WO2014095568A1 - Produit cosmétique à appliquer sous forme de mousse sur des fibres de kératine - Google Patents

Produit cosmétique à appliquer sous forme de mousse sur des fibres de kératine Download PDF

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Publication number
WO2014095568A1
WO2014095568A1 PCT/EP2013/076386 EP2013076386W WO2014095568A1 WO 2014095568 A1 WO2014095568 A1 WO 2014095568A1 EP 2013076386 W EP2013076386 W EP 2013076386W WO 2014095568 A1 WO2014095568 A1 WO 2014095568A1
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WIPO (PCT)
Prior art keywords
weight
group
product according
total amount
propellant
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Application number
PCT/EP2013/076386
Other languages
German (de)
English (en)
Inventor
Burkhard Müller
Anja Thammasiri
Original Assignee
Henkel Ag & Co. Kgaa
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Application filed by Henkel Ag & Co. Kgaa filed Critical Henkel Ag & Co. Kgaa
Publication of WO2014095568A1 publication Critical patent/WO2014095568A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the present application describes cosmetic products whose compositions can be sprayed as an aerosol and which are present in the form of a foam after spraying.
  • a further subject of this application is a hair styling process in which an aerosol foam is sprayed onto wet hair by spraying the composition, the hair style is subsequently shaped and then dried.
  • Hair sprays can be presented as a non-aerosol (pump spray) with a manually operated pump, or they are filled as aerosols and sprayed as an aerosol over the finished hairstyle. Hairsprays, which are applied in the form of an aerosol, represent the more convenient dosage form for the user.
  • Hairsprays and mousses are very different in their tasks and applications. Mousse dispensers are distributed for styling hair in damp hair and then dried, hair sprays are sprayed to fix on the finished styled hairstyle. Both product groups can be assigned specific advantages and disadvantages.
  • So mousses are particularly suitable to make a hairstyle starting from wet hair.
  • a foam is unsuitable for styling, especially at the hairline, as it can not be applied precisely in the area of the hairline. Styling foams are therefore usually not the product of choice for styling that only takes place at the hairline.
  • Hair sprays are very well suited to be used precisely at the hairline. However, hair sprays have their best effect only on dry hair, on wet hair hair sprays do not stop. When applying the hair spray on dry hair, the time available to the hairdressing stylist is also very short.
  • Spray foams offer a way to combine the advantages of both product groups.
  • a spray foam represents a product category that is formulated as an aerosol and therefore can be sprayed precisely on the hairline. Since this is a sprayable mousse, this spray foam can also be applied to wet hair and designed the hairstyle starting from wet hair.
  • Spray foams are applied in the form of an aerosol.
  • An aerosol is a disperse system in which a solid or a liquid is very finely dispersed in a gas.
  • the aerosol is usually only when using a suitable spray system by spraying solutions, emulsions or suspensions self-produced, including, for example, spray cans can be used, in which a liquefied compressed gas serves as a propellant gas.
  • a liquefied compressed gas serves as a propellant gas.
  • the spray foams known from the prior art have the disadvantage that the foam produced after spraying has little foam volume and breaks quickly. Another disadvantage is that the spray often does not fan out as desired during spraying. Too little fanning of the spray jet leads to an uneven application of Sprühguts, whereby certain parts of hair overloaded with Sprühgut, other parts of hair, however, are not wetted with sprayed material. In this case, a satisfactory hairstyle design is no longer possible.
  • the styling product should be precisely applicable in the hairline area.
  • the spray jet should have a sufficiently high fanning, which ensures the uniform application and a good styling result.
  • the spray foam applied with the styling product should also give wet hair a high hold, whereby the hairstyle design starting from wet hair is possible.
  • a product which is made up as an aerosol has an aerosol delivery device and emits a composition containing a special combination of two different propellant gases, at least one cationic surfactant and contains at least one water-soluble alcohol.
  • a first subject of the present application is a cosmetic product for foam application to keratinic fibers, in particular human hair, comprising an aerosol pressure container, an aerosol dispenser and a cosmetic composition containing
  • one or more further propellant gases selected from the group consisting of propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, isopentane and isopentene,
  • the cosmetic product comprises an aerosol pressure vessel.
  • pressure gas container come vessels made of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is coated with plastic outside, in question, in their selection pressure and fracture resistance, corrosion resistance, easy fillability as well as aesthetic aspects, Handiness, printability etc. play a role.
  • Special internal protective lacquers ensure corrosion resistance to the preparation contained in the Aersosol pressure vessel.
  • the internal pressure of the aerosol pressure vessel is at least 1.8 bar, in particular at least 2.5 bar.
  • the product further comprises an aerosol dispenser having a valve for delivering the aerosol.
  • the aerosol dispenser comprises a valve having a poppet and / or a flexible element having a return characteristic coated with a lacquer or a polymeric plastic A are preferred according to the invention.
  • the valve has a flexible element with a return characteristic and / or a valve disk of at least one plastic B, preferably an elastomeric plastic.
  • plastic B elastomeric plastics.
  • Particularly preferred elastomeric plastics are selected from Buna, in particular Buna N, Buna 421, Buna 1602 and Buna KA 6712, neoprene, butyl and chlorobutyl.
  • the flexible element with return characteristic can be formed as a spiral spring or helical compression spring.
  • the flexible element of the valve with return characteristic can be formed integrally with the valve cone and have flexible legs. This spring can be made of metal or plastic.
  • valve cone and flexible element with a return characteristic are formed.
  • valve type Ariane M available from the company Seaquist Perfect, in which the flexible element with restoring characteristic in the form of four elastic legs is formed integrally with the valve cone.
  • All the valves used in the invention preferably have an internally painted valve disk, wherein paint and valve material are compatible with each other.
  • their valve disks can be internally z. B. be coated with Micoflex paint.
  • tinplate valves are used according to the invention, their valve disks can be internally z. B. be coated with PET (polyethylene terephthalate).
  • PET polyethylene terephthalate
  • the used containers, the z. B. tinplate or aluminum may be, aluminum containers are preferred according to the invention, in view of the corrosivity of the present invention used in water emulsions must also be painted or coated inside.
  • a preferred according to the invention Inner protective lacquer is an epoxy phenolic lacquer, as it is available, inter alia, under the name Hoba 7407 P.
  • valve is a type Aptar ARM-4.00- 1-0, 32-8, 70 Green-AR Housing-Valve-AHT-1, 60-0.00 PA Natural.
  • the cosmetic composition contains as the first essential component (a) dimethyl ether as the first propellant gas.
  • Dimethyl ether leads as blowing agent (a) together with the blowing agents of group (b) and the other essential formulation components to an optimal fanning of the spray jet.
  • dimethyl ether is present as propellant gas (a) in certain quantitative ranges in the composition according to the invention.
  • the cosmetic products can therefore dimethyl ether in an amount of 2 to 20 wt .-%, preferably from 4 to 18 wt .-%, more preferably from 6 to 16 wt .-% and particularly preferably from 8 to 12 wt .-% - based on the total weight of the blowing agent-containing composition - included.
  • a product according to the invention is characterized in that it contains as the first propellant dimethyl ether (a) in an amount of from 2 to 20% by weight, preferably from 4 to 18% by weight, more preferably from 6 to 16% by weight .-% and particularly preferably from 8 to 12 wt .-% - based on the total weight of the blowing agent-containing composition - contains.
  • the composition of the product according to the invention contains one or more further propellant gases selected from propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, isopentane and isobutane. pentene.
  • blowing agent (b) also greatly influences the fanning of the spray jet.
  • the composition of the blowing agents (a) and (b) also surprisingly has an influence on the foam stability.
  • An optimal fanning of the spray jet can be achieved if one or more blowing agents from the group of n-butane, isobutane and / or propane are used in the composition of the product according to the invention as further blowing agents (b).
  • a product according to the invention is therefore characterized in that in addition to dimethyl ether as the first propellant gas (a) it contains one or more further propellant gases (b) from the group n-butane, isobutane and / or propane.
  • the propellant gases (b) are also contained in the composition in specific quantitative ranges.
  • the products according to the invention contain one or more further propellant gases (b) selected from the group consisting of propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, isopentane and isopentene in a total amount of 1 to 10 wt .-%, preferably from 2 to 9 wt .-%, more preferably from 3 to 8 wt .-% and particularly preferably from 4 to 7 wt .-% - based on the total weight of the blowing agent-containing Composition.
  • a product according to the invention is characterized in that it contains one or more propellant gases (b) from the group of n-butane, isobutane and propane in a total amount of from 1 to 10% by weight, preferably from 2 to 9 Wt .-%, more preferably from 3 to 8 wt .-% and particularly preferably from 4 to 7 wt .-% - based on the total weight of the blowing agent-containing composition - contains.
  • propellant gases b
  • n-butane is used as the only propellant gas from the group of propellant gases (b).
  • a product according to the invention is therefore characterized in that it contains as propellant gas (b) n-butane in an amount of from 1 to 10% by weight, preferably from 2 to 9% by weight, more preferably from 3 to 8 wt .-% and particularly preferably from 4 to 7 wt .-% - based on the total weight of the blowing agent-containing composition - contains.
  • a preferred product according to the invention can furthermore be characterized in that it contains dimethyl ether as blowing agent (a), n-butane as blowing agent (b) and, moreover, no further blowing agents (blowing gases).
  • the foam obtained by spraying the composition of the invention is characterized in particular by a very good foam quality, when the propellants contained in the composition (a) and (b) are used in certain proportions to each other.
  • the spray jet is fanned out widely when the propellant gases (a) and (b) are present in optimized proportions in the preparation according to the invention.
  • the weight ratio of the amount of the propellant dimethyl ether contained in the product (a) to the total amount of the propellant from group (b) contained in the product at a value of 5: 1 to 1: 2, preferably from 4: 1 to 1: 1, more preferably 3: 1 to 3: 2, and most preferably 2: 1.
  • a product according to the invention is therefore characterized in that - based on the total weight of the propellant composition - the weight ratio of the amount of the propellant contained in the product dimethyl ether (a) to the total amount of propellant contained in the product from the propane group , Propene, n-butane, iso-butane, iso-butene, n-pentane, pentene, iso-pentane and iso-pentene (b) at a value of 5: 1 to 1: 2, preferably from 4: 1 to 1 : 1, more preferably at 3: 1 to 3: 2, and most preferably at 2: 1.
  • a product according to the invention may contain, in addition to the propellant gases (a) and (b) essential to the invention, also further propellant gases.
  • Further blowing agents which are suitable according to the invention are nitrogen, air, oxygen, nitrous oxide, 1,1,1,3-tetrafluoroethane, heptafluoro-n-propane, perfluoroethane, monochlorodifluoromethane, 1,1-difluoroethane, both individually and in combination.
  • hydrophilic propellants such. As carbon dioxide, can be used advantageously in the context of the present invention, when the proportion of hydrophilic gases is selected low and lipophilic propellant gas (eg., Propane / butane) is present in excess.
  • the composition of the product according to the invention comprises at least one cationic surfactant (c).
  • Cationic surfactants are understood to mean surfactants, ie surface-active compounds, each having one or more positive charges. Cationic surfactants contain only positive charges. Usually, these surfactants are composed of a hydrophobic part and a hydrophilic head group, wherein the hydrophobic part usually consists of a hydrocarbon skeleton (eg consisting of one or two linear or branched alkyl chains), and the positive charge (s) are located in the hydrophilic head group. Cationic surfactants adsorb at interfaces and aggregate in aqueous solution above the critical micelle concentration to positively charged micelles.
  • Quaternary ammonium compounds which can carry as hydrophobic radicals one or two alkyl chains with a chain length of 8 to 28 carbon atoms
  • quaternary phosphonium salts substituted with one or more alkyl chains having a chain length of 8 to 28 C atoms or
  • the cationic charge may also be in the form of an onium structure as part of a heterocyclic ring (e.g., an imidazolium ring or a pyridinium ring).
  • the cationic surfactant may also contain other uncharged functional groups, this is the case with Esterquats
  • the use of the cationic surfactants (c) contained in the product according to the invention has a significant influence on the quality and stability of the foam obtained by the spraying process.
  • the total amount of cationic surfactants (c) present in the product according to the invention is therefore within preferred ranges.
  • a very particularly preferred product according to the invention is characterized in that it contains one or more cationic surfactants (c) in a total amount of from 0.05 to 1.3% by weight, preferably from 0.09 to 1.1% by weight, more preferably from 0, 13 to 0.8 wt .-% and particularly preferably from 0, 17 to 0.4 wt .-% - based on the total weight of the blowing agent-containing composition - contains.
  • the cationic ammonium compounds of the formula (I) have proved to be particularly suitable because of their outstanding compatibility with the other essential constituents (a), (b) and (d), R1
  • R 1, R 2 independently of one another represent a hydrogen atom, a C 1 -C 6 -alkyl group, a C 2 -C 6 -
  • R 3 is a hydrogen atom, a C 1 -C 7 -alkyl group, a C 8 -C 2 8-alkyl group,
  • R4 is a C 8 -C 28 alkyl group
  • X- represents a physiologically acceptable anion
  • a product according to the invention is therefore characterized in that it contains as cationic surfactant (s) (c) one or more compounds of the formula (I),
  • R 1, R 2 independently of one another represent a hydrogen atom, a C 1 -C 6 -alkyl group, a C 2 -C 6 -
  • R 3 is a hydrogen atom, a C 1 -C 7 -alkyl group, a C 8 -C 28 -alkyl group,
  • R4 is a C 8 -C 28 alkyl group
  • X- represents a physiologically acceptable anion
  • the substituents of the compound of formulas (I) to (II I) are exemplified below:
  • a Ci-Cö-alkyl group are the groups methyl, ethyl, propyl, isopropyl, n-butyl, s-butyl and t-butyl, n-pentyl and n-hexyl.
  • Propyl, ethyl and methyl are preferred alkyl radicals.
  • Examples of a C 2 -C 6 -alkenyl group are vinyl, allyl, but-2-enyl, but-3-enyl and isobutenyl, preferred C 2 -C 6 -alkenyl radicals are vinyl and allyl.
  • hydroxy-C 1 -C 6 -alkyl group are hydroxymethyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, 4-hydroxybutyl, 5-hydroxypentyl and 6-hydroxyhexyl ; a 2-hydroxyethyl group is particularly preferred.
  • R 1 and R 2 independently of one another are a C 1 -C 6 -alkyl group. It is particularly preferred if R1 and R2 independently of one another are a methyl group, an ethyl group or an n-propyl group. In a very particularly preferred embodiment, R 1 and R 2 both represent a methyl group or both represent an ethyl group.
  • R4 and optionally R3 stand for a C 8 -C 28 alkyl group. These alkyl groups may be branched or unbranched, saturated or unsaturated. If the C 8 -C 28 -alkyl group is not is saturated, it may be mono- or polyunsaturated, ie possess one or more double bonds.
  • R3 is preferably a C 1 -C 7 -alkyl group. Most preferably, R3 is a methyl group, an ethyl group or a propyl group, in particular a methyl group.
  • R 4 is a linear, saturated C 6 -C 2 2-alkyl group, this has a particularly advantageous effect on the properties of the foam produced by spraying.
  • R4 is therefore for a linear, saturated C 6 -C 2 2-alkyl group. It is very particularly preferred if R 4 is a linear, saturated C 2 o-alkyl group or a linear, saturated C 2 2-alkyl group.
  • a product according to the invention is therefore characterized in that it contains as cationic surfactant (s) (c) one or more compounds of the formula (I),
  • R1, R2 independently represents a Ci-C ö alkyl group, preferably both a
  • R 3 represents a methyl group, an ethyl group or a propyl group, preferably one
  • Methyl group is, and
  • R 4 is a C 16 -C 2 2-alkyl group, preferably a C 2 o-alkyl group or a C 22 -
  • Alkyl group stands.
  • Product characterized in that it contains as cationic surfactant (s) (c) one or more
  • R1, R2 both represent a methyl group
  • R3 is a methyl group
  • R 4 is a C 20 alkyl group or a C 22 alkyl group.
  • Preferred cationic surfactants of the formula (I) are, for example, physiologically tolerable salts of N, N, N-trimethyl-1-hexadecanaminium, in particular N, N, N-trimethyl-1-hexadecanaminium chloride, which is also available under the trade name Dehyquart A-CA is sold. Also preferred are salts of trimethylstearylammonium, in particular trimethylstearylammonium chloride, which is also commercially available under the trade name Genamin STAC.
  • cationic surfactants of the formula (I) are salts of trimethyl-1-eicosanaminium, in particular trimethyl-1-eicosanaminium chloride, and salts of trimethyl-1-docosanaminiums, in particular trimethyl-1-docosanaminiumchlorids.
  • a mixture of both compounds is available under the trade name Genamin KDMP from Clariant.
  • Preferred cationic surfactants (c) can also be selected from the group of cationic imidazolium compounds. Within the group of cationic imidazolium compounds, compounds of formula (II) have also been found to be particularly advantageous in terms of the properties of the foam resulting after spraying.
  • a product according to the invention is characterized in that it contains as cationic surfactant (c) one or more compounds of the formula (II),
  • R5 is a Ci-C6-alkyl group
  • R6, R7 independently of one another represent a C 7 -C 2 7-alkyl group
  • R6 and R7 are each independently a C 7 -C 2 7 alkyl group. These alkyl groups may be branched or unbranched, saturated or unsaturated. If the C 7 -C 27 -alkyl group is unsaturated, it may be mono- or polyunsaturated, ie possess one or more double bonds.
  • the product according to the invention provides, in particular, a spray foam with good performance properties when it contains a cationic surfactant (c) of the formula (II) in which
  • R5 is a methyl group
  • R6, R7 independently of one another represent a C 8 -C 2 7-alkyl group
  • esterquats are a collective name for cationic surfactants having two hydrophobic groups linked by ester bonds to a quaternized di- or triethanolamine or an analogous compound.
  • very particularly suitable esterquats are the compounds of the formula (III)
  • R 8, R 9 independently of one another are a C 1 -C 6 -alkyl group or a C 2 -C 6 -
  • R 10, R 1 independently of one another represent a C 7 -C 2 7-alkyl group and
  • X- represents a physiologically acceptable anion
  • a product according to the invention is characterized in that it contains as cationic surfactant (c) one or more compounds of the formula (III),
  • R8, R9 independently represent a Ci-C ö alkyl group or a C 2 -C 6 -
  • R 10, R 1 independently of one another represent a C 7 -C 2 7-alkyl group and
  • X- represents a physiologically acceptable anion
  • X " in the formulas (I) to (III) is in each case a physiologically tolerable anion Suitable physiologically acceptable anions are halide, hydrogensulfate, sulfate, benzenesulfonate, p-toluenesulfonate, acetate, citrate, lactate, tartrate, methylsulfate (H 3 COSO 3 " ), methyl sulfoant or trifluoromethanesulfonate. Particularly preferably A “is chloride, bromide or methyl sulfate
  • the composition of the product according to the invention comprises at least one water-soluble alcohol having 2 to 9 C atoms and 1 to 6 hydroxy groups.
  • the alcohol having 2 to 9 carbon atoms and 1 to 6 hydroxyl groups is preferably selected from at least one compound from the group ethanol, ethylene glycol, isopropanol, 1, 2-propylene glycol, 1, 3-propylene glycol, glycerol, n-butanol, 1, 3 butylene glycol.
  • Particularly preferred alcohols are ethanol and isopropanol, most preferably ethanol.
  • the amount of the or the water-soluble alcohols contained in the product according to the invention also greatly influences the properties and the fanning the spray jet.
  • the amounts of the water-soluble alcohols (d) contained in the product are chosen such that their total amount is 14 to 35% by weight, preferably 17 to 32% by weight, more preferably 20 to 29% by weight. and particularly preferably at 23 to 26 wt .-% - based on the total weight of the blowing agent-containing composition - is.
  • the fanning of the spray is at least 20 °, which ensures a uniform spray application of the compositions according to the invention on the hair tip region. Explicitly very particularly preferred is when ethanol is used in these amounts.
  • a product according to the invention is characterized in that it contains, as the water-soluble alcohol (d), ethanol in an amount of from 14 to 35% by weight, preferably from 17 to 32% by weight, more preferably from 20 to 29 Wt .-% and particularly preferably from 23 to 26 wt .-% - based on the total weight of the blowing agent-containing composition - contains.
  • d water-soluble alcohol
  • ethanol in an amount of from 14 to 35% by weight, preferably from 17 to 32% by weight, more preferably from 20 to 29 Wt .-% and particularly preferably from 23 to 26 wt .-% - based on the total weight of the blowing agent-containing composition - contains.
  • the composition of the product according to the invention contains water.
  • a water content of more than 60 wt .-% adversely affects the overall performance of the product according to the invention.
  • a product according to the invention is characterized in that it contains a maximum of 60% by weight of water (s), preferably not more than 56% by weight of water, more preferably not more than 52% by weight of water and particularly preferably not more than 48% by weight .-% water - based on the total weight of the blowing agent-containing composition - contains.
  • a particularly preferred product according to the invention is characterized in that it contains an aerosol pressure vessel, an aerosol Dispenser and containing a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition (a) 2 to 20% by weight of dimethyl ether as the first propellant,
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • Another particularly preferred product according to the invention characterized in that it contains an aerosol pressure vessel, an aerosol dispenser and a cosmetic composition
  • the products of the invention may additionally contain other formulation ingredients as optional ingredients.
  • the products according to the invention may additionally comprise one or more film-forming and / or setting polymers.
  • Film-forming polymers are to be understood as meaning those polymers which, on drying, form a continuous film leave on the keratin fibers. Particular preference is given to polymers which have a sufficient solubility in water or water / alcohol mixtures in order to be present in the product according to the invention in completely dissolved form.
  • the film-forming polymers may be of synthetic or natural origin.
  • Firming polymers contribute to the maintenance and / or build-up of the hair volume and hair fullness of the overall hairstyle. These polymers are at the same time also film-forming polymers and therefore generally typical substances for shaping hair treatment agents such as hair fixatives, hair foams, hair waxes, hair sprays.
  • the film formation can be quite selective and connect only a few fibers.
  • the film-forming and / or setting polymer may be cationic, nonionic and anionic polymers.
  • Cationic polymers are to be understood as meaning polymers which have a group in the main and / or side chain which may be “temporary” or “permanent” cationic.
  • "permanently cationic” refers to those polymers which have a cationic group, irrespective of the pH of the agent. These are usually polymers containing a quaternary nitrogen atom, for example in the form of an ammonium group.
  • Preferred cationic groups are quaternary ammonium groups.
  • those polymers in which the quaternary ammonium group are bonded via a CI_ 4 hydrocarbon group to a synthesized from acrylic acid, methacrylic acid or derivatives thereof, polymer backbone have been found to be particularly suitable.
  • Preferred cationic film-forming and / or setting polymers are, for example
  • Copolymers of N-vinylpyrrolidone, N- (3-dimethylaminopropyl) methacrylamide and 3- (methacryloylamino) propyl-lauryl-dimethylammonium chloride (INCI name: Polyquaternium-55), which, for example, under the trade name Styleze W 10 or Styleze W 20 (10 or 20% by weight of active substance in ethanol-water mixture) is sold by the company ISP.
  • Dimethylaminopropyl) methacrylamide and 3- (methacryloylamino) propyl-lauryl dimethylammonium chloride (INCI name: Polyquaternium-69), which, for example, under the trade name AquaStyle ® 300 (28-32 wt .-% active ingredient in ethanol-water mixture) of the Company ISP is distributed.
  • the cationic film-forming and / or cationic fixing polymers are particularly preferably selected from cationic, quaternized cellulose derivatives.
  • Further suitable cationic and / or setting polymers are preferably cationic, quaternized cellulose derivatives.
  • Such cationic, quaternized celluloses prove to be particularly advantageous for the purposes of the invention, which carry more than one permanent cationic charge in a side chain.
  • these cationic celluloses such cationic celluloses with the INCI name Polyquaternium-4 in turn, are particularly suitable, which are sold for example under the names of Celquat ® H 100, Celquat L 200 ® by the company National Starch.
  • the product according to the invention may also contain at least one film-forming nonionic and / or setting nonionic polymer.
  • a nonionic polymer is understood as meaning a polymer which carries in a protic solvent under standard conditions substantially no structural units having cationic or anionic groups which have to be compensated by counterions while maintaining the electroneutrality.
  • the film-forming nonionic and / or setting nonionic polymers are preferably present in the composition according to the invention in an amount of from 0.1 to 20.0% by weight, more preferably from 0.2 to 15.0% by weight .-%, most preferably from 0.5 wt .-% to 10.0 wt .-%, each based on the weight of the inventive composition.
  • homopolymers of vinyl caprolactam or vinyl pyrrolidone such as Luviskol ® K 90 or Luviskol ® K 85 from BASF SE
  • copolymers of vinylpyrrolidone and vinyl acetate such as Luviskol ® K 90 or Luviskol ® K 85 from BASF SE
  • the molar ratio of the contained from the monomer N-vinyl pyrrolidone Structural units to the structural units of the polymer contained from the monomer vinyl acetate in the range of 20 to 80 to 80 to 20, in particular from 30 to 70 to 60 to 40, for example, sold under the trademark Luviskol ® VA 37, Luviskol ® VA 55, Luviskol ® VA 64 and Luviskol ® VA 73 (from the firm BASF SE), terpolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate, polyacrylamides such as Akypomine ® P 191 (from the company CHEM-Y), polyvinyl alcohols, for example, under the
  • anionic polymer is the polymer sold under the trade name Amphomer ® 028-4910 from National Starch with the INCI name octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer.
  • Suitable anionic polymers are available from Seppic under the trade name Sepigel ® 305 (INCI name: Polyacrylamide, C13-14 isoparaffin, laureth-7) or Simulgel ® 600 (INCI name: Acrylamide / Acryloyldimethyltaurate Copolymer, Isohexadecane, Polysorbate-80 ) known.
  • Copolymers of acrylamide with methacrylic acid and acryloyldimethyltaurate are available for example under the trade name Acudyne ® SCP (Rohm & Haas). Also suitable are the polymers known by the trade name Aristoflex A 60 (INCI name: VA / Crotonates Copolymer), from BASF under the trade name Luviset CA 66 (vinyl acetate / crotonic acid copolymer 90:10, INCI name VA / Crotonates Copolymer ) and polymers sold by the company National Starch under the trade name Resyn 28-2942 or Resyn 28-2930 (INCI name: VA / Crotonates / Vinyl Neodecanoate Copolymer) commercially available polymers.
  • Aristoflex A 60 ICI name: VA / Crotonates Copolymer
  • Luviset CA 66 vinyl acetate / crotonic acid copolymer 90:10, INCI name VA
  • the products according to the invention may additionally contain at least one further nonionic, anionic and / or ampholytic surfactant.
  • the group of ampholytic or amphoteric surfactants includes zwitterionic surfactants and ampholytes.
  • the surfactants according to the invention may already have emulsifying activity.
  • the additional surfactants are in the inventive composition preferably in an amount of 0.01 wt .-% to 5 wt .-%, particularly preferably from 0.05 wt .-% to 0.5 wt .-%, each based on the Weight of the agent, included.
  • the products according to the invention may additionally contain at least one silicone, in particular at least one silicone oil.
  • silicone oils which are suitable according to the invention are in particular dialkyl and alkylaryl siloxanes, such as, for example, dimethylpolysiloxane and methylphenylpolysiloxane, and also their alkoxylated, quaternized or else anionic derivatives. Preference is given to cyclic and linear polydialkylsiloxanes, their alkoxylated and / or aminated derivatives, dihydroxypolydimethylsiloxanes and polyphenylalkylsiloxanes.
  • silicone oils is understood by the person skilled in the art as meaning several structures of silicon-organic compounds. Initially, this is understood to mean the dimethiconols.
  • Examples of such products include the following commercial products: Botanisil NU-150M (Botanigenics), Dow Coming 1-1254 Fluid, Dow Corning 2-9023 Fluid, Dow Corning 2-9026 Fluid, Ultrapure Dimethiconol (Ultra Chemical), Unisil SF- R (Universal Preserve), X-21-5619 (Shin- Etsu Chemical Co.), Abil OSW 5 (Degussa Care Specialties), ACC DL-9430 Emulsion (Taylor Chemical Company), AEC Dimethiconol & Sodium Dodecylbenzenesulfonate (A & E Connock (Perfumery & Cosmetics) Ltd.), BC Dimethiconol Emulsion 95 (Basildon Chemical Company, Ltd.), Cosmetic Fluid 1401, Cosmetic Fluid 1403, Cosmetic Fluid 1501, Cosmetic Fluid 1401 DC (all aforementioned Chemsil Silicones, Inc.), Dow Corning 1401 Fluid, Dow Corning 1403 Fluid, Dow Corning 1501 Fluid, Dow Corning 1784 HVF Em
  • Dimethicones form the second group of silicones which may be present according to the invention. These may be both linear and branched as well as cyclic or cyclic and branched.
  • Dimethicone copolyols form another group of silicones that are suitable.
  • Corresponding dimethicone copolyols are commercially available and are sold, for example, by Dow Corning under the name Dow Corning® 5330 Fluid.
  • the teaching according to the invention also encompasses the fact that the dimethiconols, dimethicones and / or dimethicone copolymers can already be present as an emulsion.
  • the corresponding emulsion of dimethiconols, dimethicones and / or dimethicone copolyols can be prepared both after the preparation of the corresponding dimethiconols, dimethicones and / or dimethicone copolyols from these and the conventional methods of emulsification known to the person skilled in the art.
  • both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions.
  • the emulsions of dimethiconols, dimethicones and / or dimethicone copolyols can also be prepared directly by an emulsion polymerization process. Such methods are also well known to the person skilled in the art.
  • the droplet size of the emulsified particles according to the invention 0.01 to 10,000 ⁇ , preferably 0.01 to 100 ⁇ , more preferably 0.01 to 20 ⁇ and most preferably 0 , 01 to 10 ⁇ .
  • the particle size is determined by the method of light scattering.
  • branched dimethiconols, dimethicones and / or dimethicone copolyols are used, it is to be understood that the branching is greater than a random branching, which occurs randomly due to impurities of the respective monomers.
  • branched dimethiconols, dimethicones and / or dimethicone copolyols are therefore to be understood as meaning that the degree of branching is greater than 0.01%.
  • a degree of branching is greater than 0.1%, and most preferably greater than 0.5%.
  • the degree of branching is determined from the ratio of the unbranched monomers to the branching monomers, that is, the amount of tri- and tetrafunctional siloxanes. According to the invention, both low-branched and highly branched dimethiconols, dimethicones and / or dimethicone copolyols can be particularly preferred.
  • cyclic dimethicones are referred to as cyclomethicones according to INCI and are known under the trade name Xiameter PMX 0244 cyclotetrasiloxanes, Xiameter PMX 0344 cyclosiloxanes blend, Xiameter PMX 0245 Cyclopentasiloxane, Xiameter PMX 0345 Cyclosiloxane blend from the manufacturer Xiameter.
  • the agents according to the invention preferably contain the silicones in amounts of from 0.01% by weight to 15%
  • Wt .-% particularly preferably from 0.05 to 2 wt .-%, based on the total agent.
  • auxiliaries and additives are, in particular, care substances.
  • compositions according to the invention optionally additionally contain at least one
  • Suitable plant extracts are obtained by extraction with organic solvents (such as, for example, ethanol, isopropanol, diethyl ether, benzene, benzene, chloroform) or by steam distillation.
  • organic solvents such as, for example, ethanol, isopropanol, diethyl ether, benzene, benzene, chloroform
  • the invention are especially the extracts of bamboo, linseed, water lily, green tea, oak bark, nettle, witch hazel, hops, henna, chamomile, burdock root, horsetail, hawthorn, linden, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut , Mango, apricot, lime, wheat, kiwi, melon, orange, grapefruit, sage, rosemary, birch, mallow, meadowfoam, quenelle, yarrow, thyme, lemon
  • the additional plant extract is preferably in the composition according to the invention in an amount of 0.05 wt .-% to 1, 0 wt .-%, in particular from 0, 1 wt .-% to 0.5 wt .-%, each based on the weight of the cosmetic product.
  • cationized protein hydrolysates can also be present as care components, the underlying protein hydrolyzate being derived from the animal, for example from collagen, milk or keratin, from the plant, for example from wheat, maize, rice, potatoes, soya or almonds, from marine life forms, for example from Fish collagen or algae, or biotechnologically derived protein hydrolysates.
  • the protein hydrolyzates on which the cationic derivatives according to the invention are based can be obtained from the corresponding proteins by chemical, in particular alkaline or acid hydrolysis, by enzymatic hydrolysis and / or a combination of both types of hydrolysis.
  • the hydrolysis of proteins usually results in a protein hydrolyzate having a molecular weight distribution of about 100 daltons up to several thousand daltons. Preference is given to those cationic protein hydrolysates whose protein content on which they are based has an average molecular weight (weight average) of from 100 to 25,000 daltons, preferably from 250 to 5,000 daltons. Furthermore, cationic protein hydrolyzates are to be understood as meaning quaternized amino acids and mixtures thereof.
  • the quaternization of the protein hydrolyzates or amino acids is often carried out using quaternary ammonium salts such as N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides.
  • the cationic protein hydrolysates may also be further derivatized.
  • typical examples of the cationic protein hydrolysates and derivatives according to the invention are under the INCI - names in the "International Cosmetic Ingredient Dictionary and Handbook” (seventh edition 1997, The Cosmetic, Toiletry, and Fragrance Association 1 101 17 th Street, NW, Suite 300, Washington, DC 20036-4702) mentioned and commercially available products.
  • At least one vitamin, a provitamin, a vitamin precursor and / or one of their derivatives can furthermore be used.
  • vitamins, pro-vitamins and vitamin precursors are preferred, which are usually assigned to groups A, B, C, E, F and H. Particularly preferred are vitamins belonging to the B group or to the vitamin B complex, most preferably vitamin B 5 (pantothenic acid, panthenol and pantolactone).
  • protein hydrolysates and / or their derivatives wherein the use of protein hydrolysates of plant origin, eg. Soy, almond, pea, potato and wheat protein hydrolysates, is preferred.
  • Such products are, for example, under the trademarks Gluadin ® (Cognis), diamine ® (Diamalt) ® (Inolex), Hydrosoy ® (Croda), hydro Lupine ® (Croda), hydro Sesame ® (Croda), Hydro tritium ® (Croda) and Crotein ® (Croda) available.
  • protein hydrolysates Although the use of the protein hydrolysates is preferred as such, amino acid mixtures otherwise obtained may be used in their place, if appropriate. Also possible is the use of derivatives of protein hydrolysates, for example in the form of their fatty acid condensation products. Such products are marketed for example under the names Lamepon ® (Cognis), Lexein ® (Inolex), Crolastin ® (Croda), Crosilk ® (Croda) or Crotein ® (Croda).
  • auxiliaries and additives can be added.
  • UV filters are not subject to any general restrictions with regard to their structure and their physical properties. On the contrary, all UV filters which can be used in the cosmetics sector and whose absorption maximum lies in the UVA (315-400 nm), in the UVB (280-315 nm) or in the UVC ( ⁇ 280 nm) range are suitable. UV filters with an absorption maximum in the UVB range, in particular in the range from about 280 to about 300 nm, are particularly preferred.
  • the UV filters preferred according to the invention can be selected, for example, from substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylic acid esters, cinnamic acid esters, salicylic acid esters, benzimidazoles and o-aminobenzoic acid esters.
  • An example is here 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt (Benzophenone- 4; Uvinul ® MS 40; Uvasorb ® S 5) mentioned.
  • the products of the invention may also contain one or more preservatives.
  • Preservatives preferred according to the invention are formaldehyde releasers (such as, for example, 1,3-dimethylol-4,4-dimethylhydantoin, INCI name DMDM hydantoin, available, for example, under the trade name Glydant from Lonza), iodopropynyl butylcarbamates such as 3-iodo 2-propynyl butylcarbamate (e.g., those available under the trade names Glycacil-L, Glycacil-S from Lonza, and / or Dekaben LMB from Jan Dekker), parabens (ie, p-hydroxybenzoic acid alkyl esters, such as methyl, ethyl, propyl, and / or butylparaben), phenoxyethanol, ethanol, benzoic acid, dibromodicyanobutane (2-bromo-2
  • Preservatives which are particularly preferred according to the invention are selected from parabens (methyl, ethyl, propyl and / or butylparaben) and / or phenoxyethanol.
  • the preservatives are in the water of the invention in oil emulsions, based on the total propellant-free water in oil emulsion, preferably in amounts of 0.01 to 3, preferably 0, 1 to 1, 5 and particularly preferably 0.2 to 1, 0 wt .-% contain.
  • the product according to the invention is particularly suitable for the hair design of wet hair, in particular in the area of the hair.
  • Another object of the present invention is a method for hair styling of wet hair, in which
  • (B) is sprayed onto the wet hair via the aerosol dispenser, preferably in the region of the hairline,
  • composition E is a composition according to the invention
  • V1 and V2 are comparative formulations.
  • Valve Aptar ARM-4.00-1-0, 32-8,70 Green - AR Housing - Valve AHT-1, 60-0,00
  • Natural Spraycap Aptar Sirena TWO PC SR 000319 24DEG Black CPC-08
  • a mirror was sprayed with the previously filled aluminum can from a distance of 20 cm. From the mirror formed a circular foam surface whose diameter and thus its radius was determined. From the distance and the radius, the spray angle in degrees was determined with known geometric formulas. In order to ensure a uniform application of the sprayable foam on keratinic fibers, the fanning of the spray jet must be at least 10 °, the application is comfortable from a fanning of 20 °.

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Abstract

L'invention concerne un produit cosmétique à appliquer sous forme de mousse sur des fibres de kératine, en particulier des cheveux humains, comprenant un récipient d'aérosol sous pression, un dispositif de distribution d'aérosol et une composition cosmétique contenant (a) du diméthyléther comme gaz propulseur, (b) un ou plusieurs autres gaz propulseurs sélectionnés dans le groupe consistant en propane, propène, n-butane, iso-butane, iso-butène, n-pentane, pentène, iso-pentane et iso-pentène, (c) au moins un tensioactif cationique, (d) au moins un alcool soluble dans l'eau ayant de 2 à 9 atomes de carbone et 1 à 6 groupes hydroxy et (e) de l'eau.
PCT/EP2013/076386 2012-12-21 2013-12-12 Produit cosmétique à appliquer sous forme de mousse sur des fibres de kératine WO2014095568A1 (fr)

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DE201210224238 DE102012224238A1 (de) 2012-12-21 2012-12-21 Kosmetisches Produkt zur Schaumapplikation auf keratinischen Fasern

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1205174A1 (fr) * 2000-11-10 2002-05-15 Wella Aktiengesellschaft Produit capillaire apportant du volume à la chevelure et fixant spécifiquement le cheveu à sa base
WO2006050788A1 (fr) * 2004-11-10 2006-05-18 The Procter & Gamble Company Produit de coiffure transparent, biphasique et moussant en aérosol
EP1666093A1 (fr) * 2004-11-19 2006-06-07 KPSS-Kao Professional Salon Services GmbH Composition de coiffage sous forme aérosol comprenant des polymères amphotériques et non-ioniques
DE102005014305A1 (de) * 2005-03-30 2006-10-12 Südzucker AG Mannheim/Ochsenfurt Verwendung sphärischer Partikel zur Haarbehandlung

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1205174A1 (fr) * 2000-11-10 2002-05-15 Wella Aktiengesellschaft Produit capillaire apportant du volume à la chevelure et fixant spécifiquement le cheveu à sa base
WO2006050788A1 (fr) * 2004-11-10 2006-05-18 The Procter & Gamble Company Produit de coiffure transparent, biphasique et moussant en aérosol
EP1666093A1 (fr) * 2004-11-19 2006-06-07 KPSS-Kao Professional Salon Services GmbH Composition de coiffage sous forme aérosol comprenant des polymères amphotériques et non-ioniques
DE102005014305A1 (de) * 2005-03-30 2006-10-12 Südzucker AG Mannheim/Ochsenfurt Verwendung sphärischer Partikel zur Haarbehandlung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"International Cosmetic Ingredient Dictionary and Handbook", 1997, THE COSMETIC, TOILETRY, AND FRAGRANCE ASSOCIATION

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