WO2014071238A1 - Systèmes et procédés pour la fabrication de membranes d'osmose directe en utilisant un traitement rouleau contre rouleau - Google Patents

Systèmes et procédés pour la fabrication de membranes d'osmose directe en utilisant un traitement rouleau contre rouleau Download PDF

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Publication number
WO2014071238A1
WO2014071238A1 PCT/US2013/068143 US2013068143W WO2014071238A1 WO 2014071238 A1 WO2014071238 A1 WO 2014071238A1 US 2013068143 W US2013068143 W US 2013068143W WO 2014071238 A1 WO2014071238 A1 WO 2014071238A1
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WIPO (PCT)
Prior art keywords
solid sheet
fabric
forward osmosis
roll
membrane
Prior art date
Application number
PCT/US2013/068143
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English (en)
Inventor
Il Juhn Roh
Ravindra Revanur
Aleksandr Noy
Olgica Bakajin
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Porifera, Inc.
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Publication date
Application filed by Porifera, Inc. filed Critical Porifera, Inc.
Priority to KR1020157014493A priority Critical patent/KR20150089024A/ko
Priority to US14/440,254 priority patent/US20150273399A1/en
Publication of WO2014071238A1 publication Critical patent/WO2014071238A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/002—Forward osmosis or direct osmosis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1216—Three or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
    • B01D69/1251—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction by interfacial polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/40—Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/56—Polyamides, e.g. polyester-amides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
    • B05D3/107—Post-treatment of applied coatings

Definitions

  • Examples described herein relate to systems and methods for fabricating forward osmosis membranes, including systems and methods using roll-to-roll processing.
  • Membranes may be used to perform osmosis, which generally occurs when two solutions of differing concentration are placed on opposite sides of a permeable or semipermeable membrane.
  • Forward osmosis is a process where water flows through a permeable or semi-permeable membrane from a solution with relatively low salt concentration (e.g. feed solution) to a solution with relatively high salt concentration (e.g. draw solution) .
  • the generated osmotic pressure difference drives the permeation of water across the membrane from . the dilute solution to the concentrated solution, while the selective property of the membrane retains the solutes in their respective solution.
  • TFC thin film composite
  • a TFC membrane is a membrane that has layers of materials (e.g. dissimilar materials) joined together to form a single membrane. This layered construction permits the use of material combinations that optimize performance and durability of the membrane.
  • TFC membranes may include a support layer and a selectivity layer. Forward osmosis membranes can incorporate fragile fabrics that are challenging to use in a roll to roll manufacturing process.
  • a first roller system may be positioned to transport a solid sheet through a casting region and a phase inversion bath.
  • a second roller system may be positioned to transport the solid sheet through any of an interfacial polymerization region and an alcohol separation bath.
  • the solid sheet may be formed from a polyolefin.
  • a casting region may include a chamber housing a casting solution, and may release the casting solution to cast polymer.
  • a polymer solution infiltrated matrix may be formed by casting polymer solution on a fabric supported by a solid sheet.
  • a polymer solution infiltrated matrix may be formed by casting polymer on a solid sheet and then applying a fabric to the cast solid sheet.
  • a phase inversion bath may house a nonsolvent coagulation agent.
  • the polymer solution infiltrated matrix may be immersed into the phase inversion bath to form a support membrane.
  • the support membrane may be a forward osmosis membrane.
  • An interfacial polymerization region may include a path through an aqueous solution, an organic solution, and an oven housed therein.
  • a selectivity layer may be formed on the support membrane in the interfacial polymerization region to form a forward osmosis membrane.
  • the selectivity layer may be a polyamide layer.
  • the selectivity layer may be formed on a side of the support membrane previously in contact with the solid sheet.
  • the selectivity layer may be formed on a side of the support membrane opposite of the solid sheet.
  • An alcohol separation bath may house an alcohol.
  • the forward osmosis membrane may be delaminated from the solid sheet by treating the forward osmosis membrane with the alcohol.
  • a delaminating element positioned proximate to the alcohol separation bath may be used to separate the forward osmosis membrane and the solid sheet.
  • Figure 1 is a schematic illustration of a membrane fabrication system arranged in accordance with embodiments of the present invention.
  • Figure 2 is a schematic illustration of a portion of the membrane fabrication system shown in Figure 1 arranged in accordance with embodiments of the present invention.
  • Figure 3 is a schematic illustration of a portion of the membrane fabrication system shown in Figure 1 arranged in accordance with embodiments of the present invention.
  • Figure 4 is a cross-sectional schematic illustration of a supported forward osmosis membrane arranged in accordance with embodiments of the present invention.
  • Figure 5 is a schematic illustration of a portion of the membrane fabrication system shown in Figure 1 arranged in accordance with embodiments of the present invention.
  • Figure 6 is a schematic illustration of a portion of a membrane fabrication system arranged in accordance with embodiments of the present invention.
  • ⁇ osmosis membranes include scalable mechanisms for conducting roll-to-roll processing to produce forward osmosis membranes with specific structural properties that may be optimized for performance and durability.
  • Forward osmosis membranes disclosed herein may include thin film composite (TFC) structures that may include a support layer that may support a selectivity layer that may enhance the membrane rejection performance.
  • TFC thin film composite
  • the performance of forward osmosis membranes is generally linked to its structural properties. Accordingly, examples described herein may provide scalable systems and methods to fabricate and handle forward osmosis membranes quickly, accurately, and at a relatively low cost.
  • FIG. 1 is a schematic illustration of a membrane fabrication system, according to one or more embodiments.
  • the membrane fabrication system may include a solid sheet feed roll 101 that may unroll during operation to transfer a solid sheet 120 to a casting region 103 of the membrane fabrication system.
  • the solid sheet feed roll 101 may be a roll wound with a support material that may not disadvantageous ⁇ react with downstream processes in the membrane fabrication system.
  • the solid sheet 120 may be a polyolefin, such as polyethylene, or polypropylene, or combinations thereof. It may be advantageous to use polyolefins due to their high mechanical strength, solvent resistance, and high heat stability in some examples.
  • polyolefins may allow the forward osmosis membrane formed by the membrane fabrication system to withstand rigors associated with the fabrication process. For example a preferably high tension that may reduce or eliminate wrinkling and may allow machines to operate at higher speeds and lower cost. Additionally, these properties of polyolefins may facilitate delamination of the support or forward osmosis membrane from the support, drying prevention and tight selectivity layer formation and prevention of double selectivity layer formation in some examples.
  • the membrane fabrication system may also include a fabric feed roll 102 positioned either upstream or downstream with respect to the casting region 103.
  • the fabric feed roll 102 may be positioned upstream from the casting region 103, and may unroll during operation to transfer fabric to be supported by (e.g. contact) the solid sheet 120 being transferred to the casting region 103.
  • the fabric feed roll 102 may be positioned downstream from the casting region 103, and may unroll to transfer fabric to be supported by (e.g. contact) a cast solid sheet being transferred from the casting region 103 to a phase inversion bath 104.
  • the fabric feed roll 102 may be a roll wound with a fabric.
  • the material for the fabric may be chosen based on desired properties, for example porosity and thickness.
  • the fabric may be made from polyester, polyamide, or combinations thereof.
  • the thickness of the fabric may be in the range of 15-150 ⁇ in some examples, 20-100 ⁇ in some examples, and 30-80 ⁇ thick in some examples.
  • the porosity of the fabric may be in the range of 20-80% in some examples and 30-70% in some examples.
  • the fabric may be woven or nonwoven.
  • the density for the nonwoven fabric may be in the range of 5-60 g/sq meter in some examples and 5-50 g/sq meter in some examples.
  • the woven fabric may have a mesh count in the range of 20-200 number/cm in some examples, 30-180 number/cm in some examples, and 30-150 number/cm in some examples.
  • FIG. 2 is a schematic illustration of a portion of the membrane fabrication system shown in FIG. 1, according to one or more embodiments.
  • a fabric supported by a solid sheet (referred to herein as supported fabric 108) may be transferred to the casting region 103 by a feed rolling system 201A-201B.
  • the feed rolling system 201A-201B may include one or more rollers that may couple with the supported fabric 108 and may spin so as to transfer it to the casting region 103.
  • the one or more rollers of the feed rolling system 201A-201B may be arranged to transfer the supported fabric 108 along a predefined path.
  • the one or more rollers of the feed rolling system 201A-201B may include features, for example a pattern of grooves, to couple with the solid sheet.
  • the one or more rollers of the feed rolling system 201 A-201B may transport the supported fabric 108 while providing a constant tension on the unwinding solid sheet roll 101 and fabric feed roll 102.
  • the one or more rollers of the feed rolling system 201A-201B may be arranged so as to minimize excessive stresses while transporting the solid sheet.
  • one or more of the rollers of the feed rolling system 201A-201B may be coupled with one or more motors 303 that may spin one or more of the rollers in a predefined manner.
  • the one or more motors 303 may be coupled to a controller 302 (an example shown in Figure 3), which may receive user input, such as spin speed.
  • the controller 302 may be an electronic device, for example a computing device, that may transmit control signals at predefined times and/or predefined intervals to the one or more motors 303 of the feed rolling system 201A-201B.
  • a single controller may be used to control the feed rolling system 201A-201B, a roller system 1 13 A- 1 13D, and the secondary roller system 1 14A-1 14D.
  • the controller 302 may control a take up roller via a motor coupled to the take up roller.
  • the take up roller may be positioned downstream from all the rollers of the membrane fabrication system.
  • the take up roller may be the only roller coupled to a motor, and may provide the driving force for transporting the solid sheet through the membrane fabrication system.
  • the casting region 103 may be positioned at any point downstream from the solid sheet feed roll lOl and upstream from a phase inversion bath 104. In some examples, as shown in FIG. 2, the casting region 103 may be positioned downstream from the solid sheet and the fabric have been unrolled and coupled to one another.
  • the casting region 103 may include a chamber housing a casting solution.
  • the casting solution may include aramid polymers, such as meta-aramids and mixtures of meta-aramids (e.g., NOMEX®) and para- aramids (e.g., KEVLAR®). Other options for the casting solution may include acrylate- modified poly(vinylidene fluoride) polymers.
  • the casting solution may have a concentration of polymer in the range of 5 - 20 wt% in some examples. In other examples, other concentrations may be used.
  • Meta-aramid or similar support materials may offer several advantages over state-of- the-art materials (such as polysulfone) in some examples. Possible advantages include (1 ) improved membrane formability and flexibility, (2) enhanced chemical resistance, (3) enhanced structural stability, (4) hydrophilicity, which could result in enhanced anti-fouling properties, and enhanced flux through the membrane in several types of applications (e.g. forward osmosis). These advantages are provided herein by way of illustration and to aid in understanding. It is to be understood that not all examples provide all advantages, and indeed some examples of the present invention may not provide any of the described advantages.
  • the meta-aramid polymer support layer also may incorporate functional ized or unfunctionalized carbon nanotubes to enhance the membrane performance.
  • the casting solution may be provided in a solvent.
  • the solvent may be polar, and may include N-methyl-2-pyrrolidone (NMP), ⁇ , ⁇ -dimethylacetamide (DMAc), N,N- dimethylformamide (DMF), dimethyl sulfoxide (DMSO), or combinations thereof.
  • the solvent may be combined with a salt, for example LiCl.
  • the casting solution may be formed by dissolving NOMEX® in DMAc-LiCl salt solution at 100°C under constant stirring for 4 hours.
  • the chamber housing the casting solution may be shaped to hold a desired amount of casting solution.
  • the chamber may be coupled to a release element, for example a casting knife or slot die that may release the casting solution at a desired rate over a desired release area.
  • the control element may be a barrier provided by a casting knife that allows only a certain thickness to pass through.
  • the control element may regulate the amount of casting solution to pass through by other known methods.
  • the release element may release the casting solution on to the solid sheet 120 or the supported fabric 108.
  • the solid sheet 120 may be treated with solvent to improve wetting of the casting solution.
  • Releasing the casting solution on to the solid sheet or the fabric supported by the solid sheet generally results in the polymer of the casting solution to be cast to form a polymer solution infiltrated matrix 109.
  • the cast polymer may integrate with the fabric (e.g. be disposed within the fabric).
  • the polymer solution infiltrated matrix 109 may then be transported to a phase inversion bath 104 where phase separation occurred and the solvent and salt from the casting solution may be removed.
  • FIG. 3 is a schematic illustration of a portion of the membrane fabrication system shown in FIG. 1, according to one or more embodiments.
  • the solid sheet and the fabric may be rolled in a combined feed roll 301.
  • the combined feed roll 301 may be arranged such that it may be unrolled to feed the casting region 103 with the supported fabric 108.
  • the combined feed roll 301 may be unrolled such that the fabric may be positioned with the fabric facing up to to receive the casting solution.
  • the supported fabric 108 may pass through the casting region 103 to be cast with polymer to form a polymer solution infiltrated matrix 109 and then transported to the phase inversion bath 104, as described above. It may be advantageous to use the combined roll 301 in some examples to reduce complexity of the membrane fabrication system and to improve the rate at which the forward osmosis membrane may be fabricated.
  • the phase inversion bath 104 may receive the polymer solution infiltrated matrix 109 and may perform a phase inversion process to form a support membrane 1 10.
  • the phase inversion 104 bath may house a number of nonsolvent-solvent mixtures, for example a nonsolvent coagulation agent 1 16. Different solvent-additive-nonsolvent mixtures may be used, such as N-methylpyrrolidone (NMP) - tetrahydrofuran - water, NMP - chloroform - water and NMP -isopropanol - water, or combinations thereof.
  • NMP N-methylpyrrolidone
  • the phase inversion bath 104 may house water.
  • the polymer solution infiltrated matrix 109 may be immersed in a phase inversion bath 104 with a first chamber housing a nonsolvent coagulation agent 1 16 and then immersed in a second chamber housing a nonsolvent agent, for example water.
  • the first chamber and the second chamber may be maintained at a predefined temperature, for example at 4-40°C, for a predefined time period, for example 1 - 60 minutes, or until the salts present in the polymer solution infiltrated matrix 109 are removed.
  • a roller system 1 13A-1 13D may be positioned inside or proximate to the phase inversion bath 104 to transport the solid sheet through the casting region 103 and the phase inversion bath 104.
  • the roller system 1 13A-113D may include one or more rollers that couple to the solid sheet.
  • the one or more rollers of the roller system 113A-1 13D may be arranged to transfer the supported fabric 108 along a predefined path.
  • the rollers may include features, for example a pattern of grooves, to couple with the solid sheet.
  • the one or more rollers of the roller system 1 13A-1 13D may be arranged so as to minimize excessive stresses while transporting the solid sheet.
  • One or more rollers of the roller system 113A-1 13D may be immersed within the phase inversion bath 104, whereby the polymer solution infiltrated matrix 109 is transported through the phase inversion bath, allowing the support membrane 110 to be formed, as described above.
  • One or more rollers of the roller system 113A-1 13D may be positioned proximate to the phase inversion bath 104, such that the polymer solution infiltrated matrix 109 may be transported from the casting region 103 to the phase inversion bath 104, and such that the support membrane 110 may be transported to downstream processes, for example, an interfacial polymerization region 105.
  • one or more of the rollers of the roller system 1 13A-1 13D may be coupled with one or more motors 303 that may spin one or more of the rollers in a predefined manner.
  • the one or more motors 303 may be coupled to a controller 302, which may receive user input, such as spin speed.
  • the controller 302 may be an electronic device, for example a computing device, that may transmit control signals at predefined times and/or predefined intervals to the one or more motors 303 of the roller system 1 13A-1 13D.
  • the membrane fabrication system may include an interfacial polymerization region 105 that may apply a selectivity layer to the support membrane 1 10 to form a forward osmosis membrane supported by a solid sheet (referred to herein as a supported forward osmosis membrane 1 1 1).
  • the interfacial polymerization region 105 may include an aqueous solution, an organic solution, and an oven.
  • the aqueous solution agent may contain a di- or polyfunctional amine.
  • the aqueous solution may include combinations of 1,3 phenylenediamine (MPDA) (e.g. 0-10%), DABA (diaminobenzoic acid) (e.g. 0-10%), triethylamine (TEA) (e.g.
  • the organic solution may contain 0-1% 1,3,5-trimesoyl chloride (TMC) and/or isophthaloyl chloride (IPC) in Isopar G, Isopar C, hexanes, heptane, octane, chloroform or other solvents.
  • TMC 1,3,5-trimesoyl chloride
  • IPC isophthaloyl chloride
  • the 20 - 150 °C) for 0-5 minutes may form a selectivity layer on the support membrane 110 as passes through the interfacial polymerization region 105, forming the supported forward osmosis membrane 1 1 1.
  • the selectivity layer may include a polyamide layer that may improve the rejection performance of the forward osmosis membrane.
  • the selectivity layer may be applied after delaminating the support membrane from the solid sheet. It may be advantageous to delaminate the membrane from the solid sheet before applying the selectivity layer when it is desired to apply the selectivity layer to the side of the membrane that was previously coupled to the solid sheet or on both sides of the membrane. Delaminating the membrane from the solid sheet may be performed using an alcohol in some examples. Additionally, after delamination the membrane may be thoroughly washed with water to remove the alcohol.
  • a selectivity layer may or may not be required to implement a forward osmosis membrane.
  • the cast polymer and fabric may themselves have sufficient performance characteristics to serve as a forward osmosis membrane without adding a selectivity layer.
  • a membrane fabrication system may or may not include an interfacial polymerization region that applies a selectivity layer.
  • a support membrane may be transferred from a phase inversion bath to an alcohol separation bath to delaminate the forward osmosis membrane without a selectivity layer from the solid sheet.
  • the membrane without a selectivity layer may be referred to as an asymmetric membrane. After delamination the membrane may be thoroughly washed with water to remove the alcohol and wetted with a solution of glycerol (2-50%) for storage.
  • FIG. 4 is a cross-sectional schematic illustration of a supported forward osmosis membrane 11 1, according to one or more embodiments.
  • the supported forward osmosis membrane 1 1 1 may include a solid sheet 401 that may support a cast polymer layer 404 and a selectivity layer 405.
  • the thickness of the cast polymer layer 404 may vary between 10 - 150 microns (preferably 15-70 micron for a nonwoven fabric and 30-90 microns for a woven fabric).
  • the thickness of the selectivity layer 405 may be preferably 50-500 nm.
  • the cast polymer layer 404 may include a cast polymer 403 and a fabric 402.
  • the viscosity of a casting solution used to cast the polymer of the cast polymer 403 may be relatively low and the fabric 402 may have a generally loose structure.
  • the fabric 402 may be integrated within the cast polymer 403 to form a matrix of a support membrane 1 10.
  • the cast polymer 403 may integrate with the fabric 402 during phase inversion to form a matrix of a support membrane 1 10.
  • the support membrane 1 10 may undergo interfacial polymerization, in which the selectivity layer 405 may be applied to the support membrane 1 10 to form the supported forward osmosis membrane 1 1 1.
  • FIG. 5 is a cross-sectional schematic illustration of a portion of the membrane fabrication system of FIG. 1, according to one or more embodiments.
  • the portion shown in FIG. 5 is a portion which may be used to delaminate a forward osmosis membrane from a solid sheet.
  • the membrane fabrication system may include an alcohol separation bath 106, which may receive a supported forward osmosis membrane 1 1 1 and may delaminate the forward osmosis membrane from the solid sheet, e.g. the forward osmosis membrane 1 18 and the solid sheet 119 of FIG. 1.
  • the alcohol separation bath 106 may house an alcohol 1 17, for example methyl alcohol, ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol, or combinations thereof.
  • the alcohol 1 17 may be diluted in water to form an alcohol solution.
  • the forward osmosis membrane 1 1 1 When the supported forward osmosis membrane 1 1 1 is immersed in the alcohol 117 or the alcohol solution, the forward osmosis membrane 118 and the solid sheet 1 19 may delaminate.
  • the membrane may be rinsed with water to remove the alcohol, and may be treated with a preservative, such as glycerol before drying, for membrane storage.
  • Secondary roller system 1 14A-1 14D may be positioned inside or proximate to the alcohol separation bath 106 to transport the supported forward osmosis membrane 1 11 through the interfacial polymerization region 105 and alcohol separation bath 106.
  • the secondary roller system 1 14A-1 14D may include one or more rollers that couple to the supported forward osmosis membrane 1 1 1.
  • the one or more rollers of the secondary roller system 1 14A-1 14D may be arranged to transfer the supported forward osmosis membrane 1 1 1 along a predefined path.
  • the rollers may include features, for example a pattern of grooves, to couple with the solid sheet.
  • the one or more rollers of the secondary roller system 1 14A-1 14D may be arranged so as to minimize excessive stresses while transporting the supported forward osmosis membrane 1 1 1.
  • One or more rollers of the secondary roller system 114A-1 14D may be immersed within the alcohol separation bath 106, such that the supported forward osmosis membrane 1 1 1 is transported through the alcohol separation bath 106, allowing the forward osmosis membrane 1 18 to delaminate from the solid sheet 1 19, as described above.
  • One or more rollers of the secondary roller system 1 14A-1 14D may be positioned proximate to the alcohol separation bath 106, such that the supported forward osmosis membrane 1 1 1 may be transported from the interfacial polymerization region 105 to the alcohol separation bath 106, and such that the delaminated forward osmosis membrane 1 18 and solid sheet 1 19 may be transported to downstream processes, for example, the delaminating element 1 15.
  • one or more of the rollers of the secondary roller system 1 14A-1 14D may be coupled with one or more motors 303 that may spin one or more of the rollers in a predefined manner.
  • the one or more motors 303 may be coupled to a controller 302, which may receive user input, such as spin speed.
  • the controller 302 may be an electronic device, for example a computing device, that may transmit control signals at predefined times and/or predefined intervals to the one or more motors 303 of the secondary roller system 1 14A-1 14D.
  • the delaminating element 1 15 may be positioned downstream relative to the alcohol bath 106.
  • the delaminating element 1 15 may be used to decouple the solid sheet 1 19 and the forward osmosis membrane 1 18 after treatment of the supported forward osmosis membrane 11 1 in the alcohol bath 106.
  • the delaminating element 1 15 may be positioned in the path crated by the secondary roller system 114A-1 14D such that the delaminated solid sheet 119 and forward osmosis membrane 1 18 may further separate and be directed to either a forward osmosis membrane roll 1 12 or a delaminated solid sheet roll.
  • the delaminating element 1 15 may be shaped to facilitate directing the forward osmosis membrane 1 18 and the solid sheet 1 19 to the appropriate roll.
  • the delaminating element 1 15 may include a relatively narrow end facing upstream and a relatively wide end facing downstream.
  • the forward osmosis membrane 1 18 and the solid sheet 1 19 may be transported to the delaminating element 1 15 after treatment in the alcohol bath 106, and the narrow end of the delaminating element may facilitate separation of the forward osmosis membrane 1 18 and the solid sheet 119. It will be understood by one skilled in the art that other mechanisms for directing a solid sheet in one direction and a forward osmosis membrane in a second direction may be used to effect a separation.
  • the forward osmosis membrane 118 may be wound on the forward osmosis membrane roll 1 12.
  • the solid sheet 1 19 delaminated from the forward osmosis membrane 1 18 may be wound on the delaminated solid sheet roll 107.
  • the forward osmosis membrane 1 18 may be washed with water prior to winding.
  • the forward osmosis membrane 1 18 may be treated with a preservative, such as glycerol before drying, for membrane storage.
  • FIG. 6 is a cross-sectional schematic illustration of a portion of a membrane fabrication system, according to one or more embodiments.
  • the solid sheet may be cast with polymer before adding the fabric. This may be achieved by unrolling the solid sheet from the solid sheet feed roll 101 to the casting region 103, and releasing the casting solution directly on to the solid sheet forming a cast solid sheet 601.
  • the solid sheet may be modified with solvent or hydrophilic coatings to improve wetting of the polymer solution.
  • the control element may even out the distribution of the cast polymer across the cast solid sheet 601.
  • the fabric feed roll 102 may be unrolled to transport woven or nonwoven fabric to the cast solid sheet 601, whereby the fabric may be at least partially embedded into the cast polymer of the cast solid sheet 601 to form a polymer solution infiltrated matrix 109.
  • the extent to which the fabric is embedded into the cast polymer may depend on the viscosity of the casting solution, the porosity of the fabric, and by the time allowed for infiltration before phase inversion.
  • the polymer solution infiltrated matrix 109 may undergo phase inversion, interfacial polymerization and delamination to form a forward osmosis membrane, as described above.
  • a thinner layer of cast polymer may have a higher flux than a membrane of the same total thickness with a thicker layer of cast polymer because of reduced concentration polarization.
  • the layer of cast polymer may be separated from the solid sheet before interfacial polymerization.

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  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

Selon la présente invention, des exemples sont décrits, comprenant des systèmes de fabrication de membrane en utilisant un traitement rouleau contre rouleau pour fabriquer une membrane d'osmose directe. Un tissu soutenu par une feuille solide peut être coulé avec un polymère et une couche de sélectivité peut être appliquée pour former la membrane d'osmose directe. La membrane d'osmose directe soutenue par la feuille solide peut être détachée en utilisant un alcool.
PCT/US2013/068143 2012-11-02 2013-11-01 Systèmes et procédés pour la fabrication de membranes d'osmose directe en utilisant un traitement rouleau contre rouleau WO2014071238A1 (fr)

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US14/440,254 US20150273399A1 (en) 2012-11-02 2013-11-01 Systems and methods for fabrication of forward osmosis membranes using roll-to-roll processing

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US8920654B2 (en) 2010-09-30 2014-12-30 Porifera, Inc. Thin film composite membranes for forward osmosis, and their preparation methods
US9216391B2 (en) 2011-03-25 2015-12-22 Porifera, Inc. Membranes having aligned 1-D nanoparticles in a matrix layer for improved fluid separation
US9227360B2 (en) 2011-10-17 2016-01-05 Porifera, Inc. Preparation of aligned nanotube membranes for water and gas separation applications
CN105617885A (zh) * 2016-03-25 2016-06-01 北京碧水源膜科技有限公司 一种连续制备正渗透复合膜的设备和方法
CN106492657A (zh) * 2016-09-26 2017-03-15 宁波大学 一种水铝英石硅纳米管杂化正渗透膜
US9636635B2 (en) 2012-12-21 2017-05-02 Porifera, Inc. Separation systems, elements, and methods for separation utilizing stacked membranes and spacers
US9861937B2 (en) 2013-03-15 2018-01-09 Porifera, Inc. Advancements in osmotically driven membrane systems including low pressure control
US10384169B2 (en) 2014-10-31 2019-08-20 Porifera, Inc. Supported carbon nanotube membranes and their preparation methods
US11541352B2 (en) 2016-12-23 2023-01-03 Porifera, Inc. Removing components of alcoholic solutions via forward osmosis and related systems
US11571660B2 (en) 2015-06-24 2023-02-07 Porifera, Inc. Methods of dewatering of alcoholic solutions via forward osmosis and related systems

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US8920654B2 (en) 2010-09-30 2014-12-30 Porifera, Inc. Thin film composite membranes for forward osmosis, and their preparation methods
US9216391B2 (en) 2011-03-25 2015-12-22 Porifera, Inc. Membranes having aligned 1-D nanoparticles in a matrix layer for improved fluid separation
US9227360B2 (en) 2011-10-17 2016-01-05 Porifera, Inc. Preparation of aligned nanotube membranes for water and gas separation applications
US10464023B2 (en) 2012-12-21 2019-11-05 Porifera, Inc. Separation systems, elements, and methods for separation utilizing stacked membranes and spacers
US11759751B2 (en) 2012-12-21 2023-09-19 Porifera, Inc. Separation systems, elements, and methods for separation utilizing stacked membranes and spacers
US9636635B2 (en) 2012-12-21 2017-05-02 Porifera, Inc. Separation systems, elements, and methods for separation utilizing stacked membranes and spacers
US11090611B2 (en) 2012-12-21 2021-08-17 Porifera, Inc. Separation systems, elements, and methods for separation utilizing stacked membranes and spacers
US9861937B2 (en) 2013-03-15 2018-01-09 Porifera, Inc. Advancements in osmotically driven membrane systems including low pressure control
US12005396B2 (en) 2013-03-15 2024-06-11 Porifera, Inc. Advancements in osmotically driven membrane systems including multi-stage purification
US10500544B2 (en) 2013-03-15 2019-12-10 Porifera, Inc. Advancements in osmotically driven membrane systems including multi-stage purification
US10384169B2 (en) 2014-10-31 2019-08-20 Porifera, Inc. Supported carbon nanotube membranes and their preparation methods
US11571660B2 (en) 2015-06-24 2023-02-07 Porifera, Inc. Methods of dewatering of alcoholic solutions via forward osmosis and related systems
CN105617885A (zh) * 2016-03-25 2016-06-01 北京碧水源膜科技有限公司 一种连续制备正渗透复合膜的设备和方法
CN106492657A (zh) * 2016-09-26 2017-03-15 宁波大学 一种水铝英石硅纳米管杂化正渗透膜
CN106492657B (zh) * 2016-09-26 2018-12-28 宁波大学 一种水铝英石硅纳米管杂化正渗透膜
US11541352B2 (en) 2016-12-23 2023-01-03 Porifera, Inc. Removing components of alcoholic solutions via forward osmosis and related systems

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