WO2014061705A1 - Food or drink with enhanced salty taste and/or umami and manufacturing method therefor, salty taste and/or umami-enhancing composition for food or drink, and method for enhancing salty taste and/or umami of food or drink - Google Patents

Food or drink with enhanced salty taste and/or umami and manufacturing method therefor, salty taste and/or umami-enhancing composition for food or drink, and method for enhancing salty taste and/or umami of food or drink Download PDF

Info

Publication number
WO2014061705A1
WO2014061705A1 PCT/JP2013/078089 JP2013078089W WO2014061705A1 WO 2014061705 A1 WO2014061705 A1 WO 2014061705A1 JP 2013078089 W JP2013078089 W JP 2013078089W WO 2014061705 A1 WO2014061705 A1 WO 2014061705A1
Authority
WO
WIPO (PCT)
Prior art keywords
chitosan
food
umami
drink
taste
Prior art date
Application number
PCT/JP2013/078089
Other languages
French (fr)
Japanese (ja)
Inventor
啓太 佐々木
貴志 宮木
浩明 長崎
Original Assignee
味の素株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 味の素株式会社 filed Critical 味の素株式会社
Publication of WO2014061705A1 publication Critical patent/WO2014061705A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/56Flavouring or bittering agents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/10Natural spices, flavouring agents or condiments; Extracts thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/88Taste or flavour enhancing agents

Definitions

  • the present invention relates to a food and drink with enhanced salty taste and / or umami and a method for producing the same, a composition for enhancing the salty taste and / or umami of food and drink, and a method for enhancing the salty and / or umami taste of food and drink.
  • Sodium chloride the main component of sodium chloride, is an essential mineral for the maintenance of human life as a sodium source. Salt is used in foods and drinks for various purposes including the addition of salty taste. However, excessive intake of salt is thought to increase the risk of causing diseases such as hypertension, kidney disease, and heart disease, although there are various theories. Therefore, from the viewpoint of health, it is important to reduce salt intake, especially sodium intake.
  • Salt intake can be reduced by, for example, reducing the amount of salt used when producing food and drink (salt reduction).
  • salt reduction reducing the amount of salt used when producing food and drink
  • salt substitute substances for example, potassium salts such as potassium chloride, ammonium salts such as ammonium chloride, magnesium salts such as magnesium chloride, and the like are known.
  • Peptides composed of basic amino acids such as glycylglycine, glycine ethyl ester hydrochloride, ornithyl taurine, ornithyl- ⁇ -alanine are also known as salt substitutes.
  • these salt substitute substances may usually exhibit unpleasant tastes such as bitterness.
  • Patent Document 1 Technology for suppressing bitterness of potassium chloride by combining calcium salt or magnesium salt of organic acid (Patent Literature 2), bitterness suppression technology (Patent Literature 3) by mixing whey minerals, sodium gluconate and potassium chloride has been reported.
  • Patent Literature 2 Technology for suppressing bitterness of potassium chloride by combining calcium salt or magnesium salt of organic acid
  • Patent Literature 3 bitterness suppression technology
  • salt reduction techniques include, for example, a method using a compound that enhances salty taste. It has been known for a long time that basic amino acids and organic acids have a salty taste enhancing action. Also, a mixture of arginine, aspartic acid and succinic acid (Patent Document 4), protein hydrolyzate such as egg white protein, gelatin, soybean protein, wheat protein, corn protein, fish protein, milk protein, meat protein (Patent Document 5) A peptide obtained by hydrolyzing collagen having a molecular weight of 50,000 daltons or less (Patent Document 6), thaumatin (Patent Document 7), a cetylpyridium salt alone or a cetylpyridium salt as a cationic surfactant It is obtained by hydrolyzing and deamidating a mixture with a basic amino acid such as arginine or lysine (Patent Document 8), a saturated aliphatic monocarboxylic acid having 3 to 8 carbon atoms (Patent Document 9
  • Patent Document 10 Acid peptide
  • Patent Document 11 aminocarbonyl reaction of peptide having molecular weight of 1000 to 5000 and carbonyl compound
  • Patent Document 12 salty taste enhancement by dipeptide comprising glutamic acid
  • umami tends to be regarded as an important component of taste, and demand for umami has been increasing year by year. Therefore, from the viewpoint of saving umami substance resources, a technique for enhancing umami is required.
  • Patent Document 13 and Non-Patent Document 1 etc. Has been.
  • Patent Document 14 and Non-Patent Document 2 report that when 10 to 5000 ppm of glucosamine is added to a food or drink, effects such as improved flavor and sweet taste are exhibited.
  • Patent Document 14 or Non-Patent Document 2 there is a problem that a unique flavor of glucosamine itself is imparted to the food or drink and rather the preference is lowered.
  • Chitin oligosaccharides, chitosan oligosaccharides and N-acetylglucosamine are known to have therapeutic effects on immune stimulation and osteoarthritis of the knee, and are mainly used to promote health and to supplements and foods and drinks. 5 to 10% have been added, and the contents are reported in Non-Patent Documents 2 to 5. However, it has not been reported so far that chitin oligosaccharide, chitosan oligosaccharide and N-acetylglucosamine have a taste enhancing effect.
  • the objective of this invention is providing the food-drinks by which saltiness and / or umami
  • the object of the present invention is to provide a salty and / or umami enhancing composition for food and drink, and a method for enhancing the salty and / or umami taste of food and drink, which can sufficiently enhance the salty and / or umami taste of the food and drink. Is to provide.
  • chitosan or glucosamine or a salt thereof is extremely low in food and drink compared to the prior art. It was found that by adding to such a food or drink, a food or drink having a sufficiently enhanced umami taste can be obtained without producing any unusual flavor. In addition, surprisingly, in addition to umami, it has also been found that a salty taste enhancing effect is also exhibited.
  • the present inventors surprisingly found that at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof is added to a food or drink with a specific concentration. It discovered that the food / beverage products which salty taste and / or umami
  • Chitosan, glucosamine, or a salt thereof (first component), or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (second component) Is a food and drink with enhanced salty taste and / or umami taste
  • first component the amount of the first component added is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste
  • the second component is added, the amount of the second component added is 0.01 to 2000 ppm by weight with respect to the whole food and beverage with enhanced salty taste and / or umami.
  • chitosan is a compound represented by formula (I).
  • the amount of the second component is 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by adding the above composition.
  • a composition for addition to food or drink is 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by adding the above composition.
  • the present invention is as shown in the above [1] to [16], which are composed of a first component (ie, chitosan or glucosamine, or a salt thereof), a second component (ie, chitin oligosaccharide, chitosan oligosaccharide, Each at least one kind of chitosan analog selected from N-acetylglucosamine or a salt thereof is decomposed and described as follows.
  • a first component ie, chitosan or glucosamine, or a salt thereof
  • a second component ie, chitin oligosaccharide, chitosan oligosaccharide,
  • Each at least one kind of chitosan analog selected from N-acetylglucosamine or a salt thereof is decomposed and described as follows.
  • a method for producing a food or drink with enhanced salty taste and / or umami comprising a step of adding chitosan or glucosamine or a salt thereof to the food or drink, The method wherein the amount of chitosan or glucosamine added or a salt thereof is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste.
  • the chitosan is a compound represented by the formula (I).
  • n 51 to 25,000.
  • a method for enhancing the salty and / or umami taste of a food or drink comprising a step of adding chitosan or glucosamine or a salt thereof to the food or drink, The method wherein the amount of the chitosan or glucosamine added or the salt thereof is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by the above method.
  • the method according to [20], wherein the chitosan is a compound represented by the formula (I).
  • n 51 to 25,000.
  • n 51 to 25,000.
  • the composition according to [26], wherein chitosan is a compound represented by formula (I).
  • a food / beverage product with enhanced saltiness and / or umami taste comprising a step of adding at least one chitosan-related compound selected from chitin oligosaccharides, chitosan oligosaccharides, N-acetylglucosamine or a salt thereof to the food / beverage products
  • the method according to [29], wherein the chitosan-related compound is represented by the formula (II).
  • R represents NH 2 or NHCOCH 3
  • n1 represents 1 to 50.
  • a method for enhancing the salty taste and / or umami taste of a food or drink comprising a step of adding at least one chitosan analog or a salt thereof selected from chitin oligosaccharide, chitosan oligosaccharide or N-acetylglucosamine to the food or drink.
  • R represents NH 2 or NHCOCH 3
  • n1 represents 1 to 50.
  • the salt of the chitosan-related compound is a hydrochloride.
  • a food or drink in which the amount of the chitosan-related compound or salt added is 0.01 to 2000 ppm by weight based on the whole food or drink with enhanced salty taste and / or umami taste.
  • a composition for enhancing the salty taste and / or umami taste of food and drink comprising at least one chitosan-related compound selected from chitin oligosaccharides, chitosan oligosaccharides, N-acetylglucosamine, or a salt thereof, Food / beverage products such that the amount of the chitosan-related compound or a salt thereof is 0.01 to 2000 ppm by weight with respect to the whole food / beverage products whose salty taste and / or umami taste is enhanced by adding the above composition.
  • a composition that is for addition to the. The composition according to [38], wherein the chitosan-related compound is represented by the formula (II).
  • taste were fully strengthened, and its manufacturing method can be provided, without providing different flavor.
  • the salty and / or umami-enhancing composition for food and drink which can sufficiently enhance the salty and / or umami taste of the food and drink without imparting a different flavor, and the food and drink A salty and / or umami enhancing method may be provided.
  • the food-drinks with enhanced salty taste and / or umami taste and its manufacturing method can be provided.
  • a salty and / or umami enhancing composition for enhancing the salty taste and / or umami of a food and drink and a method for enhancing the salty and / or umami taste of a food and drink. obtain.
  • Food / beverage products with enhanced salty taste and / or umami are chitosan, glucosamine, or salts thereof (hereinafter also referred to as “first component”). Or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (hereinafter also referred to as “second component”) at a specific concentration It is.
  • “unusual flavor” refers to an unfavorable flavor such as an irritating odor, bitterness or astringency that causes discomfort when a food or drink is taken orally.
  • the chitosan used in the present invention is obtained by deacetylating and purifying chitin contained in crustaceans such as shrimp and crab, insects such as beetles and crickets, squid cartilage, mushrooms and fungal cell walls.
  • a basic polysaccharide ( ⁇ -1,4-Poly-D-glucosamine). Chitosan is represented by the following formula (I), for example.
  • n usually represents 51 to 25,000, preferably 100 to 25,000, and particularly preferably 500 to 25,000.
  • the degree of polymerization of chitosan (n in the above formula (I)) is calculated by calculating the weight average molecular weight from the molecular weight distribution measured by size exclusion chromatography, which is the molecular weight of the monomer represented by the formula (I). It is calculated by dividing by.
  • Glucosamine used in the present invention is a monosaccharide (2-Amino-2-deoxy-D-glucose) that can be obtained by partially hydrolyzing chitosan with hydrochloric acid or an enzyme (eg, chitonase), etc., and purifying and isolating it.
  • Glucosamine is represented by the following formula (III).
  • Examples of the salt of chitosan or glucosamine include salts with organic acids (eg, acetate, lactate, citrate, etc.) and salts with inorganic acids (eg, hydrochloride, sulfate, etc.). Preferably, it is hydrochloride.
  • the method for producing chitosan or glucosamine or a salt thereof used in the present invention is not particularly limited, and any one obtained by any production method can be used. Moreover, you may use a commercial item.
  • Chitin oligosaccharides used in the present invention include chitin contained in shellfish such as shrimp and crab, insects such as beetles and crickets, squid cartilage, mushrooms, fungal cell walls, etc., with hydrochloric acid or an enzyme (eg, An oligosaccharide that can be obtained by partial hydrolysis, purification, and isolation using chitonase or the like.
  • Chitosan oligosaccharide generally refers to an oligosaccharide that can be obtained by deacetylating chitin, followed by partial hydrolysis with hydrochloric acid or an enzyme (eg, chitonase) and the like, followed by purification and isolation.
  • N-acetylglucosamine refers to a monosaccharide that can be obtained by partially hydrolyzing chitin or chitin oligosaccharide with hydrochloric acid or an enzyme (eg, chitonase), and the like, followed by purification and isolation.
  • the chitosan-related compound used in the present invention is represented by the following formula (II).
  • R represents NH 2 or NHCOCH 3 .
  • N1 is usually 1 to 50, preferably 1 to 20, more preferably 1 to 15, and particularly preferably 1 to 10.
  • the degree of polymerization of the chitosan-related compound (n1 in the above formula (II)) is calculated by calculating the weight average molecular weight from the molecular weight distribution measured by size exclusion chromatography, which is represented by the monomer represented by the formula (II) It is calculated by dividing by the molecular weight.
  • the chitin oligosaccharide which is one kind of chitosan-related compounds used in the present invention is represented by the following formula (IV).
  • n2 degree of polymerization
  • n2 degree of polymerization
  • the chitosan oligosaccharide that is one of the chitosan-related compounds used in the present invention is represented by the following formula (V).
  • n3 degree of polymerization
  • n3 degree of polymerization
  • N-acetylglucosamine which is one of the chitosan-related compounds used in the present invention, is represented by the following formula (VI).
  • Examples of the salt of a chitosan-related compound include a salt with an organic acid (eg, acetate, lactate, citrate, etc.) and a salt with an inorganic acid (eg, hydrochloride, sulfate, etc.). Preferably, it is hydrochloride.
  • an organic acid eg, acetate, lactate, citrate, etc.
  • a salt with an inorganic acid eg, hydrochloride, sulfate, etc.
  • it is hydrochloride.
  • the method for producing at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof used in the present invention is not particularly limited, and any method obtained by any production method may be used. It is possible to use. Moreover, you may use a commercial item.
  • the amount of the first component or the second component added to the food or drink is in a specific range with respect to the whole food or drink with enhanced salty taste and / or umami.
  • the amount of the first component added to the whole food and drink with enhanced salty taste and / or umami is within a specific range, the food and drink with enhanced salty taste and / or umami according to the present invention are different. It is a preferable quality in which the salty taste and / or umami taste is sufficiently enhanced without imparting any flavor.
  • taste of this invention were enhanced by the amount of this 2nd component added with respect to the whole food / beverage products with enhanced salty taste and / or umami taste being in a specific range.
  • the salty taste and / or umami taste is sufficiently enhanced.
  • the amount of the first component to be added is usually 0.01 ppm by weight or more, preferably 0.05 ppm by weight or more, based on the whole food and drink with enhanced salty taste and / or umami taste. And more preferably 0.1 ppm by weight or more.
  • the amount of the first component added is less than 0.01 ppm by weight, the salty and / or umami enhancing effect of the first component added tends to be insufficient.
  • the amount of the first component added is usually 8 ppm by weight or less, preferably 6 ppm by weight or less, more preferably 5 ppm or less, based on the whole food or drink with enhanced salty taste and / or umami taste. Weight ppm or less. When the amount of the first component added exceeds 8 ppm by weight, a different flavor is produced and the palatability is lowered.
  • the amount of the second component added is usually 0.01 ppm by weight or more, preferably 0.05 ppm by weight or more, with respect to the whole food and drink with enhanced salty taste and / or umami taste, More preferably, it is 0.1 weight ppm or more.
  • the amount of the added second component is less than 0.01 ppm by weight, the salty and / or umami enhancing effect of the added second component tends to be insufficient.
  • the amount of the second component added is usually 2000 ppm by weight or less, preferably 1000 ppm by weight or less, more preferably 500 ppm or less, based on the whole food or drink with enhanced salty taste and / or umami taste. Weight ppm or less.
  • the amount of the first component added means the amount of the first component added to the food or drink for the purpose of enhancing the salty taste and / or umami taste, and enhancing the salty taste and / or umami taste.
  • the amount of the first component (chitosan or glucosamine, or a salt thereof) originally contained in the food or drink that is the target of the above is not included.
  • the “amount of the second component added” means the amount of the second component added to the food or drink for the purpose of enhancing the salty taste and / or umami, The amount of the second component (chitosan analogue or salt thereof) originally contained in the resulting food or drink is not included.
  • the food or drink to which the first component or the second component is added is not particularly limited as long as enhanced salty taste and / or umami is desired.
  • Foods and beverages to which the first component is added include, for example, soups, sauces, dressings, mayonnaise, ketchup, flavor seasonings, noodle soup, soy sauce, miso, confectionery and snacks, processed fishery products, processed livestock products, and cooked foods.
  • soup, flavor seasoning, and noodle soup are preferable.
  • the food and drink to which the second component is added are, for example, soup, sauce, dressing, mayonnaise, ketchup, flavor seasoning, noodle soup, soy sauce, miso, confectionery and snacks (eg, potato chips, etc.), processed marine products
  • soups, flavor seasonings, noodle soups, confectionery and snacks eg, potato chips
  • the food or drink to which the first component or the second component is added is preferably a food or drink having a specific concentration of sodium chloride concentration and / or umami substance concentration.
  • the “umami substance” is not particularly limited as long as it is a substance that exhibits umami during eating. Specifically, amino acids such as sodium glutamate and sodium aspartate and salts thereof, 5′-sodium inosinate, 5 ′ -Nucleic acids such as sodium guanylate and 5'-ribonucleotide sodium and salts thereof, organic acids such as sodium succinate and sodium citrate and salts thereof, and the like, preferably sodium glutamate.
  • the sodium chloride concentration of the food and drink may be appropriately set according to the type of food and drink, etc., but is usually 0.1 to 80% by weight. Especially, when the food and drink is soup, preferably 0.1 to 3.0% by weight, more preferably 0.3 to 1.5% by weight. When the food or drink is a sauce, dressing, mayonnaise or ketchup, preferably 0.5 to 10% by weight, more preferably 1. When the food or drink is a flavor seasoning, it is preferably 10 to 80% by weight, more preferably 20 to 60% by weight.
  • the umami substance concentration of the food and drink may be appropriately set according to the type of food and drink, etc., but is usually 0.001 to 50% by weight. Especially, when the food and drink is soup, preferably 0.001 to 50% by weight, more preferably 0.01 to 1% by weight. When the food or drink is a sauce, dressing or mayonnaise, preferably 0.005 to 10% by weight, more preferably 0.05 to 7% by weight. is there.
  • the first component or the second component is added to the food or drink at a specific concentration (that is, the salty taste and / or umami of the present invention described above is enhanced).
  • a specific concentration that is, the salty taste and / or umami of the present invention described above is enhanced.
  • the step of adding the amount of the first component or the second component added to the whole food or beverage with enhanced salty taste and / or umami as described with respect to the food and beverage.
  • it can be carried out by a method similar to a known method for producing food or drink.
  • the time when the first component or the second component is added to the food or drink is not particularly limited. For example, it may be added together with other raw materials when manufacturing the food or drink, or added after the production of the food or drink. Alternatively, it may be added immediately before and / or during the eating of the food or drink.
  • composition for enhancing salty taste and / or umami taste of food and drink also provides a composition for enhancing salty taste and / or umami taste of food and drink (hereinafter also referred to as “composition of the present invention”).
  • the composition of the present invention comprises at least one chitosan analog selected from chitosan, glucosamine, or a salt thereof (hereinafter also referred to as “first component”), or chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine.
  • first component chitosan analog selected from chitosan, glucosamine, or a salt thereof
  • first component or chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine.
  • a compound or a salt thereof hereinafter also referred to as “second component” is contained as an essential component.
  • the amount of the first component or the second component contained is within the specific range described above with respect to the whole food and drink with enhanced salty taste and / or umami taste by adding the composition of the present invention. It is important that it is for adding to food and drink.
  • the food / beverage products to which the composition of the present invention is added are given a different flavor when the amount of the first component contained is within a specific range with respect to the whole food / beverage products with enhanced salty taste and / or umami taste. Without any problem, the salty taste and / or umami taste is sufficiently enhanced.
  • the specific range specifically refers to the addition of the salt and / or umami-enhanced food / beverage product having the salty and / or umami-enhanced content of the present invention described above.
  • the range is the same as the amount of one component.
  • the amount of the 2nd component to contain is a specific range with respect to the whole food / beverage products with enhanced salty taste and / or umami taste, so that the food / beverage products to which the composition of the present invention is added have a salty taste and / or Or it becomes the preferable quality in which the umami taste was fully enhanced.
  • the specific range specifically refers to the addition of the salt and / or umami-enhanced food / beverage product having the salty and / or umami-enhanced content of the present invention described above.
  • the range is the same as the amount of the two components.
  • composition of the present invention may contain components other than the first component and the second component as long as the object of the present invention is not impaired.
  • the other components include excipients, seasonings, colorants, fragrances, pH adjusters, stabilizers, preservatives, binders, disintegrants, lubricants, preservatives, anti-caking agents, An antioxidant, a brightener, etc. are mentioned.
  • composition of the present invention is not particularly limited, and examples thereof include solid (including powder, granule and the like), liquid (including slurry and the like), gel, and paste.
  • the method for producing the composition of the present invention is not particularly limited, and examples thereof include a method in which other components are added to the first component or the second component as desired and mixed using a mixer or the like.
  • the food and drink to which the composition of the present invention can be added is not particularly limited as long as it has a salty taste and / or umami, and is exemplified with respect to the food and drink with the enhanced salty taste and / or umami of the present invention described above. The same thing is mentioned. Moreover, the time to add to the food / beverage products to which the composition of the present invention is added is not particularly limited, and can be added as exemplified above for the food / beverage products with enhanced salty taste and / or umami taste of the present invention.
  • composition of the present invention can be accompanied by instructions describing the appropriate amount added to food and drink. Further, for example, a simple measuring container may be attached or a certain amount may be subdivided in advance so that the appropriate addition amount can be easily measured.
  • the present invention also provides a method for enhancing salty taste and / or umami taste of food and drink (hereinafter also referred to as “the salty taste and / or umami taste enhancing method of the present invention”).
  • the method for enhancing salty taste and / or umami taste of the present invention comprises, as food and drink, chitosan, glucosamine, or a salt thereof (hereinafter also referred to as “first component”), chitin oligosaccharide, chitosan oligosaccharide, or N-acetylglucosamine.
  • Adding at least one selected chitosan-related compound or a salt thereof (hereinafter also referred to as “second component”).
  • second component a selected chitosan-related compound or a salt thereof
  • the salty taste and / or umami enhancing method of the present invention is such that the amount of the first component or the second component added to the food or drink is enhanced by the salty taste and / or umami enhancing method of the present invention. It is important to have a specific range for the entire product.
  • the amount of the first component to be added is specifically the total amount of the salty and / or umami-enhanced foods and beverages described above for the salty and / or umami-enhanced foods and beverages of the present invention.
  • the range is the same as the amount of the first component added.
  • the amount of the second component to be added is specifically the whole food and drink with enhanced salty taste and / or umami described above for the food and drink with enhanced salty taste and / or umami of the present invention. The same range as the amount of the second component to be added.
  • the food and drink to which the salty taste and / or umami enhancing method of the present invention can be applied is not particularly limited as long as it has a salty taste and / or umami, and the food and drink with enhanced salty taste and / or umami of the present invention described above. The thing similar to what was illustrated about is mentioned.
  • the timing at which the first component or the second component is added to the food or drink is not particularly limited, and can be added as exemplified above for the food and drink with enhanced salty taste and / or umami of the present invention.
  • Glucosamine Yaizu Suisan Kogyo Co., Ltd., trade name “Natural Glucosamine”
  • Chitosan oligosaccharide Koyo Chemical Co., Ltd., trade name “Kyoyo Oligo-N-Glucosamine”
  • Degree of polymerization 2-8 N-acetylglucosamine: manufactured by Koyo Chemical Co., Ltd., trade name “Koyo N-acetylglucosamine”
  • Example 1 Evaluation of salty taste enhancement effect by chitosan
  • a 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control.
  • Chitosan was added to a 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 1-1 to 1-6 and Comparative Examples 1-1 to 1-4, respectively.
  • the amount of chitosan added was such that the concentration shown in Table 1 was obtained with respect to the entire aqueous solutions of the prepared examples and comparative examples.
  • 5 times the amount of malic acid of chitosan was also added together with chitosan.
  • the sensory evaluation was performed by two specialist panels based on the scoring method for the salty strength, the different flavor strength and the overall usefulness of each of the Examples and Comparative Examples obtained.
  • the “scoring method” refers to the method described in “Measurement of deliciousness—actuality of food sensory test” (Hideko Furukawa, Kobo, 1994) p29-49.
  • “Strength of saltiness” is 10 points with saltiness enhanced to 0.88% by weight sodium chloride aqueous solution (positive control), and the salty taste is completely different from 0.8% by weight sodium chloride aqueous solution (negative control) What was not done was evaluated as 0 points.
  • “Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did. “Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect. The results are shown in Table 1.
  • Example 2 Evaluation of umami enhancement effect by chitosan
  • a 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control.
  • Chitosan was added to a 0.2 wt% sodium glutamate aqueous solution (negative control) to prepare aqueous solutions of Examples 2-1 to 2-6 and Comparative Examples 2-1 to 2-4, respectively.
  • the amount of chitosan added was such that the concentration shown in Table 2 was obtained with respect to the entire aqueous solutions of the prepared examples and comparative examples.
  • 5 times the amount of malic acid of chitosan was also added together with chitosan.
  • Example 3 Evaluation of salty taste enhancement effect by chitosan having a high degree of polymerization
  • a 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control.
  • Chitosan having a high degree of polymerization was added to 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 3-1 and 3-2, respectively.
  • the amount of chitosan having a high degree of polymerization was set to an amount that gives the concentration shown in Table 3 with respect to the entire aqueous solutions of the prepared examples.
  • Example 4 Evaluation of umami enhancement effect by chitosan having a high degree of polymerization
  • a 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control.
  • Chitosan having a high degree of polymerization was added to a 0.2 wt% sodium glutamate aqueous solution (negative control) to prepare aqueous solutions of Examples 4-1 and 4-2, respectively.
  • the amount of chitosan having a high degree of polymerization was set to an amount that gives the concentration shown in Table 4 with respect to the entire aqueous solutions of the prepared examples.
  • Example 5 Evaluation of salty taste enhancing effect by glucosamine
  • a 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control.
  • Glucosamine was added to 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 5-1 to 5-6 and Comparative examples 5-1 to 5-4, respectively.
  • the amount of the added glucosamine was set to an amount having a concentration shown in Table 5 with respect to each of the prepared aqueous solutions of Examples and Comparative Examples.
  • Example 6 Evaluation of umami enhancing effect by glucosamine
  • a 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control.
  • Glucosamine was added to a 0.2 wt% aqueous sodium glutamate solution (negative control) to prepare aqueous solutions of Examples 6-1 to 6-6 and Comparative Examples 6-1 to 6-4, respectively.
  • the amount of glucosamine added was set to an amount that gives the concentration shown in Table 6 with respect to the entire aqueous solutions of the prepared Examples and Comparative Examples.
  • Example 7 Evaluation of the effect of chitosan on food and drink
  • a commercially available noodle soup manufactured by Yamaki Co., Ltd.
  • kelp ponzu manufactured by Mitsukan Co., Ltd.
  • a positive control was prepared by adding 0.1 g of sodium chloride to 100 ml of each prepared negative control.
  • the salty strength, umami strength, taste preference, strength of different flavors, and overall usefulness were sensory based on a rating method by three specialist panels. Evaluation was performed. “Saltiness” was evaluated as 10 points when the saltiness was enhanced equivalently to the positive control, and 0 points when the saltiness did not change at all from the negative control. “Umami strength” was evaluated as 10 points when the umami was very strong, and 0 points when the umami did not change at all from the negative control. The “preference for taste” was evaluated as 10 points that were improved as much as the positive control, and 0 points that did not change at all from the negative control.
  • “Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did. “Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect. The results are shown in Table 7.
  • Example 8 Evaluation of the effect of glucosamine on food and drink
  • Hot water was added to commercially available Chinese soup (manufactured by Ajinomoto Co., Inc.), corn soup (manufactured by Ajinomoto Co., Inc.), and consomme soup (manufactured by Ajinomoto Co., Inc.) to a dilution of 1.25 times.
  • Sodium chloride is added to each of the prepared negative controls, and the concentration of each sodium chloride is the same as that prepared according to the normal preparation method (160 ml / 160 ml / day for products normally prepared by pouring hot water with food). The concentration was adjusted to that obtained by pouring hot water with food, and used as a positive control.
  • Glucosamine was added to the prepared negative control to prepare soups of Examples 8-1 to 8-3.
  • the amount of glucosamine added was 1 ppm by weight with respect to the whole soup of the prepared example.
  • the sensory evaluation was performed by three specialist panels on the salty strength, umami strength, preference as a soup, strength of different flavors, and overall usefulness of each Example obtained. “Saltiness” was evaluated as 10 points when the saltiness was enhanced equivalently to the positive control, and 0 points when the saltiness did not change at all from the negative control. “Umami strength” was evaluated as 10 points when the umami was very strong, and 0 points when the umami did not change at all from the negative control. The “preference for soup” was evaluated as 10 points that were improved as much as the positive control, and 0 points that did not change at all from the negative control.
  • “Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did. “Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect. The results are shown in Table 8.
  • Example 9 Evaluation of salty taste enhancing effect by chitin oligosaccharide
  • a 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control.
  • Chitin oligosaccharides were added to a 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 9-1 to 9-12 and Comparative Examples 9-1 and 9-2, respectively.
  • the amount of the chitin oligosaccharide added was such that the concentration shown in Tables 9-1 and 9-2 was obtained with respect to the entire aqueous solutions prepared in Examples and Comparative Examples.
  • Example 10 Evaluation of umami enhancing effect by chitin oligosaccharide
  • Example 10-2 A 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control.
  • Chitin oligosaccharides were added to a 0.2 wt% sodium glutamate aqueous solution (negative control) to prepare aqueous solutions of Examples 10-1 to 10-12 and Comparative Examples 10-1 and 10-2, respectively.
  • the amount of chitin oligosaccharide added was such that the concentrations shown in Tables 10-1 and 10-2 were obtained with respect to the whole aqueous solutions of the prepared examples and comparative examples.
  • Example 11 Evaluation of salty taste enhancing effect by chitosan oligosaccharide
  • Example 11 Evaluation of salty taste enhancing effect by chitosan oligosaccharide
  • a 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control.
  • Chitosan oligosaccharide was added to 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 11-1 to 11-12 and Comparative Examples 11-1 and 11-2, respectively.
  • the amount of chitosan oligosaccharide added was such that the concentration shown in Tables 11-1 and 11-2 was obtained for each of the prepared aqueous solutions of Examples and Comparative Examples.
  • Example 12 Evaluation of umami enhancing effect by chitosan oligosaccharide
  • a 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control.
  • Chitosan oligosaccharides were added to 0.2 wt% sodium glutamate aqueous solution (negative control) to prepare aqueous solutions of Examples 12-1 to 12-12 and Comparative Examples 12-1 and 12-2, respectively.
  • the amount of chitosan oligosaccharide added was such that the concentration shown in Tables 12-1 and 12-2 was obtained for each of the prepared aqueous solutions of Examples and Comparative Examples.
  • Example 13 Evaluation of salty taste enhancing effect by N-acetylglucosamine
  • a 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control.
  • N-acetylglucosamine was added to a 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 13-1 to 13-12 and Comparative Examples 13-1 and 13-2, respectively.
  • the amount of N-acetylglucosamine added was such that the concentration shown in Tables 13-1 and 13-2 was obtained for each of the prepared aqueous solutions of Examples and Comparative Examples.
  • Example 14 Evaluation of umami enhancing effect by N-acetylglucosamine
  • a 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control.
  • N-acetylglucosamine was added to a 0.2 wt% sodium glutamate aqueous solution (negative control) to prepare aqueous solutions of Examples 14-1 to 14-12 and Comparative Examples 14-1 and 14-2, respectively.
  • the amount of N-acetylglucosamine added was such that the concentrations shown in Tables 14-1 and 14-2 were obtained for each of the prepared aqueous solutions of Examples and Comparative Examples.
  • At least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof has an effect of enhancing salty taste and / or umami taste. It was confirmed to have. Further, when the amount of the chitosan-related compound or salt thereof added is in the range of 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami, the salty taste and / or umami is enhanced. It was confirmed that the effect of
  • Example 15 Evaluation of effect of chitosan oligosaccharide on liquid food
  • Commercial egg soup (Ajinomoto Co.), Chinese soup (Ajinomoto Co.), spinach soup (Ajinomoto Co.), Mozuku soup (Ajinomoto Co.), corn soup (Ajinomoto Co.), Potage soup (Ajinomoto Co.), Hot water was added to Consomme Soup (Ajinomoto Co., Inc.), Chicken Consomme Soup (Ajinomoto Co., Inc.), and Maru Chicken Gara Soup (Ajinomoto Co., Inc.) so that it would be diluted 1.25 times (usually 160ml / pour hot water with food) After adding hot water at 200 ml / meal to the product prepared in step 1), the ingredients filtered through a net were used as negative controls.
  • Sodium chloride is added to each of the prepared negative controls, and the concentration of each sodium chloride is the same as that prepared according to the normal preparation method (160 ml / 160 ml / day for products normally prepared by pouring hot water with food). The concentration was adjusted to that obtained by pouring hot water with food, and used as a positive control.
  • the sensory evaluation was performed by three specialist panels on the salty strength, umami strength, preference as a soup, strength of different flavors, and overall usefulness of each Example obtained. “Saltiness” was evaluated as 10 points when the saltiness was enhanced equivalently to the positive control, and 0 points when the saltiness did not change at all from the negative control. “Umami strength” was evaluated as 10 points when the umami was very strong, and 0 points when the umami did not change at all from the negative control. The “preference for soup” was evaluated as 10 points that were improved as much as the positive control, and 0 points that did not change at all from the negative control.
  • “Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did. “Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect. The results are shown in Tables 15-1 to 15-3.
  • Example 16 Evaluation of effect of chitin oligosaccharide on liquid food
  • Hot water was added to commercially available Chinese soup (manufactured by Ajinomoto Co., Inc.) and corn soup (manufactured by Ajinomoto Co., Inc.) to a dilution of 1.25 times (normally 160 ml / 200 ml / for products prepared by pouring hot water with food) After pouring hot water with food), the ingredients filtered through a net were used as negative controls.
  • Sodium chloride is added to each of the prepared negative controls, and the concentration of each sodium chloride is the same as that prepared according to the normal preparation method (160 ml / 160 ml / day for products normally prepared by pouring hot water with food). The concentration was adjusted to that obtained by pouring hot water with food, and used as a positive control.
  • the sensory evaluation was performed by three specialist panels on the salty strength, umami strength, preference as a soup, strength of different flavors, and overall usefulness of each Example obtained. “Saltiness” was evaluated as 10 points when the saltiness was enhanced equivalently to the positive control, and 0 points when the saltiness did not change at all from the negative control. “Umami strength” was evaluated as 10 points when the umami was very strong, and 0 points when the umami did not change at all from the negative control. The “preference for soup” was evaluated as 10 points that were improved as much as the positive control, and 0 points that did not change at all from the negative control.
  • “Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did. “Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect. The results are shown in Table 16.
  • Example 17 Evaluation of effect of chitosan oligosaccharide on solid food
  • a commercially available potato chip manufactured by Yamazaki Nabisco Co., Ltd.
  • a chip dust powder having the composition shown in Table 17 was used as a negative control.
  • 1 g of the chips dust powder was applied to 9 g of potato chips.
  • 1 g of sodium chloride with respect to 10 g of prepared negative control potato chips was made into positive control.
  • the sodium chloride concentration of the negative control potato chips is 0.6% by weight, and the sodium chloride concentration of the positive control potato chips is 1.6% by weight. Therefore, the negative control potato chips are 62.5% salt-reduced product of the positive control potato chips.
  • Chitosan oligosaccharide was added to the prepared negative control potato chips to prepare the potato chips of Examples 17-1 to 17-4.
  • the amount of chitosan oligosaccharide added was such that the concentration is as shown in Table 18 with respect to the whole prepared potato chips of Example. Chitosan oligosaccharide was added by trituration with dextrin.
  • the sensory evaluation was performed by three specialized panels on the salty strength, umami strength, overall taste strength, taste preference, and overall usefulness of each of the Examples obtained. “Saltiness” was evaluated as 10 points when the saltiness was enhanced equivalently to the positive control, and 0 points when the saltiness did not change at all from the negative control. “Umami strength” was evaluated as 10 points when the umami was very strong, and 0 points when the umami did not change at all from the negative control. “Overall taste intensity” was evaluated as 10 points that were improved as much as the positive control, and 0 points that did not change at all from the negative control.
  • taste which are not provided with different flavor were fully strengthened can be provided.
  • the salty and / or umami-enhancing composition for food and drink which can sufficiently enhance the salty and / or umami taste of the food and drink without imparting a different flavor, and the food and drink A salty and / or umami enhancing method may be provided.
  • the food-drinks with enhanced salty taste and / or umami taste, and its manufacturing method can be provided.
  • a salty and / or umami enhancing composition for enhancing the salty taste and / or umami of a food and drink, and a method for enhancing the salty and / or umami taste of a food and drink. obtain.

Abstract

The purpose of the present invention is to provide a food or drink with amply enhanced salty taste and/or umami and a manufacturing method therefor. A method for manufacturing a food or drink with enhanced salty taste and/or umami, the method comprising a process for adding chitosan, glucosamine, or a salt thereof (first component) or at least one kind of chitosan-related compound selected from chitin oligosaccharides, chitosan oligosaccharides, and N-acetyl glucosamine, or a salt thereof (second component) to the food or drink so as to give a specified concentration.

Description

塩味及び/又はうま味が増強された飲食品及びその製造方法、飲食品の塩味及び/又はうま味増強用組成物、飲食品の塩味及び/又はうま味増強方法Food / beverage products with enhanced salty taste and / or umami and method for producing the same, salty and / or umami enhancing composition for food / beverage products, and salty and / or umami enhancing method for food / beverage products
 本発明は、塩味及び/又はうま味が増強された飲食品及びその製造方法、飲食品の塩味及び/又はうま味増強用組成物、飲食品の塩味及び/又はうま味増強方法に関する。 The present invention relates to a food and drink with enhanced salty taste and / or umami and a method for producing the same, a composition for enhancing the salty taste and / or umami of food and drink, and a method for enhancing the salty and / or umami taste of food and drink.
 食塩の主成分である塩化ナトリウムは、必須ミネラルであるナトリウム源として、ヒトの生命維持に不可欠な物質である。食塩は、塩味(salty taste)の付与を始めとする種々の用途で飲食品に利用されている。しかしながら、食塩の過剰摂取は、諸説あるものの高血圧、腎臓病、心臓病等の疾病を引き起こすリスクを高めると考えられている。そのため、健康面から、食塩摂取量、特にナトリウム摂取量を低減することが重要視されている。 Sodium chloride, the main component of sodium chloride, is an essential mineral for the maintenance of human life as a sodium source. Salt is used in foods and drinks for various purposes including the addition of salty taste. However, excessive intake of salt is thought to increase the risk of causing diseases such as hypertension, kidney disease, and heart disease, although there are various theories. Therefore, from the viewpoint of health, it is important to reduce salt intake, especially sodium intake.
 食塩摂取量は、例えば、飲食品を製造する際の食塩の使用量を減らすこと(減塩)により低減できる。しかしながら、減塩時には、塩味の不足により満足感が低下するという問題が生ずる。そのため、食塩の使用量を低減しても飲食品の塩味や満足感を損なわない減塩技術の開発が強く求められている。 Salt intake can be reduced by, for example, reducing the amount of salt used when producing food and drink (salt reduction). However, at the time of salt reduction, there arises a problem that satisfaction is lowered due to lack of salty taste. Therefore, there is a strong demand for the development of a salt reduction technique that does not impair the salty taste and satisfaction of food and drink even when the amount of salt used is reduced.
 減塩技術としては、例えば、それ自体が塩味を呈する化合物(食塩代替物質)で食塩の一部を代替する方法が挙げられる。食塩代替物質としては、例えば、塩化カリウム等のカリウム塩、塩化アンモニウム等のアンモニウム塩、塩化マグネシウム等のマグネシウム塩等が知られている。また、グリシルグリシン、グリシンエチルエステル塩酸塩、オルニチルタウリン、オルニチル-β-アラニン等の塩基性アミノ酸からなるペプチド類も食塩代替物質として知られている。しかしながら、これら食塩代替物質は、通常、苦味等の不快な呈味を示す場合がある。そこで、このような苦味等の不快な呈味を低減する技術として、塩化カリウムと塩化アンモニウムと乳酸カルシウムとL-アスパラギン酸ナトリウムを特定の比率で配合することで塩味の質を向上させ、更にL-グルタミン酸塩および/または核酸系呈味素材を特定の比率で配合することによる塩化カリウムの苦味抑制改善技術(特許文献1)、有機酸のカルシウム塩やマグネシウム塩を組み合わせた塩化カリウムの苦味抑制技術(特許文献2)、乳清ミネラルとグルコン酸ナトリウム、塩化カリウムの混合による苦味抑制技術(特許文献3)等が報告されている。しかしながら、完全に苦味等の不快な呈味を低減することは達成できておらず、消費者のニーズにあった減塩技術に十分到達しているとは言えない。 As a salt reduction technique, for example, a method of substituting a part of sodium chloride with a compound (salt substitute substance) that itself has a salty taste can be mentioned. As salt substitute substances, for example, potassium salts such as potassium chloride, ammonium salts such as ammonium chloride, magnesium salts such as magnesium chloride, and the like are known. Peptides composed of basic amino acids such as glycylglycine, glycine ethyl ester hydrochloride, ornithyl taurine, ornithyl-β-alanine are also known as salt substitutes. However, these salt substitute substances may usually exhibit unpleasant tastes such as bitterness. Therefore, as a technique for reducing such unpleasant taste such as bitterness, the quality of salty taste is improved by blending potassium chloride, ammonium chloride, calcium lactate and sodium L-aspartate at a specific ratio, and further, L -Technology for improving bitterness suppression of potassium chloride by combining glutamate and / or nucleic acid-based flavoring material in a specific ratio (Patent Document 1), Technology for suppressing bitterness of potassium chloride by combining calcium salt or magnesium salt of organic acid (Patent Literature 2), bitterness suppression technology (Patent Literature 3) by mixing whey minerals, sodium gluconate and potassium chloride has been reported. However, it has not been possible to completely reduce unpleasant taste such as bitterness, and it cannot be said that the salt reduction technology that meets the needs of consumers has been sufficiently achieved.
 さらに、その他の減塩技術としては、例えば、塩味を増強する化合物を用いる方法が挙げられる。古くから、塩基性アミノ酸や有機酸類は塩味の増強作用を有することが知られている。また、アルギニンとアスパラギン酸とコハク酸の混合物(特許文献4)、卵白蛋白質、ゼラチン、大豆蛋白質、小麦蛋白質、コーン蛋白質、魚蛋白質、乳蛋白質、肉蛋白質等の蛋白質加水分解物(特許文献5)、分子量が50,000ダルトン以下のコラーゲンを加水分解して得られるペプチド(特許文献6)、ソーマチン(特許文献7)、陽イオン性界面活性剤であるセチルピリジウム塩単独またはセチルピリジウム塩とアルギニンやリジン等の塩基性アミノ酸との混合物(特許文献8)、炭素数が3~8の飽和脂肪族モノカルボン酸(特許文献9)、酸性ペプチドまたは蛋白質を加水分解及び脱アミド処理して得られる酸性ペプチド(特許文献10)、分子量1000~5000のペプチドとカルボニル化合物とのアミノカルボニル反応物(特許文献11)、グルタミン酸を含むジペプチドによる塩味増強(特許文献12)等が報告されている。しかしながら、減塩時の塩味の不足と満足感の低下を完全に改善できる技術には到達していない。
 このように、食塩代替物質や塩味増強物質を使用する減塩技術が数多く報告されているものの、減塩効果やコスト、安全性などのあらゆる面を十分満足させるほどの技術には到達していない。
Furthermore, other salt reduction techniques include, for example, a method using a compound that enhances salty taste. It has been known for a long time that basic amino acids and organic acids have a salty taste enhancing action. Also, a mixture of arginine, aspartic acid and succinic acid (Patent Document 4), protein hydrolyzate such as egg white protein, gelatin, soybean protein, wheat protein, corn protein, fish protein, milk protein, meat protein (Patent Document 5) A peptide obtained by hydrolyzing collagen having a molecular weight of 50,000 daltons or less (Patent Document 6), thaumatin (Patent Document 7), a cetylpyridium salt alone or a cetylpyridium salt as a cationic surfactant It is obtained by hydrolyzing and deamidating a mixture with a basic amino acid such as arginine or lysine (Patent Document 8), a saturated aliphatic monocarboxylic acid having 3 to 8 carbon atoms (Patent Document 9), an acidic peptide or protein. Acid peptide (Patent Document 10), aminocarbonyl reaction of peptide having molecular weight of 1000 to 5000 and carbonyl compound (Patent Document 11), salty taste enhancement by dipeptide comprising glutamic acid (Patent Document 12) have been reported. However, it has not yet reached a technology that can completely improve the lack of salty taste and the decrease in satisfaction during salt reduction.
In this way, although many salt reduction techniques using salt substitutes and salty taste enhancing substances have been reported, they have not yet reached a level that satisfies all aspects of salt reduction effect, cost, safety, etc. .
 また、近年、味を構成する要素のうち、うま味が重要視される傾向にあり、うま味の需要は年々上昇傾向にある。そこで、うま味物質資源の節約の観点から、うま味を増強する技術が求められている。 In recent years, umami tends to be regarded as an important component of taste, and demand for umami has been increasing year by year. Therefore, from the viewpoint of saving umami substance resources, a technique for enhancing umami is required.
 一方、キトサン又グルコサミンは、主にコレステロール値の低下等の健康増進を目的として、飲食品へ0.5~10%添加されてきており、その内容は特許文献13及び非特許文献1等に報告されている。また、グルコサミンを飲食品に10~5000ppm添加すると、風味の向上や甘味の改善等の効果を示すことが、特許文献14及び非特許文献2等に報告されている。しかしながら、実際には、特許文献14及び非特許文献2に従ってグルコサミンを飲食品に添加すると、グルコサミン自身が持つ独特の風味が飲食品に付与され、むしろ嗜好性が下がるという課題が存在した。そのため、現在まで、グルコサミンやキトサンを調味目的で飲食品へ添加することは、ほとんど行われていない。このような現状の中、キトサン又はグルコサミンを、塩味及び/又はうま味を有する飲食品に添加することによって、異風味を全く生じることなく自然に、好ましい呈味を増強し得ることは、これまで一切報告されていない。 On the other hand, chitosan or glucosamine has been added to foods and drinks for the purpose of promoting health mainly by lowering cholesterol levels, and the contents thereof are reported in Patent Document 13 and Non-Patent Document 1 etc. Has been. In addition, Patent Document 14 and Non-Patent Document 2 report that when 10 to 5000 ppm of glucosamine is added to a food or drink, effects such as improved flavor and sweet taste are exhibited. However, in reality, when glucosamine is added to a food or drink according to Patent Document 14 or Non-Patent Document 2, there is a problem that a unique flavor of glucosamine itself is imparted to the food or drink and rather the preference is lowered. Therefore, until now, glucosamine and chitosan are hardly added to foods and drinks for the purpose of seasoning. Under such circumstances, by adding chitosan or glucosamine to foods and drinks having a salty taste and / or umami taste, it has never been possible to enhance the preferred taste naturally without producing any unusual flavor. Not reported.
 また、キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンは、免疫賦活化や変形性膝関節症に対する治療効果があることが分かっており、主に健康増進を目的とし、サプリメントや飲食品へ0.5~10%添加されてきており、その内容は非特許文献2~5に報告されている。しかしながら、キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンに、呈味増強効果があることは、これまで一切報告されていない。 Chitin oligosaccharides, chitosan oligosaccharides and N-acetylglucosamine are known to have therapeutic effects on immune stimulation and osteoarthritis of the knee, and are mainly used to promote health and to supplements and foods and drinks. 5 to 10% have been added, and the contents are reported in Non-Patent Documents 2 to 5. However, it has not been reported so far that chitin oligosaccharide, chitosan oligosaccharide and N-acetylglucosamine have a taste enhancing effect.
特開平11-187841号公報JP-A-11-187841 特開平4-108358号公報JP-A-4-108358 特開2008-289426号公報JP 2008-289426 A 特開2002-345430号公報JP 2002-345430 A 特開平7-289198号公報JP-A-7-289198 特開昭63-003766号公報JP-A 63-003766 特開昭63-137658号公報JP-A-63-137658 特表平3-502517号公報Japanese National Patent Publication No. 3-502517 特開平5-184326号公報JP-A-5-184326 国際公開第01/039613号パンフレットInternational Publication No. 01/039613 Pamphlet 国際公開第2012/107020号パンフレットInternational Publication No. 2012/107020 Pamphlet 国際公開第2009/113563号パンフレットInternational Publication No. 2009/113563 Pamphlet 特表2000-504724号公報Special Table 2000-504724 特表2012-527611号公報Special table 2012-527611 gazette
 従って、本発明の目的は、塩味及び/又はうま味が十分に増強された飲食品及びその製造方法を提供することである。
 また、本発明の目的は、飲食品の塩味及び/又はうま味を十分に増強することが出来る、飲食品の塩味及び/又はうま味増強用組成物、並びに、飲食品の塩味及び/又はうま味増強方法を提供することである。
Therefore, the objective of this invention is providing the food-drinks by which saltiness and / or umami | taste was fully strengthened, and its manufacturing method.
In addition, the object of the present invention is to provide a salty and / or umami enhancing composition for food and drink, and a method for enhancing the salty and / or umami taste of food and drink, which can sufficiently enhance the salty and / or umami taste of the food and drink. Is to provide.
 本発明者らは、上記の目的を達成すべく鋭意研究を重ねた結果、驚くべき事に、飲食品に対し、キトサン若しくはグルコサミン、又はそれらの塩を、先行技術と比べて極めて低濃度となるよう飲食品に添加することによって、異風味を全く生じることなく、うま味が十分に増強された飲食品が得られることを見出した。また、驚くべき事に、うま味に加えて、塩味の増強効果も発揮されることも新たに見出した。
 さらに、本発明者らは、驚くべき事に、飲食品に対し、キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物又はその塩を、特定の濃度となるよう飲食品に添加することによって、塩味及び/又はうま味が増強された飲食品が得られることを見出した。
 本発明者らは、これらの発見により、異風味を全く生じることなく塩味及び/又はうま味が十分に増強された飲食品を完成するに至った。
 即ち、本発明は以下の通りである。
As a result of intensive studies to achieve the above-mentioned object, the present inventors have surprisingly found that chitosan or glucosamine or a salt thereof is extremely low in food and drink compared to the prior art. It was found that by adding to such a food or drink, a food or drink having a sufficiently enhanced umami taste can be obtained without producing any unusual flavor. In addition, surprisingly, in addition to umami, it has also been found that a salty taste enhancing effect is also exhibited.
Furthermore, the present inventors surprisingly found that at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof is added to a food or drink with a specific concentration. It discovered that the food / beverage products which salty taste and / or umami | taste were strengthened by adding to food / beverage products so that it may become.
By these discoveries, the present inventors have completed a food / beverage product having a sufficiently enhanced salty taste and / or umami taste without causing any unusual flavor.
That is, the present invention is as follows.
[1] キトサン、グルコサミン、若しくはそれらの塩(第1成分)、又は
 キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(第2成分)
を飲食品に添加する工程を含む、塩味及び/又はうま味が増強された飲食品の製造方法であって、
 第1成分を添加する場合、該添加される第1成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmであり、
 第2成分を添加する場合、該添加される第2成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmである方法。
[2] キトサンが、式(I)で表される化合物である、[1]記載の方法。
[1] Chitosan, glucosamine, or a salt thereof (first component), or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (second component)
A method for producing a food or drink with enhanced salty taste and / or umami,
When the first component is added, the amount of the first component added is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste,
A method in which when the second component is added, the amount of the second component added is 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste.
[2] The method according to [1], wherein chitosan is a compound represented by formula (I).
Figure JPOXMLDOC01-appb-C000009
Figure JPOXMLDOC01-appb-C000009
(式中、nは、51~25,000を示す。)
[3] キトサン類縁化合物が、式(II)で表される、[1]記載の方法。
(In the formula, n represents 51 to 25,000.)
[3] The method according to [1], wherein the chitosan-related compound is represented by the formula (II).
Figure JPOXMLDOC01-appb-C000010
Figure JPOXMLDOC01-appb-C000010
(式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
[4] キトサン若しくはグルコサミンの塩、又はキトサン類縁化合物の塩が、塩酸塩である、[1]~[3]のいずれか1つに記載の方法。
[5] キトサン、グルコサミン、若しくはそれらの塩(第1成分)、又は
 キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(第2成分)
を飲食品に添加する工程を含む、飲食品の塩味及び/又はうま味増強方法であって、
 第1成分を添加する場合、該添加される第1成分の量が、上記方法によって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmであり、
 第2成分を添加する場合、該添加される第2成分の量が、上記方法によって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmである方法。
[6] キトサンが、式(I)で表される化合物である、[5]記載の方法。
(In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
[4] The method according to any one of [1] to [3], wherein the salt of chitosan or glucosamine or the salt of a chitosan-related compound is a hydrochloride.
[5] Chitosan, glucosamine, or a salt thereof (first component), or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (second component)
A method for enhancing the salty and / or umami taste of food and drink,
When the first component is added, the amount of the first component added is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by the above method,
A method in which when the second component is added, the amount of the added second component is 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by the above method.
[6] The method according to [5], wherein the chitosan is a compound represented by the formula (I).
Figure JPOXMLDOC01-appb-C000011
Figure JPOXMLDOC01-appb-C000011
(式中、nは、51~25,000を示す。)
[7] キトサン類縁化合物が、式(II)で表される、[5]記載の方法。
(In the formula, n represents 51 to 25,000.)
[7] The method according to [5], wherein the chitosan-related compound is represented by the formula (II).
Figure JPOXMLDOC01-appb-C000012
Figure JPOXMLDOC01-appb-C000012
(式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
[8] キトサン若しくはグルコサミンの塩、又はキトサン類縁化合物の塩が、塩酸塩である、[5]~[7]のいずれか1つに記載の方法。
[9] キトサン、グルコサミン、若しくはそれらの塩(第1成分)、又は
 キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(第2成分)
を飲食品に添加してなる、塩味及び/又はうま味が増強された飲食品であって、
 第1成分を添加する場合、該添加される第1成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmであり、
 第2成分を添加する場合、該添加される第2成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmである飲食品。
[10] キトサンが、式(I)で表される化合物である、[9]記載の飲食品。
(In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
[8] The method according to any one of [5] to [7], wherein the salt of chitosan or glucosamine or the salt of a chitosan-related compound is a hydrochloride.
[9] Chitosan, glucosamine, or a salt thereof (first component), or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (second component)
Is a food and drink with enhanced salty taste and / or umami taste,
When the first component is added, the amount of the first component added is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste,
When the second component is added, the amount of the second component added is 0.01 to 2000 ppm by weight with respect to the whole food and beverage with enhanced salty taste and / or umami.
[10] The food or drink according to [9], wherein chitosan is a compound represented by formula (I).
Figure JPOXMLDOC01-appb-C000013
Figure JPOXMLDOC01-appb-C000013
(式中、nは、51~25,000を示す。)
[11] キトサン類縁化合物が、式(II)で表される、[9]記載の飲食品。
(In the formula, n represents 51 to 25,000.)
[11] The food or drink according to [9], wherein the chitosan-related compound is represented by the formula (II).
Figure JPOXMLDOC01-appb-C000014
Figure JPOXMLDOC01-appb-C000014
(式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
[12] キトサン若しくはグルコサミンの塩、又はキトサン類縁化合物の塩が、塩酸塩である、[9]~[11]のいずれか1つに記載の飲食品。
[13] キトサン、グルコサミン、若しくはそれらの塩(第1成分)、又は
 キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(第2成分)
を含有する、飲食品の塩味及び/又はうま味増強用組成物であって、
 第1成分を含有する場合、該第1成分の量が、上記組成物を添加されたことによって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmとなるように、飲食品に添加するためのものであり、
 第2成分を含有する場合、該第2成分の量が、上記組成物を添加されたことによって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmとなるように、飲食品に添加するためのものである組成物。
[14] キトサンが、式(I)で表される化合物である、[13]記載の組成物。
(In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
[12] The food or drink according to any one of [9] to [11], wherein the salt of chitosan or glucosamine or the salt of a chitosan-related compound is a hydrochloride.
[13] Chitosan, glucosamine, or a salt thereof (first component), or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (second component)
A composition for enhancing the salty and / or umami taste of food and drink,
When the first component is contained, the amount of the first component is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by adding the above composition. So that it is for addition to food and drink,
When the second component is contained, the amount of the second component is 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by adding the above composition. Thus, a composition for addition to food or drink.
[14] The composition according to [13], wherein chitosan is a compound represented by formula (I).
Figure JPOXMLDOC01-appb-C000015
Figure JPOXMLDOC01-appb-C000015
(式中、nは、51~25,000を示す。)
[15] キトサン類縁化合物が、式(II)で表される、[13]記載の組成物。
(In the formula, n represents 51 to 25,000.)
[15] The composition according to [13], wherein the chitosan-related compound is represented by the formula (II).
Figure JPOXMLDOC01-appb-C000016
Figure JPOXMLDOC01-appb-C000016
(式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
[16] キトサン若しくはグルコサミンの塩、又はキトサン類縁化合物の塩が、塩酸塩である、[13]~[15]のいずれか1つに記載の組成物。
(In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
[16] The composition according to any one of [13] to [15], wherein the salt of chitosan or glucosamine or the salt of a chitosan-related compound is a hydrochloride.
 本発明は上記[1]~[16]に示す通りであるが、これらを第1成分(即ち、キトサン若しくはグルコサミン、又はそれらの塩)、第2成分(即ち、キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物又はその塩)ごとに分解して記載すると以下の通りである。 The present invention is as shown in the above [1] to [16], which are composed of a first component (ie, chitosan or glucosamine, or a salt thereof), a second component (ie, chitin oligosaccharide, chitosan oligosaccharide, Each at least one kind of chitosan analog selected from N-acetylglucosamine or a salt thereof is decomposed and described as follows.
[17] キトサン若しくはグルコサミン、又はそれらの塩を飲食品に添加する工程を含む、塩味及び/又はうま味が増強された飲食品の製造方法であって、
 該添加されるキトサン若しくはグルコサミン、又はそれらの塩の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmである方法。
[18] キトサンが、式(I)で表される化合物である、[17]記載の方法。
[17] A method for producing a food or drink with enhanced salty taste and / or umami, comprising a step of adding chitosan or glucosamine or a salt thereof to the food or drink,
The method wherein the amount of chitosan or glucosamine added or a salt thereof is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste.
[18] The method according to [17], wherein the chitosan is a compound represented by the formula (I).
Figure JPOXMLDOC01-appb-C000017
Figure JPOXMLDOC01-appb-C000017
(式中、nは、51~25,000を示す。)
[19] キトサン又はグルコサミンの塩が、塩酸塩である、[17]又は[18]記載の方法。
[20] キトサン若しくはグルコサミン、又はそれらの塩を飲食品に添加する工程を含む、飲食品の塩味及び/又はうま味増強方法であって、
 該添加されるキトサン若しくはグルコサミン、又はそれらの塩の量が、上記方法によって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmである方法。
[21] キトサンが、式(I)で表される化合物である、[20]記載の方法。
(In the formula, n represents 51 to 25,000.)
[19] The method according to [17] or [18], wherein the salt of chitosan or glucosamine is hydrochloride.
[20] A method for enhancing the salty and / or umami taste of a food or drink comprising a step of adding chitosan or glucosamine or a salt thereof to the food or drink,
The method wherein the amount of the chitosan or glucosamine added or the salt thereof is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by the above method.
[21] The method according to [20], wherein the chitosan is a compound represented by the formula (I).
Figure JPOXMLDOC01-appb-C000018
Figure JPOXMLDOC01-appb-C000018
(式中、nは、51~25,000を示す。)
[22] キトサン又はグルコサミンの塩が、塩酸塩である、[20]又は[21]記載の方法。
[23] キトサン若しくはグルコサミン、又はそれらの塩を飲食品に添加してなる、塩味及び/又はうま味が増強された飲食品であって、
 該添加されるキトサン若しくはグルコサミン、又はそれらの塩の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmである飲食品。
[24] キトサンが、式(I)で表される化合物である、[23]記載の飲食品。
(In the formula, n represents 51 to 25,000.)
[22] The method according to [20] or [21], wherein the salt of chitosan or glucosamine is hydrochloride.
[23] A food and drink with enhanced salty taste and / or umami, wherein chitosan or glucosamine or a salt thereof is added to the food or drink,
Food / beverage products in which the amount of chitosan or glucosamine added or salt thereof is 0.01 to 8 ppm by weight with respect to the whole food / beverage products with enhanced salty taste and / or umami taste.
[24] The food or drink according to [23], wherein chitosan is a compound represented by formula (I).
Figure JPOXMLDOC01-appb-C000019
Figure JPOXMLDOC01-appb-C000019
(式中、nは、51~25,000を示す。)
[25] キトサン又はグルコサミンの塩が、塩酸塩である、[23]又は[24]記載の飲食品。
[26] キトサン若しくはグルコサミン、又はそれらの塩を含有する、飲食品の塩味及び/又はうま味増強用組成物であって、
 該キトサン若しくはグルコサミン、又はそれらの塩の量が、上記組成物を添加されたことによって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmとなるように、飲食品に添加するためのものである組成物。
[27] キトサンが、式(I)で表される化合物である、[26]記載の組成物。
(In the formula, n represents 51 to 25,000.)
[25] The food or drink according to [23] or [24], wherein the salt of chitosan or glucosamine is a hydrochloride.
[26] A composition for enhancing the salty taste and / or umami taste of food and drink, comprising chitosan or glucosamine, or a salt thereof,
The amount of the chitosan or glucosamine or a salt thereof is 0.01 to 8 ppm by weight with respect to the whole food and drink having enhanced salty taste and / or umami taste by adding the above composition. A composition for addition to a food or drink.
[27] The composition according to [26], wherein chitosan is a compound represented by formula (I).
Figure JPOXMLDOC01-appb-C000020
Figure JPOXMLDOC01-appb-C000020
(式中、nは、51~25,000を示す。)
[28] キトサン又はグルコサミンの塩が、塩酸塩である、[26]又は[27]記載の組成物。
(In the formula, n represents 51 to 25,000.)
[28] The composition according to [26] or [27], wherein the salt of chitosan or glucosamine is hydrochloride.
[29] キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物又はその塩を飲食品に添加する工程を含む、塩味及び/又はうま味が増強された飲食品の製造方法であって、
 該添加されるキトサン類縁化合物又はその塩の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmである方法。
[30] キトサン類縁化合物が、式(II)で表される、[29]記載の方法。
[29] A food / beverage product with enhanced saltiness and / or umami taste, comprising a step of adding at least one chitosan-related compound selected from chitin oligosaccharides, chitosan oligosaccharides, N-acetylglucosamine or a salt thereof to the food / beverage products A manufacturing method of
The method wherein the amount of the added chitosan-related compound or a salt thereof is 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste.
[30] The method according to [29], wherein the chitosan-related compound is represented by the formula (II).
Figure JPOXMLDOC01-appb-C000021
Figure JPOXMLDOC01-appb-C000021
(式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
[31] キトサン類縁化合物の塩が、塩酸塩である、[29]又は[30]記載の方法。
[32] キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物又はその塩を飲食品に添加する工程を含む、飲食品の塩味及び/又はうま味増強方法であって、
 該添加されるキトサン類縁化合物又はその塩の量が、上記方法によって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmである方法。
[33] キトサン類縁化合物が、式(II)で表される、[32]記載の方法。
(In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
[31] The method according to [29] or [30], wherein the salt of the chitosan-related compound is a hydrochloride.
[32] A method for enhancing the salty taste and / or umami taste of a food or drink, comprising a step of adding at least one chitosan analog or a salt thereof selected from chitin oligosaccharide, chitosan oligosaccharide or N-acetylglucosamine to the food or drink. There,
The method wherein the amount of the chitosan-related compound added or the salt thereof is 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by the above method.
[33] The method according to [32], wherein the chitosan-related compound is represented by the formula (II).
Figure JPOXMLDOC01-appb-C000022
Figure JPOXMLDOC01-appb-C000022
(式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
[34] キトサン類縁化合物の塩が、塩酸塩である、[32]又は[33]記載の方法。
[35] キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物又はその塩を飲食品に添加してなる、塩味及び/又はうま味が増強された飲食品であって、
 該添加されるキトサン類縁化合物又はその塩の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmである飲食品。
[36] キトサン類縁化合物が、式(II)で表される、[35]記載の飲食品。
(In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
[34] The method according to [32] or [33], wherein the salt of the chitosan-related compound is a hydrochloride.
[35] A food and drink with enhanced salty taste and / or umami taste, wherein at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide and N-acetylglucosamine or a salt thereof is added to the food or drink. There,
A food or drink in which the amount of the chitosan-related compound or salt added is 0.01 to 2000 ppm by weight based on the whole food or drink with enhanced salty taste and / or umami taste.
[36] The food or drink according to [35], wherein the chitosan-related compound is represented by the formula (II).
Figure JPOXMLDOC01-appb-C000023
Figure JPOXMLDOC01-appb-C000023
(式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
[37] キトサン類縁化合物の塩が、塩酸塩である、[35]又は[36]記載の飲食品。
[38] キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物又はその塩を含有する、飲食品の塩味及び/又はうま味増強用組成物であって、
 該キトサン類縁化合物又はその塩の量が、上記組成物を添加されたことによって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmとなるように、飲食品に添加するためのものである組成物。
[39] キトサン類縁化合物が、式(II)で表される、[38]記載の組成物。
(In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
[37] The food or drink according to [35] or [36], wherein the salt of the chitosan-related compound is a hydrochloride.
[38] A composition for enhancing the salty taste and / or umami taste of food and drink, comprising at least one chitosan-related compound selected from chitin oligosaccharides, chitosan oligosaccharides, N-acetylglucosamine, or a salt thereof,
Food / beverage products such that the amount of the chitosan-related compound or a salt thereof is 0.01 to 2000 ppm by weight with respect to the whole food / beverage products whose salty taste and / or umami taste is enhanced by adding the above composition. A composition that is for addition to the.
[39] The composition according to [38], wherein the chitosan-related compound is represented by the formula (II).
Figure JPOXMLDOC01-appb-C000024
Figure JPOXMLDOC01-appb-C000024
(式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
[40] キトサン類縁化合物の塩が、塩酸塩である、[38]又は[39]記載の組成物。
(In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
[40] The composition according to [38] or [39], wherein the salt of the chitosan-related compound is a hydrochloride.
 本発明によれば、異風味が付与されることなく、塩味及び/又はうま味が十分に増強された飲食品及びその製造方法を提供し得る。
 また本発明によれば、異風味を付与することなく、飲食品の塩味及び/又はうま味を十分に増強することが出来る、飲食品の塩味及び/又はうま味増強用組成物、並びに、飲食品の塩味及び/又はうま味増強方法を提供し得る。
ADVANTAGE OF THE INVENTION According to this invention, the food-drinks by which salty taste and / or umami | taste were fully strengthened, and its manufacturing method can be provided, without providing different flavor.
According to the present invention, the salty and / or umami-enhancing composition for food and drink, which can sufficiently enhance the salty and / or umami taste of the food and drink without imparting a different flavor, and the food and drink A salty and / or umami enhancing method may be provided.
 また本発明によれば、塩味及び/又はうま味が増強された飲食品並びにその製造方法を提供し得る。
 また本発明によれば、飲食品の塩味及び/又はうま味を増強することが出来る、飲食品の塩味及び/又はうま味増強用組成物、並びに、飲食品の塩味及び/又はうま味増強方法を提供し得る。
Moreover, according to this invention, the food-drinks with enhanced salty taste and / or umami taste, and its manufacturing method can be provided.
Moreover, according to the present invention, there is provided a salty and / or umami enhancing composition for enhancing the salty taste and / or umami of a food and drink, and a method for enhancing the salty and / or umami taste of a food and drink. obtain.
1.塩味及び/又はうま味が増強された飲食品
 本発明の塩味及び/又はうま味が増強された飲食品は、飲食品に、キトサン、グルコサミン、若しくはそれらの塩(以下、「第1成分」とも称する)、又はキチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(以下、「第2成分」とも称する)を、特定の濃度で添加してなるものである。
 本明細書において「異風味」とは、飲食品を経口摂取する際に不快感を生じさせる、刺激臭、苦味、渋み等の好ましくない風味をいう。
1. Food / beverage products with enhanced salty taste and / or umami The food / beverage products with enhanced salty taste and / or umami taste of the present invention are chitosan, glucosamine, or salts thereof (hereinafter also referred to as “first component”). Or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (hereinafter also referred to as “second component”) at a specific concentration It is.
In the present specification, “unusual flavor” refers to an unfavorable flavor such as an irritating odor, bitterness or astringency that causes discomfort when a food or drink is taken orally.
 本発明に用いられるキトサンは、エビ、カニ等の甲殻類、カブトムシ、コオロギ等の昆虫類、イカの軟骨、キノコ類、真菌類の細胞壁等含まれるキチンを脱アセチル化処理し、精製して得ることができる塩基性多糖類(β-1,4-Poly-D-glucosamine)をいう。キトサンは、例えば、下記の式(I)で表される。 The chitosan used in the present invention is obtained by deacetylating and purifying chitin contained in crustaceans such as shrimp and crab, insects such as beetles and crickets, squid cartilage, mushrooms and fungal cell walls. A basic polysaccharide (β-1,4-Poly-D-glucosamine). Chitosan is represented by the following formula (I), for example.
Figure JPOXMLDOC01-appb-C000025
Figure JPOXMLDOC01-appb-C000025
 式中、nは、通常51~25,000を示し、好ましくは100~25,000を示し、特に好ましくは500~25,000を示す。 In the formula, n usually represents 51 to 25,000, preferably 100 to 25,000, and particularly preferably 500 to 25,000.
 キトサンの重合度(上記の式(I)中のn)は、サイズ排除クロマトグラフィーにより測定した分子量分布から重量平均分子量を算出し、それを式(I)で示されている単量体の分子量で割ることで求められる。 The degree of polymerization of chitosan (n in the above formula (I)) is calculated by calculating the weight average molecular weight from the molecular weight distribution measured by size exclusion chromatography, which is the molecular weight of the monomer represented by the formula (I). It is calculated by dividing by.
 本発明に用いられるグルコサミンは、キトサンを塩酸又は酵素(例、キトナーゼ等)等によって部分加水分解し、精製、単離して得ることができる単糖(2-Amino-2-deoxy-D-glucose)をいう。グルコサミンは、下記の式(III)で表される。 Glucosamine used in the present invention is a monosaccharide (2-Amino-2-deoxy-D-glucose) that can be obtained by partially hydrolyzing chitosan with hydrochloric acid or an enzyme (eg, chitonase), etc., and purifying and isolating it. Say. Glucosamine is represented by the following formula (III).
Figure JPOXMLDOC01-appb-C000026
Figure JPOXMLDOC01-appb-C000026
 キトサン又はグルコサミンの塩としては、例えば、有機酸との塩(例、酢酸塩、乳酸塩、クエン酸塩等)及び無機酸との塩(例、塩酸塩、硫酸塩等)等が挙げられるが、好ましくは塩酸塩である。 Examples of the salt of chitosan or glucosamine include salts with organic acids (eg, acetate, lactate, citrate, etc.) and salts with inorganic acids (eg, hydrochloride, sulfate, etc.). Preferably, it is hydrochloride.
 本発明に用いられるキトサン若しくはグルコサミン、又はそれらの塩の製造方法は特に限定はされず、いかなる製法によって得られたものでも使用することが可能である。また、市販品を使用してもよい。 The method for producing chitosan or glucosamine or a salt thereof used in the present invention is not particularly limited, and any one obtained by any production method can be used. Moreover, you may use a commercial item.
 本発明に用いられるキチンオリゴ糖は、エビ、カニ等の甲殻類、カブトムシ、コオロギ等の昆虫類、イカの軟骨、キノコ類、真菌類の細胞壁等に含まれるキチンを、塩酸又は酵素(例、キトナーゼ等)等によって部分加水分解し、精製、単離して得ることができるオリゴ糖をいう。キトサンオリゴ糖は、一般に、キチンを脱アセチル化処理した後、塩酸又は酵素(例、キトナーゼ等)等によって部分加水分解し、精製、単離して得ることができるオリゴ糖をいう。N-アセチルグルコサミンは、キチン又はキチンオリゴ糖を塩酸又は酵素(例、キトナーゼ等)等によって部分加水分解し、精製、単離して得ることができる単糖をいう。 Chitin oligosaccharides used in the present invention include chitin contained in shellfish such as shrimp and crab, insects such as beetles and crickets, squid cartilage, mushrooms, fungal cell walls, etc., with hydrochloric acid or an enzyme (eg, An oligosaccharide that can be obtained by partial hydrolysis, purification, and isolation using chitonase or the like. Chitosan oligosaccharide generally refers to an oligosaccharide that can be obtained by deacetylating chitin, followed by partial hydrolysis with hydrochloric acid or an enzyme (eg, chitonase) and the like, followed by purification and isolation. N-acetylglucosamine refers to a monosaccharide that can be obtained by partially hydrolyzing chitin or chitin oligosaccharide with hydrochloric acid or an enzyme (eg, chitonase), and the like, followed by purification and isolation.
 本発明に用いられるキトサン類縁化合物は、下記の式(II)で表される。 The chitosan-related compound used in the present invention is represented by the following formula (II).
Figure JPOXMLDOC01-appb-C000027
Figure JPOXMLDOC01-appb-C000027
 式中、Rは、NH又はNHCOCH示す。
 また、n1は、通常1~50を示し、好ましくは1~20を示し、さらに好ましくは1~15を示し、特に好ましくは1~10を示す。
In the formula, R represents NH 2 or NHCOCH 3 .
N1 is usually 1 to 50, preferably 1 to 20, more preferably 1 to 15, and particularly preferably 1 to 10.
 キトサン類縁化合物の重合度(上記の式(II)中のn1)は、サイズ排除クロマトグラフィーにより測定した分子量分布から重量平均分子量を算出し、それを式(II)で示されている単量体の分子量で割ることで求められる。 The degree of polymerization of the chitosan-related compound (n1 in the above formula (II)) is calculated by calculating the weight average molecular weight from the molecular weight distribution measured by size exclusion chromatography, which is represented by the monomer represented by the formula (II) It is calculated by dividing by the molecular weight.
 本発明に用いられるキトサン類縁化合物の1種であるキチンオリゴ糖は、下記の式(IV)で表される。 The chitin oligosaccharide which is one kind of chitosan-related compounds used in the present invention is represented by the following formula (IV).
Figure JPOXMLDOC01-appb-C000028
Figure JPOXMLDOC01-appb-C000028
 式中、n2(重合度)は、通常2~50を示し、好ましくは2~20を示し、さらに好ましくは2~15を示し、特に好ましくは2~10を示す。 In the formula, n2 (degree of polymerization) is usually 2 to 50, preferably 2 to 20, more preferably 2 to 15, and particularly preferably 2 to 10.
 本発明に用いられるキトサン類縁化合物の1種であるキトサンオリゴ糖は、下記の式(V)で表される。 The chitosan oligosaccharide that is one of the chitosan-related compounds used in the present invention is represented by the following formula (V).
Figure JPOXMLDOC01-appb-C000029
Figure JPOXMLDOC01-appb-C000029
 式中、n3(重合度)は、通常1~50を示し、好ましくは2~20を示し、さらに好ましくは2~15を示し、特に好ましくは2~10を示す。 In the formula, n3 (degree of polymerization) is usually 1 to 50, preferably 2 to 20, more preferably 2 to 15, and particularly preferably 2 to 10.
 本発明に用いられるキトサン類縁化合物の1種であるN-アセチルグルコサミンは、下記の式(VI)で表される。 N-acetylglucosamine, which is one of the chitosan-related compounds used in the present invention, is represented by the following formula (VI).
Figure JPOXMLDOC01-appb-C000030
Figure JPOXMLDOC01-appb-C000030
 キトサン類縁化合物の塩としては、例えば、有機酸との塩(例、酢酸塩、乳酸塩、クエン酸塩等)及び無機酸との塩(例、塩酸塩、硫酸塩等)等が挙げられるが、好ましくは塩酸塩である。 Examples of the salt of a chitosan-related compound include a salt with an organic acid (eg, acetate, lactate, citrate, etc.) and a salt with an inorganic acid (eg, hydrochloride, sulfate, etc.). Preferably, it is hydrochloride.
 本発明に用いられる、キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物又はその塩の製造方法は特に限定はされず、いかなる製法によって得られたものでも使用することが可能である。また、市販品を使用してもよい。 The method for producing at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof used in the present invention is not particularly limited, and any method obtained by any production method may be used. It is possible to use. Moreover, you may use a commercial item.
 本発明は、飲食品に添加される第1成分又は第2成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して、特定の範囲であることが重要である。
 塩味及び/又はうま味が増強された飲食品全体に対する、該添加される第1成分の量が、特定の範囲であることによって、本発明の塩味及び/又はうま味が増強された飲食品は、異風味が全く付与されることなく、塩味及び/又はうま味が十分に増強された好ましい品質となる。また、塩味及び/又はうま味が増強された飲食品全体に対する、該添加される第2成分の量が、特定の範囲であることによって、本発明の塩味及び/又はうま味が増強された飲食品は、塩味及び/又はうま味が十分に増強された好ましい品質となる。
 具体的には、該添加される第1成分の量は、塩味及び/又はうま味が増強された飲食品全体に対して、通常0.01重量ppm以上であり、好ましくは0.05重量ppm以上であり、より好ましくは0.1重量ppm以上である。該添加される第1成分の量が、0.01重量ppm未満であると、該添加される第1成分による塩味及び/又はうま味の増強効果が十分でない傾向がある。また、該添加される第1成分の量は、塩味及び/又はうま味が増強された飲食品全体に対して、通常8重量ppm以下であり、好ましくは6重量ppm以下であり、より好ましくは5重量ppm以下である。該添加される第1成分の量が、8重量ppmを超えると、異風味が生じ、嗜好性が低下する。
 また、該添加される第2成分の量は、塩味及び/又はうま味が増強された飲食品全体に対して、通常0.01重量ppm以上であり、好ましくは0.05重量ppm以上であり、より好ましくは0.1重量ppm以上である。該添加される第2成分の量が、0.01重量ppm未満であると、該添加される第2成分による塩味及び/又はうま味の増強効果が十分でない傾向がある。また、該添加される第2成分の量は、塩味及び/又はうま味が増強された飲食品全体に対して、通常2000重量ppm以下であり、好ましくは1000重量ppm以下であり、より好ましくは500重量ppm以下である。該添加される第2成分の量が、2000重量ppmを超えると、味の輪郭がぼやけ、塩味増強効果が発揮されなくなる。
 尚、ここで「該添加される第1成分の量」とは、塩味及び/又はうま味の増強を目的として飲食品に添加される第1成分の量を意味し、塩味及び/又はうま味の増強の対象となる飲食品に元から含まれる第1成分(キトサン若しくはグルコサミン、又はそれらの塩)の量は含まない。また「該添加される第2成分の量」とは、塩味及び/又はうま味の増強を目的として飲食品に添加される第2成分の量を意味し、塩味及び/又はうま味の増強の対象となる飲食品に元から含まれる第2成分(キトサン類縁化合物又はその塩)の量は含まない。
In the present invention, it is important that the amount of the first component or the second component added to the food or drink is in a specific range with respect to the whole food or drink with enhanced salty taste and / or umami.
When the amount of the first component added to the whole food and drink with enhanced salty taste and / or umami is within a specific range, the food and drink with enhanced salty taste and / or umami according to the present invention are different. It is a preferable quality in which the salty taste and / or umami taste is sufficiently enhanced without imparting any flavor. Moreover, the food / beverage products by which the salty taste and / or umami | taste of this invention were enhanced by the amount of this 2nd component added with respect to the whole food / beverage products with enhanced salty taste and / or umami taste being in a specific range. The salty taste and / or umami taste is sufficiently enhanced.
Specifically, the amount of the first component to be added is usually 0.01 ppm by weight or more, preferably 0.05 ppm by weight or more, based on the whole food and drink with enhanced salty taste and / or umami taste. And more preferably 0.1 ppm by weight or more. If the amount of the first component added is less than 0.01 ppm by weight, the salty and / or umami enhancing effect of the first component added tends to be insufficient. The amount of the first component added is usually 8 ppm by weight or less, preferably 6 ppm by weight or less, more preferably 5 ppm or less, based on the whole food or drink with enhanced salty taste and / or umami taste. Weight ppm or less. When the amount of the first component added exceeds 8 ppm by weight, a different flavor is produced and the palatability is lowered.
Further, the amount of the second component added is usually 0.01 ppm by weight or more, preferably 0.05 ppm by weight or more, with respect to the whole food and drink with enhanced salty taste and / or umami taste, More preferably, it is 0.1 weight ppm or more. When the amount of the added second component is less than 0.01 ppm by weight, the salty and / or umami enhancing effect of the added second component tends to be insufficient. In addition, the amount of the second component added is usually 2000 ppm by weight or less, preferably 1000 ppm by weight or less, more preferably 500 ppm or less, based on the whole food or drink with enhanced salty taste and / or umami taste. Weight ppm or less. When the amount of the second component added exceeds 2000 ppm by weight, the outline of the taste is blurred and the salty taste enhancing effect is not exhibited.
Here, “the amount of the first component added” means the amount of the first component added to the food or drink for the purpose of enhancing the salty taste and / or umami taste, and enhancing the salty taste and / or umami taste. The amount of the first component (chitosan or glucosamine, or a salt thereof) originally contained in the food or drink that is the target of the above is not included. The “amount of the second component added” means the amount of the second component added to the food or drink for the purpose of enhancing the salty taste and / or umami, The amount of the second component (chitosan analogue or salt thereof) originally contained in the resulting food or drink is not included.
 第1成分又は第2成分が添加される飲食品は、増強された塩味及び/又はうま味を所望されるものであれば特に制限されない。第1成分が添加される飲食品は、例えば、スープ、ソース、ドレッシング、マヨネーズ、ケチャップ、風味調味料、めんつゆ、しょう油、味噌、菓子・スナック類、水産加工品、畜産加工品、調理食品等が挙げられ、中でもスープ、風味調味料、めんつゆが好ましい。また、第2成分が添加される飲食品は、例えば、スープ、ソース、ドレッシング、マヨネーズ、ケチャップ、風味調味料、めんつゆ、しょう油、味噌、菓子・スナック類(例、ポテトチップス等)、水産加工品、畜産加工品、調理食品等が挙げられ、中でもスープ、風味調味料、めんつゆ、菓子・スナック類(例、ポテトチップス等)が好ましい。 The food or drink to which the first component or the second component is added is not particularly limited as long as enhanced salty taste and / or umami is desired. Foods and beverages to which the first component is added include, for example, soups, sauces, dressings, mayonnaise, ketchup, flavor seasonings, noodle soup, soy sauce, miso, confectionery and snacks, processed fishery products, processed livestock products, and cooked foods. Among them, soup, flavor seasoning, and noodle soup are preferable. The food and drink to which the second component is added are, for example, soup, sauce, dressing, mayonnaise, ketchup, flavor seasoning, noodle soup, soy sauce, miso, confectionery and snacks (eg, potato chips, etc.), processed marine products Processed livestock products, cooked foods, and the like, soups, flavor seasonings, noodle soups, confectionery and snacks (eg, potato chips) are particularly preferable.
 第1成分又は第2成分が添加される飲食品は、塩化ナトリウム濃度及び/又はうま味物質濃度が、特定の濃度である飲食品が好ましい。ここで「うま味物質」とは、喫食時にうま味を呈する物質であれば特に制限されないが、具体的には、グルタミン酸ナトリウム、アスパラギン酸ナトリウム等のアミノ酸およびその塩、5’-イノシン酸ナトリウム、5’-グアニル酸ナトリウム、5’-リボヌクレオチドナトリウム等の核酸およびその塩、コハク酸ナトリウム、クエン酸ナトリウム等の有機酸およびその塩等が挙げられ、好ましくは、グルタミン酸ナトリウムである。 The food or drink to which the first component or the second component is added is preferably a food or drink having a specific concentration of sodium chloride concentration and / or umami substance concentration. Here, the “umami substance” is not particularly limited as long as it is a substance that exhibits umami during eating. Specifically, amino acids such as sodium glutamate and sodium aspartate and salts thereof, 5′-sodium inosinate, 5 ′ -Nucleic acids such as sodium guanylate and 5'-ribonucleotide sodium and salts thereof, organic acids such as sodium succinate and sodium citrate and salts thereof, and the like, preferably sodium glutamate.
 飲食品の塩化ナトリウム濃度は、飲食品の種類等に応じて適宜設定すればよいが、通常0.1~80重量%であり、中でも、飲食品がスープである場合、好ましくは0.1~3.0重量%、より好ましくは0.3~1.5重量%であり、飲食品がソース、ドレッシング、マヨネーズ、ケチャップである場合、好ましくは0.5~10重量%、より好ましくは1.0~6.0重量%であり、飲食品が風味調味料である場合、好ましくは10~80重量%、より好ましくは20~60重量%である。 The sodium chloride concentration of the food and drink may be appropriately set according to the type of food and drink, etc., but is usually 0.1 to 80% by weight. Especially, when the food and drink is soup, preferably 0.1 to 3.0% by weight, more preferably 0.3 to 1.5% by weight. When the food or drink is a sauce, dressing, mayonnaise or ketchup, preferably 0.5 to 10% by weight, more preferably 1. When the food or drink is a flavor seasoning, it is preferably 10 to 80% by weight, more preferably 20 to 60% by weight.
 飲食品のうま味物質濃度は、飲食品の種類等に応じて適宜設定すればよいが、通常0.001~50重量%であり、中でも、飲食品がスープである場合、好ましくは0.001~50重量%、より好ましくは0.01~1重量%であり、飲食品がソース、ドレッシング、マヨネーズである場合、好ましくは0.005~10重量%、より好ましくは0.05~7重量%である。 The umami substance concentration of the food and drink may be appropriately set according to the type of food and drink, etc., but is usually 0.001 to 50% by weight. Especially, when the food and drink is soup, preferably 0.001 to 50% by weight, more preferably 0.01 to 1% by weight. When the food or drink is a sauce, dressing or mayonnaise, preferably 0.005 to 10% by weight, more preferably 0.05 to 7% by weight. is there.
 本発明の塩味及び/又はうま味が増強された飲食品の製造方法は、飲食品に第1成分又は第2成分を、特定の濃度(即ち、前掲の本発明の塩味及び/又はうま味が増強された飲食品に関して述べた、塩味及び/又はうま味が増強された飲食品全体に対する、該添加される第1成分又は第2成分の量)となるように添加する工程を含む以外は、公知の飲食品と同様の原料を用い、公知の飲食品の製造方法と同様の方法によって行うことができる。 In the method for producing a food or drink with enhanced salty taste and / or umami according to the present invention, the first component or the second component is added to the food or drink at a specific concentration (that is, the salty taste and / or umami of the present invention described above is enhanced). Other than the step of adding the amount of the first component or the second component added to the whole food or beverage with enhanced salty taste and / or umami, as described with respect to the food and beverage. Using the same raw material as the product, it can be carried out by a method similar to a known method for producing food or drink.
 飲食品に第1成分又は第2成分を添加する時期は特に制限されず、例えば、飲食品を製造する際に他の原料と併せて添加してもよいし、飲食品の製造後に添加してもよいし、飲食品の喫食直前及び/又は喫食中に添加してもよい。 The time when the first component or the second component is added to the food or drink is not particularly limited. For example, it may be added together with other raw materials when manufacturing the food or drink, or added after the production of the food or drink. Alternatively, it may be added immediately before and / or during the eating of the food or drink.
2.飲食品の塩味及び/又はうま味増強用組成物
 本発明は、飲食品の塩味及び/又はうま味増強用組成物(以下、「本発明の組成物」とも称する)も提供する。
 本発明の組成物は、キトサン、グルコサミン、若しくはそれらの塩(以下、「第1成分」とも称する)、又はキチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(以下、「第2成分」とも称する)を必須として含有する。当該第1成分又は第2成分としては、前掲の本発明の塩味及び/又はうま味が増強された飲食品において例示したものと同様のものが挙げられる。
2. Composition for enhancing salty taste and / or umami taste of food and drink The present invention also provides a composition for enhancing salty taste and / or umami taste of food and drink (hereinafter also referred to as “composition of the present invention”).
The composition of the present invention comprises at least one chitosan analog selected from chitosan, glucosamine, or a salt thereof (hereinafter also referred to as “first component”), or chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine. A compound or a salt thereof (hereinafter also referred to as “second component”) is contained as an essential component. As the said 1st component or 2nd component, the thing similar to what was illustrated in the food-drinks by which the salty taste and / or umami | taste of this invention mentioned above were reinforced is mentioned.
 本発明の組成物は、含有する第1成分又は第2成分の量が、本発明の組成物を添加されたことにより塩味及び/又はうま味が増強された飲食品全体に対して上記特定の範囲となるように、飲食品に添加するためのものであることが重要である。
 含有する第1成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して特定の範囲であることによって、本発明の組成物を添加された飲食品は、異風味が付与されることなく、塩味及び/又はうま味が十分に増強された好ましい品質となる。当該特定の範囲は、具体的には、前掲の本発明の塩味及び/又はうま味が増強された飲食品に関して述べた、塩味及び/又はうま味が増強された飲食品全体に対する、該添加される第1成分の量と同様の範囲である。
 また、含有する第2成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して特定の範囲であることによって、本発明の組成物を添加された飲食品は、塩味及び/又はうま味が十分に増強された好ましい品質となる。当該特定の範囲は、具体的には、前掲の本発明の塩味及び/又はうま味が増強された飲食品に関して述べた、塩味及び/又はうま味が増強された飲食品全体に対する、該添加される第2成分の量と同様の範囲である。
In the composition of the present invention, the amount of the first component or the second component contained is within the specific range described above with respect to the whole food and drink with enhanced salty taste and / or umami taste by adding the composition of the present invention. It is important that it is for adding to food and drink.
The food / beverage products to which the composition of the present invention is added are given a different flavor when the amount of the first component contained is within a specific range with respect to the whole food / beverage products with enhanced salty taste and / or umami taste. Without any problem, the salty taste and / or umami taste is sufficiently enhanced. The specific range specifically refers to the addition of the salt and / or umami-enhanced food / beverage product having the salty and / or umami-enhanced content of the present invention described above. The range is the same as the amount of one component.
Moreover, the amount of the 2nd component to contain is a specific range with respect to the whole food / beverage products with enhanced salty taste and / or umami taste, so that the food / beverage products to which the composition of the present invention is added have a salty taste and / or Or it becomes the preferable quality in which the umami taste was fully enhanced. The specific range specifically refers to the addition of the salt and / or umami-enhanced food / beverage product having the salty and / or umami-enhanced content of the present invention described above. The range is the same as the amount of the two components.
 本発明の組成物は、本発明の目的を損なわない限りにおいて、第1成分、第2成分以外の他の成分を含有してもよい。当該他の成分としては、例えば、賦形剤、調味剤、着色剤、香料、pH調節剤、安定化剤、防腐剤、結合剤、崩壊剤、滑沢剤、保存剤、固結防止剤、酸化防止剤、光沢剤等が挙げられる。 The composition of the present invention may contain components other than the first component and the second component as long as the object of the present invention is not impaired. Examples of the other components include excipients, seasonings, colorants, fragrances, pH adjusters, stabilizers, preservatives, binders, disintegrants, lubricants, preservatives, anti-caking agents, An antioxidant, a brightener, etc. are mentioned.
 本発明の組成物の形態は、特に制限されないが、例えば、固体状(粉末状、顆粒状等を含む)、液体状(スラリー状等を含む)、ゲル状、ペースト状等が挙げられる。 The form of the composition of the present invention is not particularly limited, and examples thereof include solid (including powder, granule and the like), liquid (including slurry and the like), gel, and paste.
 本発明の組成物の製造方法は特に制限されず、例えば、第1成分又は第2成分に、所望により他の成分を加え、ミキサー等を用いて混合する方法等が挙げられる。 The method for producing the composition of the present invention is not particularly limited, and examples thereof include a method in which other components are added to the first component or the second component as desired and mixed using a mixer or the like.
 本発明の組成物を添加し得る飲食品は、塩味及び/又はうま味を有するものであれば特に制限されず、前掲の本発明の塩味及び/又はうま味が増強された飲食品に関して例示したものと同様のものが挙げられる。
 また、本発明の組成物を添加する飲食品に添加する時期も特に制限されず、前掲の本発明の塩味及び/又はうま味が増強された飲食品に関して例示したように添加できる。
The food and drink to which the composition of the present invention can be added is not particularly limited as long as it has a salty taste and / or umami, and is exemplified with respect to the food and drink with the enhanced salty taste and / or umami of the present invention described above. The same thing is mentioned.
Moreover, the time to add to the food / beverage products to which the composition of the present invention is added is not particularly limited, and can be added as exemplified above for the food / beverage products with enhanced salty taste and / or umami taste of the present invention.
 本発明の組成物には、飲食品に対する適切な添加量を記載した説明書を添付することができる。また、適切な添加量の計量が容易になるように、例えば、簡便な計量容器を添付してもよいし、又は、予め一定量を小分けしてもよい。 The composition of the present invention can be accompanied by instructions describing the appropriate amount added to food and drink. Further, for example, a simple measuring container may be attached or a certain amount may be subdivided in advance so that the appropriate addition amount can be easily measured.
3.飲食品の塩味及び/又はうま味増強方法
 本発明は、飲食品の塩味及び/又はうま味増強方法(以下、「本発明の塩味及び/又はうま味増強方法」とも称する)も提供する。
 本発明の塩味及び/又はうま味増強方法は、飲食品に、キトサン、グルコサミン、若しくはそれらの塩(以下、「第1成分」とも称する)、又はキチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(以下、「第2成分」とも称する)を添加する工程を含む。当該第1成分又は第2成分としては、前掲の本発明の塩味及び/又はうま味が増強された飲食品に関して例示したものと同様のものが挙げられる。
3. Method for enhancing salty taste and / or umami taste of food and drink The present invention also provides a method for enhancing salty taste and / or umami taste of food and drink (hereinafter also referred to as “the salty taste and / or umami taste enhancing method of the present invention”).
The method for enhancing salty taste and / or umami taste of the present invention comprises, as food and drink, chitosan, glucosamine, or a salt thereof (hereinafter also referred to as “first component”), chitin oligosaccharide, chitosan oligosaccharide, or N-acetylglucosamine. Adding at least one selected chitosan-related compound or a salt thereof (hereinafter also referred to as “second component”). As said 1st component or 2nd component, the thing similar to what was illustrated regarding the food-drinks by which the salty taste and / or umami | taste of this invention which were mentioned above was reinforced is mentioned.
 本発明の塩味及び/又はうま味増強方法は、飲食品に添加される第1成分又は第2成分の量が、本発明の塩味及び/又はうま味増強方法によって塩味及び/又はうま味が増強された飲食品全体に対して、特定の範囲であることが重要である。
 該添加される第1成分の量は、具体的には、前掲の本発明の塩味及び/又はうま味が増強された飲食品に関して述べた、塩味及び/又はうま味が増強された飲食品全体に対する、該添加される第1成分の量と同様の範囲である。
 また、該添加される第2成分の量は、具体的には、前掲の本発明の塩味及び/又はうま味が増強された飲食品に関して述べた、塩味及び/又はうま味が増強された飲食品全体に対する、該添加される第2成分の量と同様の範囲である。
The salty taste and / or umami enhancing method of the present invention is such that the amount of the first component or the second component added to the food or drink is enhanced by the salty taste and / or umami enhancing method of the present invention. It is important to have a specific range for the entire product.
The amount of the first component to be added is specifically the total amount of the salty and / or umami-enhanced foods and beverages described above for the salty and / or umami-enhanced foods and beverages of the present invention. The range is the same as the amount of the first component added.
In addition, the amount of the second component to be added is specifically the whole food and drink with enhanced salty taste and / or umami described above for the food and drink with enhanced salty taste and / or umami of the present invention. The same range as the amount of the second component to be added.
 本発明の塩味及び/又はうま味増強方法を適用し得る飲食品は、塩味及び/又はうま味を有するものであれば特に制限されず、前掲の本発明の塩味及び/又はうま味が増強された飲食品に関して例示したものと同様のものが挙げられる。
 また、飲食品に、第1成分又は第2成分を添加する時期も特に制限されず、前掲の本発明の塩味及び/又はうま味が増強された飲食品に関して例示したように添加できる。
The food and drink to which the salty taste and / or umami enhancing method of the present invention can be applied is not particularly limited as long as it has a salty taste and / or umami, and the food and drink with enhanced salty taste and / or umami of the present invention described above. The thing similar to what was illustrated about is mentioned.
In addition, the timing at which the first component or the second component is added to the food or drink is not particularly limited, and can be added as exemplified above for the food and drink with enhanced salty taste and / or umami of the present invention.
 以下の実施例において本発明を更に具体的に説明するが、本発明はこれらの例によってなんら限定されるものではない。 The present invention will be described more specifically in the following examples, but the present invention is not limited to these examples.
 以下の実施例において用いたキトサン及びグルコサミンを下記に示す。
 キトサン:焼津水産工業社製、商品名「キトサンLL-40」、重合度=625(平均値)
 重合度の高いキトサン:甲陽ケミカル社製、商品名「コーヨーキトサンFH-80」、重合度=6250~25000(規格値)、13500(平均値)
 グルコサミン:焼津水産工業社製、商品名「ナチュラルグルコサミン」
The chitosan and glucosamine used in the following examples are shown below.
Chitosan: manufactured by Yaizu Suisan Kogyo Co., Ltd., trade name “Chitosan LL-40”, degree of polymerization = 625 (average value)
Chitosan having a high degree of polymerization: manufactured by Koyo Chemical Co., Ltd., trade name “Koyo Chitosan FH-80”, degree of polymerization = 6250-25000 (standard value), 13500 (average value)
Glucosamine: Yaizu Suisan Kogyo Co., Ltd., trade name “Natural Glucosamine”
 また、以下の実施例において用いたキチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンを下記に示す。
 キチンオリゴ糖:甲陽ケミカル社製、商品名「オリゴ-N-アセチルグルコサミン」、重合度=2~8
 キトサンオリゴ糖:甲陽ケミカル社製、商品名「コーヨーオリゴ-N-グルコサミン」、重合度=2~8
 N-アセチルグルコサミン:甲陽ケミカル社製、商品名「コーヨーN-アセチルグルコサミン」
In addition, chitin oligosaccharide, chitosan oligosaccharide and N-acetylglucosamine used in the following examples are shown below.
Chitin oligosaccharide: manufactured by Koyo Chemical Co., Ltd., trade name “Oligo-N-acetylglucosamine”, degree of polymerization = 2-8
Chitosan oligosaccharide: Koyo Chemical Co., Ltd., trade name “Kyoyo Oligo-N-Glucosamine”, Degree of polymerization = 2-8
N-acetylglucosamine: manufactured by Koyo Chemical Co., Ltd., trade name “Koyo N-acetylglucosamine”
 (実施例1:キトサンによる塩味増強効果の評価)
[実施例1-1~1-6、比較例1-1~1-4の調製]
 0.88重量%塩化ナトリウム水溶液をポジティブコントロールとし、0.8重量%塩化ナトリウム水溶液をネガティブコントロールとして用いた。0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)にキトサンを添加して、実施例1-1~1-6、比較例1-1~1-4の水溶液をそれぞれ調製した。添加したキトサンの量は、調製した実施例及び比較例の各水溶液全体に対して、表1に示す濃度となる量とした。尚、キトサンを溶解させるため、キトサンの5倍量のリンゴ酸も、キトサンと併せて添加した。
(Example 1: Evaluation of salty taste enhancement effect by chitosan)
[Preparation of Examples 1-1 to 1-6 and Comparative Examples 1-1 to 1-4]
A 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control. Chitosan was added to a 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 1-1 to 1-6 and Comparative Examples 1-1 to 1-4, respectively. The amount of chitosan added was such that the concentration shown in Table 1 was obtained with respect to the entire aqueous solutions of the prepared examples and comparative examples. In addition, in order to dissolve chitosan, 5 times the amount of malic acid of chitosan was also added together with chitosan.
[官能評価]
 得られた各実施例及び比較例の塩味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 ここで「評点法」とは、「おいしさを測る-食品官能検査の実際-」(古川秀子著、幸書房、1994年)p29~49に記載の方法をいう。
 「塩味の強さ」は、塩味が0.88重量%塩化ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、塩味が0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表1に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialist panels based on the scoring method for the salty strength, the different flavor strength and the overall usefulness of each of the Examples and Comparative Examples obtained.
Here, the “scoring method” refers to the method described in “Measurement of deliciousness—actuality of food sensory test” (Hideko Furukawa, Kobo, 1994) p29-49.
“Strength of saltiness” is 10 points with saltiness enhanced to 0.88% by weight sodium chloride aqueous solution (positive control), and the salty taste is completely different from 0.8% by weight sodium chloride aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Table 1.
Figure JPOXMLDOC01-appb-T000031
Figure JPOXMLDOC01-appb-T000031
 表1に示す結果から明らかな通り、添加されるキトサンの量が、調製した水溶液全体に対して、0.01~5重量ppmであるとき、全く異風味が付与されることなく、塩味が増強された。また、添加されるキトサンの量が、調製した水溶液全体に対して、0.5~5重量ppmであるとき、非常に有用な効果があった。 As is apparent from the results shown in Table 1, when the amount of chitosan added is 0.01 to 5 ppm by weight with respect to the total amount of the prepared aqueous solution, the salty taste is enhanced without any unusual flavor being imparted. It was done. Further, when the amount of chitosan added was 0.5 to 5 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect.
 (実施例2:キトサンによるうま味増強効果の評価)
[実施例2-1~2-6、比較例2-1~2-4の調製]
 0.24重量%グルタミン酸ナトリウム水溶液をポジティブコントロールとし、0.2重量%グルタミン酸ナトリウム水溶液をネガティブコントロールとして用いた。0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)にキトサンを添加して、実施例2-1~2-6、比較例2-1~2-4の水溶液をそれぞれ調製した。添加したキトサンの量は、調製した実施例及び比較例の各水溶液全体に対して、表2に示す濃度となる量とした。尚、キトサンを溶解させるため、キトサンの5倍量のリンゴ酸も、キトサンと併せて添加した。
(Example 2: Evaluation of umami enhancement effect by chitosan)
[Preparation of Examples 2-1 to 2-6 and Comparative Examples 2-1 to 2-4]
A 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control. Chitosan was added to a 0.2 wt% sodium glutamate aqueous solution (negative control) to prepare aqueous solutions of Examples 2-1 to 2-6 and Comparative Examples 2-1 to 2-4, respectively. The amount of chitosan added was such that the concentration shown in Table 2 was obtained with respect to the entire aqueous solutions of the prepared examples and comparative examples. In addition, in order to dissolve chitosan, 5 times the amount of malic acid of chitosan was also added together with chitosan.
[官能評価]
 得られた各実施例及び比較例のうま味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「うま味の強さ」は、うま味が0.24重量%グルタミン酸ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、うま味が0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表2に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialized panels based on the scoring method for the strength of umami, the strength of different flavors, and the overall usefulness of each Example and Comparative Example obtained.
“Umami strength” is 10 points with umami enhanced by 0.24 wt% sodium glutamate aqueous solution (positive control), and umami completely changed from 0.2 wt% sodium glutamate aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Table 2.
Figure JPOXMLDOC01-appb-T000032
Figure JPOXMLDOC01-appb-T000032
 表2に示す結果から明らかな通り、添加されるキトサンの量が、調製した水溶液全体に対して、0.01~5重量ppmであるとき、全く異風味が付与されることなく、うま味が増強された。また、添加されるキトサンの量が、調製した水溶液全体に対して、0.5~5重量ppmであるとき、非常に有用な効果があった。 As is apparent from the results shown in Table 2, when the amount of chitosan added is 0.01 to 5 ppm by weight based on the total amount of the prepared aqueous solution, the umami taste is enhanced without any unusual flavor being imparted. It was done. Further, when the amount of chitosan added was 0.5 to 5 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect.
 (実施例3:重合度が高いキトサンによる塩味増強効果の評価)
[実施例3-1及び3-2の調製]
 0.88重量%塩化ナトリウム水溶液をポジティブコントロールとし、0.8重量%塩化ナトリウム水溶液をネガティブコントロールとして用いた。0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)に重合度が高いキトサンを添加して、実施例3-1及び3-2の水溶液をそれぞれ調製した。添加した重合度が高いキトサンの量は、調製した実施例の各水溶液全体に対して、表3に示す濃度となる量とした。尚、重合度が高いキトサンを溶解させるため、重合度が高いキトサンの5倍量のリンゴ酸も、重合度が高いキトサンと併せて添加した。
(Example 3: Evaluation of salty taste enhancement effect by chitosan having a high degree of polymerization)
[Preparation of Examples 3-1 and 3-2]
A 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control. Chitosan having a high degree of polymerization was added to 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 3-1 and 3-2, respectively. The amount of chitosan having a high degree of polymerization was set to an amount that gives the concentration shown in Table 3 with respect to the entire aqueous solutions of the prepared examples. In addition, in order to dissolve chitosan with a high degree of polymerization, malic acid in an amount 5 times that of chitosan with a high degree of polymerization was also added together with chitosan with a high degree of polymerization.
[官能評価]
 得られた各実施例の塩味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「塩味の強さ」は、塩味が0.88重量%塩化ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、塩味が0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表3に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialist panels based on the scoring method for the salty strength, the strength of different flavors, and the overall usefulness of each Example obtained.
“Strength of saltiness” is 10 points with saltiness enhanced to 0.88% by weight sodium chloride aqueous solution (positive control), and the salty taste is completely different from 0.8% by weight sodium chloride aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Table 3.
Figure JPOXMLDOC01-appb-T000033
Figure JPOXMLDOC01-appb-T000033
 表3に示す結果から明らかな通り、添加される重合度が高いキトサンの量が、調製した水溶液全体に対して、0.01~1重量ppmであるとき、全く異風味が付与されることなく、塩味が増強された。また、添加される重合度が高いキトサンの量が、調製した水溶液全体に対して、1重量ppmであるとき、非常に有用な効果があった。この結果から、本発明の塩味増強効果は重合度によらず、発揮されることが分かった。 As is apparent from the results shown in Table 3, when the amount of chitosan having a high degree of polymerization added is 0.01 to 1 ppm by weight with respect to the total amount of the prepared aqueous solution, no different flavor is imparted. The salty taste was enhanced. Further, when the amount of chitosan having a high degree of polymerization added was 1 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect. From this result, it was found that the salty taste enhancing effect of the present invention is exhibited regardless of the degree of polymerization.
 (実施例4:重合度が高いキトサンによるうま味増強効果の評価)
[実施例4-1及び4-2の調製]
 0.24重量%グルタミン酸ナトリウム水溶液をポジティブコントロールとし、0.2重量%グルタミン酸ナトリウム水溶液をネガティブコントロールとして用いた。0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)に重合度が高いキトサンを添加して、実施例4-1及び4-2の水溶液をそれぞれ調製した。添加した重合度が高いキトサンの量は、調製した実施例の各水溶液全体に対して、表4に示す濃度となる量とした。尚、重合度が高いキトサンを溶解させるため、重合度が高いキトサンの5倍量のリンゴ酸も、重合度が高いキトサンと併せて添加した。
(Example 4: Evaluation of umami enhancement effect by chitosan having a high degree of polymerization)
[Preparation of Examples 4-1 and 4-2]
A 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control. Chitosan having a high degree of polymerization was added to a 0.2 wt% sodium glutamate aqueous solution (negative control) to prepare aqueous solutions of Examples 4-1 and 4-2, respectively. The amount of chitosan having a high degree of polymerization was set to an amount that gives the concentration shown in Table 4 with respect to the entire aqueous solutions of the prepared examples. In addition, in order to dissolve chitosan with a high degree of polymerization, malic acid in an amount 5 times that of chitosan with a high degree of polymerization was also added together with chitosan with a high degree of polymerization.
[官能評価]
 得られた各実施例のうま味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「うま味の強さ」は、うま味が0.24重量%グルタミン酸ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、うま味が0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表4に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialist panels based on the scoring method for the strength of umami, the strength of different flavors, and the overall usefulness of each Example obtained.
“Umami strength” is 10 points with umami enhanced by 0.24 wt% sodium glutamate aqueous solution (positive control), and umami completely changed from 0.2 wt% sodium glutamate aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Table 4.
Figure JPOXMLDOC01-appb-T000034
Figure JPOXMLDOC01-appb-T000034
 表4に示す結果から明らかな通り、添加される重合度が高いキトサンの量が、調製した水溶液全体に対して、0.01~1重量ppmであるとき、全く異風味が付与されることなく、うま味が増強された。また、添加される重合度が高いキトサンの量が、調製した水溶液全体に対して、1重量ppmであるとき、非常に有用な効果があった。この結果から、本発明のうま味増強効果は重合度によらず、発揮されることが分かった。 As is apparent from the results shown in Table 4, when the amount of chitosan having a high degree of polymerization added is 0.01 to 1 ppm by weight with respect to the whole prepared aqueous solution, no unusual flavor is imparted. The umami was enhanced. Further, when the amount of chitosan having a high degree of polymerization added was 1 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect. From this result, it was found that the umami enhancing effect of the present invention is exhibited regardless of the degree of polymerization.
 (実施例5:グルコサミンによる塩味増強効果の評価)
[実施例5-1~5-6、比較例5-1~5-4の調製]
 0.88重量%塩化ナトリウム水溶液をポジティブコントロールとし、0.8重量%塩化ナトリウム水溶液をネガティブコントロールとして用いた。0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)にグルコサミンを添加して、実施例5-1~5-6、比較例5-1~5-4の水溶液をそれぞれ調製した。添加したグルコサミンの量は、調製した実施例及び比較例の各水溶液全体に対して、表5に示す濃度となる量とした。
(Example 5: Evaluation of salty taste enhancing effect by glucosamine)
[Preparation of Examples 5-1 to 5-6 and Comparative Examples 5-1 to 5-4]
A 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control. Glucosamine was added to 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 5-1 to 5-6 and Comparative examples 5-1 to 5-4, respectively. The amount of the added glucosamine was set to an amount having a concentration shown in Table 5 with respect to each of the prepared aqueous solutions of Examples and Comparative Examples.
[官能評価]
 得られた各実施例及び比較例の塩味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「塩味の強さ」は、塩味が0.88重量%塩化ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、塩味が0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表5に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialist panels based on the scoring method for the salty strength, the different flavor strength and the overall usefulness of each of the Examples and Comparative Examples obtained.
“Strength of saltiness” is 10 points with saltiness enhanced to 0.88% by weight sodium chloride aqueous solution (positive control), and the salty taste is completely different from 0.8% by weight sodium chloride aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Table 5.
Figure JPOXMLDOC01-appb-T000035
Figure JPOXMLDOC01-appb-T000035
 表5に示す結果から明らかな通り、添加されるグルコサミンの量が、調製した水溶液全体に対して、0.01~5重量ppmであるとき、全く異風味が付与されることなく、塩味が増強された。また、添加されるグルコサミンの量が、調製した水溶液全体に対して、0.5~5重量ppmであるとき、非常に有用な効果があった。 As is apparent from the results shown in Table 5, when the amount of glucosamine added is 0.01 to 5 ppm by weight with respect to the total amount of the prepared aqueous solution, the salty taste is enhanced without any unusual flavor. It was done. Further, when the amount of glucosamine added was 0.5 to 5 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect.
 (実施例6:グルコサミンによるうま味増強効果の評価)
[実施例6-1~6-6、比較例6-1~6-4の調製]
 0.24重量%グルタミン酸ナトリウム水溶液をポジティブコントロールとし、0.2重量%グルタミン酸ナトリウム水溶液をネガティブコントロールとして用いた。0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)にグルコサミンを添加して、実施例6-1~6-6、比較例6-1~6-4の水溶液をそれぞれ調製した。添加したグルコサミンの量は、調製した実施例及び比較例の各水溶液全体に対して、表6に示す濃度となる量とした。
(Example 6: Evaluation of umami enhancing effect by glucosamine)
[Preparation of Examples 6-1 to 6-6 and Comparative Examples 6-1 to 6-4]
A 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control. Glucosamine was added to a 0.2 wt% aqueous sodium glutamate solution (negative control) to prepare aqueous solutions of Examples 6-1 to 6-6 and Comparative Examples 6-1 to 6-4, respectively. The amount of glucosamine added was set to an amount that gives the concentration shown in Table 6 with respect to the entire aqueous solutions of the prepared Examples and Comparative Examples.
[官能評価]
 得られた各実施例及び比較例のうま味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「うま味の強さ」は、うま味が0.24重量%グルタミン酸ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、うま味が0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表6に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialized panels based on the scoring method for the strength of umami, the strength of different flavors, and the overall usefulness of each Example and Comparative Example obtained.
“Umami strength” is 10 points with umami enhanced by 0.24 wt% sodium glutamate aqueous solution (positive control), and umami completely changed from 0.2 wt% sodium glutamate aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Table 6.
Figure JPOXMLDOC01-appb-T000036
Figure JPOXMLDOC01-appb-T000036
 表6に示す結果から明らかな通り、添加されるグルコサミンの量が、調製した水溶液全体に対して、0.01~5重量ppmであるとき、全く異風味が付与されることなく、うま味が増強された。また、添加されるグルコサミンの量が、調製した水溶液全体に対して、1~5重量ppmであるとき、非常に有用な効果があった。 As is apparent from the results shown in Table 6, when the amount of added glucosamine is 0.01 to 5 ppm by weight with respect to the total amount of the prepared aqueous solution, umami is enhanced without any unusual flavor being imparted. It was done. Further, when the amount of glucosamine added was 1 to 5 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect.
 表1~6の結果から、キトサン及びグルコサミンは全く異風味を生じることなく塩味及び/又はうま味を増強する効果を有することが確認され、特に、添加されるキトサン又はグルコサミンの量が、塩味及び/又はうま味が増強された飲食品全体に対して0.01~5重量ppmの範囲であるとき、全く異風味を付与することなく、塩味及び/又はうま味を十分に増強するという効果を発揮することが確認された。
 また、重合度が高いキトサンについても、異風味を付与することなく、塩味及び/又はうま味を十分に増強するという効果を発揮することが確認された。
From the results of Tables 1 to 6, it was confirmed that chitosan and glucosamine have an effect of enhancing salty taste and / or umami taste without causing any unusual flavor, and in particular, the amount of chitosan or glucosamine added is different from the salty taste and / or savory taste. Or, when it is in the range of 0.01 to 5 ppm by weight with respect to the whole food and drink with enhanced umami, it exhibits the effect of sufficiently enhancing salty taste and / or umami without imparting a different flavor at all. Was confirmed.
Moreover, it was confirmed that chitosan having a high degree of polymerization exhibits the effect of sufficiently enhancing the salty taste and / or umami taste without imparting a different flavor.
 (実施例7:飲食品に対するキトサンの効果の評価)
[ネガティブコントロール及びポジティブコントロールの調製]
 市販のめんつゆ(ヤマキ社製)、昆布ポン酢(ミツカン社製)を8倍に希釈したものを、それぞれネガティブコントロールとした。
 調製した各ネガティブコントロール100mlに塩化ナトリウム0.1gを添加したものを、ポジティブコントロールとした。
(Example 7: Evaluation of the effect of chitosan on food and drink)
[Preparation of negative control and positive control]
A commercially available noodle soup (manufactured by Yamaki Co., Ltd.) and kelp ponzu (manufactured by Mitsukan Co., Ltd.) diluted 8-fold were used as negative controls.
A positive control was prepared by adding 0.1 g of sodium chloride to 100 ml of each prepared negative control.
[実施例7-1及び7-2の調製]
 調製したネガティブコントロールに、キトサンを添加して実施例7-1及び7-2の飲食品を調製した。添加したキトサンの量は、調製した実施例の飲食品全体に対して1重量ppmとなる量とした。尚、キトサンを溶解させるため、キトサンの5倍量のリンゴ酸も、キトサンと併せて添加した。
[Preparation of Examples 7-1 and 7-2]
Chitosan was added to the prepared negative control to prepare food and drink products of Examples 7-1 and 7-2. The amount of chitosan added was 1 ppm by weight with respect to the whole food and drink of the prepared examples. In addition, in order to dissolve chitosan, 5 times the amount of malic acid of chitosan was also added together with chitosan.
[官能評価]
 得られた各実施例の塩味の強さ、うま味の強さ、呈味の好ましさ、異風味の強さ及び総合的な有用性について、3名の専門パネルにより評点法に準拠して官能評価を行った。
 「塩味の強さ」は、塩味がポジティブコントロールと同等に増強されたものを10点とし、塩味がネガティブコントロールから全く変化しなかったものを0点として評価した。
 「うま味の強さ」は、うま味がとても強まったものを10点とし、うま味がネガティブコントロールから全く変化しなかったものを0点として評価した。
 「呈味の好ましさ」は、ポジティブコントロールと同等に向上したものを10点とし、ネガティブコントロールから全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表7に示す。
[sensory evaluation]
In each of the examples, the salty strength, umami strength, taste preference, strength of different flavors, and overall usefulness were sensory based on a rating method by three specialist panels. Evaluation was performed.
“Saltiness” was evaluated as 10 points when the saltiness was enhanced equivalently to the positive control, and 0 points when the saltiness did not change at all from the negative control.
“Umami strength” was evaluated as 10 points when the umami was very strong, and 0 points when the umami did not change at all from the negative control.
The “preference for taste” was evaluated as 10 points that were improved as much as the positive control, and 0 points that did not change at all from the negative control.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Table 7.
Figure JPOXMLDOC01-appb-T000037
Figure JPOXMLDOC01-appb-T000037
 表7の結果から明らかなように、キトサンの添加によって、めんつゆ(8倍希釈)、昆布ポン酢のどちらにおいても塩味の強さ、呈味の好ましさが向上した。また、うま味の強さも向上した。従って、キトサンの塩味増強効果及びうま味増強効果は、実際の飲食品に対しても発揮されることが確認された。 As is apparent from the results in Table 7, the addition of chitosan improved the salty strength and taste preference in both noodle soup (diluted 8 times) and kelp ponzu. In addition, the strength of umami was improved. Therefore, it was confirmed that the salty taste enhancing effect and umami enhancing effect of chitosan are also exerted on actual food and drink.
 (実施例8:飲食品に対するグルコサミンの効果の評価)
[ネガティブコントロール及びポジティブコントロールの調製]
 市販の中華スープ(味の素社製)、コーンスープ(味の素社製)、コンソメスープ(味の素社製)に1.25倍希釈となるようにお湯を加えた(通常は160ml/食でお湯を注いで調製する商品に対し、200ml/食でお湯を注いだ)後、ネットで具材を濾したものを、それぞれネガティブコントロールとした。
 調製した各ネガティブコントロールに塩化ナトリウムを添加して、それぞれの塩化ナトリウム濃度を、通常の調製方法に従って調製した場合と同等の濃度(160ml/食でお湯を注いで通常調製する商品に対し、160ml/食でお湯を注いで調製したときの濃度)に調整し、ポジティブコントロールとした。
(Example 8: Evaluation of the effect of glucosamine on food and drink)
[Preparation of negative control and positive control]
Hot water was added to commercially available Chinese soup (manufactured by Ajinomoto Co., Inc.), corn soup (manufactured by Ajinomoto Co., Inc.), and consomme soup (manufactured by Ajinomoto Co., Inc.) to a dilution of 1.25 times. A product prepared by pouring hot water with 200 ml / meal) and then filtering the ingredients with a net was used as a negative control.
Sodium chloride is added to each of the prepared negative controls, and the concentration of each sodium chloride is the same as that prepared according to the normal preparation method (160 ml / 160 ml / day for products normally prepared by pouring hot water with food). The concentration was adjusted to that obtained by pouring hot water with food, and used as a positive control.
[実施例8-1~8-3の調製]
 調製したネガティブコントロールに、グルコサミンを添加して実施例8-1~8-3のスープを調製した。添加したグルコサミンの量は、調製した実施例のスープ全体に対して1重量ppmとなる量とした。
[Preparation of Examples 8-1 to 8-3]
Glucosamine was added to the prepared negative control to prepare soups of Examples 8-1 to 8-3. The amount of glucosamine added was 1 ppm by weight with respect to the whole soup of the prepared example.
[官能評価]
 得られた各実施例の塩味の強さ、うま味の強さ、スープとしての好ましさ、異風味の強さ及び総合的な有用性について、3名の専門パネルにより官能評価を行った。
 「塩味の強さ」は、塩味がポジティブコントロールと同等に増強されたものを10点とし、塩味がネガティブコントロールから全く変化しなかったものを0点として評価した。
 「うま味の強さ」は、うま味がとても強まったものを10点とし、うま味がネガティブコントロールから全く変化しなかったものを0点として評価した。
 「スープとしての好ましさ」は、ポジティブコントロールと同等に向上したものを10点とし、ネガティブコントロールから全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表8に示す。
[sensory evaluation]
The sensory evaluation was performed by three specialist panels on the salty strength, umami strength, preference as a soup, strength of different flavors, and overall usefulness of each Example obtained.
“Saltiness” was evaluated as 10 points when the saltiness was enhanced equivalently to the positive control, and 0 points when the saltiness did not change at all from the negative control.
“Umami strength” was evaluated as 10 points when the umami was very strong, and 0 points when the umami did not change at all from the negative control.
The “preference for soup” was evaluated as 10 points that were improved as much as the positive control, and 0 points that did not change at all from the negative control.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Table 8.
Figure JPOXMLDOC01-appb-T000038
Figure JPOXMLDOC01-appb-T000038
 表8の結果から明らかなように、グルコサミンの添加によって、中華スープ、コーンスープ、コンソメスープの全てにおける減塩時の塩味の強さ、スープとしての好ましさが向上した。また、うま味の強さも向上した。従って、グルコサミンの塩味増強効果及びうま味増強効果は、実際の飲食品に対しても発揮されることが確認された。 As is apparent from the results in Table 8, the addition of glucosamine improved the salty strength during salt reduction and the preference for soup in all Chinese soups, corn soups, and consomme soups. In addition, the strength of umami was improved. Therefore, it was confirmed that the salty taste enhancing effect and umami enhancing effect of glucosamine are also exerted on actual food and drink.
 (実施例9:キチンオリゴ糖による塩味増強効果の評価)
[実施例9-1~9-12、比較例9-1及び9-2の調製]
 0.88重量%塩化ナトリウム水溶液をポジティブコントロールとし、0.8重量%塩化ナトリウム水溶液をネガティブコントロールとして用いた。0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)にキチンオリゴ糖を添加して、実施例9-1~9-12、比較例9-1及び9-2の水溶液をそれぞれ調製した。添加したキチンオリゴ糖の量は、調製した実施例及び比較例の各水溶液全体に対して、表9-1及び9-2に示す濃度となる量とした。
(Example 9: Evaluation of salty taste enhancing effect by chitin oligosaccharide)
[Preparation of Examples 9-1 to 9-12 and Comparative Examples 9-1 and 9-2]
A 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control. Chitin oligosaccharides were added to a 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 9-1 to 9-12 and Comparative Examples 9-1 and 9-2, respectively. The amount of the chitin oligosaccharide added was such that the concentration shown in Tables 9-1 and 9-2 was obtained with respect to the entire aqueous solutions prepared in Examples and Comparative Examples.
[官能評価]
 得られた各実施例及び比較例の塩味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「塩味の強さ」は、塩味が0.88重量%塩化ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、塩味が0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表9-1及び9-2に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialist panels based on the scoring method for the salty strength, the different flavor strength and the overall usefulness of each of the Examples and Comparative Examples obtained.
“Strength of saltiness” is 10 points with saltiness enhanced to 0.88% by weight sodium chloride aqueous solution (positive control), and the salty taste is completely different from 0.8% by weight sodium chloride aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Tables 9-1 and 9-2.
Figure JPOXMLDOC01-appb-T000039
Figure JPOXMLDOC01-appb-T000039
Figure JPOXMLDOC01-appb-T000040
Figure JPOXMLDOC01-appb-T000040
 表9-1及び9-2に示す結果から明らかな通り、添加されるキチンオリゴ糖の量が、調製した水溶液全体に対して0.01~2000重量ppmであるとき、塩味が増強され、中でも、添加されるキチンオリゴ糖の量が、調製した水溶液全体に対して0.01~10重量ppmであるとき、異風味が付与されることなく塩味が増強された。また、添加されるキチンオリゴ糖の量が、調製した水溶液全体に対して、0.5~10重量ppmであるとき、非常に有用な効果があった。 As is apparent from the results shown in Tables 9-1 and 9-2, when the amount of chitin oligosaccharide added is 0.01 to 2000 ppm by weight with respect to the total amount of the prepared aqueous solution, the salty taste is enhanced. When the amount of chitin oligosaccharide added was 0.01 to 10 ppm by weight with respect to the whole prepared aqueous solution, the salty taste was enhanced without imparting a different flavor. Further, when the amount of chitin oligosaccharide added was 0.5 to 10 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect.
 (実施例10:キチンオリゴ糖によるうま味増強効果の評価)
[実施例10-1~10-12、比較例10-1及び10-2の調製]
 0.24重量%グルタミン酸ナトリウム水溶液をポジティブコントロールとし、0.2重量%グルタミン酸ナトリウム水溶液をネガティブコントロールとして用いた。0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)にキチンオリゴ糖を添加して、実施例10-1~10-12、比較例10-1及び10-2の水溶液をそれぞれ調製した。添加したキチンオリゴ糖の量は、調製した実施例及び比較例の各水溶液全体に対して、表10-1及び10-2に示す濃度となる量とした。
(Example 10: Evaluation of umami enhancing effect by chitin oligosaccharide)
[Preparation of Examples 10-1 to 10-12 and Comparative Examples 10-1 and 10-2]
A 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control. Chitin oligosaccharides were added to a 0.2 wt% sodium glutamate aqueous solution (negative control) to prepare aqueous solutions of Examples 10-1 to 10-12 and Comparative Examples 10-1 and 10-2, respectively. The amount of chitin oligosaccharide added was such that the concentrations shown in Tables 10-1 and 10-2 were obtained with respect to the whole aqueous solutions of the prepared examples and comparative examples.
[官能評価]
 得られた各実施例及び比較例のうま味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「うま味の強さ」は、うま味が0.24重量%グルタミン酸ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、うま味が0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表10-1及び10-2に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialized panels based on the scoring method for the strength of umami, the strength of different flavors, and the overall usefulness of each Example and Comparative Example obtained.
“Umami strength” is 10 points with umami enhanced by 0.24 wt% sodium glutamate aqueous solution (positive control), and umami completely changed from 0.2 wt% sodium glutamate aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Tables 10-1 and 10-2.
Figure JPOXMLDOC01-appb-T000041
Figure JPOXMLDOC01-appb-T000041
Figure JPOXMLDOC01-appb-T000042
Figure JPOXMLDOC01-appb-T000042
 表10-1及び10-2に示す結果から明らかな通り、添加されるキチンオリゴ糖の量が、調製した水溶液全体に対して0.01~2000重量ppmであるとき、うま味が増強され、中でも、添加されるキチンオリゴ糖の量が、調製した水溶液全体に対して0.01~10重量ppmであるとき、異風味が付与されることなくうま味が増強された。また、添加されるキチンオリゴ糖の量が、調製した水溶液全体に対して、1~10重量ppmであるとき、非常に有用な効果があった。 As is apparent from the results shown in Tables 10-1 and 10-2, when the amount of chitin oligosaccharide added is 0.01 to 2000 ppm by weight with respect to the total amount of the prepared aqueous solution, umami is enhanced. When the amount of chitin oligosaccharide added was 0.01 to 10 ppm by weight with respect to the entire prepared aqueous solution, the umami taste was enhanced without imparting a different flavor. Further, when the amount of chitin oligosaccharide added was 1 to 10 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect.
 (実施例11:キトサンオリゴ糖による塩味増強効果の評価)
[実施例11-1~11-12、比較例11-1及び11-2の調製]
 0.88重量%塩化ナトリウム水溶液をポジティブコントロールとし、0.8重量%塩化ナトリウム水溶液をネガティブコントロールとして用いた。0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)にキトサンオリゴ糖を添加して、実施例11-1~11-12、比較例11-1及び11-2の水溶液をそれぞれ調製した。添加したキトサンオリゴ糖の量は、調製した実施例及び比較例の各水溶液全体に対して、表11-1及び11-2に示す濃度となる量とした。
(Example 11: Evaluation of salty taste enhancing effect by chitosan oligosaccharide)
[Preparation of Examples 11-1 to 11-12 and Comparative Examples 11-1 and 11-2]
A 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control. Chitosan oligosaccharide was added to 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 11-1 to 11-12 and Comparative Examples 11-1 and 11-2, respectively. The amount of chitosan oligosaccharide added was such that the concentration shown in Tables 11-1 and 11-2 was obtained for each of the prepared aqueous solutions of Examples and Comparative Examples.
[官能評価]
 得られた各実施例及び比較例の塩味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「塩味の強さ」は、塩味が0.88重量%塩化ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、塩味が0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表11-1及び11-2に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialist panels based on the scoring method for the salty strength, the different flavor strength and the overall usefulness of each of the Examples and Comparative Examples obtained.
“Strength of saltiness” is 10 points with saltiness enhanced to 0.88% by weight sodium chloride aqueous solution (positive control), and the salty taste is completely different from 0.8% by weight sodium chloride aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Tables 11-1 and 11-2.
Figure JPOXMLDOC01-appb-T000043
Figure JPOXMLDOC01-appb-T000043
Figure JPOXMLDOC01-appb-T000044
Figure JPOXMLDOC01-appb-T000044
 表11-1及び11-2に示す結果から明らかな通り、添加されるキトサンオリゴ糖の量が、調製した水溶液全体に対して0.01~2000重量ppmであるとき、塩味が増強され、中でも、添加されるキトサンオリゴ糖の量が、調製した水溶液全体に対して0.01~10重量ppmであるとき、異風味が付与されることなく塩味が増強された。また、添加されるキトサンオリゴ糖の量が、調製した水溶液全体に対して、0.1~10重量ppmであるとき、非常に有用な効果があった。 As is apparent from the results shown in Tables 11-1 and 11-2, when the amount of chitosan oligosaccharide added is 0.01 to 2000 ppm by weight with respect to the total amount of the prepared aqueous solution, the salty taste is enhanced. When the amount of chitosan oligosaccharide added was 0.01 to 10 ppm by weight with respect to the whole prepared aqueous solution, the salty taste was enhanced without imparting a different flavor. Further, when the amount of chitosan oligosaccharide added was 0.1 to 10 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect.
 (実施例12:キトサンオリゴ糖によるうま味増強効果の評価)
[実施例12-1~12-12、比較例12-1及12-2の調製]
 0.24重量%グルタミン酸ナトリウム水溶液をポジティブコントロールとし、0.2重量%グルタミン酸ナトリウム水溶液をネガティブコントロールとして用いた。0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)にキトサンオリゴ糖を添加して、実施例12-1~12-12、比較例12-1及び12-2の水溶液をそれぞれ調製した。添加したキトサンオリゴ糖の量は、調製した実施例及び比較例の各水溶液全体に対して、表12-1及び12-2に示す濃度となる量とした。
(Example 12: Evaluation of umami enhancing effect by chitosan oligosaccharide)
[Preparation of Examples 12-1 to 12-12 and Comparative Examples 12-1 and 12-2]
A 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control. Chitosan oligosaccharides were added to 0.2 wt% sodium glutamate aqueous solution (negative control) to prepare aqueous solutions of Examples 12-1 to 12-12 and Comparative Examples 12-1 and 12-2, respectively. The amount of chitosan oligosaccharide added was such that the concentration shown in Tables 12-1 and 12-2 was obtained for each of the prepared aqueous solutions of Examples and Comparative Examples.
[官能評価]
 得られた各実施例及び比較例のうま味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「うま味の強さ」は、うま味が0.24重量%グルタミン酸ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、うま味が0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表12-1及び12-2に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialized panels based on the scoring method for the strength of umami, the strength of different flavors, and the overall usefulness of each Example and Comparative Example obtained.
“Umami strength” is 10 points with umami enhanced by 0.24 wt% sodium glutamate aqueous solution (positive control), and umami completely changed from 0.2 wt% sodium glutamate aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Tables 12-1 and 12-2.
Figure JPOXMLDOC01-appb-T000045
Figure JPOXMLDOC01-appb-T000045
Figure JPOXMLDOC01-appb-T000046
Figure JPOXMLDOC01-appb-T000046
 表12-1及び12-2に示す結果から明らかな通り、添加されるキトサンオリゴ糖の量が、調製した水溶液全体に対して0.01~2000重量ppmであるとき、うま味が増強され、中でも、添加されるキトサンオリゴ糖の量が、調製した水溶液全体に対して0.01~50重量ppmであるとき、異風味が付与されることなくうま味が増強された。また、添加されるキトサンオリゴ糖の量が、調製した水溶液全体に対して、1~100重量ppmであるとき、非常に有用な効果があった。 As is apparent from the results shown in Tables 12-1 and 12-2, when the amount of chitosan oligosaccharide added is 0.01 to 2000 ppm by weight with respect to the total amount of the prepared aqueous solution, umami taste is enhanced. When the amount of chitosan oligosaccharide added was 0.01 to 50 ppm by weight with respect to the whole prepared aqueous solution, the umami taste was enhanced without imparting a different flavor. Further, when the amount of chitosan oligosaccharide added was 1 to 100 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect.
 (実施例13:N-アセチルグルコサミンによる塩味増強効果の評価)
[実施例13-1~13-12、比較例13-1及び13-2の調製]
 0.88重量%塩化ナトリウム水溶液をポジティブコントロールとし、0.8重量%塩化ナトリウム水溶液をネガティブコントロールとして用いた。0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)にN-アセチルグルコサミンを添加して、実施例13-1~13-12、比較例13-1及び13-2の水溶液をそれぞれ調製した。添加したN-アセチルグルコサミンの量は、調製した実施例及び比較例の各水溶液全体に対して、表13-1及び13-2に示す濃度となる量とした。
(Example 13: Evaluation of salty taste enhancing effect by N-acetylglucosamine)
[Preparation of Examples 13-1 to 13-12 and Comparative Examples 13-1 and 13-2]
A 0.88 wt% sodium chloride aqueous solution was used as a positive control, and a 0.8 wt% sodium chloride aqueous solution was used as a negative control. N-acetylglucosamine was added to a 0.8 wt% sodium chloride aqueous solution (negative control) to prepare aqueous solutions of Examples 13-1 to 13-12 and Comparative Examples 13-1 and 13-2, respectively. The amount of N-acetylglucosamine added was such that the concentration shown in Tables 13-1 and 13-2 was obtained for each of the prepared aqueous solutions of Examples and Comparative Examples.
[官能評価]
 得られた各実施例及び比較例の塩味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「塩味の強さ」は、塩味が0.88重量%塩化ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、塩味が0.8重量%塩化ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表13-1及び13-2に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialist panels based on the scoring method with respect to the salty strength, the strength of different flavors, and the overall usefulness of each Example and Comparative Example obtained.
“Strength of salty taste” is 10 points where the salty taste is enhanced by 0.88% by weight sodium chloride aqueous solution (positive control), and the salty taste is completely different from 0.8% by weight sodium chloride aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but that feels different flavors outside the allowable range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Tables 13-1 and 13-2.
Figure JPOXMLDOC01-appb-T000047
Figure JPOXMLDOC01-appb-T000047
Figure JPOXMLDOC01-appb-T000048
Figure JPOXMLDOC01-appb-T000048
 表13-1及び13-2に示す結果から明らかな通り、添加されるN-アセチルグルコサミンの量が、調製した水溶液全体に対して0.01~2000重量ppmであるとき、塩味が増強され、中でも、添加されるN-アセチルグルコサミンの量が、調製した水溶液全体に対して0.01~50重量ppmであるとき、異風味が付与されることなく塩味が増強された。また、添加されるN-アセチルグルコサミンの量が、調製した水溶液全体に対して、0.5~10重量ppmであるとき、非常に有用な効果があった。 As is apparent from the results shown in Tables 13-1 and 13-2, when the amount of N-acetylglucosamine added is 0.01 to 2000 ppm by weight with respect to the total amount of the prepared aqueous solution, the saltiness is enhanced, In particular, when the amount of N-acetylglucosamine added was 0.01 to 50 ppm by weight with respect to the whole prepared aqueous solution, the salty taste was enhanced without imparting a different flavor. Further, when the amount of N-acetylglucosamine added was 0.5 to 10 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect.
 (実施例14:N-アセチルグルコサミンによるうま味増強効果の評価)
[実施例14-1~14-12、比較例14-1及び14-2の調製]
 0.24重量%グルタミン酸ナトリウム水溶液をポジティブコントロールとし、0.2重量%グルタミン酸ナトリウム水溶液をネガティブコントロールとして用いた。0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)にN-アセチルグルコサミンを添加して、実施例14-1~14-12、比較例14-1及び14-2の水溶液をそれぞれ調製した。添加したN-アセチルグルコサミンの量は、調製した実施例及び比較例の各水溶液全体に対して、表14-1及び14-2に示す濃度となる量とした。
(Example 14: Evaluation of umami enhancing effect by N-acetylglucosamine)
[Preparation of Examples 14-1 to 14-12 and Comparative Examples 14-1 and 14-2]
A 0.24 wt% sodium glutamate aqueous solution was used as a positive control, and a 0.2 wt% sodium glutamate aqueous solution was used as a negative control. N-acetylglucosamine was added to a 0.2 wt% sodium glutamate aqueous solution (negative control) to prepare aqueous solutions of Examples 14-1 to 14-12 and Comparative Examples 14-1 and 14-2, respectively. The amount of N-acetylglucosamine added was such that the concentrations shown in Tables 14-1 and 14-2 were obtained for each of the prepared aqueous solutions of Examples and Comparative Examples.
[官能評価]
 得られた各実施例及び比較例のうま味の強さ、異風味の強さ及び総合的な有用性について、2名の専門パネルにより評点法に準拠して官能評価を行った。
 「うま味の強さ」は、うま味が0.24重量%グルタミン酸ナトリウム水溶液(ポジティブコントロール)相当に増強されたものを10点とし、うま味が0.2重量%グルタミン酸ナトリウム水溶液(ネガティブコントロール)から全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表14-1及び14-2に示す。
[sensory evaluation]
The sensory evaluation was performed by two specialized panels based on the scoring method for the strength of umami, the strength of different flavors, and the overall usefulness of each Example and Comparative Example obtained.
“Umami strength” is 10 points with umami enhanced by 0.24 wt% sodium glutamate aqueous solution (positive control), and umami completely changed from 0.2 wt% sodium glutamate aqueous solution (negative control) What was not done was evaluated as 0 points.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Tables 14-1 and 14-2.
Figure JPOXMLDOC01-appb-T000049
Figure JPOXMLDOC01-appb-T000049
Figure JPOXMLDOC01-appb-T000050
Figure JPOXMLDOC01-appb-T000050
 表14-1及び14-2に示す結果から明らかな通り、添加されるN-アセチルグルコサミンの量が、調製した水溶液全体に対して0.01~2000重量ppmであるとき、うま味が増強され、中でも、添加されるN-アセチルグルコサミンの量が、調製した水溶液全体に対して0.01~50重量ppmであるとき、異風味が付与されることなくうま味が増強された。また、添加されるN-アセチルグルコサミンの量が、調製した水溶液全体に対して、1~10重量ppmであるとき、非常に有用な効果があった。 As is apparent from the results shown in Tables 14-1 and 14-2, when the amount of N-acetylglucosamine added is 0.01 to 2000 ppm by weight with respect to the total amount of the prepared aqueous solution, umami is enhanced, In particular, when the amount of N-acetylglucosamine added was 0.01 to 50 ppm by weight with respect to the total amount of the prepared aqueous solution, the umami taste was enhanced without imparting a different flavor. Further, when the amount of N-acetylglucosamine added was 1 to 10 ppm by weight with respect to the whole prepared aqueous solution, there was a very useful effect.
 表9-1~14-2の結果から、キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物又はその塩は、塩味及び/又はうま味を増強する効果を有することが確認された。また、添加されるキトサン類縁化合物又はその塩の量が、塩味及び/又はうま味が増強された飲食品全体に対して0.01~2000重量ppmの範囲であるとき、塩味及び/又はうま味を増強するという効果を発揮することが確認された。 From the results shown in Tables 9-1 to 14-2, at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof has an effect of enhancing salty taste and / or umami taste. It was confirmed to have. Further, when the amount of the chitosan-related compound or salt thereof added is in the range of 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami, the salty taste and / or umami is enhanced. It was confirmed that the effect of
 (実施例15:液体食品に対するキトサンオリゴ糖の効果の評価)
[ネガティブコントロール及びポジティブコントロールの調製]
 市販の卵スープ(味の素社製)、中華スープ(味の素社製)、ほうれん草スープ(味の素社製)、もずくスープ(味の素社製)、コーンスープ(味の素社製)、ポタージュスープ(味の素社製)、コンソメスープ(味の素社製)、チキンコンソメスープ(味の素社製)、丸鶏がらスープ(味の素社製)に1.25倍希釈となるようにお湯を加えた(通常は160ml/食でお湯を注いで調製する商品に対し、200ml/食でお湯を注いだ)後、ネットで具材を濾したものを、それぞれネガティブコントロールとした。
 調製した各ネガティブコントロールに塩化ナトリウムを添加して、それぞれの塩化ナトリウム濃度を、通常の調製方法に従って調製した場合と同等の濃度(160ml/食でお湯を注いで通常調製する商品に対し、160ml/食でお湯を注いで調製したときの濃度)に調整し、ポジティブコントロールとした。
(Example 15: Evaluation of effect of chitosan oligosaccharide on liquid food)
[Preparation of negative control and positive control]
Commercial egg soup (Ajinomoto Co.), Chinese soup (Ajinomoto Co.), spinach soup (Ajinomoto Co.), Mozuku soup (Ajinomoto Co.), corn soup (Ajinomoto Co.), Potage soup (Ajinomoto Co.), Hot water was added to Consomme Soup (Ajinomoto Co., Inc.), Chicken Consomme Soup (Ajinomoto Co., Inc.), and Maru Chicken Gara Soup (Ajinomoto Co., Inc.) so that it would be diluted 1.25 times (usually 160ml / pour hot water with food) After adding hot water at 200 ml / meal to the product prepared in step 1), the ingredients filtered through a net were used as negative controls.
Sodium chloride is added to each of the prepared negative controls, and the concentration of each sodium chloride is the same as that prepared according to the normal preparation method (160 ml / 160 ml / day for products normally prepared by pouring hot water with food). The concentration was adjusted to that obtained by pouring hot water with food, and used as a positive control.
[実施例15-1~15-9の調製]
 調製したネガティブコントロールに、キトサンオリゴ糖を添加して実施例15-1~15-9のスープを調製した。添加したキトサンオリゴ糖の量は、調製した実施例のスープ全体に対して1重量ppmとなる量とした。
[Preparation of Examples 15-1 to 15-9]
Chitosan oligosaccharide was added to the prepared negative control to prepare soups of Examples 15-1 to 15-9. The amount of chitosan oligosaccharide added was 1 wt ppm with respect to the whole soup of the prepared example.
[官能評価]
 得られた各実施例の塩味の強さ、うま味の強さ、スープとしての好ましさ、異風味の強さ及び総合的な有用性について、3名の専門パネルにより官能評価を行った。
 「塩味の強さ」は、塩味がポジティブコントロールと同等に増強されたものを10点とし、塩味がネガティブコントロールから全く変化しなかったものを0点として評価した。
 「うま味の強さ」は、うま味がとても強まったものを10点とし、うま味がネガティブコントロールから全く変化しなかったものを0点として評価した。
 「スープとしての好ましさ」は、ポジティブコントロールと同等に向上したものを10点とし、ネガティブコントロールから全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表15-1~15-3に示す。
[sensory evaluation]
The sensory evaluation was performed by three specialist panels on the salty strength, umami strength, preference as a soup, strength of different flavors, and overall usefulness of each Example obtained.
“Saltiness” was evaluated as 10 points when the saltiness was enhanced equivalently to the positive control, and 0 points when the saltiness did not change at all from the negative control.
“Umami strength” was evaluated as 10 points when the umami was very strong, and 0 points when the umami did not change at all from the negative control.
The “preference for soup” was evaluated as 10 points that were improved as much as the positive control, and 0 points that did not change at all from the negative control.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Tables 15-1 to 15-3.
Figure JPOXMLDOC01-appb-T000051
Figure JPOXMLDOC01-appb-T000051
Figure JPOXMLDOC01-appb-T000052
Figure JPOXMLDOC01-appb-T000052
Figure JPOXMLDOC01-appb-T000053
Figure JPOXMLDOC01-appb-T000053
 表15-1~15-3の結果から明らかなように、キトサンオリゴ糖の添加によって、卵スープ、中華スープ、ほうれん草スープ、もずくスープ、コーンスープ、ポタージュスープ、コンソメスープ、チキンコンソメスープ、丸鶏がらスープの全てにおける減塩時の塩味の強さ、スープとしての好ましさが向上した。また、うま味の強さも向上した。従って、キトサンオリゴ糖の塩味増強効果及びうま味増強効果は、実際の液体食品に対しても発揮されることが確認された。 As is clear from the results in Tables 15-1 to 15-3, egg soup, Chinese soup, spinach soup, mozuku soup, corn soup, potage soup, consommé soup, chicken consommé soup, and whole chicken by adding chitosan oligosaccharide The strength of saltiness when reducing salt in all of the soups and the preference for soups improved. In addition, the strength of umami was improved. Therefore, it was confirmed that the salty taste enhancing effect and the umami enhancing effect of chitosan oligosaccharide are also exerted on an actual liquid food.
 (実施例16:液体食品に対するキチンオリゴ糖の効果の評価)
[ネガティブコントロール及びポジティブコントロールの調製]
 市販の中華スープ(味の素社製)、コーンスープ(味の素社製)に1.25倍希釈となるようにお湯を加えた(通常は160ml/食でお湯を注いで調製する商品に対し、200ml/食でお湯を注いだ)後、ネットで具材を濾したものを、それぞれネガティブコントロールとした。
 調製した各ネガティブコントロールに塩化ナトリウムを添加して、それぞれの塩化ナトリウム濃度を、通常の調製方法に従って調製した場合と同等の濃度(160ml/食でお湯を注いで通常調製する商品に対し、160ml/食でお湯を注いで調製したときの濃度)に調整し、ポジティブコントロールとした。
(Example 16: Evaluation of effect of chitin oligosaccharide on liquid food)
[Preparation of negative control and positive control]
Hot water was added to commercially available Chinese soup (manufactured by Ajinomoto Co., Inc.) and corn soup (manufactured by Ajinomoto Co., Inc.) to a dilution of 1.25 times (normally 160 ml / 200 ml / for products prepared by pouring hot water with food) After pouring hot water with food), the ingredients filtered through a net were used as negative controls.
Sodium chloride is added to each of the prepared negative controls, and the concentration of each sodium chloride is the same as that prepared according to the normal preparation method (160 ml / 160 ml / day for products normally prepared by pouring hot water with food). The concentration was adjusted to that obtained by pouring hot water with food, and used as a positive control.
[実施例16-1~16-4の調製]
 調製したネガティブコントロールに、キチンオリゴ糖又はN-アセチルグルコサミンを添加して実施例16-1~16-4のスープを調製した。添加したキチンオリゴ糖及びN-アセチルグルコサミンの量は、調製した実施例のスープ全体に対して1重量ppmとなる量とした。
[Preparation of Examples 16-1 to 16-4]
Chitin oligosaccharide or N-acetylglucosamine was added to the prepared negative control to prepare soups of Examples 16-1 to 16-4. The amount of chitin oligosaccharide and N-acetylglucosamine added was 1 ppm by weight with respect to the whole soup of the prepared example.
[官能評価]
 得られた各実施例の塩味の強さ、うま味の強さ、スープとしての好ましさ、異風味の強さ及び総合的な有用性について、3名の専門パネルにより官能評価を行った。
 「塩味の強さ」は、塩味がポジティブコントロールと同等に増強されたものを10点とし、塩味がネガティブコントロールから全く変化しなかったものを0点として評価した。
 「うま味の強さ」は、うま味がとても強まったものを10点とし、うま味がネガティブコントロールから全く変化しなかったものを0点として評価した。
 「スープとしての好ましさ」は、ポジティブコントロールと同等に向上したものを10点とし、ネガティブコントロールから全く変化しなかったものを0点として評価した。
 「異風味の強さ」は、異風味を強く感じるものを10点とし、強くはないが、許容範囲外の異風味を感じるものを5点とし、異風味が全くないものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表16に示す。
[sensory evaluation]
The sensory evaluation was performed by three specialist panels on the salty strength, umami strength, preference as a soup, strength of different flavors, and overall usefulness of each Example obtained.
“Saltiness” was evaluated as 10 points when the saltiness was enhanced equivalently to the positive control, and 0 points when the saltiness did not change at all from the negative control.
“Umami strength” was evaluated as 10 points when the umami was very strong, and 0 points when the umami did not change at all from the negative control.
The “preference for soup” was evaluated as 10 points that were improved as much as the positive control, and 0 points that did not change at all from the negative control.
“Strength of different flavor” is rated as 10 points for those that feel strongly different flavors, 5 points for those that are not strong, but 5 points for those that feel outside the permissible range, and 0 points for those that do not have a different flavor at all did.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Table 16.
Figure JPOXMLDOC01-appb-T000054
Figure JPOXMLDOC01-appb-T000054
 表16の結果から明らかなように、キチンオリゴ糖又はN-アセチルグルコサミンの添加によって、中華スープ及びコーンスープにおける減塩時の塩味の強さ、スープとしての好ましさが向上した。また、うま味の強さも向上した。従って、キチンオリゴ糖及びN-アセチルグルコサミンの塩味増強効果及びうま味増強効果は、実際の液体食品に対しても発揮されることが確認された。 As is clear from the results in Table 16, the addition of chitin oligosaccharide or N-acetylglucosamine improved the strength of saltiness during salt reduction and the preference for soup in Chinese soup and corn soup. In addition, the strength of umami was improved. Therefore, it was confirmed that the salty taste enhancing effect and umami enhancing effect of chitin oligosaccharide and N-acetylglucosamine are also exerted on the actual liquid food.
 (実施例17:固形食品に対するキトサンオリゴ糖の効果の評価)
[ネガティブコントロール及びポジティブコントロールの調製]
 市販のポテトチップス(ヤマザキナビスコ社製)に、表17に示す配合のチップスまぶし粉をまぶしたものを、ネガティブコントロールとした。チップスまぶし粉は、ポテトチップス9gに対して1gまぶした。
 また、調製したネガティブコントロールのポテトチップス10gに対し、1gの塩化ナトリウムを添加したものを、ポジティブコントロールとした。
 ネガティブコントロールのポテトチップスの塩化ナトリウム濃度は0.6重量%であり、ポジティブコントロールのポテトチップスの塩化ナトリウム濃度は1.6重量%である。従って、ネガティブコントロールのポテトチップスは、ポジティブコントロールのポテトチップスの62.5%減塩品である。
(Example 17: Evaluation of effect of chitosan oligosaccharide on solid food)
[Preparation of negative control and positive control]
A commercially available potato chip (manufactured by Yamazaki Nabisco Co., Ltd.) coated with a chip dust powder having the composition shown in Table 17 was used as a negative control. 1 g of the chips dust powder was applied to 9 g of potato chips.
Moreover, what added 1 g of sodium chloride with respect to 10 g of prepared negative control potato chips was made into positive control.
The sodium chloride concentration of the negative control potato chips is 0.6% by weight, and the sodium chloride concentration of the positive control potato chips is 1.6% by weight. Therefore, the negative control potato chips are 62.5% salt-reduced product of the positive control potato chips.
Figure JPOXMLDOC01-appb-T000055
Figure JPOXMLDOC01-appb-T000055
[実施例17-1~17-4の調製]
 調製したネガティブコントロールのポテトチップスに、キトサンオリゴ糖を添加して実施例17-1~17-4のポテトチップスを調製した。添加したキトサンオリゴ糖の量は、調製した実施例のポテトチップス全体に対して、表18に示す濃度となる量とした。キトサンオリゴ糖は、デキストリンで倍散して添加した。
[Preparation of Examples 17-1 to 17-4]
Chitosan oligosaccharide was added to the prepared negative control potato chips to prepare the potato chips of Examples 17-1 to 17-4. The amount of chitosan oligosaccharide added was such that the concentration is as shown in Table 18 with respect to the whole prepared potato chips of Example. Chitosan oligosaccharide was added by trituration with dextrin.
[官能評価]
 得られた各実施例の塩味の強さ、うま味の強さ、全体的な味の強さ、味の好ましさ及び総合的な有用性について、3名の専門パネルにより官能評価を行った。
 「塩味の強さ」は、塩味がポジティブコントロールと同等に増強されたものを10点とし、塩味がネガティブコントロールから全く変化しなかったものを0点として評価した。
 「うま味の強さ」は、うま味がとても強まったものを10点とし、うま味がネガティブコントロールから全く変化しなかったものを0点として評価した。
 「全体的な味の強さ」は、ポジティブコントロールと同等に向上したものを10点とし、ネガティブコントロールから全く変化しなかったものを0点として評価した。
 「味の好ましさ」は、ポジティブコントロールと同等に向上したものを10点とし、ネガティブコントロールから全く変化しなかったものを0点として評価した。
 「総合的な有用性」は、非常に有用な効果があるものを◎とし、有用な効果があるものを○とし、効果がないものを×として評価した。
 結果を表18に示す。
[sensory evaluation]
The sensory evaluation was performed by three specialized panels on the salty strength, umami strength, overall taste strength, taste preference, and overall usefulness of each of the Examples obtained.
“Saltiness” was evaluated as 10 points when the saltiness was enhanced equivalently to the positive control, and 0 points when the saltiness did not change at all from the negative control.
“Umami strength” was evaluated as 10 points when the umami was very strong, and 0 points when the umami did not change at all from the negative control.
“Overall taste intensity” was evaluated as 10 points that were improved as much as the positive control, and 0 points that did not change at all from the negative control.
The “preference for taste” was evaluated with 10 points that were improved to the same level as the positive control, and 0 points that did not change at all from the negative control.
“Comprehensive usability” was evaluated as “A” for a very useful effect, “A” for a useful effect, and “No” for an ineffective effect.
The results are shown in Table 18.
Figure JPOXMLDOC01-appb-T000056
Figure JPOXMLDOC01-appb-T000056
 表18の結果から明らかなように、キトサンオリゴ糖の添加によって、ポテトチップスにおける塩味の強さ、全体的な味の強さ、味の好ましさが向上した。また、うま味の強さも向上した。従って、キトサンオリゴ糖の塩味増強効果及びうま味増強効果は、固形食品に対しても発揮されることが確認された。 As is clear from the results in Table 18, the addition of chitosan oligosaccharide improved the salty strength, overall taste strength, and taste preference of potato chips. In addition, the strength of umami was improved. Therefore, it was confirmed that the salty taste enhancing effect and umami enhancing effect of chitosan oligosaccharide are also exerted on solid foods.
 本発明によれば、異風味が付与されることない塩味及び/又はうま味が十分に増強された飲食品及びその製造方法を提供し得る。
 また本発明によれば、異風味を付与することなく、飲食品の塩味及び/又はうま味を十分に増強することが出来る、飲食品の塩味及び/又はうま味増強用組成物、並びに、飲食品の塩味及び/又はうま味増強方法を提供し得る。
 また本発明によれば、塩味及び/又はうま味が増強された飲食品並びにその製造方法を提供し得る。
 また本発明によれば、飲食品の塩味及び/又はうま味を増強することが出来る、飲食品の塩味及び/又はうま味増強用組成物、並びに、飲食品の塩味及び/又はうま味増強方法を提供し得る。
ADVANTAGE OF THE INVENTION According to this invention, the food / beverage products and its manufacturing method by which the salty taste and / or umami | taste which are not provided with different flavor were fully strengthened can be provided.
According to the present invention, the salty and / or umami-enhancing composition for food and drink, which can sufficiently enhance the salty and / or umami taste of the food and drink without imparting a different flavor, and the food and drink A salty and / or umami enhancing method may be provided.
Moreover, according to this invention, the food-drinks with enhanced salty taste and / or umami taste, and its manufacturing method can be provided.
Moreover, according to the present invention, there is provided a salty and / or umami enhancing composition for enhancing the salty taste and / or umami of a food and drink, and a method for enhancing the salty and / or umami taste of a food and drink. obtain.
 本出願は、日本で出願された特願2012-229272(出願日:2012年10月16日)及び特願2012-229273(出願日:2012年10月16日)を基礎としており、それらの内容は本明細書に全て包含されるものである。 This application is based on Japanese Patent Application No. 2012-229272 (filing date: October 16, 2012) and Japanese Patent Application No. 2012-229273 (filing date: October 16, 2012) filed in Japan. Are all encompassed herein.

Claims (16)

  1.  キトサン、グルコサミン、若しくはそれらの塩(第1成分)、又は
     キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(第2成分)
    を飲食品に添加する工程を含む、塩味及び/又はうま味が増強された飲食品の製造方法であって、
     第1成分を添加する場合、該添加される第1成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmであり、
     第2成分を添加する場合、該添加される第2成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmである方法。
    Chitosan, glucosamine, or a salt thereof (first component), or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (second component)
    A method for producing a food or drink with enhanced salty taste and / or umami,
    When the first component is added, the amount of the first component added is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste,
    A method in which when the second component is added, the amount of the second component added is 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste.
  2.  キトサンが、式(I)で表される化合物である、請求項1記載の方法。
    Figure JPOXMLDOC01-appb-C000001
    (式中、nは、51~25,000を示す。)
    The method according to claim 1, wherein the chitosan is a compound represented by the formula (I).
    Figure JPOXMLDOC01-appb-C000001
    (In the formula, n represents 51 to 25,000.)
  3.  キトサン類縁化合物が、式(II)で表される、請求項1記載の方法。
    Figure JPOXMLDOC01-appb-C000002
    (式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
    The method according to claim 1, wherein the chitosan-related compound is represented by the formula (II).
    Figure JPOXMLDOC01-appb-C000002
    (In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
  4.  キトサン若しくはグルコサミンの塩、又はキトサン類縁化合物の塩が、塩酸塩である、請求項1~3のいずれか1項に記載の方法。 The method according to any one of claims 1 to 3, wherein the salt of chitosan or glucosamine or the salt of a chitosan-related compound is a hydrochloride.
  5.  キトサン、グルコサミン、若しくはそれらの塩(第1成分)、又は
     キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(第2成分)
    を飲食品に添加する工程を含む、飲食品の塩味及び/又はうま味増強方法であって、
     第1成分を添加する場合、該添加される第1成分の量が、上記方法によって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmであり、
     第2成分を添加する場合、該添加される第2成分の量が、上記方法によって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmである方法。
    Chitosan, glucosamine, or a salt thereof (first component), or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (second component)
    A method for enhancing the salty and / or umami taste of food and drink,
    When the first component is added, the amount of the first component added is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by the above method,
    A method in which when the second component is added, the amount of the added second component is 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by the above method.
  6.  キトサンが、式(I)で表される化合物である、請求項5記載の方法。
    Figure JPOXMLDOC01-appb-C000003
    (式中、nは、51~25,000を示す。)
    The method according to claim 5, wherein the chitosan is a compound represented by the formula (I).
    Figure JPOXMLDOC01-appb-C000003
    (In the formula, n represents 51 to 25,000.)
  7.  キトサン類縁化合物が、式(II)で表される、請求項5記載の方法。
    Figure JPOXMLDOC01-appb-C000004
    (式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
    The method according to claim 5, wherein the chitosan-related compound is represented by the formula (II).
    Figure JPOXMLDOC01-appb-C000004
    (In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
  8.  キトサン若しくはグルコサミンの塩、又はキトサン類縁化合物の塩が、塩酸塩である、請求項5~7のいずれか1項に記載の方法。 The method according to any one of claims 5 to 7, wherein the salt of chitosan or glucosamine or the salt of a chitosan-related compound is a hydrochloride.
  9.  キトサン、グルコサミン、若しくはそれらの塩(第1成分)、又は
     キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(第2成分)
    を飲食品に添加してなる、塩味及び/又はうま味が増強された飲食品であって、
     第1成分を添加する場合、該添加される第1成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmであり、
     第2成分を添加する場合、該添加される第2成分の量が、塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmである飲食品。
    Chitosan, glucosamine, or a salt thereof (first component), or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (second component)
    Is a food and drink with enhanced salty taste and / or umami taste,
    When the first component is added, the amount of the first component added is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste,
    When the second component is added, the amount of the second component added is 0.01 to 2000 ppm by weight with respect to the whole food and beverage with enhanced salty taste and / or umami.
  10.  キトサンが、式(I)で表される化合物である、請求項9記載の飲食品。
    Figure JPOXMLDOC01-appb-C000005
    (式中、nは、51~25,000を示す。)
    The food / beverage products of Claim 9 whose chitosan is a compound represented by a formula (I).
    Figure JPOXMLDOC01-appb-C000005
    (In the formula, n represents 51 to 25,000.)
  11.  キトサン類縁化合物が、式(II)で表される、請求項9記載の飲食品。
    Figure JPOXMLDOC01-appb-C000006
    (式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
    The food or drink according to claim 9, wherein the chitosan-related compound is represented by the formula (II).
    Figure JPOXMLDOC01-appb-C000006
    (In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
  12.  キトサン若しくはグルコサミンの塩、又はキトサン類縁化合物の塩が、塩酸塩である、請求項9~11のいずれか1項に記載の飲食品。 The food or drink according to any one of claims 9 to 11, wherein the salt of chitosan or glucosamine or the salt of a chitosan-related compound is a hydrochloride.
  13.  キトサン、グルコサミン、若しくはそれらの塩(第1成分)、又は
     キチンオリゴ糖、キトサンオリゴ糖、N-アセチルグルコサミンから選択される少なくとも1種のキトサン類縁化合物若しくはその塩(第2成分)
    を含有する、飲食品の塩味及び/又はうま味増強用組成物であって、
     第1成分を含有する場合、該第1成分の量が、上記組成物を添加されたことによって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~8重量ppmとなるように、飲食品に添加するためのものであり、
     第2成分を含有する場合、該第2成分の量が、上記組成物を添加されたことによって塩味及び/又はうま味が増強された飲食品全体に対して、0.01~2000重量ppmとなるように、飲食品に添加するためのものである組成物。
    Chitosan, glucosamine, or a salt thereof (first component), or at least one chitosan-related compound selected from chitin oligosaccharide, chitosan oligosaccharide, N-acetylglucosamine or a salt thereof (second component)
    A composition for enhancing the salty and / or umami taste of food and drink,
    When the first component is contained, the amount of the first component is 0.01 to 8 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by adding the above composition. So that it is for addition to food and drink,
    When the second component is contained, the amount of the second component is 0.01 to 2000 ppm by weight with respect to the whole food and drink with enhanced salty taste and / or umami taste by adding the above composition. Thus, a composition for addition to food or drink.
  14.  キトサンが、式(I)で表される化合物である、請求項13記載の組成物。
    Figure JPOXMLDOC01-appb-C000007
    (式中、nは、51~25,000を示す。)
    The composition of Claim 13 whose chitosan is a compound represented by a formula (I).
    Figure JPOXMLDOC01-appb-C000007
    (In the formula, n represents 51 to 25,000.)
  15.  キトサン類縁化合物が、式(II)で表される、請求項13記載の組成物。
    Figure JPOXMLDOC01-appb-C000008
    (式中、Rは、NH又はNHCOCH示し、n1は、1~50を示す。)
    The composition according to claim 13, wherein the chitosan-related compound is represented by the formula (II).
    Figure JPOXMLDOC01-appb-C000008
    (In the formula, R represents NH 2 or NHCOCH 3 , and n1 represents 1 to 50.)
  16.  キトサン若しくはグルコサミンの塩、又はキトサン類縁化合物の塩が、塩酸塩である、請求項13~15のいずれか1項に記載の組成物。 The composition according to any one of claims 13 to 15, wherein the salt of chitosan or glucosamine or the salt of a chitosan-related compound is a hydrochloride.
PCT/JP2013/078089 2012-10-16 2013-10-16 Food or drink with enhanced salty taste and/or umami and manufacturing method therefor, salty taste and/or umami-enhancing composition for food or drink, and method for enhancing salty taste and/or umami of food or drink WO2014061705A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2012229272 2012-10-16
JP2012229273 2012-10-16
JP2012-229273 2012-10-16
JP2012-229272 2012-10-16

Publications (1)

Publication Number Publication Date
WO2014061705A1 true WO2014061705A1 (en) 2014-04-24

Family

ID=50488266

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2013/078089 WO2014061705A1 (en) 2012-10-16 2013-10-16 Food or drink with enhanced salty taste and/or umami and manufacturing method therefor, salty taste and/or umami-enhancing composition for food or drink, and method for enhancing salty taste and/or umami of food or drink

Country Status (2)

Country Link
TW (1) TW201438596A (en)
WO (1) WO2014061705A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018518197A (en) * 2015-05-27 2018-07-12 ドゥーマトーク リミテッド Enhanced salt composition and method for its preparation

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5344664A (en) * 1976-10-04 1978-04-21 Eisai Co Ltd Seasoning and food and drink with same
JPS61216648A (en) * 1985-03-20 1986-09-26 Lion Corp Food and drink
JPH01291799A (en) * 1988-05-20 1989-11-24 Nakano Vinegar Co Ltd Production of chitosan-oligosaccharide and use thereof
JPH02283251A (en) * 1989-04-20 1990-11-20 Nakano Vinegar Co Ltd Ingredient for 'mazegohan' and production thereof
JPH08252074A (en) * 1995-03-17 1996-10-01 Kao Corp Seasoning for meat
JP2012110263A (en) * 2010-11-24 2012-06-14 Kao Corp Acid seasoning

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5344664A (en) * 1976-10-04 1978-04-21 Eisai Co Ltd Seasoning and food and drink with same
JPS61216648A (en) * 1985-03-20 1986-09-26 Lion Corp Food and drink
JPH01291799A (en) * 1988-05-20 1989-11-24 Nakano Vinegar Co Ltd Production of chitosan-oligosaccharide and use thereof
JPH02283251A (en) * 1989-04-20 1990-11-20 Nakano Vinegar Co Ltd Ingredient for 'mazegohan' and production thereof
JPH08252074A (en) * 1995-03-17 1996-10-01 Kao Corp Seasoning for meat
JP2012110263A (en) * 2010-11-24 2012-06-14 Kao Corp Acid seasoning

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Shokuhin Shin Sozai Yuko Riyo Gijutsu Series 32 N-Acetylglucosamine Glucosamine", FOOD SCIENCE, vol. 42, no. 8, August 2000 (2000-08-01), pages 87 - 92 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018518197A (en) * 2015-05-27 2018-07-12 ドゥーマトーク リミテッド Enhanced salt composition and method for its preparation

Also Published As

Publication number Publication date
TW201438596A (en) 2014-10-16

Similar Documents

Publication Publication Date Title
KR101889113B1 (en) Method for improving salty taste of food or beverage and salty taste improving agent
JP5680815B2 (en) Method for producing potassium chloride-containing food and drink, and potassium chloride-containing food and drink obtained by the production method
JP5012024B2 (en) Seasoning composition, seasoning material, and method for producing food using the same
JP4308316B2 (en) Salty taste-enhancing method and salty taste-enhancing agent for food and drink
JP5593641B2 (en) Low salt food and beverage composition
JP5181669B2 (en) Taste improving agent
JPWO2019177003A1 (en) Salty and / or spice enhancer
US20120034368A1 (en) Method for improving salty taste of food or beverage and salty taste improving agent
JP5093101B2 (en) Method for enhancing salty taste of γ-polyglutamic acid-containing food
WO2014061705A1 (en) Food or drink with enhanced salty taste and/or umami and manufacturing method therefor, salty taste and/or umami-enhancing composition for food or drink, and method for enhancing salty taste and/or umami of food or drink
JP6314841B2 (en) Kokumi imparting agent
WO2011055846A1 (en) Liquid seasoning having improved flavor
JPWO2019039441A1 (en) Method of enhancing salty taste of liquid food
JP2015130840A (en) Powder food
JP5678281B2 (en) Liquid seasoning with enhanced umami taste of glutamic acid
JP4997365B1 (en) Saltiness enhancing method with salty taste enhancer and salt reducing method for salt-containing foods and drinks
JP2011155967A (en) Method for producing body-increasing seasoning
JP2008259440A (en) Solid seasoning composition, solid seasoning material, and method for producing food using them
AU2005318566B2 (en) Flavour enhancer
WO2015111428A1 (en) Saltiness enhancer
JP6044159B2 (en) Food and drink with enhanced saltiness and method for producing the same
WO2023190557A1 (en) Salty taste enhancer
JP2019170188A (en) Salty taste enhancing composition
JP2017176077A (en) Composition having function of imparting richness
JPH0870812A (en) New full-bodied seasoning raw material

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13847188

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 13847188

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: JP