WO2014026396A1 - 具有增效作用的杀菌组合物 - Google Patents
具有增效作用的杀菌组合物 Download PDFInfo
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- WO2014026396A1 WO2014026396A1 PCT/CN2012/080379 CN2012080379W WO2014026396A1 WO 2014026396 A1 WO2014026396 A1 WO 2014026396A1 CN 2012080379 W CN2012080379 W CN 2012080379W WO 2014026396 A1 WO2014026396 A1 WO 2014026396A1
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- WO
- WIPO (PCT)
- Prior art keywords
- thiazolone
- composition
- composition according
- active component
- epoxiconazole
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
Definitions
- the present invention is in the field of agricultural plant protection, and more particularly to a bactericidal composition having improved properties, and more particularly to a bactericidal composition contained therein.
- Benzothiazolinone is a fungicide. It is a new, broad-spectrum fungicide that has a preventive and therapeutic effect on fungal diseases. During the sterilization process, the nuclear structure of the pathogen is destroyed, causing it to lose its heart and die, causing the metabolism of the cells to interfere with the physiological disorder and eventually leading to death. Kill the germs completely and achieve the desired effect of eradicating the disease. It is mainly used to control cucumber downy mildew, pear black spot disease, apple acne, citrus anthracnose, grape black pox, etc., and has special effects on various bacterial and fungal diseases.
- Dimethomorph is a broad-spectrum bactericide of morpholine, which has a unique action on the fungi of the genus Aspergillus and the genus Phytophthora, mainly causing the decomposition of the sporangia wall, thus making the fungus# 3 ⁇ 4 dead.
- Dimethomorph is a fungicide of the genus Oomycetes, which is characterized by the destruction of the formation of HI mo, which has a role in all stages of the life history of the oocysts, and is particularly sensitive in the formation of spore vines and oospores. It is inhibited at very low concentrations ( ⁇ 0.25 g/ml) and is not resistant to phenyl hydrazine M agents.
- Dithianon is a protective fungicide for many leaf diseases of many pome fruit and stone fruit, with multiple mechanisms of action.
- a series of fungal enzymes are inhibited by reacting with sulfur-containing groups and interfering with cellular respiration, which ultimately leads to disease death. It has a good protective activity and also has a certain therapeutic activity.
- Suitable cropping fruit trees include pome fruits and fruit such as apples, pears, peaches, apricots, cherries, citrus, coffee, grapes, strawberries, hops, and the like.
- the control object can control almost all fruit tree diseases such as black spot disease, mildew disease, leaf spot disease, rust, anthracnose, scab, downy mildew, brown rot and so on.
- Iprodione is a highly effective broad-spectrum, contact-killing fungicide with a certain therapeutic and protective effect. It can also be absorbed by the roots. Can effectively prevent and treat benzopyrene-type systemic fungicides Resistant fungi. Suitable for controlling early defoliation, gray mold, early blight of various fruit trees, vegetables, melons and other crops
- Epoxiconazol is a systemic triazole fungicide. Its mechanism of action is to inhibit the synthesis of ergosterol, which hinders the formation of cell walls. It not only has good protection, treatment and eradication activity, but also has systemic and better residual active epoxiconazole, which can increase the activity of the vegetal enzyme of the crop, leading to the contraction of the fungal squirt and inhibiting the invasion of the bacteria. This is the fluorine ring. Frustrated in all three frustrations. It has good control effect on leaf spot, powdery mildew, rust, anthracnose and white rot on grapes, such as banana, onion, celery, kidney bean, melon, asparagus, peanut and sugar beet.
- the technical problem to be solved by the invention is: for the anti-f and soil residue problems of the bactericide in practical application, the bactericides of two different sterilization principles are screened to compound, so as to improve the control effect of the bactericide and delay the generation of resistance, Reduce the amount of application, control costs.
- the present invention provides a bactericidal composition
- a bactericidal composition comprising two active ingredients A and B, the active component A is thiazolone, and the active component B is selected from the group consisting of dicyandiquinone and olefin.
- One of acymorpholine, iprodione or epoxiconazole One of acymorpholine, iprodione or epoxiconazole.
- the compounds containing component A and component B have different structural types and different mechanisms of action. The combination of the two can bind to the broad spectrum of bactericidal spectrum, and can delay the generation and development of pathogenic bacteria resistance on a certain number, and the components There is no cross-resistance between A and component B.
- Another object of the present invention is to provide a preparation method comprising the two active ingredients A and B bactericidal compositions and 30 ⁇ 30: 1.
- the bactericidal composition of the present invention is composed of 6 to 92% by weight of the living component and 94 to 8% by weight of the pesticide adjuvant.
- the present invention provides a bactericidal composition
- a bactericidal composition comprising component A (thiazolone) and component B (one selected from the group consisting of dicyandione, enoylmorpholine, iprodiurea or epoxiconazole) for controlling plant diseases Use in.
- compositions further comprise a carrier, an adjuvant and/or a surfactant.
- a carrier an adjuvant and/or a surfactant.
- Common auxiliaries can be mixed during the application.
- the auxiliaries can be solid or liquid, they are usually used in the processing of dosage forms, such as natural or recycled minerals, solvents, dispersants, wetting agents, adhesives, thickeners, adhesives. .
- the applicator of the composition of the invention the brain comprises the composition of the invention for use in aerial parts of plants, in particular leaves or foliage.
- the frequency of administration and the amount administered will depend on the biological and climatic conditions of the pathogen.
- the plant growth site such as rice fields, may be wetted with a liquid formulation of the composition, or the composition may be applied to the soil in solid form, such as in the form of granules (soil application), the composition may be passed from the soil to the plant through the roots of the plant. In vivo (systemic action).
- compositions may be applied only with the active ingredient, or may be mixed with the additives, so that the composition of the present invention can be prepared into various dosage forms such as wettable powders, suspending agents, oil suspensions, water-dispersible granules, Water emulsion, microemulsion.
- the compositions may be applied by spraying, misting, dusting, spreading or splashing, and the like.
- composition of the present invention can be prepared into various dosage forms by a known method, and the active ingredient and the auxiliary agent, such as I", a solid carrier, if necessary, can be uniformly mixed with the surfactant, ground, and prepared as needed. Formulation.
- the above solvent may be selected from aromatic hydrocarbons, and the crane contains 8-12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, and aliphatic hydrocarbons.
- phthalates such as dibutyl phthalate or dicaprylic acid
- aliphatic hydrocarbons such as cyclists or paraffin, alcohols and glycols and their ethers and esters, such as ethanol, ethylene glycol, ethylene glycol monomethyl; ketones, such as cyclohexanone, strong polar solvents, such as N-methyl -2-pyrrolidone, dimethyl sulfoxide or dimethylformamidine, and vegetable or vegetable oils such as soybean oil.
- the above solid carriers are usually natural mineral fillers such as talc, kaolin. Earth, montmorillonite or activated clay.
- a highly dispersible silicic acid or a highly dispersible adsorbent polymer carrier such as a particulate adsorbent carrier or a non-adsorbing carrier.
- Suitable particulate adsorbent carriers are porous, such as pumice and bentonite.
- non-adsorbing carriers such as calcite or sand.
- a large amount of pre-granulated materials of inorganic or organic nature can be used as a carrier, in particular dolomite.
- suitable surfactants are lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, alkaline earth metal salt, salt, salt, arylsulfonate, hospital Base sulphur ship, sulphur-based sulphur ship, sulphuric acid sulphur M3 ⁇ 4, sulphuric acid and sulphated fatty alcohol glycol ether, condensate of sulfonated naphthalene and naphthalene derivatives with formaldehyde, naphthalene or naphthalene sulfonic acid Condensate with phenol and formaldehyde, polyoxyethylene octyl phenyl ether, ethoxylated isooctyl phenol, octyl phenol, nonyl phenol, aryl aryl glycol ether, tributyl glycol Et
- the two effective pours in the compositions of the present invention are synergistic, the activity of the composition is more pronounced than the expected sum of the living compounds of the shed, and the insect activity of the individual compounds.
- the synergistic effect is manifested by allowing a wider application of the fungicidal control profile, quicker effect, longer lasting control effect, comforting one or a few applications for better control of plant harmful fungi, and widening the possible application interval .
- This temple is particularly needed in the practice of plant fungus control.
- the composition of the present invention is particularly directed to the following crop diseases: yellow mold pathogen, cucumber gray mold disease, banana leaf spot disease, grape downy mildew or lychee Phytophthora.
- the other characteristics exhibited by the bactericidal composition of the present invention are mainly as follows: 1.
- the compounding of the composition of the present invention has obvious synergistic effect; 2. Since the chemical composition of the two single agents of the composition is greatly different, the effect The mechanism is completely different, there is no cross-resistance, and the problem of resistance caused by the separate use of the two single agents can be delayed; 3.
- the composition of the invention has good safety and control effect on crops. It has been verified by i that the fungicidal composition of the present invention has stable chemical properties, remarkable synergistic effect, and exhibits obvious synergistic effect and complementary effect on the control object.
- Example 1 620/0 thiaminone ⁇ dicyandiquinone dispersible granules
- Example 2 65% thiazolone - dicyandiquinone dispersible granules
- Thiazolone 63. /. enoylmorpholine 2. /. , sodium lignosulfonate 6. /. , 12 yards of base sulfonate 3 . /. , xanthan gum 1%, carboxymethyl lake f3 1%, attapulgite to 100%.
- Example 5 620/0 thiazolone ⁇ Isobacteria water dispersible granules
- Example 6 75% thiazolone ⁇ Isobacteria water dispersible granules
- Example 7 62% thiazolone ⁇ epoxiconazole water dispersible granules
- Example 8 62% thiazolone ⁇ epoxiconazole water dispersible granules
- a ratio of the active ingredient of thiazolone to one of dicyandione, dimethomorph, iprodione or epoxiconazole, and components such as dispersant, wetting agent, thickener and water After mixing evenly, after sanding and/or high-speed shearing, a semi-finished product is obtained. After analysis, water is added and uniformly filtered to obtain a finished product.
- Thiazolone 40 / 0 , enoylmorpholine 2. / 0 , the month of the fatty alcohol polyoxyethylene ether phosphate 7. / 0 , white carbon black 3. / 0 , glycerol 6. / 0 , 2% in benzamidine, 7 to 100%.
- Example 12 32% thiazolone ⁇ enoylmorpholine suspension
- Example 14 42% thiazolone ⁇ different bacteria leg float
- Example 15 55% thiazolone-epoxiconazole suspension
- Example 16 55% thiazolone ⁇ epoxiconazole suspension
- Example 17 90% thiazolone ⁇ dicyandione wettable powder
- Example 19 55% thiazolone ⁇ dicyandione wettable powder
- Example 24 50% thiazolone ⁇ iprodione wettable powder
- Example 25 85% thiazolone ⁇ iprodione wettable powder
- Example 26 88% thiazolone ⁇ epoxiconazole wettable powder
- Example 27 86% thiazolone ⁇ epoxiconazole wettable powder
- Example 28 50% thiazolone ⁇ epoxiconazole wettable powder
- One of the active ingredient, thiazolone A, and the active ingredient B dicyandione, dimethomorph, iprodione or epoxiconazole After completely dissolving in the solvent, stir, add emulsifier, synergist and antifreeze. After the above system is mixed, add water slowly to the above mixture, and mix well to prepare different A microemulsion in the amount.
- Example 29 18% thiazolone - dicyandione microemulsion
- Example 30 30% thiazolone ⁇ dicyandione microemulsion
- Example 31 15% thiazolone ⁇ enoylmorpholine microemulsion
- Example 32 15% thiazolone ⁇ enoylmorpholine microemulsion
- Example 33 18% thiazolone ⁇ Isobacteria microemulsion
- Example 34 21% thiazolone ⁇ Isobacteria microemulsion
- Tefmosone 20% Iprodione 1%, Moon fatty acid polyoxyethylene ester and phenethyl phenol polyoxyethylene ether 4%, glycerol 2%, methanol 11%, azone 1%, 7 complement to 100%.
- Example 35 12% thiazolone ⁇ Fluorine ring microemulsion
- thiazolone 10% of epoxiconazole, 1% of propylene glycol, 1% of phenylsulfonyl sulfonate, and phthalic acid, M3 ⁇ 4 13%, 1% of ethyl ketone, and 11% of ethyl acetate.
- Example 36 15% thiazolone ⁇ Fluorine ring microemulsion
- the active ingredient, thiazolone A, and one of the B active ingredients dicyandione, dimethomorph, iprodione or epoxiconazole are uniformly mixed with a solvent and an auxiliary agent under mechanical stirring, and then The emulsifier and the stabilizer are added to be evenly stirred. Finally, water is added and stirred at 100-12000 rpm for 10-30 minutes to make it a homogeneous milky product.
- Example 37 42% thiazolone ⁇ dicyandione emulsion
- Example 38 44% thiazolone ⁇ dicyandiquinone emulsion
- Example 39 22% thiazolone ⁇ enoylmorpholine emulsion
- Example 40 22% thiazolone ⁇ enoylmorpholine emulsion
- Example 41 30% thiazolone-isobacteria aqueous emulsion
- Example 42 420/0 thiazolone ⁇ Isobacteria aqueous emulsion
- Example 43 21% thiazolone flucyclazole water emulsion Tefmosone 20%, epoxiconazole 1%, propylene glycol 1%, xanthan gum 1%, polyisosuccinic anhydride-polyethylene glycol copolymer 2%, polyoxyethylene block copolymer 2%, silicone elimination
- the foaming agent is 1.5%, and the water is made up to 100%.
- thiazolone 40% of epoxiconazole, 2% of castor oil polyoxyethylene ether, 1% of N-tweldium-based pyrrolidone, 2% of glycerol, 1.1% of polyvinyl alcohol, 2 of benzamidine %, isooctyl alcohol 1%, made up to 100%.
- Formulating one of the active ingredient, thiazolone A, and one of the active ingredients of diacetyl cyanide, dimethomorph, iprodiurea or epoxiconazole with a dispersing agent, a stabilizer, an antifoaming agent and a solvent The proportions are mixed, put into a sanding kettle and ground, and then fed into a homomixer to mix and obtain the finished product.
- Example 45 42% thiazolone ⁇ dicyandione oil suspension
- Example 46 55% thiazolone ⁇ dicyandione oil suspension
- Example 47 30% of thiazolone enoylmorpholine Suspending agent
- Example 48 42% thiazolone ⁇ Dimethomorph oil suspension
- Example 49 18% thiazolone ⁇ Iprobiotic oil suspension
- Example 50 Thiafenone ⁇ Isobacteria oil suspension
- Example 51 30% thiazolone-epoxiconazole oil suspension
- Test subject Huangsu hearing bacteria
- the incidence of cucumber leaves was investigated, and the disease index and control effect were calculated.
- the control effect is converted into the probability value (y)
- the liquid height (g/ml) is converted into a logarithmic value (x)
- the virulence equation is calculated by the least squares method and the medium concentration EC50 is suppressed
- the virulence of the drug is calculated according to the method of Sun Yunpei.
- Measured virulence index (ATI) (standard drug EC50/test drug EC50)*100
- Theoretical virulence index (TTI) ⁇ toxic virulence index * ⁇ of the + + + B Pharmacotoxicity Index * The amount of B in the mixture
- the ratio of thiazolone dicyandione 1 10:1 1.58 205.69 96.37 213.438
- the ratio of thiazolone: dicyandifine 1:1 2.08 156.25 80.05 195.191 ratio of thiazolone: dicyandiamide 1:10 2.26 143.81 63.73 225.655
- Proportional thiabendazole different bacteria 1 2.07 203.38 86.170 236.02
- Test method In the early stage of the disease, immediately spray the first time, and after 7 days, apply the second time, each treatment
- Level 0 no lesions
- Grade 1 The number of leaf lesions is less than 5, and the length is less than lcm
- Grade 3 6-10 leaf lesions, some lesions are longer than lcm;
- Grade 5 11-25 leaf lesions, some lesions are connected into pieces, the lesion area accounts for 10-25% of the leaf area; Grade 7: More than 26 leaf lesions, the lesions are connected into pieces, and the lesion area accounts for 26-50% of the leaf area; Grade 9: The lesions are connected into pieces, and the area of the lesions accounts for more than 50% of the leaf area or the whole leaves die.
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2012387919A AU2012387919B2 (en) | 2012-08-13 | 2012-08-20 | Synergistic fungicide composition |
PL17162712T PL3210470T3 (pl) | 2012-08-13 | 2012-08-20 | Synergistyczna kompozycja fungicydu |
PL17162732T PL3210471T3 (pl) | 2012-08-13 | 2012-08-20 | Synergistyczna kompozycja fungicydu |
EA201590368A EA025481B1 (ru) | 2012-08-13 | 2012-08-20 | Синергетическая фунгицидная композиция |
EP17162712.8A EP3210470B1 (en) | 2012-08-13 | 2012-08-20 | Synergistic fungicide composition |
DK12883005.6T DK2885971T3 (en) | 2012-08-13 | 2012-08-20 | SYNERGISTIC FUNGICIDE COMPOSITION |
CA2881512A CA2881512C (en) | 2012-08-13 | 2012-08-20 | Synergistic fungicide composition comprising benzisothiazolinone |
ES12883005.6T ES2654314T3 (es) | 2012-08-13 | 2012-08-20 | Composición fungicida sinérgica |
US14/421,125 US9282744B2 (en) | 2012-08-13 | 2012-08-20 | Synergistic fungicide composition |
PL12883005T PL2885971T3 (pl) | 2012-08-13 | 2012-08-20 | Synergistyczna kompozycja fungicydu |
EP17162742.5A EP3210472B1 (en) | 2012-08-13 | 2012-08-20 | Synergistic fungicide composition |
EP12883005.6A EP2885971B1 (en) | 2012-08-13 | 2012-08-20 | Synergistic fungicide composition |
LTEP12883005.6T LT2885971T (lt) | 2012-08-13 | 2012-08-20 | Sinergetinė fungicidų kompozicija |
EP17162732.6A EP3210471B1 (en) | 2012-08-13 | 2012-08-20 | Synergistic fungicide composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210287687.2 | 2012-08-13 | ||
CN201210287687.2A CN102763657B (zh) | 2012-08-13 | 2012-08-13 | 具有增效作用的杀菌组合物 |
Publications (1)
Publication Number | Publication Date |
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WO2014026396A1 true WO2014026396A1 (zh) | 2014-02-20 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/CN2012/080379 WO2014026396A1 (zh) | 2012-08-13 | 2012-08-20 | 具有增效作用的杀菌组合物 |
Country Status (13)
Country | Link |
---|---|
US (1) | US9282744B2 (zh) |
EP (4) | EP2885971B1 (zh) |
CN (1) | CN102763657B (zh) |
AU (4) | AU2012387919B2 (zh) |
CA (4) | CA2941028C (zh) |
DK (2) | DK2885971T3 (zh) |
EA (1) | EA025481B1 (zh) |
ES (3) | ES2730205T3 (zh) |
HU (4) | HUE045173T2 (zh) |
LT (3) | LT3210472T (zh) |
PL (3) | PL2885971T3 (zh) |
PT (3) | PT3210470T (zh) |
WO (1) | WO2014026396A1 (zh) |
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CN105613517A (zh) * | 2016-02-29 | 2016-06-01 | 陕西西大华特科技实业有限公司 | 噻霉酮在防治马铃薯疮痂病上的应用及防治马铃薯疮痂病方法 |
CN105613518A (zh) * | 2016-02-29 | 2016-06-01 | 陕西西大华特科技实业有限公司 | 噻霉酮在防治马铃薯黑痣病上的应用及防治马铃薯黑痣病方法 |
WO2018000528A1 (zh) * | 2016-06-26 | 2018-01-04 | 江苏辉丰农化股份有限公司 | 一种杀菌剂组合物 |
WO2022198049A1 (en) * | 2021-03-19 | 2022-09-22 | Arxada, LLC | Biocidal composition and method |
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CN104094950B (zh) * | 2013-06-09 | 2016-06-01 | 江苏辉丰农化股份有限公司 | 具有增效作用的杀菌组合物 |
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EP3282852A1 (en) * | 2015-04-16 | 2018-02-21 | Basf Se | Attenuation of phytotoxicity of multisite fungicides by high-molecular-weight dispersants |
CN105685060A (zh) * | 2015-10-19 | 2016-06-22 | 陕西西大华特科技实业有限公司 | 杀菌组合物的制备及应用 |
CN106818723A (zh) * | 2015-12-04 | 2017-06-13 | 陕西西大华特科技实业有限公司 | 含噻霉酮的组合物及其制备方法 |
CN106259384B (zh) * | 2016-05-30 | 2019-06-21 | 江苏辉丰农化股份有限公司 | 一种杀菌剂组合物 |
CN106538549A (zh) * | 2016-10-31 | 2017-03-29 | 广东中迅农科股份有限公司 | 一种含有噻霉酮和氟吗啉的杀菌组合物 |
CN107306972A (zh) * | 2017-06-13 | 2017-11-03 | 中国农业科学院植物保护研究所 | 百里香酚及其组合物 |
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