuit connected to the condenser.

Claims

1) Fuel storage and distribution installation, in particular for motor vehicles, comprising at least one fuel dispensing device (18), at least one light fuel tank (12, 14), and at least one vent pipe (38), the vent pipe (38) connected to the light fuel tank being provided with a pressure / vacuum valve (44) and carrying a condenser (40) for condensing gasoline vapors from said tank , characterized in that the installation further comprises a dehumidifier (42) for the outside air admitted inside the light fuel tank.

2) Installation according to claim 1, characterized in that the installation comprises the dehumidifier (42) and the condenser (40) carried by the vent duct (38) being placed in series with respect to the other.

3) Installation according to claim 1, characterized in that the installation comprises the dehumidifier (42) carried by a breathing duct (68) and the condenser (40) carried by the vent duct (38).

4) Installation according to claim 3, characterized in that the breathing duct (68) comprises a non-return valve (74).

5) Installation according to claim 3 or 4, characterized in that the breathing duct (68) comprises a vacuum valve (70) calibrated more weakly than the vacuum setting value of the valve of the vent duct (44) carrying the condenser (40).

6) Installation according to one of the preceding claims, characterized in that the dehumidifier (42) comprises a drain (50) for discharging water extracted from the fluid flowing through it. 7) Installation according to one of the preceding claims, characterized in that the installation comprises a manifold (36) between the vent duct (38) carrying the condenser (40) and at least one vent duct (28, 30) from a light fuel tank (12, 14).

8) Installation according to one of the preceding claims, characterized in that the installation comprises a gas collection return duct (78), released during the distribution of light fuel at a dispensing gun (56) a fuel dispensing device (18), which leads to the dehumidifier (42).

9) A method for storing and dispensing fuels, in particular for motor vehicles, comprising at least one fuel dispensing device (18), at least one light fuel tank (12, 14), and at least one fuel line; vent (38), the vent pipe connected to the light fuel tank being provided with a pressure / vacuum valve (44) and carrying a condenser (40) for condensing gasoline vapors from said tank, characterized in that it consists, when introducing outside air into the light fuel tank, to dehumidify the outside air prior to this introduction.

10) A method according to claim 9, characterized in that it consists in dehumidifying the outside air introduced into the light fuel tank during fuel dispensing operations.

1 1) Method according to claim 10, characterized in that it consists in condensing the gasoline vapors escaping from the tank during filling operations of the tank. 12) A method according to claim 1 1, characterized in that it consists in discharging the condensates to one of the tanks of light fuel.